CN117050740A - Foaming agent composition - Google Patents
Foaming agent composition Download PDFInfo
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- CN117050740A CN117050740A CN202311018519.8A CN202311018519A CN117050740A CN 117050740 A CN117050740 A CN 117050740A CN 202311018519 A CN202311018519 A CN 202311018519A CN 117050740 A CN117050740 A CN 117050740A
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- foam
- glucoside
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- foaming agent
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000004088 foaming agent Substances 0.000 title claims abstract description 32
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims abstract description 21
- 229940073499 decyl glucoside Drugs 0.000 claims abstract description 21
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims abstract description 16
- 229940048848 lauryl glucoside Drugs 0.000 claims abstract description 16
- 229930182478 glucoside Natural products 0.000 claims abstract description 15
- 150000008131 glucosides Chemical class 0.000 claims abstract description 15
- 229940080421 coco glucoside Drugs 0.000 claims abstract description 11
- 239000004604 Blowing Agent Substances 0.000 claims description 11
- 239000003292 glue Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 85
- 239000007788 liquid Substances 0.000 abstract description 16
- 238000005187 foaming Methods 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 238000000926 separation method Methods 0.000 abstract description 3
- 239000002671 adjuvant Substances 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 33
- 230000032683 aging Effects 0.000 description 25
- 239000003921 oil Substances 0.000 description 12
- 230000008859 change Effects 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920002401 polyacrylamide Polymers 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000001687 destabilization Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000008398 formation water Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000005556 structure-activity relationship Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
Abstract
The present invention provides a foaming agent composition comprising a biomacromolecule hotplate gum, a main foaming agent decyl glucoside, and an adjuvant comprising one or more of cetostearyl glucoside, coco glucoside and lauryl glucoside. The foaming agent composition not only can generate foam with the volume of 4.7 times that of an original foaming system, but also has the half-life of foam liquid separation exceeding 17 hours, and effectively solves the problem of short application plates of the current water-based foam medicament. Meanwhile, the composition has biological affinity and wide material sources, and is environment-friendly and economical.
Description
Technical Field
The invention belongs to the technical field of surface chemistry and high polymer materials, and particularly relates to a foaming agent composition.
Background
Oil recovery can be divided into three distinct stages. The first stage is primary recovery, in which the natural fluid pressure and rock expansion of the reservoir push the crude oil toward the well. Such a kind ofThe method can recover 30% of crude oil. The next stage is secondary oil recovery. In this method, oil is transferred to a production well using water flooding or pressurized non-miscible gas injection techniques, thereby enhancing oil recovery. However, complex geologic formations remain a challenge for the production of reservoir residual oil. To address this problem, foam has been introduced as a miscible fluid in applications to enhance reservoir recovery. Foam has shown great potential in improving surface wave and efficiency and vertical wave and efficiency, thereby significantly improving the recovery efficiency of hydrocarbon reservoirs. The foam is formed by different surfactants and gas phase (air, N 2 Or CO 2 ) Two-phase systems (i.e., flow bubbles and trapped bubbles) are formed. Physically, flowing bubbles cause flow resistance, and trapped bubbles block some flow channels, reducing the relative permeability of the gas. In addition, foam can significantly improve wash efficiency by reducing residual oil saturation, i.e., IFT to ultra-low values, using surfactants to reduce water-oil interfacial tension (IFT). A number of experimental measurements indicate that the presence of oil has an adverse effect on the propagation kinetics of the foam in the porous medium. After the foam enters larger pores and throats in the porous medium, the flow resistance is increased due to the Jamin effect, and then the foam turns to gradually enter smaller pores and throats, so that the oil saturation is higher, and the recovery ratio is improved.
The basic principle of the foam flooding technology is that a certain amount of foaming agent and foam stabilizer are added into injected water, and the injected fluid forms foam in underground pores through gas-liquid co-injection, so that the viscosity of the injected fluid is improved, gas streaming in the stratum is prevented, and powerful foam flakes are generated in a high-permeability area to improve the sweep efficiency of a heterogeneous reservoir. However, the use of foam in porous media also faces challenges such as thermal and mechanical stability of the foam, optimal surfactant concentration to achieve maximum stability, interaction mechanism of the foam-oil interface, in situ generation and expansion of the foam. There are three interdependent conditions for foam destabilization: (1) Foam drainage, under the action of gravity, liquid is separated from the surface of the bubbles, and the surface of the bubbles is blocked by capillary force and shearing stress; (2) liquid film rupture; (3) Gas diffusion between bubbles caused by uneven size distribution of bubbles. The above problems can be improved by increasing the amount of the foaming agent, but the cost is increased, and the conventional ionic surfactant is greatly influenced by divalent ions in the formation water, which is mainly represented by compression of a double-electrode layer of the molecule, so that the dispersion of the surfactant is poor, and the interfacial activity is reduced. Foam properties can be enhanced by adding foam stabilizers (or adjuvants) in addition to foaming agents, which are commonly done by adding polymers to increase the viscosity of the aqueous phase, and by viscous forces to slow the liquid release rate. The network of polymer stretched in solvent water can increase the strength of the liquid film and improve the foam stability. However, common Polyacrylamide (PAM) polymers have the defects of excessively large molecular weight, weak hydration capacity and weak shearing resistance, and can not better solve the problem of premature destabilization of foam.
Disclosure of Invention
In view of the above problems, the present invention provides a foaming agent composition having good stability, and the technical scheme of the present invention is as follows:
the foaming agent composition comprises the following substances in percentage by mass:
the temperature wheel glue is 20-40 wt%;
decyl glucoside, 30-50 wt%;
the total content of the temperature wheel gel and the decyl glucoside is 70-90 wt%;
the rest is at least one of cetostearyl glucoside, coco glucoside and lauryl glucoside.
As a specific embodiment of the present invention, the temperature wheel glue has a weight average molecular weight of 350000g/mol to 670000 g/mol. Preferably, the temperature-wheel glue has a weight average molecular weight of 350000g/mol to 600000g/mol, within which range it is more thermally stable, and further preferably, the temperature-wheel glue has a weight average molecular weight of 500000g/mol, which has excellent stability.
As a specific embodiment of the present invention, the content of the cetostearyl glucoside, coco glucoside, lauryl glucoside is not more than 20wt%.
The invention has the beneficial effects that:
the foaming agent composition containing the nonionic surfactant and the biomacromolecule temperature wheel gel provided by the invention has good dispersibility in oil field injection water, and can be directly used for preparing a foaming system by using the oil field injection water. The foaming agent has a foam stabilizing mechanism that (1) the temperature wheel gel is used as a foam stabilizer, is a microbial extracellular secretion, has a large number of hydrophilic groups in a molecular structure, and endows the temperature wheel gel with extremely strong water absorption and water retention; (2) The temperature wheel glue can generate considerable viscosity, the liquid separation rate can be further reduced through viscous force, and the strength of the foam film is enhanced; (3) All nonionic surfactants adopted in the invention are alkyl polyglycosides, have rich hydrophilic groups, and can form hydrogen bonds with solvent water and temperature wheel glue to generate stable structure-activity relationship.
Drawings
FIG. 1 is a graph of foam analysis half-life versus foam volume for each of the foamer compositions;
FIG. 2 is a microscopic view of the foam prepared from each blowing agent composition over time;
FIG. 3 is a plot of the foam entity produced after stirring the blowing agent composition of example 1 at 3000rad/min for 60 s;
FIG. 4 is a graph of the foam entity produced after stirring the foamer composition of example 3 at a speed of 3000rad/min for 60 s;
FIG. 5 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of comparative example 1 at 120℃ for various periods of time;
FIG. 6 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of comparative example 2 at 120℃ for various periods of time;
FIG. 7 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of comparative example 3 at 120℃ for various periods of time;
FIG. 8 is a graph showing the half-life of the foam concentrate after aging of the blowing agent composition of comparative example 2 at 120℃for various times;
FIG. 9 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of example 1 at 120℃for various periods of time;
FIG. 10 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of example 4 at 120℃for various periods of time;
FIG. 11 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of example 2 at 120℃for various periods of time;
FIG. 12 is a graph showing the half-life of the foam concentrate after aging of the foamer composition of example 3 at 120℃for various periods of time;
FIG. 13 is a comparison of the foam properties prepared in examples 3-6 with varying percentages of temperature-roller gum/decyl glucoside.
Detailed Description
In order to make the technical scheme and technical advantages of the present invention more clear, the technical scheme in the implementation process of the present invention will be clearly and completely described below with reference to the embodiments and the accompanying drawings.
The hotwheel gel used in the invention is purchased from Zhengzhou Kai Yu food additive Co Ltd (industrial grade), decyl glucoside, cocoyl glucoside, lauryl glucoside and cetylstearyl glucoside are purchased from Jiangsu Wan Qiqi biological technology Co Ltd (daily chemical grade, effective content 50%), and the rest medicines are industrial grade unless special description is given;
the brine mentioned in the present invention is composed of 82000ppm NaCl and 1500ppm CaCl 2 1500ppm MgCl 2 Simulated water having a composition mineralization of 85000ppm was formulated to provide a blowing agent composition that was designed to more closely approximate performance testing conditions to the application environment.
Example 1
The foaming agent composition comprises: about 35 parts by weight of a temperature wheel gel having a molecular weight of 600000 g/mol; about 45 parts by weight decyl glucoside; about 8 parts by weight of coco glucoside; about 8 parts by weight of lauryl glucoside and about 4 parts by weight of cetylstearyl glucoside.
Example 2
The foaming agent composition comprises: about 20 parts by weight, a molecular weight of 400000g/mol of a temperature roller gum, about 50 parts by weight of decyl glucoside, about 15 parts by weight of coco glucoside, and about 15 parts by weight of lauryl glucoside.
Example 3
The foaming agent composition comprises: about 40 parts by weight of a temperature roller gum having a molecular weight of 500000g/mol, about 50 parts by weight of decyl glucoside, about 8 parts by weight of lauryl glucoside, and about 2 parts by weight of cetostearyl glucoside.
Example 4
The foaming agent composition comprises: about 35 parts by weight, a molecular weight of 350000g/mol of a temperature roller gum, about 50 parts by weight of decyl glucoside, about 6 parts by weight of lauryl glucoside, and about 9 parts by weight of cetostearyl glucoside.
Comparative example 1
The foaming agent composition comprises: about 35 parts by weight of 300 ten thousand molecular weight polyacrylamide, about 45 parts by weight decyl glucoside, about 8 parts by weight coco glucoside, about 8 parts by weight lauryl glucoside, and about 4 parts by weight cetostearyl glucoside.
Comparative example 2
The foaming agent composition comprises: about 20 parts by weight of a temperature roller gum having a molecular weight of 670000g/mol, about 50 parts by weight decyl glucoside, about 15 parts by weight lauryl glucoside, and about 15 parts by weight cetylstearyl glucoside.
Comparative example 3
The foaming agent composition comprises: about 40 parts by weight of xanthan gum, about 40 parts by weight of decyl glucoside, about 10 parts by weight of coco glucoside, about 5 parts by weight of coco glucoside, and about 5 parts by weight of lauryl glucoside.
Comparative example 4
The foaming agent composition comprises: about 35 parts by weight of 100 ten thousand molecular weight polyacrylamide, about 45 parts by weight decyl glucoside, about 8 parts by weight coco glucoside, about 8 parts by weight lauryl glucoside, and about 4 parts by weight cetostearyl glucoside.
Comparative example 5
The foaming agent composition comprises: about 10 parts by weight of a temperature roller gum having a molecular weight of 500000g/mol, about 50 parts by weight of decyl glucoside, about 8 parts by weight of lauryl glucoside, and about 2 parts by weight of cetostearyl glucoside.
Comparative example 6
The foaming agent composition comprises: about 35 parts by weight, a molecular weight of 350000g/mol of a temperature roller gum, about 15 parts by weight of decyl glucoside, about 6 parts by weight of lauryl glucoside, and about 4 parts by weight of cetostearyl glucoside.
Test case
The test examples mentioned in the present invention are all composed of 82000ppm NaCl and 1500ppm CaCl 2 And a foaming agent composition solution having a mass concentration of 0.4wt% of a simulated water formulation having a mineralization of 85000ppm composed of 1500ppm MgCl2 produced a foam after stirring for 60s at 3000rad/min using a Waring stirrer.
Test example 1 (foam comprehensive Property)
Referring to FIG. 1, FIG. 1 shows the foam volume and foam liquid half-life produced after stirring for 60 seconds at 3000rad/min using a Waring stirrer for examples 1-4 with an effective content of 0.4wt% and comparative examples 1-4 with an effective content of 0.4wt% in a saline solution configuration. It can be seen that the half-lives of the foam of comparative example 1, comparative example 3 and comparative example 4 are all below 5h, while the half-lives of the foam of comparative example 2 containing the hotplate glue and the foam of examples 1-4 are all above 10h, and the half-lives of the foam of examples 1-4 provided by the invention are all above 15h. The foams prepared in example 3 all had the longest foam-to-liquid half-life (20 h) and the foams prepared in example 4 all had the largest foam initial volume (520 mL). The above performance comparison fully demonstrates the excellent performance of the blowing agent compositions provided by the present invention.
Test example 2 (foam microcosmic appearance)
Referring to FIG. 2, FIG. 2 shows the foam particle size change, foam liquid film thickness and foam decay process (0 hours, 2 hours and 6 hours after foaming, shown in sequence from left to right) of the foam produced by stirring the test examples 1-4 and comparative examples 1-4 with a Waring stirrer at 3000rad/min for 60s at 0-6 hours with an effective content of 0.4wt% are listed and compared. The foams of examples 1-4 were drained slower, foam film thickness stabilized and bubbles coalesced slowly over 0-6 hours as compared to the foams of comparative examples 1-4 which were drained faster, foam film thickness decreased and foam particle size increased due to coalescence. The above performance comparison fully shows that the foaming agent composition provided by the invention has stronger water-retaining property.
Test example 3 (foam solid pattern)
FIG. 3 shows example 1, which shows the foam solids produced after stirring with a Waring stirrer at 3000rad/min for 60s at an effective level of 0.4wt%, and the foam break-up time of 16.5h, which is the shortest in the examples provided by the present invention, but comparing FIG. 1, it is clear that example 1 is still much higher in foam stabilizing performance than comparative examples 1-4, even as the blowing agent composition providing the shortest in the present invention.
FIG. 4 shows the foam bodies produced after stirring with a Waring stirrer at 3000rad/min for 60s with an effective content of 0.4wt% for example 3, the foam concentrate half-life being 20h. Comparing the liquid volume of the foam of fig. 3 and 4 at 20h after foaming, it is evident that when 100mL of the foam of example 1 has passed the liquid half-life, the foam prepared in example 3 has just reached the liquid half-life.
Test example 4 (foam Performance vs aging time)
FIG. 5 shows the change in foam properties with aging time at 120℃for a solution of the foaming agent composition of comparative example 1 having an effective content of 0.4% by weight. Wherein the lathering volume is reduced from 370mL in the unaged state to 227mL after 33 days of aging, the lathering performance is greatly lost, and the lathering half-life is reduced from the initial 1 hour to 0.33 hours (about 20 minutes).
FIG. 6 shows the change in foam properties with aging time at 120℃for a solution of the blowing agent composition of comparative example 4 having an effective level of 0.4 wt%. Wherein the lathering volume is reduced from 400mL in the unaged state to 195mL after 33 days of aging, the lathering performance is greatly lost, and the lathering half-life is reduced from the initial 3 hours to 0.6 hours.
FIG. 7 shows the change in foam properties with aging time at 120℃for a solution of the foaming agent composition of comparative example 3 having an effective content of 0.4% by weight. Wherein the foaming volume was reduced from 390mL in the unaged state to 326mL after 33 days of aging, and the foam bath half-life was reduced from the initial 8 hours to 1.2 hours, and the foaming performance was greatly lost.
FIG. 8 shows the change in foam properties with aging time at 120℃for a solution of the foaming agent composition of comparative example 2 having an effective content of 0.4% by weight. Wherein the foaming volume was reduced from 410mL in the unaged state to 355mL after 33 days of aging, and the foam bath half-life was reduced from the initial 10.5 hours to 5.2 hours, and the foaming performance was greatly lost. Comparative example 2 the foaming agent composition contains a hotplate gum, which is a composition containing a biological macromolecule, and has better performance than comparative example 3 containing xanthan gum and comparative examples 1 and 4 containing polyacrylamide.
FIG. 9 shows the change in foam analysis half-life with aging time at 120℃for a 0.4wt% effective level of the example 1 foamer composition solution. Wherein the foaming volume was reduced from 450mL in the unaged state to 411mL after 33 days of aging without significant loss, but the foam's liquid half-life was reduced from the initial 17 hours to 7 hours. As can be seen from a comparison of fig. 5 and 1, the example 1 foamer composition aged for 33 days still performed better than the example 1 foamer composition and the example 4 foamer composition when not aged.
FIG. 10 shows the change in foam analysis half-life over aging time at 120℃for a 0.4wt% effective level of the example 4 foamer composition solution. Wherein the lathering volume was reduced from 520mL in the unaged state to 435mL after 33 days of aging without significant loss, but the lather analysis half-life was reduced from the initial 18 hours to 7.3 hours.
FIG. 11 shows the change in foam analysis half-life with aging time at 120℃for a 0.4wt% effective amount of the example 2 foamer composition solution. Wherein the foaming volume was reduced from 480mL in the unaged state to 420mL after 33 days of aging without significant loss, but the foam analysis half-life was reduced from the initial 17.5 hours to 8.2 hours.
FIG. 12 shows the change in foam analysis half-life over aging time at 120℃for a 0.4wt% effective level of the example 3 foamer composition solution. Wherein the foaming volume was reduced from 500mL in the unaged state to 460mL after 33 days of aging without significant loss, but the foam's liquid half-life was reduced from the initial 20 hours to 9.2 hours. Example 3 the blowing agent composition has all of the comparative examples and the foam properties that are optimal for the examples.
Test example 5 (Performance variation of decyl glucoside and temperature wheel gel in different parts by weight)
Fig. 13 shows the foam properties of the blowing agent compositions of example 3, example 4, comparative example 5 and comparative example 6 at an effective level of 0.4 wt%. Example 3 has the same foaming agent composition as comparative example 5, but the contents of the components are different, the content of the temperature-roller gum in comparative example 5 is 10wt%, the total content of the temperature-roller gum and decyl glucoside is 60wt%, and the liquid separation half-life of comparative example 5 is only 5 hours and is 15 hours less than that of example 3. Also, in example 4 and comparative example 6, the decyl glucoside content in comparative example 6 was 15wt%, and the total content of the temperature roller gum and decyl glucoside was 50wt%, resulting in a foaming volume of 140mL less than that of example 4, and a half-life of 10 hours less than that of example 4.
The present invention is not limited to the above-mentioned embodiments, but is intended to be limited to the following embodiments, and any modifications, equivalents and modifications can be made to the above-mentioned embodiments without departing from the scope of the invention.
Claims (5)
1. A foaming agent composition, which is characterized by comprising the following substances in percentage by mass:
the temperature wheel glue is 20-40 wt%;
decyl glucoside, 30-50 wt%;
the total content of the temperature wheel gel and the decyl glucoside is 70-90 wt%;
the rest is at least one of cetostearyl glucoside, coco glucoside and lauryl glucoside.
2. A foamer composition according to claim 1, characterized in that the hotplate gum has a weight average molecular weight of 350000g/mol to 670000 g/mol.
3. A blowing agent composition according to claim 4 wherein the hotplate gum has a weight average molecular weight of 350000g/mol to 600000 g/mol.
4. A blowing agent composition according to claim 5 wherein the hotplate has a weight average molecular weight of 500000 g/mol.
5. A foaming agent composition according to claim 1, wherein the content of cetostearyl glucoside, coco glucoside, lauryl glucoside is not more than 20% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311018519.8A CN117050740A (en) | 2023-08-14 | 2023-08-14 | Foaming agent composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311018519.8A CN117050740A (en) | 2023-08-14 | 2023-08-14 | Foaming agent composition |
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| Publication Number | Publication Date |
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| CN117050740A true CN117050740A (en) | 2023-11-14 |
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| CN202311018519.8A Pending CN117050740A (en) | 2023-08-14 | 2023-08-14 | Foaming agent composition |
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| Country | Link |
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| CN (1) | CN117050740A (en) |
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2023
- 2023-08-14 CN CN202311018519.8A patent/CN117050740A/en active Pending
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