CN117019832A - Method, device and system for cooperatively disposing solid waste by gasified slag - Google Patents

Method, device and system for cooperatively disposing solid waste by gasified slag Download PDF

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Publication number
CN117019832A
CN117019832A CN202311098077.2A CN202311098077A CN117019832A CN 117019832 A CN117019832 A CN 117019832A CN 202311098077 A CN202311098077 A CN 202311098077A CN 117019832 A CN117019832 A CN 117019832A
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China
Prior art keywords
slag
gasification slag
gasification
particles
solid waste
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Withdrawn
Application number
CN202311098077.2A
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Chinese (zh)
Inventor
李�一
彭扬
罗建军
傅雪
崔海峰
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Jiangsu Yuexiang Environmental Protection Technology Co ltd
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Jiangsu Yuexiang Environmental Protection Technology Co ltd
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Priority to CN202311098077.2A priority Critical patent/CN117019832A/en
Publication of CN117019832A publication Critical patent/CN117019832A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/35Shredding, crushing or cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/32Compressing or compacting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/38Stirring or kneading
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to the technical field of solid waste treatment, in particular to a method, a device and a system for cooperatively disposing solid waste by gasification slag, which comprises the following steps: s1, crushing gasification slag to be treated to obtain gasification slag particles; s2, uniformly mixing gasification slag particles and solid waste according to a preset weight ratio to obtain a mixed material, wherein the solid waste is garbage fly ash or aluminum ash; s3, extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement; s4, conveying the mixture particles to an SPI self-propagating pyrolysis incineration device for self-propagating pyrolysis incineration; s5, crushing the incinerated residues, and sorting according to the particle size to obtain a plurality of products with different particle sizes. The method can be used for cooperatively disposing solid wastes such as garbage fly ash or aluminum ash while harmlessly disposing gasification slag, so that the disposal cost of gasification slag and other solid wastes is saved to a large extent, the harmless disposal and resource recycling of the solid wastes are realized, waste materials are changed into valuable materials, and higher economic value is generated.

Description

Method, device and system for cooperatively disposing solid waste by gasified slag
Technical Field
The invention relates to the technical field of solid waste treatment, in particular to a method, a device and a system for cooperatively disposing solid waste by gasification slag.
Background
The energy structure of China has the characteristics of rich coal, less gas and lean oil, and the energy structure is mainly made of coal. The efficient clean utilization of coal promotes the development of the coal chemical industry, and the coal gasification technology is vigorously developed in recent years as a tap of the coal chemical industry. Coal gasification refers to the process of converting coal into synthesis gas and a small amount of residue by reacting the coal with a gasifying agent to perform various chemical reactions. In 2018, the modern coal chemical industry converts 9560 ten thousand tons of coal altogether, and in the last half of 2019, about 5570 ten thousand tons of coal are converted. With the large-scale popularization of the coal gasification technology, a large amount of gasified slag is generated, and the annual production of gasified slag exceeds 3300 ten thousand tons.
The coal gas slag is generated by incomplete combustion of coal and oxygen or oxygen-enriched air to generate CO and H 2 In the process of (2), inorganic minerals in the coal undergo different physical-chemical transformations along with solid residues formed by residual carbon particles in the coal, and the solid residues can be divided into coarse residues and fine residues. The coarse slag is generated at a slag discharging port of the gasification furnace and accounts for 60% -80%; the fine slag is mainly generated in a dust removing device of the synthesis gas and accounts for 20% -40%. The existing treatment mode of gasified slag mainly comprises stockpiling and landfill, and has not been applied in large-scale industrialization. Along with the large-scale popularization and application of the coal gasification technology, the yield of the gas slag is increased, a large amount of piled gas slag not only pollutes the environment, but also causes the waste of a large amount of land resources, and also causes adverse effects on the sustainable development of various coal chemical enterprises.
The gasification slag is mainly composed of SiO 2 、A1 2 O 3 、MgO、CaO、Fe 2 O 3 And C and other substances, the content of carbon residue in gasified fine slag is higher than that in gasified coarse slag, and in the aspect of recycling, the research on the application of gasified slag at home and abroad is mainly focused on the following aspects: (1) and (3) preparing construction building materials: aggregate, cementing material, wall material, baking-free bricks and the like; (2) soil and method for producing soilAnd (3) water body restoration: soil improvement, water restoration and the like; (3) residual carbon utilization: carbon residue property, carbon residue quality improvement, cyclic blending combustion and the like; (4) preparing a high added value material: catalyst carrier, rubber-plastic filler, ceramic material, silicon-based material, etc. Although the economic benefit is relatively obvious, the problems of high cost, complex flow, difficult regulation and control of impurities, small downstream market and the like are mainly existed in laboratory research or expansion test stage, and the large-scale utilization can not be realized. Meanwhile, due to the characteristics of high carbon content, high impurity content and the like, the problems of low doping amount of construction materials, unstable quality, serious secondary pollution in ecological treatment and the like are caused, and the economic and environmental benefits are poor.
At present, the method mainly adopted by recycling waste gas slags as building material resources comprises two modes of direct utilization, incineration recycling and the like, and Chinese patent document CN106116348A discloses a sunlight greenhouse wall body containing coal gasification slag and a preparation method thereof. The gasified slag has complex components, contains more combustible carbon in the interior, is directly used by reference, has larger influence on the strength and fireproof performance of building materials, has limited application, and is difficult to popularize and apply.
Disclosure of Invention
The invention aims to provide a gasification slag treatment method, a gasification slag treatment device and a gasification slag treatment system, which have the advantages of simple process and high treatment efficiency, and can cooperatively treat solid wastes such as garbage fly ash or aluminum ash while harmlessly treating gasification slag, so that the treatment cost of gasification slag and other solid wastes is saved to a great extent, the harmless treatment and resource recycling of the solid wastes are realized, waste materials are changed into valuable materials, and higher economic value is generated.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
in a first aspect, the invention provides a method for cooperatively disposing solid wastes by gasification slag, which comprises the following steps:
s1, crushing gasification slag to be treated to obtain gasification slag particles;
s2, uniformly mixing gasification slag particles and solid waste according to a preset weight ratio to obtain a mixed material, wherein the solid waste is garbage fly ash or aluminum ash;
s3, extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement;
s4, conveying the mixture particles to an SPI self-propagating pyrolysis incineration device for self-propagating pyrolysis incineration;
s5, crushing the incinerated residues, and sorting according to the particle size to obtain a plurality of products with different particle sizes.
Further, in the step S2, the weight ratio of the gasification slag particles in the mixed material is 50-80%.
Further, in S1, the gasification slag to be treated is crushed to 20 meshes or less.
Further, the extrusion granulation pressure in the step S3 is set to be 2-10 MPa, and the particle size of the prepared mixture particles is 3-8 mm.
Further, the thickness of the incineration layer in the self-propagating pyrolysis incineration in the S4 is 400-600 mm, the incineration temperature is more than or equal to 1000 ℃, and the incineration time is 70-90 min.
In a second aspect, the present invention provides an apparatus for co-disposing of solid wastes from gasification slag, which is capable of performing the steps of the above method for co-disposing of solid wastes from gasification slag, comprising a crushing unit, a mixing unit, a granulating unit, a self-propagating pyrolysis incineration unit and a sorting unit,
the crushing unit is used for crushing the slag to be treated and the burned residues;
the mixing unit is used for uniformly mixing the gasified slag particles and the solid waste according to a preset weight ratio to obtain a mixed material;
the granulating unit is used for extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement;
the self-propagating pyrolysis incineration unit is used for carrying out self-propagating pyrolysis incineration treatment on the mixture particles;
the sorting unit is used for sorting the broken residues according to the particle size to obtain a plurality of products with different particle sizes.
In a third aspect, the invention provides a system for cooperatively disposing solid wastes by using gasification slag, which comprises the device for cooperatively disposing solid wastes by using gasification slag.
The invention has the beneficial effects that:
1. according to the invention, solid wastes such as garbage fly ash, aluminum ash and the like are mixed with crushed gasified slag particles, extrusion granulation is carried out, so that the prepared mixture particles have good air permeability, harmful substances in the mixture can be well removed by combining proper incineration temperature and incineration time in the subsequent SPI self-propagating pyrolysis incineration treatment process, the performance of the product is enhanced, and the product qualification rate is improved.
2. According to the invention, the agglomerated gasification slag is crushed by crushing the gasification slag first and then mixing and extruding the gasification slag for pelletizing, so that the granulated mixture has uniform particle texture, the density of the mixture particles is increased, the subsequent self-propagating pyrolysis incineration is more complete, and the strength of the incinerated product is increased.
3. The invention adopts extrusion granulation to granulate the crushed gasified slag, solid waste mixture such as garbage fly ash, aluminum ash and the like, which is convenient for adjusting the density of the mixture particles so as to control the parameters such as density, porosity, compressive strength and the like of the product obtained by self-propagating pyrolysis incineration. The product particles after self-propagating pyrolysis incineration treatment are larger, and qualified products with different particle diameters are screened out after crushing treatment, so that the recycling utilization of gasified slag, solid wastes such as garbage fly ash and aluminum ash is realized.
4. The invention has simple process and high treatment efficiency, saves the disposal cost of gasification slag, garbage fly ash, aluminum ash and other solid wastes to a great extent, is suitable for the regeneration of various gasification slag, realizes the recycling of resources, changes waste into valuable, and generates higher economic value.
Drawings
FIG. 1 is a flow chart of a method for co-disposing of solid wastes from gasification slag in an embodiment of the present invention;
FIG. 2 is a schematic structural view of an apparatus for co-disposing of solid wastes from gasification slag according to an embodiment of the present invention;
fig. 3 is a schematic structural diagram of a system for co-disposing of solid wastes from gasification slag according to an embodiment of the present invention.
In the figure, the device comprises a 1-crushing unit, a 2-mixing unit, a 3-granulating unit, a 4-self-propagating pyrolysis incineration unit, a 5-sorting unit, a 6-conveying belt, a 7-distributing unit, an 8-flue gas treatment unit, a 9-finished product bin and a 10-raw material bin.
Detailed Description
Further advantages and effects of the present invention will become readily apparent to those skilled in the art from the disclosure herein, by referring to the accompanying drawings and the preferred embodiments. The invention may be practiced or carried out in other embodiments that depart from the specific details, and the details of the present description may be modified or varied from the spirit and scope of the present invention. It should be understood that the preferred embodiments are presented by way of illustration only and not by way of limitation.
It should be noted that the illustrations provided in the following embodiments merely illustrate the basic concept of the present invention by way of illustration, and only the components related to the present invention are shown in the drawings and are not drawn according to the number, shape and size of the components in actual implementation, and the form, number and proportion of the components in actual implementation may be arbitrarily changed, and the layout of the components may be more complicated.
In a first embodiment, referring to fig. 1, a method for co-disposing solid waste by gasification slag includes the following steps:
s1, crushing gasification slag to be treated to obtain gasification slag particles; in the embodiment, the gasification slag to be treated is crushed to have the particle size of 20 meshes or less, so that the subsequent extrusion granulation is facilitated.
S2, uniformly mixing the gasified slag particles and solid waste according to a preset weight ratio to obtain a mixed material, wherein the solid waste is garbage fly ash or aluminum ash.
In this embodiment, the weight ratio of the gasification slag particles in the mixed material is 50-80%. The component content of the mixture is specially limited, and the subsequent extrusion granulation treatment process is combined, so that the prepared mixture particles have good air permeability, harmful substances in the mixture can be well removed by combining proper incineration temperature and incineration time in the subsequent SPI self-propagating pyrolysis incineration treatment process, the performance of the product is enhanced, and the product qualification rate is improved.
And S3, extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement. In this embodiment, the particle size of the mixture particles is required to be 3-8 mm, if the particle size of the prepared mixture particles is too large, the porosity will be too large, the incineration speed is too high, the aggregation of heat is not facilitated, and the incineration temperature is insufficient, so that harmful substances in the mixture cannot be thoroughly removed. If the particle size of the prepared mixture is too small, the air permeability is insufficient, the oxygen content is too low, incomplete combustion is caused, and the incineration temperature is low.
The invention adopts extrusion granulation to granulate the crushed gasified slag, solid waste mixture such as garbage fly ash, aluminum ash and the like, which is convenient for adjusting the density of the mixture particles so as to control the parameters such as density, porosity, compressive strength and the like of the product obtained by self-propagating pyrolysis incineration.
And S4, conveying the mixture particles to an SPI self-propagating pyrolysis incineration device for self-propagating pyrolysis incineration, wherein the incineration layer thickness is 400-600 mm, and sequentially entering a drying preheating section, an ignition section, an incineration section and a residue cooling section of the SPI self-propagating pyrolysis incineration device according to a preset speed, wherein the incineration temperature is 800 ℃ and above, and the incineration time is 70-90 min. The thickness of the incineration layer, the incineration temperature and the incineration time are reasonably adjusted according to actual conditions.
S5, crushing the incinerated residues, and sorting according to the particle size to obtain a plurality of products with different particle sizes.
The whole method has simple flow and high treatment efficiency, saves the treatment cost of gasification slag, garbage fly ash, aluminum ash and other solid wastes to a great extent, is suitable for the regeneration of various gasification slag, realizes the recycling of resources, changes waste into valuable, and generates higher economic value.
In a second embodiment, referring to fig. 2, a device for cooperatively disposing solid wastes from gasification slag is capable of executing the steps of the method for cooperatively disposing solid wastes from gasification slag, and includes a crushing unit 1, a mixing unit 2, a granulating unit 3, a self-propagating pyrolysis incineration unit 4 and a sorting unit 5, wherein the crushing unit 1 is used for crushing the gasification slag to be treated and the residue after incineration; the mixing unit 2 is used for uniformly mixing gasification slag particles with solid wastes such as garbage fly ash, aluminum ash and the like according to a preset weight ratio to obtain a mixed material; the granulating unit 3 is used for extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement; the self-propagating pyrolysis incineration unit 4 is used for carrying out self-propagating pyrolysis incineration treatment on the mixture particles; the sorting unit 5 is used for sorting the broken residues according to the particle size to obtain a plurality of products with different particle sizes. The device has simple structure and high treatment efficiency, saves the treatment cost of solid wastes such as gasified slag, garbage fly ash, aluminum ash and the like to a great extent, is suitable for the regeneration of various gasified slag, realizes the recycling of resources, changes waste into valuable, and generates higher economic value.
In a third embodiment, referring to fig. 3, a system for co-disposing of solid waste by using gasification slag includes the device for co-disposing of solid waste by using gasification slag as described above. The specific working flow of the system is as follows: the gasified slag in the raw material bin 10 is fed to a conveying belt 6, the gasified slag is conveyed to a crushing unit 1 through the conveying belt 6 for crushing and screening, the gasified slag powder with the grain diameter of 20 meshes or less enters a mixing unit 2 to be uniformly mixed with solid wastes such as garbage fly ash, aluminum ash and the like, and the gasified slag powder with the grain diameter of more than 20 meshes returns to the crushing unit 1 for crushing treatment again.
The crushed gasified slag powder and solid waste such as garbage fly ash, aluminum ash and the like are uniformly mixed in a mixing unit 2 to obtain a mixed material.
The mixture is conveyed to a granulating unit 3 through a conveying belt 6 for extrusion granulation, and the mixture particles meeting the particle size requirement are obtained.
And conveying the mixture particles meeting the particle size requirement obtained by extrusion granulation to a self-propagating pyrolysis incineration unit 4 through a distribution unit 7 for self-propagating pyrolysis incineration treatment, purifying the fume generated by incineration through a fume treatment unit 8, and discharging the fume into the atmosphere. And conveying the incinerated residues to a crushing unit 1 for crushing treatment, and then conveying to a sorting unit 5 for sorting according to the particle size to obtain a plurality of products with different particle sizes. The product is transported to a finished product warehouse 9 for storage.
The above embodiments are merely preferred embodiments for fully explaining the present invention, and the scope of the present invention is not limited thereto. Equivalent substitutions and modifications will occur to those skilled in the art based on the present invention, and are intended to be within the scope of the present invention.

Claims (7)

1. The method for cooperatively disposing the solid waste by the gasified slag is characterized by comprising the following steps:
s1, crushing gasification slag to be treated to obtain gasification slag particles;
s2, uniformly mixing gasification slag particles and solid waste according to a preset weight ratio to obtain a mixed material, wherein the solid waste is garbage fly ash or aluminum ash;
s3, extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement;
s4, conveying the mixture particles to an SPI self-propagating pyrolysis incineration device for self-propagating pyrolysis incineration;
s5, crushing the incinerated residues, and sorting according to the particle size to obtain a plurality of products with different particle sizes.
2. The method for cooperatively disposing solid wastes from gasification slag according to claim 1, wherein: and S2, the weight ratio of the gasification slag particles in the mixed material is 50-80%.
3. The method for cooperatively disposing solid wastes from gasification slag according to claim 1, wherein: and S1, crushing the gasification slag to be treated to a particle size of 20 meshes or less.
4. The method for cooperatively disposing solid wastes from gasification slag according to claim 1 or 2, characterized in that: and S3, setting the extrusion granulating pressure to be 2-10 MPa, and setting the particle size of the prepared mixture particles to be 3-8 mm.
5. The method for cooperatively disposing solid wastes from gasification slag according to claim 1 or 2, characterized in that: and S4, arranging the thickness of the incineration layer in the self-propagating pyrolysis incineration process to be 400-600 mm, wherein the incineration temperature is more than or equal to 1000 ℃, and the incineration time is 70-90 min.
6. The utility model provides a gasification sediment is device of disposing solid useless in coordination which characterized in that: the method for cooperatively disposing solid wastes from gasification slag according to any one of claims 1 to 5, comprising the steps of:
the crushing unit is used for crushing the slag to be treated and the burned residues;
the mixing unit is used for uniformly mixing the gasified slag particles and the solid waste according to a preset weight ratio to obtain a mixed material;
the granulating unit is used for extruding and granulating the mixture to obtain mixture particles meeting the particle size requirement;
the self-propagating pyrolysis incineration unit is used for carrying out self-propagating pyrolysis incineration treatment on the mixture particles;
and the sorting unit is used for sorting the crushed residues according to the particle size to obtain a plurality of products with different particle sizes.
7. The utility model provides a gasification sediment is system of disposing solid useless in coordination which characterized in that: an apparatus comprising the gasification slag of claim 6 for co-disposal of solid waste.
CN202311098077.2A 2023-08-29 2023-08-29 Method, device and system for cooperatively disposing solid waste by gasified slag Withdrawn CN117019832A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311098077.2A CN117019832A (en) 2023-08-29 2023-08-29 Method, device and system for cooperatively disposing solid waste by gasified slag

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311098077.2A CN117019832A (en) 2023-08-29 2023-08-29 Method, device and system for cooperatively disposing solid waste by gasified slag

Publications (1)

Publication Number Publication Date
CN117019832A true CN117019832A (en) 2023-11-10

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