CN1170062A - Process for continuous dyeing of plyester yarns - Google Patents

Process for continuous dyeing of plyester yarns Download PDF

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Publication number
CN1170062A
CN1170062A CN97110988A CN97110988A CN1170062A CN 1170062 A CN1170062 A CN 1170062A CN 97110988 A CN97110988 A CN 97110988A CN 97110988 A CN97110988 A CN 97110988A CN 1170062 A CN1170062 A CN 1170062A
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Prior art keywords
yarn
dye solution
dye
grams per
dyestuff
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Inventor
R·珍尼
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Novartis AG
BASF Schweiz AG
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Ciba Geigy AG
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • D06B19/0005Fixing of chemicals, e.g. dyestuffs, on textile materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00Successive treatments of textile materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • D06P1/50Derivatives of cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257(Meth)acrylic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/54Polyesters using dispersed dyestuffs

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Method for continuous dyeing of polyester yarn with disperse dyes comprises spraying an aqueous dyebath containing disperse dye and migration inhibitor onto polyester filament(s) running continuously at high speed from a yarn reservoir to a yarn collector, and then fixing the dye on the yarn.

Description

The method of continuous dyeing of plyester yarns
The present invention relates to a kind of passing through makes the fixing of dye make the method for continuous dyeing of plyester yarns on fiber on the yarn of dyestuff spray-painting to one or more fast moving subsequently.
For example for polyamide yarn dyeing, this class colouring method and equipment are known, also make many effort here, make polyester yarn dyeing with similar mode.But up to the present resulting result can not be satisfactory, particularly has the level dyeing degree difference of dyed yarn and the problem of frosting.It is shocking that found now that a kind of this method is based on being added to specific dyeing assistant in the dye solution with the continuous spray-painting of DISPERSE DYES improving one's methods to the polyester yarn, this method can produce level dyeing, and non-blooming.
So, the present invention relates to a kind of method that makes continuous dyeing of plyester yarns with DISPERSE DYES, this method comprises on the polyester yarn that the moisture dye solution spray-painting that will contain at least a DISPERSE DYES and a kind of migration inhibitor moves to yarn coiler device continuous high speed to one or more from the yarn storage facility, makes the fixing of dye then to yarn.
In each case, to also have the yarn coiler device for example be a bobbin or several bobbins of arbitrary arrangement or dye beams to the yarn storage facility.Therefore, yarn or various yarn are transferable, for example from the bobbin to the bobbin, from one or more bobbins to dye beams, from dye beams to one or more bobbins or from the dye beams to the dye beams, shift.
The translational speed of yarn from the yarn storage facility to the yarn coiler device for example be 〉=100 meters/minute, preferred 〉=150 meter/minute, more preferably 200~800 meters/minute, preferred especially 200~600 meters/minute.
Dye solution preferably uses the nozzle spray-painting to yarn, on yarn also is possible with several different dye solutions by the one-pass mode spray-painting of yarn with several nozzles of arranging arbitrarily.The present invention's one embodiment preferred relates to the generation effect dyeing.These for example can be used on nozzle and the yarn that moves past between the rotation porous disc installed produce, porous disc guarantees that dye solution is penetrated on the yarn at interval at some.Therefore the production of effect yarn is possible, for example, if a kind of dye solution spray-painting is had on the yarn of rotation porous disc to the centre with nozzle.If the yarn that moves past with several different dye solution spray-paintings, being coated with of dye solution spilt the rotation porous disc of all using therebetween and controlled under each situation, therefore can get various polychromatic dyeings.
Contained dyestuff is a DISPERSE DYES in dyeing liquor, and they are generally used for Polyester Fibers dyeing, for example at " color index ", the 3rd edition, 1971 and title be in the supplement of " DISPERSE DYES ".Its example is monoazo dyes, polyazo dye, anthraquinone dye or the nitro aryl dyestuff that does not contain sulfo group.
The quantity of dyestuff can change in wide region in dye solution, and this is relevant with required depth of color, and its amount for example is 5~100 grams per liter dye solutions, preferred 10~70 grams per liter dye solutions, preferred especially 10~50 grams per liter dye solutions.The used dye solution of the present invention can contain one or more dyestuffs.
The migration inhibitor that is applicable to the inventive method for example is (i) cellulose derivative, as cellulose ether, as methyl-, ethyl-, ethoxy-, dimethyl hydroxyethyl-, hydroxypropyl-, hydroxypropyl methyl-, carboxymethyl-, carboxyethyl-or cyanoethyl-cellulose; Or cellulose esters, as the acetyl group cellulose; (ii) based on the synthetic thickening agent of polyacrylate, as contain the prescription of following component: the copolymer of acrylic acid and acrylamide, acrylic acid copolymer and polyacrylic mixture or by acrylamide or the acid amides of Methacrylamide (as propylene propylamine, Methacrylamide or N,N-DMAA) and N-vinyl-replacement or the copolymer that vinyl esters (as N-vinyl-N methacrylamide) makes unsubstituted or that N-replaces; Perhaps (iii) alginates are as mosanom.
Alginates are preferred as the migration inhibitor in the methods of the invention.
The quantity of migration inhibitor in dye solution is preferably 1~10 grams per liter dye solution, more preferably 1~5 grams per liter dye solution, preferred especially 1~3 grams per liter dye solution.
Except dyestuff and migration inhibitor, dye solution also can contain additive, as the infiltration accelerator.The infiltration accelerator that is fit to is known, for example by textile auxiliary sample 1994/95, and KonradinVerlag Robert Kohlhammer, Leinfelden Echterdingen is known in title 3.3 dyeing wetting agents and the degasser.The infiltration accelerator that is preferred for this method contains one or more and is selected from alcohol ethoxylate, alkaryl ethoxylate, alkylene oxide particularly oxirane, expoxy propane or both mixtures add to addition compound product, alkylphosphonate, alkane sulfonate, alkyl aryl ether sulfate, paraffin oil and aliphatic series on the highly undersaturated or saturated aliphatic acid or the component of aromatic carboxylic acid ester.
If the infiltration accelerator contains alcohol ethoxylate, it for example can meet following formula so
R-(CH 2-CH 2-O) P-(CHY 1-CHY 2-O) q-R 1(1) in the formula, R is C straight chain or side chain 8-C 22Alkyl, R 1Be C straight chain or side chain 1-C 8Alkyl, C 5~C 8Cycloalkyl, phenyl-C 1~C 4Alkyl or styryl, Y 1And Y 2In one be methyl or ethyl, and another is a hydrogen, p and q independently are the number in 0~24 separately, the p+q sum is 2~24.
R base C in formula (1) 8~C 22Alkyl for example can be octyl group straight chain or side chain, nonyl, decyl, undecyl, dodecyl, tridecyl, myristyl, pentadecyl, cetyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl or docosyl.R is preferably C straight chain or side chain 8~C 14Alkyl is preferably C especially 8~C 10Alkyl.
R 1Base C 1~C 8Alkyl for example can be methyl, ethyl, n-pro-pyl or isopropyl, normal-butyl, isobutyl group, sec-butyl or the tert-butyl group, or amyl group straight chain or side chain, hexyl, heptyl or octyl group.R here 1Be preferably C 1~C 4Alkyl.
R 1Base C 5~C 8Cycloalkyl for example can be cyclopentyl or particularly cyclohexyl, and they can be unsubstituted or by methyl substituted.
R 1Base phenyl-C 1~C 4Alkyl for example is phenethyl or particularly benzyl.
R 1Be preferably C 1~C 4Alkyl, cyclohexyl or benzyl, preferred especially C 1~C 4Alkyl.
P is preferably the number, preferred especially 4~9, especially preferred 6~8 in 2~24.Q is preferably the number, preferred especially 1~8, especially preferred 1~3 in 0~15.P and q can be integer, also can be mark.
Particularly preferred alcohol ethoxylate is the alcohol ethoxylate of the formula (1) stipulated above, and wherein R is C straight chain or side chain 8~C 14Alkyl, R 1Be C 1~C 4Alkyl, p are the number in 4~9, and q is the number in 1~3, and Y 1And Y 2For what as above stipulate.
Particularly preferred infiltration accelerator is the aqueous formulation that contains alcohol ethoxylate and alkylphosphonate.
The infiltration quantity of accelerator in dye solution is preferably 1~10 grams per liter dye solution, more preferably 1~4 grams per liter dye solution.
The used dye solution of the inventive method also can contain ultra-violet absorber, and for example ultra-violet absorber is used for making polyester fiber photochemical stable and thermally-stabilised.For experienced technical staff, the ultra-violet absorber that is fit to is known.Ultra-violet absorber for example is 2-hydroxyl benzophenone, 2-(2 '-hydroxyphenyl) benzotriazole, 2-hydroxyphenyl-1,3,5-triazine, oxalic acid diamides, acrylate, cinnamate or replacement or unsubstituted benzoic acid or its ester, preferred 2-hydroxyphenyl-1,3, the 5-triazine.
Dye solution also can contain other additives commonly used, as wetting agent, acid or alkali.
Dyestuff preferably be not higher than 95 ℃, particularly be not higher than under 80 ℃ the temperature spray-painting on yarn.It is particularly preferred not being higher than 70 ℃ here, particularly not being higher than 60 ℃ temperature.It is especially preferred not being higher than 50 ℃, particularly not being higher than 40 ℃ temperature.Preferred lowest temperature is 5 ℃, preferred 10 ℃, preferred especially 15 ℃.Flood the temperature of yarn and in the spray-painting process temperature of dye solution in the said temperature one is here arranged.It is significant especially at room temperature for example carrying out spray-painting under 5~40 ℃, preferred 10~40 ℃, preferred especially 15~40 ℃, so that before the spray-painting step, particularly in the spray-painting process, fully different heating equipment.The above-mentioned step that yarn is twisted in one or more thread-carriers 3 that preferably also is applicable to.The above-mentioned spray-painting material step in the past that preferably yet is applicable to did not particularly heat yarn in the past in this spray-painting.
Spray-painting is after on the yarn for dyestuff, and dyestuff is fixed on the polyester yarn with method commonly used, for example by the effect of heat.
If the effect by heat is fixed, this rule steam method or thermosol method in this way so.
In steam method, in steamer, use steam treatment with the textile strand of dye solution dipping, water vapour can be superheated steam, is preferably 98~210 ℃, more preferably 100~180 ℃, most preferably is 102~130 ℃ of steam.
Can be in the middle of do not have not dry or have under middle the drying and carry out with so-called thermosol method fixed dye, for example 140-210 ℃, preferred 140-220 ℃, drying in the middle of 140-180 ℃ most preferably.Thermosol was handled sustainable 20 seconds to 5 minutes, preferred 30~60 seconds, and this is relevant with used temperature.
After the dyeing course, dyed yarn cleans with method commonly used usually, for example cleans with hot water or cold water or cleans with the reduction post processing, and is dry then.
Decatize and drying are preferably carried out continuously, for example carry out with superheated steam in steamer, preferably 98-210 ℃, more preferably 100-180 ℃, most preferably 102~150 ℃ of processing down.
Use method of the present invention, might under high speed, make polyester yarn dyeing, be i.e. high productive rate was arranged in the unit interval.In addition, method of the present invention can be produced effect yarn, and effect yarn can only make with the yarn that spins several different colours so far, and can not make with decoration method.In addition, method of the present invention has special significance in the application of automobile sector.If this method is carried out with the dye solution that contains ultra-violet absorber, so therefore can produce the fabulous photochemical stability and the polyester yarn of heat endurance, as required, for example be used for production automotive seats cover.
Following embodiment is used for illustrating the present invention.
Embodiment 1
Will be by spinning continuously on natural white warp thread piece that polyester bulk yarn the makes speed with 200 meters/minute winds the line fixed band from the yarn storage facility, in this process, with the dye solution spray-painting of nozzle with following composition, excessive dyestuff blows off with air-flow.The composition of dye solution: the dyestuff F of 2.6 grams per liter following formulas 1 3.6 grams per liter contains the dye mixture F of following formula dyestuff 2 1.7 the dyestuff F of grams per liter following formula 3
Figure A9711098800083
2.5 the moderately viscous mosanom 2.0 grams per liters infiltration of the grams per liter accelerator (straight chain C that contains alkyl terminal groups end-blocking 9-C 11The fatty alcohol ethoxy
Baseization thing, castor oil polyglycol ether, paraffin oil, maleic acid two (2-ethylhexyl)
Ester, di(2-ethylhexyl)phosphate (2-ethylhexyl) ester and NaOH are water-soluble as main component
Liquid)
The warp thread piece of deposition is dry under 145 ℃ then, fixes with heated dry air under 180 ℃ subsequently.Behind hot wash operation and subsequent drying, yarn-dyed one-tenth light brown pool, it has good all round properties.
As described in step such as the embodiment 1; but use 2.5 grams per liter methyl-, ethyl-, ethoxy-, dimethyl hydroxyethyl-, hydroxypropyl-, hydroxypropyl methyl-, carboxymethyl-, carboxyethyl-or the prescription of cyanoethyl-cellulose, acetyl group cellulose, the copolymer that contains acrylic acid and acrylamide, acrylic acid copolymer and polyacrylic mixture or the copolymer that makes by acrylamide, Methacrylamide or N,N-DMAA and N-vinyl-N methacrylamide replace the moderately viscous mosanom of 2.5 grams per liters.Obtain being coloured to the yarn of light brown gloss equally.
Embodiment 2
On the natural white warp thread piece that will be made by the polyester staple fiber yarn winds the line fixed band with 200 meters/minute speed from the yarn storage facility, in this process, with the dye solution spray-painting of nozzle with following composition.The porous disc of one rotation is installed in dye nozzles and the warp thread piece that moves past between, only be penetrated on the yarn at interval to guarantee dye solution at some.The composition of dye solution: the dyestuff F of 5.0 grams per liter following formulas 4
Figure A9711098800091
1.7 the dyestuff F of grams per liter following formula 5
Figure A9711098800092
3.0 the dyestuff F of grams per liter embodiment 1 33.0 the moderately viscous mosanom 1.5 grams per liters infiltration of the grams per liter accelerator (straight chain C that contains alkyl end group end-blocking 9~C 11The fatty alcohol ethyoxyl
Change thing, castor oil polyglycol ether, paraffin oil, maleic acid two (2-ethylhexyl) ester,
Di(2-ethylhexyl)phosphate (2-ethylhexyl) ester and NaOH are as the aqueous solution of key component)
The ultra-violet absorber UV of 20 grams per liter following formulas 1
Figure A9711098800101
Then with the warp thread piece drying that deposits, and with heated dry air or dry in vapours, subsequently with hot water clean, dry and reel, obtain a kind of effect yarn, it is coloured to olive-ash, it satisfies the requirement of automobile sector to light fastness, and wherein be unstained part and coloured portions replace.
Embodiment 3
On the natural white warp thread piece that will be made by the polyester staple fiber yarn winds the line fixed band with 200 meters/minute speed from the yarn storage facility, in this process, with three kinds of different dyes liquid spray-painting of nozzle with following composition.The porous disc of one rotation is installed in dye nozzles and the yarn that moves past between, only can be penetrated on the yarn at interval under each situation to guarantee dye solution at some.The composition of maceration extract: the dyestuff F of dye solution 1:20 grams per liter embodiment 2 41.7 the dyestuff F of grams per liter embodiment 2 54.0 the moderately viscous mosanom 1.5 grams per liters infiltration of the grams per liter accelerator (straight chain C that contains alkyl end group end-blocking 9~C 11The fatty alcohol ethyoxyl
Change thing, castor oil polyglycol ether, paraffin oil, maleic acid two (2-ethylhexyl) ester,
Di(2-ethylhexyl)phosphate (2-ethylhexyl) ester and NaOH are as the aqueous solution of key component) the ultra-violet absorber UV of 20 grams per liter embodiment 2 1The dyestuff F of dye solution 2:6.0 grams per liter embodiment 2 42.0 the dyestuff F of grams per liter embodiment 2 52.6 the dyestuff F of grams per liter embodiment 1 32.1 the dyestuff F of grams per liter following formula 6
Figure A9711098800111
4.0 the moderately viscous mosanom 1.5 grams per liters infiltration of the grams per liter accelerator (straight chain C that contains alkyl end group end-blocking 9~C 11Alcohol ethoxylate, castor oil polyglycol ether, paraffin oil, maleic acid two (2-ethylhexyl) ester, di(2-ethylhexyl)phosphate (2-ethylhexyl) ester and NaOH are as the aqueous solution of key component) the ultra-violet absorber UV of 20 grams per liter embodiment 2 1The dyestuff F of dye solution 3:18.0 grams per liter embodiment 2 46.0 the dyestuff F of grams per liter embodiment 2 57.8 the dyestuff F of grams per liter embodiment 1 36.3 the dyestuff F of grams per liter dye solution 2 64.0 the moderately viscous mosanom 1.5 grams per liters infiltration of the grams per liter accelerator (straight chain C that contains alkyl end group end-blocking 9~C 11The fatty alcohol ethyoxyl
Change thing, castor oil polyglycol ether, paraffin oil, maleic acid two (2-ethylhexyl) ester,
Di(2-ethylhexyl)phosphate (2-ethylhexyl) ester and NaOH are as the aqueous solution of key component) the ultra-violet absorber UV of 20 grams per liter embodiment 2 1
The warp thread piece drying of deposition is also fixed with 180 ℃ of heated drying air, subsequently with hot water cleaning, dry and coiling.Obtain the effect yarn of polychrome, it satisfies automobile sector to the light fastness performance demands, and wherein orange, light grey and middle grey color and luster section alternately exists.

Claims (11)

1. method that makes continuous dyeing of plyester yarns with DISPERSE DYES, this method comprise will contain the moisture dye solution spray-painting of at least a DISPERSE DYES and migration inhibitor to on one or more polyester yarn that move continuously from the yarn storage facility to the yarn coiler device at a high speed, then with the fixing of dye on yarn.
According to the process of claim 1 wherein the translational speed of yarn from the yarn storage facility to the yarn coiler device more than or equal to 150 meters/minute, preferred 200-800 rice/minute.
3. according to the method for claim 1 or 2, wherein cellulose ether, cellulose esters, based on the synthetic thickening agent of polyacrylate or alginates as the migration inhibitor, preferred alginates.
4. according to each method in the claim 1~3, wherein DISPERSE DYES is monoazo dyes, two azo dyess, polyazo dye, anthraquinone dye or nitro aryl dyestuff.
5. according to each method in the claim 1~4, wherein moisture dye solution also contains the infiltration accelerator.
6. according to the method for claim 5, wherein used infiltration accelerator is to contain to be selected from alcohol ethoxylate, alkyl aryl ethoxylates, alkylene oxide particularly oxirane, expoxy propane add to the composition of one or more components of addition product, alkylphosphonate, alkane sulfonate, alkyl aryl ether sulfate, paraffin oil and aliphatic series on the highly undersaturated or saturated aliphatic acid or aromatic carboxylic acid ester.
7. according to the method for claim 5, wherein used infiltration accelerator is the composition that contains alcohol ethoxylate and alkylphosphonate.
8. according to each method in the claim 1~7, wherein dye solution also contains ultra-violet absorber.
9. according to each method in the claim 1~8, wherein dyestuff is by heat effect, preferably be fixed on the yarn by heated drying air or saturated vapor effect.
10. method that produces effect dyeing according to claim 1 with DISPERSE DYES at polyester, this method comprises uses the nozzle spray-painting to one or more yarns that move continuously from the yarn storage facility to the yarn coiler device with high speed the dye solution that contains at least a DISPERSE DYES and a kind of migration inhibitor, control the coating of dye solution with the rotation porous disc between the yarn that is installed in nozzle and moves past, so that dye solution only reaches at interval on the yarn at some; And make the fixing of dye on fiber.
11. method that produces polychromatic dyeing according to claim 10, this method with nozzle with several different dye solution spray-paintings to yarn, the coating of each single dye solution is controlled with the rotation porous disc between the yarn that is installed in nozzle and moves past, so that dye solution only reaches on the yarn at interval at some under each situation.
CN97110988A 1996-05-03 1997-04-29 Process for continuous dyeing of plyester yarns Pending CN1170062A (en)

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CH1137/96 1996-05-03

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CN101619527B (en) * 2009-07-15 2012-05-09 无锡市天然绿色纤维科技有限公司 Camouflage color yarn production method
CN103498343A (en) * 2013-10-08 2014-01-08 南通田园纺织科技有限公司 High sunlight-resistant terylene decorative cloth
CN106436358A (en) * 2016-08-23 2017-02-22 苏州市恒信针织印染有限责任公司 Natural dyeing composition for polyester fabrics and application of natural dyeing composition
CN108978276A (en) * 2018-08-09 2018-12-11 界首市恒仁服饰有限公司 A kind of dyeing treatment of polyester fabric
CN111041624A (en) * 2019-12-20 2020-04-21 恩平锦兴纺织印染企业有限公司 Preparation process of polyester fabric with efficient sweat absorption and sweat discharge effects

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DE10212233B4 (en) * 2001-03-19 2012-05-10 Textilforschungsinstitut Thüringen-Vogtland e.V. Method for producing forgery-proof marking threads and arrangement for carrying out the method
KR20040045534A (en) * 2002-11-23 2004-06-02 김영균 Dyeing method of synthetic fiber filament yarn

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Publication number Priority date Publication date Assignee Title
CN101619527B (en) * 2009-07-15 2012-05-09 无锡市天然绿色纤维科技有限公司 Camouflage color yarn production method
CN103498343A (en) * 2013-10-08 2014-01-08 南通田园纺织科技有限公司 High sunlight-resistant terylene decorative cloth
CN103498343B (en) * 2013-10-08 2016-02-24 南通田园纺织科技有限公司 A kind of high sunlight-resistant terylene decorative cloth
CN106436358A (en) * 2016-08-23 2017-02-22 苏州市恒信针织印染有限责任公司 Natural dyeing composition for polyester fabrics and application of natural dyeing composition
CN108978276A (en) * 2018-08-09 2018-12-11 界首市恒仁服饰有限公司 A kind of dyeing treatment of polyester fabric
CN111041624A (en) * 2019-12-20 2020-04-21 恩平锦兴纺织印染企业有限公司 Preparation process of polyester fabric with efficient sweat absorption and sweat discharge effects

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EP0805229A3 (en) 1999-05-26
TW333572B (en) 1998-06-11
JPH1037082A (en) 1998-02-10
TR199700330A3 (en) 1997-11-21
TR199700330A2 (en) 1997-11-21

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