CN1169934C - Phosphateless environmentally friendly washing powder - Google Patents
Phosphateless environmentally friendly washing powder Download PDFInfo
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- CN1169934C CN1169934C CNB021241872A CN02124187A CN1169934C CN 1169934 C CN1169934 C CN 1169934C CN B021241872 A CNB021241872 A CN B021241872A CN 02124187 A CN02124187 A CN 02124187A CN 1169934 C CN1169934 C CN 1169934C
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- washing powder
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Abstract
The present invention relates to environment protection type washing powder without phosphorous, which belongs to the field of a detergent. The washing powder comprises components of the following content: 20 to 30 wt% of sodium carbonate, 5 to 19 wt% of sodium silicate, 14 to 30 wt% of anhydrous sodium sulfate, 2 to 5 wt% of fatty alcohol-polyoxyethylene ether, 5 to 35 wt% of coconut oil powder and 0.5 to 2 wt% of sodium carboxymethylcellulose. Sodium bicarbonate with a total addition amount of 4 to 6 wt% of the environment protection type washing powder withoutphosphorous is further added to the environment protection type washing powder without phosphorous. The washing powder of the present invention has the advantages of great washing power, biodegradable degree of 99%, no pollution, and abundant raw material source.
Description
Technical field
The invention belongs to detergent applications, particularly Phosphateless environmentally friendly washing powder.
Background technology
Many weeks, phosphorus in the phosphoric acid salt is one of indispensable composition of plant-growth, if the phosphorated clean-out system is along with in the river the flows to various waters, will cause the appearance of water quality eutrophication, it breeds the pasture and water in the water in a large number, and pasture and water must absorb a large amount of oxygen in the water, water oxygen level is reduced, organism in water can't be survived and mass mortality, impel bacterium to have little time to decompose carcase and water quality is fouled, anerobe multiplies rapidly, also can produce toxin and unpleasant sulfocompound, can make water quality corrupt in not using.White dyes is in being applied to cleaning fabric in addition, and it can be transferred to from washing powder and be washed in the fabric, and white dyes and skin have extremely strong bonding force, once combine with skin, skin is produced stimulates easily.
Tensio-active agent and decontamination ratio relation in table 1 washing powder
| Kind | Quantity/number | Surfactant content/% | Decontamination ratio | |||||||
| Scope | On average | Scope | On average | |||||||
| Time | 1998 | 2000 | 1998 | 2000 | 1998 | 2000 | 1998 | 2000 | 1998 | 2000 |
| Contain phosphorus powder | 68 | 40 | 11-23 | 10-24 | 15.98 | 16.60 | 0.9-2 | 1.1- 2.5 | 1.40 | 1.52 |
| No phosphorus powder | 60 | 12 | 6-29 | 8-23 | 16.25 | 17.50 | 0.7-1.6 | 1.1- 1.6 | 1.17 | 1.27 |
In [tensio-active agent and decontamination ratio relation in the washing powder] table 1 that provides according to calendar year 2001 light industry " household chemicals science " magazine the 24th volume the 6th phase " focus search ", we see that existing market sells present situation phosphorous and non-phosphide detergent, decontamination index is that scourability is all undesirable and contain the severe contamination of phosphorus product to environment, and it is imperative therefore to develop the cleaning product that high-performance, safety, environmental protection, raw material be easy to get.
The all uses of phosphorus restriction in washing composition of most of country such as Japan, America and Europe at present, the domestic use that under the major premise of environmental protection regulation, has also begun phosphorus restriction at present.
Summary of the invention
The objective of the invention is to overcome existing phosphorous all undesirable, and contain phosphorus product and environment is easily caused defectives such as severe contamination, provide a kind of soil removability strong Phosphateless environmentally friendly washing powder with the non-phosphide detergent scourability.
The present invention adopts yellow soda ash to remove the pollution of phosphorus to environment, simultaneously good cleaning function is arranged again, is the natural environmental-protective raw material.Adopt senior cocounut oil powder tensio-active agent, its cocounut oil powder is that white particle is water-soluble, has good decontamination, dispersion, degreasing, wetting and emulsifying capacity, and its biological degradability is 99%.Fatty alcohol-polyoxyethylene ether is a nonionogenic tenside, and biological degradability is extremely low, can replace TX-10, has decontamination, soft fiber, demineralized water function.Water glass is a kind of good dispersion agent, tool disinfectant properties, softening water performance and Corrosion Protection.Carboxymethyl cellulose is the white fiber shape, and water absorbability is arranged, and soluble in water and basic solution forms the transparence colloid, has the soil redeposition of preventing effect.The reasonably preparation of food grade materials in sum strengthens effect mutually and produces the obvious synergistic effect, and environmentally safe possesses very strong decontamination, wetting, emulsification, dispersion, degreasing, reduces surface tension.The raw materials market that the present invention adopts is in liberal supply, and wide material sources, technological design are rationally advanced, and product is accepted by market and consumers in general easily.
Phosphateless environmentally friendly washing powder of the present invention is formed and content is:
Yellow soda ash 20-30wt%
Water glass 5-19wt%
Anhydrous sodium sulphate 14-30wt%
Fatty alcohol-polyoxyethylene ether 2-5wt%
Cocounut oil powder 5-35wt%
Xylo-Mucine 0.5-2wt%
The present invention can further add sodium bicarbonate in said components, the add-on of its sodium bicarbonate is the 4-6wt% of Phosphateless environmentally friendly washing powder total amount, to strengthen the anti-hard water effect of Phosphateless environmentally friendly washing powder.
The present invention for a kind of be raw material with the food grade, obtain the environment-protection detergent powder of without phosphorus, the non-4 A zeolite of national environmental protection authentication marks, the international invention award of Paris, FRA, no benzene derivative, no zymin, no white dyes.It does not have above composition, but can reach above-mentioned composition role in washing process, and washability is very strong, it can wash the dirt that the indelible gentian voiet of general washing powder, the tincture of iodine, ballpoint pen oil, lipstick, oil stain, bloodstain, milk stain, fruit juice, dish juice etc. are difficult to remove, its decontamination index is Phosphateless environmentally friendly worthy of the name, efficient, multifunctional washing powder about 2.0.
Do not have benzene derivative in this component design, it unlike the petrochemical industry lotion, with compositions such as ABS or LAS, can cause pollution of waterhead to the residual underground water source that is penetrated into of benzene.The product decontamination ratio of our development is much higher than all without phosphorus or parts and contains phosphorus product all about 1.6～2.5
Phosphateless environmentally friendly washing powder of the present invention with present domestic and international market other several big characteristics of sell goods phase region is: 1. without phosphorus, no aluminium, no benzene derivative, no zymin, no white dyes, no any dangerous composition, adopt raw material to be food grade; 2. save the water power equal energy source, use this product only need be mixed with the aqueous solution soaking certain hour, do not need to adopt mechanical forces such as washing machine again, rinsing is still clear water for 2 times; 3. do not stimulate, do not injure the effect that skin also can possess natural sterilization simultaneously; 4. washability is strong, all can clean various stupid stains, and the washing wide ranges; 5. 99% height degradation property has protection and governance role to the water source; 6. agricultural chemicals remaining in the plant and chemical fertilizer there are very strong emulsification and capacity of decomposition.And acid soil there is improving effect, can cause soil compaction.
Embodiment
Embodiment 1.
Yellow soda ash 30wt%
Water glass 19wt%
Anhydrous sodium sulphate 14wt%
Fatty alcohol-polyoxyethylene ether 5wt%
Cocounut oil powder 30wt%
Xylo-Mucine 2wt%
Blending process:
At first yellow soda ash, water glass, anhydrous sodium sulphate, cocounut oil powder, Xylo-Mucine are filtered with 20 order stainless steel sifts in proportion, once stir, stirring after five minutes once is sprayed on fatty alcohol-polyoxyethylene ether in the solid composition of above-mentioned mixing with high-pressure pump, treat that the solid, liquid two-phase mixing enters the vibration bed and adsorbs aging program after two minutes, filter qualified back to be tested packing at last with 20 order stainless steel sifts.
| Interventions Requested | Standard code | Measured data | Individual event is estimated |
| Granularity % | Screen rate by the 1.25mm sieve is not less than 90 | 98 | Qualified |
| Outward appearance | The no conglomeration powdery of white | The no conglomeration powdery of white | Qualified |
| Apparent density g/cm 3 | ≥0.60 | 0.66 | Qualified |
| PH value (25 ℃ of 0.1% solution) | ≤11.0 | 10.7 | Qualified |
| Gross activity thing content % | ≥10 | 16 | Qualified |
| Total Vanadium Pentoxide in FLAKES (P2O5) content % | ≤1.1 | 0.2 | Qualified |
| White dyes (2.0% solution) | Must not detect | Do not detect | Qualified |
| Relative standard's powder is to the decontamination ratio (0.1% solution) of greasy dirt cloth | ≥1.0 | 1.7 | Qualified |
Embodiment 2.
On the basis of embodiment 1, replenish sodium bicarbonate 5wt%, strengthen the anti-hard water effect in prescription.Reduce the water hardness and be about 30mg/kg.
Embodiment 3.
Yellow soda ash 26wt%
Water glass 16wt%
Anhydrous sodium sulphate 29wt%
Fatty alcohol-polyoxyethylene ether 3wt%
Cocounut oil powder 25wt%
Xylo-Mucine 1wt%
Blending process is with embodiment 1
| Interventions Requested | Standard code | Measured data | Individual event is estimated |
| Granularity % | Screen rate by the 1.25mm sieve is not less than 90 | 98 | Qualified |
| Outward appearance | The no conglomeration powdery of white | The no conglomeration powdery of white | Qualified |
| Apparent density g/cm 3 | ≥0.60 | 0.66 | Qualified |
| PH value (25 ℃ of 0.1% solution) | ≤11.0 | 10.7 | Qualified |
| Gross activity thing content % | ≥10 | 16 | Qualified |
| Total Vanadium Pentoxide in FLAKES (P2O5) content % | ≤1.1 | 0.2 | Qualified |
| White dyes (2.0% solution) | Must not detect | Do not detect | Qualified |
| Relative standard's powder is to the decontamination ratio (0.1% solution) of greasy dirt cloth | ≥1.0 | 1.7 | Qualified |
Embodiment 4.
Yellow soda ash 20wt%
Water glass 19wt%
Anhydrous sodium sulphate 30wt%
Fatty alcohol-polyoxyethylene ether 5wt%
Cocounut oil powder 25wt%
Xylo-Mucine 1wt%
Blending process is with embodiment 1
| Interventions Requested | Standard code | Measured data | Individual event is estimated |
| Granularity % | Screen rate by the 1.25mm sieve is not less than 90 | 98 | Qualified |
| Outward appearance | The no conglomeration powdery of white | The no conglomeration powdery of white | Qualified |
| Apparent density g/cm3 | ≥0.60 | 0.66 | Qualified |
| PH value (25 ℃ of 0.1% solution) | ≤11.0 | 10.7 | Qualified |
| Gross activity thing content % | ≥10 | 16 | Qualified |
| Total Vanadium Pentoxide in FLAKES (P2O5) content % | ≤1.1 | 0.2 | Qualified |
| White dyes (2.0% solution) | Must not detect | Do not detect | Qualified |
| Relative standard's powder is to the decontamination ratio (0.1% solution) of greasy dirt cloth | ≥1.0 | 1.7 | Qualified |
Claims (2)
1. Phosphateless environmentally friendly washing powder is characterized in that: described washing powder is formed and content is:
Yellow soda ash 20-30wt%
Water glass 5-19wt%
Anhydrous sodium sulphate 14-30wt%
Fatty alcohol-polyoxyethylene ether 2-5wt%
Cocounut oil powder 5-35wt%
Xylo-Mucine 0.5-2wt%.
2. washing powder as claimed in claim 1 is characterized in that: further add in the described Phosphateless environmentally friendly washing powder that sodium bicarbonate, its add-on are arranged is the 4-6wt% of Phosphateless environmentally friendly washing powder total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021241872A CN1169934C (en) | 2002-08-02 | 2002-08-02 | Phosphateless environmentally friendly washing powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021241872A CN1169934C (en) | 2002-08-02 | 2002-08-02 | Phosphateless environmentally friendly washing powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1401752A CN1401752A (en) | 2003-03-12 |
| CN1169934C true CN1169934C (en) | 2004-10-06 |
Family
ID=4745361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021241872A Expired - Fee Related CN1169934C (en) | 2002-08-02 | 2002-08-02 | Phosphateless environmentally friendly washing powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1169934C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888295B (en) * | 2012-10-24 | 2013-09-04 | 浙江建中竹业科技有限公司 | Plant carbon washing powder |
| CN106336961A (en) * | 2016-08-24 | 2017-01-18 | 郭睿航 | Antibacterial and efficient laundry detergent liquid |
-
2002
- 2002-08-02 CN CNB021241872A patent/CN1169934C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1401752A (en) | 2003-03-12 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| DD01 | Delivery of document by public notice |
Addressee: Zhao Junlong Document name: Notification to Pay the Fees |
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| DD01 | Delivery of document by public notice |
Addressee: Zhao Junlong Document name: Notification of Termination of Patent Right |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20041006 Termination date: 20150802 |