CN116990210B - Hydrogen storage bottle permeability influence test device for producing hydrogen by water electrolysis - Google Patents

Hydrogen storage bottle permeability influence test device for producing hydrogen by water electrolysis Download PDF

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Publication number
CN116990210B
CN116990210B CN202311253053.XA CN202311253053A CN116990210B CN 116990210 B CN116990210 B CN 116990210B CN 202311253053 A CN202311253053 A CN 202311253053A CN 116990210 B CN116990210 B CN 116990210B
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China
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hydrogen storage
groove
storage bottle
fixing
sliding
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CN116990210A (en
Inventor
徐成俊
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Changzhou Lanbo Hydrogen Energy Technology Co ltd
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Changzhou Lanbo Hydrogen Energy Technology Co ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/08Investigating permeability, pore-volume, or surface area of porous materials
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/08Investigating permeability, pore-volume, or surface area of porous materials
    • G01N15/0806Details, e.g. sample holders, mounting samples for testing
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/08Investigating permeability, pore-volume, or surface area of porous materials
    • G01N15/088Investigating volume, surface area, size or distribution of pores; Porosimetry

Abstract

The application relates to the technical field of performance test of hydrogen storage bottles, in particular to a permeability influence test device of a hydrogen storage bottle for hydrogen production by electrolyzed water, which solves the defects existing in the prior art and comprises a base, an adjusting mechanism and a detecting mechanism, wherein a control terminal and a heating power supply are arranged on the base, a fixing frame is also arranged on the base, a fixing component is arranged below the fixing frame and used for assisting in positioning the hydrogen storage bottle, a test rod carved with scales is also arranged on the lower surface of the fixing frame, a sliding rod vertically sliding under the influence of pressure difference is arranged on the outer wall of the test rod, and the bottom of the sliding rod is inserted into the hydrogen storage bottle. Compared with the prior art, the method can effectively detect the permeability of the hydrogen storage bottle through the separation test between the fiber winding layer and the plastic lining in the horizontal direction and the vertical direction, and improves the detection comprehensiveness.

Description

Hydrogen storage bottle permeability influence test device for producing hydrogen by water electrolysis
Technical Field
The application relates to the technical field of performance test of hydrogen storage bottles, in particular to a permeability influence test device of a hydrogen storage bottle for producing hydrogen by water electrolysis.
Background
Electrolytic water to produce hydrogen is a common and efficient method. The specific process is to decompose water into hydrogen and oxygen by electrolysis, typically using a conductive solution or electrolyte to increase the effectiveness of the electrolysis. During electrolysis, the positive electrode (anode) releases oxygen and the negative electrode (cathode) releases hydrogen. The method is widely applied to the fields of hydrogen production, energy storage, fuel cells and the like.
The hydrogen storage bottle is an important container for storing hydrogen energy, and the high-pressure gaseous hydrogen storage technology realizes the storage and release of hydrogen through the hydrogen storage bottle. The hydrogen storage bottles with different materials selected according to the internal structure are mainly divided into a pure steel metal bottle (type I), a steel liner fiber winding bottle (type II), an aluminum liner fiber winding bottle (type III) and a plastic liner fiber winding bottle (type IV). The inner part of the hydrogen storage bottle mainly comprises an inner container, an intermediate layer and a surface layer, the inner container is a core component of the hydrogen storage bottle and mainly plays a role in blocking hydrogen, the inner containers of the I, II and III type hydrogen storage bottles are mostly made of metal materials, but the hydrogen and the metal materials can generate a hydrogen embrittlement effect to lead the metal plasticity to be reduced, induce cracks and even crack, and the inner container of the IV type hydrogen storage bottle is not suitable for long-term storage, adopts plastic and other composite materials, and has good hydrogen permeation resistance and heat resistance. The middle layer is a thicker pressure-resistant layer and mainly acts as pressure bearing, carbon fibers are widely used as the middle layer in II, III and IV type bottles by virtue of better tensile strength and lighter weight, and the surface layer is generally used for protecting the internal structure by using glass fiber and other wrapping materials.
The fiber composite material shell and the plastic lining of the hydrogen storage bottle are different in material, the plastic can age along with the extension of working time, the lining and the fiber winding layer are separated, the molecular mass of hydrogen is small and is easy to exude from the molecular pores of the lining material, so that the permeability of the IV-type hydrogen storage bottle needs to be tested in series in the process of producing the IV-type hydrogen storage bottle so as to reach corresponding standards.
The application patent with publication number of CN113188974B discloses a high-pressure hydrogen permeation test device and a high-pressure hydrogen permeation test method for IV gas cylinder liner materials, and the permeation test of the patent is mainly used for realizing test items under constant pressure and circulating pressure, but the influence on the permeation caused by the separation degree between a fiber winding layer and a plastic liner, which is proposed above, cannot be solved.
Therefore, it is necessary to provide a device for testing the influence of the permeability of a hydrogen storage bottle for producing hydrogen by electrolysis of water, which can detect the influence of the degree of separation between a fiber wound layer and a plastic liner of the hydrogen storage bottle on the permeability.
Disclosure of Invention
The application aims to provide a device for testing the permeability influence of a hydrogen storage bottle for producing hydrogen by water electrolysis, which aims to solve the problems in the background technology.
In order to solve the technical problems, the application provides the following technical scheme: the utility model provides a hydrogen storage bottle permeability influence test device for electrolysis water hydrogen production, includes base, adjustment mechanism and detection mechanism, install control terminal and heating power supply on the base, and still install the mount on the base, the below of mount is provided with fixed subassembly for to the location assistance of hydrogen storage bottle, and still be provided with the test rod of carved with the scale on the lower surface of mount, be provided with on the outer wall of test rod and receive the pressure differential influence and take place the slide bar of vertical slip, the bottom of slide bar is inserted in the hydrogen storage bottle;
the adjusting mechanism comprises a lifting seat, a lifting assembly, a rotating assembly and a driving assembly, wherein a movable seat is arranged on the base in a sliding manner along the width direction of the base, a fixed column is arranged on the movable seat, and the lifting seat slides and is positioned on the fixed column;
the lifting assembly is arranged between the side walls of the lifting seat and comprises a first driving shaft, and the lifting seat is driven to vertically lift by the rotation input of the first driving shaft;
the rotating assembly is also arranged between the side walls of the lifting seat and comprises a driving shaft II and a connecting shaft, and the connecting shaft is driven to synchronously rotate in the vertical direction by the rotation input of the driving shaft II in the horizontal direction;
the driving component is arranged on the outer side wall of one side of the lifting seat, and the driving component reciprocally rotates in the horizontal and vertical directions, so that the driving and the adjusting of the lifting component and the rotating component can be switched;
the detection mechanism comprises a fixed disc, a rotating handle, a telescopic rod and an insert, wherein the fixed disc is arranged on the lifting seat, the rotating handle is rotationally arranged between the inner walls of the fixed disc and is connected with the connecting shaft synchronously, the telescopic rod moves on one side of the fixed disc along a straight line and is also connected with the linkage handle with the rotating handle, and the insert is arranged on the side wall of the telescopic rod in a threaded connection mode.
In one embodiment, the fixing assembly comprises an upper fixing ring and a supporting seat, a square bottom plate is fixed on the base, a fixing seat which is vertically installed is arranged on the bottom plate, a vertical groove is formed in the fixing seat, a lifting block is arranged between the inner walls of the vertical groove in a sliding mode, and the lifting block is connected with the upper fixing ring into a whole;
the middle of supporting seat has offered circular arc formula fixed slot, and thereby its circular arc face can transfer heat to the flow of gas in the acceleration bottle in the hydrogen storage bottle, still installs the support that plays the fixed action between supporting seat and the bottom plate to install down solid fixed ring on the roof of supporting seat, go up solid fixed ring and solid fixed ring structure down unanimously, and evenly distributed installs 3 at least locating levers on its circumference surface for to the assistance-localization real-time of hydrogen storage bottle.
In one embodiment, a groove is formed in the base, a first screw rod arranged along the length direction of the groove is arranged in the groove, the movable seat is in a T-shaped structure and is slidably adjusted along the inner wall of the groove, the screw rod penetrates through the movable seat and is in threaded transmission fit with the movable seat, and an external power supply III connected with the PLC through an electric signal is externally embedded on the top surface of the movable seat;
side grooves which are vertically arranged are formed in the side walls of the fixed column, opposite to the two sides of the fixed column, a first silicon steel sheet which is connected with an external power supply through a three-way wire is embedded in the concave surface of each side groove, and a plurality of tooth grooves which are uniformly distributed along the vertical direction are formed in the side wall of the other side of the fixed column;
the lifting seat is provided with a through hole matched with the fixed column, iron sliding blocks are arranged on the inner side walls of the two sides of the lifting seat, the sliding blocks slide between the inner walls of the side grooves, and when an external power supply is started, current flows through the silicon steel sheet I, so that suction is generated between the sliding blocks and the side grooves, and the lifting seat is positioned on the fixed column.
In one embodiment, the driving assembly comprises an adjusting handle and a rotating disc, a rotating motor IV is arranged on the inner side wall of one side of the lifting seat, a driving shaft III is arranged at the output end of the rotating motor IV, one end of the adjusting handle is connected with the driving shaft III into a whole, and the rotating disc is rotatably arranged at the other end of the adjusting handle;
and a positioning groove II is formed in the rotating disc, an external power supply I connected with the PLC through an electric signal is arranged on the circumferential outer wall of the rotating disc, and a steel sheet III connected with the external power supply I through a lead is embedded on the inner wall of the positioning groove II.
In an embodiment, the lifting assembly further comprises a driving gear and a first sliding part, the driving gear is installed on the outer wall of the first driving shaft through a key connection, the driving gear is meshed with the tooth slot, one end of the first driving shaft is rotatably arranged on the inner side wall of the lifting seat, the other end of the first driving shaft penetrates through and is rotatably arranged on the lifting seat, and the first sliding part is slidably arranged at one end of the first driving shaft and moves outside the lifting seat.
In an embodiment, the rotating assembly further comprises a first bevel gear, a second bevel gear and a second sliding piece, the first bevel gear is meshed with the second bevel gear, the installation positions of the first bevel gear and the second bevel gear are perpendicular to each other, the second driving shaft penetrates through and rotates to be arranged on the lifting seat, one end of the second driving shaft is connected with the first bevel gear through a key, the connecting shaft is fixedly welded to the center of the top wall of the second bevel gear, and the second sliding piece is arranged at one end of the second driving shaft in a sliding mode and also moves outside the lifting seat.
In one embodiment, the first sliding part and the second sliding part are identical in structure and are sleeve-shaped, are iron products, are provided with shaft holes, and are welded with ribs on the inner walls of the first sliding part and the second sliding part, and the ribs are positioned in the shaft holes;
the diameter of the first driving shaft is equal to that of the second driving shaft, the outer surfaces of the first driving shaft and the second driving shaft are respectively provided with a prismatic groove arranged along the length direction of the first driving shaft, the prismatic ribs are arranged along the prismatic grooves in a sliding way, and the second screw rod which is arranged along the length direction of the prismatic grooves, penetrates through the prismatic ribs and is in threaded transmission fit with the prismatic ribs is arranged in the prismatic grooves in a rotating way;
two positioning grooves I are formed in the outer side wall of one side of the lifting seat, the driving shaft I and the driving shaft II are respectively arranged in the two positioning grooves I in a penetrating mode, and the positioning grooves I and the positioning grooves II are arranged in the same diameter.
In one embodiment, when the adjusting handle is in a horizontal state, the center of the rotating disk is collinear with the axis of the driving shaft II, the sliding piece II slides to one side of the rotating disk from the position of the positioning groove I, when the convex edge on the sliding piece II slides to one end, close to the rotating disk, in the corresponding edge groove, one end of the sliding piece II moves into the positioning groove II and is connected with the rotating disk into a whole, and then the rotating disk can drive the driving shaft II to synchronously rotate and transmit and output force through the connecting shaft;
when the adjusting handle is in a vertical state, the second sliding part is separated from the rotating disc and moves back into the corresponding first positioning groove, at the moment, the center of the rotating disc is collinear with the axis of the first driving shaft, the first sliding part slides to one side of the rotating disc from the position of the first positioning groove, when the convex edge on the first sliding part slides to one end, close to the rotating disc, in the corresponding edge groove, one end of the first sliding part moves into the second positioning groove and is connected with the connecting disc into a whole, and then the rotating disc can drive the driving shaft to rotate synchronously, so that the driving gear is driven to start to act.
In one embodiment, the fixed disk is provided with a semicircular arc-shaped fixed hole, the top end of the connecting shaft penetrates through the fixed disk and is fixedly connected with one end of the rotating handle, which is arranged in the fixed disk, the rotating handle is internally penetrated with a sliding bolt, the bottom end of the sliding bolt is slidably arranged along the inner wall of the fixed hole, the top end of the sliding bolt is exposed, the outer surface of the fixed disk is welded with a fixed rod, the center extension line of the fixed rod passes through the center of the circle of the fixed disk, the fixed rod is slidably provided with a blocky guide piece, the top wall of the fixed rod is also welded with a limiting block for limiting the guide piece, one end of the telescopic rod is provided with a connecting groove, and a linkage handle is movably connected between the connecting groove and the top end of the sliding bolt.
Compared with the prior art, the application has the following beneficial effects:
1. through inserting the plug-in components between the fibre winding layer and the plastics inside lining of hydrogen storage bottle, control drive assembly is connected with lifting unit, makes drive shaft one along with the synchronous rotation of rotary disk to make lifting seat follow the fixed column from top to bottom reciprocating motion, and then drive the plug-in components and constantly follow vertical direction and separate the fibre winding layer gradually, in order to detect the hydrogen storage bottle under this circumstances the permeability of the interior gaseous of bottle.
2. Through inserting the plug-in components between the fiber winding layer of hydrogen storage bottle and the plastics inside lining and locating in a certain high position department, control drive assembly is connected with rotating assembly, makes drive shaft two rotate along with the rotary disk is synchronous to make the connecting axle drive the turning handle in step and rotate the regulation, and then through the removal regulation to the telescopic link drive the plug-in components and do horizontal direction's linear motion, thereby make can detect the permeability of gas in the hydrogen storage bottle under the circumstances that fiber winding layer separates to both sides simultaneously.
3. Through setting up slide bar and test rod in the bottleneck department of hydrogen storage bottle, utilize the inside and outside pressure difference that the gas leaks in the bottle and cause to make the slide bar slide along the test rod to the bottle and adjust, judge the permeability of hydrogen storage bottle with this in-process gliding distance how.
In summary, the application can effectively detect the permeability of the hydrogen storage bottle through the separation test between the fiber winding layer and the plastic lining in the horizontal direction and the vertical direction, and improves the detection comprehensiveness.
Drawings
The technical solution and other advantageous effects of the present application will be made apparent by the following detailed description of the specific embodiments of the present application with reference to the accompanying drawings.
In the drawings:
FIG. 1 is a schematic view of the overall structure of the present application;
FIG. 2 is another view angle schematic of FIG. 1;
FIG. 3 is a schematic view of the structure of the base, the fixing assembly, the fixing frame, etc. of the present application;
FIG. 4 is a schematic view of the structure of the fixing post, the adjusting mechanism and the detecting mechanism of the present application;
FIG. 5 is a schematic view of the structure of the adjustment mechanism of the present application;
FIG. 6 is a schematic top view of the structure of FIG. 5;
FIG. 7 is a schematic view of the drive assembly of the present application;
FIG. 8 is a schematic structural view of the detection mechanism of the present application;
FIG. 9 is a schematic illustration of the connection between the slider and the first drive shaft of the present application;
fig. 10 is a schematic diagram of the circuit connection between the external power supply II and the two silicon steel sheets II.
In the figure: 1. a base; 11. a groove; 111. a first screw; 12. a control terminal; 13. a heating power supply;
2. a fixing frame; 21. a test rod; 22. a slide bar;
3. a fixing seat; 31. an upper fixing ring; 32. a lifting block;
4. a support base; 41. a lower fixing ring;
5. fixing the column; 51. a side groove; 52. tooth slots;
6. an adjusting mechanism; 61. a drive gear; 611. a first driving shaft; 612. a first sliding member; 62. bevel gears I; 621. a second driving shaft; 622. a second sliding piece; 63. bevel gears II; 631. a connecting shaft; 64. a positioning groove I; 65. an adjusting handle; 651. a third driving shaft; 66. a rotating disc; 661. an external power supply I; 662. a positioning groove II; 67. a lifting seat; 671. a slide block; 672. an external power supply II; 68. a second screw; 69. a rib;
7. a detection mechanism; 71. a fixed plate; 711. a fixing hole; 72. a rotating handle; 721. a slide bolt; 73. a linkage handle; 74. a fixed rod; 741. a limiting block; 75. a telescopic rod; 751. a guide member; 76. an insert;
8. a movable seat; 81. and an external power supply III.
Detailed Description
The following disclosure provides many different embodiments, or examples, for implementing different features of the application. In order to simplify the present disclosure, components and arrangements of specific examples are described below. They are, of course, merely examples and are not intended to limit the application. Furthermore, the present application may repeat reference numerals and/or letters in the various examples, which are for the purpose of brevity and clarity, and which do not themselves indicate the relationship between the various embodiments and/or arrangements discussed. In addition, the present application provides examples of various specific processes and materials, but one of ordinary skill in the art will recognize the application of other processes and/or the use of other materials.
As shown in fig. 1-3, the application provides the technical scheme that: a hydrogen storage bottle permeability influence test device for producing hydrogen by electrolyzing water comprises a base 1, an adjusting mechanism 6 and a detecting mechanism 7;
the control terminal 12 and the heating power supply 13 are fixedly arranged on two sides of the base 1 through bolts respectively, a PLC controller is attached to the control terminal 12, the power line diagram of the control terminal 12 is not shown, and the heating power supply 13 is connected with the control terminal 12 through wires (not shown).
Still be provided with the fixed subassembly that vertically distributes on the base 1, fixed subassembly includes solid fixed ring 31 and supporting seat 4, be fixed with square bottom plate through the bolt on base 1, it has vertical fixing base 3 of setting to have through bolt fixed mounting on the bottom plate, set up vertical groove on the fixing base 3, it is provided with lifting block 32 to slide between the inner wall in vertical groove, run through the screw rod three that has the screw drive setting with it between the inner wall of lifting block 32, the one end of screw rod three is installed rotating electrical machines three through the screw at the top surface of fixing base 3, pass through screw fixation as an organic wholely between lifting block 32 and the last solid fixed ring 31.
The middle of supporting seat 4 has seted up circular arc type fixed slot, the inside of supporting seat 4 is provided with the heating coil, connect through the wire between supporting seat 4 and the heating power 13 (not shown in the figure), heating coil accessible heat transfer's mode is with in the heat storage hydrogen bottle, thereby accelerate the flow of bottle internal gas, improve test efficiency, be provided with the support through screw fixation with it on the outer wall of supporting seat 4, the bottom of support is inlayed in the bottom plate, and still additionally pass through bolt fixed connection between supporting seat 4 and the bottom plate, there is fixed ring 41 down through screw fixation on the roof of supporting seat 4, go up fixed ring 31 and the structure of fixed ring 41 down unanimous, and at least 3 locating levers are installed to the distribution on its circumference surface, all screw in (or unscrew) with the mode of screw drive between locating lever and the fixed ring 31 down, the flat end top to the locating lever during the screw in tightly stores up the outer wall of hydrogen bottle can.
The upper part of the base 1 is also provided with a fixing frame 2, the bottom end of the fixing frame 2 is fixed on the base 1 through welding, a test rod 21 is connected with the middle of the lower surface of the fixing frame 2 through threads, the test rod 21 is of a round rod-shaped structure, scales (not shown in the figure) are carved on the outer wall of the test rod 21, a slide rod 22 is arranged on the outer wall of the test rod 21 in a sliding manner, and the slide rod 22 is not separated from the test rod 21 all the time.
It should be further noted that, through vertically standing the hydrogen storage bottle on the supporting seat 4, adjusting the position of the upper fixing ring 31, stopping after contacting with the body of the hydrogen storage bottle, then screwing the positioning rod again to further position the hydrogen storage bottle, at this time, the bottle mouth center of the hydrogen storage bottle with the fixed position is located right below the center of the sliding rod 22, then manually installing the sealing plug at the bottle mouth of the hydrogen storage bottle, placing the bottom end of the sliding rod 22 in the hydrogen storage bottle through the sealing plug, then injecting a proper amount of helium gas into the hydrogen storage bottle to replace hydrogen gas for simulation test, and in the test process, heating the hydrogen storage tank by starting the heating power supply 13, thereby accelerating the flow of internal gas;
when the gas in the bottle leaks, the internal pressure changes, and the pressure difference between the inside and the outside of the bottle is utilized, so that the slide bar 22 is jacked into the bottle, and the permeability degree of the hydrogen storage bottle can be known by reading the downward moving distance of the slide bar 22.
As shown in fig. 1 and fig. 4, a groove 11 is further formed in the base 1, a first screw 111 arranged along the length direction of the groove 11 is installed in the groove 11, a first rotating motor is fixedly installed on the outer wall of the base 1 through a bolt at one end of the first screw 111, a movable seat 8 is slidably arranged between the inner walls of the groove 11, the first screw 111 penetrates through the movable seat 8 and is in threaded transmission with the movable seat 8, an external power supply III 81 is externally embedded on the top surface of the movable seat 8, and the external power supply III 81 is connected with a PLC controller through an electric signal.
The top surface of the movable seat 8 is welded with a fixed column 5, two opposite side walls of the fixed column 5 are respectively provided with a side groove 51 which is vertically arranged, a first silicon steel sheet (see a shadow part of fig. 4) is fixedly embedded in a concave surface of the side groove 51, a third external power supply 81 is connected with the first silicon steel sheet through a lead (not shown in the figure), a plurality of tooth grooves 52 are uniformly formed in the side wall of the other side along the vertical direction, an adjusting mechanism 6 is arranged along the lifting adjustment of the fixed column 5, and a detecting mechanism 7 is arranged above the adjusting mechanism 6.
It should be further noted that the insert 76 of the detection mechanism 7 is inserted between the filament wound layer on the outer surface of the hydrogen storage bottle and the plastic liner, and the vertical movement or the horizontal movement of the insert 76 is matched to detect the influence on the permeability of the hydrogen storage bottle in different situations.
As shown in fig. 5 to 7, the adjusting mechanism 6 includes a lifting seat 67, a lifting assembly, a rotating assembly, and a driving assembly;
the lifting assembly comprises a drive gear 61, a first drive shaft 611 and a first slider 612;
the rotating assembly comprises a first bevel gear 62, a second bevel gear 63, a second driving shaft 621, a connecting shaft 631 and a second sliding piece 622;
the drive assembly includes an adjustment handle 65 and a rotating disk 66;
the lifting seat 67 is provided with a through hole matched with the fixed column 5, iron slide blocks 671 are arranged on the lifting seat 67 through screws on two sides of the through hole, the slide blocks 671 slide between the inner walls of the side grooves 51, and when an external power supply III 81 is started, suction force is generated between the slide blocks 671 and the side grooves 51, so that the positions of the slide blocks 671 and the side grooves 51 are fixed.
Two positioning grooves I64 are formed in the outer side wall of one side of the lifting seat 67, a driving shaft I611 and a driving shaft II 621 are respectively arranged in the middle of the two positioning grooves I64 in a penetrating mode, a sliding piece I612 is arranged at one end of the driving shaft I611 in a sliding mode, the other end of the driving shaft I611 is rotatably arranged on the inner side wall of the lifting seat 67, a driving gear 61 is fixedly arranged on the driving shaft I611 through key connection, the driving gear 61 is meshed with one side of the tooth groove 52, a sliding piece II 622 is arranged at one end of the driving shaft II 621 in a sliding mode, a bevel gear II 63 is arranged at the other end of the driving shaft II 621 in a meshed mode through key connection, and a connecting shaft 631 is welded on the bevel gear II 63 for output.
The adjusting handle 65 is further rotatably arranged on the outer side wall of the lifting seat 67, one end of the adjusting handle 65 is connected with the driving shaft three 651, the rotating motor four is arranged on the inner side wall of one side of the lifting seat 67 through screws, the driving shaft three 651 is arranged on the output end of the rotating motor four and can drive the adjusting handle 65 to rotate and adjust, the rotating disk 66 is rotatably arranged on the other end of the adjusting handle 65, the rotating motor five which is connected with the rotating disk 66 to be driven is fixedly arranged on the side wall of the adjusting handle 65 through screws, the external power source one 661 is arranged on the outer wall of the rotating disk 66 through screws, the external power source one 661 is connected with a PLC controller through electric signals, a positioning groove two 662 is formed in the center of the surface of the side, where the rotating disk 66 faces the lifting seat 67, the positioning groove two 662 is equal to the positioning groove one 64 in diameter, the sliding piece one 612 and the sliding piece two 622 are matched with the positioning groove one 64 and the positioning groove two 662, a silicon steel sheet three (see a shadow part of fig. 7) is embedded on the inner wall of the positioning groove two 662, and the external power source one 661 is connected with the silicon steel sheet three through a wire (not shown in the figure).
The inner walls of the first positioning grooves 64 are embedded with second silicon steel sheets, the outer side wall of the lifting seat 67 is also embedded with second external power supply 672, and a circuit distribution diagram between the second external power supply 672 and the second silicon steel sheets is not shown in detail, but the circuit principle is shown in fig. 10, specifically:
two silicon steel sheets II are respectively corresponding to the two branches in the figure;
after the external power supply II 672 is started, current flows out from the positive electrode and then flows in from the negative electrode, and when the external power supply II 672 is not in a working state, no current passes through the two silicon steel sheets II; when the SW1 is closed and the SW2 is opened, only the second upper silicon steel sheet can flow current, so that suction force is generated; when the SW1 is in an open state and the SW2 is in a closed state, only the second silicon steel sheet below can flow through current, so that suction force is generated, and current control between the second external power supply 672 and the second silicon steel sheet is completed.
In addition, the first slide 612 and the second slide 622 are identical in structure and are sleeve-shaped, and are all iron, diameters of the first drive shaft 611 and the second drive shaft 621 are equal, shaft holes matched with the first drive shaft 611 are formed in the first slide 612 and the second slide 622, ribs 69 are welded on inner walls of the first slide 612 and the second slide 622 on one side of the shaft holes, rib grooves are formed in the first drive shaft 611 and the second drive shaft 621, the ribs 69 are slidably arranged along the rib grooves, a second screw 68 penetrating the ribs 69 and in threaded transmission fit with the ribs is mounted in the rib grooves, miniature rotary motors are mounted on inner walls of the first drive shaft 611 and the second drive shaft 621 through screws and used for driving the corresponding second screw 68 to rotate, and contact sensors (not shown in the drawings) are embedded on groove walls at two ends of the rib grooves and used for monitoring specific positions of the ribs 69 at the moment.
It should be further noted that, when the adjusting handle 65 is in the state shown in fig. 5, the adjusting handle 65 is in a horizontal state, and at this time, the center of the rotating disk 66 is collinear with the center of the second driving shaft 621, the rotating motor on the second driving shaft 621 is started, the second screw 68 is rotated and controls the second slider 622 to slide to one side of the rotating disk 66, when the contact sensor near the side of the rotating disk 66 is triggered, the rotating motor stops outputting, and one end of the second slider 622 is moved into the second positioning slot 662, meanwhile, the external power source 661 is started, the second slider 622 and the rotating disk 66 are connected into a whole by suction, then, the rotating motor five starts to control the second driving shaft 621 to synchronously rotate, so that the first bevel gear 62 synchronously rotates the second bevel gear 63, and then the angle of the rotating handle 72 can be adjusted, after the adjustment, the suction between the second slider 622 and the rotating disk 66 is disconnected, and the contact sensor near the side of the rotating disk 66 is triggered, then, the external power source 672 is started, the second slider 622 and the lifting seat 67 are connected into a whole by suction, and the second slider 622 and the rotating disk 66 are separated.
When the adjusting handle 65 is turned down by 90 degrees from the state shown in fig. 5, the adjusting handle 65 is in a vertical state, and at this time, the center of the rotating disk 66 is collinear with the axis of the first driving shaft 611, the rotating motor on the first driving shaft 611 is started, the first sliding member 612 is controlled to slide to one side of the rotating disk 66, when the contact sensor near the side where the rotating disk 66 is located is triggered, the output of the rotating motor is stopped, one end of the first sliding member 612 is moved into the second positioning groove 662, meanwhile, the first external power source 661 is started, the first sliding member 612 is connected with the rotating disk 66 into a whole, then the rotating motor five is started to drive the first driving shaft 611 to rotate, so that the driving gear 61 can rotate synchronously with the first driving shaft 611, then the third external power source 81 is started after the driving shaft is adjusted to a proper position, the sliding member 671 is fixedly connected with the fixed column 5 through suction, then the suction force between the first sliding member 612 and the rotating disk 66 is disconnected, the first sliding member 612 is controlled to move to the contact sensor on the other side in the opposite direction until the second positioning groove 662 is triggered, and then the second external power source 672 is started, the first sliding member 612 is connected with the first sliding member 612 and the first sliding member 67 is separated into a whole through the suction force 67.
As shown in fig. 8 to 9, the detection mechanism 7 includes a fixed plate 71, a rotating handle 72, a telescopic rod 75, and an insert 76;
the fixed disk 71 is fixedly installed on the top wall of the lifting seat 67 through screws, a semicircular arc-shaped fixing hole 711 is formed in the fixed disk 71, a rotating handle 72 is rotatably arranged between the inner walls of the fixed disk 71, the top end of a driving shaft three 651 penetrates through the bottom wall of the fixed disk 71 and is fixedly connected with one end of the rotating handle 72, so that the output effect of the driving shaft three 651 drives the rotating handle 72 to rotate and adjust, the other end of the rotating handle 72 is located outside the fixed disk 71, a sliding bolt penetrates through the rotating handle 72, the sliding bolt 721 is slidably arranged along the inner wall of the fixing hole 711, the top of the sliding bolt 721 is also located outside the fixed disk 71 and is connected with a linkage handle 73, a fixing rod 74 is welded on the outer surface of the fixed disk 71, the center extension line of the fixing rod 74 passes through the center of the fixed disk 71, a limiting block 741 is welded on the fixing rod 74, a block-shaped guide 751 is slidably arranged on the outer wall of the fixing rod 74, a telescopic rod 75 is welded on the top end of the guide 751, one end of the telescopic rod 75 is provided with a connecting groove, the other end of the linkage handle 73 is installed between the inner walls of the connecting groove through a shaft connection, one side of the side walls of the telescopic rod 75 is also connected with a telescopic stud 76 in a side wall (the side wall is not shown in the figure), one side of the side is screwed into the side wall 76 through the side of the telescopic stud 76, and the side is screwed into the side wall 76.
It should be further noted that, through the rotation output of the driving shaft three 651, the rotating handle 72 moves circumferentially along with the rotation output, so that the linkage handle 73 drives the telescopic rod 75 to move and adjust along the linear direction, and the positioning work of the insert 76 and the horizontal pulling effect of the insert 76 on the fiber winding layer can be achieved.
Working principle:
it should be noted that the hydrogen storage bottle in this test is a type iv hydrogen storage bottle;
firstly, a hydrogen storage bottle to be tested is erected on a supporting seat 4, the position of the hydrogen storage bottle is reinforced and positioned through an upper fixing ring 31 and a lower fixing ring 41, a sealing plug is arranged at the bottle mouth of the hydrogen storage bottle, a sliding rod 22 is arranged in the sealing plug, and then a proper amount of helium gas is injected into the hydrogen storage bottle;
secondly, the second driving shaft 621 is controlled to be connected with the rotary disk 66 into a whole, the rotary disk 66 drives the third output shaft to output and drive the rotary handle 72 to adjust, the position of the plug-in 76 is moved, the plug-in 76 stops after being adjusted to a required position, and then the plug-in 76 is driven to be inserted between a fiber winding layer and a plastic lining of the hydrogen storage bottle through the axial movement of the movable seat 8 until the fiber winding layer is positioned at the position of the clamping groove;
because the fiber winding layer is coated on the outer layer of the plastic lining, the plastic lining can age along with the extension of working time, so that corresponding separation occurs between the lining and the fiber winding layer, and the different separation degree between the lining and the fiber winding layer has a certain influence on the permeability of the hydrogen storage bottle:
when the insert 76 moves from top to bottom, the separation degree between the fiber winding layer and the plastic lining is also expanded from top to bottom, at this time, the first driving shaft 611 is required to be connected with the rotating disc 66 into a whole by controlling the first driving shaft 611 to be driven by the rotating disc 66, the first driving shaft 611 rotates along with the first driving shaft and drives the driving gear 61 to roll along the tooth grooves 52, so as to drive the insert 76 to reciprocate for a plurality of times, in the moving process, the moving speed of the insert 76 can be accelerated by starting the heating power supply 13 to heat the gas in the bottle, the detection efficiency is improved, the pressure in the bottle is reduced along with the leakage of the gas, so that the slide bar 22 is jacked into the bottle under the action of the internal and external pressure difference, and the result of a plurality of tests can be judged by the sliding distance of the slide bar 22;
when the insert 76 moves to the side far away from the hydrogen storage bottle, the separation degree between the fiber winding layer and the plastic lining is expanded to two sides by the position of the insert 76, at this time, the switching rotary disk 66 and the driving shaft two 621 are connected into a whole, the rotary disk 66 is driven, the output shaft three outputs and drives the rotary handle 72 to adjust, the rotary handle 72 moves along the fixing hole 711 from the side close to the hydrogen storage bottle to the side far away from the hydrogen storage bottle, so that the linkage handle 73 synchronously drives the telescopic rod 75 to move along the linear direction to the side far away from the hydrogen storage bottle, the insert 76 then pulls the outer fiber winding layer outwards, the effect that the separation degree between the fiber winding layer and the plastic lining is expanded to two sides by a certain position is achieved, the rotary disk 66 is driven by the rotary disk three outputs and drives the rotary handle 72 to adjust, and the sliding rod 22 slides down for a plurality of hours in the period of time after the rotary disk is pulled to the required position, and the test result is judged.
And after the test is finished, the hydrogen storage bottle is taken down.
In the description of the present application, it should be noted that, unless explicitly specified and limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically connected, electrically connected or can be communicated with each other; may be directly connected, may be in communication with the interior of two elements or may be in interaction with two elements. The meaning of the above terms in the present application can be understood by those of ordinary skill in the art according to the specific circumstances.
The hydrogen storage bottle permeability influence test device for hydrogen production by water electrolysis provided by the embodiment of the application is described in detail, and specific examples are applied to explain the principle and the implementation mode of the application, and the description of the above examples is only used for helping to understand the technical scheme and the core idea of the application; those of ordinary skill in the art will appreciate that: the technical scheme described in the foregoing embodiments can be modified or some technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the application.

Claims (8)

1. A hydrogen storage bottle permeability influence test device for producing hydrogen by electrolyzing water, which is characterized by comprising:
the hydrogen storage device comprises a base (1), wherein a control terminal (12) and a heating power supply are arranged on the base (1), a fixing frame (2) is further arranged on the base (1), a fixing component is arranged below the fixing frame (2) and used for assisting in positioning a hydrogen storage bottle, a test rod (21) with scales is further arranged on the lower surface of the fixing frame (2), a sliding rod (22) which vertically slides under the influence of pressure difference is arranged on the outer wall of the test rod (21), and the bottom of the sliding rod (22) is inserted into the hydrogen storage bottle;
the fixing assembly comprises an upper fixing ring (31) and a supporting seat (4), a square bottom plate is fixed on a base (1), a vertically installed fixing seat (3) is arranged on the bottom plate, a vertical groove is formed in the fixing seat (3), lifting blocks (32) are slidably arranged between the inner walls of the vertical groove, the lifting blocks (32) are connected with the upper fixing ring (31) into a whole, a circular arc type fixing groove is formed in the middle of the supporting seat (4), heat can be transferred to a hydrogen storage bottle through an arc surface of the circular arc type fixing groove, so that the flow of gas in the bottle is accelerated, a bracket with a fixing function is further arranged between the supporting seat (4) and the bottom plate, a lower fixing ring (41) is arranged on the top wall of the supporting seat (4), the upper fixing ring (31) is consistent with the lower fixing ring (41), at least 3 positioning rods are uniformly distributed on the circumferential outer surface of the fixing seat, and the hydrogen storage bottle to be detected is erected on the supporting seat (4), and the position of the hydrogen storage bottle is reinforced and positioned through the upper fixing ring (31) and the lower fixing ring (41);
the adjusting mechanism (6), the adjusting mechanism (6) comprises a lifting seat (67), a lifting assembly, a rotating assembly and a driving assembly, a movable seat (8) is arranged on the base (1) in a sliding manner along the width direction of the base, a fixed column (5) is arranged on the movable seat (8), and the lifting seat (67) slides and is positioned on the fixed column (5);
the lifting assembly is arranged between the side walls of the lifting seat (67), and comprises a driving shaft I (611), and the lifting seat (67) is driven to vertically lift by the rotation input of the driving shaft I (611);
the rotating assembly is also arranged between the side walls of the lifting seat (67) and comprises a driving shaft II (621) and a connecting shaft (631), and the rotation input of the driving shaft II (621) in the horizontal direction drives the connecting shaft (631) to synchronously rotate in the vertical direction;
the driving component is arranged on the outer side wall of one side of the lifting seat (67), and the driving component reciprocally rotates in the horizontal and vertical directions, so that the driving and the adjusting of the lifting component and the rotating component can be switched;
detection mechanism (7), detection mechanism (7) include fixed disk (71), stem (72), telescopic link (75) and plug-in components (76), and fixed disk (71) are installed on elevating socket (67), and stem (72) rotate set up between the inner wall of fixed disk (71) and it is connected synchronous with connecting axle (631), and telescopic link (75) are along the straight line activity in one side of fixed disk (71) and it still is connected with linkage handle (73) of transfer power effect between stem (72), and plug-in components (76) are installed on the lateral wall of telescopic link (75) through threaded connection's mode.
2. The device for testing the permeability influence of the hydrogen storage bottle for the hydrogen production by the water electrolysis according to claim 1, wherein the base (1) is provided with a groove (11), a first screw (111) arranged along the length direction of the groove (11) is arranged in the groove (11), the movable seat (8) is arranged in a T-shaped structure and is slidably regulated along the inner wall of the groove (11), the first screw (111) penetrates through the movable seat (8) and is in threaded transmission fit with the movable seat (8), and an external power supply III (81) connected with a PLC (programmable logic controller) through an electric signal is externally embedded on the top surface of the movable seat (8);
side grooves (51) which are vertically arranged are formed in the side walls of the fixed column (5) opposite to the two sides of the fixed column, a first silicon steel sheet connected with an external power supply III (81) through a lead is embedded in the concave surface of the side groove (51), and a plurality of tooth grooves (52) which are uniformly distributed along the vertical direction are formed in the side wall of the other side of the fixed column (5);
the lifting seat (67) is provided with a through hole matched with the fixed column (5), iron sliding blocks (671) are arranged on the inner side walls of the two sides of the lifting seat (67), the sliding blocks (671) slide between the inner walls of the side grooves (51), and when an external power supply III (81) is started, current flows through the silicon steel sheet I, so that suction is generated between the sliding blocks (671) and the side grooves (51) and the lifting seat (67) is positioned on the fixed column (5).
3. The hydrogen storage bottle permeability influence test device for water electrolysis and hydrogen production according to claim 2, wherein the driving assembly comprises an adjusting handle (65) and a rotating disc (66), a rotating motor IV is arranged on the inner side wall of one side of the lifting seat (67), a driving shaft III (651) is arranged at the output end of the rotating motor IV, one end of the adjusting handle (65) is connected with the driving shaft III (651) into a whole, and the rotating disc (66) is rotatably arranged at the other end of the adjusting handle (65);
and a positioning groove II (662) is formed in the rotary disc (66), an external power supply I (661) connected with the PLC through an electric signal is arranged on the circumferential outer wall of the rotary disc (66), and a steel sheet III connected with the external power supply I (661) through a wire is embedded on the inner wall of the positioning groove II (662).
4. A hydrogen storage bottle permeability influence test apparatus for producing hydrogen by electrolyzing water as claimed in claim 3 wherein the elevation assembly further comprises a driving gear (61) and a first slide member (612), the driving gear (61) is mounted on an outer wall of the first drive shaft (611) through a key connection, the driving gear (61) is engaged with the tooth groove (52), one end of the first drive shaft (611) is rotatably disposed on an inner side wall of the elevation seat (67), the other end of the first drive shaft penetrates through and is rotatably disposed on the elevation seat (67), and the first slide member (612) is slidably disposed on one end of the first drive shaft (611) and moves outside the elevation seat (67).
5. The hydrogen storage bottle permeability influence test apparatus for producing hydrogen by water electrolysis according to claim 4, wherein the rotation assembly further comprises a first bevel gear (62), a second bevel gear (63) and a second slide member (622), wherein the first bevel gear (62) and the second bevel gear (63) are meshed with each other and are perpendicular to each other in installation position, the second drive shaft (621) penetrates through and is rotatably arranged on the lifting seat (67) and one end of the second drive shaft is connected with the first bevel gear (62) through a key, the connecting shaft (631) is fixedly welded to the center of the top wall of the second bevel gear (63), and the second slide member (622) is slidably arranged on one end of the second drive shaft (621) and also moves outside the lifting seat (67).
6. The device for testing the permeability influence of the hydrogen storage bottle for the hydrogen production by the electrolysis of water according to claim 5, wherein the first sliding part (612) and the second sliding part (622) are identical in structure and are sleeve-shaped, are iron products, shaft holes are formed in the first sliding part (612) and the second sliding part (622), ribs (69) are welded on the inner walls of the first sliding part (612) and the second sliding part (622), and the ribs (69) are located in the shaft holes;
the diameters of the driving shaft I (611) and the driving shaft II (621) are equal, the outer surfaces of the driving shaft I and the driving shaft II are respectively provided with a prismatic groove arranged along the length direction, the prismatic rib (69) is arranged along the prismatic groove in a sliding way, and the prismatic groove is rotationally provided with a screw rod II (68) which is arranged along the length direction, penetrates through the prismatic rib (69) and is in threaded transmission fit with the prismatic rib;
two first positioning grooves (64) are formed in the outer side wall of one side of the lifting seat (67), the first driving shaft (611) and the second driving shaft (621) are respectively arranged in the first positioning grooves (64) in a penetrating mode, and the first positioning grooves (64) and the second positioning grooves (662) are arranged in the same diameter mode.
7. The device for testing the permeability influence of a hydrogen storage bottle for producing hydrogen by water electrolysis according to claim 6, wherein when the adjusting handle (65) is positioned in a horizontal state, the center of the rotating disc (66) is collinear with the axis of the driving shaft two (621), the sliding piece two (622) slides to one side of the rotating disc (66) from the position of the positioning groove one (64), and when the convex rib (69) on the sliding piece two (622) slides to one end, close to the rotating disc (66), in the corresponding edge groove, one end of the sliding piece two (622) moves into the positioning groove two (662) and is connected with the rotating disc (66) into a whole, and then the rotating disc (66) can drive the driving shaft two (621) to synchronously rotate and perform force transmission output through the connecting shaft (631);
when the adjusting handle (65) is in a vertical state, the second sliding part (622) is separated from the rotating disc (66) and moves back into the corresponding first positioning groove (64), at the moment, the center of the rotating disc (66) is collinear with the axis of the first driving shaft (611), the first sliding part (612) slides to one side of the rotating disc (66) from the position of the first positioning groove (64), and when the convex rib (69) on the first sliding part (612) slides to one end, close to the rotating disc (66), in the corresponding edge groove, one end of the first sliding part (612) moves into the second positioning groove (662) and is connected with the connecting disc into a whole, and then the rotating disc (66) can drive the first driving shaft (611) to synchronously rotate, so that the driving gear (61) is driven to start to act.
8. The hydrogen storage bottle permeability influence test device for water electrolysis and hydrogen production according to claim 7, wherein a semicircular arc-shaped fixing hole (711) is formed in the fixing disc (71), the top end of the connecting shaft (631) penetrates through the fixing disc (71) and is connected and fixed with one end of the rotating handle (72) arranged in the fixing disc (71), a sliding bolt (721) penetrates through the rotating handle (72), the bottom end of the sliding bolt (721) is arranged in a sliding mode along the inner wall of the fixing hole (711) and the top end of the sliding bolt is exposed, a fixing rod (74) is welded on the outer surface of the fixing disc (71), a central extension line of the fixing rod (74) passes through the circle center of the fixing disc (71), a blocky guide piece (751) is arranged on the fixing rod (74) in a sliding mode, a limiting block (741) for limiting the guide piece (751) is further welded on the top wall of the fixing rod (74), a connecting groove is formed in one end of the telescopic rod (75), and a linkage handle (73) is movably connected between the connecting groove and the top end of the sliding bolt (721).
CN202311253053.XA 2023-09-27 2023-09-27 Hydrogen storage bottle permeability influence test device for producing hydrogen by water electrolysis Active CN116990210B (en)

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