CN116949251A - Deep quenching layer cold rolling working roller and manufacturing method thereof - Google Patents

Deep quenching layer cold rolling working roller and manufacturing method thereof Download PDF

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Publication number
CN116949251A
CN116949251A CN202310597692.1A CN202310597692A CN116949251A CN 116949251 A CN116949251 A CN 116949251A CN 202310597692 A CN202310597692 A CN 202310597692A CN 116949251 A CN116949251 A CN 116949251A
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temperature
tempering
annealing
quenching
raw materials
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黄智�
宋雷钧
李祝茂
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Jiangsu Yulong Special Metal Material Technology Co ltd
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Jiangsu Yulong Special Metal Material Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/06Surface hardening
    • C21D1/09Surface hardening by direct application of electrical or wave energy; by particle radiation
    • C21D1/10Surface hardening by direct application of electrical or wave energy; by particle radiation by electric induction
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/25Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/32Soft annealing, e.g. spheroidising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a deep quenching layer cold rolling working roller and a manufacturing method thereof, comprising the following steps: s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%; s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1100-1200 ℃ and the annealing time is 5 hours; s3, spheroidizing annealing: annealing at 870 ℃ for 7h; s4, rough machining; s5, ultrasonic flaw detection; s6, heat treatment; s7, finish machining. According to the invention, before heat treatment, the steel ingot is subjected to diffusion annealing and spheroidizing annealing, so that the chemical components and microstructure of the steel ingot can be reduced or eliminated, and diffusion dehydrogenation can be realized, so that the spheroidizing structure of the roller blank is good, and the roller blank has no flaky carbide, has complete carbide particles, uniform distribution and good processability and penetrating property.

Description

Deep quenching layer cold rolling working roller and manufacturing method thereof
Technical Field
The invention relates to the field of cold-rolling working rolls, in particular to a deep quenching hard layer cold-rolling working roll and a manufacturing method thereof.
Background
At present, MC5 steel is widely used for manufacturing cold-rolled working rolls due to excellent performance, and the surfacing metal is required to have high hardness, high crack resistance and high strength and toughness.
When the cold rolling working roll is rolled and rolled, the surface of the roll body is required to bear larger contact stress, alternating stress and friction force, so that the traditional cold rolling working roll is easy to generate hot crack in the rolling process, the conditions of working roll explosion, peeling and breakage are easy to occur, meanwhile, the cold rolling working roll is easy to bend and deform under the action of larger external stress, the service life is reduced, the requirements of customers cannot be met, the quality of the cold rolling working roll is mostly dependent on the metallographic structure treatment quality of a heat treatment processing technology, the condition that the hardness of the roll surface is uneven is easily caused due to uneven metallographic structure distribution of the cold rolling working roll, the overall use strength of the working roll is reduced, and the condition that the hardening layer of the surface of the working roll is shallow and the hardness distribution is uneven is caused by the traditional heat treatment technology of tempering and cooling after quenching, so that the hardness and stability of the surface of the working roll are reduced.
Disclosure of Invention
The invention aims to provide a manufacturing method of a deep quenching layer cold rolling working roller.
The invention has the innovation points that the chemical components and microstructure of the steel ingot can be reduced or eliminated by diffusion annealing and spheroidizing annealing before heat treatment, and the diffusion dehydrogenation can be realized, so that the spheroidizing structure of the roller blank is good, the flaky carbide is avoided, the carbide particles are complete, the distribution is uniform, and the processing performance and the penetrating property are good.
In order to achieve the above purpose, the technical scheme of the invention is as follows:
a manufacturing method of a deep quenching layer cold rolling working roller comprises the following steps: s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%; s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1100-1200 ℃ and the annealing time is 5 hours; s3, spheroidizing annealing: annealing at 870 ℃ for 7h; s4, rough machining; s5, ultrasonic flaw detection; s6, heat treatment;
s7, finish machining. The diffusion annealing and spheroidizing annealing are carried out before the heat treatment, so that the chemical components and microstructure of the steel ingot can be reduced or eliminated, the diffusion dehydrogenation can be carried out, the occurrence of internal stress after the roller forging is avoided, meanwhile, spherical carbide can be formed, and the netlike carbide is eliminated, so that the spheroidized structure of the roller blank is good, the flaky carbide is avoided, carbide particles are complete, the distribution is uniform, and the processability and the penetrating property are good.
Preferably, the heat treatment in step S6 comprises the steps of: s61, quenching and tempering; s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours; s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1050-1150 ℃; s64, tempering at low temperature: tempering temperature is 500-650 ℃, tempering is carried out for 3-4 times, and tempering time is 3h. The hardening and tempering can thoroughly remove netlike carbide to obtain the sirolimus or sorbite, increase the bending strength, meet the requirements of the roll neck on the aspect of hardness, and lay a good foundation for subsequent processing.
Preferably, in step S61, the quenching and tempering process includes quenching and high temperature tempering, wherein the quenching temperature is 580 ℃ and the high temperature tempering temperature is 600 ℃.
Preferably, in step S63, the intermediate frequency coil is additionally heated to 220 ℃ to 500 ℃.
The invention also provides a working roll manufactured by the deep quenching layer cold rolling manufacturing method, which comprises the following chemical components in percentage by mass: c:0.8 to 0.9 percent; si 0.7-1%; cr:4.5 to 5.5 percent; ni:0.4 to 0.6 percent; mo:0.2 to 0.4 percent; v:0.1 to 0.2 percent, and the balance of Fe and unavoidable impurities.
The beneficial effects of the invention are as follows:
1. according to the invention, before heat treatment, the steel ingot is subjected to diffusion annealing and spheroidizing annealing, so that the chemical components and microstructure of the steel ingot can be reduced or eliminated, and diffusion dehydrogenation can be realized, so that the spheroidizing structure of the roller blank is good, and the roller blank has no flaky carbide, has complete carbide particles, uniform distribution and good processability and penetrating property.
Detailed Description
The following description of the technical solution in the embodiments of the present invention is clear and complete.
The described embodiments are only some, but not all, embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
A manufacturing method of a deep quenching layer cold rolling working roller comprises the following steps:
s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%;
s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1100-1200 ℃ and the annealing time is 5 hours;
s3, spheroidizing annealing: annealing at 870 ℃ for 7h;
s4, rough machining;
s5, ultrasonic flaw detection;
s6, heat treatment;
s61, hardening and tempering: quenching and tempering treatment comprises quenching and high-temperature tempering, wherein the quenching temperature is 580 ℃ and the high-temperature tempering temperature is 600 ℃;
s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours;
s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1050-1150 ℃;
s64, tempering at low temperature: tempering temperature is 500-650 ℃, tempering is carried out for 3-4 times, and tempering time is 3h;
s7, finish machining.
Example 2
The method comprises the following steps:
s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%;
s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1100 ℃, and the annealing is carried out for 5 hours;
s3, spheroidizing annealing: annealing at 870 ℃ for 7h;
s4, rough machining;
s5, ultrasonic flaw detection;
s6, heat treatment;
s61, hardening and tempering: quenching and tempering treatment comprises quenching and high-temperature tempering, wherein the quenching temperature is 580 ℃ and the high-temperature tempering temperature is 600 ℃;
s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours;
s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1050 ℃;
s64, tempering at low temperature: tempering temperature is 500 ℃, tempering is carried out for 3 times, and tempering time is 3 hours.
S7, finish machining.
Example 3
The method comprises the following steps:
s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%;
s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1150 ℃, and the annealing is carried out for 5 hours;
s3, spheroidizing annealing: annealing at 870 ℃ for 7h;
s4, rough machining;
s5, ultrasonic flaw detection;
s6, heat treatment;
s61, hardening and tempering: quenching and tempering treatment comprises quenching and high-temperature tempering, wherein the quenching temperature is 580 ℃ and the high-temperature tempering temperature is 600 ℃;
s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours;
s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1100 ℃;
s64, tempering at low temperature: tempering temperature is 550 ℃, tempering is carried out for 3 times, and tempering time is 3 hours.
S7, finish machining.
Example 4
The method comprises the following steps:
s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%;
s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1200 ℃, and the annealing is carried out for 5 hours;
s3, spheroidizing annealing: annealing at 870 ℃ for 7h;
s4, rough machining;
s5, ultrasonic flaw detection;
s6, heat treatment;
s61, hardening and tempering: quenching and tempering treatment comprises quenching and high-temperature tempering, wherein the quenching temperature is 580 ℃ and the high-temperature tempering temperature is 600 ℃;
s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours;
s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1150 ℃;
s64, tempering at low temperature: tempering temperature is 650 ℃, tempering is carried out for 3-4 times, and tempering time is 3h.
S7, finish machining.
Example 5
The deep hardening layer cold rolling working roll comprises the following chemical components in percentage by mass:
c:0.8 to 0.9 percent; si 0.7-1%; cr:4.5 to 5.5 percent; ni:0.4 to 0.6 percent; mo:0.2 to 0.4 percent; v:0.1 to 0.2 percent, and the balance of Fe and unavoidable impurities.
Example 6
Comprises the following chemical components in percentage by mass:
c: 0.8%; 0.7% of Si; cr: 4.5%; ni:0.4%; mo: 0.2%; v:0.1% of Fe and the balance of unavoidable impurities.
Example 7
Comprises the following chemical components in percentage by mass:
c: 0.85%; si 0.9%; cr: 5%; ni:0.5%; mo: 0.3%; v:0.15% of Fe and the balance of unavoidable impurities.
Example 8
Comprises the following chemical components in percentage by mass:
c: 0.9%; 1% of Si; cr: 5.5%; ni:0.6%; mo: 0.4%; v:0.2% of Fe and the balance of unavoidable impurities.
The described embodiments are only some, but not all, embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.

Claims (5)

1. A method for manufacturing a deep quenching layer cold rolling working roller is characterized in that,
the method comprises the following steps:
s1, electric furnace smelting: mixing the metal raw materials according to chemical components, putting the mixed metal raw materials into an electric furnace, heating and melting the mixed metal raw materials at 1000 ℃, boiling the mixed metal raw materials at Wen Jilie high in oxidation period, automatically flowing slag, and enabling pure boiling time to be more than or equal to 10 parts and decarburization amount to be more than or equal to 0.3%;
s2, oil pressure rapid forging and diffusion annealing: the diffusion annealing temperature is 1100-1200 ℃ and the annealing time is 5 hours;
s3, spheroidizing annealing: annealing at 870 ℃ for 7h;
s4, rough machining;
s5, ultrasonic flaw detection;
s6, heat treatment;
s7, finish machining.
2. The method for manufacturing the deep quenching layer cold rolling working roll according to claim 1, wherein,
the heat treatment in step S6 includes the steps of:
s61, quenching and tempering;
s62, preheating a roller: the preheating temperature is 500 ℃, and the preheating time is 4 hours;
s63, double-frequency quenching: the method comprises the steps of firstly, preheating the surface of a roller by using an intermediate frequency coil, and then, carrying out supplementary heating by using the intermediate frequency coil before quenching treatment to balance the temperature of the roller surface, wherein the quenching temperature is 1050-1150 ℃;
s64, tempering at low temperature: tempering temperature is 500-650 ℃, tempering is carried out for 3-4 times, and tempering time is 3h.
3. The method for manufacturing the deep quenching layer cold rolling working roll according to claim 2, wherein,
in step S61, the tempering includes quenching and high temperature tempering, the quenching temperature being 580 ℃, and the high temperature tempering temperature being 600 ℃.
4. The method for manufacturing the deep quenching layer cold rolling working roll according to claim 2, wherein,
in step S63, the intermediate frequency coil is additionally heated to 220-500 ℃.
5. A work roll manufactured by the deep quench hardening cold rolling manufacturing method according to any one of claims 1 to 4, characterized in that,
comprises the following chemical components in percentage by mass:
c:0.8 to 0.9 percent; si 0.7-1%; cr:4.5 to 5.5 percent; ni:0.4 to 0.6 percent; mo:0.2 to 0.4 percent; v:0.1 to 0.2 percent, and the balance of Fe and unavoidable impurities.
CN202310597692.1A 2023-05-25 2023-05-25 Deep quenching layer cold rolling working roller and manufacturing method thereof Pending CN116949251A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310597692.1A CN116949251A (en) 2023-05-25 2023-05-25 Deep quenching layer cold rolling working roller and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310597692.1A CN116949251A (en) 2023-05-25 2023-05-25 Deep quenching layer cold rolling working roller and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN116949251A true CN116949251A (en) 2023-10-27

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN116949251A (en)

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