CN116811471A - Hollow colored glaze frosted grape cluster and manufacturing method thereof - Google Patents

Hollow colored glaze frosted grape cluster and manufacturing method thereof Download PDF

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Publication number
CN116811471A
CN116811471A CN202310801653.9A CN202310801653A CN116811471A CN 116811471 A CN116811471 A CN 116811471A CN 202310801653 A CN202310801653 A CN 202310801653A CN 116811471 A CN116811471 A CN 116811471A
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China
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grape
tubule
colored glaze
ball
powder
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Chinese (zh)
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孙磊
孙凤军
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Zibo Jingyi Liuli Art Co ltd
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Zibo Jingyi Liuli Art Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/04Re-forming tubes or rods
    • C03B23/047Re-forming tubes or rods by drawing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/04Re-forming tubes or rods
    • C03B23/07Re-forming tubes or rods by blowing, e.g. for making electric bulbs
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/20Uniting glass pieces by fusing without substantial reshaping
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/23Mixtures
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Composite Materials (AREA)
  • Glass Compositions (AREA)
  • Joining Of Building Structures In Genera (AREA)

Abstract

The application relates to a hollow colored glaze frosted grape cluster and a manufacturing method thereof, wherein the hollow colored glaze frosted grape cluster comprises a main stem, a plurality of grape ears burnt and fused on the main stem, the grape ears comprise secondary stems and a plurality of grape balls. The grape balls are respectively burnt and fused on the secondary stems through the branch stems. The main stem, the secondary stem, the branch stem and the grape ball are all made of colored glaze, and the grape ball is sequentially made of transparent colored glaze, white colored glaze and dark purple colored glaze from inside to outside; the surface of the grape ball is provided with white frost which is fused with the colored glaze part on the surface of the grape ball; the grape ball is provided with a connecting hole with a part connected with the branch by burning and melting. The hollow colored glaze frosted grape cluster is more realistic and vivid, the main stems, the secondary stems, the branch stems and the grape balls are all connected through softening and melting of the colored glaze, the stringing mode is simpler, the steps of coloring and waxing are omitted, and the adhesive force of white frost on the surface of the grape balls is stronger. In addition, the application also realizes the release of the internal stress of the colored glaze grape ball by reserving the connecting hole, and avoids the explosion of the colored glaze grape ball.

Description

Hollow colored glaze frosted grape cluster and manufacturing method thereof
Technical Field
The application belongs to the technical field of preparation of colored glaze lampworkers, and particularly relates to a hollow colored glaze frosted grape cluster and a preparation method thereof.
Background
The colored glaze artware attracts a large number of colored glaze artware lovers by virtue of the advantages of crystal clear, bright and attractive colors, bright colors, difficult fading and wear. Among the various colored glaze artware, the colored glaze products with grape shapes are relatively few, in particular to colored glaze grapes with hollow cavities and white frost effect on the surfaces.
In the prior art, the common manufacturing method of the colored glaze grape is that colored glaze is solid or simply blown to form round beads, cotton paper and the like are used for wrapping iron wires/copper wires and are plugged into the colored glaze beads, purple pigment is used for coloring the outer surfaces of the colored glaze beads, after the pigment is dried, molten paraffin is used for waxing, and finally, the manufacturing of a grape ball is completed through frosting. And winding cotton paper and iron wires/copper wires to connect a plurality of grape balls to form grape clusters.
However, the grape prepared by the method has the advantages of single bright color and luster, vivid and dead appearance, no gas generation, lack of real effect, higher grape molding difficulty, difficult control of the shape of the grape ball, complex manufacturing process and low yield. In addition, the white frost on the surface of the grape in the prior art is easy to rub off in the touch process, and the subsequent ornamental effect is affected.
In order to solve the problems, the same inventor of the present application submits an application with the application number of 202110444891.X in 24 of 2021 and the name of a method for preparing hollow glazed grape cream. However, the application of the application only briefly summarizes the processes of preparing, blanking, blowing and frosting the grape balls, lacks detailed description of each step, does not have a complete manufacturing process of grape strings, and has the problem of unclear description, so that the technical scheme is relatively imperfect. Therefore, the same inventor as the prior application carries out further supplement and improvement on the manufacturing method of the hollow colored glaze frosted grape cluster and the like on the basis of the prior application, and further carries out detailed description on more technical characteristics and effects thereof, so that the whole technical scheme is more perfect.
Disclosure of Invention
First, the technical problem to be solved
The application provides a hollow colored glaze frosted grape cluster and a manufacturing method thereof, aiming at solving the problems of complicated manufacturing procedure, low yield and easy dropping of white frost on the surface of the grape in the prior art.
(II) technical scheme
In order to achieve the above object, in a first aspect, the present application provides a hollow colored glaze frosted grape cluster, comprising a main stem, a plurality of grape ears burnt and melted on the main stem, wherein the grape ears comprise secondary stems and a plurality of grape balls; the grape balls are respectively burnt and melted on the secondary stems through the branch stems;
the main stem, the secondary stem, the branch stem and the grape balls are all made of colored glaze;
the grape balls are sequentially transparent colored glaze, white colored glaze and dark purple colored glaze from inside to outside;
the surface of the grape ball is provided with white frost which is fused with the colored glaze part on the surface of the grape ball;
the grape ball is provided with a connecting hole, the connecting hole is connected with the branch by burning and melting, and the other part is communicated with the outside.
The hollow colored glaze frosted grape cluster is characterized in that the white frost is preferably rare earth long-acting noctilucent powder, talcum powder or reflective powder;
the rare earth long-acting noctilucent powder is prepared by firing a mixture of strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid at 1400 ℃;
the talcum powder is magnesium silicate salt mineral;
the reflective powder is a mixture of silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide.
In a second aspect, the application also provides a method for manufacturing the hollow colored glaze frosted grape cluster, which comprises the following steps:
s1, preparing materials: sleeving a transparent glass material in a molten state by using a blowing rod, blowing the transparent glass material into bubbles, sleeving a white glass material in the molten state and a dark purple glass material in the molten state in sequence, and pulling a Cheng Kongxin glass tube sleeved with the obtained glass material for standby;
s2, wire drawing: heating one end of the hollow colored glaze pipe obtained in the step S1 to soften by using a flame spray gun, pulling out a first tubule, and then heating the hollow colored glaze pipe with a certain length to soften by taking the joint of the first tubule and the hollow colored glaze pipe as a starting point, and pulling out a second tubule to obtain a blowing part; the middle part of the blowing part is a blowing bubble, and two ends of the blowing bubble are respectively connected with the first tubule and the second tubule;
s3, blowing: melting and plugging one of the first tubule or the second tubule, and keeping the other one open; then holding the first tubule and the second tubule by hand, after firing the blown bubble into orange, blowing air into the blown bubble through the first tubule or the second tubule with holes, rotating a blowing part through adjusting the first tubule and the second tubule in the blowing process, and taking down one of the first tubule or the second tubule after the volume of the blown bubble is increased and a purple grape ball is formed, so as to obtain a preliminary grape ball;
s4, frosting: preheating the grape ball part in the preliminary grape ball, putting the grape ball part in white frost powder for rolling for one circle, taking out, and heating the grape ball part again to finish frosting;
s5, annealing: removing one of the first tubule or the second tubule with the opening, leaving a connecting hole on the grape ball, connecting the branch with the connecting hole by burning and melting, and then putting the grape ball with the branch into a temperature-reducing furnace for annealing;
s6, forming strings: after annealing, connecting a plurality of branch stems with the secondary stems through burning and melting to form grape ears, and then connecting a plurality of secondary stems with the main stems through burning and melting to obtain grape clusters.
In the above manufacturing method, preferably, in step S1, the transparent glass material, the white glass material and the deep purple glass material are respectively melted for 18 hours at 1250-1450 ℃ to enable the transparent glass material, the white glass material and the deep purple glass material to reach a syrup shape;
the diameter of the hollow colored glaze pipe is 10-15mm.
In the above-described production method, preferably, in step S2, the first tubule has a diameter of 1.5 to 2.5mm and a length of 90 to 120mm; the diameter of the second tubule is 1.5-2.5mm, and the length is 90-120 mm;
after the first tubule is pulled out, the hollow glass tube with the length of 12-17mm is heated to soften by taking the joint of the first tubule and the hollow glass tube as a starting point.
In the above manufacturing method, preferably, in step S3, during the process of increasing the volume of the blown bulb, the blown article is kept in a rotating state, so that the distance between the central axis of the preliminary grape ball and the straight line where the first tubule and the second tubule are located is less than 1.5mm.
In the above manufacturing method, preferably, in step S4, the white frost powder is rare earth long-acting noctilucent powder, talcum powder or reflective powder;
the rare earth long-acting noctilucent powder is prepared by firing a mixture of strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid at 1400 ℃;
the talcum powder is magnesium silicate salt mineral;
the reflective powder is a mixture of silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide;
the particle size of the rare earth long-acting noctilucent powder, talcum powder or reflecting powder is 150-450 meshes.
In the above manufacturing method, preferably, in step S5, the annealing temperature is 350-420 ℃, and the annealing time period is 24-72 hours.
In the above manufacturing method, preferably, in step S6, the diameter of the secondary stem is 5-6mm, and the length is 35-40mm; the diameter of the main stem is 8-9mm, and the length is 200-210mm;
each spike of grape spike comprises 3-5 grape balls, and each string of grape strings comprises 10-12 spike of grape spikes.
(III) beneficial effects
The beneficial effects of the application are as follows:
the hollow colored glaze frosted grape cluster is more real and vivid, the main stems, the secondary stems, the branch stems and the grape balls are made of colored glaze, and the main stems, the secondary stems, the branch stems and the grape balls are all connected through softening and melting of colored glaze, so that the cluster forming mode is simpler. The grape ball is transparent colored glaze, white colored glaze and dark purple colored glaze from inside to outside in proper order, and white colored glaze is in order to avoid showing the effect of totally transparent after the grape ball blows the attenuation, so white is as one deck substrate at the inlayer, avoids whole transparentization, and dark purple colored glaze becomes thin gradually in blowing process, finally presents grape purple, need not to adopt pigment etc. to carry out the colouring in grape ball outside to colored glaze itself has gloss, consequently also need not to wax the grape ball. The white frost on the surface of the grape ball can be partially fused with the colored glaze on the surface of the grape ball, so that the white frost on the surface of the grape ball has strong adhesive force and is not easy to fall off in the processes of touching and the like. In addition, the grape ball is also provided with a connecting hole which is communicated with the outside, so that the stress of the colored glaze grape ball is released.
In addition, the manufacturing method of the hollow colored glaze frosted grape cluster is simpler, the steps of coloring, waxing and the like are omitted, the manufacturing difficulty is reduced, the manufacturing speed of the finished product is faster, and the yield is high.
Specifically, the transparent colored glaze material is used as a support, white colored glaze is used as an inner lining, and the deep purple colored glaze enables the blown grape balls to be in grape purple, so that the coloring step is omitted, and the waxing step is also omitted because the colored glaze has glossiness.
In the process of blowing the grape balls, the first thin rods and the second thin rods are pulled out at the two ends of the blowing bubble in advance, so that an operator holds the two thin rods by hands respectively in the process of blowing the grape balls and keeps the blowing bubble in a rotating state, a plump grape ball shape is obtained, the position of the central axis of the grape ball is ensured to coincide with the straight line of the two thin rods as much as possible, the difficulty of blowing the grape balls is reduced, and the dependence on the proficiency of the operator in the process of blowing the grape balls is reduced.
The application can directly frost the surface of the colored glaze material grape ball, and improves the white frost component, so that the colored glaze grape ball is partially fused with the white frost in the two heating processes before and after the frosting, therefore, the white cream is firmly combined with the grape balls, has strong adhesive force and is not easy to be rubbed off in the process of touching and the like.
Finally, in the stringing process, the main stems, the secondary stems, the branch stems and the grape balls are all made of colored glaze materials, so that the stringing can be connected by only burning and melting, and the operation is simple and convenient.
Drawings
FIG. 1 is a schematic structural view of a hollow glass tube in the application;
FIG. 2 is a radial cross-sectional view of a hollow glass tube of the present application;
FIG. 3a is a schematic view of a blow molding structure according to the present application;
FIG. 3b is a schematic view of the structure after one end of the blown article is melted and plugged;
FIG. 4 is a schematic view of the structure of the blown article of the present application after blowing;
FIG. 5 is a schematic view of the structure of the preliminary grape ball of the present application;
FIG. 6a is a schematic view of a grape ball according to the present application;
FIG. 6b is a schematic view of a grape ball at another angle;
FIG. 7 is a schematic view of the structure of the grape ball after it is connected to the stem;
FIG. 8 is a schematic view of the structure of a spike of grape according to the present application;
FIG. 9 is a schematic diagram of a hollow glass frosted grape cluster according to the present application.
[ reference numerals description ]
1: a hollow glass tube; 2: transparent glass material; 3: white colored glaze material; 4: deep purple colored glaze material; 5: a first tubule; 6: a second tubule; 7: blowing bubbles; 8: grape ball; 9: a branch stalk; 10: a connection hole; 11: secondary stems; 12: a main stem; 13: and plugging the end.
Detailed Description
The application will be better explained by the following detailed description of the embodiments with reference to the drawings.
The application provides a hollow colored glaze frosted grape cluster which comprises a main stalk, a plurality of grape ears burnt and fused on the main stalk, wherein each grape ear comprises a secondary stalk and a plurality of grape balls, and the grape balls are burnt and fused on the secondary stalk through branch stalks respectively. The main stem, the secondary stem, the branch stem and the grape balls are all made of colored glaze, and are particularly soda-lime glass.
The grape ball is sequentially transparent colored glaze, white colored glaze and dark purple colored glaze from inside to outside, and the surface of the grape ball is provided with white frost which is partially fused with the colored glaze on the surface of the grape ball. The grape ball is provided with a connecting hole, part of the connecting hole is connected with the branch by burning and melting, and the other part of the connecting hole enables the grape ball to be communicated with the outside, so that stress in the grape ball is released, and the grape ball is prevented from being burst.
The dark purple colored glaze in the application may be black in visual sense, and is specifically obtained by adding a colorant such as manganese dioxide to the colored glaze.
The white cream used in the application is any one of rare earth long-acting noctilucent powder, talcum powder or reflecting powder. Specifically, the rare earth long-acting noctilucent powder is prepared by firing a mixture of strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid at 1400 ℃, mechanically crushing and grinding the mixture into powder, and sieving the powder with a 150-mesh sieve. Talc powder is magnesium silicate mineral, and is mechanically crushed and ground into 400-450 mesh powder. The reflective powder is prepared from silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide by mechanically crushing and grinding into 400-450 mesh powder.
As shown in fig. 1-9, the application also provides a method for manufacturing the hollow colored glaze frosted grape cluster, which comprises the following steps:
s1, preparing materials: taking transparent glass material 2 in a molten state by using a blowing rod sleeve, and blowing the transparent glass material into bubbles; then sequentially sleeving a white colored glaze material 3 in a molten state and a dark purple colored glaze material 4 in a molten state, and pulling Cheng Kongxin colored glaze pipe 1 by the sleeved colored glaze material to serve as a standby, wherein the specific structure of the hollow colored glaze pipe 1 is shown by referring to figures 1-2. In the process of sleeving the colored glaze materials with different colors, the viscosity of the white glass and the viscosity of the dark purple glass are lower, the transparent colored glaze materials are difficult to directly sleeve and form, and the viscosity of the transparent colored glaze is higher, so that the transparent colored glaze materials are firstly sleeved in the step, then blown into glass bubbles to play a role in shaping, the transparent colored glaze materials are used as supports for the white colored glaze materials and the dark purple colored glaze materials, then the white colored glaze materials and the dark purple colored glaze materials with lower viscosity wrap the outer sides of the transparent colored glaze materials respectively, and then the transparent colored glaze materials are rapidly drawn into a hollow colored glaze pipe with 3 layers and one body, wherein the diameter of the hollow colored glaze pipe is 10-15mm, before the colored glaze materials are hardened.
According to the application, the white colored glaze is directly used for mixing colors of colored glaze, and is used as a substrate by overlapping the white colored glaze and the dark purple colored glaze, and the white colored glaze is not transparent, so that the obtained grape ball has a relatively real color, and the grape ball is prevented from being transparent. The dark purple colored glaze after sleeving has a certain thickness and volume, so that the dark purple colored glaze has a darker color, and after the dark purple colored glaze is blown and the thickness is gradually thinned to form grape balls, the dark purple colored glaze can finally have purple color close to real grape particles, so that the coloring step is omitted. In addition, the colored glaze has glossiness and avoids the step of waxing.
It should be noted that the purple degree of different grape balls in the same grape string may be different, so the application can also adjust the thickness of the dark purple colored glaze material and the white colored glaze material in different hollow colored glaze pipes, so that the similarity between the colored glaze grape string and the real grape is higher.
S2, wire drawing: and (3) heating one end of the hollow colored glaze pipe obtained in the step (S1) to 750-850 ℃ by using a lamper flame spray gun with the flame temperature of 950-1100 ℃, pulling out the first tubule 5 after the hollow colored glaze pipe is softened, and then heating the hollow colored glaze pipe with a certain length to be softened by taking the joint of the first tubule 5 and the hollow colored glaze pipe 1 as a starting point, and pulling out the second tubule 6 to obtain a blowing piece. As shown in fig. 3a, the middle part of the blow molding is a blowing bubble 7, and two ends of the blowing bubble 7 are respectively connected with the first tubule 5 and the second tubule 6 into a whole.
S3, blowing: as shown in fig. 3b, the end of one of the first tubule or the second tubule is melted and sealed to form a sealed end 13, and the other is kept open. Then, the first tubule and the second tubule are respectively held by both hands, after the blown bubble 7 is burned to be orange, the blown bubble is blown into the blown bubble through the first tubule or the second tubule with holes, the first tubule and the second tubule are rotated by both hands, so that the blown part is in a rotating state, after the volume of the blown bubble is increased and the purple grape ball shown in fig. 4 is formed, the blown is stopped, and one of the first tubule or the second tubule which is melted and blocked is taken down, so that the preliminary grape ball shown in fig. 5 is obtained.
In the step S2 and the step S3, the purpose of drawing the first tubule and the second tubule is to make the operation of the process of blowing the grape balls simpler and to improve the completion efficiency and the yield. In the prior art, the blowing bubble has only one blowing rod, and the colored glaze is easy to droop and deform in the blowing process in the blowing bubble, which is an important reason that the grape balls are difficult to manufacture, the shapes are difficult to control and the yield is low in the prior art. According to the application, the tubules are respectively drawn at the two ends of the blowing bubble, so that an operator can conveniently hold the two tubules by hands respectively, and after blowing the blowing bubble, the blowing part can be rotated by manually rotating the tubules, so that the distance between the central axis of the grape ball body and the straight line where the first tubule and the second tubule are positioned is smaller than 1.5mm, and the shape of the obtained grape ball is ensured to be better. Therefore, the first tubule and the second tubule can ensure that the shape of the filled grape balls is obtained after the grape balls are blown, the positions of the central axes of the grape balls are overlapped with the straight lines of the two thin rods as much as possible, meanwhile, the difficulty of blowing the grape balls is reduced, the blowing speed is improved, and the dependence on the proficiency of operators in the process of blowing the grape balls is reduced.
Melting and plugging one end of the tubule is an important step of blowing, and if the first tubule and the second tubule are not plugged, the shape of the colored glaze grape is difficult to blow out under the condition that the first tubule and the second tubule are ventilated.
S4, frosting: the grape ball part in the preliminary grape ball is placed on a flame spray gun for preheating, so that the grape ball part is heated uniformly to 120-150 ℃, and the temperature can lead the white frost and the grape ball surface to be partially fused, thereby improving the adhesive force of the white frost. After heating, putting the grape ball part into white frost powder for rolling for one circle, taking out, heating the grape ball part again to uniformly heat the grape ball part to 100-120 ℃, and carrying out secondary heating for strengthening fusion between the grape ball and the white frost, so as to further improve the bonding firmness degree of the white frost and the grape ball and finish frosting. It should be noted that, the frosting operation may be performed multiple times according to actual situations, until the white frost on the surface of the grape ball meets the standards in terms of appearance and adhesion. When the first heating is performed before frosting, white frost is difficult to adhere to the surface of the grape balls when the heating temperature is too low and lower than 120 ℃, and when the heating temperature is too high and higher than 150 ℃, a large amount of white frost is adhered to the surface of the grape balls, so that the grape balls are difficult to show a real frosting effect due to excessive white frost, and in addition, the grape balls are softened and deformed at an excessive temperature. If the temperature of the second heating is too low, the fusion strengthening effect between the grape balls and the white frost is reduced when the temperature is lower than 100 ℃.
In addition, in the above step S3, the reasons why the closed tubule is removed after the blowing is completed include two aspects:
firstly, after removing one end of the tubule and plugging the position of the tubule with forceps, the grape ball may slightly deform, and at this time, the grape ball needs to be heated again, and blown into the grape ball through the tubule with the opening, so as to perform shaping, so as to keep the shape of the grape ball round and full. If the tubule with the opening is removed, the grape ball cannot be molded.
Secondly, if the perforated tubule is removed, the interior of the grape ball is vacuumized in a short time, and the grape ball is still at a higher temperature at this time, so that the grape ball is likely to break during the cooling shrinkage process, and the grape ball with a vacuum structure is avoided.
S5, annealing: as shown in fig. 6a and 6b, one of the first tubule or the second tubule, which is provided with openings, is removed and a connecting hole 10 is left in the grape ball 8. As shown in fig. 7, the stem 9 of the green hollow colored glaze material and the connection hole 10 are partially connected by burning and melting, and then the grape ball with the stem 9 is put into a annealing furnace for annealing. In this step, stress is already generated in the glass during the heating process, so that even after the grape balls and the branches are in fusion connection, the connection holes 10 are required to be ensured to be communicated with the outside, so that the grape balls are prevented from forming a complete closed structure, the stress is released during the annealing process, and the grape balls are prevented from cracking under the influence of the stress.
S6, forming strings: after annealing, a plurality of branch stems are connected with secondary stems 11 made of green hollow colored glaze material through burning and melting to form grape ears shown in fig. 8, and then a plurality of secondary stems are connected with main stems 12 made of green hollow colored glaze material through burning and melting to obtain grape clusters shown in fig. 9. Besides white frost, other structures of the grape strings are colored glaze products, and the bonding strength is high.
Preferably, in step S1, the transparent glass material, the white glass material and the dark purple glass material are melted at 1250-1350 ℃ for 18 hours, respectively, so that the transparent glass material, the white glass material and the dark purple glass material reach a syrup form.
In order to facilitate the operator to hold the first tubule and the second tubule in the blowing member and ensure smooth blowing, in step S2, the diameter of the first tubule is preferably 1.5-2.5mm, the length is preferably 90-120 mm, and likewise, the diameter of the second tubule is preferably 1.5-2.5mm, and the length is preferably 90-120 mm. After the first tubule is pulled out, the hollow glass tube with the length of 12-17mm is heated to soften by taking the joint of the first tubule and the hollow glass tube as a starting point, and the color and the size of the grape balls are ensured to be relatively close to those of real grapes within the length range.
Preferably, in step S5, the annealing temperature is 350-420 ℃, and the annealing time is 24-72h.
In the step S6, the diameter of the secondary stem is 5-6mm, and the length is 35-40mm; the diameter of the main stem is 8-9mm, and the length is 200-210mm. Each spike of grape spike comprises 3-5 grape balls, and each string of grape strings comprises 10-12 spike of grape spikes.
Preferably, the application also improves the white cream component, specifically, in the step S4, the white cream powder is any one of rare earth long-acting noctilucent powder, talcum powder or reflecting powder, and through researches, the three white creams are considered to have components similar to glass at present, and the three white creams can be chemically combined with the glass of the grape ball at high temperature, so that the white cream is firm and is not easy to fall off. However, the white frost obtained after coloring and waxing is easy to fall off along with the pigment and paraffin along with touching. The specific composition and particle size of the white cream have been described above and will not be described in detail.
In this embodiment, the main stem, the secondary stem and the branch stem may be sleeved with green colored glaze to obtain a green solid rod, and then one end of the obtained green solid rod is heated by a flame spray gun until the end is softened, and the corresponding diameters and lengths of the main stem, the secondary stem and the branch stem are pulled out. Wherein the preparation of the branch stems only needs to be completed before the annealing in the step S5, and the preparation of the secondary stems and the main stems only needs to be completed before the stringing in the step S6.
Example 1
The embodiment of the application provides a manufacturing method of a hollow colored glaze frosted grape cluster, which comprises the following steps:
s1: preparing materials: respectively taking transparent soda lime glass, porcelain white material and porcelain black material, respectively melting at 1300 ℃, blowing a rod to take the transparent glass material once or more times, blowing small bubbles, then sleeving the porcelain white material and the porcelain black material in sequence, and rapidly drawing into a hollow glass tube with the diameter of 15mm for later use.
S2: and (3) wiredrawing: the flame temperature of a lamper flame spray gun is kept at 950 ℃, the tail end of a hollow colored glaze pipe with the diameter of 15mm is heated to about 750 ℃, the hollow colored glaze pipe is softened, after the degree of stretching is met, a first tubule with the diameter of about 1.5mm and the length of about 110mm is rapidly stretched, and then a region with the length of about 15mm on one side of the hollow colored glaze pipe is used as a blowing bubble to be heated in a rotating way to be softened, and a second tubule with the diameter of 1.5mm and the length of 110mm is also rapidly stretched.
S3: blowing: one of the first tubule or the second tubule is softened and blocked, then when the blown bubble glass is burned to be orange, the unblocked tubule is rapidly placed into the mouth for blowing, and the pressure of the blown gas is very low in the blowing process. In the blowing process, the first tubule and the second tubule are rotated by both hands, so that the blowing part is in a rotating state, blowing is stopped after the volume of the blown bubble is increased to a proper size, and one of the first tubule or the second tubule, which is melted and blocked, is taken down to obtain the preliminary grape ball.
S4: and (3) preheating the grape ball part in the preliminary grape ball on a flame spray gun, rolling the grape ball part in white frost powder for one circle, taking out, and heating the grape ball part again to finish frosting.
S5: one of the openings arranged in the first tubule or the second tubule is removed, and a connecting hole is reserved on the grape ball. The branch stems and the connecting hole are connected by burning and melting, and then the grape balls with the branch stems are put into a temperature-reducing furnace with the temperature of 380 ℃ for annealing for 24 hours.
S6, forming strings: after annealing, 4 branches are connected with secondary branches with the diameter of 5mm and the length of 35mm through burning and melting to form grape ears, and then 12 secondary branches are connected with a primary stem with the diameter of 9mm and the length of 210mm through burning and melting to obtain grape clusters.
The white frost powder in the step S4 is rare earth long-acting noctilucent powder, and the preparation method comprises the following steps: mixing strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid uniformly, firing the mixture into blocks at a high temperature of 1400 ℃, mechanically crushing and grinding the blocks into powder, filtering out impurities and large particles by using a 150-mesh screen, and screening the powder for standby.
Example 2
The embodiment of the application provides a manufacturing method of a hollow colored glaze frosted grape cluster, which comprises the following steps:
s1: preparing materials: respectively taking transparent soda lime glass, porcelain white material and porcelain black material, respectively melting at 1450 ℃, blowing a rod to take the transparent glass material once or more times, blowing small bubbles, then sleeving the porcelain white material and the porcelain black material in sequence, and rapidly drawing into a hollow glass tube with the diameter of 12mm for later use.
S2: and (3) wiredrawing: and (3) keeping the flame temperature of the lamper flame spray gun at 1020 ℃, heating the tail end of the hollow colored glaze pipe with the diameter of 12mm to about 780 ℃, softening the hollow colored glaze pipe, rapidly stretching out a first tubule with the diameter of about 2mm and the length of about 110mm after the hollow colored glaze pipe accords with the stretching degree, and then carrying out rotary heating to soften the first tubule with the diameter of 2mm and the length of 110mm as a blowing bubble in a region with the length of about 15mm on one side of the hollow colored glaze pipe, wherein the second tubule with the diameter of about 110mm is also rapidly stretched out.
S3: blowing: the operation is the same as that of example 1, and will not be described again.
S4: and (3) preheating the grape ball part in the preliminary grape ball on a flame spray gun, rolling the grape ball part in white frost powder for one circle, taking out, and heating the grape ball part again to finish frosting.
S5: one of the openings arranged in the first tubule or the second tubule is removed, and a connecting hole is reserved on the grape ball. The branch stems and the connecting hole are connected by burning and melting, and then the grape balls with the branch stems are put into a temperature-reducing furnace with the temperature of 380 ℃ for annealing for 24 hours.
S6, forming strings: after annealing, 5 branches are connected with secondary branches with the diameter of 6mm and the length of 40mm through burning and melting to form grape ears, and then 11 secondary branches are connected with a primary stem with the diameter of 9mm and the length of 210mm through burning and melting to obtain grape clusters.
The white frost powder in the step S4 is reflective powder, and the main components of the white frost powder are a mixture of silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide, and the white frost powder is mechanically crushed and ground into 450-mesh powder for later use.
Example 3
The embodiment of the application provides a manufacturing method of a hollow colored glaze frosted grape cluster, which comprises the following steps:
s1: preparing materials: respectively taking transparent soda lime glass, porcelain white material and porcelain black material, respectively melting at 1350 ℃, blowing a rod to take the transparent glass material once or more times, blowing small bubbles, then sleeving the porcelain white material and the porcelain black material in sequence, and rapidly drawing into a hollow glass tube with the diameter of 10mm for later use.
S2: and (3) wiredrawing: the flame temperature of a flame spray gun of a lamp worker is kept at 1100 ℃, the tail end of a hollow colored glaze pipe with the diameter of 10mm is heated to about 800 ℃, the hollow colored glaze pipe is softened, after the degree of stretching is met, a first tubule with the diameter of about 2.5mm and the length of about 110mm is rapidly stretched, then a region with the length of about 15mm on one side of the hollow colored glaze pipe is used as a blowing bubble to be heated and softened, and a second tubule with the diameter of 2.5mm and the length of 110mm is also rapidly stretched.
S3: blowing: the operation is the same as that of example 1, and will not be described again.
S4: and (3) preheating the grape ball part in the preliminary grape ball on a flame spray gun, rolling the grape ball part in white frost powder for one circle, taking out, and heating the grape ball part again to finish frosting.
S5: one of the openings arranged in the first tubule or the second tubule is removed, and a connecting hole is reserved on the grape ball. The branch stems and the connecting hole are connected by burning and melting, and then the grape balls with the branch stems are put into a temperature-reducing furnace with the temperature of 380 ℃ for annealing for 24 hours.
S6, forming strings: after annealing, 3 branches are connected with secondary branches with the diameter of 5mm and the length of 35mm through burning and melting to form grape ears, and then 12 secondary branches are connected with a primary stem with the diameter of 9mm and the length of 210mm through burning and melting to obtain grape clusters.
The talcum powder in the step S4 is magnesium silicate mineral (Mg 3 [Si 4 O 10 ](OH) 2 ) Mechanically crushing and grinding into 400-450 mesh powder for later use.
The colored glaze grape strings obtained in the embodiment 1, the embodiment 2 and the embodiment 3 are all real and vivid, the white frost effect on the colored glaze grape strings is relatively similar to that on real grapes, the colored glaze grape strings are not dropped in the processes of long-time placement and multiple touches, and the bonding force between the colored glaze grape strings and the grape balls is relatively good.
The ceramic white materials in examples 1, 2 and 3 are white colored glaze materials, and the "ceramic black material" actually refers to dark purple colored glaze, but the colored glaze materials themselves have a certain thickness and volume, and are observed to be relatively close to black by naked eyes, so that the colored glaze materials are called as "ceramic black materials" according to the habit.
The above embodiments are only for explaining the present application and do not limit the scope of protection of the present application, and those skilled in the art make various variations or modifications within the scope of the claims, which fall within the essential content of the present application.

Claims (9)

1. The hollow colored glaze frosted grape cluster is characterized by comprising a main stalk, a plurality of grape ears burnt on the main stalk, wherein each grape ear comprises a secondary stalk and a plurality of grape balls; the grape balls are respectively burnt and melted on the secondary stems through the branch stems;
the main stem, the secondary stem, the branch stem and the grape balls are all made of colored glaze;
the grape balls are sequentially transparent colored glaze, white colored glaze and dark purple colored glaze from inside to outside;
the surface of the grape ball is provided with white frost which is fused with the colored glaze part on the surface of the grape ball;
the grape ball is provided with a connecting hole, the connecting hole is connected with the branch by burning and melting, and the other part is communicated with the outside.
2. The hollow colored glaze frosted grape cluster according to claim 1, wherein the white frost is rare earth long-acting noctilucent powder, talcum powder or reflecting powder;
the rare earth long-acting noctilucent powder is prepared by firing a mixture of strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid at 1400 ℃;
the talcum powder is magnesium silicate salt mineral;
the reflective powder is a mixture of silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide.
3. A method for making a hollow colored glaze frosted grape cluster according to any one of claims 1-2, comprising the steps of:
s1, preparing materials: sleeving a transparent glass material in a molten state by using a blowing rod, blowing the transparent glass material into bubbles, sleeving a white glass material in the molten state and a dark purple glass material in the molten state in sequence, and pulling a Cheng Kongxin glass tube sleeved with the obtained glass material for standby;
s2, wire drawing: heating one end of the hollow colored glaze pipe obtained in the step S1 to soften by using a flame spray gun, pulling out a first tubule, and then heating the hollow colored glaze pipe with a certain length to soften by taking the joint of the first tubule and the hollow colored glaze pipe as a starting point, and pulling out a second tubule to obtain a blowing part; the middle part of the blowing part is a blowing bubble, and two ends of the blowing bubble are respectively connected with the first tubule and the second tubule;
s3, blowing: melting and plugging one of the first tubule or the second tubule, and keeping the other one open; then holding the first tubule and the second tubule by hand, after firing the blown bubble into orange, blowing air into the blown bubble through the first tubule or the second tubule with holes, rotating a blowing part through adjusting the first tubule and the second tubule in the blowing process, and taking down one of the first tubule or the second tubule after the volume of the blown bubble is increased and a purple grape ball is formed, so as to obtain a preliminary grape ball;
s4, frosting: preheating the grape ball part in the preliminary grape ball, putting the grape ball part in white frost powder for rolling for one circle, taking out, and heating the grape ball part again to finish frosting;
s5, annealing: removing one of the first tubule or the second tubule with the opening, leaving a connecting hole on the grape ball, connecting the branch with the connecting hole by burning and melting, and then putting the grape ball with the branch into a temperature-reducing furnace for annealing;
s6, forming strings: after annealing, connecting a plurality of branch stems with the secondary stems through burning and melting to form grape ears, and then connecting a plurality of secondary stems with the main stems through burning and melting to obtain grape clusters.
4. The method according to claim 3, wherein in step S1, the transparent glass material, the white glass material and the dark purple glass material are melted at 1250-1450 ℃ for 18 hours, respectively, so that the transparent glass material, the white glass material and the dark purple glass material reach a syrup form;
the diameter of the hollow colored glaze pipe is 10-15mm.
5. A method according to claim 3, wherein in step S2, the first tubule has a diameter of 1.5-2.5mm and a length of 90-120 mm; the diameter of the second tubule is 1.5-2.5mm, and the length is 90-120 mm;
after the first tubule is pulled out, the hollow glass tube with the length of 12-17mm is heated to soften by taking the joint of the first tubule and the hollow glass tube as a starting point.
6. A method according to claim 3, wherein in step S3, the blown article is kept in a rotated state during the increase of the volume of the blown bulb, so that the distance between the central axis of the preliminary grape ball and the straight line where the first tubule and the second tubule are located is less than 1.5mm.
7. The method according to claim 3, wherein in step S4, the white frost powder is rare earth long-acting noctilucent powder, talcum powder or reflective powder;
the rare earth long-acting noctilucent powder is prepared by firing a mixture of strontium carbonate, aluminum oxide, europium oxide, dysprosium oxide and boric acid at 1400 ℃;
the talcum powder is magnesium silicate salt mineral;
the reflective powder is a mixture of silicon dioxide, calcium oxide, sodium oxide, titanium dioxide and barium oxide;
the particle size of the rare earth long-acting noctilucent powder, talcum powder or reflecting powder is 150-450 meshes.
8. The method according to claim 3, wherein in step S5, the annealing temperature is 350-420 ℃ and the annealing time period is 24-72h.
9. The method according to claim 3, wherein in step S6, the diameter of the secondary stem is 5-6mm and the length is 35-40mm; the diameter of the main stem is 8-9mm, and the length is 200-210mm;
each spike of grape spike comprises 3-5 grape balls, and each string of grape strings comprises 10-12 spike of grape spikes.
CN202310801653.9A 2022-07-01 2023-07-03 Hollow colored glaze frosted grape cluster and manufacturing method thereof Pending CN116811471A (en)

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CN86100654A (en) * 1986-01-24 1987-08-05 北京市东城区葡萄常工艺厂 A kind of ornamental Artificial grape
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