CN116745953A - Electrode sheet, electrode assembly, battery cell, battery, electricity using device, and manufacturing method - Google Patents

Electrode sheet, electrode assembly, battery cell, battery, electricity using device, and manufacturing method Download PDF

Info

Publication number
CN116745953A
CN116745953A CN202180089188.XA CN202180089188A CN116745953A CN 116745953 A CN116745953 A CN 116745953A CN 202180089188 A CN202180089188 A CN 202180089188A CN 116745953 A CN116745953 A CN 116745953A
Authority
CN
China
Prior art keywords
pole piece
tab
electrode
electrode sheet
folding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202180089188.XA
Other languages
Chinese (zh)
Inventor
肖海河
张小文
彭爽娟
黄亚萍
刘强
李白清
金海族
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Contemporary Amperex Technology Co Ltd
Original Assignee
Contemporary Amperex Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Contemporary Amperex Technology Co Ltd filed Critical Contemporary Amperex Technology Co Ltd
Publication of CN116745953A publication Critical patent/CN116745953A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0583Construction or manufacture of accumulators with folded construction elements except wound ones, i.e. folded positive or negative electrodes or separators, e.g. with "Z"-shaped electrodes or separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0431Cells with wound or folded electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/045Cells or batteries with folded plate-like electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/045Cells or batteries with folded plate-like electrodes
    • H01M10/0454Cells or batteries with electrodes of only one polarity folded
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0459Cells or batteries with folded separator between plate-like electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/103Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/533Electrode connections inside a battery casing characterised by the shape of the leads or tabs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/584Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/586Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/584Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/59Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
    • H01M50/595Tapes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The application relates to the field of batteries, in particular to an electrode plate, an electrode assembly, a battery cell, a battery, an electric device and a manufacturing method. Wherein, be equipped with folding guide portion on the electrode slice, folding guide portion guides the electrode slice folding. Based on this, the electrode slice can fold the back, stacks again, need not to pile up one by one, and the folding in-process, can be under folding guide's guide, consequently, can effectively improve the production efficiency of lamination battery.

Description

Electrode sheet, electrode assembly, battery cell, battery, electricity using device, and manufacturing method Technical Field
The application relates to the field of batteries, in particular to an electrode plate, an electrode assembly, a battery cell, a battery, an electric device and a manufacturing method.
Background
Currently, batteries are increasingly widely applied to energy storage power supply systems such as hydraulic power, firepower, wind power and solar power stations, electric vehicles such as electric bicycles, electric motorcycles and electric automobiles, and a plurality of fields such as military equipment and aerospace.
Laminated batteries are an important battery type, however, the laminated batteries have low production efficiency due to the limitations of the structure thereof.
Disclosure of Invention
The application provides an electrode plate, an electrode assembly, a battery cell, a battery, an electric device and manufacturing methods of the electrode plate and the electrode assembly, so as to improve the production efficiency of a laminated battery.
In order to achieve the above purpose, the electrode sheet provided by the application is provided with a folding guide part, and the folding guide part guides the electrode sheet to fold. Based on this, the electrode slice can fold the back, stacks again, need not to pile up one by one, and the folding in-process, can be under folding guide's guide, consequently, can effectively improve the production efficiency of lamination battery.
In some embodiments, the folding guide comprises a score or crease. The arranged nicks or folds can effectively play a role in folding and guiding, and are convenient to fold.
In some embodiments, the fold guides are of a continuous or intermittent type. When the folding guide part is in a continuous line shape, the structure of the folding guide part is simpler and the processing is more convenient. When the folding guide part is in a discontinuous line type, the area occupied by the folding guide part is relatively small, so that the folding guide part is beneficial to improving the structural strength of the electrode plate as much as possible while facilitating the folding of the electrode plate.
In some embodiments, the fold guide is in the form of a dashed line. The dashed line is easier to process than other types of broken line.
In some embodiments, the fold guides are dotted or linear dashed lines. Thus, the processing of the virtual linear folding guide part is convenient.
In some embodiments, the folding guides are parallel to the width direction of the electrode sheet, or the folding guides are inclined with respect to the width direction of the electrode sheet. Wherein, when folding guide part is parallel to the width direction of electrode slice, folding guide part's processing is comparatively convenient. When the folding guide part inclines relative to the width direction of the electrode plate, the lithium separation risk is reduced, and the safety performance is improved.
In some embodiments, only one fold guide is provided on the electrode sheet to guide the electrode sheet to make a single fold. Thus, the electrode plate can be guided by the folding guide part to rapidly complete the folding process.
The electrode assembly provided by the application comprises:
a first pole piece; and
a second pole piece having a polarity opposite to the first pole piece and stacked with the first pole piece;
wherein at least one of the first pole piece and the second pole piece is the electrode piece of the application.
By providing at least one of the first and second electrode sheets as an electrode sheet having a folding guide portion, it is advantageous to improve the production efficiency of the laminated battery.
In some embodiments, the first pole piece is reciprocally folded in a first direction such that the first pole piece comprises a plurality of first laminations connected and stacked in sequence, and the second pole piece is singly folded in a second direction such that the second pole piece comprises two second laminations connected to each other, the second direction being perpendicular or parallel to the first direction, the second laminations being alternately stacked in sequence with the first laminations.
In the above-mentioned setting, the first pole piece carries out Z shape folding, and the second pole piece carries out U-shaped fifty percent discount, can shorten the time of cutting process to improve lamination efficiency, and then effectively promote lamination battery's production efficiency.
In some embodiments, the tab of the first pole piece is located at an edge beyond the bend of the first pole piece; and/or the tab of the second pole piece is positioned at the edge outside the bending part of the second pole piece. When the tab of the first pole piece and/or the second pole piece is positioned at the edge outside the bending part, the tab is not easy to damage due to the folding process, and the structural reliability is higher.
In some embodiments, the second direction is perpendicular to the first direction, the tab of the first pole piece is located at an edge of the first pole piece adjacent to the bend, and the tab of the second pole piece is located at an end of the second pole piece remote from the bend. Based on the above, the first pole piece and the second pole piece adopt a tab outlet mode along the folding direction of the second pole piece in an orthogonal Z+U-shaped lamination mode, so that the tab outlet mode on the same side or different sides of the first pole piece and the second pole piece in the second direction is convenient, and the design requirement of the battery monomer with the positive and negative poles arranged on the same side or different sides is met.
In some embodiments, the second direction is perpendicular to the first direction, and of any two adjacent first laminations, only one first lamination has a tab, and the bent portion of the second pole piece encases the first lamination without the tab. Therefore, the positive and negative lugs are conveniently and physically isolated, and short circuit between the positive and negative lugs is prevented.
In some embodiments, the second direction is parallel to the first direction, the tab of the first pole piece is located at an edge of the first pole piece adjacent to the bend, and the tab of the second pole piece is located at an edge of the second pole piece adjacent to the bend. Based on the above, the first pole piece and the second pole piece adopt a tab outlet mode perpendicular to the folding direction of the second pole piece in an orthogonal Z+U-shaped lamination mode, so that the first pole piece and the second pole piece can conveniently output tabs on the same side or different sides of the longitudinal direction of the first pole piece, and the design requirement of the battery monomer with the positive and negative poles arranged on the same side or different sides is met.
In some embodiments, at least one of the two second laminations of the second pole piece has a tab. When only one of the two second laminations of the second pole piece is provided with the pole lug, the structure is simpler. When two second lamination of second pole piece all have the utmost point ear, electric energy transmission efficiency is higher, and operational reliability is higher.
In some embodiments, the second pole piece has an inactive region comprising a fold of the second pole piece, the inactive region being uncoated with the active substance. Based on this, the area size of the portion of the negative electrode sheet that exceeds the positive electrode sheet is convenient to control.
In some embodiments, the surface of the inactive region of the second pole piece facing the first pole piece is provided with an insulating substance. Therefore, the insulation between the first pole piece and the second pole piece is improved, and the safety performance is improved.
In some embodiments, the tab of the first pole piece and the tab of the second pole piece are on the same side or on opposite sides. When the tab of the first pole piece and the tab of the second pole piece are positioned on the same side, the design requirement of the battery monomer with the positive and negative poles arranged on the same side is conveniently met. When the tab of the first pole piece and the tab of the second pole piece are positioned on two opposite sides, the design requirement of the battery cell with the negative electrode terminal arranged on two opposite sides is conveniently met.
In some embodiments, the tab of the first pole piece and the tab of the second pole piece are on the same side, and the tab of the first pole piece and the tab of the second pole piece are staggered in the folding direction of the first pole piece. Therefore, the positive and negative lugs can be effectively separated, and the mutual interference of the positive and negative lugs on the same side is prevented.
In some embodiments, the electrode assembly includes a membrane separating the first and second pole pieces, and two membranes on opposite sides of the same second pole piece in the thickness direction are folded over and cover the edges of the second pole piece where no tab is located. Based on the method, the short circuit risk can be reduced, and the safety performance is improved.
In some embodiments, the first pole piece is a negative pole piece and the second pole piece is a positive pole piece. Therefore, the area of the negative plate is conveniently larger than that of the positive plate, and the phenomenon of lithium precipitation is effectively prevented.
The battery cell provided by the application comprises a shell and further comprises the electrode assembly provided by the application, wherein the electrode assembly is arranged in the shell. Since the production efficiency of the electrode assembly is improved, the production efficiency of the battery cell including the electrode assembly is improved.
In some embodiments, the tab of the second pole piece is located at an end of the second pole piece distal from the bend, the bend of the second pole piece being in contact with the inner wall of the housing. Thus, the electrode assembly can contact with the case to transfer heat, improving the heat dissipation performance of the battery cell.
In some embodiments, a surface of the fold of the second pole piece distal from the first pole piece faces in the direction of gravity. Therefore, the second pole piece can be conveniently and fully contacted with the inner wall of the shell under the action of gravity, and a better heat dissipation effect is realized.
The battery provided by the application comprises a packaging box and further comprises the battery monomer provided by the embodiment of the application, wherein the battery monomer is arranged in the packaging box. Since the production efficiency of the battery cell is improved, the production efficiency of the battery including the battery cell is improved.
The power utilization device comprises a body, and further comprises the battery cell or the battery of the embodiment of the application, wherein the battery cell provides electric energy for the body. Based on this, the production efficiency of the power utilization device can be effectively improved.
The application provides a method for manufacturing an electrode slice, which is characterized by comprising the following steps:
a folding guide part is arranged on the electrode plate; and
the electrode sheet is folded under the guide of the folding guide portion.
The electrode plate manufactured by the method can be quickly folded under the guidance of the folding guide part and then assembled with other electrode plates, so that the production efficiency of the laminated battery is improved.
The manufacturing method of the electrode assembly provided by the application comprises the following steps:
providing a first pole piece, and reciprocally folding the first pole piece along a first direction, so that the first pole piece comprises a plurality of first laminations which are sequentially connected and stacked;
providing a second pole piece with polarity opposite to that of the first pole piece, and performing single folding on the second pole piece along a second direction, so that the second pole piece comprises two second lamination sheets connected with each other, and the second direction is perpendicular or parallel to the first direction; and
Inserting the second pole piece into the first pole piece, and enabling the second lamination and the first lamination to be alternately stacked in sequence.
The electrode assembly manufactured by the method has high efficiency.
In some embodiments, before the second pole piece is folded along the second direction for a single time, two diaphragms are further arranged on two opposite sides of the second pole piece along the thickness direction, and the two diaphragms located on two opposite sides of the same second pole piece along the thickness direction are folded and cover the edge of the second pole piece, where no tab is arranged.
Before the second pole piece is folded, the two diaphragms are utilized to carry out double-layer edge wrapping on the edge of the second pole piece, which is not provided with the pole lugs, so that the safety performance of the electrode assembly can be effectively improved under the condition that the second pole piece is convenient to fold.
In the application, the electrode plate is provided with the folding guide part, so that the electrode plate can be quickly folded under the guidance of the folding guide part and then assembled with other electrode plates without stacking one by one, thereby having higher efficiency and being beneficial to improving the production efficiency of the laminated battery.
The foregoing description is only an overview of the present application, and is intended to be implemented in accordance with the teachings of the present application in order that the same may be more clearly understood and to make the same and other objects, features and advantages of the present application more readily apparent.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this specification, illustrate embodiments of the application and together with the description serve to explain the application and do not constitute a limitation on the application. In the drawings:
FIG. 1 is a schematic diagram of an electrical device in an embodiment of the application.
Fig. 2 is a schematic diagram of a battery in an embodiment of the present application.
Fig. 3 is a perspective view of a battery cell according to a first embodiment of the present application.
Fig. 4 is a front view of a battery cell according to a first embodiment of the present application.
Fig. 5 is a cross-sectional view A-A of fig. 4.
Fig. 6 is an enlarged partial schematic view of I of fig. 5.
Fig. 7 is an enlarged partial schematic view of II of fig. 5.
Fig. 8 is a B-B cross-sectional view of fig. 4.
Fig. 9 is an enlarged partial schematic view of III of fig. 8.
Fig. 10 is a schematic diagram of the lamination process of the first pole piece and the second pole piece in the first embodiment.
Fig. 11 is a side view of fig. 10.
Fig. 12 is an enlarged partial schematic view of IV of fig. 11.
Fig. 13 is a partially enlarged view of V of fig. 11.
Fig. 14 is a perspective view of a battery cell according to a second embodiment of the present application.
Fig. 15 is a schematic view of a battery cell in a second embodiment of the application in longitudinal section.
Fig. 16 is a front view of an electrode assembly according to a second embodiment of the present application.
Fig. 17 is a schematic diagram of a lamination process of a first pole piece and a second pole piece in a second embodiment of the application.
Fig. 18 is a side view of fig. 17.
Fig. 19 is a side view of an electrode assembly in a second embodiment of the present application.
Fig. 20 is an enlarged schematic view of a portion of VI of fig. 19.
Fig. 21 is an enlarged partial schematic view of VII of fig. 19.
Fig. 22 is an enlarged partial schematic view of the contact between the electrode assembly and the case in the second embodiment of the present application.
Fig. 23 is a perspective view of an electrode assembly according to a third embodiment of the present application.
Fig. 24 is a schematic view showing a lamination process of the first pole piece and the second pole piece in the third embodiment of the present application.
Fig. 25 is a schematic perspective view of a second pole piece with a folding guide portion in an unfolded state according to an embodiment of the present application.
Fig. 26 is a modification of the second pole piece shown in fig. 25.
Fig. 27 is an enlarged partial schematic view of the second tab of fig. 26 at the score.
Fig. 28 is a modification of the second pole piece shown in fig. 25.
Fig. 29 is an enlarged schematic view of part of M of fig. 28.
Fig. 30 is a modification of the second pole piece shown in fig. 25.
Fig. 31 is an enlarged partial view of N of fig. 30.
Fig. 32 is a modification of the second pole piece shown in fig. 25.
FIG. 33 is a schematic view of a membrane wrapping a second pole piece according to an embodiment of the present application.
Fig. 34 shows a method of manufacturing an electrode sheet in an embodiment of the present application.
Fig. 35 illustrates a method of manufacturing an electrode assembly in an embodiment of the present application.
Reference numerals illustrate:
100. an electric device; 101. a vehicle; 102. a controller; 103. a power plant; 104. a motor; 105. a body;
10. a battery;
20. a battery cell; 201. an electrode assembly; 202. a housing; 203. a housing; 204. an end cap; 205. an adapter; 206. an electrode terminal; 20a, a negative terminal; 20b, a positive terminal;
30. a packaging box; 301. a case; 302. a case cover;
1. a first pole piece; 11. a first lamination; 12. a first tab; 13. a negative electrode ear; 14. a negative electrode sheet; 15. a tab;
2. a second pole piece; 21. a second lamination; 22. a second lug; 23. a positive electrode tab; 24. a positive plate; 25. a bending part; 26. an inert zone; 27. an insulating substance; 28. a folding guide portion; 281. scoring; 282. folding; 29. an active substance;
3. a diaphragm; 31. flanging;
4. an electrode sheet;
x, a first direction; y, second direction; z, third direction.
Detailed Description
Embodiments of the technical scheme of the present application will be described in detail below with reference to the accompanying drawings. The following examples are only for more clearly illustrating the technical aspects of the present application, and thus are merely examples, and are not intended to limit the scope of the present application.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs; the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the application; the terms "comprising" and "having" and any variations thereof in the description of the application and the claims and the description of the drawings above are intended to cover a non-exclusive inclusion.
In the description of embodiments of the present application, the technical terms "first," "second," and the like are used merely to distinguish between different objects and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated, a particular order or a primary or secondary relationship. In the description of the embodiments of the present application, the meaning of "plurality" is two or more unless explicitly defined otherwise.
Reference herein to "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment may be included in at least one embodiment of the application. The appearances of such phrases in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those of skill in the art will explicitly and implicitly appreciate that the embodiments described herein may be combined with other embodiments.
In the description of the embodiments of the present application, the term "and/or" is merely an association relationship describing an association object, and indicates that three relationships may exist, for example, a and/or B may indicate: a exists alone, A and B exist together, and B exists alone. In addition, the character "/" herein generally indicates that the front and rear associated objects are an "or" relationship.
In the description of the embodiments of the present application, the term "plurality" means two or more (including two), and similarly, "plural sets" means two or more (including two), and "plural sheets" means two or more (including two).
In the description of the embodiments of the present application, the orientation or positional relationship indicated by the technical terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc. are based on the orientation or positional relationship shown in the drawings, and are merely for convenience of description and simplification of the description, and do not indicate or imply that the apparatus or element referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the embodiments of the present application.
In the description of the embodiments of the present application, unless explicitly specified and limited otherwise, the terms "mounted," "connected," "secured" and the like should be construed broadly and may be, for example, fixedly connected, detachably connected, or integrally formed; or may be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communicated with the inside of two elements or the interaction relationship of the two elements. The specific meaning of the above terms in the embodiments of the present application will be understood by those of ordinary skill in the art according to specific circumstances.
With the rapid development of electric devices such as electronic products and electric vehicles, batteries are increasingly widely applied not only to energy storage power supply systems such as hydraulic power, firepower, wind power and solar power stations, but also to electric vehicles such as electric bicycles, electric motorcycles and electric vehicles, as well as to a plurality of fields such as military equipment and aerospace. With the continuous expansion of the application field of the power battery, the market demand of the power battery is also continuously expanded, which puts higher demands on the production efficiency of the battery.
Laminated batteries are an important battery type, which is more freely opened in structure and has higher internal space utilization and higher energy density than wound batteries, and thus, are a very popular structural form. However, in the current production process of the laminated battery, a plurality of positive plates and a plurality of negative plates need to be stacked alternately in sequence, so that the production efficiency of the laminated battery is low, which has become an important factor for restricting the development of the laminated battery. Therefore, it is important to improve the production efficiency of the laminated battery.
In order to improve the production efficiency of laminated batteries, the application provides an electric device, a battery cell, an electrode assembly and a manufacturing method thereof, and an electrode sheet and a manufacturing method thereof.
Fig. 1-35 illustrate an electrical device, a battery, a cell, an electrode assembly and methods of making the same, and an electrode tab and methods of making the same in some embodiments of the application.
The application will be described with reference to fig. 1-35.
Fig. 1 exemplarily shows a structure of an electric device 100.
Referring to fig. 1, an electric device 100 is a device using a battery cell 20 as a power source, and includes the battery cell 20 and a body 105, wherein the battery 10 is disposed on the body 105 and provides electric power to the body 105; alternatively, the power consumption device 100 includes a body 105 and a battery 10 including a battery cell 20, the battery 10 is disposed on the body 105, and the battery cell 20 of the battery 10 provides electric energy for the body 105.
The power utilization device 100 can be various electric equipment such as a mobile phone, a tablet, a notebook computer, an electric toy, an electric tool, a battery car, an electric automobile, a ship, a spacecraft and the like. Among them, the electric toy may include fixed or mobile electric toys, such as a game machine, an electric car toy, an electric ship toy, and an electric airplane toy, etc. Spacecraft may include airplanes, rockets, space shuttles, spacecraft, and the like.
The power utilization device 100 includes a power source including a battery 10, the battery 10 providing driving force for the power utilization device 100. In some embodiments, the driving force of the power utilization device 100 is all electric energy, and the power source only includes the battery 10. In other embodiments, the driving force of the power utilization device 100 includes electrical energy and other energy sources (e.g., mechanical energy), where the power source includes the battery 10 and other devices such as an engine.
Taking the case where the electric device 100 is the vehicle 101 as an example. Referring to fig. 1, in some embodiments, an electric device 100 is a new energy vehicle such as a pure electric vehicle, a hybrid electric vehicle or an extended range vehicle, and includes a battery 10, a controller 102, and a power device 103 such as a motor 104, where the battery 10 is electrically connected to the power device 103 such as the motor 104 through the controller 102, so that the battery 10 can supply power to the power device 103 such as the motor 104 under the control of the controller 102.
It can be seen that the battery 10 and its battery cells 20 are important components of the power utilization device 100.
Fig. 2 exemplarily shows the structure of the battery 10.
Referring to fig. 2, the battery 10 includes a package case 30 and battery cells 20 disposed in the package case 30. The package 30 includes a case 301 and a case cover 302. The case 301 and the case cover 302 are fastened to each other, so that a closed accommodating space is formed inside the packing case 30 to accommodate the battery cells 20. The number of the battery cells 20 in the packaging box 30 can be at least two to provide more electric energy and meet higher electricity requirements. The battery cells 20 in the battery 10 are electrically connected in series, parallel or series-parallel to achieve a larger capacity or power. In fig. 2, the battery cell 20 is schematically drawn.
It can be seen that the battery cell 20 is the smallest unit cell for supplying electric power, which is a core component of the battery 10 and the power consumption device 100, and its performance directly affects the performance of the battery 10 and the power consumption device 100, and at the same time, its production efficiency directly affects the production efficiency of the power consumption device 100 and the battery 10. The improvement of the production efficiency and the performance of the battery cell 20 is advantageous to the improvement of the production efficiency and the performance of the power consumption device 100 and the battery 10.
The battery cell 20 may be various battery cells such as a lithium ion battery, and may have various shapes such as square or cylindrical.
Fig. 3 to 33 exemplarily show the structure of the battery cell.
Referring to fig. 3 to 33, the battery cell 20 includes a case 202, an electrode assembly 201, an adapter 205, and an electrode terminal 206.
Wherein the housing 202 is used to house components (e.g., the electrode assembly 201 and the adapter 205) located inside the housing 202 to provide protection for the components located inside the housing 202. The housing 202 includes a shell 203 and an end cap 204. The end cap 204 is covered with the end opening of the case 203 such that a closed space for accommodating the electrode assembly 201 and the like is formed inside the case 202.
The electrode assembly 201 is for generating electric power, is disposed inside the case 202, and provides electric power by performing an electrochemical reaction with an electrolyte injected into the case 202. The electrode assembly 201 includes the electrode sheet 4, and includes two kinds of electrode sheets 4 of the first electrode sheet 1 and the second electrode sheet 2 combined together. The first electrode sheet 1 and the second electrode sheet 2 are electrode sheets 4 having opposite polarities, and when one of them is a negative electrode sheet 14 (also referred to as an anode sheet), the other is a positive electrode sheet 24 (also referred to as a cathode sheet). The thickness of the first pole piece 1 and the second pole piece 2 is 0.05-0.2 mm. After the first pole piece 1 and the second pole piece 2 are combined, a laminated structure is formed and separated by a diaphragm 3 so as to prevent short circuit between the first pole piece 1 and the second pole piece 2. The first and second electrode sheets 1 and 2 each have a tab 15, and electric energy generated from the electrode assembly 201 is transmitted outward through the tab 15. The tabs 15 of the first and second pole pieces 1 and 2 are referred to as first and second tabs 12 and 22, respectively, for convenience of distinction.
The tab 15 is a portion of the positive and negative electrode sheets of the electrode assembly 201, which is not coated with the active material 29, extends outward from the active material 29-coated portion of the positive and negative electrode sheets, and is electrically connected to an external circuit through the adaptor 205 and the electrode terminal 206 to achieve outward transfer of electric energy. The tab 15 of the negative electrode tab 14 is referred to as a negative electrode tab 13, and the tab 15 of the positive electrode tab 24 is referred to as a positive electrode tab 23.
The adaptor 205 is disposed in the case 202 and located between the tab 15 and the electrode terminal 206 of the electrode assembly 201, for making an electrical connection between the electrode assembly 201 and the electrode terminal 206, so as to transfer the electrical energy generated by the electrode assembly 201 to the electrode terminal 206. Among them, the adapter 205 corresponding to the positive tab is called a positive adapter, and the adapter 205 corresponding to the negative tab is called a negative adapter.
The electrode terminal 206 is electrically connected to the electrode assembly 201 through the adapter 205, and is used to be connected to an external circuit to transfer electric energy generated from the electrode assembly 201 to the outside of the battery cell 20. Among them, the electrode terminal 206 corresponding to the negative electrode tab 13 is referred to as a negative electrode terminal 20a, and the electrode terminal 206 corresponding to the positive electrode tab 23 is referred to as a positive electrode terminal 20b.
It can be seen that the electrode assembly 201 is an important component of the battery cell 20, and is a key point that the battery cell 20 can provide electric energy.
The combination of the first electrode sheet 1 and the second electrode sheet 2 in the electrode assembly 201 is mainly two, namely a winding mode and a lamination mode. When the first pole piece 1 and the second pole piece 2 are combined together in a winding manner, the corresponding battery cell 20 is called a winding battery; and when the first and second pole pieces 1 and 2 are combined together in a laminated manner, the corresponding battery cell 20 is called a laminated battery. The laminated battery has no corner of the wound battery, so that the structure is more freely opened, the utilization rate of the internal space is high, and the energy density is high, thereby having better application prospect.
However, the current development of laminated batteries is severely limited by the problem of low production efficiency.
The electrode assembly 201 of the laminated battery cannot be wound as rapidly as the electrode assembly 201 of the wound battery, and in the related art, the electrode assembly 201 of the laminated battery can be stacked only in a single sheet manner, i.e., only the cut first and second electrode sheets 1 and 2 can be stacked one by one, so that the first and second electrode sheets 1 and 2 are alternately stacked in sequence and separated by the separator 3. Since in this monolithic stack each individual electrode sheet 4 needs to be cut, the cut metal edges inevitably create metal burrs and metal chips, which when entering the interior of the stack of first and second electrode sheets 1, 2, create a risk of the sheet being pierced and shorted. Further, when stacking, stacking one by one is required, and thus there is a problem in that production efficiency is low.
In view of the above, the present application improves the structure and manufacturing method of the electrode assembly 201 and the electrode tab 4 to further improve the safety performance of the laminated battery and to improve the production efficiency of the laminated battery.
Fig. 3 to 33 exemplarily show the structure of the battery cell 20 and the electrode assembly 201 and the electrode tab 4 thereof.
Referring to fig. 3-33, in the present application, an electrode assembly 201 includes a first electrode sheet 1 and a second electrode sheet 2. The first pole piece 1 is reciprocally folded in the first direction X such that the first pole piece 1 comprises a plurality of first laminations 11 connected and stacked in sequence. The second pole piece 2 is of opposite polarity to the first pole piece 1 and is folded once in the second direction Y such that the second pole piece 2 comprises two second laminations 21 connected to each other. The second direction Y is perpendicular or parallel to the first direction X. The second laminations 21 are alternately stacked in sequence with the first laminations 11.
Since the first pole piece 1 is folded back and forth along the first direction X, which is a Z-shaped (or S-shaped) folding manner, and the second pole piece 2 is folded once along the second direction Y, which is a U-shaped folding manner, in the above arrangement, the electrode assembly 201 adopts a lamination manner of a "z+u" shape.
In the lamination mode of the "z+u" shape, the electrode sheets 4 do not need to be stacked one by one, but the Z-shaped folding of the first electrode sheet 1 and the U-shaped folding of the second electrode sheets 2 may be performed respectively, and then the folded second electrode sheets 2 may be directly inserted into the first electrode sheet 1 at the same time, so that the second lamination 21 and the first lamination 11 are stacked alternately in sequence, and therefore, the production efficiency of the electrode assembly 201, the battery cell 20, the battery 10, and the power consumption device 100 may be effectively improved as compared to the single-sheet stacking mode.
Wherein, because the first pole piece 1 adopts the Z-shaped folding mode, each first lamination 11 is connected together, need not to cut first pole piece 1 into the first lamination 11 of a slice in advance, and the second pole piece 2 adopts the U-shaped folio folding mode, two second lamination 21 are connected together, need not to cut second pole piece 2 into two second lamination 21 in advance, consequently, can omit corresponding cutting step, reduce the required time of cutting process, thereby improve production efficiency.
In addition, the second pole piece 2 adopts a U-shaped folding manner, so that tens of second pole pieces 2 are simultaneously operated to be inserted into the first pole piece 1 together in the lamination process, the assembly with the first pole piece 1 is completed, the second lamination 21 is not required to be stacked on the first lamination 11 one by one, and the production efficiency is also improved from the aspect of convenience.
Therefore, the Z+U-shaped lamination mode adopted by the application can effectively improve the production efficiency of the laminated battery by shortening the time of the cutting process and improving the lamination efficiency.
In addition, in the lamination mode of the "z+u" shape, the first lamination 11 of the first pole piece 1 and the second lamination 21 of the second pole piece 2 do not need to be cut off, so, compared with the case that in the single-piece stacking mode, the lamination is disconnected from each other, and the number of the cut-off ports is effectively reduced, the reduction of the number of the cut-off ports is beneficial to reducing the occurrence probability of burrs, reducing the short-circuit risk and improving the working safety. The more the fracture is, the greater the probability of burrs being generated, which in turn easily pierces the membrane 3, resulting in a short-circuit between the first pole piece 1 and the second pole piece 2, and therefore the higher the risk of short-circuit, the lower the operational safety. In the present application, since the first lamination 11 and the second lamination 21 are cut only on three sides and are not cut on four sides, the cut-off openings of the first lamination 11 and the second lamination 21 are reduced, and thus the risk of short circuit is reduced and the working safety is improved.
It can be seen that the present application can not only effectively improve the production efficiency of the laminated battery, but also effectively improve the operational safety of the laminated battery by providing the electrode assembly 201 molded in a "z+u" shaped lamination manner.
In addition, the Z+U-shaped lamination mode adopted by the application is also convenient for improving the heat dissipation performance of the battery cell 20. For example, referring to fig. 22, in some embodiments, the tab 15 of the second pole piece 2 is located at the end of the second pole piece 2 remote from the bend 25, the bend 25 of the second pole piece 2 being in contact with the inner wall of the housing 202.
It will be understood that the bent portion 25 refers to a portion where the electrode sheet 4 is folded. Specifically, the bent portion 25 of the first pole piece 1 is a portion where the first pole piece 1 is folded, or a portion where two adjacent first laminations 11 are connected to each other after the first pole piece 1 is folded. The bent portion 25 of the second pole piece 2 is a portion where the second pole piece 2 is folded, or a portion where the two second lamination pieces 21 are connected to each other after the second pole piece 2 is folded. Referring to fig. 9, in some embodiments, the bent portion 25 of the first pole piece 1 is curved, such that the first pole piece 1 is generally S-shaped overall. Referring to fig. 12, in some embodiments, the bent portion 25 of the second pole piece 2 is curved, such that the second pole piece 2 is generally U-shaped overall.
In the related art, an insulating pallet is generally disposed between the electrode sheet 4 and the case 202 for accommodating the electrode assembly 201, and the insulating pallet is spaced between the two and is not in direct contact with the electrode assembly 201, wherein the insulating pallet supports the electrode assembly 201 and is generally made of an insulating material such as a polymer material, in which case, heat generated from the electrode assembly 201 is difficult to rapidly dissipate, and heat is accumulated in the case 202, thereby easily causing safety accidents such as overheat explosion.
Unlike the related art, in the above embodiment, the insulating support plate is not disposed between the electrode assembly 201 and the case 202, but the bending portion 25 of the second electrode plate 2 of the electrode assembly 201 adopting the U-shaped folded manner is in contact with the inner wall of the case 202, so that, since the second electrode plate 2 is generally made of a material with better heat conducting performance such as a metal material, the case 202 for accommodating the electrode assembly 201 is also generally made of a material with better heat conducting performance such as a metal material (e.g. aluminum), and the number of the second electrode plates 2 is large, and the bending portions 25 of all the second electrode plates 2 are in contact with the inner wall of the case 202, so that the total contact area is large, the direct contact heat dissipation process between the electrode assembly 201 and the case 202 can be realized, and the heat generated by the electrode assembly 201 can be quickly dissipated to the outside of the case 202, thereby effectively improving the heat dissipation performance of the battery cell 20, reducing the risk of safety accidents caused by heat accumulation, and improving the working safety.
Meanwhile, in the above embodiment, when the bending portion 25 of the second pole piece 2 contacts with the inner wall of the housing 202, the tab 15 of the second pole piece 2 is disposed at the end portion of the second pole piece 2 away from the bending portion 25, so that the bending portion 25 of the second pole piece 2 contacting with the housing 202 does not have the tab 15, and the tab 15 of the second pole piece 2 is located at the opposite side of the bending portion 25.
Therefore, by positioning the tab 15 of the second pole piece 2 at the end of the second pole piece 2 away from the bending portion 25, the bending portion 25 of the second pole piece 2 contacts with the inner wall of the housing 202, so that efficient heat dissipation between the electrode assembly 201 and the housing 202 can be achieved without affecting the implementation of the power transmission function of the second pole piece 2, and the heat dissipation performance of the battery cell 20 can be effectively improved.
Wherein, referring to fig. 22, in some embodiments, the surface of the bent portion 25 of the second pole piece 2 facing away from the first pole piece 1 faces the direction of gravity. Based on this, the bent portion 25 of the second pole piece 2 can be more fully contacted with the inner wall of the housing 202 under the action of gravity, and heat transfer is more efficient, thus being beneficial to further improving the heat dissipation performance of the battery cell 20.
As described above, in the present application, the first electrode sheet 1 and the second electrode sheet 2 are electrode sheets 4 having opposite polarities. In some embodiments, the first pole piece 1 is a positive pole piece 24 and the second pole piece 2 is a negative pole piece 14. In other embodiments, the first electrode sheet 1 is the negative electrode sheet 14 and the second electrode sheet 2 is the positive electrode sheet 24. When the first pole piece 1 and the second pole piece 2 are the negative pole piece 14 and the positive pole piece 24 respectively, since the first pole piece 1 adopts a Z-shaped folding manner and the second pole piece 2 adopts a U-shaped folding manner, the area of the first pole piece 1 can be conveniently designed to be larger than that of the second pole piece 2, so that the area of the negative pole piece 14 is conveniently larger than that of the positive pole piece 24, and the negative pole piece 14 can have a sufficient position to receive lithium ions, thereby being beneficial to preventing the occurrence of a lithium precipitation phenomenon.
The lithium deposition phenomenon is a phenomenon in which lithium ions are deposited on the surface of the negative electrode sheet at a position where the negative electrode sheet does not receive lithium ions.
The charge and discharge process of the lithium ion battery is the process of intercalation and deintercalation of lithium ions in the positive and negative electrode plates and the process of energy absorption and release. When the lithium ion battery is charged, lithium ions are generated on the positive plate of the lithium ion battery, the generated lithium ions move to the negative plate through the electrolyte and are combined with electrons to be embedded into active substances of the negative plate, and the more the embedded lithium ions are, the higher the charging capacity is. When the lithium ion battery is discharged, lithium ions embedded in the negative electrode plate are separated and move back to the positive electrode plate. The more lithium ions go back to the positive electrode, the higher the discharge capacity. However, if the negative electrode sheet does not have a position to accept lithium ions, lithium ions may precipitate (i.e., precipitate lithium) on the surface of the negative electrode sheet to form lithium dendrites, which once pierce through the separator to contact the positive electrode sheet, may cause short circuit of the battery, resulting in occurrence of fire or even explosion accidents. Therefore, the occurrence of the lithium precipitation phenomenon affects the safety performance of the lithium ion battery.
When the negative electrode sheet 14 adopts a Z-shaped folding manner and the positive electrode sheet 24 adopts a U-shaped folding manner, the area of the negative electrode sheet 14 can be conveniently larger than that of the positive electrode sheet 24, so that the occurrence of the lithium precipitation phenomenon is prevented, and the working safety of the laminated battery is further improved.
In addition, the folding direction of the first pole piece 1 and the second pole piece 2 may be perpendicular or parallel, that is, the first direction X and the second direction Y may be perpendicular or parallel, when lamination is performed.
When the first direction X and the second direction Y are perpendicular, the folding direction of the first pole piece 1 and the second pole piece 2 is perpendicular, and the lamination mode at this time may be referred to as an orthogonal "z+u" lamination mode. In this orthogonal "z+u" lamination mode, when the second pole piece 2 is folded in half and inserted into the folded first pole piece 1, on one hand, the bent portion 25 of the second pole piece 2 spans and wraps one edge of the first pole piece 1 adjacent to the bent portion 25, and the bent portion 25 of the second pole piece 2 may play a certain limiting role on the first pole piece 1 in the folding direction (i.e., the second direction Y) of the second pole piece 2, on the other hand, the bent portion 25 of the first pole piece 1 may wrap the edge of the second pole piece 2 adjacent to the bent portion 25 itself, and play a certain limiting role on the second pole piece 2 in the folding direction (i.e., the first direction X) of the first pole piece 1, and at the same time, two adjacent first laminations 11 of the first pole piece 1 sandwich one second lamination 21 of the second pole piece 2, and may play a certain limiting role on the second pole piece 2 in the third direction Z (i.e., the stacking direction of each first lamination 11) perpendicular to the first direction X and the second direction Y. Therefore, when the orthogonal Z+U-shaped lamination mode is adopted, the first pole piece 1 and the second pole piece 2 can be mutually limited, and the limiting can be realized in more directions, so that the limiting reliability is higher.
When the first direction X is parallel to the first direction Y, the folding directions of the first pole piece 1 and the second pole piece 2 are parallel, and the lamination mode at this time may be referred to as a parallel "z+u" lamination mode. In this parallel "z+u" lamination manner, when the second pole piece 2 is folded in half and inserted into the folded first pole piece 1, the bent portion 25 of the second pole piece 2 spans and wraps the bent portion 25 of the first pole piece 1, so that a certain limiting effect can be achieved on the first pole piece 1 in the folding direction (i.e., the second direction Y) of the second pole piece 2, and two adjacent first laminations 11 of the first pole piece 1 sandwich one second lamination 21 of the second pole piece 2, so that a certain limiting effect can be achieved on the second pole piece 2 in the stacking direction (i.e., the third direction Z) of each first lamination 11. It can be seen that when a parallel "z+u" lamination is used, the first pole piece 1 and the second pole piece 2 may also be limited to each other. Meanwhile, the parallel Z+U-shaped lamination mode is convenient to assemble.
It can be seen that, when the "z+u" lamination mode is adopted, no matter the orthogonal lamination mode when the first direction X is perpendicular to the second direction Y, or the parallel lamination mode when the first direction X is parallel to the second direction Y, the first pole piece 1 and the second pole piece 2 can be mutually limited, such a mutual limiting effect between the first pole piece 1 and the second pole piece 2 is beneficial to improving the structural reliability of the electrode assembly 201, and is also convenient to realize the control of the area size of the portion of the negative pole piece exceeding the positive pole piece, thereby being beneficial to improving the safety performance of the laminated battery.
The part of the negative plate beyond the positive plate is also called as Overhang, and is mainly a concept proposed for improving the safety performance of the lithium ion battery.
As described above, since lithium is separated if the area of the negative electrode sheet receiving lithium ions is insufficient during the charging process of the lithium ion battery, and dendrites generated by the separation of lithium may cause a short circuit of the battery cells if they pierce the separator, resulting in explosion or ignition, in order to allow the negative electrode sheet to have a sufficient area to receive lithium ions to improve the safety of the lithium ion battery, the negative electrode sheet is usually overdesigned, i.e., the area of the negative electrode sheet is larger than that of the positive electrode sheet, so that the edge of the negative electrode sheet generally exceeds the edge of the positive electrode sheet, and thus the portion of the negative electrode sheet exceeding the positive electrode sheet is referred to as the portion of the negative electrode sheet exceeding the positive electrode sheet.
Therefore, the part of the negative electrode plate exceeding the positive electrode plate is designed to be the size difference of the negative electrode plate exceeding the positive electrode plate, physical isolation between the positive electrode plate and the negative electrode can be formed by the size difference design, lithium ions are prevented from being separated out on the surface of the negative electrode plate, lithium crystal branches are formed, and the short circuit risk between the positive electrode plate and the negative electrode plate is reduced, so that the safety performance of the lithium ion battery can be effectively improved.
However, in the process of designing the portion of the negative electrode sheet beyond the positive electrode sheet, there is a problem that the area of the portion of the negative electrode sheet beyond the positive electrode sheet is difficult to control. Because the number of the pole pieces is large, the positive pole pieces of different layers and the negative pole pieces of different layers are difficult to align, and the relative positions between the positive pole pieces and the negative pole pieces are easy to change due to the loosening of rubberizing and the like, the control difficulty of the area of the part of the negative pole pieces exceeding the positive pole pieces is high. If the area of the part of the negative electrode plate exceeding the positive electrode plate cannot be effectively controlled, the area of the part of the negative electrode plate exceeding the positive electrode plate is easy to be too small or too large, and the battery performance is adversely affected. For example, if the area of the portion of the negative electrode tab that exceeds the positive electrode tab is too small, the portion of the negative electrode tab that exceeds the positive electrode tab easily disappears when the positive and negative electrode tabs are dislocated, resulting in failure of the short circuit preventing effect. For another example, if the area of the negative electrode plate beyond the positive electrode plate is too large, the negative electrode plate needs to occupy too much internal space of the lithium battery, which easily causes space waste, resulting in lower space utilization and affecting the improvement of energy density.
Therefore, how to effectively control the area of the portion of the negative electrode plate beyond the positive electrode plate is an important problem, but is also a difficult problem.
In the Z+U-shaped lamination mode, the area of the part of the negative electrode plate exceeding the positive electrode plate can be controlled conveniently due to the limiting effect of the bending part 25 of the second electrode plate 2 on the first electrode plate 1.
For example, referring to fig. 6 and 12, in some embodiments, the first and second electrode sheets 1 and 2 are configured as a negative electrode sheet 14 and a positive electrode sheet 24, respectively, and the second electrode sheet 2 is configured with an inactive region 26, the inactive region 26 including the bent portion 25 of the second electrode sheet 2, and the inactive region 26 being uncoated with the active material 29. Wherein, illustratively, the dimension of the inactive region 26 in the second direction Y (being one half of the width of the inactive region 26 in the expanded state) is 1-18 mm, e.g., in some embodiments, the dimension of the inactive region 26 in the second direction Y is 3-4 mm.
Because the inert area 26 of the second electrode plate 2 is not coated with the active material 29, the inert area 26 of the second electrode plate 2 forms an inactive area and does not participate in electrochemical reaction in the charge-discharge process, in this case, the portion of the first electrode plate 1 extending into the corresponding inert area 26 is the portion exceeding the second electrode plate 2, and because the first electrode plate 1 and the second electrode plate 2 are the negative electrode plate 14 and the positive electrode plate 24 respectively, the portion of the first electrode plate 1 extending into the corresponding inert area 26, namely the portion of the negative electrode plate 14 exceeding the positive electrode plate 24, does not generate lithium precipitation, can form the portion of the negative electrode plate exceeding the positive electrode plate, and at this time, the area size of the portion of the corresponding negative electrode plate exceeding the positive electrode plate depends on the area size of the inert area 26, so that the effective control of the area size of the portion exceeding the positive electrode plate by the negative electrode plate can be realized only by controlling the area size of the inert area 26. During specific assembly, the size of the part of the negative electrode plate 14 exceeding the positive electrode plate 24 can be controlled by inserting the second electrode plate 2 processed in the inert region 26 into the first electrode plate 1, so that the more accurate control of the size of the part of the negative electrode plate exceeding the positive electrode plate is conveniently realized.
It should be noted that, in fig. 6, the blank area between the bent portion 25 of the second pole piece 2 and the end portion of the first lamination 11 is actually filled with the diaphragm 3, but the corresponding diaphragm portion is not shown in the drawing, that is, during the process of inserting the second pole piece 2 into the first pole piece 1, the second pole piece 2 is directly inserted into the bottom, and the distance between the edge of the bent portion 25 of the second pole piece 2 and the edge of the first pole piece 1 enclosed by the bent portion 25 of the second pole piece 2 is only approximately equal to the thickness of the diaphragm 3 or a multiple of the thickness of the diaphragm 3.
In addition, the inert region 26 of the second pole piece 2 is convenient for controlling the area of the part of the negative pole piece exceeding the positive pole piece and improving the insulation reliability between the first pole piece 1 and the second pole piece 2. For example, referring to fig. 12, in some embodiments, the surface of the inactive area 26 of the second pole piece 2 facing the first pole piece 1 is provided with an insulating substance 27. By way of example, the insulating substance 27 is a ceramic coating or an insulating glue (for example an insulating glue or an insulating paste).
No matter the second pole piece 2 is the positive pole piece 24 or the negative pole piece 14, when the surface of the inertia area 26 of the second pole piece 2 facing the first pole piece 1 is provided with the insulating material 27, the inertia area 26 and the first pole piece 1 can be insulated through the diaphragm 3 and the insulating material 27, so that the insulativity between the first pole piece 1 and the second pole piece 2 is better, the occurrence of short-circuit accidents can be prevented more reliably, and the working safety is further improved. Since the inert region 26 is not provided with the active material 29, the insulating material 27 is provided in the inert region 26, and the insulating material 27 does not affect the normal electrochemical reaction. Therefore, the insulating material 27 is arranged on the surface of the inert area 26 of the second pole piece 2 facing the first pole piece 1, so that the insulativity between the first pole piece 1 and the second pole piece 2 can be further improved under the condition that normal electrochemical reaction is not affected, and the working safety is more effectively improved.
In the application, the tab-out modes of the first pole piece 1 and the second pole piece 2 can be varied.
For example, referring to fig. 3-24, in some embodiments, the tab 15 of the first pole piece 1 is located at an edge beyond the bend 25 of the first pole piece 1. At this time, the tab 15 of the first pole piece 1 is not located at the bent portion 25 of the first pole piece 1 and is not easily damaged by folding, so that the reliability is higher than the case where the tab 15 of the first pole piece 1 is located at the bent portion 25 of the first pole piece 1.
As another example, referring to fig. 3-24, in some embodiments, the tab 15 of the second pole piece 2 is located at an edge beyond the bend 25 of the second pole piece 2. At this time, the tab 15 of the second pole piece 2 is not located at the bent portion 25 of the second pole piece 2 and is not easily damaged by folding, so that the reliability is higher than the case where the tab 15 of the second pole piece 2 is located at the bent portion 25 of the second pole piece 2. In addition, when the tab 15 of the second pole piece 2 is located at the edge outside the bending portion 25, but not located at the bending portion 25, contact heat transfer between the bending portion 25 of the second pole piece 2 and the inner wall of the housing 202 is facilitated. Meanwhile, the tab 15 of the second pole piece 2 is not located at the bending part 25 of the second pole piece 2, and the first pole piece 1 is conveniently limited by using the bending part 25 of the second pole piece 2. Since the tab 15 generally has a longer extension length and a relatively soft hardness, if the tab 15 of the second pole piece 2 is located at the bending portion 25, this means that the bending portion 25 needs to extend longer and has a softer hardness, and in this case, the bending portion 25 of the second pole piece 2 has no more effective limiting effect on the first pole piece 1.
As another example, referring to fig. 3-24, in some embodiments, the tabs 15 of the first pole piece 1 and the second pole piece 2 are each located at an edge beyond the bend 25. Since in this case, the tabs of both the first and second pole pieces 1 and 2 are not easily damaged by folding, the reliability is higher.
As an example of the edges of the first pole piece 1 and the second pole piece 2, which are both located outside the bending portion 25, referring to fig. 3 to 20, the second direction Y is perpendicular to the first direction X, the tab 15 of the first pole piece 1 is located at the edge of the first pole piece 1 adjacent to the bending portion 25, and the tab 15 of the second pole piece 2 is located at the end of the second pole piece 2 away from the bending portion 25.
In the above example, since the second direction Y is perpendicular to the first direction X, an orthogonal "z+u" lamination is adopted between the first pole piece 1 and the second pole piece 2. Meanwhile, since the tab 15 of the first pole piece 1 is located at the edge of the first pole piece 1 adjacent to the bending portion 25, and the tab 15 of the second pole piece 2 is located at the end of the second pole piece 2 away from the bending portion 25, the extending directions (abbreviated as tab directions) of the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 are all along the folding direction (i.e., the second direction Y) of the second pole piece 2. Therefore, in the above example electrode assembly 201, the first electrode plate 1 and the second electrode plate 2 adopt a tab-out manner along the folding direction of the second electrode plate 2 in the orthogonal "z+u" lamination manner, and in this case, the first electrode plate 1 and the second electrode plate 2 can be tab-out on the same side or different sides in the second direction Y, so as to conveniently meet the design requirements of the battery cells with the positive and negative electrodes arranged on the same side or different sides.
As a specific implementation manner of the above example, referring to fig. 3 to 13, in some embodiments, the second direction Y is perpendicular to the first direction X, and, among any two adjacent first laminations 11, only one first lamination 11 has a tab 15, and the bent portion 25 of the second lamination 2 encases the first lamination 11 where the tab 15 is not disposed. Based on this setting, the mode that the tab was gone out to first pole piece 1 adoption interval, that is, separates a first lamination 11, goes out a tab 15, because under this case, the first lamination 11 of not going out tab 15 can be for the tab 15 reservation space of second pole piece 2, only need make the tab direction that goes out of first lamination 11 of tab and the tab direction that goes out of second pole piece 2 opposite, that is, only need make first pole piece 1 and second pole piece 2 go out the tab in the opposite both sides in second direction Y, can carry out the physics to positive and negative tab and keep apart, prevent the short circuit between positive and negative pole ear, it is simple and convenient.
As another example of the edges of the first pole piece 1 and the second pole piece 2, in which the tabs 15 are located outside the bent portion 25, the second direction Y is parallel to the first direction X, the tabs 15 of the first pole piece 1 are located at the edge of the first pole piece 1 adjacent to the bent portion 25, and the tabs 15 of the second pole piece 2 are located at the edge of the second pole piece 2 adjacent to the bent portion 25, as shown in fig. 23 to 24.
In the above example, since the second direction Y is parallel to the first direction X, a parallel "z+u" lamination is adopted between the first pole piece 1 and the second pole piece 2. Meanwhile, since the tab 15 of the first pole piece 1 is located at the edge of the first pole piece 1 adjacent to the bending portion 25 and the tab 15 of the second pole piece 2 is located at the edge of the second pole piece 2 adjacent to the bending portion 25, the tab directions of the first pole piece 1 and the second pole piece 2 are both perpendicular to the folding direction of the second pole piece 2 (i.e., the second direction Y, which is also the first direction X in this example). As can be seen, in the above example electrode assembly 201, the first electrode plate 1 and the second electrode plate 2 adopt a tab-out mode perpendicular to the folding direction of the second electrode plate 2 in the orthogonal "z+u" lamination mode, in this case, the first electrode plate 1 and the second electrode plate 2 may perform tab-out on the same side or different sides in the direction perpendicular to the second direction Y (in this example, the second direction Y is consistent with the first direction X) and the third direction Z, so as to conveniently meet the design requirement of the battery cell with the positive electrode terminal and the negative electrode terminal disposed on the same side or different sides.
Therefore, in the orthogonal lamination mode of the 'Z+U' shape or in the parallel lamination mode of the 'Z+U' shape, the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 can be positioned on the same side or opposite sides, that is, the first pole piece 1 and the second pole piece 2 can both carry out tab on the same side or opposite sides, thus conveniently meeting the design requirement of the battery monomer with the positive and negative poles arranged on the same side or opposite sides.
When the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 are located on the same side, contact heat transfer between the bent portion 25 of the second pole piece 2 and the inner wall of the housing 202 is more convenient, and at this time, the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 may be staggered in the first direction X, so as to prevent mutual interference between the positive and negative tabs.
Referring to fig. 6-32, in the present application, at least one of the two second laminations 21 of the second pole piece 2 has a tab 15, that is, only one second lamination 21 of the two second laminations 21 of the second pole piece 2 has a tab 15, or both second laminations 21 of the second pole piece 2 have a tab 15. When only one second lamination 21 of the two second laminations 21 of the second pole piece 2 has the tab 15, since the two second laminations 21 are connected together by the bending portion 25, the two second laminations 21 can share one tab 15 to transmit electric energy outwards, wherein the second lamination 21 without the tab 15 can transmit electric energy to the second lamination 21 with the tab 15 through the bending portion 25 and is transmitted outwards by the tab 15 with the tab 15 of the second lamination 21. In this case, the second pole piece 2 can complete the outward transmission of the electric energy only by one pole lug 15, so the structure is simpler. When the two second laminations 21 of the second pole piece 2 are provided with the tabs 15, the second pole piece 2 can transmit electric energy outwards through the two tabs 15, so that the electric energy transmission efficiency is higher, meanwhile, the tabs 15 of the two second laminations 21 can be mutually standby, so that when the tab 15 of one second lamination 21 fails, the second pole piece 2 can still transmit electric energy normally through the tab 15 of the other second lamination 21, and therefore, the working reliability of the second pole piece 2, the electrode assembly 201, the battery cell 20, the battery 10 and the power utilization device 100 can be further effectively improved.
In each of the foregoing embodiments, the electrode sheets 4 of the electrode assembly 201 need to be folded first before being assembled together. To facilitate folding of the electrode sheet 4, see fig. 25-32, in some embodiments, a folding guide 28 is provided on the electrode sheet 4, the folding guide 28 guiding the electrode sheet 4 to fold.
Based on the above arrangement, the electrode sheet 4 can be folded under the guidance of the folding guide portion 28, on one hand, the electrode sheet 4 can be assembled with other electrode sheets 4 after being folded without being stacked one by one, on the other hand, the electrode sheet 4 can rapidly complete the folding process under the guidance of the folding guide portion 28, and under this condition, not only the cutting efficiency of the electrode sheet 4 is high, but also the stacking efficiency of the electrode sheet 4 and other electrode sheets 4 is high, and therefore, the production efficiency of the laminated battery can be effectively improved.
The electrode sheet 4 provided with the folding guide portion 28 may be applied not only to the electrode assembly 201 adopting the z+u-shaped lamination mode, but also to laminated batteries in which the electrode sheet 4 needs to be folded but the folding modes are different, and in practice, any laminated battery in which the electrode sheet 4 is assembled after being folded may be used, the electrode sheet 4 provided with the folding guide portion 28 provided by the present application. In the foregoing electrode assembly 201 adopting the "z+u" lamination mode, when the electrode sheet 4 is provided with the folding guide portion 28, the production efficiency of the laminated battery can be more effectively improved, and the safety performance of the laminated battery is also more excellent.
The electrode sheet 4 provided with the folding guide 28 may be at least one of the first electrode sheet 1 and the second electrode sheet 2 of the electrode assembly 201, that is, only the first electrode sheet 1 or only the second electrode sheet 2 may be provided with the folding guide 28, or both the first electrode sheet 1 and the second electrode sheet 2 may be provided with the folding guide 28, for example, in some embodiments, both the positive electrode sheet 24 and the negative electrode sheet 14 may be provided with the folding guide 28, and in other embodiments, only the positive electrode sheet 24 may be provided with the folding guide 28, and the negative electrode sheet 14 may not be provided with the folding guide 28.
When the folding guide parts 28 are arranged on the first pole piece 1 and the second pole piece 2, the first pole piece 1 and the second pole piece 2 can be folded under the guidance of the folding guide parts 28, so that the folding efficiency is higher, and the production efficiency of the laminated battery is improved.
When only one of the first and second electrode sheets 1 and 2 is provided with the folding guide portions 28, the production efficiency of the laminated battery can be improved to some extent, and at the same time, in this case, the number of the folding guide portions 28 is relatively small, and there is no need to process as many folding guide portions 28, so that the structure of the electrode assembly 201 is simple, and the processing is convenient, that is, in this case, the production efficiency and the structural simplicity of the laminated battery can be considered.
In addition, the number of the folding guides 28 on the electrode sheet 4 is not limited, for example, in some embodiments, only one folding guide 28 is provided on the electrode sheet 4, in which case, the electrode sheet 4 may be folded once under the guiding action of the folding guides 28 to form the second electrode sheet 2 in the aforementioned U-shaped folded-in-half manner.
In the present application, the folding guide 28 may have various kinds of structures. For example, referring to fig. 25-32, in some embodiments, the folding guide 28 includes a score 281 or crease 282. The provided scores 281 or the folds 282 can effectively play a role in folding guide, so that the electrode plate 4 can be folded along the corresponding scores 281 or folds 282, folding is completed quickly, and deviation of folding positions is not easy to occur. It will be appreciated that score 281 is an engraved trace that is recessed downwardly from the engraved surface as a weakened portion having a certain depth. Crease 282 is a trace of the fold that is not depressed downwardly from the folded surface, and has no depth.
In addition, the shape of the folding guide 28 may be varied. For example, referring to fig. 25-32, in some embodiments, the fold guides 28 are of a continuous or intermittent type.
When the folding guide portion 28 is in a continuous line shape, the folding guide portion 28 has a simple structure and is convenient to process. Illustratively, the fold guide 28, which is a continuous line, is a continuous straight line or a continuous curve.
When the folding guide portion 28 is in a discontinuous line shape, the area occupied by the folding guide portion 28 is relatively small, which is beneficial to improving the structural strength of the electrode sheet 4 as much as possible while facilitating the folding of the electrode sheet 4. Illustratively, the fold guides 28 are in the form of broken lines, e.g., see fig. 28-31, and in some embodiments, the fold guides 28 are in the form of dotted lines or linear lines. The broken line is easier to process than other types of broken line, and in particular, the dotted broken line and the linear broken line are more convenient to process.
The folding guide 28 provided in each of the above embodiments may be parallel to the width direction of the electrode sheet 4 or inclined with respect to the width direction of the electrode sheet 4. It is understood that the width direction of the electrode sheet 4 refers to the extending direction of the shorter side of the surface of the electrode sheet 4 perpendicular to the thickness direction, also referred to as the lateral direction of the electrode sheet 4, which is perpendicular to the longitudinal direction of the electrode sheet 4. The longitudinal direction of the electrode sheet 4 is the extending direction of the longer side of the surface of the electrode sheet 4 perpendicular to the thickness direction. The width direction of the first pole piece 1 folded in the Z-shape is also the extending direction of the two edges of the first lamination 11 adjacent to the bending portion 25. The width direction of the aforementioned second pole piece 2 folded in U-shape is also the opposite arrangement direction of the two edges of the second lamination 21 adjacent to the folded portion 25.
Here, referring to fig. 25 to 31, when the folding guide 28 is parallel to the width direction of the electrode sheet 4, the folding guide 28 is easily processed.
Referring to fig. 32, when the folding guide portion 28 is inclined with respect to the width direction of the electrode sheet 4, the folding guide portion 28 has a deflection angle, and can guide the electrode sheet 4 to be folded in two in a deflection manner, so that two adjacent laminates obtained after folding are staggered in the width direction. When the deflected folding guide portion 28 is disposed on the second pole piece 2 that is the positive pole piece 24, the two second lamination pieces 21 of the positive pole piece 24 may be staggered in the width direction, so, on one hand, since the two second lamination pieces 21 are not completely aligned and attached, it is more convenient to insert the second pole piece 2 into the first pole piece 1, on the other hand, it is also convenient to control the relative positional relationship between the second pole piece 2 and the first pole piece 1 after inserting the second pole piece 2 into the first pole piece 1, so that the two second lamination pieces 21 of the positive pole piece 24 are far away from the discontinuous end of the negative pole piece 14 as far as possible and are near the continuous end of the negative pole piece 14 as far as possible, that is, the two second lamination pieces 21 of the positive pole piece 24 are near the bending portion 25 of the negative pole piece 14 as far as possible and far away from the open end of the negative pole piece 14, so that the positive pole piece 24 is not easy to exceed the negative pole piece 14 in the width direction, which is beneficial to preventing the problem of lithium precipitation caused by the positive pole piece 24 exceeding the negative pole piece 14 in the width direction, thereby further improving the working safety.
It was mentioned before that a membrane 3 is arranged between the first pole piece 1 and the second pole piece 2, the membrane 3 separating the first pole piece 1 and the second pole piece 2 to prevent a short circuit between the first pole piece 1 and the second pole piece 2. However, in actual operation, the separator 3 may be pierced by foreign substances such as edge burrs or falling edge dressings generated during the cutting of the electrode sheet 4, and dendrites grown during the charging, causing a short circuit. For example, during the charging process, lithium ions are extracted from the positive electrode plate 24 and enter the negative electrode plate 14, the negative electrode plate 14 expands after absorbing lithium ions, and meanwhile, the positive electrode plate 24 expands after extracting lithium ions, so that during the charging process, the membrane 3 between the positive electrode plate and the negative electrode plate is pressed due to the expansion of the positive electrode plate and the negative electrode plate, and in this case, foreign matters on the positive electrode plate and the negative electrode plate easily pierce the membrane, so that short circuit is caused, and safety accidents are caused.
To further enhance the safety performance, referring to fig. 33, in some embodiments, two diaphragms 3 located on opposite sides of the same second pole piece 2 in the thickness direction are folded and cover the edges of the second pole piece 2 where no tab 15 is located.
In the related art, the separator 3 is located only between the surfaces of the adjacent two electrode sheets 4 perpendicular to the thickness direction without wrapping the edges of the electrode sheets 4, and in this case, the foreign matter at the edges of the electrode sheets 4 easily causes a short circuit problem. In the embodiment of the application, the separator 3 wraps the edge of the second pole piece 2, so that the separator 3 can be used for blocking the edge foreign matters from conducting the anode and the cathode electrically, and the risk of short-circuit accidents caused by the edge foreign matters can be effectively reduced.
In addition, in the embodiment of the application, more than one diaphragm 3 wraps the edge of the second pole piece 2, but two diaphragms 3 on two sides of the thickness direction of the second pole piece 2 wrap the edge of the second pole piece 2, even if the foreign matter on the edge of the first pole piece 1 and/or the second pole piece 2 pierces one diaphragm 3 wrapped on the edge, the other diaphragm 3 wrapped on the edge is blocked, thereby preventing short circuit more reliably and improving the safety performance more effectively.
Meanwhile, the separator 3 is used for wrapping the edge of the electrode plate 4, and the separator 3 is of an original structure of the battery cell 20, and other structural components are not required to be additionally arranged for wrapping the edge of the electrode plate 4, so that the structure is simpler. More importantly, if other structural components are used to wrap the edge of the electrode sheet 4, the other structural components easily affect the normal transmission of lithium ions, so that the transmission of lithium ions in the wrapped area is prevented, and the overall capacity of the electrode assembly 201 and the battery cell 20 is lost. The separator 3 is used for wrapping the edge of the electrode plate 4, so that the corresponding problem can be effectively solved, and the separator 3 does not prevent lithium ion transmission, so that the loss of the whole capacity of the electrode assembly 201 and the battery cell 20 is avoided, and the risk of lithium accumulation is not increased.
In addition, in the application, the first pole piece 1 adopts a Z-shaped folding mode, and the second pole piece 2 adopts a U-shaped folding mode, so that compared with the situation that the diaphragm 3 wraps the edge of the first pole piece 1, the diaphragm 3 is utilized to wrap the edge of the second pole piece 2, and the method is simpler and more convenient.
Meanwhile, the edge of the second pole piece 2 wrapped by the two diaphragms 3 is the edge of the second pole piece 2, which is not provided with the pole lug 15, so that the normal pole lug output of the second pole piece 2 is not influenced.
Therefore, by folding and coating the edges of the second electrode sheet 2, which are not provided with the tabs 15, of the two diaphragms 3 positioned on the two opposite sides of the same second electrode sheet 2 in the thickness direction, the occurrence of short-circuit accidents caused by edge foreign matters can be prevented more reliably on the basis of not affecting the whole capacity exertion and not increasing the lithium precipitation risk on the basis of a simpler structure, so that the safety performance is improved more effectively.
When the two diaphragms 3 wrap the edges of the second pole piece 2, all edges of the second pole piece 2, which are not provided with the tab 15, can be wrapped, so that the edges of the second pole piece 2 except the edge where the tab 15 is located can be wrapped with the flanges 31 of the two diaphragms 3, and the full-closed wrapping of all free edges of each second lamination 21 is realized, thereby further enhancing the safety performance.
When the diaphragm 3 and the second pole piece 2 are combined, the diaphragm 3 can be compounded on the second pole piece 2 by adopting modes such as hot pressing or bonding so as to enhance the wrapping firmness. And the degree of lithium ion intercalation and deintercalation at the edge of the electrode plate 4 can be regulated and controlled through hot pressing or bonding process adjustment.
To facilitate folding of the second pole piece 2, in some embodiments, the separator 3 wraps the edge of the second pole piece 2 where the tab 15 is not located before the second pole piece 2 is folded.
Examples shown in fig. 3-33 are further described below.
For simplicity of description, it will be understood that in the following description, the upper, lower, left and right will be defined based on the upper, lower, left and right of fig. 5, wherein the upper, lower, left and right of fig. 5 coincides with the upper, lower, left and right of fig. 14, and conforms to the orientation and positional relationship when the battery cell 20 and the battery 10 are normally disposed on the vehicle, wherein the upper is the direction opposite to the direction of gravity, and the lower is the same direction as the direction of gravity.
In addition, in order to clearly show the relationship between the first pole piece 1 and the second pole piece 2, the separator 3 is not shown in some of the drawings, for example, fig. 10 to 12, fig. 17 to 18, and fig. 23 to 24.
First, a first embodiment shown in fig. 3-13 will be described.
In this first embodiment, as shown in fig. 3-13, the battery cells 20 are square laminated cells and transmit electrical energy outwardly from opposite sides.
In this first embodiment, as shown in fig. 3 to 7, the casing 202 of the battery cell 20 has a square shape, and the left and right ends of the casing 203 are respectively provided with one end cap 204, and the two end caps 204 are detachably connected to the left and right ends of the casing 203, so that a closed space for accommodating the electrode assembly 201, the electrolyte, and the like is formed inside the casing 202.
Electrode terminals 206 are provided on both end caps 204 such that the two electrode terminals 206 of the battery cell 20 are located at the left and right sides of the case 202. Specifically, as shown in fig. 5, the negative electrode terminal 20a is provided on the left end cap 204, and the positive electrode terminal 20b is provided on the right end cap 204.
In order to achieve electrical connection with the two electrode terminals 206 on the left and right sides, as shown in fig. 5, in this embodiment, the tabs 15 of the electrode assembly 201 are disposed on the left and right sides of the electrode assembly 201. Specifically, as can be seen from fig. 5-6, negative electrode tab 13 is disposed on the left side of electrode assembly 201 and is electrically connected to negative electrode terminal 20a on the left side via adaptor 205 on the left side; as can be seen from fig. 5 and 7, the positive electrode tab 23 is provided on the right side of the electrode assembly 201, and is electrically connected to the positive electrode terminal 20b on the right side via the adapter 205 on the right side. In this manner, the electric power generated from the electrode assembly 201 may be transmitted from opposite sides in the left-right direction.
Fig. 5-13 illustrate the structure and lamination process of the electrode assembly 201 in this embodiment.
As shown in fig. 5 to 13, in this embodiment, the electrode assembly 201 includes a first electrode sheet 1, a second electrode sheet 2, and a separator 3. The first electrode sheet 1, the second electrode sheet 2 and the separator 3 are alternately laminated together in a lamination manner to form an electrode assembly 201, and the electrode assembly 201 at this time is also commonly referred to as a battery cell.
As can be seen from fig. 5-13, in this embodiment, the first pole piece 1 and the second pole piece 2 are a negative pole piece 14 and a positive pole piece 24, respectively. In this case, the active material 29 coated on the surface of the first pole piece 1 is a positive active material, for example, one or more of lithium cobaltate (LiCoO 2), lithium manganate, lithium iron phosphate, nickel cobalt manganese metal oxide (NCM), the current collector of the first pole piece 1 for carrying the active material 29 is a positive current collector such as aluminum foil, and the tab 15 of the first pole piece 1 is a negative tab 13; meanwhile, the active material 29 coated on the surface of the second pole piece 2 is a negative active material such as graphite, the current collector of the second pole piece 2 for carrying the active material 29 is a negative current collector such as copper foil, and the tab 15 of the second pole piece 2 is a positive tab 23.
In addition, as shown in fig. 5 to 13, in this embodiment, the first pole piece 1 is folded in a Z-shape, the second pole piece 2 is folded in a U-shape, and the folding direction (i.e., the first direction X) of the first pole piece 1 is along the up-down direction, and the folding direction (i.e., the second direction Y) of the second pole piece 2 is along the left-right direction, so that the first direction X and the second direction Y are orthogonal, and an orthogonal "z+u" lamination manner is formed. After the first pole piece 1 is folded in a Z-shape, a plurality of first laminations 11 connected by the bent portions 25 are formed. After the second pole piece 2 is folded in a U shape, two second lamination sheets 21 connected by a bending part 25 are formed. The plurality of folded second pole pieces 2 are inserted into the first pole piece 1 such that each first lamination 11 and each second lamination 21 are alternately laminated in sequence along the third direction Z. The third direction Z is along the thickness direction of each lamination, in particular in this embodiment, perpendicular to the first direction X and the second direction Y.
As can be seen from fig. 5 to 13, in this exemplary embodiment, the first pole piece 1, which is embodied as a negative pole piece 14, is formed by separating tabs, i.e., one tab 15 is separated from each first lamination 11 of the first pole piece 1, and only one tab 15 is provided in two adjacent first laminations 11. In addition, as shown in fig. 5-6 and fig. 10-11, in this embodiment, the first lamination 11 provided with the tab 15 only has a tab on one side in the second direction Y, so that the first pole piece 1 only has a tab on one side in the second direction Y, and at this time, the tab-out mode of the first pole piece 1 is a single-side tab-out mode. Specifically, as shown in fig. 5-6, the tabs 15 of the first pole piece 1 are all located at the left end of the first pole piece 1, and precisely, each tab 15 of the first pole piece 1 is located at the left edge of each first lamination 11. As can be seen in connection with fig. 6 and 10, in this embodiment, the left edge of the first lamination 11 is the edge of the first lamination 11 adjacent to the bent portion 25 of the first pole piece 1, and it can be seen that in this embodiment, the tab 15 of the first pole piece 1 is located at the edge of the first pole piece 1 adjacent to the bent portion 25. Since the first electrode tab 1 of this embodiment is the negative electrode tab 14, the tab 15 of the first electrode tab 1 is the negative electrode tab 13, and the tab 15 of the first electrode tab 1 is disposed on the left side, so that the negative electrode tab 13 is electrically connected to the negative electrode terminal 20a located on the left side of the battery cell 20.
With continued reference to fig. 5-13, in this embodiment, the second pole piece 2, which is configured as a positive pole piece 24, has the tab 15 on only one of its two second lamination pieces 21, and the tab 15 is located at the end of the second lamination piece 21 remote from the bent portion 25 of the second pole piece 2, in which case, since the two second lamination pieces 21 are connected by the bent portion 25, electric energy can be smoothly transferred to the outside even if the second pole piece 2 is provided with one tab 15. Also, as can be seen in fig. 5-7, in this embodiment, the bent portions 25 of all the second pole pieces 2 face to the left and wrap the left edge of the first lamination 11 of the first pole piece 1 where the tab 15 is not disposed, and at the same time, the tabs 15 of all the second pole pieces 2 are located at the right end of the second pole pieces 2, that is, the tab 15 of each second lamination 21 is located at the right edge of the corresponding second lamination 21. Since the second pole piece 2 of this embodiment is the positive electrode piece 24, the tab 15 of the second pole piece 2 is the positive electrode tab 23, and the tab 15 of the second pole piece 2 is disposed on the right side, so that the positive electrode tab 23 is electrically connected to the negative electrode terminal 20b located on the right side.
In this embodiment, the first pole piece 1 adopts a single-side spaced tab-out mode, the second pole piece 2 adopts a single-side single-piece tab-out mode, and the tab-out directions of the first pole piece 1 and the second pole piece 2 are opposite and are positioned at two opposite sides of the second direction Y and respectively extend towards the left side and the right side, so that the positive and negative tabs do not interfere with each other, and can be respectively and conveniently electrically connected with the positive and negative terminals at the left side and the right side, thereby meeting the design requirements of the battery cells with the electrode terminals arranged at the left side and the right side. Of course, referring to fig. 7, in this embodiment, two second laminations 21 of the second pole piece 2 may be provided with tabs 15, and since in this embodiment, the first pole piece 1 does not protrude from one side of the tab of the second pole piece 2, even if two second laminations 21 of the second pole piece 2 protrude from the tab, interference with the tab of the first pole piece 1 will not occur. When the two second laminations 21 of the second pole piece 2 are provided with the tabs 15, the conductivity efficiency is higher and the conductivity reliability is stronger.
Also, as can be seen from fig. 6 and fig. 11 to 12, in this embodiment, the bent portion 25 of the second pole piece 2 and the portions of the flat sections located near both ends of the bent portion 25 are configured as inert areas 26, and the surface of the inert areas 26 facing the first pole piece 1 is not coated with an active material 29, and is insulated with an insulating material 27 such as a ceramic coating, a glue or a paste.
In this embodiment, the second electrode sheet 2 is the positive electrode sheet 24, so the bending portion 25 of the second electrode sheet 2 wrapping the first electrode sheet 1 and the area nearby the bending portion are configured as the inactive area 26, so that lithium ions are not generated in the corresponding inactive area 26, and the portion of the first lamination 11 extending into the corresponding inactive area 26 becomes the portion of the negative electrode sheet 14 beyond the positive electrode sheet 24, i.e., the portion of the negative electrode sheet beyond the positive electrode sheet, so that the problem of lithium precipitation caused by the bending portion 25 of the second electrode sheet 2 beyond the first electrode sheet 1 can be fundamentally solved, and the working safety is effectively improved. And, only need the area size of control inertia district 26, can effectively control the area size of corresponding negative pole piece surpass the part of positive pole piece, it is simple and convenient, can ingenious solution negative pole piece surpass the problem that the partial area size of positive pole piece is difficult to control.
And the insulating material 27 is further arranged in the inert region 26, so that the insulativity between the positive and negative plates can be enhanced, the short circuit between the positive and negative plates can be prevented more reliably, and the safety performance can be improved more effectively.
As shown in fig. 10 to 11, in this embodiment, when the electrode assembly 201 is assembled, only the first electrode sheet 1 is folded back and forth along the first direction X, and the plurality of second electrode sheets 2 are folded in half, and then the folded plurality of second electrode sheets 2 are together, and from the side of the first electrode sheet 1 adjacent to the bending portion 25 and not provided with the tab 15, the orthogonal lamination process of the first electrode sheet 1 and the second electrode sheet 2 can be completed by inserting the positions of the first laminations 11 of the respective non-tab 15 of the first electrode sheet 1. Because the lamination process is simple and convenient, and the earlier cutting process is also simpler, the production efficiency of the electrode assembly 201, the battery cell 20, the battery 10 and the power utilization device 100 can be effectively improved, and the lamination process has important significance for popularization and application of the lamination battery.
After each second pole piece 2 is folded in half, the two second lamination pieces 21 are not completely attached, but are opened by a certain angle, so that the second pole piece 2 is conveniently inserted into the first pole piece 1.
Next, a second embodiment shown in fig. 14-22 will be described. For simplicity of description, the differences between the second embodiment and the first embodiment will be mainly described, and other non-described parts will be understood with reference to the first embodiment example.
In this second embodiment, as shown in fig. 14-22, the battery cell 20 is still a square laminated battery, and the electrode assembly 201 is still in an orthogonal "z+u" laminated mode, but it is no longer in a mode of left and right side tab and electrode terminal, but in a mode of top tab and electrode terminal.
In particular, as can be seen in fig. 14-15, in this embodiment, the housing 202 has only one end cap 204 removably attached, and the end cap 204 is removably attached to the top end of the housing 203. Two electrode terminals 206, namely, a negative electrode terminal 20a and a positive electrode terminal 20b, are provided on the top end cap 204 and protrude upward from the top end cap 204 to the outside of the case 202. Specifically, the negative terminal 20a is located in the left portion of the top end cap 204, and the positive terminal 20b is located in the right portion of the top end cap 204.
In this embodiment, as shown in fig. 16 to 20, the folding direction of the first pole piece 1 (i.e., the first direction X) of the Z-fold method is along the left-right direction, and the folding direction of the second pole piece 2 (i.e., the second direction Y) of the U-fold method is upward, so that the first direction X and the second direction Y are orthogonal to each other, forming an orthogonal "z+u" lamination method. The plurality of first laminations 11 formed by folding the first pole piece 1 and the plurality of second laminations 21 formed by folding all the second pole pieces 2 are alternately stacked in sequence along the third direction Z. The third direction Z is along the thickness direction of each lamination and, in this embodiment, perpendicular to the first direction X and the second direction Y.
As can be seen from fig. 16 to 20, in this embodiment, the first pole piece 1 is configured as a negative pole piece 14, which is not separated by a tab on one side, but is continuously separated by a tab on one side, specifically, each first lamination 11 of the first pole piece 1 is provided with one tab 15, and all the tabs 15 of the first pole piece 1 are located at the top edge of the first lamination 11 where each is located. Since the first electrode tab 1 of this embodiment is the negative electrode tab 14, the tab 15 of the first electrode tab 1 is the negative electrode tab 13, and the tab 15 of the first electrode tab 1 is disposed at the top edge of the first electrode tab 1, so that the negative electrode tab 13 is electrically connected to the negative electrode terminal 20a located at the top of the battery cell 20. As shown in fig. 17, in this embodiment, the top edge of the first lamination 11 is the edge of the first lamination 11 adjacent to the bent portion 25 of the first pole piece 1, and it can be seen that in this embodiment, the tab 15 of the first pole piece 1 is located at the edge of the first pole piece 1 adjacent to the bent portion 25.
With continued reference to fig. 16-20, in this embodiment, the second pole piece 2 is configured as a positive pole piece 24 that is no longer in a single-sided, single-tab manner, but rather in a single-sided, double-tab manner, that is, both second laminations 21 of the second pole piece 2 are provided with tabs 15, and the tabs 15 are located at the ends of the second laminations 21 that are distal from the bent portions 25 of the second pole piece 2. Since the folding direction of the second pole piece 2 is upward in this embodiment, and therefore the bending portion 25 of the second pole piece 2 is downward, the end portion of the second pole piece 2 away from the bending portion 25 of the second pole piece 2 is the top edge of the second lamination 21, and therefore all the tabs 15 of the second pole piece 2 are located at the top edge of the second pole piece 2 in this embodiment. Since the second pole piece 2 of this embodiment is the positive pole piece 24, the tab 15 of the second pole piece 2 is the positive pole tab 23, and the tab 15 of the second pole piece 2 is disposed at the top edge of the second pole piece 2, so that the positive pole tab 23 is electrically connected with the negative terminal 20b located at the top of the battery cell 20.
Since the tabs 15 of the first and second pole pieces 1, 2 are both located at the top in this embodiment, the tabs 15 of the first and second pole pieces 1, 2 are located on the same side in the first direction Y. In this case, in order to prevent the positive and negative tabs from interfering with each other, as shown in fig. 17, in this embodiment, the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 are arranged offset in the folding direction (i.e., the first direction X) of the first pole piece 1. Specifically, as shown in fig. 17, in this embodiment, in any two adjacent bent portions 25 of the first pole piece 1, only the edge near one bent portion 25 is provided with the tab 15, and the edge near the other bent portion 25 is not provided with the tab 15. All the tabs 15 of the first pole piece 1 are arranged close to the bent portion 25 of the first pole piece 1, and all the tabs 15 of the second pole piece 2 are arranged far from the bent portion 25 of the first pole piece 1. In this way, the tab 15 of the first pole piece 1 and the tab 15 of the second pole piece 2 are completely staggered in the first direction X and do not overlap each other, so that mutual interference of the positive and negative tabs can be effectively prevented in the case that the positive and negative tabs are arranged on the same side.
Because the positive and negative lugs are staggered in the first direction X, and the first direction X is along the left-right direction, as shown in fig. 15-16, the positive and negative lugs can be staggered in the left-right direction, all the negative lugs 13 are positioned on the left side of the top, all the positive lugs 23 are positioned on the right side of the top, the positive and negative lugs are conveniently and respectively electrically connected with the negative terminal 20a on the left side of the top and the positive terminal 20b on the right side of the top, and the design requirement of the battery cell of the top outlet electrode terminal is met.
As previously described, in this embodiment, all the bent portions 25 of the second electrode tab 2 are downward, in which case, in order to improve the heat dissipation performance of the electrode assembly 201 and the battery cell 20, referring to fig. 22, in this embodiment, all the bent portions 25 of the second electrode tab 2 are in contact with the inner surface of the bottom wall of the case 202. Since the second pole piece 2 of this embodiment is vertically arranged, the orientation of the bent portion 25 of the second pole piece 2 is the same as the gravity direction, and precisely, the surface of the bent portion 25 of the second pole piece 2 away from the first pole piece 1 is oriented in the gravity direction, therefore, after the electrode assembly 201 is installed in the case 202, the second pole piece 2 can naturally sink under the action of gravity, and natural contact between the bent portion 25 of the second pole piece 2 and the inner surface of the bottom wall of the case 202 is achieved. After the bending part 25 of the second pole piece 2 contacts with the bottom wall of the housing 202, the bending part 25 can be deformed under pressure, so that the surface of the bending part 25 facing away from the first pole piece 1 is changed from an arc shape into a substantially rectangular shape, thereby facilitating the bending part 25 of the second pole piece 2 to contact with the bottom wall of the housing 202 more fully.
Because the bending parts 25 of the second pole pieces 2 and the housing 202 are both made of metal materials, the heat conducting performance is good, and the contact area between the bending parts 25 of all the second pole pieces 2 of the electrode assembly 201 and the bottom wall of the housing 202 is large, and the contact area can occupy approximately half of the inner surface area of the bottom wall of the housing 202, in this embodiment, the electrode assembly 201 and the housing 202 can efficiently and fully conduct contact heat transfer, so that the heat generated by the electrode assembly 201 is rapidly dissipated to the outside of the housing 202, and the working safety is improved.
In this second embodiment, the second electrode sheet 2 is also provided with an inactive area 26 including a bent portion 25, and the inactive area 26 is also provided with an insulating material 27 to improve safety by further insulating and preventing lithium precipitation, and effectively controlling the area of the portion of the negative electrode sheet beyond the positive electrode sheet. Please refer to the related description in the first embodiment for understanding, and will not be repeated here.
A third embodiment shown in fig. 23-24 is described next.
As shown in fig. 23 to 24, in this third embodiment, the electrode assembly 201 no longer employs an orthogonal "z+u" lamination, but employs a parallel "z+u" lamination, that is, the folding direction (first direction X) of the first pole piece 1 folded in Z is parallel to the folding direction (second direction Y) of the second pole piece 2 folded in U. After lamination, the lamination direction (i.e., the third direction Z) of each lamination is perpendicular to the first direction X, the second direction Y, and the longitudinal direction of the first pole piece 1. At this time, the longitudinal direction of the first pole piece 1 is perpendicular to the second direction Y (first direction X) and the third direction Z.
In addition, as shown in fig. 23 to 24, in this embodiment, the first pole piece 1 and the second pole piece 2 are the negative pole piece 14 and the positive pole piece 24, respectively, the bending portion 25 of the second pole piece 2 wraps the bending portion 25 of the first pole piece 1, and at the same time, any two adjacent second pole pieces 2 are located at two opposite sides of the first pole piece 1 along the first direction X, so as to wrap different bending portions 25 of the first pole piece 1. Wherein, two second pole pieces 2 are a pair, wrap up two consecutive kinks 25 of the first pole piece 1, and between two adjacent pairs of second pole pieces 2, then interval one kink 25 of the first pole piece 1, namely after two consecutive kinks 25 of the first pole piece 1 are wrapped, have one kink 25 not wrapped, afterwards, two consecutive kinks 25 are wrapped again, then, another kink 25 is not wrapped, so circulate. It will be appreciated that in fig. 24, only one pair of second pole pieces 2 is subjected to explosion treatment, and that the other pairs of second pole pieces 2 are shown in a state of being coated on the first pole piece 1.
Meanwhile, as shown in fig. 23 to 24, in this embodiment, the tabs 15 of the first pole piece 1 and the second pole piece 2 are located at the edges adjacent to the bending portion 25, and the tab outlet directions are the same, and are located at the same side of the first pole piece 1 in the longitudinal direction (or the length direction), so as to meet the design requirements of tab outlet and electrode terminal at the same side of the battery cell. Wherein, two second lamination sheets 21 of the second pole piece 2 are respectively provided with a pole lug 15; neither of the first laminations 11 of the first pole piece 1 has a tab 15. All tabs 15 of the first pole piece 1 and all tabs 15 of the second pole piece 2 are arranged in a staggered manner in the first direction X so as to prevent mutual interference of the positive and negative tabs. Specifically, in this embodiment, the tabs 15 of the second pole piece 2 are all located at the end of the edge adjacent to the bending portion 25, which is far away from the bending portion 25, and all the tabs 15 of the first pole piece 1 are all located at the end of the edge connected to the bending portion 25, which is close to the bending portion 25, because in this embodiment, the bending portion 25 of the second pole piece 2 wraps the bending portion of the first pole piece 1, so after this, all the tabs 15 of the first pole piece 1 and all the tabs 15 of the second pole piece 2 can be arranged in a staggered manner in the first direction X.
It can be seen that fig. 23-24 illustrate a parallel "z+u" lamination, taking as an example the case where the first pole piece 1 and the second pole piece 2 are tab-like on the same side. However, it should be understood that in the manner of lamination using parallel "z+u" shapes, the tab directions of the first pole piece 1 and the second pole piece 2 may be opposite, and may be located on opposite sides of the longitudinal direction of the first pole piece 1.
Fig. 25 to 32 exemplarily show the structure of the second pole piece 2 in the present application.
The second pole piece 2 is foldable, and the state before and after folding is called an unfolded state and a folded state, respectively. In the finished battery cell 20, the second pole piece 2 is in a folded state, the corresponding folded state being shown in fig. 6-24. The structure of the second pole piece 2 in the unfolded state, i.e. the second pole piece 2 which is not folded, is shown in fig. 25-32.
Wherein fig. 25 shows a first example of a second pole piece 2. As shown in fig. 25, in this example, the second electrode sheet 2 is provided with an inactive region 26, and the active material 29 is not provided on the surface of the inactive region 26, so that the inactive region 26 is actually a current collector portion not covered with the active material 29. The surface of the inert region 26 is provided with an insulating substance 27, which can improve the insulation between the positive and negative plates.
Also, as shown in fig. 25, in this example, a folding guide 28 is provided on the second pole piece 2, which folding guide 28 is provided in the inactive area 26 of the second pole piece 2, and in particular a crease 282. The crease 282 is a linear crease, and extends from one edge of the second pole piece 2 in the width direction to the other edge of the second pole piece 2 in the width direction, and the extending direction is parallel to the width direction of the second pole piece 2. Based on this, when needed, only need carry out the fifty percent discount with second pole piece 2 along crease 282, can accomplish the U-shaped fifty percent discount of second pole piece 2, compare with the condition that does not set up folding guide 28 on the second pole piece 2, folding process is simpler and more convenient. After folding, the two second laminates 21 of the second pole piece 2 are aligned in the width direction edge-wise without deflection. Meanwhile, since the crease 282 is arranged in the inert area 26, after folding, the inert area 26 comprises the bending part 25 for connecting the two second laminations 21, so that the area of the part of the negative electrode plate exceeding the positive electrode plate is conveniently controlled by the inert area 26, and the safety is improved.
Fig. 26-27 illustrate a second example of a second pole piece. As shown in fig. 26, in this example, the folding guide 28 is still provided in the inactive area 26 of the second pole piece 2, but unlike the first example shown in fig. 25, the folding guide 28 is no longer a crease 282 but is a score 281, and in this example, the score 281 is a continuous straight line score extending from one edge in the width direction of the second pole piece 2 to the other edge in the width direction of the second pole piece 2, and the extending direction is parallel to the width direction of the second pole piece 2. Therefore, the U-shaped folding of the second pole piece 2 can be completed simply and conveniently by folding the second pole piece 2 along the notch 281. Compared with the crease 282, the notch 281 has a certain depth in the thickness direction of the second pole piece 2, so that the folding is more conveniently guided, the second pole piece 2 can be more accurately guided to be folded along the notch 281, deviation is not easy to occur, meanwhile, the notch 281 can be directly processed in the production process of the second pole piece 2, the notch 281 is not required to be obtained by pre-folding after the second pole piece 2 is processed, and the processing process of the notch 281 is also more convenient.
Fig. 28-29 illustrate a third example of a second pole piece. As shown in fig. 28-29, in this example, the fold guides 28 within the inactive region 26 of the second pole piece 2 remain as scores 281, and the scores 281 remain extending along the width direction of the second pole piece 2, but in this example, the scores 281 are no longer continuous straight scores, but become dotted-line type scores, which are composed of a plurality of small holes spaced side by side along the width direction of the second pole piece 2. The small holes are through holes or blind holes. Based on this, the fold-over folding of the second pole piece 2 can also be conveniently accomplished.
Fig. 30-31 illustrate a fourth example of a second pole piece. As shown in fig. 30 to 31, in this example, the dashed-line type score provided in the inactive area 26 of the second pole piece 2 is still parallel to the width direction of the second pole piece 2, but unlike the third example shown in fig. 28 to 29, in this example, the dashed-line type score 281 is no longer a dotted-line type score, but becomes a linear dashed-line type score. Based on this, the fold-over folding of the second pole piece 2 can also be conveniently accomplished.
Fig. 32 shows a fifth example of the second pole piece. As shown in fig. 32, this example is mainly different from the examples shown in the foregoing fig. 25 to 31 in that the folding guides 28 are no longer parallel to the width direction of the second pole piece 2, but have an angle with the width direction of the second pole piece 2, that is, in this example, the folding guides 28 are deflected with respect to the width direction of the second pole piece 2. Thus, after being folded, the two second lamination sheets 21 of the second pole piece 2 are not aligned in the width direction any more, but deflect, so that the second pole piece 2 can be conveniently unfolded for a certain angle after being folded, and is conveniently inserted into the first pole piece 1, and after the second pole piece 2 is assembled onto the first pole piece 1, each second lamination sheet 21 does not exceed the first lamination sheet 11, and the lithium separation risk is reduced.
Note that, although the folding guide 28 shown in fig. 32 is a continuous linear type, the folding guide 28 may be formed in other shapes such as a dot or a linear virtual line, and the folding guide 28 may be formed by a crease 282 or a score 281.
As can be seen from fig. 25-32, in these several examples, the two ends of the second pole piece 2 are provided with the tabs 15, that is, the two second laminations 21 of the second pole piece 2 are provided with the tabs 15, and the second pole piece 2 adopts a single-sided double-tab mode, however, it should be understood that this does not limit the present application, and when only one end of the second pole piece 2 is provided with the tabs 15 and only one of the two second laminations 21 is provided with the tabs 15, the second pole piece 2 may be provided with the various folding guides 28.
Fig. 33 is an example in which the second electrode sheet 2 is surrounded by two sheets of the separator 3.
As shown in fig. 33, in this embodiment, two diaphragms 3 located on opposite sides of the same second pole piece 2 in the thickness direction are folded to form flanges 31, and the flanges 31 of the two diaphragms 3 cover all edges of the second pole piece 2 where no tab 15 is provided, so that all edges of the second pole piece 2 where no tab 15 is provided are covered by the flanges 31 of the two diaphragms 3. The flange 31 encloses a region of 1-20mm near the edge of the second pole piece 2. In the cladding process, the diaphragm 3 positioned on the first side of the second pole piece 2 can be folded, so that the turned-over flange 31 bypasses the surface of the second pole piece 2 corresponding to the corresponding edge, reaches the second side of the second pole piece 2, covers the area of the surface of the second side, which is adjacent to the corresponding edge and is 1-20mm, and forms an inner-layer wrapping edge; and then, the diaphragm 3 positioned on the second side of the second pole piece 2 is turned over, so that the turned over flange 31 bypasses the surface of the second pole piece 2 corresponding to the corresponding edge, reaches the first side of the second pole piece 2, covers the area of the first side surface, which is adjacent to the corresponding edge and is 1-20mm, and forms an outer-layer wrapping edge which is wrapped outside the inner-layer wrapping edge, and thus, the diaphragm double-layer wrapping edge is obtained. After each layer of diaphragm edge is wrapped, the diaphragm edge wrapping area can be fixed by adopting modes such as hot pressing or adhesive bonding. And, the corresponding taping process may be completed before the second pole piece 2 is folded in half or sliced.
The arranged diaphragm double-layer edge wrapping can more reliably prevent short-circuit accidents caused by edge foreign matters on the basis of not affecting the whole capacity exertion and not increasing the lithium separation risk. Therefore, the safety performance can be effectively improved as compared with the case where the separator 3 does not edge-wrap the second pole piece 2.
Referring to fig. 34 to 35, the present application also provides a method of manufacturing an electrode sheet and a method of manufacturing an electrode assembly, based on the foregoing embodiments.
Fig. 34 illustrates an example of a method for manufacturing the electrode sheet. Referring to fig. 34, the manufacturing method of the electrode sheet 4 includes:
s10, arranging a folding guide part 28 on the electrode slice 4;
s20, the electrode sheet 4 is folded under the guide of the folding guide 28.
The electrode sheet 4 manufactured by the above method is folded, so that the electrode sheet 4 can be assembled again after being folded to form the electrode assembly 201, and therefore, the production efficiency of the laminated battery can be effectively improved compared with the single-sheet stacking method in the related art. In addition, the electrode sheet 4 can be folded more conveniently under the guidance of the folding guide part 28 in the folding process, and the folding efficiency is higher, so that the production efficiency of the laminated battery can be further improved.
Fig. 35 exemplarily shows a manufacturing method of the electrode assembly. Referring to fig. 35, the manufacturing method of the electrode assembly 201 includes:
s100, providing a first pole piece 1, and reciprocally folding the first pole piece 1 along a first direction X, so that the first pole piece 1 comprises a plurality of first laminations 11 which are sequentially connected and stacked;
s200, providing a second pole piece 2 with polarity opposite to that of the first pole piece 1, and performing single folding on the second pole piece 2 along a second direction Y, so that the second pole piece 2 comprises two second lamination sheets 21 connected with each other, and the second direction Y is perpendicular or parallel to the first direction X; and
s300, inserting the second pole piece 2 into the first pole piece 1, and stacking the second lamination 21 and the first lamination 11 alternately in sequence.
The electrode assembly 201 manufactured by the method has high efficiency, and can effectively improve the production efficiency of the electrode assembly, the battery cell, the battery and the power utilization device.
The sequence of steps S100 and S200 is not limited, and step S100 may be before step S200 may be after step S200, step S200 may be before step S100 may be after step S200, or step S100 and step S200 may be performed simultaneously.
In some embodiments, before the second sheet 2 is folded in the second direction Y once, two diaphragms 3 are further disposed on opposite sides of the second sheet 2 in the thickness direction, and the two diaphragms 3 disposed on opposite sides of the same second sheet 2 in the thickness direction are folded and cover the edges of the second sheet 2 where the tabs 15 are not disposed.
Before the second pole piece 2 is folded, the two diaphragms 3 are utilized to carry out double-layer edge wrapping on the edge of the second pole piece 2, where the pole lug 15 is not arranged, so that the safety performance of the electrode assembly can be effectively improved under the condition that the second pole piece 2 is convenient to fold.
In the manufacturing method of the electrode assembly 201 of each of the above embodiments, the first and/or second electrode tabs 1 and 2 may be folded under the guide of the folding guide 28. For example, in some embodiments, when the second pole piece 2 is folded in step S200, the second pole piece 2 is folded along the folding guide portion 28 on the second pole piece 2, so that the second pole piece 2 is folded in half along the folding guide portion 28 to form the U-shaped folded second pole piece 2.
Features of the above-mentioned various embodiments and the above-mentioned various embodiments of the present application may be mutually referred to, and those skilled in the art may flexibly combine technical features of different embodiments to form further embodiments as the structure allows.
The principles and embodiments of the present application have been described herein with reference to specific examples, which are intended to be merely illustrative of the methods of the present application and their core ideas. It should be noted that it will be apparent to those skilled in the art that various modifications and adaptations of the application can be made without departing from the principles of the application and these modifications and adaptations are intended to be within the scope of the application as defined in the following claims.

Claims (27)

  1. An electrode sheet (4), characterized in that a folding guide part (28) is arranged on the electrode sheet (4), and the folding guide part (28) guides the electrode sheet (4) to fold.
  2. Electrode sheet (4) according to claim 1, characterized in that the folding guide (28) comprises a crease (282) or a score (281).
  3. Electrode sheet (4) according to claim 2, characterized in that the folding guides (28) are of continuous or intermittent type.
  4. An electrode sheet (4) according to claim 3, characterized in that the folding guides (28) are in the form of broken lines.
  5. Electrode sheet (4) according to claim 4, characterized in that the folding guides (28) are dotted or short-line shaped.
  6. Electrode sheet (4) according to any of claims 1-5, characterized in that the folding guides (28) are parallel to the width direction of the electrode sheet (4) or that the folding guides (28) are inclined with respect to the width direction of the electrode sheet (4).
  7. Electrode sheet (4) according to any of claims 1-6, characterized in that only one of the folding guides (28) is provided on the electrode sheet (4) for guiding the electrode sheet (4) to a single fold.
  8. An electrode assembly (201), characterized by comprising:
    a first pole piece (1); and
    a second pole piece (2) of opposite polarity to the first pole piece (1) and stacked with the first pole piece (1);
    wherein at least one of the first pole piece (1) and the second pole piece (2) is an electrode piece (4) according to any one of claims 1-8.
  9. The electrode assembly (201) according to claim 8, wherein the first pole piece (1) is reciprocally folded in a first direction (X) such that the first pole piece (1) comprises a plurality of first laminations (11) connected and stacked in sequence, and the second pole piece (2) is singly folded in a second direction (Y) such that the second pole piece (2) comprises two second laminations (21) connected to each other, the second direction (Y) being perpendicular or parallel to the first direction (X), the second laminations (21) being alternately stacked in sequence with the first laminations (11).
  10. The electrode assembly (201) of claim 9, wherein the tab (15) of the first pole piece (1) is located at an edge other than the bent portion of the first pole piece (1); and/or the lug (15) of the second pole piece (2) is positioned at the edge outside the bending part of the second pole piece (2).
  11. The electrode assembly (201) according to claim 10, wherein the second direction (Y) is perpendicular to the first direction (X), the tab (15) of the first pole piece (1) being located at an edge of the first pole piece (1) adjacent to the bend (25), the tab (15) of the second pole piece (2) being located at an end of the second pole piece (2) remote from the bend (25); or, the second direction (Y) is parallel to the first direction (X), the tab (15) of the first pole piece (1) is located at an edge of the first pole piece (1) adjacent to the bending portion (25), and the tab (15) of the second pole piece (2) is located at an edge of the second pole piece (2) adjacent to the bending portion (25).
  12. The electrode assembly (201) according to claim 11, wherein the second direction (Y) is perpendicular to the first direction (X), only one of the first laminations (11) has a tab (15) and the bent portion (25) of the second lamination (2) encases the first lamination (11) where no tab (15) is provided.
  13. The electrode assembly (201) according to any of claims 9-12, wherein at least one of the two second laminations (21) of the second pole piece (2) has a tab (15).
  14. The electrode assembly (201) according to any of claims 9-13, wherein the second electrode sheet (2) has an inactive zone (26), the inactive zone (26) comprising a bend (25) of the second electrode sheet (2), the inactive zone (26) being uncoated with active material (29).
  15. The electrode assembly (201) according to claim 14, characterized in that the surface of the inert zone (26) of the second pole piece (2) facing the first pole piece (1) is provided with an insulating substance (27).
  16. The electrode assembly (201) according to any one of claims 8-13, wherein the tab (15) of the first pole piece (1) and the tab (15) of the second pole piece (2) are located on the same side or on opposite sides.
  17. The electrode assembly (201) according to claim 16, wherein the tab (15) of the first pole piece (1) and the tab (15) of the second pole piece (2) are located on the same side, and the tab (15) of the first pole piece (1) and the tab (15) of the second pole piece (2) are arranged offset in the folding direction of the first pole piece (1).
  18. The electrode assembly (201) according to any one of claims 8 to 17, wherein the electrode assembly (201) comprises a separator (3), the separator (3) separates the first pole piece (1) and the second pole piece (2), and two separator (3) located on two opposite sides of the same second pole piece (2) in the thickness direction are folded and cover the edge of the second pole piece (2) where no tab (15) is located.
  19. The electrode assembly (201) according to any of claims 8-18, wherein the first electrode sheet (1) is a negative electrode sheet (14) and the second electrode sheet (2) is a positive electrode sheet (24).
  20. A battery cell (20) comprising a housing (202), further comprising an electrode assembly (201) according to any one of claims 8-19, the electrode assembly (201) being disposed within the housing (202).
  21. The battery cell (20) of claim 20, wherein the tab (15) of the second pole piece (2) is located at an edge other than the bent portion (25) of the second pole piece (2), and wherein the bent portion (25) of the second pole piece (2) is in contact with the inner wall of the outer case (202).
  22. The battery cell (20) of claim 21, wherein a surface of the bent portion (25) of the second pole piece (2) remote from the first pole piece (1) is oriented in a gravitational direction.
  23. A battery (10) comprising a packaging case (30), further comprising a battery cell (20) according to any one of claims 20-22, said battery cell (20) being disposed in said packaging case (30).
  24. An electrical device (100) comprising a body (105), characterized by further comprising a battery cell (20) according to any one of claims 20-22 or a battery (10) according to claim 23, said battery cell (20) providing electrical energy to said body (105).
  25. A method of manufacturing an electrode sheet (4), comprising:
    a folding guide part (28) is arranged on the electrode sheet (4); and
    the electrode sheet (4) is folded under the guidance of the folding guide part (28).
  26. A method of manufacturing an electrode assembly (201), comprising:
    providing a first pole piece (1), and reciprocally folding the first pole piece (1) along a first direction (X) so that the first pole piece (1) comprises a plurality of first laminations (11) which are sequentially connected and stacked;
    -providing a second pole piece (2) of opposite polarity to the first pole piece (1), -single folding the second pole piece (2) along a second direction (Y) such that the second pole piece (2) comprises two second laminations (21) connected to each other, the second direction (Y) being perpendicular or parallel to the first direction (X); and
    the second pole piece (2) is inserted into the first pole piece (1) so that the second lamination (21) and the first lamination (11) are alternately stacked in sequence.
  27. The manufacturing method according to claim 26, characterized in that, before the second pole piece (2) is folded in the second direction (Y) once, two diaphragms (3) are further provided on opposite sides of the second pole piece (2) in the thickness direction, and the two diaphragms (3) located on opposite sides of the same second pole piece (2) in the thickness direction are folded over and cover edges of the second pole piece (2) where no tab (15) is provided.
CN202180089188.XA 2021-11-23 2021-11-23 Electrode sheet, electrode assembly, battery cell, battery, electricity using device, and manufacturing method Pending CN116745953A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2021/132425 WO2023092276A1 (en) 2021-11-23 2021-11-23 Electrode sheet, electrode assembly, battery cell, battery, electric apparatus, and manufacturing methods

Publications (1)

Publication Number Publication Date
CN116745953A true CN116745953A (en) 2023-09-12

Family

ID=86538627

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202180089188.XA Pending CN116745953A (en) 2021-11-23 2021-11-23 Electrode sheet, electrode assembly, battery cell, battery, electricity using device, and manufacturing method

Country Status (5)

Country Link
EP (1) EP4254587A1 (en)
JP (1) JP2024501573A (en)
KR (1) KR20230125024A (en)
CN (1) CN116745953A (en)
WO (1) WO2023092276A1 (en)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1079254A (en) * 1996-09-04 1998-03-24 Denso Corp Rectangular battery
KR100907623B1 (en) * 2006-05-15 2009-07-15 주식회사 엘지화학 Electrolyte Assembly for Secondary Battery of Novel Laminated Structure
JP5716701B2 (en) * 2012-04-17 2015-05-13 株式会社デンソー Manufacturing method and manufacturing apparatus of laminated electrode body
CN103887472A (en) * 2014-04-01 2014-06-25 广州中国科学院工业技术研究院 Electrode assembly, manufacture method thereof and lithium secondary battery
CN104282948B (en) * 2014-09-18 2016-07-06 广州中国科学院工业技术研究院 The core of lithium battery and assembly method
CN104900905A (en) * 2015-06-03 2015-09-09 深圳市迪凯特电池科技有限公司 Laminated lithium ion battery and production process thereof
US10312547B2 (en) * 2015-11-25 2019-06-04 Robert Bosch Battery Systems Llc Cross-woven electrode assembly
CN109599589A (en) * 2018-12-12 2019-04-09 河北银隆新能源有限公司 Battery core method for making and battery
CN113224391A (en) * 2021-03-24 2021-08-06 荣盛盟固利新能源科技有限公司 Manufacturing method of laminated pole group, laminated pole group and battery
CN113571762A (en) * 2021-09-26 2021-10-29 东莞塔菲尔新能源科技有限公司 Battery cell and manufacturing method thereof

Also Published As

Publication number Publication date
JP2024501573A (en) 2024-01-12
KR20230125024A (en) 2023-08-28
WO2023092276A1 (en) 2023-06-01
EP4254587A1 (en) 2023-10-04

Similar Documents

Publication Publication Date Title
CN217158290U (en) Electrode assembly, battery cell, battery and power consumption device
US20230395952A1 (en) Battery cell, battery and electrical device
CN215896616U (en) Electrode assembly, battery monomer, battery and consumer
US20230411700A1 (en) Electrode assembly, manufacturing method therefor, battery cell, battery, and electric apparatus
US20230361354A1 (en) Electrode assembly and manufacturing method therefor, battery cell, battery, and power consuming device
KR20220164005A (en) Electrode Assemblies, Battery Cells, Batteries and Electronics
CN212161993U (en) Electrode assembly, battery module, battery pack, device using battery, and device for manufacturing electrode assembly
CN115413379A (en) Electrode assembly, battery cell, battery, and method and apparatus for manufacturing electrode assembly
CN218867151U (en) Electrode component, battery monomer, battery and power consumption device
CN217788704U (en) Battery cell, battery and consumer
CN114503334A (en) Electrode assembly and related battery, device, manufacturing method and manufacturing device thereof
EP4102606A1 (en) Electrode assembly, battery cell, battery, and power-consuming device
CN116686157A (en) Winding type electrode assembly, battery cell, battery and electric equipment
WO2023092276A1 (en) Electrode sheet, electrode assembly, battery cell, battery, electric apparatus, and manufacturing methods
WO2023092289A1 (en) Battery cell, battery, power consuming device, and method for manufacturing battery cell
CN220291027U (en) Battery monomer, battery and power consumption device
CN219144431U (en) Electrode assembly, battery cell, battery and electricity utilization device
CN217788494U (en) Electrode assembly, battery cell, battery and electric equipment
CN220291033U (en) Battery monomer, battery and power consumption device
CN220672722U (en) Battery cell, battery and electricity utilization device
EP4254610A1 (en) Battery, electric device, method for preparing battery cell, and device
CN216413208U (en) Electrode assembly, battery cell, battery, and power consumption device
CN217768426U (en) Electrode assembly, battery cell, battery, and power consumption device
WO2023092300A1 (en) Electrode assembly, battery cell, battery, and electric apparatus
EP4318755A1 (en) Battery, electric device, and method and device for preparing battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination