CN116730701A - Osmotic crystallization waterproof agent and production process thereof - Google Patents
Osmotic crystallization waterproof agent and production process thereof Download PDFInfo
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- CN116730701A CN116730701A CN202210199076.6A CN202210199076A CN116730701A CN 116730701 A CN116730701 A CN 116730701A CN 202210199076 A CN202210199076 A CN 202210199076A CN 116730701 A CN116730701 A CN 116730701A
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- 238000002425 crystallisation Methods 0.000 title claims abstract description 64
- 230000008025 crystallization Effects 0.000 title claims abstract description 64
- 230000003204 osmotic effect Effects 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 51
- 239000004568 cement Substances 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000843 powder Substances 0.000 claims abstract description 45
- 239000004567 concrete Substances 0.000 claims abstract description 38
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 36
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 36
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 36
- -1 alkali metal sodium silicate Chemical class 0.000 claims abstract description 25
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- 239000006004 Quartz sand Substances 0.000 claims abstract description 22
- 239000004576 sand Substances 0.000 claims abstract description 22
- 239000010424 alunite Substances 0.000 claims abstract description 21
- 229910052934 alunite Inorganic materials 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 21
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 21
- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 claims abstract description 21
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 20
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 20
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 20
- 239000010881 fly ash Substances 0.000 claims abstract description 20
- 239000010440 gypsum Substances 0.000 claims abstract description 20
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 20
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 18
- 239000011734 sodium Substances 0.000 claims abstract description 18
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011863 silicon-based powder Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims description 35
- 239000002994 raw material Substances 0.000 claims description 24
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 18
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 12
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical class [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 230000008595 infiltration Effects 0.000 claims description 10
- 238000001764 infiltration Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 230000004927 fusion Effects 0.000 claims description 8
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000001913 cellulose Chemical class 0.000 claims description 6
- 229920002678 cellulose Chemical class 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 230000007306 turnover Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 238000004078 waterproofing Methods 0.000 claims description 3
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical class CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 claims description 2
- AVBJHQDHVYGQLS-AWEZNQCLSA-N (2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-AWEZNQCLSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000000899 Gutta-Percha Substances 0.000 claims 1
- 240000000342 Palaquium gutta Species 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical class CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 229920000588 gutta-percha Polymers 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 239000002585 base Substances 0.000 abstract description 12
- 239000011248 coating agent Substances 0.000 abstract description 11
- 238000000576 coating method Methods 0.000 abstract description 11
- 239000002002 slurry Substances 0.000 abstract description 10
- 239000011083 cement mortar Substances 0.000 abstract description 9
- 239000013078 crystal Substances 0.000 abstract description 7
- 239000013543 active substance Substances 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000012466 permeate Substances 0.000 abstract description 4
- 230000002035 prolonged effect Effects 0.000 abstract description 4
- 239000003973 paint Substances 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 10
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical class CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 8
- ZLNXPOHTTBSBIH-HNNXBMFYSA-N (2s)-2-(dodecylamino)pentanedioic acid Chemical compound CCCCCCCCCCCCN[C@H](C(O)=O)CCC(O)=O ZLNXPOHTTBSBIH-HNNXBMFYSA-N 0.000 description 5
- BSWXAWQTMPECAK-UHFFFAOYSA-N 6,6-diethyloctyl dihydrogen phosphate Chemical class CCC(CC)(CC)CCCCCOP(O)(O)=O BSWXAWQTMPECAK-UHFFFAOYSA-N 0.000 description 5
- 229920002907 Guar gum Polymers 0.000 description 5
- 150000004996 alkyl benzenes Chemical class 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 5
- 235000011130 ammonium sulphate Nutrition 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- NADLOSPYPYYGDY-UHFFFAOYSA-N [Na].OS(=O)(=O)Cc1cccc2ccccc12 Chemical compound [Na].OS(=O)(=O)Cc1cccc2ccccc12 NADLOSPYPYYGDY-UHFFFAOYSA-N 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a permeable crystallization waterproof agent and a production process thereof, belonging to the technical field of waterproof paint, and comprising the following formula: cement, mesh sand, quartz sand, a surfactant, a dispersing agent, a penetration crystallization master batch silicone zirconium, silicon powder, a catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylnaphthalene sulfonate sodium high-efficiency water reducing agent, alkali metal sodium silicate solution and water. According to the permeable crystallization waterproof agent and the production process, the cement-based permeable crystallization waterproof coating is coated on the surface of cement concrete, active substances in the coating permeate into the cement concrete to form needle-shaped crystals, so that defects such as capillary holes and cracks of a cement base layer are blocked, the impervious pressure of the cement slurry, cement mortar, concrete and other base layers is enhanced by 200-500 times, the continuous waterproof effect is achieved, the service life of the cement-based permeable crystallization waterproof agent is prolonged, the strength is not reduced, and the overall waterproof performance is effectively improved.
Description
Technical Field
The invention relates to the technical field of waterproof paint, in particular to a permeable crystallization waterproof agent and a production process thereof.
Background
Measures taken from the construction material and construction to prevent water penetration into certain parts of the building. Waterproof is used in roofing, underground building, underground part of building, inner room and water storing structure. According to the measures and means adopted by the waterproof material, the waterproof material is divided into two categories, namely material waterproof and structural waterproof. The material waterproof is to block the water passage by building material to reach waterproof purpose or to increase the leakage resistance, such as coiled material waterproof, film waterproof, concrete and cement mortar rigid waterproof, clay, ash waterproof, etc. The waterproof structure adopts a proper structural form to block the passage of water so as to achieve the aim of waterproof, such as a water stop belt, a cavity structure and the like.
1. The existing waterproof material cannot well fill the interior of a building, is plugged, and is easy to cause water leakage after being contacted with water for a long time.
2. The existing waterproof material cannot expand when meeting water, cannot react inside, cannot interact with cement slurry, cement mortar, concrete and other base layers, and has poor seepage prevention performance.
Disclosure of Invention
The invention aims to provide a permeable crystallization waterproof agent and a production process thereof, which are used for solving the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions: an osmotic crystallization waterproof agent comprises the following formula: cement, mesh sand, quartz sand, surfactant, dispersant, infiltration crystallization master batch silicone zirconium, silicon powder, catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylene naphthalene sulfonate sodium high-efficiency water reducer, alkali metal sodium silicate solution and water, and the following components are proportioned according to mass: 59-160 parts of cement, 30-43 parts of mesh sand, 29-56 parts of quartz sand, 0.7-1.5 parts of surfactant, 0.3-0.8 part of dispersing agent, 16-31 parts of permeable crystallization master batch silicone zirconium, 9-18 parts of silica powder, 0.1-0.8 part of catalyst, 20-42 parts of aluminum sulfate, 15-32 parts of permeable crystallization master batch silicone zirconium, 8-17 parts of fly ash, 3-10 parts of calcined gypsum powder, 2.5-8.6 parts of CEA alunite concrete composite expanding agent, 0.9-1.8 parts of NF polymethylnaphthalene sulfonate high-efficiency water reducer, 12-23 parts of alkali metal sodium silicate solution and 15-45 parts of water.
Further, the raw materials are prepared from the following components in parts by weight: 65 parts of cement, 33 parts of mesh sand, 32 parts of quartz sand, 0.8 part of surfactant, 0.4 part of dispersing agent, 17 parts of permeable crystallization master batch silicone zirconium, 11 parts of silica powder, 0.3 part of catalyst, 22 parts of aluminum sulfate, 17 parts of permeable crystallization master batch silicone zirconium, 9 parts of fly ash, 4 parts of calcined gypsum powder, 3.5 parts of CEA alunite concrete composite expanding agent, 1.2 parts of NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, 15 parts of alkali metal sodium silicate solution and 18 parts of water.
Further, the raw materials are prepared from the following components in parts by weight: 59 parts of cement, 30 parts of mesh sand, 29 parts of quartz sand, 0.7 part of surfactant, 0.3 part of dispersing agent, 16 parts of permeable crystallization master batch silicone zirconium, 9 parts of silicon powder, 0.1 part of catalyst, 20 parts of aluminum sulfate, 15 parts of permeable crystallization master batch silicone zirconium, 8 parts of fly ash, 3 parts of calcined gypsum powder, 2.5 parts of CEA alunite concrete composite expanding agent, 0.9 part of NF polymethylnaphthalene sulfonate high-efficiency water reducing agent, 12 parts of alkali metal sodium silicate solution and 35 parts of water.
Further, the raw materials are prepared from the following components in parts by weight: 120 parts of cement, 40 parts of mesh sand, 39 parts of quartz sand, 1.2 parts of surfactant, 0.4 part of dispersing agent, 25 parts of permeable crystallization master batch silicone zirconium, 16 parts of silicon powder, 0.5 part of catalyst, 35 parts of aluminum sulfate, 29 parts of permeable crystallization master batch silicone zirconium, 12 parts of fly ash, 7 parts of calcined gypsum powder, 6.3 parts of CEA alunite concrete composite expanding agent, 1.6 parts of NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, 20 parts of alkali metal sodium silicate solution and 32 parts of water.
Further, the surfactant is formed by combining one or more of linear alkylbenzene sodium sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, sodium laurylsulfate, laurylglutamic acid and nonylphenol polyoxyethylene ether.
Further, the dispersing agent is formed by combining one or more of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivative, polyacrylamide, guar gum and fatty acid polyethylene glycol ester.
The invention provides another technology, comprising a production process of a permeable crystallization waterproof agent, which comprises the following steps:
s1: adding cement, mesh sand, quartz sand, infiltration crystalline master batch silicone zirconium and silicon powder into a high-speed pulverizer to be dispersed to form a primary material, then putting the primary material into a grinding machine, and grinding the primary material in a slow stirring mill with the speed of 30-50 min/r for 1-2.5 hours to obtain fine raw material powder;
s2: putting the raw material powder obtained in the step one into a sieving machine, carrying out particle screening and filtering, and removing large particle impurities in the raw material powder;
s3: pouring the filtered powder into a cantilever double-spiral conical mixer according to the formula amount, sequentially placing the rest materials into the cantilever double-spiral conical mixer according to the proportion, and stirring for 15min at room temperature under the condition that the relative humidity in the air is not higher than 65%;
s4: heating the stirred solution to 70-80 ℃ for 30-60 minutes in a reactor, and continuously stirring the solution in the heating process;
s5: all the materials which are stirred together are taken out from the reactor and are kept stand for 1 hour, and then the packaging is carried out, thus obtaining the finished product of the permeable crystallization waterproof agent.
Further, in the S3, the rotation motion of the spiral shaft and the revolution motion of the spiral shaft along with the turnover of the rotating arm along the cylinder wall in the cantilever double-spiral conical mixer are all formed cycloidal pin gear reducers with large speed ratio and high efficiency, so that the fusion speed is effectively improved.
Compared with the prior art, the invention has the beneficial effects that: according to the permeable crystallization waterproof agent and the production process, the permeable crystallization master batch silicone zirconium is subjected to reaction fusion with CEA alunite concrete composite expanding agent, NF (sodium polymethylene naphthalene sulfonate) high-efficiency water reducing agent and alkali metal sodium silicate solution through the catalyst, the aluminum sulfate fly ash, the calcined gypsum powder and the CEA alunite concrete composite expanding agent to form a coating, the cement-based permeable crystallization waterproof coating is coated on the surface of cement concrete, active substances in the coating permeate into the cement concrete to form needle-shaped crystals, so that defects such as pores and cracks of a cement base layer are blocked, and the impervious pressure of the cement slurry, cement mortar, concrete and other base layers is enhanced by 200-500 times, so that the continuous waterproof effect is achieved, the service life of the cement slurry, the cement mortar, the concrete and other base layers is prolonged, the strength of the cement slurry is not reduced, and the overall waterproof performance is effectively improved.
Drawings
FIG. 1 is a process flow diagram of the present invention.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Embodiment one:
an osmotic crystallization waterproof agent comprises the following formula: cement, mesh sand, quartz sand, surfactant, dispersant, infiltration crystallization master batch silicone zirconium, silicon powder, catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, alkali metal sodium silicate solution and water, wherein the raw materials comprise the following components in parts by weight: 65 parts of cement, 33 parts of mesh sand, 32 parts of quartz sand, 0.8 part of surfactant, 0.4 part of dispersing agent, 17 parts of permeable crystallization master batch silicone zirconium, 11 parts of silica powder, 0.3 part of catalyst, 22 parts of aluminum sulfate, 17 parts of permeable crystallization master batch silicone zirconium, 9 parts of fly ash, 4 parts of calcined gypsum powder, 3.5 parts of CEA alunite concrete composite expanding agent, 1.2 parts of NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, 15 parts of alkali metal sodium silicate solution and 18 parts of water.
The surfactant is formed by combining one or more of linear alkylbenzene sodium sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, sodium laurylsulfate, laurylglutamic acid and nonylphenol polyoxyethylene ether.
The dispersing agent is formed by combining one or more of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivative, polyacrylamide, guar gum and fatty acid polyethylene glycol ester.
The invention provides another technology, comprising a production process of a permeable crystallization waterproof agent, which comprises the following steps:
s1: adding cement, mesh sand, quartz sand, infiltration crystalline master batch silicone zirconium and silicon powder into a high-speed pulverizer to be dispersed to form a primary material, then putting the primary material into a grinding machine, and grinding the primary material in a slow stirring mill with the speed of 30-50 min/r for 1-2.5 hours to obtain fine raw material powder;
s2: putting the raw material powder obtained in the step one into a sieving machine, carrying out particle screening and filtering, and removing large particle impurities in the raw material powder;
s3: pouring the filtered powder into a cantilever double-spiral conical mixer according to the formula amount, sequentially placing the rest materials into the cantilever double-spiral conical mixer according to the proportion, and stirring for 15min at room temperature under the condition that the relative humidity in the air is not higher than 65%;
s4: heating the stirred solution to 70-80 ℃ for 30-60 minutes in a reactor, and continuously stirring the solution in the heating process;
s5: all the materials which are stirred together are taken out from the reactor and are kept stand for 1 hour, and then the packaging is carried out, thus obtaining the finished product of the permeable crystallization waterproof agent.
In the S3, the rotation motion of the spiral shaft and the revolution motion of the spiral shaft along with the turnover of the rotating arm along the cylinder wall in the cantilever double-spiral conical mixer are all formed cycloidal pin gear reducers with large speed ratio and high efficiency, so that the fusion speed is effectively improved.
Embodiment two:
an osmotic crystallization waterproof agent comprises the following formula: cement, mesh sand, quartz sand, surfactant, dispersant, infiltration crystallization master batch silicone zirconium, silicon powder, catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, alkali metal sodium silicate solution and water, wherein the raw materials comprise the following components in parts by weight: 59 parts of cement, 30 parts of mesh sand, 29 parts of quartz sand, 0.7 part of surfactant, 0.3 part of dispersing agent, 16 parts of permeable crystallization master batch silicone zirconium, 9 parts of silicon powder, 0.1 part of catalyst, 20 parts of aluminum sulfate, 15 parts of permeable crystallization master batch silicone zirconium, 8 parts of fly ash, 3 parts of calcined gypsum powder, 2.5 parts of CEA alunite concrete composite expanding agent, 0.9 part of NF polymethylnaphthalene sulfonate high-efficiency water reducing agent, 12 parts of alkali metal sodium silicate solution and 35 parts of water.
The surfactant is formed by combining one or more of linear alkylbenzene sodium sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, sodium laurylsulfate, laurylglutamic acid and nonylphenol polyoxyethylene ether.
The dispersing agent is formed by combining one or more of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivative, polyacrylamide, guar gum and fatty acid polyethylene glycol ester.
The invention provides another technology, comprising a production process of a permeable crystallization waterproof agent, which comprises the following steps:
s1: adding cement, mesh sand, quartz sand, infiltration crystalline master batch silicone zirconium and silicon powder into a high-speed pulverizer to be dispersed to form a primary material, then putting the primary material into a grinding machine, and grinding the primary material in a slow stirring mill with the speed of 30-50 min/r for 1-2.5 hours to obtain fine raw material powder;
s2: putting the raw material powder obtained in the step one into a sieving machine, carrying out particle screening and filtering, and removing large particle impurities in the raw material powder;
s3: pouring the filtered powder into a cantilever double-spiral conical mixer according to the formula amount, sequentially placing the rest materials into the cantilever double-spiral conical mixer according to the proportion, and stirring for 15min at room temperature under the condition that the relative humidity in the air is not higher than 65%;
s4: heating the stirred solution to 70-80 ℃ for 30-60 minutes in a reactor, and continuously stirring the solution in the heating process;
s5: all the materials which are stirred together are taken out from the reactor and are kept stand for 1 hour, and then the packaging is carried out, thus obtaining the finished product of the permeable crystallization waterproof agent.
In the S3, the rotation motion of the spiral shaft and the revolution motion of the spiral shaft along with the turnover of the rotating arm along the cylinder wall in the cantilever double-spiral conical mixer are all formed cycloidal pin gear reducers with large speed ratio and high efficiency, so that the fusion speed is effectively improved.
Embodiment III:
an osmotic crystallization waterproof agent comprises the following formula: cement, mesh sand, quartz sand, surfactant, dispersant, infiltration crystallization master batch silicone zirconium, silicon powder, catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, alkali metal sodium silicate solution and water, wherein the raw materials comprise the following components in parts by weight: 59 parts of cement, 30 parts of mesh sand, 29 parts of quartz sand, 0.7 part of surfactant, 0.3 part of dispersing agent, 16 parts of permeable crystallization master batch silicone zirconium, 9 parts of silicon powder, 0.1 part of catalyst, 20 parts of aluminum sulfate, 15 parts of permeable crystallization master batch silicone zirconium, 8 parts of fly ash, 3 parts of calcined gypsum powder, 2.5 parts of CEA alunite concrete composite expanding agent, 0.9 part of NF polymethylnaphthalene sulfonate high-efficiency water reducing agent, 12 parts of alkali metal sodium silicate solution and 35 parts of water.
The surfactant is formed by combining one or more of linear alkylbenzene sodium sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, sodium laurylsulfate, laurylglutamic acid and nonylphenol polyoxyethylene ether.
The dispersing agent is formed by combining one or more of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methyl amyl alcohol, cellulose derivative, polyacrylamide, guar gum and fatty acid polyethylene glycol ester.
The invention provides another technology, comprising a production process of a permeable crystallization waterproof agent, which comprises the following steps:
s1: adding cement, mesh sand, quartz sand, infiltration crystalline master batch silicone zirconium and silicon powder into a high-speed pulverizer to be dispersed to form a primary material, then putting the primary material into a grinding machine, and grinding the primary material in a slow stirring mill with the speed of 30-50 min/r for 1-2.5 hours to obtain fine raw material powder;
s2: putting the raw material powder obtained in the step one into a sieving machine, carrying out particle screening and filtering, and removing large particle impurities in the raw material powder;
s3: pouring the filtered powder into a cantilever double-spiral conical mixer according to the formula amount, sequentially placing the rest materials into the cantilever double-spiral conical mixer according to the proportion, and stirring for 15min at room temperature under the condition that the relative humidity in the air is not higher than 65%;
s4: heating the stirred solution to 70-80 ℃ for 30-60 minutes in a reactor, and continuously stirring the solution in the heating process;
s5: all the materials which are stirred together are taken out from the reactor and are kept stand for 1 hour, and then the packaging is carried out, thus obtaining the finished product of the permeable crystallization waterproof agent.
In the S3, the rotation motion of the spiral shaft and the revolution motion of the spiral shaft along with the turnover of the rotating arm along the cylinder wall in the cantilever double-spiral conical mixer are all formed cycloidal pin gear reducers with large speed ratio and high efficiency, so that the fusion speed is effectively improved.
The surfactant in the first embodiment, the second embodiment and the third embodiment is formed by combining one or more of linear alkylbenzene sodium sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, sodium laurylsulfate, laurylglutamic acid and nonylphenol polyoxyethylene ether, and the dispersing agent is formed by combining one or more of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methylpentanol, cellulose derivative, polyacrylamide, guar gum and fatty acid polyethylene glycol ester.
Table one is a test table for waterproofing agent
| Impermeability to water | Water absorption rate | Acid-base treatment | Crystallization treatment | Bond strength | |
| Example 1 | No water seepage | 0.5 | No break | Needle-like crystals | 1.6 |
| Example two | No water seepage | 0.85 | No break | Needle-like crystals | 1.8 |
| Example III | No water seepage | 1.23 | No break | Needle-like crystals | 1.1 |
According to the data of table one, the whole shown in example three is more excellent in water repellency of the water absorption.
The permeable crystallization master batch silicone zirconium is subjected to reaction fusion by a catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF (sodium sulfomethyl naphthalene) sodium sulfonate high-efficiency water reducing agent and alkali metal sodium silicate solution to form a coating, the cement-based permeable crystallization waterproof coating is coated on the surface of cement concrete, active substances in the coating permeate into the cement concrete to form needle-shaped crystals, so that defects such as pores and cracks of a cement base layer are blocked, the impervious pressure of the cement slurry, cement mortar, concrete and other base layers is enhanced by 200-500 times, so that the continuous waterproof effect is achieved, the service life of the cement slurry, the cement mortar, the concrete and other base layers is prolonged, the strength is not reduced, and the overall waterproof performance is effectively improved.
To sum up: according to the permeable crystallization waterproof agent and the production process, the permeable crystallization master batch silicone zirconium is subjected to reaction fusion with CEA alunite concrete composite expanding agent, NF (sodium polymethylene naphthalene sulfonate) high-efficiency water reducing agent and alkali metal sodium silicate solution through a catalyst, aluminum sulfate fly ash, calcined gypsum powder and the like to form a coating, the cement-based permeable crystallization waterproof coating is coated on the surface of cement concrete, active substances in the coating permeate into the cement concrete to form needle-shaped crystals, so that defects such as capillary holes and cracks of a cement base layer are blocked, and the impervious pressure of the cement slurry, cement mortar, concrete and other base layers is enhanced by 200-500 times, so that the continuous waterproof effect is achieved, the service life of the cement slurry, the cement mortar, the cement concrete and the like is prolonged, the strength of the cement slurry is not reduced, and the overall waterproof performance is effectively improved.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should be covered by the protection scope of the present invention by making equivalents and modifications to the technical solution and the inventive concept thereof.
Claims (8)
1. An osmotic crystallization waterproof agent is characterized by comprising the following formula: cement, mesh sand, quartz sand, surfactant, dispersant, infiltration crystallization master batch silicone zirconium, silicon powder, catalyst, aluminum sulfate fly ash, calcined gypsum powder, CEA alunite concrete composite expanding agent, NF polymethylene naphthalene sulfonate sodium high-efficiency water reducer, alkali metal sodium silicate solution and water, and the following components are proportioned according to mass: 59-160 parts of cement, 30-43 parts of mesh sand, 29-56 parts of quartz sand, 0.7-1.5 parts of surfactant, 0.3-0.8 part of dispersing agent, 16-31 parts of permeable crystallization master batch silicone zirconium, 9-18 parts of silica powder, 0.1-0.8 part of catalyst, 20-42 parts of aluminum sulfate, 15-32 parts of permeable crystallization master batch silicone zirconium, 8-17 parts of fly ash, 3-10 parts of calcined gypsum powder, 2.5-8.6 parts of CEA alunite concrete composite expanding agent, 0.9-1.8 parts of NF polymethylnaphthalene sulfonate high-efficiency water reducer, 12-23 parts of alkali metal sodium silicate solution and 15-45 parts of water.
2. The permeable crystallization waterproof agent as claimed in claim 1, wherein the raw materials are prepared from the following materials in parts by weight: 65 parts of cement, 33 parts of mesh sand, 32 parts of quartz sand, 0.8 part of surfactant, 0.4 part of dispersing agent, 17 parts of permeable crystallization master batch silicone zirconium, 11 parts of silica powder, 0.3 part of catalyst, 22 parts of aluminum sulfate, 17 parts of permeable crystallization master batch silicone zirconium, 9 parts of fly ash, 4 parts of calcined gypsum powder, 3.5 parts of CEA alunite concrete composite expanding agent, 1.2 parts of NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, 15 parts of alkali metal sodium silicate solution and 18 parts of water.
3. The permeable crystallization waterproof agent as claimed in claim 1, wherein the raw materials are prepared from the following materials in parts by weight: 59 parts of cement, 30 parts of mesh sand, 29 parts of quartz sand, 0.7 part of surfactant, 0.3 part of dispersing agent, 16 parts of permeable crystallization master batch silicone zirconium, 9 parts of silicon powder, 0.1 part of catalyst, 20 parts of aluminum sulfate, 15 parts of permeable crystallization master batch silicone zirconium, 8 parts of fly ash, 3 parts of calcined gypsum powder, 2.5 parts of CEA alunite concrete composite expanding agent, 0.9 part of NF polymethylnaphthalene sulfonate high-efficiency water reducing agent, 12 parts of alkali metal sodium silicate solution and 35 parts of water.
4. The permeable crystallization waterproof agent as claimed in claim 1, wherein the raw materials are prepared from the following materials in parts by weight: 120 parts of cement, 40 parts of mesh sand, 39 parts of quartz sand, 1.2 parts of surfactant, 0.4 part of dispersing agent, 25 parts of permeable crystallization master batch silicone zirconium, 16 parts of silicon powder, 0.5 part of catalyst, 35 parts of aluminum sulfate, 29 parts of permeable crystallization master batch silicone zirconium, 12 parts of fly ash, 7 parts of calcined gypsum powder, 6.3 parts of CEA alunite concrete composite expanding agent, 1.6 parts of NF polymethylnaphthalene sulfonate sodium high-efficiency water reducer, 20 parts of alkali metal sodium silicate solution and 32 parts of water.
5. The permeable crystallization waterproof agent according to claim 1, wherein the surfactant is composed of one or more of linear alkylbenzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate, ammonium fatty alcohol-polyoxyethylene ether sulfate, sodium lauryl sulfate, lauroyl glutamic acid and nonylphenol polyoxyethylene ether.
6. The permeable crystalline waterproofing agent of claim 1, wherein the dispersant is comprised of one or more of triethylhexyl phosphate, sodium dodecyl sulfate, methylpentanol, cellulose derivatives, polyacrylamide, gutta percha, and polyethylene glycol esters of fatty acids.
7. The process for producing an osmotically crystalline waterproofing agent according to claim 1, comprising the steps of:
s1: adding cement, mesh sand, quartz sand, infiltration crystalline master batch silicone zirconium and silicon powder into a high-speed pulverizer to be dispersed to form a primary material, then putting the primary material into a grinding machine, and grinding the primary material in a slow stirring mill with the speed of 30-50 min/r for 1-2.5 hours to obtain fine raw material powder;
s2: putting the raw material powder obtained in the step one into a sieving machine, carrying out particle screening and filtering, and removing large particle impurities in the raw material powder;
s3: pouring the filtered powder into a cantilever double-spiral conical mixer according to the formula amount, sequentially placing the rest materials into the cantilever double-spiral conical mixer according to the proportion, and stirring for 15min at room temperature under the condition that the relative humidity in the air is not higher than 65%;
s4: heating the stirred solution to 70-80 ℃ for 30-60 minutes in a reactor, and continuously stirring the solution in the heating process;
s5: all the materials which are stirred together are taken out from the reactor and are kept stand for 1 hour, and then the packaging is carried out, thus obtaining the finished product of the permeable crystallization waterproof agent.
8. The process for producing a permeable crystallization waterproof agent according to claim 7, wherein for the rotation movement of the screw shaft in the cantilever double-screw conical mixer and the revolution movement of the screw shaft along with the turnover of the rotating arm along the cylinder wall in the step S3, a shaping cycloidal pin gear reducer with high speed ratio and high efficiency is adopted, so that the fusion speed is effectively improved.
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| CN202210199076.6A CN116730701A (en) | 2022-03-01 | 2022-03-01 | Osmotic crystallization waterproof agent and production process thereof |
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| CN202210199076.6A CN116730701A (en) | 2022-03-01 | 2022-03-01 | Osmotic crystallization waterproof agent and production process thereof |
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