CN116622930A - Method for regulating slag and protecting converter by using white coal - Google Patents

Method for regulating slag and protecting converter by using white coal Download PDF

Info

Publication number
CN116622930A
CN116622930A CN202310591006.XA CN202310591006A CN116622930A CN 116622930 A CN116622930 A CN 116622930A CN 202310591006 A CN202310591006 A CN 202310591006A CN 116622930 A CN116622930 A CN 116622930A
Authority
CN
China
Prior art keywords
slag
converter
white coal
splashing
protecting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310591006.XA
Other languages
Chinese (zh)
Inventor
吴成阳
王军
鲁川
刘呈军
高平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Iron and Steel Co Ltd
Original Assignee
Nanjing Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Iron and Steel Co Ltd filed Critical Nanjing Iron and Steel Co Ltd
Priority to CN202310591006.XA priority Critical patent/CN116622930A/en
Publication of CN116622930A publication Critical patent/CN116622930A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/36Processes yielding slags of special composition
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/44Refractory linings
    • C21C5/441Equipment used for making or repairing linings
    • C21C5/443Hot fettling; Flame gunning
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The invention discloses a method for regulating slag and protecting a converter by using white coal, which is characterized by comprising the following steps of: comprising the following steps: 1) The steel tapping of the converter adopts the operation of slag retention and steel retention, and the slag retention amount is 2-3% of the volume capacity of the converter; 2) Adding white coal into the converter after tapping of the converter to regulate slag, and reducing the oxygen content in the slag through a carbon-oxygen reaction, wherein the addition amount of the white coal is 1% -2% of the slag remaining amount of the converter; 3) After the white coal is put into, starting slag splashing furnace protection operation, wherein the slag splashing gun position is changed from high to low, and the slag splashing time is 3-4 min; 4) And pressing the gun position to 0.8m according to the slag splashing effect, lifting the gun, and ending the slag splashing furnace protection. The invention can effectively reduce the oxygen content in the slag, strengthen the viscosity of the slag, enable the slag to be more easily hung on the furnace wall, play a role in protecting the furnace lining, and simultaneously have short furnace time of slag mixing by adding white coal, and can effectively reduce the slag splashing furnace protection time, thereby improving the production efficiency.

Description

Method for regulating slag and protecting converter by using white coal
Technical Field
The invention relates to the field of metallurgy, in particular to a method for regulating slag and protecting a converter by using white coal.
Background
White coal is used as one of auxiliary materials commonly used in steelmaking, and is mainly used for providing a certain amount of chemical heat through a carbon-oxygen reaction when the physical heat and the chemical heat value of molten iron are insufficient. However, the practical application shows that when the molten steel is peroxidized at the end point, the content of FeO in the slag is increased, so that the slag is difficult to remove when the slag is splashed to protect the furnace, the viscosity of the slag is insufficient, the slag cannot be adhered to the furnace lining, and the furnace protecting effect is greatly reduced. Therefore, a method for maintaining the converter lining is required to be developed in a targeted manner so as to play a role in protecting the converter lining.
Disclosure of Invention
The invention aims to: aiming at the defects and defects of the prior art, the invention provides the method for regulating and protecting the slag by using the white coal for the converter, which can effectively reduce the oxygen content in the slag, strengthen the viscosity of the slag, enable the slag to be more easily hung on the furnace wall, play a role in protecting the furnace lining, ensure that the time for taking up the slag by adding the white coal for regulating the slag is short, and effectively reduce the time for splashing slag and protecting the furnace, thereby improving the production efficiency.
The technical scheme is as follows: the invention relates to a method for regulating slag and protecting a converter by using white coal, which is characterized by comprising the following steps of: comprising the following steps:
1) The steel tapping of the converter adopts the operation of slag retention and steel retention, and the slag retention amount is 2-3% of the volume capacity of the converter;
2) Adding white coal into the converter after tapping of the converter to regulate slag, and reducing the oxygen content in the slag through a carbon-oxygen reaction, wherein the addition amount of the white coal is 1% -2% of the slag remaining amount of the converter;
3) After the white coal is put into, the slag splashing furnace protection operation is started, the slag splashing nitrogen pressure is controlled to be 1.0 MPa-1.4 MPa, and the nitrogen flow is controlled to be 26000Nm 3 /h~29000Nm 3 And (h) controlling the distance between the gun head and the slag surface from high to low, changing the gun position, and sputtering the slag for 3-4 min;
4) And pressing the gun position to 0.8m according to the slag splashing effect, lifting the gun, and ending the slag splashing furnace protection.
Wherein, in the step 1), the converter is a 120T converter, and the slag remaining amount is 2-3% of the volume capacity of the converter.
Wherein the weight of the slag in the step 2) is 2.4T-3.6T.
Wherein, the weight of the white coal added in the step 2) is 20 kg-40 kg.
Wherein, the pressure of the slag splashing nitrogen in the step 3) is controlled between 1.1MPa and 1.3MPa.
Wherein, in the step 3), the nitrogen flow is controlled at 27000Nm 3 /h~28000Nm 3 /h。
Wherein, the slag splashing gun position in the step 3) is divided into a slag splashing early stage, a slag splashing middle stage and a slag splashing end stage from high to low, and the distance between the gun head and the slag surface is controlled within the range of 800 mm-1500 mm.
Wherein, the earlier stage of slag splashing adopts high gun position operation, and the gun position is put to 1500mm. The effect of slowly stirring the slag to strengthen the carbon-oxygen reaction is achieved, so that the oxidizing property of the slag is reduced, and the viscosity is enhanced to be firmly hung on the wall of the converter.
Wherein, the gun position is adjusted to 1200mm in the middle of slag splashing, and after the slag is inactive, the gun position is slowly pressed down by 800-1000 mm.
Wherein, the gun position pressure at the end of slag splashing is 800mm, and the slag splashing furnace protection is finished by lifting the gun with the advantages of high slag lifting density at the furnace mouth and certain viscosity of the slag in a sheet shape.
The beneficial effects are that: compared with the prior art, the invention has the following remarkable advantages: the invention uses the white coal to temper the converter slag, can effectively improve the peroxidized slag, reduce the oxidizing property of the slag and increase the viscosity of the slag. After slag is regulated by using white coal, slag can be quickly removed, slag splashing furnace protection time of peroxidation tapping can be reduced, and production efficiency can be improved.
Detailed Description
The technical scheme of the invention is further described below with reference to the specific embodiments.
The invention solves the problems of poor slag splashing effect, long slag splashing time, and influence on the service life of a furnace lining and the operation rate of a converter of the conventional peroxidized steel tapping furnace. After tapping, the peroxide slag is quenched and tempered by adding the white coal, so that the oxygen content in the slag can be effectively reduced, the viscosity of the slag becomes stronger, the slag is more easily hung on the furnace wall, the effect of protecting the furnace lining is achieved, meanwhile, the slag removing time of the furnace time of slag mixing by adding the white coal is short, the slag splashing furnace protecting time can be effectively reduced, and the production efficiency is improved.
Example 1:
the method for slag adjustment and furnace protection of white coal for a converter in the embodiment comprises the following steps:
(1) The weight of molten iron fed into the converter is 104 tons, the addition amount of scrap steel is 24 tons, and the tapping amount is 118 tons.
(2) After tapping, the slag remaining amount is calculated to be about 3 tons, the addition amount of the white coal is 34kg, and the slag sample components are as follows:
TABLE 1 slag sample composition table
(3) When the slag splashing furnace protection is operated, the overall gun position is adjusted in a high-low mode according to the slag lifting effect, the initial slag splashing gun position is 1500mm, the initial slag splashing gun position is adjusted to 1200mm after slag lifting, and the gun is gradually and slowly pressed to 800mm.
(4) The gun lifting ends the slag splashing, and the actual nitrogen supply amount is 1256Nm3. Slag splashing time 3:12, the slag lifting speed is high, the slag is firmly hung on the furnace wall, and the falling area is small.
Example 2:
the method for slag adjustment and furnace protection of white coal for a converter in the embodiment comprises the following steps:
(1) The weight of molten iron fed into the converter is 109 tons, the addition amount of scrap steel is 26 tons, and the tapping amount is calculated to be 125 tons.
(2) After tapping, calculating the slag remaining amount to be about 3 tons, wherein the addition amount of the white coal is 43kg, and the slag sample components are shown in the following table;
TABLE 2 slag sample composition Table
(3) When the slag splashing furnace protection is operated, the overall gun position is adjusted in a high-low mode according to the slag lifting effect, the initial slag splashing gun position is 1500mm, the initial slag splashing gun position is adjusted to 1200mm after slag lifting, and the gun is gradually and slowly pressed to 800mm.
(4) And the gun lifting ends the slag splashing, and the actual nitrogen supply amount is 1342Nm3. Slag splashing time 3:32, the slag lifting speed is high, the slag is firmly hung on the furnace wall, and the falling area is small.
According to the embodiment, by adopting the method for regulating and protecting the slag of the white coal for the converter, disclosed by the invention, the white coal is added after tapping, the content of (FeO) in the slag is reduced, the slag is quickly cooled through slag splashing and protecting, the oxidizing property of the slag can be quickly reduced through high-pressure nitrogen injection at a high gun position, the slag lifting time is short, the slag can be quickly and firmly hung on the furnace wall, the effect of protecting refractory bricks at the furnace bottom is achieved, and the service life of the furnace is prolonged.

Claims (10)

1. A method for regulating slag and protecting a converter by using white coal is characterized by comprising the following steps of: comprising the following steps:
1) The steel tapping of the converter adopts the operation of slag retention and steel retention, and the slag retention amount is 2-3% of the volume capacity of the converter;
2) Adding white coal into the converter after tapping of the converter to regulate slag, and reducing the oxygen content in the slag through a carbon-oxygen reaction, wherein the addition amount of the white coal is 1% -2% of the slag remaining amount of the converter;
3) After the white coal is put into, the slag splashing furnace protection operation is started, the slag splashing nitrogen pressure is controlled to be 1.0 MPa-1.4 MPa, and the nitrogen flow is controlled to be 26000Nm 3 /h~29000Nm 3 And (h) controlling the distance between the gun head and the slag surface from high to low, changing the gun position, and sputtering the slag for 3-4 min;
4) And pressing the gun position to 0.8m according to the slag splashing effect, lifting the gun, and ending the slag splashing furnace protection.
2. The method for slag conditioning and protecting of white coal for a converter according to claim 1, wherein: the converter in the step 1) is a 120T converter, and the slag remaining amount is 2% -3% of the volume capacity of the converter.
3. The method for slag control and furnace protection of white coal for a converter according to claim 2, wherein: the weight of the slag in the step 2) is 2.4T-3.6T.
4. A method for slag conditioning and protecting of white coal for a converter according to claim 3, wherein: the weight of the white coal added in the step 2) is 20 kg-40 kg.
5. The method for slag conditioning and protecting of white coal for a converter according to claim 1, wherein: the pressure of the slag splashing nitrogen in the step 3) is controlled to be 1.1-1.3 MPa.
6. The method for slag conditioning and protecting of white coal for a converter according to claim 1, wherein: the nitrogen flow rate in the step 3) is controlled at 27000Nm 3 /h~28000Nm 3 /h。
7. The method for slag conditioning and protecting of white coal for a converter according to claim 1, wherein: the slag splashing gun position in the step 3) is divided into a slag splashing early stage, a slag splashing middle stage and a slag splashing end stage from high to low, and the distance between the gun head and the slag surface is controlled within the range of 800 mm-1500 mm.
8. The method for slag control and furnace protection of white coal for a converter according to claim 7, wherein: the high gun position operation is adopted in the earlier stage of slag splashing, and the gun position is set to 1500mm.
9. The method for slag conditioning and protecting of white coal for a converter according to claim 8, wherein: and the gun position is regulated to 1200mm in the middle of slag splashing, and after the slag is inactive, the gun position is slowly pressed down by 800-1000 mm.
10. The method for slag conditioning and protecting of white coal for a converter according to claim 9, wherein: the gun position pressure at the end of slag splashing is 800mm.
CN202310591006.XA 2023-05-24 2023-05-24 Method for regulating slag and protecting converter by using white coal Pending CN116622930A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310591006.XA CN116622930A (en) 2023-05-24 2023-05-24 Method for regulating slag and protecting converter by using white coal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310591006.XA CN116622930A (en) 2023-05-24 2023-05-24 Method for regulating slag and protecting converter by using white coal

Publications (1)

Publication Number Publication Date
CN116622930A true CN116622930A (en) 2023-08-22

Family

ID=87636106

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310591006.XA Pending CN116622930A (en) 2023-05-24 2023-05-24 Method for regulating slag and protecting converter by using white coal

Country Status (1)

Country Link
CN (1) CN116622930A (en)

Similar Documents

Publication Publication Date Title
CN109136466B (en) Method for making steel from sulfur-containing and aluminum-containing steel
CN109385503B (en) Carbon-manganese-protecting converter steelmaking process
CN112680565B (en) By using CO in AOD furnace2Method for smelting high-manganese stainless steel by decarburization
CN109252010B (en) Smelting method for controlling oxidability of IF steel top slag
CN111647714A (en) Smelting method for improving service life of electric furnace
CN109628697B (en) High-carbon dephosphorization method for smelting medium-high carbon steel grade in converter
CN108300831B (en) Method for improving heat source in smelting process of dephosphorization converter
CN113652517B (en) Magnesite slag remaining, slag adjusting and furnace protecting method for converter
CN114606357A (en) Method for removing phosphorus and leaving carbon in medium-high carbon steel by converter
CN101638706A (en) Liquid steel pre-deoxidizing technology in steelmaking revolving furnace
CN107058679A (en) A kind of method for stablizing half steel quality
CN111154939B (en) Method for reducing height of converter bottom
CN107955858A (en) A kind of production method of ultra-low-carbon steel SAE1006
CN109825665B (en) Method for reducing carbon and oxygen deposit of molten steel at converter end point
CN116622930A (en) Method for regulating slag and protecting converter by using white coal
CN113355477B (en) Method for realizing high scrap ratio smelting of converter by bottom blowing hydrogen
CN113699301B (en) Converter smelting method for improving energy production by adopting high-flow oxygen
CN114317871B (en) Method for reducing TFe content in converter final slag
CN113136476A (en) Slag-removing smelting method for waste steel
CN116287531A (en) Smelting process of vanadium-containing molten iron converter
CN115261549B (en) Control method for 150t converter high-phosphorus high-silicon single slag model
CN114427015B (en) Integrated method for controlling stability of converter high molten iron ratio smelting process
CN115679032B (en) Converter steelmaking method for single-slag deep desulfurization
CN111334639B (en) Method for promoting vanadium extraction and carbon conservation by using CO
CN113774189B (en) Steelmaking method suitable for producing high-strength steel on CSP production line

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination