CN116573880A - High-performance admixture for sprayed concrete, application and concrete - Google Patents

High-performance admixture for sprayed concrete, application and concrete Download PDF

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Publication number
CN116573880A
CN116573880A CN202310560875.6A CN202310560875A CN116573880A CN 116573880 A CN116573880 A CN 116573880A CN 202310560875 A CN202310560875 A CN 202310560875A CN 116573880 A CN116573880 A CN 116573880A
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China
Prior art keywords
admixture
parts
performance
sprayed concrete
concrete
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Pending
Application number
CN202310560875.6A
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Chinese (zh)
Inventor
李志林
孙振平
耿瑶
田俊涛
林明卉
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Fluorine Industry Environmental Protection Technology Yunan Co ltd
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Fluorine Industry Environmental Protection Technology Yunan Co ltd
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Application filed by Fluorine Industry Environmental Protection Technology Yunan Co ltd filed Critical Fluorine Industry Environmental Protection Technology Yunan Co ltd
Priority to CN202310560875.6A priority Critical patent/CN116573880A/en
Publication of CN116573880A publication Critical patent/CN116573880A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00146Sprayable or pumpable mixtures
    • C04B2111/00155Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention provides a high-performance admixture for sprayed concrete, which comprises the following components in parts by mass: 60-65 parts of a first component and 35-40 parts of a second component. The first component comprises the following components in parts by weight: 60-70 parts of superfine mineral admixture, 15-20 parts of redispersible emulsion powder and 15-20 parts of guar gum. The second component comprises the following components in parts by mass: 50-70 parts of metakaolin and 30-50 parts of ground rice hull ash. The admixture for high-performance sprayed concrete improves the cohesiveness of the sprayed concrete, reduces the rebound rate, improves the one-time spraying thickness and the early strength of the sprayed concrete, and increases the compactness of the sprayed concrete. Meanwhile, the admixture for high-performance sprayed concrete improves the impermeability and durability of the sprayed concrete. The admixture for high-performance sprayed concrete has the advantages of simple production process and low raw material cost, and is suitable for large-scale production.

Description

High-performance admixture for sprayed concrete, application and concrete
Technical Field
The invention relates to the field of building materials, in particular to an admixture for high-performance sprayed concrete, application and concrete.
Background
The sprayed concrete is an important component of tunnel engineering, and the construction performance, the mechanical property and durability after setting and hardening, and the performance in the service process are important factors influencing the construction progress, the construction quality and the later use state of the tunnel engineering. Construction of sprayed concrete is divided into dry spraying construction and wet spraying construction according to whether water is added to concrete mixture before spraying for stirring. The dry spraying method is used for construction, and dust pollution is serious in the spraying construction process, so that the damage to constructors is large, and the dry spraying method is rarely used at present. The wet spraying method effectively reduces dust pollution in the spraying process, reduces the rebound rate of sprayed concrete and obviously improves the construction efficiency. Currently, wet-spraying construction has become a major construction method for tunnel shotcrete. However, due to the adaptability problems of the accelerator to other raw materials of concrete (such as cement, water reducer, pumping aid and aggregate) and the environment, the phenomena of high rebound rate, insufficient early strength of concrete and the like are still difficult to avoid in the construction process of spraying concrete by adopting a wet spraying method. These phenomena will seriously reduce the construction efficiency of the sprayed concrete, cause the waste of materials, and cause the engineering problems of shrinkage cracking, leakage and the like of the sprayed concrete structure. On the other hand, the conventional shotcrete only considers the compressive strength index requirement in the process of designing the mixing ratio, and hardly considers the durability index requirement, and all the problems need to be further solved.
Disclosure of Invention
In order to overcome the existing technology: 1. sometimes, the phenomena of high rebound rate, insufficient early strength of concrete and the like are still difficult to avoid. 2. The invention aims to provide a high-performance admixture for sprayed concrete, which only considers the compressive strength index requirement and does not consider the problem of the durability index requirement, and comprises the following components in parts by mass: 60-65 parts of a first component and 35-40 parts of a second component. The first component comprises the following components in parts by weight: 60-70 parts of superfine mineral admixture, 15-20 parts of redispersible emulsion powder and 15-20 parts of guar gum. The second component comprises the following components in parts by mass: 50-70 parts of metakaolin and 30-50 parts of ground rice hull ash.
Exemplary of the inventionThere is provided an ultra-fine mineral admixture comprising: at least one of silica fume and superfine slag powder, and the particle size d of the superfine mineral admixture 50 ≤5μm。
The invention provides redispersible emulsion powder, which comprises the following components: at least one of 5010N-type redispersible emulsion powder and 5024N-type redispersible emulsion powder.
The invention provides guar gum, which is characterized in that: white to yellow instant powder, and when the guar gum is dissolved in water to form a solution with the mass fraction of 1%, the apparent viscosity of the guar gum is more than or equal to 6000 mPa.s.
The invention provides metakaolin, which is prepared from the following components in percentage by weight: powdery particles with the particle size d50 less than or equal to 5 mu m.
The invention provides a preparation method of metakaolin, which comprises the following steps: calcining kaolin at 800-900 ℃ for 2-3h, cooling, grinding, and screening the product with the target particle size.
The invention provides an exemplary method for grinding rice hull ash, which comprises the following steps: and d50 is less than or equal to 5 mu m, and 28d activity index is more than or equal to 85 percent.
The invention provides a preparation method of ground rice hull ash, which comprises the following steps: calcining rice husk at 600-700 deg.c for 2-3 hr, cooling, grinding and sieving to obtain the product with target grain size.
The second object of the present invention is to provide an application of the admixture for high-performance shotcrete, wherein the admixture is the admixture for high-performance shotcrete, and the admixture is applied to shotcrete; the high-performance admixture for sprayed concrete accounts for 5-10% of the mass of the concrete cementing material in the sprayed concrete.
The invention provides a method for using a high-performance admixture for sprayed concrete in sprayed concrete, which comprises the following steps: the concrete mixture is stirred for 3-5min, and then the admixture for high-performance sprayed concrete is mixed into the concrete mixture at a nozzle.
The invention further aims to provide concrete which comprises 5-10% of the admixture for the high-performance sprayed concrete, wherein the admixture is prepared by mixing the concrete cementing material with the admixture.
Compared with the prior art, the invention has at least one of the following beneficial effects:
1. the admixture for high-performance sprayed concrete improves the cohesiveness of the sprayed concrete, reduces the rebound rate and improves the one-time spraying thickness.
2. The admixture for high-performance sprayed concrete improves the early strength of the sprayed concrete and the compactness of the sprayed concrete.
3. The admixture for high-performance sprayed concrete improves the impermeability and durability of the sprayed concrete.
4. The admixture for high-performance sprayed concrete has the advantages of simple production process and low raw material cost, and is suitable for large-scale production.
Detailed Description
In order to make the technical problems, technical schemes and technical effects to be solved more clearly apparent, the technical schemes of the invention are clearly and completely described in detail below by combining with the embodiments. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention. Unless otherwise indicated, the starting materials and reagents used in the following examples were either commercially available or were prepared by known methods. In the following examples, unless otherwise indicated, raw material products or processing techniques are all typical commercial products or conventional processing techniques in the art.
In the following examples and comparative examples:
the superfine mineral admixture is as follows: particle diameter d 50 Silica fume of less than or equal to 5 mu m.
The redispersible emulsion powder comprises: 5010N type redispersible emulsion powder.
Guar gum is: white to yellow instant powder, and when the guar gum is dissolved in water to form a solution with the mass fraction of 1%, the apparent viscosity of the guar gum is more than or equal to 6000 mPa.s.
Metakaolin is: particle diameter d 50 Powdery particles less than or equal to 5 mu m, and the preparation method comprises the following steps: subjecting kaolin to a high temperature of 900 DEG CCalcining for 2h, cooling, grinding and screening the product with the target particle size.
The ground rice hull ash is as follows: particle diameter d 50 Powdery particles with an activity index of less than or equal to 5 mu m and 28d of more than or equal to 85 percent are prepared by the following steps: calcining rice husk at 700 deg.c for 2 hr, cooling, grinding and sieving to obtain the product with target grain size.
The cement is as follows: conch brand P.O 42.5.5 cement.
The sand is as follows: ordinary river sand with fineness modulus of 2.6.
The stone is as follows: crushed stone with the grain diameter of 5-15 mm.
The water reducer is as follows: polycarboxylic acid water reducer.
The accelerator is as follows: commercially available alkali-free liquid accelerator.
Example 1
The admixture for the high-performance sprayed concrete comprises the following components in parts by mass: 60 parts of a first component and 40 parts of a second component. The first component comprises the following components in parts by weight: 60 parts of superfine mineral admixture, 20 parts of redispersible emulsion powder and 20 parts of guar gum. The second component comprises the following components in parts by mass: 50 parts of metakaolin and 50 parts of ground rice hull ash.
Test pieces were prepared according to the compounding ratios in the following table.
The preparation method of the test piece comprises the following steps:
s1, mixing P.O 42.5.5 cement, fly ash, sand, stone, water and a water reducing agent according to a proportion and stirring for 3min.
S2, the admixture for high-performance sprayed concrete obtained in the embodiment is mixed into a concrete mixture at a nozzle.
S3, when the product is manufactured, an accelerator is added at the nozzle, wherein the mixing amount of the accelerator is 7% of the total mass of all cementing materials (cement, fly ash and admixture for high-performance sprayed concrete).
Example 2
The admixture for the high-performance sprayed concrete comprises the following components in parts by mass: 65 parts of the first component and 35 parts of the second component. The first component comprises the following components in parts by weight: 70 parts of superfine mineral admixture, 15 parts of redispersible emulsion powder and 15 parts of guar gum. The second component comprises the following components in parts by mass: 70 parts of metakaolin and 30 parts of ground rice hull ash.
Test pieces were prepared according to the compounding ratios in the following table.
The preparation method of the test piece comprises the following steps:
s1, mixing P.O 42.5.5 cement, fly ash, sand, stone, water and a water reducing agent according to a proportion and stirring for 3min.
S2, the admixture for high-performance sprayed concrete obtained in the embodiment is mixed into a concrete mixture at a nozzle.
S3, when the product is manufactured, an accelerator is added at the nozzle, wherein the mixing amount of the accelerator is 7% of the total mass of all cementing materials (cement, fly ash and admixture for high-performance sprayed concrete).
Example 3
The admixture for the high-performance sprayed concrete comprises the following components in parts by mass: 63 parts of first component and 37 parts of second component. The first component comprises the following components in parts by weight: 64 parts of superfine mineral admixture, 17 parts of redispersible emulsion powder and 19 parts of guar gum. The second component comprises the following components in parts by mass: 60 parts of metakaolin and 40 parts of ground rice hull ash.
Test pieces were prepared according to the compounding ratios in the following table.
The preparation method of the test piece comprises the following steps:
s1, mixing P.O 42.5.5 cement, fly ash, sand, stone, water and a water reducing agent according to a proportion and stirring for 3min.
S2, the admixture for high-performance sprayed concrete obtained in the embodiment is mixed into a concrete mixture at a nozzle.
S3, when the product is manufactured, an accelerator is added at the nozzle, wherein the mixing amount of the accelerator is 7% of the total mass of all cementing materials (cement, fly ash and admixture for high-performance sprayed concrete).
Comparative example 1
Test pieces were prepared according to the compounding ratios in the following table.
The preparation method of the test piece comprises the following steps:
s1, mixing P.O 42.5.5 cement, fly ash, sand, stone, water and a water reducing agent according to a proportion and stirring for 3min.
S2, when the product is manufactured, an accelerator is added at the nozzle, wherein the mixing amount of the accelerator is 7% of the total mass of all cementing materials (cement, fly ash and admixture for high-performance sprayed concrete).
The above examples and comparative examples were tested using a wet spray technique, with the test section being a class iii surrounding rock. The test results are shown in the following table:
TABLE 1 results of Performance test of examples and comparative examples
As can be seen from the above table, examples 1 to 3, to which the inventive blend was added, all had significant improvements in sidewall rebound, dome rebound, 1d compressive strength and 28d barrier rating compared to comparative example 1, to which the inventive blend was not added, wherein: the sidewall rebound rate was reduced below 43.8% for comparative example 1, the dome rebound rate was reduced below 49.7% for comparative example 1, the 1d compressive strength was increased above 153.3% for comparative example 1, and the 28d permeation resistance rating was increased to P6.
The reason for this is that: in the invention, the silica fume and the superfine slag powder are common superfine mineral admixture which is filled in gaps formed by overlapping cement particles to play a role of a ball bearing; the main component of the redispersible emulsion powder is ethylene-polyvinyl acetate, and the redispersible emulsion powder is dispersed in water to enhance the liquid phase consistency; guar gum is a common tackifying and water-retaining component, and after being dissolved in water, the guar gum greatly increases the viscosity of water, so that concrete sprayed on a base layer is not easy to fall down, and the rebound rate is reduced. The metakaolin prepared by the method has high reactivity and obvious early strength effect. The finely ground rice hull ash prepared by the method not only utilizes agricultural solid waste, but also provides an active admixture with activity close to that of silica fume for concrete. Meanwhile, metakaolin reacts with calcium hydroxide which is a cement hydration product to form ettringite and hydrated calcium silicate, and rice hull ash reacts with calcium hydroxide which is a cement hydration product to form volcanic ash, and the formed product is mainly hydrated calcium silicate with low calcium-silicon ratio, and is filled in capillary holes, so that the strength of the slurry is improved, and the impermeability and erosion resistance of the slurry are greatly improved. The effect of the admixture of the invention is that the side wall rebound rate and the vault rebound rate are obviously reduced, and the 1d compressive strength and the impermeability are obviously improved after the admixture is added into concrete.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (10)

1. The admixture for the high-performance sprayed concrete is characterized by comprising the following components in parts by mass: 60-65 parts of a first component and 35-40 parts of a second component; the first component comprises the following components in parts by weight: 60-70 parts of superfine mineral admixture, 15-20 parts of redispersible emulsion powder and 15-20 parts of guar gum; the second component comprises the following components in parts by mass: 50-70 parts of metakaolin and 30-50 parts of ground rice hull ash.
2. The admixture for high performance shotcrete according to claim 1, wherein the ultra fine mineral admixture comprises: at least one of silica fume and superfine slag powder, and the particle size d of the superfine mineral admixture 50 ≤5μm。
3. The admixture for high-performance shotcrete according to claim 1, wherein the redispersible emulsion powder comprises: at least one of 5010N-type redispersible emulsion powder and 5024N-type redispersible emulsion powder.
4. The admixture for high performance shotcrete according to claim 1, wherein said guar gum is a white to yellow instant powder; when the guar gum is dissolved in water to form a solution with the mass fraction of 1%, the apparent viscosity of the guar gum is more than or equal to 6000 mPa.s.
5. The admixture for high performance shotcrete according to claim 1, wherein the metakaolin is: particle diameter d 50 Powdery particles less than or equal to 5 mu m.
6. The admixture for high-performance shotcrete according to claim 5, wherein the preparation method of metakaolin is as follows: calcining kaolin at 800-900 ℃ for 2-3h, cooling, grinding, and screening the product with the target particle size.
7. The admixture for high performance shotcrete according to claim 1, wherein the ground rice hull ash is: d, d 50 Powdery particles with an activity index of less than or equal to 5 mu m and 28d of more than or equal to 85 percent.
8. The admixture for high performance shotcrete according to claim 7, wherein the preparation method of the ground rice hull ash comprises the steps of: calcining rice husk at 600-700 deg.c for 2-3 hr, cooling, grinding and sieving to obtain the product with target grain size.
9. Use of the admixture for high-performance shotcrete according to any one of claims 1 to 8 in shotcrete; the high-performance admixture for sprayed concrete accounts for 5-10% of the mass of the concrete cementing material in the sprayed concrete.
10. A concrete characterized in that the concrete comprises 5-10% of the admixture for the high-performance sprayed concrete, wherein the admixture is the admixture for the high-performance sprayed concrete according to any one of claims 1-8.
CN202310560875.6A 2023-05-18 2023-05-18 High-performance admixture for sprayed concrete, application and concrete Pending CN116573880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310560875.6A CN116573880A (en) 2023-05-18 2023-05-18 High-performance admixture for sprayed concrete, application and concrete

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310560875.6A CN116573880A (en) 2023-05-18 2023-05-18 High-performance admixture for sprayed concrete, application and concrete

Publications (1)

Publication Number Publication Date
CN116573880A true CN116573880A (en) 2023-08-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN116573880A (en)

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