CN116554953A - Wear-resistant antifriction water-dispersible emulsion for titanium alloy surface and application method thereof - Google Patents
Wear-resistant antifriction water-dispersible emulsion for titanium alloy surface and application method thereof Download PDFInfo
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- CN116554953A CN116554953A CN202310495376.3A CN202310495376A CN116554953A CN 116554953 A CN116554953 A CN 116554953A CN 202310495376 A CN202310495376 A CN 202310495376A CN 116554953 A CN116554953 A CN 116554953A
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- 239000000839 emulsion Substances 0.000 title claims abstract description 66
- 229910001069 Ti alloy Inorganic materials 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 45
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 37
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 37
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 35
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 34
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 32
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 30
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 14
- 239000000243 solution Substances 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005461 lubrication Methods 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000003831 antifriction material Substances 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 101100175010 Caenorhabditis elegans gbf-1 gene Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021431 alpha silicon carbide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical group O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an antiwear antifriction aqueous dispersion emulsion for a titanium alloy surface, which comprises a cubic silicon carbide aqueous dispersion, a polyvinyl alcohol aqueous solution and a polytetrafluoroethylene aqueous emulsion, wherein the mass concentration of cubic silicon carbide in the cubic silicon carbide aqueous dispersion is 30%, the mass concentration of polyvinyl alcohol in the polyvinyl alcohol aqueous solution is 50%, the mass concentration of polytetrafluoroethylene in the polytetrafluoroethylene aqueous emulsion is 60%, the volume of each component of the aqueous dispersion is 20-30% of the cubic silicon carbide dispersion, 5-10% of the polyvinyl alcohol solution, 2-3% of the polytetrafluoroethylene emulsion and the balance of water. All materials used in the invention are in an aqueous emulsion state, and no organic solvent pollution exists. Has better and longer lubrication effect, the use method is very convenient, and complex equipment is not needed.
Description
Technical Field
The invention relates to the technical field of materials, in particular to an antiwear antifriction water dispersion emulsion for a titanium alloy surface and a use method thereof.
Background
The titanium alloy is widely applied to various fields of aerospace, navigation, automobiles, energy, chemical industry, biomedical use and the like. However, titanium alloys are not excellent in poor wear resistance and friction lubricity, limiting the field of application. Improving the frictional wear properties of titanium alloys has been a continuing effort by the skilled artisan.
The optimization of the sliding condition of the friction layer is a simple and practical wear-resistant antifriction technology. In recent years, some researchers at home and abroad have new knowledge when further exploring the dry sliding friction and wear performance of the titanium alloy, and under special conditions such as high temperature and high speed, an oxide-containing friction layer is formed on the surface of the titanium alloy, so that the titanium alloy has a protective effect, and the wear resistance of the titanium alloy is improved.
However, such protection is incomplete, e.g., such oxides must be formed under certain conditions, but hardly formed under conventional conditions; moreover, the formation of the friction layer is based on the consumption of the friction pair matrix material, which will cause abrasion of the material; more importantly, the antiwear properties of antiwear materials do not always reduce friction at the same time, resulting in insufficient lubrication.
Chinese patent CN 201611018013.7 is an antiwear antifriction material, which contains antiwear agent 33-83% and antifriction agent 17-67%. Wherein the antiwear agent is ferric oxide nano particles, and the antifriction agent is multilayer graphene. The two nano materials are mixed and stirred uniformly and then are directly added to the sliding interface of the titanium alloy component, so that the self-lubricating nano material containing the oxide can be formed. The method has the following defects: the antiwear material cannot be well distributed on the interface, and the multilayer graphene is used, so that the lubricating capability is insufficient, and the antifriction and antiwear functions cannot be continuously exerted.
Disclosure of Invention
In order to solve the technical problems, the invention discloses a novel titanium alloy surface wear-resistant antifriction water-dispersible emulsion and a use method thereof.
The technical scheme of the titanium alloy surface wear-resistant antifriction water-dispersible emulsion is as follows: the titanium alloy surface wear-resistant antifriction water-dispersible emulsion comprises a cubic silicon carbide aqueous dispersion, a polyvinyl alcohol aqueous solution and a polytetrafluoroethylene aqueous emulsion, wherein the mass concentration of cubic silicon carbide in the cubic silicon carbide aqueous dispersion is 30%, the mass concentration of polyvinyl alcohol in the polyvinyl alcohol aqueous solution is 50%, the mass concentration of polytetrafluoroethylene in the polytetrafluoroethylene aqueous emulsion is 60%, the volume of each component of the water-dispersible emulsion is 20-30 parts of cubic silicon carbide dispersion, 5-10 parts of polyvinyl alcohol solution, 2-3 parts of polytetrafluoroethylene emulsion and the balance of water.
The powder average particle diameter D50 of the cubic silicon carbide dispersion liquid is 50 nm.
The molecular weight of the polyvinyl alcohol is 12-15 ten thousand.
Preferably, the water-dispersible emulsion comprises 15% of cubic silicon carbide dispersion liquid, 7% of polyvinyl alcohol solution, 2.5% of polytetrafluoroethylene emulsion and the balance of water.
The invention also provides a use method of the titanium alloy surface wear-resistant antifriction water-dispersible emulsion, which uses the materials and comprises the following steps:
(1) Cleaning and degreasing the surface of the titanium alloy;
(2) Treating the titanium alloy by a silane coupling agent KH550, and drying for later use;
(3) Soaking the surface of the treated titanium alloy into the prepared emulsion;
(4) The immersed emulsion is dried and then used.
Preferably, the infiltration time is not less than 5 minutes.
Preferably, the drying temperature is 100-150 ℃.
Advantageous effects
All materials used in the invention are in an aqueous emulsion state, and no organic solvent pollution exists.
According to the invention, after the titanium alloy surface is soaked in the aqueous emulsion and dried, cubic silicon carbide is used as a wear-resistant material, polytetrafluoroethylene is used as a lubricating material, so that the titanium alloy surface can be better used for resisting wear and reducing friction, and polyvinyl alcohol is used as a filling material to fill gaps to play a role in auxiliary lubrication, and meanwhile, the coating powder can be adhered and coated, so that the acting time is prolonged.
Compared with other complex surface treatment methods, the invention has the advantages of convenient use method, no need of complex equipment and effective effect only by soaking and drying during construction.
Detailed Description
The following is a description of the technical solution of the present invention by taking specific embodiments as examples.
The following experiment adopts a cubic silicon carbide aqueous dispersion with the mass concentration of 30 percent, which is a standard product sold in the market, wherein the cubic silicon carbide, namely beta-SiC, belongs to a cubic crystal system (diamond crystal form), and has better friction resistance performance compared with common silicon carbide micro powder alpha-SiC, and the D50 is 50 and nm.
The adopted polyvinyl alcohol aqueous solution is a self-prepared polymer solution, the molecular weight of the polyvinyl alcohol is 12-15 ten thousand, the preparation method is that the polyvinyl alcohol with fixed weight is added, water is added according to the solid content proportion, the temperature of the water is heated to 95 ℃, and then the water is continuously stirred, and the polyethylene is dissolved in hot water, wherein the mass concentration is 50%.
The polytetrafluoroethylene aqueous emulsion is a commercially available standard product with the mass concentration of 60 percent.
Example 1
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 30 percent of cubic silicon carbide dispersion, 10 percent of polyvinyl alcohol solution, 2 percent of polytetrafluoroethylene emulsion and the balance of water.
Example 2
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 20 percent of cubic silicon carbide dispersion, 10 percent of polyvinyl alcohol solution, 3 percent of polytetrafluoroethylene emulsion and the balance of water.
Example 3
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 17 percent of the cubic silicon carbide dispersion, 4 percent of the polyvinyl alcohol solution, 2.5 percent of the polytetrafluoroethylene emulsion and the balance of water.
Example 4
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 15 percent of cubic silicon carbide dispersion, 7 percent of polyvinyl alcohol solution, 2.5 percent of polytetrafluoroethylene emulsion and the balance of water.
Comparative example 1
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 15 percent of the cubic silicon carbide dispersion, 7 percent of the polyvinyl alcohol solution and the balance of water.
Comparative example 2
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 7 percent of polyvinyl alcohol solution, 2.5 percent of polytetrafluoroethylene emulsion and the balance of water.
Comparative example 3
The wear-resistant antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises cubic silicon carbide aqueous dispersion, polyvinyl alcohol aqueous solution and polytetrafluoroethylene aqueous emulsion, wherein the volume content of each component of the aqueous dispersion emulsion is 15 percent of the cubic silicon carbide dispersion, 2.5 percent of the polytetrafluoroethylene emulsion and the balance of water.
The prepared anti-wear antifriction water-dispersible emulsion on the surface of the titanium alloy in the above examples and comparative examples is prepared for use, and when in use, the preparation method comprises the following steps:
(1) Cleaning and degreasing the surface of the titanium alloy;
(2) Treating the titanium alloy by a silane coupling agent KH550, and drying for later use;
(3) Soaking the surface of the treated titanium alloy into the prepared emulsion;
(4) The immersed emulsion is dried and then used.
The soaking time is not less than 5min, and the drying temperature is 100-150 ℃ after the soaking is finished.
The testing process comprises the following steps: the actual application effect of the invention in TC11 alloy in dry sliding friction and wear is tested by adopting an MPX-2000 type disc pin type friction and wear testing machine. The test specifications were determined as follows: the pin sample is TC11 alloy with phi 5 multiplied by 23 mm 2; the disk sample is GCr15 bearing steel with phi 34 multiplied by 10mm < 2 >, and the hardness is 50 HRC; the sliding speed is 0.5 m/s; the sliding distance is 800-4000 m, and the interval is 800 m; the load was 100N. The coefficient of friction value is automatically read out by the software matched with the testing machine at intervals of 0.001 s.
Conclusion of experimental results analysis:
in comparative example 2, when only polyvinyl alcohol and polytetrafluoroethylene were added, the abrasion rate of the TC11 alloy was higher than that in the case of no addition, and the friction coefficient was kept low for a very short period of time and then increased to the level in the case of no addition.
In comparative example 1, the abrasion rate was slightly lower than that of comparative example 2 when only cubic silicon carbide and polyvinyl alcohol were added, and the friction coefficient was raised to be high within a sliding distance of about 150 m and then lowered to a level when not added, rather than adding any material.
When the nano-hybrid material is added, the wear rate and friction coefficient remain extremely low over a range of sliding distances, and then rise. In particular, the wear rate and coefficient of friction remained extremely low up to 4000 m according to the formulation of example 4, which was additionally tested and found not to gradually start to rise until 8800 m. For this reason, when the nanomaterial is added, the titanium alloy surface will form a friction layer whose composition depends on the composition of the nanomaterial. The friction layer has no bearing capacity only by adding polytetrafluoroethylene, and the friction layer is destroyed in a short time. The friction layer has a certain bearing capacity but poor lubricity, which is shown by a high friction coefficient in a period of time when sliding starts, by adding cubic silicon carbide, so that the friction layer is broken in a short time under a high load of 100N due to shearing stress.
Comparative example 3 shows that both antifriction and antiwear components are added, but no polyvinyl alcohol is added, the gap between the two materials is free of fillers and fixtures, and the sustainability is insufficient, resulting in poor frictional wear properties of the alloy, and the wear rate gradually increases from 2000m over example 4.
When polyvinyl alcohol is added, the friction layer can be stably maintained for a long time under high load by filling and coating the friction layer between the two materials, the persistence is obviously enhanced, and the titanium alloy has more excellent friction and wear performance.
However, the friction reducing component is not as much as it is, and example 2 adds more polyvinyl alcohol, and the friction layer cannot improve the frictional wear properties of the titanium alloy because of its non-load bearing capacity. The proportion of antiwear component and antifriction material is therefore appropriate, and the lubricity is optimized only if the friction layer has sufficient load-bearing capacity. Therefore, the proportion of antifriction and antiwear components in the nano mixed material has a better range, and the comprehensive performance of wear resistance and friction resistance is better than that of example 3 and example 1 and is better than that of example 2. Embodiment 4 is the most preferred embodiment.
The above examples are of several preferred embodiments of the invention, the scope of which is defined by the claims.
Claims (7)
1. The anti-wear antifriction aqueous dispersion emulsion for the surface of the titanium alloy comprises a cubic silicon carbide aqueous dispersion, a polyvinyl alcohol aqueous solution and a polytetrafluoroethylene aqueous emulsion, wherein the mass concentration of cubic silicon carbide in the cubic silicon carbide aqueous dispersion is 30%, the mass concentration of polyvinyl alcohol in the polyvinyl alcohol aqueous solution is 50%, and the mass concentration of polytetrafluoroethylene in the polytetrafluoroethylene aqueous emulsion is 60%.
2. The titanium alloy surface wear-resistant antifriction water-dispersible emulsion of claim 1 wherein the powder average particle size D50 of the cubic silicon carbide dispersion is 50 nm.
3. The titanium alloy surface wear-resistant antifriction water-dispersible emulsion of claim 1 wherein the molecular weight of the polyvinyl alcohol is 12-15 ten thousand.
4. The titanium alloy surface wear-resistant antifriction water-dispersible emulsion of claim 1 wherein the volume content of the components of the water-dispersible emulsion is 15% cubic silicon carbide dispersion, 7% polyvinyl alcohol solution, 2.5% polytetrafluoroethylene emulsion and the balance water.
5. The use method of the titanium alloy surface wear-resistant antifriction water-dispersible emulsion is characterized by comprising the following steps of:
(1) Cleaning and degreasing the surface of the titanium alloy;
(2) Treating the titanium alloy by a silane coupling agent KH550, and drying for later use;
(3) Soaking the surface of the treated titanium alloy into the prepared emulsion;
(4) The immersed emulsion is dried and then used.
6. The method of using an antiwear antifriction water dispersion emulsion on a titanium alloy surface according to claim 5, wherein the soaking time is not less than 5 minutes.
7. The method for using the anti-wear antifriction water-dispersible emulsion on the surface of the titanium alloy according to claim 5, wherein the drying temperature is 100-150 ℃.
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刘建芳;顾卡丽;李健;: "聚四氟乙烯乳液对绿色水基润滑剂摩擦学性能的影响", 润滑与密封, no. 02, 15 February 2008 (2008-02-15) * |
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