CN116547141A - Composite glass pane with locally applied reflective layer - Google Patents

Composite glass pane with locally applied reflective layer Download PDF

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Publication number
CN116547141A
CN116547141A CN202280006008.1A CN202280006008A CN116547141A CN 116547141 A CN116547141 A CN 116547141A CN 202280006008 A CN202280006008 A CN 202280006008A CN 116547141 A CN116547141 A CN 116547141A
Authority
CN
China
Prior art keywords
glass pane
composite
vitreous
layer
pane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202280006008.1A
Other languages
Chinese (zh)
Inventor
A·戈默
V·舒尔茨
B·恩吉姆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Original Assignee
Saint Gobain Glass France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS filed Critical Saint Gobain Glass France SAS
Publication of CN116547141A publication Critical patent/CN116547141A/en
Pending legal-status Critical Current

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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/25Metals
    • C03C2217/251Al, Cu, Mg or noble metals
    • C03C2217/252Al
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/01Head-up displays
    • G02B27/0101Head-up displays characterised by optical features

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  • Optics & Photonics (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
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  • Ceramic Engineering (AREA)
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Abstract

The invention relates to a composite glass pane (100) comprising at least an outer glass pane (1), a thermoplastic interlayer (3), an inner glass pane (2), a masking layer (4) arranged in one region of the composite glass pane (100), an adhesive layer (5), a vitreous glass pane (6) having an outer side surface (V) and an inner side surface (VI) and having a thickness of 20 [ mu ] m to 500 [ mu ] m. The inner glass plate (2) is arranged between the outer glass plate (1) and the vitreous glass plate (6), the thermoplastic interlayer (3) is arranged between the outer glass plate (1) and the inner glass plate (2), the adhesive layer (5) is arranged between the inner glass plate (2) and the vitreous glass plate (6), the reflective layer (7) for reflecting light is arranged on the outer side surface (V) of the vitreous glass plate (6) and/or on the inner side surface (VI) of the vitreous glass plate (6), and the vitreous glass plate (6) is arranged in a region of the composite glass plate (100) which is entirely located in the region in which the masking layer (4) is arranged when seen vertically through the composite glass plate (100).

Description

具有局部施加的反射层的复合玻璃板Composite glass pane with locally applied reflective layer

本发明涉及具有局部施加的反射层的复合玻璃板、其制造方法及其用途以及投影装置。The invention relates to a composite glass pane with a locally applied reflective layer, a method for its production and its use as well as a projection device.

现代汽车越来越多地配备有所谓的平视显示器(HUD)。通过通常位于仪表板区域中的投影器,将图像投影到挡风玻璃板上,在那里被反射并被驾驶员感知为(从他的角度来看)挡风玻璃板后面的虚拟图像。因此,可以将重要信息投影到驾驶员的视野中,例如当前的行驶速度、导航或警告指示,驾驶员无需将视线从车道上移开即可感知这些信息。因此,平视显示器可以明显为提高交通安全做出贡献。Modern vehicles are increasingly equipped with so-called head-up displays (HUD). Via a projector, usually located in the dashboard area, an image is projected onto the windscreen panel, where it is reflected and perceived by the driver as (from his point of view) a virtual image behind the windscreen panel. Important information, such as current driving speed, navigation or warning indications, can thus be projected into the driver's field of vision and perceived without taking his eyes off the roadway. Head-up displays can therefore clearly contribute to improving traffic safety.

JP H09 43530 A、US 2009/295681 A1、WO 2021/145387A1、US 2019/285882A1、EP3 429 844 81和CN 113 238 377 A中公开了HUD投影装置。HUD projection devices are disclosed in JP H09 43530 A, US 2009/295681 A1, WO 2021/145387 A1, US 2019/285882 A1, EP3 429 844 81 and CN 113 238 377 A.

然而,平视显示器经常存在的问题是,被设置用于反射由投影器投影的光的挡风玻璃板区域必须具有通常至少70%的高透明度。因此,被反射的投影器的光与来自外部环境的光叠加,这根据光的条件会导致虚拟图像的对比度降低和因此导致驾驶员的视觉可感知性较差。在所有天气和光的条件下,都应保证尤其与安全相关的信息,例如车道辅助、速度显示或发动机转数的足够的视觉可感知性。因此会希望具有基于平视显示技术的投影装置,其中不出现不希望的副图像,并且其布置可以相对容易地实现,同时具有良好的可识别性以及所示图像信息的足够亮度和对比度。为了实现这一点,必须增加挡风玻璃板的反射区域中的对比度。对比度的增加例如可以通过使反射区域的背景大部分或完全不透明来实现。然而,这种解决方案要求仅在挡风玻璃板的局部有限区域中施加反射层。However, a frequent problem with head-up displays is that the area of the windshield panel which is arranged to reflect the light projected by the projector must have a high transparency, typically at least 70%. The reflected projector light is thus superimposed on the light from the external environment, which, depending on the light conditions, leads to a reduction in the contrast of the virtual image and thus to a poorer visual perception of the driver. Sufficient visual perceptibility of especially safety-relevant information such as lane assistance, speed display or engine speed should be ensured in all weather and light conditions. It would therefore be desirable to have a projection device based on head-up display technology in which no unwanted secondary images occur and whose arrangement can be realized relatively easily with good legibility and sufficient brightness and contrast of the displayed image information. In order to achieve this, the contrast in the reflective area of the windshield must be increased. An increase in contrast can be achieved, for example, by making the background of the reflective area mostly or completely opaque. However, this solution requires the application of the reflective layer only in locally limited areas of the windscreen.

金属反射涂层在玻璃质玻璃板上的施加通常通过溅射,特别是磁控管溅射来实现。在溅射中,原子通过离子轰击从靶材,例如金属材料中释放出来。使用物理气相沉积,在抽真空的腔室中对玻璃质玻璃板涂覆从靶材释放的原子。所述原子在此在电场的引导下穿过腔室移动到玻璃质玻璃板上。因此,它们从布置有靶材的阴极移动到阳极。由于在阴极和阳极之间布置玻璃质玻璃板,在玻璃质玻璃板上形成层。在磁控管溅射的情况下,在阴极后面布置额外的磁场,这导致更快的层生长和更致密的,即较低孔隙率的层。使用溅射来涂覆玻璃质玻璃板的方法例如从WO 9900528A1、DE 10126868C1和WO 2017198363A1中已知。The application of metallic reflective coatings on vitreous glass panes is usually achieved by sputtering, in particular magnetron sputtering. In sputtering, atoms are released from a target, such as a metallic material, by ion bombardment. Using physical vapor deposition, a vitreous glass plate is coated with atoms released from a target in an evacuated chamber. The atoms are moved through the chamber to the vitreous glass plate guided by the electric field. Thus, they move from the cathode, where the target is arranged, to the anode. Due to the arrangement of the vitreous glass plate between the cathode and the anode, layers are formed on the vitreous glass plate. In the case of magnetron sputtering, an additional magnetic field is arranged behind the cathode, which leads to faster layer growth and denser, ie lower porosity, layers. Methods for coating vitreous glass sheets using sputtering are known, for example, from WO 9900528A1, DE 10126868C1 and WO 2017198363A1.

磁控管溅射因此也适用于涂覆玻璃质玻璃板,因为与许多其它涂覆技术不同,其也可以用于弯曲的玻璃质玻璃板的情况,例如在被设置用于运载工具行业的玻璃板的情况中那样。然而,溅射的缺点是在没有特殊预防措施的情况下无法选择性地仅涂覆特定表面区域,而是总是只能涂覆整个表面。仅特定表面区域的选择性涂覆可以例如通过对不应被涂覆的区域进行复杂的掩蔽来实现。Magnetron sputtering is therefore also suitable for coating vitreous glass sheets because, unlike many other coating technologies, it can also be used in the case of curved vitreous glass sheets, e.g. as in the case of the board. However, sputtering has the disadvantage that it is not possible to selectively coat only specific surface areas without special precautions, but always only the entire surface. A selective coating of only certain surface regions can be achieved, for example, by complex masking of the regions that should not be coated.

冷气喷涂也适用于涂覆玻璃质玻璃板的方法,并且是本领域技术人员通常已知的涂覆方法,其中以非常高的速度将金属粉末施加到载体上。通过冷气喷涂进行涂覆的方法例如从WO 2010/003396A1、EP 3845685A1和EP 2 902 530 A1中已知。Cold air spraying is also suitable as a method of coating vitreous glass sheets and is a coating method generally known to those skilled in the art in which metal powder is applied to the support at very high speed. Methods of coating by cold-air spraying are known, for example, from WO 2010/003396 A1, EP 3845685 A1 and EP 2 902 530 A1.

WO 2019/186495A1公开了具有至少一个阶梯状功能区段的复合玻璃,其包括两个由组件制成的堆叠体,即其中不希望其性能发生变化的组件的主堆叠体以及包括功能层的第二组件堆叠体。所述功能层可以选自可切换膜、可切换层、显示器、照明装置、触敏层、传感器层、光传感器、声学传感器、声学PVB层、热反射膜和热吸收膜。WO 2019/186495 A1 discloses a composite glazing with at least one stepped functional section comprising two stacks made of components, namely a main stack of components whose properties are not desired to be altered and a second stack comprising functional layers Two-component stack. The functional layer may be selected from switchable films, switchable layers, displays, lighting devices, touch sensitive layers, sensor layers, light sensors, acoustic sensors, acoustic PVB layers, heat reflective films and heat absorbing films.

本发明的目的是提供具有局部施加的反射层的改进的复合玻璃板。特别地,复合玻璃板应易于制造。It is an object of the present invention to provide an improved composite glass pane with a locally applied reflective layer. In particular, the composite glass pane should be easy to manufacture.

根据本发明,本发明的目的通过根据权利要求1的复合玻璃板来实现。优选实施方案由从属权利要求中得出。According to the invention, the object of the invention is achieved by a composite glass pane according to claim 1 . Preferred embodiments emerge from the dependent claims.

根据本发明的复合玻璃板包括外玻璃板、热塑性中间层、掩蔽层、内玻璃板、胶粘层和玻璃质玻璃板。热塑性中间层布置在外玻璃板和内玻璃板之间,并且胶粘层布置在内玻璃板和玻璃质玻璃板之间。根据本发明,掩蔽层布置在复合玻璃板的一个区域中,并且玻璃质玻璃板布置在复合玻璃板的一个区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中。The composite glass pane according to the invention comprises an outer glass pane, a thermoplastic interlayer, a masking layer, an inner glass pane, an adhesive layer and a vitreous glass pane. A thermoplastic interlayer is arranged between the outer glass pane and the inner glass pane, and an adhesive layer is arranged between the inner glass pane and the vitreous glass pane. According to the invention, the masking layer is arranged in a region of the composite glass pane and the vitreous glass pane is arranged in a region of the composite glass pane which, when viewed perpendicularly through the composite glass pane, is completely located in the area in which the masking layer is arranged in the area.

复合玻璃板被设置用于在运载工具的窗户开口中将内部空间与外部环境隔开。在本发明的上下文中,内玻璃板是指复合玻璃板的面向运载工具内部空间的玻璃板。外玻璃板是指面向外部环境的玻璃板。Composite glass panels are provided to separate the interior space from the external environment in the window openings of the vehicle. In the context of the present invention, an inner glass pane refers to the glass pane of the composite glass pane facing the vehicle interior. The outer glass pane is the glass pane facing the external environment.

复合玻璃板特别是具有上边缘和下边缘,以及在其间延伸的两个侧边缘。上边缘是指被设置为在安装位置中指向上方的边缘。下边缘是指被设置为在安装位置中指向下方的边缘。在挡风玻璃板的情况下,上边缘通常称为顶边缘,并且下边缘称为发动机边缘。In particular, the laminated glass pane has an upper edge and a lower edge, as well as two side edges extending between them. By an upper edge is meant an edge which is arranged to point upwards in the installed position. The lower edge refers to the edge which is arranged to point downwards in the installed position. In the case of a windshield, the upper edge is usually called the top edge and the lower edge is called the engine edge.

外玻璃板、内玻璃板和玻璃质玻璃板各自具有外侧表面和内侧表面以及在其间延伸的环绕侧边缘。在本发明的上下文中,外侧表面是指被设置为在安装位置中面向外部环境的主表面。在本发明的上下文中,内侧表面是指被设置为在安装位置中面向内部空间的主表面。外玻璃板的内侧表面和内玻璃板的外侧表面彼此面对并且通过热塑性中间层彼此接合。The outer glass pane, the inner glass pane, and the vitreous glass pane each have an outer side surface and an inner side surface and a surrounding side edge extending therebetween. In the context of the present invention, an outer side surface refers to the main surface which is arranged to face the external environment in the installed position. In the context of the present invention, an inner side surface refers to the main surface which is arranged to face the inner space in the installed position. The inner side surface of the outer glass pane and the outer side surface of the inner glass pane face each other and are joined to each other by a thermoplastic interlayer.

外玻璃板的外侧表面称为I面。外玻璃板的内侧表面称为II面。内玻璃板的外侧表面称为III面。内玻璃板的内侧表面称为IV面。玻璃质玻璃板的外侧表面称为V面。玻璃质玻璃板的内侧表面称为VI面。The outside surface of the outer glass pane is called the I-plane. The inner surface of the outer glass sheet is called the II face. The outer surface of the inner pane is called the III plane. The inside surface of the inner glass sheet is called the IV face. The outer surface of the vitreous glass plate is called the V surface. The inner surface of the vitreous glass plate is called VI surface.

应理解的是,内玻璃板布置在外玻璃板和玻璃质玻璃板之间。外玻璃板的内侧表面和内玻璃板的外侧表面彼此面对。内玻璃板的内侧表面和玻璃质玻璃板的外侧表面彼此面对。It should be understood that the inner glass pane is arranged between the outer glass pane and the vitreous glass pane. The inner side surface of the outer glass sheet and the outer side surface of the inner glass sheet face each other. The inside surface of the inner glass sheet and the outside surface of the vitreous glass sheet face each other.

根据本发明,玻璃质玻璃板具有20μm(微米)至500μm的厚度。因此,玻璃质玻璃板是由超薄玻璃制成的玻璃板。这种由超薄玻璃制成的玻璃板是柔性的并且可以与玻璃板的弯曲相适配。According to the invention, the vitreous glass pane has a thickness of 20 μm (micrometer) to 500 μm. Therefore, a vitreous glass panel is a glass panel made of ultra-thin glass. This glass pane made of ultra-thin glass is flexible and adapts to the curvature of the glass pane.

此外,根据本发明,在玻璃质玻璃板的外侧表面上和/或在玻璃质玻璃板的内侧表面上布置用于反射光的反射层。Furthermore, according to the invention, a reflective layer for reflecting light is arranged on the outer surface of the vitreous pane and/or on the inner surface of the vitreous pane.

在复合玻璃板在运载工具中的安装位置中,反射层与掩蔽层相比具有与运载工具内部空间的更小距离。In the installed position of the composite glass pane in the vehicle, the reflective layer has a smaller distance from the vehicle interior than the masking layer.

由于玻璃质玻璃板布置在复合玻璃板的一个区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中,因此施加在该玻璃质玻璃板上的反射层也布置在这样的区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中。因此,反射层在透过复合玻璃板垂直透视时或在复合玻璃板上正交投影时被布置成与掩蔽层重叠或叠合。因此,反射层没有不与掩蔽层重叠的区段,即反射层仅被设计在看向复合玻璃板的内侧时位于掩蔽层前面的位置处。Since the vitreous glass pane is arranged in a region of the composite glass pane which, when viewed perpendicularly through the composite glass pane, lies entirely in the region in which the masking layer is arranged, the reflective layer applied to this vitreous glass pane also It is arranged in a region which, when viewed vertically through the laminated glass pane, lies entirely in the region in which the masking layer is arranged. Thus, the reflective layer is arranged to overlap or superpose the masking layer when viewed perpendicularly through the laminated glass pane or when projected orthogonally on the laminated glass pane. The reflective layer therefore has no sections which do not overlap the masking layer, ie the reflective layer is designed only at a position in front of the masking layer when looking towards the inside of the laminated glass pane.

在根据本发明的复合玻璃板的一个优选实施方案中,玻璃质玻璃板具有50μm至300μm,优选50μm至100μm,例如70μm的厚度。In a preferred embodiment of the composite glass pane according to the invention, the vitreous glass pane has a thickness of 50 μm to 300 μm, preferably 50 μm to 100 μm, for example 70 μm.

如上所述,反射层是用于反射光的反射层。反射层优选是不透光或部分透光的,这在本发明的上下文中意味着它在可见光谱范围内具有优选最多80%,特别优选最多50%,尤其是小于10%的平均透射率(根据ISO 9050:2003)。反射层优选反射至少10%,特别优选至少50%,非常特别优选至少80%,特别是至少90%的入射到反射层上的光。反射层优选等比例地反射p偏振光和s偏振光,但也可以不同程度地反射p偏振光和s偏振光。As described above, the reflective layer is a reflective layer for reflecting light. The reflective layer is preferably opaque or partially light-transmissive, which means in the context of the present invention that it has an average transmission in the visible spectral range of preferably at most 80%, particularly preferably at most 50%, especially less than 10% ( According to ISO 9050:2003). The reflective layer preferably reflects at least 10%, particularly preferably at least 50%, very particularly preferably at least 80%, in particular at least 90% of the light incident on the reflective layer. The reflective layer preferably reflects p-polarized light and s-polarized light in equal proportions, but may also reflect p-polarized light and s-polarized light in different degrees.

被反射层反射的光优选是可见光,即波长范围约380nm至780nm的光。对于p偏振和/或s偏振辐射,反射层优选具有高且均匀的反射率(在不同的入射角下),从而确保高强度和颜色中性的图像显示。The light reflected by the reflective layer is preferably visible light, ie light in the wavelength range of about 380nm to 780nm. The reflective layer preferably has a high and uniform reflectivity (at different angles of incidence) for p-polarized and/or s-polarized radiation, thus ensuring a high-intensity and color-neutral image display.

在此,偏振方向的说明是指辐射在复合玻璃板上的入射平面。p偏振辐射是其电场在入射平面内振荡的辐射。s偏振辐射是其电场垂直于入射平面振荡的辐射。入射平面由入射矢量和在受照射区域的几何中心处复合玻璃板的面法线撑开。In this case, the specification of the polarization direction refers to the plane of incidence of the radiation on the composite glass pane. P-polarized radiation is radiation whose electric field oscillates in the plane of incidence. S-polarized radiation is radiation whose electric field oscillates perpendicular to the plane of incidence. The plane of incidence is spanned by the incident vector and the surface normal of the composite glass pane at the geometric center of the illuminated area.

换句话说,偏振,即特别是p和s偏振辐射的比例,在被图像显示装置照射的区域中的点处确定,优选在受照射区域的几何中心处。由于复合玻璃板可以是弯曲的(例如当其被设计为挡风玻璃板时),这影响图像显示装置辐射的入射平面,因此在其它区域中可能出现略微与其不同的偏振比例,这出于物理原因是不可避免的。In other words, the polarization, ie in particular the proportion of p- and s-polarized radiation, is determined at a point in the area illuminated by the image display device, preferably at the geometric center of the illuminated area. Since the composite glass pane can be curved (e.g. when it is designed as a windshield pane), which affects the plane of incidence of the radiation of the image display device, polarization ratios slightly different from it can occur in other areas, due to physical The reason is unavoidable.

在本发明的一个优选实施方案中,反射层是金属层,即包含金属或由金属组成的层。In a preferred embodiment of the invention, the reflective layer is a metallic layer, ie a layer comprising or consisting of metal.

反射层优选含有选自铝、镁、锡、铟、钛、钽、铌、镍、铜、铬、钴、铁、锰、锆、铈、钪、钇、银、金、铂和钯、钌的至少一种金属或其混合物。铝、钛和/或镍是优选的,因为它们可以具有对p偏振光或s偏振光的高反射率。特别优选铝。The reflective layer preferably contains elements selected from the group consisting of aluminum, magnesium, tin, indium, titanium, tantalum, niobium, nickel, copper, chromium, cobalt, iron, manganese, zirconium, cerium, scandium, yttrium, silver, gold, platinum and palladium, ruthenium At least one metal or a mixture thereof. Aluminum, titanium and/or nickel are preferred because they can have high reflectivity for p- or s-polarized light. Aluminum is particularly preferred.

反射层的厚度优选是10nm(纳米)至100μm(微米),特别优选50nm至50μm,特别是100nm至5μm。The thickness of the reflective layer is preferably 10 nm (nanometer) to 100 μm (micrometer), particularly preferably 50 nm to 50 μm, in particular 100 nm to 5 μm.

在本发明的一个特定实施方案中,反射层是包含薄层堆叠体,即薄单层的层序列的涂层。该薄层堆叠体包含一个或多个基于镍、钛和/或铝的导电层。基于镍、钛和/或铝的导电层赋予反射层基本的反射性能和此外IR反射效果和导电性。导电层基于镍、钛和/或铝形成。导电层优选含有至少90重量%的镍、钛和/或铝,特别优选至少99重量%的铝,非常特别优选至少99.9重量%的镍、钛和/或铝。基于铝、镍和/或钛的层可以具有掺杂物,例如钯、金、铜或银。基于铝、镍和/或钛的材料特别适用于反射光,特别优选p偏振光。在金属涂层中使用镍、钛和/或铝已被证明对光的反射特别有利。铝、镍和/或钛比许多其它金属,例如金或银明显便宜。薄层堆叠体的单层优选具有10nm至1μm的厚度。薄层堆叠体优选具有2至20个单层,尤其是5至10个单层。In a particular embodiment of the invention, the reflective layer is a coating comprising a layer sequence of thin layer stacks, ie thin individual layers. The thin-film stack comprises one or more electrically conductive layers based on nickel, titanium and/or aluminium. The conductive layer based on nickel, titanium and/or aluminum imparts substantially reflective properties to the reflective layer and furthermore an IR reflective effect and electrical conductivity. The conductive layer is formed based on nickel, titanium and/or aluminum. The electrically conductive layer preferably contains at least 90% by weight of nickel, titanium and/or aluminum, particularly preferably at least 99% by weight of aluminum, very particularly preferably at least 99.9% by weight of nickel, titanium and/or aluminum. Layers based on aluminum, nickel and/or titanium may have dopants such as palladium, gold, copper or silver. Materials based on aluminum, nickel and/or titanium are particularly suitable for reflecting light, particularly preferably p-polarized light. The use of nickel, titanium and/or aluminum in metallic coatings has proven to be particularly advantageous for the reflection of light. Aluminum, nickel and/or titanium are significantly cheaper than many other metals, such as gold or silver. The individual layers of the thin-layer stack preferably have a thickness of 10 nm to 1 μm. The thin-film stack preferably has 2 to 20 individual layers, in particular 5 to 10 individual layers.

如上所述,在根据本发明的复合玻璃板中,掩蔽层布置在复合玻璃板的一个区域中。掩蔽层优选布置在复合玻璃板的边缘区域中,该边缘区域通常与玻璃板的玻璃板边缘邻接。当复合玻璃板用作运载工具中的挡风玻璃板时,得出这种布置的巨大优点,因为掩蔽层布置在驾驶员的主透视区域之外的边缘区域中。As mentioned above, in the composite glass pane according to the invention, the masking layer is arranged in one region of the composite glass pane. The masking layer is preferably arranged in an edge region of the composite glass pane, which usually adjoins a pane edge of the glass pane. When the composite glass pane is used as a windshield pane in a vehicle, this arrangement yields great advantages, since the masking layer is arranged in the edge region outside the driver's main viewing area.

掩蔽层优选地至少沿着下边缘布置并且与下边缘邻接。在复合玻璃板的俯视图时,由此出现沿着下边缘布置的矩形不透明条带。The masking layer is preferably arranged at least along and adjoins the lower edge. In a plan view of the laminated glass pane, this results in a rectangular opaque strip arranged along the lower edge.

在根据本发明的复合玻璃板的一个特别优选的实施方案中,掩蔽层被设计成框架状环绕。在其中玻璃质玻璃板以及因此施加到其上的反射层与掩蔽层重叠布置的区段中,被设计成框架状的掩蔽层优选配备有加宽部,即具有比其它区段中更大的宽度(垂直于延伸的尺寸)。以这种方式,掩蔽层可以合适地与其上施加有反射层的玻璃质玻璃板的尺寸适配。In a particularly preferred embodiment of the composite glass pane according to the invention, the masking layer is designed as a frame-like circumference. In the section in which the vitreous glass panes and thus the reflective layer applied thereto are arranged one above the other, the masking layer, which is designed as a frame, is preferably equipped with a widening, ie has a larger diameter than in other sections. Width (the dimension perpendicular to the extension). In this way, the masking layer can be suitably adapted to the dimensions of the vitreous glass pane on which the reflective layer is applied.

在一个实施方案中,掩蔽层因此被设计成框架状环绕,并且特别是在与玻璃质玻璃板重叠的区段中具有比与其不同的区段中更大的宽度。In one embodiment, the masking layer is therefore designed frame-like surrounding and in particular has a greater width in the section overlapping the vitreous glass pane than in the section differing therefrom.

其上施加有反射层的玻璃质玻璃板优选具有基本上矩形的形状,其在靠近下边缘的区域中在两个侧边缘之间延伸。特别优选地,玻璃质玻璃板的边缘不到达侧边缘和下边缘,而是与其隔开例如2cm至5cm。The vitreous glass pane, on which the reflective layer is applied, preferably has an essentially rectangular shape, which extends between the two side edges in the region close to the lower edge. Particularly preferably, the edges of the vitreous pane do not reach the side and lower edges, but are spaced therefrom, for example by 2 cm to 5 cm.

本发明的上下文中的掩蔽层是防止透过复合玻璃板透视的层。在此,可见光谱的光的最多5%,优选最多2%,特别优选最多1%,特别是最多0.1%透过掩蔽层透射。因此,掩蔽层是不透明掩蔽层,优选黑色掩蔽层。A masking layer in the context of the present invention is a layer that prevents seeing through the laminated glass pane. In this case, at most 5%, preferably at most 2%, particularly preferably at most 1%, in particular at most 0.1%, of the light in the visible spectrum is transmitted through the masking layer. Thus, the masking layer is an opaque masking layer, preferably a black masking layer.

掩蔽层优选是由一个或多个层制成的涂层。替代地,掩蔽层也可以是热塑性中间层的着色区域。根据复合玻璃板的一个优选实施方案,掩蔽层由单层组成。这具有的优点是复合玻璃板的制造特别简单和成本有利,因为只需要设计用于掩蔽层的单层。The masking layer is preferably a coating made of one or more layers. Alternatively, the masking layer can also be a colored region of the thermoplastic intermediate layer. According to a preferred embodiment of the composite glass pane, the masking layer consists of a single layer. This has the advantage that the production of the composite glass pane is particularly simple and cost-effective, since only a single layer designed for the masking layer is required.

掩蔽层尤其是由深色,优选黑色的搪瓷制成的不透明覆盖印刷物。The masking layer is in particular an opaque covering print made of dark, preferably black, enamel.

在一个优选的实施方案中,掩蔽层被设计为布置在外玻璃板的内侧表面上的第一不透明覆盖印刷物,其尤其由深色,优选黑色的搪瓷制成。In a preferred embodiment, the masking layer is designed as a first opaque cover print arranged on the inside surface of the outer pane, which is made in particular of a dark, preferably black, enamel.

在一个替代性优选实施方案中,掩蔽层被设计为布置在内玻璃板的外侧表面上的第一不透明覆盖印刷物,其尤其由深色,优选黑色的搪瓷制成。In an alternative preferred embodiment, the masking layer is designed as a first opaque cover print arranged on the outer surface of the inner pane, which is made in particular of a dark, preferably black, enamel.

在一个替代性优选实施方案中,掩蔽层被设计为热塑性中间层的不透明着色区域。In an alternative preferred embodiment, the masking layer is designed as an opaque colored region of the thermoplastic interlayer.

在一个实施方案中,热塑性中间层被设计为一体的并且在一个区域中是不透明着色的。In one embodiment, the thermoplastic intermediate layer is designed in one piece and is opaquely colored in one region.

被设计为热塑性中间层的不透明着色区域的掩蔽层也可以通过使用由不透明热塑性膜和透明热塑性膜组成的热塑性中间层来实现。不透明热塑性膜和透明热塑性膜优选彼此偏移地布置,以使得这两个膜在透过复合玻璃板透视时不重叠。透明和不透明膜由相同的塑料组成或优选包含相同的塑料。可基于其形成不透明膜和透明膜的材料是也被描述用于热塑性中间层的那些材料。不透明膜优选是着色膜,其可以具有不同的颜色,特别是黑色。A masking layer designed as an opaque colored region of the thermoplastic interlayer can also be realized by using a thermoplastic interlayer consisting of an opaque thermoplastic film and a transparent thermoplastic film. The opaque thermoplastic film and the transparent thermoplastic film are preferably arranged offset from one another so that the two films do not overlap when viewed through the laminated glass pane. The transparent and opaque films consist of or preferably contain the same plastic. Materials upon which the opaque and transparent films can be formed are those materials which are also described for the thermoplastic interlayer. The opaque film is preferably a colored film, which can have different colors, especially black.

根据本发明的复合玻璃板可以还具有布置在内玻璃板的内侧表面上的第二不透明覆盖印刷物,特别是至少在其中布置有玻璃质玻璃板的区域中。通过内玻璃板的内侧表面上的这种覆盖印刷物,改进表面与胶粘层的粘附性能。第二不透明覆盖印刷物优选被设计为框架状。The composite glass pane according to the invention may also have a second opaque cover print arranged on the inner side surface of the inner glass pane, in particular at least in the region in which the vitreous glass pane is arranged. By such overprinting on the inside surface of the inner glass pane, the adhesion properties of the surface to the adhesive layer are improved. The second opaque cover print is preferably designed as a frame.

在根据本发明的复合玻璃板的一个优选实施方案中,在玻璃质玻璃板的内侧表面上布置用于反射光的反射层,并且在该反射层上布置保护层。In a preferred embodiment of the composite glass pane according to the invention, a reflective layer for reflecting light is arranged on the inside surface of the vitreous glass pane, and a protective layer is arranged on the reflective layer.

在根据本发明的复合玻璃板的另一个优选实施方案中,在玻璃质玻璃板的内侧表面上和在玻璃质玻璃板的外侧表面上都分别布置用于反射光的反射层,并且在布置在玻璃质玻璃板的内侧表面上的那个反射层上布置保护层。对于布置在玻璃质玻璃板的外侧表面上的反射层,不需要保护层,因为该反射层通过胶粘层与内玻璃板接合并因此受保护。然而,任选地,也可以在布置在玻璃质玻璃板的外侧表面上的反射层上布置保护层。In another preferred embodiment of the composite glass pane according to the invention, reflective layers for reflecting light are respectively arranged on the inner surface of the vitreous glass pane and on the outer surface of the vitreous glass pane, and A protective layer is arranged on the reflective layer on the inside surface of the vitreous glass pane. For the reflective layer arranged on the outer surface of the vitreous glass pane, no protective layer is required, since the reflective layer is bonded to the inner glass pane by the adhesive layer and thus protected. Optionally, however, a protective layer can also be arranged on the reflective layer arranged on the outer surface of the vitreous glass pane.

保护层优选是透明和平坦的,特别是全等地施加到反射层上。保护层优选是基于聚丙烯酸酯、聚肟、醇酸树脂、聚氨酯或其混合物的聚合物。保护层的厚度优选为50nm至10μm,更优选100nm至5μm。The protective layer is preferably transparent and flat, in particular applied congruently to the reflective layer. The protective layer is preferably a polymer based on polyacrylates, polyoximes, alkyds, polyurethanes or mixtures thereof. The thickness of the protective layer is preferably 50 nm to 10 μm, more preferably 100 nm to 5 μm.

保护层保护反射层免受诸如刮擦之类的机械损伤。它还可以用于增加反射层的耐久性。通过该保护层,随着时间的推移分离出较少金属颗粒,并且玻璃质玻璃板的反射层更长时间地保持其形状。The protective layer protects the reflective layer from mechanical damage such as scratches. It can also be used to increase the durability of the reflective layer. As a result of this protective layer, fewer metal particles are separated over time and the reflective layer of the vitreous pane retains its shape longer.

在本发明的一个特别优选的实施方案中,保护层是易清洁层和/或“防指纹”层。在本发明的上下文中的“易清洁层”是指保护层上的例如指纹、油渍和污垢颗粒形式的污垢可以通过使用布,优选超细纤维布从保护层上去除。因此,在清洁保护层时基本上避免溶解油脂或磨擦的清洁剂和溶剂,例如基于醇的那些。在本发明的上下文中,“防指纹”层是指附着在保护层上的指纹在视觉上几乎不可感知或根本无法感知的层。指纹尤其是指在触摸表面时可能残留在其上并产生不美观效果的人手指的含油脂成分。In a particularly preferred embodiment of the invention, the protective layer is an easy-to-clean layer and/or an "anti-fingerprint" layer. "Easy-clean layer" in the context of the present invention means that dirt on the protective layer in the form of eg fingerprints, oil stains and dirt particles can be removed from the protective layer by using a cloth, preferably a microfibre cloth. Therefore, basically avoid grease-dissolving or abrasive cleaners and solvents, such as those based on alcohol, when cleaning the protective layer. In the context of the present invention, an "anti-fingerprint" layer is a layer in which fingerprints adhering to the protective layer are hardly or not visually perceptible. Fingerprints in particular refer to the greasy composition of human fingers which may remain on surfaces when they are touched and produce unaesthetic effects.

优选地,胶粘层是热塑性层或光学透明胶粘剂(OCA)。Preferably, the adhesive layer is a thermoplastic layer or an optically clear adhesive (OCA).

合适的光学透明胶粘剂,所谓的光学透明胶粘剂(OCA)是本领域技术人员已知的。Suitable optically clear adhesives, so-called optically clear adhesives (OCAs), are known to those skilled in the art.

被设计为热塑性层的胶粘层包含至少一种热塑性聚合物,优选乙烯乙酸乙烯酯(EVA)、聚乙烯醇缩丁醛(PVB)或聚氨酯(PU)或其混合物或共聚物或衍生物,特别优选PVB。热塑性层通常由热塑性膜(接合膜)形成。热塑性层的厚度优选为0.2mm至2mm,特别优选0.3mm至1mm,例如760μm。热塑性层可由单个膜或多于一个膜形成。The adhesive layer designed as a thermoplastic layer comprises at least one thermoplastic polymer, preferably ethylene vinyl acetate (EVA), polyvinyl butyral (PVB) or polyurethane (PU) or mixtures or copolymers or derivatives thereof, Particular preference is given to PVB. The thermoplastic layer is generally formed of a thermoplastic film (bonding film). The thickness of the thermoplastic layer is preferably 0.2 mm to 2 mm, particularly preferably 0.3 mm to 1 mm, for example 760 μm. The thermoplastic layer can be formed from a single film or from more than one film.

复合玻璃板优选地在空间的一个或多个方向上弯曲,这对于机动车玻璃板是常见的,其中典型的曲率半径为约10cm至约40m。然而,复合玻璃板也可以是平坦的,例如如果它被设置为公共汽车、火车或拖拉机的玻璃板。The composite glass pane is preferably curved in one or more directions in space, as is common for automotive glass panes, with typical radii of curvature ranging from about 10 cm to about 40 m. However, the composite glass pane can also be flat, eg if it is provided as a glass pane for a bus, train or tractor.

用于将外玻璃板和内玻璃板接合的热塑性中间层包含至少一种热塑性聚合物,优选乙烯乙酸乙烯酯(EVA)、聚乙烯醇缩丁醛(PVB)或聚氨酯(PU)或其混合物或共聚物或衍生物,特别优选PVB。热塑性中间层典型地由热塑性膜(接合膜)形成。热塑性中间层的厚度优选为0.2mm至2mm,特别优选0.3mm至1mm,例如760μm。热塑性中间层可由单个膜或多于一个膜形成。热塑性中间层也可以是具有功能性能的膜,例如具有声学阻尼性能的膜。The thermoplastic interlayer for joining the outer and inner glass panes comprises at least one thermoplastic polymer, preferably ethylene vinyl acetate (EVA), polyvinyl butyral (PVB) or polyurethane (PU) or mixtures thereof or Copolymers or derivatives, PVB is particularly preferred. The thermoplastic interlayer is typically formed of a thermoplastic film (tie film). The thickness of the thermoplastic intermediate layer is preferably 0.2 mm to 2 mm, particularly preferably 0.3 mm to 1 mm, for example 760 μm. The thermoplastic interlayer can be formed from a single film or from more than one film. The thermoplastic interlayer may also be a film with functional properties, such as a film with acoustic damping properties.

外玻璃板和内玻璃板包含或优选由玻璃组成,特别优选平板玻璃、浮法玻璃、石英玻璃、硼硅酸盐玻璃、钠钙玻璃、铝硅酸盐玻璃或透明塑料,优选刚性透明塑料,特别是聚乙烯,聚丙烯、聚碳酸酯、聚甲基丙烯酸甲酯、聚苯乙烯、聚酰胺、聚酯、聚氯乙烯和/或它们的混合物。The outer and inner glass panes comprise or preferably consist of glass, particularly preferably flat glass, float glass, quartz glass, borosilicate glass, soda lime glass, aluminosilicate glass or transparent plastic, preferably rigid transparent plastic, In particular polyethylene, polypropylene, polycarbonate, polymethylmethacrylate, polystyrene, polyamide, polyester, polyvinyl chloride and/or mixtures thereof.

外玻璃板和内玻璃板可以是透明的和无色的,也可以是有色或着色的。在一个优选实施方案中,透过被设计为挡风玻璃板的复合玻璃板的总透射率在主透视区域中大于70%(光类型A)。术语总透射率基于由ECE-R 43,附录3,第9.1节规定的用于测试机动车玻璃板的透光率的方法。外玻璃板和内玻璃板可以彼此独立地是未预加应力、部分预加应力或预加应力的。如果这些玻璃板的至少一个应具有预应力,则这可以是热或化学预应力。The outer and inner glass panes can be clear and colorless, tinted or tinted. In a preferred embodiment, the total transmission through the composite glass pane designed as a windshield pane is greater than 70% in the main perspective area (light type A). The term total transmittance is based on the method specified by ECE-R 43, Appendix 3, Section 9.1 for testing the light transmittance of glass panels for motor vehicles. The outer glass pane and the inner glass pane can be non-prestressed, partially prestressed or prestressed independently of each other. If at least one of the panes is to have a prestress, this can be thermal or chemical.

外玻璃板和内玻璃板的厚度可以宽泛地变化,因此在各个情况中与要求适配。外玻璃板和内玻璃板的厚度优选为0.5mm至5mm,特别优选1mm至3mm,非常特别优选1.6mm至2.1mm。例如,外玻璃板的厚度为2.1mm,内玻璃板的厚度为1.6mm。然而,外玻璃板或特别是内玻璃板也可以是厚度例如0.55mm的薄玻璃。The thickness of the outer glass pane and the inner glass pane can vary widely and is therefore adapted to the requirements in each case. The thickness of the outer and inner glass panes is preferably 0.5 mm to 5 mm, particularly preferably 1 mm to 3 mm, very particularly preferably 1.6 mm to 2.1 mm. For example, the thickness of the outer glass plate is 2.1 mm and the thickness of the inner glass plate is 1.6 mm. However, the outer glass pane or in particular the inner glass pane can also be thin glass with a thickness of eg 0.55 mm.

玻璃质玻璃板优选包含铝硅酸盐玻璃、硼硅酸盐玻璃、铝硼硅酸盐玻璃或由其组成。玻璃质玻璃板可以是预加应力、部分预加应力或未预加应力的。The vitreous glass pane preferably comprises or consists of aluminosilicate glass, borosilicate glass, aluminoborosilicate glass. Vitreous glass sheets may be prestressed, partially prestressed or not prestressed.

根据本发明的复合玻璃板可包含一个或多个额外的中间层,特别是功能性中间层。所述额外的中间层尤其可以是具有声学阻尼性能的中间层、反射红外辐射的中间层、吸收红外辐射的中间层、吸收UV辐射的中间层、至少局部着色的中间层和/或至少局部有色的中间层。如果存在多个额外的中间层,它们也可以具有不同的功能。The composite glass pane according to the invention may comprise one or more additional interlayers, in particular functional interlayers. The additional intermediate layer can in particular be an intermediate layer with acoustic damping properties, an intermediate layer reflecting infrared radiation, an intermediate layer absorbing infrared radiation, an intermediate layer absorbing UV radiation, an at least partially colored intermediate layer and/or an at least partially colored the middle layer. If multiple additional intermediate layers are present, they can also have different functions.

本发明还涉及至少包括根据本发明的复合玻璃板和指向反射层的成像单元的投影装置。The invention also relates to a projection device comprising at least a composite glass pane according to the invention and an imaging unit directed towards a reflective layer.

因此,根据本发明还有投影装置,其至少包括Therefore, according to the invention there is also a projection device comprising at least

-复合玻璃板,其至少包括具有外侧表面和内侧表面的外玻璃板、热塑性中间层、具有外侧表面和内侧表面的内玻璃板、在外玻璃板和内玻璃板之间布置在复合玻璃板的一个区域中的掩蔽层、胶粘层和具有外侧表面和内侧表面且厚度为20μm至500μm的玻璃质玻璃板,- a composite glass pane comprising at least an outer glass pane with an outer side surface and an inner side surface, a thermoplastic interlayer, an inner glass pane with an outer side surface and an inner side surface, one of the composite glass panes arranged between the outer glass pane and the inner glass pane A masking layer, an adhesive layer and a vitreous glass sheet having an outer surface and an inner surface and having a thickness of 20 μm to 500 μm in the region,

其中内玻璃板布置在外玻璃板和玻璃质玻璃板之间,热塑性中间层布置在外玻璃板和内玻璃板之间,胶粘层布置在内玻璃板和玻璃质玻璃板之间,在玻璃质玻璃板的外侧表面上和/或在玻璃质玻璃板的内侧表面上布置用于反射光的反射层,The inner glass plate is arranged between the outer glass plate and the vitreous glass plate, the thermoplastic interlayer is arranged between the outer glass plate and the inner glass plate, the adhesive layer is arranged between the inner glass plate and the vitreous glass plate, and the vitreous glass a reflective layer for reflecting light is arranged on the outer surface of the plate and/or on the inner surface of the vitreous glass plate,

并且其中玻璃质玻璃板布置在复合玻璃板的一个区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中,and wherein the vitreous glass pane is arranged in a region of the composite glass pane which, when viewed vertically through the composite glass pane, lies entirely in the region in which the masking layer is arranged,

-以及指向反射层的成像单元。- and an imaging unit directed towards the reflective layer.

特别地,反射层与从运载工具乘员的角度来看位于其后方的掩蔽层的组合导致在根据本发明的投影装置中图像的良好可见度,即使在外部太阳辐射的情况下和在使用弱光成像单元时也是如此。即使在这些情况下,由成像单元形成的图像也显得明亮并且极好可识别。这使得能够降低成像单元的功率并因此降低能耗。In particular, the combination of the reflective layer with the masking layer located behind the vehicle occupant from the point of view of it leads to good visibility of the image in the projection device according to the invention, even in the case of external solar radiation and when using low-light imaging The same is true for units. Even in these cases, images formed by the imaging unit appear bright and are excellently recognizable. This makes it possible to reduce the power of the imaging unit and thus reduce energy consumption.

从运载工具乘员的角度来看,反射层在透过内玻璃板透视时在空间上布置在掩蔽层的前面。由此,其中布置有反射层的复合玻璃板的区域看起来不透明。表述“透过复合玻璃板透视时”是指从复合玻璃板的内侧表面开始透过复合玻璃板看。在本发明的上下文中,“在空间上前面”是指反射层被布置成在空间上比掩蔽层更远离外玻璃板的外侧表面。优选地,掩蔽层至少在与反射层重叠并且其中复合玻璃板用于显示图像的区域中加宽。这意味着,掩蔽层在该区域中在垂直于复合玻璃板的环绕边缘的最近区段观察时具有比其它区段中更大的宽度。由此,掩蔽层可以与反射层的尺寸适配。From the vehicle occupant's point of view, the reflective layer is spatially arranged in front of the masking layer when viewed through the inner glass pane. As a result, the region of the composite glass pane in which the reflective layer is arranged appears opaque. The expression "when seeing through the composite glass pane" means looking through the composite glass pane starting from the inside surface of the composite glass pane. In the context of the present invention, "spatially in front" means that the reflective layer is arranged spatially farther from the outer side surface of the outer glass pane than the masking layer. Preferably, the masking layer widens at least in the region overlapping the reflective layer and in which the composite glass pane is used to display an image. This means that the masking layer has a greater width in this region when viewed perpendicularly to the closest section of the surrounding edge of the laminated glass pane than in other sections. As a result, the masking layer can be adapted to the dimensions of the reflective layer.

投影装置的成像单元发射光,并布置在内玻璃板的内侧表面附近,以使得成像单元照射该表面,其中光被复合玻璃板的反射层反射。反射层优选反射至少10%,特别优选至少50%,非常特别优选至少80%,尤其是至少90%的射到反射层上的400nm至700nm波长范围内且55°至80°入射角的光。这对于实现由成像单元发射并在反射层上反射的图像的最大可能亮度而言是有利的。The imaging unit of the projection device emits light and is arranged near the inner surface of the inner glass pane so that the imaging unit illuminates the surface, wherein the light is reflected by the reflective layer of the composite glass pane. The reflective layer preferably reflects at least 10%, particularly preferably at least 50%, very particularly preferably at least 80%, especially at least 90% of the light incident on the reflective layer in the wavelength range from 400 nm to 700 nm and at an angle of incidence of 55° to 80°. This is advantageous for achieving the maximum possible brightness of the image emitted by the imaging unit and reflected on the reflective layer.

成像单元用于发射图像,因此也可称为投影器、显示装置或图像显示装置。例如,显示器或本领域技术人员已知的其它装置也可以用作成像单元。成像单元优选是显示器,特别优选LCD显示器、LED显示器、OLED显示器或电致发光显示器,特别是LCD显示器。显示器的安装高度低,因此容易且节省空间地集成到运载工具的仪表板中。此外,显示器比其它成像单元明显更节能地运行。在此,在根据本发明的反射层和位于其后的掩蔽层的组合中,显示器的相对较低的亮度是完全足够的。来自成像单元的辐射优选以55°至80°,优选62°至77°的入射角射到复合玻璃板上的反射层区域中。入射角是来自图像显示装置的辐射的入射矢量与反射层的几何中心处的面法线之间的角度。The imaging unit is used to emit an image, so it can also be called a projector, a display device or an image display device. For example, a display or other devices known to those skilled in the art may also be used as imaging unit. The imaging unit is preferably a display, particularly preferably an LCD display, LED display, OLED display or electroluminescent display, in particular an LCD display. The low installation height of the display allows easy and space-saving integration into the instrument panel of the vehicle. Furthermore, the display runs significantly more energy-efficient than other imaging units. In this case, the relatively low brightness of the display is entirely sufficient in the combination of the reflective layer according to the invention and the underlying masking layer. The radiation from the imaging unit impinges preferably at an angle of incidence of 55° to 80°, preferably 62° to 77°, into the region of the reflective layer on the laminated glass pane. The angle of incidence is the angle between the incident vector of radiation from the image display device and the surface normal at the geometric center of the reflective layer.

通过将反射层布置在胶粘到内玻璃板的内侧表面上且厚度为20μm至500μm的玻璃质玻璃板的外侧表面和/或内侧表面上,避免出现干扰性幻像。Interfering phantoms are avoided by arranging the reflective layer on the outer and/or inner surface of the vitreous glass pane glued to the inner surface of the inner glass pane and having a thickness of 20 μm to 500 μm.

在具有安置在玻璃质玻璃板的内侧表面上的反射层的投影装置中,所需的虚拟图像通过在反射层上的反射产生并且不出现幻像。In a projection device with a reflective layer arranged on the inner surface of a vitreous glass pane, the desired virtual image is produced by reflection on the reflective layer and no ghost images appear.

在具有安置在玻璃质玻璃板的外侧表面上的反射层的投影装置中,所需的虚拟图像通过在反射层上的反射产生,并且另外第二虚拟图像,所谓的幻像或“幻像”也通过在玻璃质玻璃板的内侧表面上的反射产生。In projection devices with a reflective layer arranged on the outer surface of a vitreous glass plate, the desired virtual image is produced by reflection on the reflective layer and additionally a second virtual image, the so-called phantom or "phantom" is also produced by Reflection on the inner surface of the vitreous glass pane occurs.

在具有安置在玻璃质玻璃板的外侧表面上的反射层和安置在玻璃质玻璃板的内侧表面上的反射层的投影装置中,第一虚拟图像通过在安置在玻璃质玻璃板的外侧表面上的反射层上的反射产生,并且另外第二虚拟图像在安置在玻璃质玻璃板的内侧表面上的反射层上产生。In a projection device having a reflective layer disposed on the outer surface of the vitreous glass plate and a reflective layer disposed on the inner surface of the vitreous glass plate, the first virtual image passes through the A reflection on the reflective layer of the vitreous glass pane is produced, and additionally a second virtual image is produced on the reflective layer disposed on the inner surface of the vitreous glass pane.

然而,在根据本发明的玻璃质玻璃板的低厚度下,第一虚拟图像和幻像之间或第一虚拟图像和第二虚拟图像之间的空间偏移足够小,以使得显得不具干扰性。该效果归因于人眼的典型角度视敏度:根据本发明的薄的玻璃质玻璃板导致的第一虚拟图像和幻像之间或第一虚拟图像和第二虚拟图像之间的偏移对于人眼而言不再可分辨。However, at the low thickness of the vitreous glass pane according to the invention, the spatial offset between the first virtual image and the phantom or between the first virtual image and the second virtual image is small enough to appear undisturbing. This effect is due to the typical angular visual acuity of the human eye: the shift between the first virtual image and the phantom or between the first virtual image and the second virtual image caused by the thin vitreous glass plate according to the invention is of great importance to the human eye. It is no longer discernible to the naked eye.

根据本发明的复合玻璃板的上述优选实施方案也相应地适用于包括根据本发明的复合玻璃板和成像单元的根据本发明的投影装置,反之亦然。The above-described preferred embodiments of the composite glass pane according to the invention also apply correspondingly to the projection device according to the invention comprising the composite glass pane according to the invention and an imaging unit, and vice versa.

根据本发明还有制造根据本发明的复合玻璃板的方法,其至少包括:Also according to the invention is a method for producing a composite glass pane according to the invention, which comprises at least:

a)提供由具有外侧表面和内侧表面的外玻璃板、热塑性中间层和具有外侧表面和内侧表面的内玻璃板制成的复合体,其中热塑性中间层布置在外玻璃板和内玻璃板之间,并且在外玻璃板和内玻璃板之间的一个区域中布置掩蔽层;a) providing a composite body made of an outer glass pane having an outer surface and an inner surface, a thermoplastic interlayer and an inner glass pane having an outer surface and an inner surface, wherein the thermoplastic interlayer is arranged between the outer glass pane and the inner glass pane, and a masking layer is arranged in a region between the outer glass pane and the inner glass pane;

b)提供具有外侧表面和内侧表面的玻璃质玻璃板,其中在玻璃质玻璃板的外侧表面上和/或在玻璃质玻璃板的内侧表面上布置用于反射光的反射层;b) providing a vitreous glass pane with an outer surface and an inner surface, wherein a reflective layer for reflecting light is arranged on the outer surface of the vitreous glass pane and/or on the inner surface of the vitreous glass pane;

c)通过胶粘层将玻璃质玻璃板与所述复合体的内玻璃板接合以形成复合玻璃板,以使得玻璃质玻璃板布置在复合玻璃板的一个区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中。c) joining the vitreous glass panes with the inner glass panes of the composite body by means of an adhesive layer to form a composite glass pane, such that the vitreous glass panes are arranged in a region of the composite glass panes that is visible through the composite glass Seen vertically, the plate lies entirely in the region in which the masking layer is arranged.

步骤a)和b)可以所示顺序、同时或以相反顺序进行。步骤c)在步骤a)和b)之后进行。Steps a) and b) can be carried out in the sequence indicated, simultaneously or in reverse order. Step c) is carried out after steps a) and b).

如上所述,玻璃质玻璃板布置在复合玻璃板的一个区域中,该区域在透过复合玻璃板垂直透视时完全位于其中布置有掩蔽层的区域中。因此,玻璃质玻璃板的外部尺寸小于复合玻璃板的外玻璃板和内玻璃板。在步骤b)中提供玻璃质玻璃板可以通过在具有所需尺寸的未涂覆玻璃质玻璃板的内侧表面和/或外侧表面的整面上施加反射层来进行。As already mentioned above, the vitreous glass pane is arranged in a region of the composite glass pane which, when viewed vertically through the composite glass pane, lies entirely in the region in which the masking layer is arranged. Thus, the outer dimensions of the vitreous glass pane are smaller than the outer and inner glass panes of the composite glass pane. The provision of the vitreous glass pane in step b) can be carried out by applying a reflective layer over the entire inner and/or outer surface of the uncoated vitreous glass pane of the desired dimensions.

替代地,在步骤b)中提供玻璃质玻璃板也可以通过下列方式进行,即在其在外部尺寸,即宽度和长度方面大于所需的未涂覆玻璃质玻璃板的内侧表面和/或外侧表面的整面上施加反射层,然后从这种经涂覆玻璃质玻璃板中例如通过激光切割方法切出具有所需尺寸的一部分。Alternatively, the provision of the vitreous glass pane in step b) can also be carried out in such a way that its outer dimensions, i.e. width and length, are larger than the desired inner surface and/or outer side of the uncoated vitreous glass pane A reflective layer is applied over the entire surface, and then a portion of the desired dimensions is cut out of this coated vitreous glass pane, for example by laser cutting.

通过配备有反射层的玻璃质玻璃板,反射层可以选择性地布置在复合玻璃板的一个区域中。With the vitreous glass pane provided with the reflective layer, the reflective layer can be selectively arranged in a region of the composite glass pane.

在步骤b)中提供玻璃质玻璃板还可以额外地包括将保护层施加到施加在内侧表面和/或外侧表面上的反射层上。保护层优选通过喷涂或喷射,例如使用压力雾化器,施加到反射层上。Providing the vitreous pane in step b) may additionally comprise applying a protective layer to the reflective layer applied on the inner side surface and/or the outer side surface. The protective layer is preferably applied to the reflective layer by spraying or spraying, for example using a pressure atomizer.

如果复合玻璃板应是弯曲的,则在步骤a)中提供复合体时使用弯曲的外玻璃板和弯曲的内玻璃板。具有反射层的玻璃质玻璃板由于玻璃质玻璃板的低厚度而具有柔性,并且在步骤c)中与复合体的弯曲的内玻璃板适配。这是根据本发明的方法的优点。在根据本发明的方法中,反射层的涂覆发生在平坦的基底上。If the composite glass panes are to be curved, a curved outer glass pane and a curved inner glass pane are used in step a) to provide the composite body. The vitreous pane with the reflective layer is flexible due to the low thickness of the vitreous pane and is adapted in step c) to the curved inner pane of the composite body. This is an advantage of the method according to the invention. In the method according to the invention, the application of the reflective layer takes place on a flat substrate.

可以通过本领域技术人员熟悉的层压方法在步骤a)中提供复合体。The composite body can be provided in step a) by lamination methods familiar to the person skilled in the art.

在步骤b)中提供玻璃质玻璃板时,可以通过通常已知的涂覆方法,例如磁控管溅射或冷气喷涂来施加反射层。When providing the vitreous glass pane in step b), the reflective layer can be applied by generally known coating methods, for example magnetron sputtering or cold gas spraying.

根据本发明的复合玻璃板的上述优选实施方案也相应地适用于制造根据本发明的复合玻璃板的方法。The above-described preferred embodiments of the composite glass pane according to the invention also apply correspondingly to the method for producing the composite glass pane according to the invention.

本发明还涉及根据本发明的复合玻璃板作为水陆空交通运输工具中,特别是机动车中的运载工具玻璃板,尤其是作为用于平视显示器的挡风玻璃板的用途。The invention also relates to the use of the composite glass pane according to the invention as a vehicle glass pane in water, land and air transport, in particular in motor vehicles, in particular as a windshield pane for a head-up display.

下面参考附图和实施例更详细地解释本发明。附图是示意图而不是按比例绘制的。附图不以任何方式限制本发明。The invention is explained in more detail below with reference to the drawings and examples. The drawings are schematic and not drawn to scale. The drawings do not limit the invention in any way.

其中:in:

图1显示了根据本发明的复合玻璃板的一个实施方案的俯视图,Figure 1 shows a top view of one embodiment of a composite glass pane according to the invention,

图2显示了穿过图1所示的实施方案的截面,Figure 2 shows a section through the embodiment shown in Figure 1,

图3显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 3 shows a section through another embodiment of a composite glass pane according to the invention,

图4显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 4 shows a section through another embodiment of a composite glass pane according to the invention,

图5显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 5 shows a section through another embodiment of a composite glass pane according to the invention,

图6显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 6 shows a section through another embodiment of a composite glass pane according to the invention,

图7显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 7 shows a section through another embodiment of a composite glass pane according to the invention,

图8显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 8 shows a section through another embodiment of a composite glass pane according to the invention,

图9显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 9 shows a section through another embodiment of a composite glass pane according to the invention,

图10显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 10 shows a section through another embodiment of a composite glass pane according to the invention,

图11显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 11 shows a section through another embodiment of a composite glass pane according to the invention,

图12显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 12 shows a section through another embodiment of a composite glass pane according to the invention,

图13显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 13 shows a section through another embodiment of a composite glass pane according to the invention,

图14显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 14 shows a section through another embodiment of a composite glass pane according to the invention,

图15显示了穿过根据本发明的复合玻璃板的另一个实施方案的截面,Figure 15 shows a section through another embodiment of a composite glass pane according to the invention,

图16显示了穿过根据本发明的投影装置的一个实施方案的截面,Figure 16 shows a section through an embodiment of a projection device according to the invention,

图17显示了根据本发明的复合玻璃板的另一个实施方案的俯视图,Figure 17 shows a top view of another embodiment of a composite glass pane according to the invention,

图18显示了穿过图17所示的实施方案的截面,并且Figure 18 shows a section through the embodiment shown in Figure 17, and

图19使用流程图显示了根据本发明的方法的一个实施例。Figure 19 shows an embodiment of the method according to the invention using a flowchart.

图1显示了根据本发明的复合玻璃板100的一个实施方案的俯视图,并且图2显示了沿切割线X-X′穿过图1所示的复合玻璃板100的截面。图1和图2所示的复合玻璃板100具有上边缘O、下边缘U和两个侧边缘S,并包括具有外侧表面I和内侧表面II的外玻璃板1、具有外侧表面III和内侧表面IV的内玻璃板2、热塑性中间层3、掩蔽层4、胶粘层5和具有外侧表面V和内侧表面VI的玻璃质玻璃板6。热塑性中间层3布置在外玻璃板1和内玻璃板2之间,内玻璃板2布置在外玻璃板1和玻璃质玻璃板6之间,并且胶粘层5布置在内玻璃板2和玻璃质玻璃板6之间。外玻璃板1、热塑性中间层3和内玻璃板2整面彼此叠置。掩蔽层4在外玻璃板1和内玻璃板2之间布置在复合玻璃板100的一个区域中。在图1和图2所示的实施方案中,掩蔽层4被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物并且仅布置在复合玻璃板100的与下边缘U邻接的边缘区域中。玻璃质玻璃板6布置在复合玻璃板100的一个区域中,该区域在透过复合玻璃板100垂直透视时完全位于其中布置有掩蔽层4的区域中。因此,玻璃质玻璃板6的外部尺寸小于内玻璃板2。玻璃质玻璃板6的外侧表面V通过胶粘层5与内玻璃板2的内侧表面IV接合。在图2所示的实施方案中,在玻璃质玻璃板6的内侧表面VI上布置用于反射光的反射层7。FIG. 1 shows a top view of one embodiment of a composite glass pane 100 according to the invention, and FIG. 2 shows a section through the composite glass pane 100 shown in FIG. 1 along cutting line X-X'. The composite glass pane 100 shown in FIGS. 1 and 2 has an upper edge O, a lower edge U and two side edges S and comprises an outer glass pane 1 with an outer surface I and an inner surface II, an outer surface III and an inner surface An inner glass pane 2 of IV, a thermoplastic interlayer 3, a masking layer 4, an adhesive layer 5 and a vitreous glass pane 6 having an outer surface V and an inner surface VI. The thermoplastic interlayer 3 is arranged between the outer glass pane 1 and the inner glass pane 2, the inner glass pane 2 is arranged between the outer glass pane 1 and the vitreous glass pane 6, and the adhesive layer 5 is arranged between the inner glass pane 2 and the vitreous glass between plates 6. The outer glass pane 1 , the thermoplastic interlayer 3 and the inner glass pane 2 lie on top of each other over the entire surface. The masking layer 4 is arranged in a region of the composite glass pane 100 between the outer glass pane 1 and the inner glass pane 2 . In the embodiment shown in FIGS. 1 and 2 , the masking layer 4 is designed as a first opaque cover print which is arranged on the inner side surface II of the outer glass pane 1 and is only arranged on the part of the composite glass pane 100 adjoining the lower edge U. in the edge area. The vitreous glass pane 6 is arranged in a region of the composite glass pane 100 which, when viewed vertically through the composite glass pane 100 , lies entirely in the region in which the masking layer 4 is arranged. The outer dimensions of the vitreous pane 6 are therefore smaller than the inner pane 2 . The outer surface V of the vitreous pane 6 is bonded to the inner surface IV of the inner pane 2 by means of an adhesive layer 5 . In the embodiment shown in FIG. 2 , a reflective layer 7 for reflecting light is arranged on the inner surface VI of the vitreous glass pane 6 .

玻璃质玻璃板6例如由铝硅酸盐玻璃组成并且具有70μm的厚度。热塑性中间层3包含例如PVB并且具有0.76mm的厚度。外玻璃板1例如由钠钙玻璃组成并且厚度为2.1mm。内玻璃板2例如由钠钙玻璃组成并且厚度为1.6mm。The vitreous glass pane 6 consists, for example, of aluminosilicate glass and has a thickness of 70 μm. The thermoplastic intermediate layer 3 comprises, for example, PVB and has a thickness of 0.76 mm. The outer glass pane 1 consists, for example, of soda lime glass and has a thickness of 2.1 mm. The inner pane 2 consists, for example, of soda lime glass and has a thickness of 1.6 mm.

胶粘层5例如是光学透明胶粘剂。The adhesive layer 5 is, for example, an optically transparent adhesive.

反射层7例如是厚度为100nm的金属层并含有铝。The reflective layer 7 is, for example, a metal layer with a thickness of 100 nm and contains aluminum.

在图1和2所示的实施方案中,掩蔽层4在复合玻璃板100的两个侧边缘S之间延伸,并且从复合玻璃板100的下边缘U开始例如具有30cm的宽度。In the embodiment shown in FIGS. 1 and 2 , the masking layer 4 extends between the two side edges S of the composite glass pane 100 and has, for example, a width of 30 cm starting from the lower edge U of the composite glass pane 100 .

应理解的是,复合玻璃板100可以具有各种任意合适的几何形状和/或曲率。通常,复合玻璃板100是弯曲的复合玻璃板。It should be understood that the composite glass pane 100 may have any suitable geometry and/or curvature. Typically, composite glass pane 100 is a curved composite glass pane.

图3显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图3中以截面显示的实施方案与图2中所示的实施方案的不同之处仅在于,此外在施加在玻璃质玻璃板6的内侧表面VI上的反射层7的整面上施加保护层8。保护层8例如是基于聚丙烯酸酯、聚肟、醇酸树脂、聚氨酯或其混合物的聚合物。保护层8例如具有500nm的厚度。FIG. 3 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 3 differs from the embodiment shown in FIG. 2 only in that a protective layer is additionally applied over the entire surface of the reflective layer 7 applied on the inner surface VI of the vitreous glass pane 6. 8. The protective layer 8 is, for example, a polymer based on polyacrylates, polyoximes, alkyds, polyurethanes or mixtures thereof. Protective layer 8 has a thickness of, for example, 500 nm.

图4显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图4中以截面显示的实施方案与图2所示的实施方案的不同之处仅在于,掩蔽层4不被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物,而是被设计为布置在内玻璃板2的外侧表面III上的第一不透明覆盖印刷物。FIG. 4 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 4 differs from the embodiment shown in FIG. 2 only in that the masking layer 4 is not designed as a first opaque cover print arranged on the inner side surface II of the outer glass pane 1, but Designed as a first opaque cover print arranged on the outer side surface III of the inner pane 2 .

图5显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图5中以截面显示的实施方案与图3中所示的实施方案的不同之处仅在于,掩蔽层4不被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物,而是被设计为布置在内玻璃板2的外侧表面III上的第一不透明覆盖印刷物。FIG. 5 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 5 differs from the embodiment shown in FIG. 3 only in that the masking layer 4 is not designed as a first opaque cover print arranged on the inner side surface II of the outer glass pane 1, but is a first opaque cover print designed to be placed on the outer side surface III of the inner glass pane 2 .

图6显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图6中以截面显示的实施方案与图2中所示的实施方案的不同之处仅在于,掩蔽层4不被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物,而是被设计为热塑性中间层3的不透明着色区域。FIG. 6 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 6 differs from the embodiment shown in FIG. 2 only in that the masking layer 4 is not designed as a first opaque covering print arranged on the inner side surface II of the outer glass pane 1, but is an opaque colored area designed as a thermoplastic interlayer 3 .

图7显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图7中以截面显示的实施方案与图3中所示的实施方案的不同之处仅在于,掩蔽层4不被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物,而是被设计为热塑性中间层3的不透明着色区域。FIG. 7 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 7 differs from the embodiment shown in FIG. 3 only in that the masking layer 4 is not designed as a first opaque covering print arranged on the inner side surface II of the outer glass pane 1, but is an opaque colored area designed as a thermoplastic interlayer 3 .

图8显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图8中以截面显示的实施方案与图2中所示的实施方案的不同之处仅在于,反射层7不布置在玻璃质玻璃板6的内侧表面VI上,而是布置在玻璃质玻璃板6的外侧表面V上。任选地,在该实施例中也可以此外在反射层7上与胶粘层5直接相邻地布置保护层。FIG. 8 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 8 differs from the embodiment shown in FIG. 2 only in that the reflective layer 7 is not arranged on the inner surface VI of the vitreous glass pane 6 but on the vitreous glass pane 6 on the outer surface V. Optionally, a protective layer can also be arranged directly adjacent to the adhesive layer 5 on the reflective layer 7 in this exemplary embodiment.

图9显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图9中以截面显示的实施方案与图2中所示的实施方案的不同之处仅在于,除了布置在玻璃质玻璃板6的内侧表面VI上的反射层7外,还在玻璃质玻璃板6的外侧表面V上布置反射层7。FIG. 9 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 9 differs from the embodiment shown in FIG. 2 only in that, in addition to the reflective layer 7 arranged on the inner surface VI of the vitreous glass pane 6 , the vitreous glass pane A reflective layer 7 is arranged on the outer surface V of 6 .

图10显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图10中以截面显示的实施方案与图9中所示的实施方案的不同之处仅在于,此外在施加在玻璃质玻璃板6的内侧表面VI上的反射层7上施加保护层8。保护层8例如是基于聚丙烯酸酯、聚肟、醇酸树脂、聚氨酯或其混合物的聚合物。保护层8具有例如500nm的厚度。任选地,在该实施方案中,此外可以在施加在玻璃质玻璃板6的外侧表面V上的反射层7上与胶粘层5直接邻接地布置另一保护层。FIG. 10 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 10 differs from the embodiment shown in FIG. 9 only in that a protective layer 8 is additionally applied on the reflective layer 7 applied on the inner surface VI of the vitreous pane 6 . The protective layer 8 is, for example, a polymer based on polyacrylates, polyoximes, alkyds, polyurethanes or mixtures thereof. Protective layer 8 has a thickness of, for example, 500 nm. Optionally, in this embodiment a further protective layer can additionally be arranged directly adjacent to the adhesive layer 5 on the reflective layer 7 applied on the outer surface V of the vitreous glass pane 6 .

图11显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图11中以截面显示的实施方案与图2中所示的实施方案的不同之处仅在于,复合玻璃板100此外具有施加在内玻璃板2的内侧表面IV上的第二不透明覆盖印刷物9。在图11所示的实施方案中,第二不透明覆盖印刷物9被设计成框架状。FIG. 11 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 11 differs from the embodiment shown in FIG. 2 only in that the composite glass pane 100 additionally has a second opaque cover print 9 applied on the inner side surface IV of the inner glass pane 2 . In the embodiment shown in FIG. 11 , the second opaque cover print 9 is designed as a frame.

图12显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图12中以截面显示的实施方案与图3中所示的实施方案的不同之处仅在于,复合玻璃板100此外具有施加在内玻璃板2的内侧表面VI上的第二不透明覆盖印刷物9。在图12所示的实施方案中,第二不透明覆盖印刷物9被设计成框架状。FIG. 12 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 12 differs from the embodiment shown in FIG. 3 only in that the composite glass pane 100 additionally has a second opaque cover print 9 applied on the inner side surface VI of the inner glass pane 2 . In the embodiment shown in FIG. 12, the second opaque cover print 9 is designed as a frame.

图13显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图13中以截面显示的实施方案与图8中所示的实施方案的不同之处仅在于,复合玻璃板100此外具有施加在内玻璃板2的内侧表面IV上的第二不透明覆盖印刷物9。在图13所示的实施方案中,第二不透明覆盖印刷物9被设计成框架状。FIG. 13 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 13 differs from the embodiment shown in FIG. 8 only in that the composite glass pane 100 additionally has a second opaque cover print 9 applied on the inner side surface IV of the inner glass pane 2 . In the embodiment shown in FIG. 13, the second opaque cover print 9 is designed as a frame.

图14显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图14中以截面显示的实施方案与图9中所示的实施方案的不同之处仅在于,复合玻璃板100此外具有施加在内玻璃板2的内侧表面IV上的第二不透明覆盖印刷物9。在图14所示的实施方案中,第二不透明覆盖印刷物9被设计成框架状。FIG. 14 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 14 differs from that shown in FIG. 9 only in that the composite glass pane 100 additionally has a second opaque cover print 9 applied on the inner side surface IV of the inner glass pane 2 . In the embodiment shown in FIG. 14, the second opaque cover print 9 is designed as a frame.

图15显示了穿过根据本发明的复合玻璃板100的另一个实施方案的截面。图15中以截面显示的实施方案与图10中所示的实施方案的不同之处仅在于,复合玻璃板100此外具有施加在内玻璃板2的内侧表面IV上的第二不透明覆盖印刷物9。在图15所示的实施方案中,第二不透明覆盖印刷物9被设计成框架状。FIG. 15 shows a section through another embodiment of a composite glass pane 100 according to the invention. The embodiment shown in section in FIG. 15 differs from the embodiment shown in FIG. 10 only in that the composite glass pane 100 additionally has a second opaque cover print 9 applied on the inner side surface IV of the inner glass pane 2 . In the embodiment shown in FIG. 15, the second opaque cover print 9 is designed as a frame.

图16显示了穿过根据本发明的投影装置101的一个实施方案的截面。图16所示的投影装置101包括复合玻璃板100和成像单元10。Figure 16 shows a section through an embodiment of a projection device 101 according to the invention. A projection device 101 shown in FIG. 16 includes a composite glass plate 100 and an imaging unit 10 .

复合玻璃板100如图2所示设计并包括具有外侧表面I和内侧表面II的外玻璃板1、具有外侧表面III和内侧表面IV的内玻璃板2、热塑性中间层3、掩蔽层4、胶粘层5和具有外侧表面V和内侧表面VI的玻璃质玻璃板6。热塑性中间层3布置在外玻璃板1和内玻璃板2之间,内玻璃板2布置在外玻璃板1和玻璃质玻璃板6之间,并且胶粘层5布置在内玻璃板2和玻璃质玻璃板6之间。外玻璃板1、热塑性中间层3和内玻璃板2整面地彼此叠置。掩蔽层4在外玻璃板1和内玻璃板2之间布置在复合玻璃板100的一个区域中。掩蔽层4被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物并且仅布置在复合玻璃板100的与下边缘邻接的边缘区域中。玻璃质玻璃板6布置在复合玻璃板100的一个区域中,该区域在透过复合玻璃板100垂直透视时完全位于其中布置有掩蔽层4的区域中。因此,玻璃质玻璃板6的外部尺寸小于内玻璃板2。玻璃质玻璃板6的外侧表面V通过胶粘层5与内玻璃板2的内侧表面IV接合。在图16所示的实施方案中,在玻璃质玻璃板6的内侧表面VI上布置用于反射光的反射层7。The composite glass pane 100 is designed as shown in FIG. 2 and comprises an outer glass pane 1 having an outer surface I and an inner surface II, an inner glass pane 2 having an outer surface III and an inner surface IV, a thermoplastic interlayer 3, a masking layer 4, glue An adhesive layer 5 and a vitreous glass pane 6 having an outer surface V and an inner surface VI. The thermoplastic interlayer 3 is arranged between the outer glass pane 1 and the inner glass pane 2, the inner glass pane 2 is arranged between the outer glass pane 1 and the vitreous glass pane 6, and the adhesive layer 5 is arranged between the inner glass pane 2 and the vitreous glass between plates 6. The outer glass pane 1 , the thermoplastic interlayer 3 and the inner glass pane 2 lie on top of each other over the entire surface. The masking layer 4 is arranged in a region of the composite glass pane 100 between the outer glass pane 1 and the inner glass pane 2 . The masking layer 4 is designed as a first opaque cover print which is arranged on the inner side surface II of the outer glass pane 1 and is only arranged in the edge region of the composite glass pane 100 adjoining the lower edge. The vitreous glass pane 6 is arranged in a region of the composite glass pane 100 which, when viewed vertically through the composite glass pane 100 , lies entirely in the region in which the masking layer 4 is arranged. The outer dimensions of the vitreous pane 6 are therefore smaller than the inner pane 2 . The outer surface V of the vitreous pane 6 is bonded to the inner surface IV of the inner pane 2 by means of an adhesive layer 5 . In the embodiment shown in FIG. 16 , a reflective layer 7 for reflecting light is arranged on the inner surface VI of the vitreous glass pane 6 .

玻璃质玻璃板6例如由铝硅酸盐玻璃组成并且具有70μm的厚度。热塑性中间层3包含例如PVB并且具有0.76mm的厚度。外玻璃板1例如由钠钙玻璃组成并且厚度为2.1mm。内玻璃板2例如由钠钙玻璃组成并且厚度为1.6mm。The vitreous glass pane 6 consists, for example, of aluminosilicate glass and has a thickness of 70 μm. The thermoplastic intermediate layer 3 comprises, for example, PVB and has a thickness of 0.76 mm. The outer glass pane 1 consists, for example, of soda lime glass and has a thickness of 2.1 mm. The inner pane 2 consists, for example, of soda lime glass and has a thickness of 1.6 mm.

胶粘层5例如是光学透明胶粘剂。The adhesive layer 5 is, for example, an optically transparent adhesive.

反射层7例如是厚度为100nm的金属层并含有铝。The reflective layer 7 is, for example, a metal layer with a thickness of 100 nm and contains aluminum.

例如,复合玻璃板100是机动车的挡风玻璃板。For example, the composite glass pane 100 is a windshield pane of a motor vehicle.

投影装置101具有成像单元10。成像单元10用于产生p偏振光和/或s偏振光(图像信息),其指向反射层7并被反射层7作为反射光反射到运载工具内部空间中,其可以在那里被观察者,例如驾驶员感知。反射层7被设计成适合于反射来自成像单元10的光,即由成像单元的光形成的图像。光优选地以55°至80°,特别是62°至77°的入射角射到反射层7上。成像单元10例如是显示器,特别是LCD显示器。The projection device 101 has an imaging unit 10 . The imaging unit 10 is used to generate p-polarized and/or s-polarized light (image information), which is directed towards the reflective layer 7 and is reflected by the reflective layer 7 as reflected light into the vehicle interior, where it can be viewed by an observer, e.g. driver perception. The reflective layer 7 is designed to be suitable for reflecting the light from the imaging unit 10, ie the image formed by the light of the imaging unit. The light impinges on reflective layer 7 preferably at an angle of incidence of 55° to 80°, in particular 62° to 77°. The imaging unit 10 is, for example, a display, in particular an LCD display.

图17显示了根据本发明的复合玻璃板100的一个实施方案的俯视图,并且图18显示了沿切割线Y-Y′穿过图17所示的复合玻璃板100的截面。图17和18所示的复合玻璃板100具有上边缘O、下边缘U和两个侧边缘S,并且包括具有外侧表面I和内侧表面II的外玻璃板1、具有外侧表面III和内侧表面IV的内玻璃板2、热塑性中间层3、掩蔽层4、胶粘层5和具有外侧表面V和内侧表面VI的玻璃质玻璃板6。热塑性中间层3布置在外玻璃板1和内玻璃板2之间,内玻璃板2布置在外玻璃板1和玻璃质玻璃板6之间,并且胶粘层5布置在内玻璃板2和玻璃质玻璃板6之间。外玻璃板1、热塑性中间层3和内玻璃板2整面地彼此叠置。掩蔽层4在外玻璃板1和内玻璃板2之间布置在复合玻璃板100的一个区域中。其中布置有掩蔽层4的区域配备有附图标记A。在图17和18所示的实施方案中,掩蔽层4被设计为布置在外玻璃板1的内侧表面II上的第一不透明覆盖印刷物并布置在环绕的边缘区域中,该边缘区域在与反射层7重叠的区段中具有比与其不同的区段中更大的宽度。为了简化显示,掩蔽层在图17中未显示为黑色,而是带图案的。玻璃质玻璃板6布置在复合玻璃板100的一个区域中,该区域在透过复合玻璃板100垂直透视时完全位于其中布置有掩蔽层4的区域中,并且在图17中配备有附图标记B。因此,玻璃质玻璃板6的外部尺寸小于内玻璃板2。玻璃质玻璃板6的外侧表面V通过胶粘层5与内玻璃板2的内侧表面IV接合。在图18所示的实施方案中,在玻璃质玻璃板6的内侧表面VI上布置用于反射光的反射层7。Figure 17 shows a top view of one embodiment of a composite glass pane 100 according to the present invention, and Figure 18 shows a section through the composite glass pane 100 shown in Figure 17 along cut line Y-Y'. The composite glass pane 100 shown in Figures 17 and 18 has an upper edge O, a lower edge U and two side edges S and comprises an outer glass pane 1 with an outer surface I and an inner surface II, an outer surface III and an inner surface IV An inner glass pane 2, a thermoplastic interlayer 3, a masking layer 4, an adhesive layer 5 and a vitreous glass pane 6 having an outer surface V and an inner surface VI. The thermoplastic interlayer 3 is arranged between the outer glass pane 1 and the inner glass pane 2, the inner glass pane 2 is arranged between the outer glass pane 1 and the vitreous glass pane 6, and the adhesive layer 5 is arranged between the inner glass pane 2 and the vitreous glass between plates 6. The outer glass pane 1 , the thermoplastic interlayer 3 and the inner glass pane 2 lie on top of each other over the entire surface. The masking layer 4 is arranged in a region of the composite glass pane 100 between the outer glass pane 1 and the inner glass pane 2 . The region in which the masking layer 4 is arranged is provided with the reference A. In the embodiment shown in FIGS. 17 and 18 , the masking layer 4 is designed as a first opaque cover print which is arranged on the inner side surface II of the outer glass pane 1 and is arranged in a surrounding edge region which is in contact with the reflective layer. 7 Overlapping segments have a greater width than segments differing therefrom. For simplicity of illustration, the masking layer is not shown black in Figure 17, but is patterned. The vitreous glass pane 6 is arranged in a region of the composite glass pane 100 which, when viewed vertically through the composite glass pane 100 , lies entirely in the region in which the masking layer 4 is arranged and is assigned the reference numerals in FIG. 17 b. The outer dimensions of the vitreous pane 6 are therefore smaller than the inner pane 2 . The outer surface V of the vitreous pane 6 is bonded to the inner surface IV of the inner pane 2 by means of an adhesive layer 5 . In the embodiment shown in FIG. 18 , a reflective layer 7 for reflecting light is arranged on the inner surface VI of the vitreous glass pane 6 .

玻璃质玻璃板6例如由铝硅酸盐玻璃组成并且具有70μm的厚度。热塑性中间层3包含例如PVB并且具有0.76mm的厚度。外玻璃板1例如由钠钙玻璃组成并且厚度为2.1mm。内玻璃板2例如由钠钙玻璃组成并且厚度为1.6mm。The vitreous glass pane 6 consists, for example, of aluminosilicate glass and has a thickness of 70 μm. The thermoplastic intermediate layer 3 comprises, for example, PVB and has a thickness of 0.76 mm. The outer glass pane 1 consists, for example, of soda lime glass and has a thickness of 2.1 mm. The inner pane 2 consists, for example, of soda lime glass and has a thickness of 1.6 mm.

胶粘层5例如是光学透明胶粘剂。The adhesive layer 5 is, for example, an optically transparent adhesive.

反射层7例如是厚度为100nm的金属层并含有铝。The reflective layer 7 is, for example, a metal layer with a thickness of 100 nm and contains aluminum.

应理解的是,复合玻璃板100可以具有各种任意合适的几何形状和/或曲率。通常,复合玻璃板100是弯曲的复合玻璃板。It should be understood that the composite glass pane 100 may have any suitable geometry and/or curvature. Typically, composite glass pane 100 is a curved composite glass pane.

图19使用流程图显示了根据本发明的方法的一个实施例。Figure 19 shows an embodiment of the method according to the invention using a flowchart.

在第一步骤S1中,提供由具有外侧表面I和内侧表面II的外玻璃板1、热塑性中间层3和具有外侧表面III和内侧表面IV的内玻璃板2制成的复合体,其中热塑性中间层3布置在外玻璃板1和内玻璃板2之间,并且在外玻璃板1和内玻璃板2之间的一个区域中布置掩蔽层4。In a first step S1, a composite body is provided made of an outer glass pane 1 having an outer surface I and an inner surface II, a thermoplastic interlayer 3 and an inner glass pane 2 having an outer surface III and an inner surface IV, wherein the thermoplastic interlayer A layer 3 is arranged between the outer glass pane 1 and the inner glass pane 2 and a masking layer 4 is arranged in a region between the outer glass pane 1 and the inner glass pane 2 .

在第二步骤S2中,提供具有外侧表面V和内侧表面VI的玻璃质玻璃板6,其中在玻璃质玻璃板6的外侧表面V上和/或在玻璃质玻璃板6的内侧表面VI上布置用于反射光的反射层7。In a second step S2, a vitreous glass pane 6 is provided having an outer surface V and an inner surface VI, wherein on the outer surface V of the vitreous glass pane 6 and/or on the inner surface VI of the vitreous glass pane 6 is arranged A reflective layer 7 for reflecting light.

在第三步骤S3中,玻璃质玻璃板6通过胶粘层5与复合体的内玻璃板2接合以形成复合玻璃板100,以使得玻璃质玻璃板6布置在复合玻璃板100的一个区域中,该区域在透过复合玻璃板100垂直透视时完全位于其中布置有掩蔽层4的区域中。In a third step S3, the vitreous glass pane 6 is bonded to the inner glass pane 2 of the composite body via an adhesive layer 5 to form a composite glass pane 100 such that the vitreous glass pane 6 is arranged in one region of the composite glass pane 100 , this region, when viewed vertically through the composite glass pane 100 , lies entirely in the region in which the masking layer 4 is arranged.

步骤S1和S2也可以相反的顺序或同时进行。Steps S1 and S2 can also be performed in reverse order or simultaneously.

附图标记列表:List of reference signs:

100 复合玻璃板100 composite glass panels

101 投影装置101 projection device

1 外玻璃板1 outer glass panel

2 内玻璃板2 inner glass panels

3 热塑性中间层3 thermoplastic interlayer

4 掩蔽层4 masking layer

5 胶粘层5 adhesive layer

6 玻璃质玻璃板6 vitreous panes

7 反射层7 reflective layer

8 保护层8 layers of protection

9 第二不透明覆盖印刷物9 Second opaque overlay print

10 成像单元10 imaging unit

O 复合玻璃板100的上边缘O the upper edge of the composite glass panel 100

U 复合玻璃板100的下边缘U Lower edge of the composite glass pane 100

S 复合玻璃板100的侧边缘S the side edge of the composite glass pane 100

I 外玻璃板1的外侧表面I Outer surface of the outer glass pane 1

II 外玻璃板1的内侧表面II inner side surface of outer glass pane 1

III 内玻璃板2的外侧表面III External surface of inner glass plate 2

IV 内玻璃板2的内侧表面IV The inside surface of the inner glass plate 2

V 玻璃质玻璃板6的外侧表面V outside surface of vitreous glass plate 6

VI 玻璃质玻璃板6的内侧表面VI The inside surface of the vitreous glass plate 6

A 其中布置有掩蔽层4的区域A area in which the masking layer 4 is arranged

B 其中布置有玻璃质玻璃板6的区域B Area in which the vitreous glass pane 6 is arranged

X′-X 切割线X′-X cutting line

Y-Y′ 切割线。Y-Y′ cutting line.

Claims (15)

1. A composite glass sheet (100) comprising at least
An outer glass pane (1) having an outer side surface (I) and an inner side surface (II),
a thermoplastic intermediate layer (3),
an inner glass pane (2) having an outer side surface (III) and an inner side surface (IV),
-a masking layer (4),
an adhesive layer (5),
a vitreous glass plate (6) having an outer side surface (V) and an inner side surface (VI) and a thickness of 20 μm to 500 μm,
wherein the inner glass pane (2) is arranged between the outer glass pane (1) and the vitreous glass pane (6),
a thermoplastic interlayer (3) is arranged between the outer glass pane (1) and the inner glass pane (2),
the masking layer (4) is arranged between the outer glass pane (1) and the inner glass pane (2) in a region of the composite glass pane (100),
the adhesive layer (5) is arranged between the inner glass plate (2) and the vitreous glass plate (6),
a reflective layer (7) for reflecting light is arranged on an outer side surface (V) of the vitreous glass plate (6) and/or on an inner side surface (VI) of the vitreous glass plate (6),
and wherein the vitreous glass plate (6) is arranged in a region of the composite glass plate (100) which, when seen vertically through the composite glass plate (100), is entirely located in the region in which the masking layer (4) is arranged.
2. The composite glass sheet (100) according to claim 1, wherein the vitreous glass sheet (6) has a thickness of 50 μm to 300 μm, preferably 50 μm to 100 μm.
3. The composite glass pane (100) according to claim 1 or 2, wherein the reflective layer (7) reflects at least 10%, preferably at least 50%, particularly preferably at least 80%, in particular at least 90% of visible light.
4. A composite glass sheet (100) according to any of claims 1 to 3, wherein the reflective layer (7) is a metal layer.
5. The composite glass pane (100) according to any one of claims 1 to 4, wherein the reflective layer (7) comprises or consists of aluminum, titanium and/or nickel, in particular aluminum.
6. The composite glass pane (100) according to any one of claims 1 to 5, wherein the masking layer (4) is designed to surround in a frame-like manner and has a greater width, in particular in the region overlapping the reflective layer (7), than in the region differing therefrom.
7. The composite glass pane (100) according to any one of claims 1 to 6, wherein the masking layer (4) is designed as a first opaque overlay print arranged on the inner side surface (II) of the outer glass pane (1) or the outer side surface (III) of the inner glass pane (2).
8. The composite glass sheet (100) according to any of claims 1 to 6, wherein the masking layer (4) is designed as an opaque coloured region of the thermoplastic interlayer (3).
9. The composite glass pane (100) according to any one of claims 1 to 8, wherein the composite glass pane (100) additionally has a second opaque overlay print (9) arranged on the inner side surface (IV) of the inner glass pane (2) at least in the region in which the vitreous glass pane (6) is arranged.
10. The composite glass pane (100) according to any of claims 1 to 9, wherein a reflective layer (7) for reflecting light is arranged on an inner side surface (VI) of the glass pane (6) or a reflective layer (7) for reflecting light is arranged on an outer side surface (V) of the glass pane (6) and on an inner side surface (VI) of the glass pane (6),
and wherein a protective layer (8) is arranged at least on the reflective layer (7) arranged on the inner side surface (VI) of the vitreous glass plate (6).
11. The composite glass sheet (100) according to any one of claims 1 to 10, wherein the adhesive layer (5) is a thermoplastic layer or an Optically Clear Adhesive (OCA).
12. The composite glass sheet (100) according to any of claims 1 to 11, wherein the composite glass sheet (100) is a curved composite glass sheet.
13. Projection device (101) comprising at least
Composite glass pane (100) according to any of claims 1 to 12,
-an imaging unit (10) directed towards the reflective layer (7).
14. Method of manufacturing a composite glass sheet (100) according to any of claims 1 to 12, comprising at least
a) Providing a composite made of an outer glass plate (1) having an outer side surface (I) and an inner side surface (II), a thermoplastic interlayer (3) and an inner glass plate (2) having an outer side surface (III) and an inner side surface (IV), wherein the thermoplastic interlayer (3) is arranged between the outer glass plate (1) and the inner glass plate (2) and a masking layer (4) is arranged in one region between the outer glass plate (1) and the inner glass plate (2);
b) Providing a vitreous glass plate (6) having an outer side surface (V) and an inner side surface (VI), wherein a reflective layer (7) for reflecting light is arranged on the outer side surface (V) of the vitreous glass plate (6) and/or on the inner side surface (VI) of the vitreous glass plate (6);
c) The vitreous glass plate (6) is joined to the inner glass plate (2) of the composite body by means of an adhesive layer (5) to form a composite glass plate (100) such that the vitreous glass plate (6) is arranged in a region of the composite glass plate (100) which, when seen vertically through the composite glass plate (100), is entirely located in the region in which the masking layer (4) is arranged.
15. Use of a composite glass sheet (100) according to any one of claims 1 to 12 as a vehicle glass sheet in an amphibious vehicle, in particular in a motor vehicle, in particular as a windscreen sheet for a head-up display.
CN202280006008.1A 2021-12-02 2022-11-22 Composite glass pane with locally applied reflective layer Pending CN116547141A (en)

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