CN116496659A - High-temperature-resistant water-based ink for cigarette tipping material - Google Patents
High-temperature-resistant water-based ink for cigarette tipping material Download PDFInfo
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- CN116496659A CN116496659A CN202310481209.3A CN202310481209A CN116496659A CN 116496659 A CN116496659 A CN 116496659A CN 202310481209 A CN202310481209 A CN 202310481209A CN 116496659 A CN116496659 A CN 116496659A
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- cigarette tipping
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000000463 material Substances 0.000 title claims abstract description 28
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 22
- 239000000839 emulsion Substances 0.000 claims abstract description 122
- 239000000049 pigment Substances 0.000 claims abstract description 51
- 239000006185 dispersion Substances 0.000 claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 31
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 26
- 239000004814 polyurethane Substances 0.000 claims abstract description 26
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 26
- 239000000945 filler Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 239000010703 silicon Substances 0.000 claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 15
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- 150000003077 polyols Chemical class 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 12
- 229920005862 polyol Polymers 0.000 claims description 12
- 229920005692 JONCRYL® Polymers 0.000 claims description 11
- 229920002050 silicone resin Polymers 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 5
- 239000004014 plasticizer Substances 0.000 claims description 3
- 101100407152 Arabidopsis thaliana PBL7 gene Proteins 0.000 claims description 2
- 101000614399 Homo sapiens Serine/threonine-protein phosphatase 2A regulatory subunit B'' subunit beta Proteins 0.000 claims description 2
- 102100040471 Serine/threonine-protein phosphatase 2A regulatory subunit B'' subunit beta Human genes 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000001038 titanium pigment Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- 208000028571 Occupational disease Diseases 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention provides high-temperature-resistant water-based ink for cigarette tipping materials, which belongs to the technical field of printing ink and comprises water-based acrylic emulsion dispersion, water-based polyurethane emulsion dispersion, water-based organic silicon resin emulsion, polyalcohol, ethanol, water, pigment, filler and auxiliary agent.
Description
Technical Field
The invention relates to the technical field of high-temperature-resistant water-based ink for cigarette tipping materials, in particular to high-temperature-resistant water-based ink for cigarette tipping materials.
Background
The traditional ink for the cigarette tipping paper is prepared by mixing one or more of PVB resin, nitrocotton, polyurethane, thermoplastic acrylic acid and the like as a connecting material; one or more of ethanol, isopropanol, n-propanol, ethyl acetate, n-propyl acetate, propylene glycol methyl ether and the like are used as solvents; thermoplastic acrylic acid, nitrocotton, solvent polyurethane and the like are used as connecting materials, and one or more organic solvents such as ethanol, isopropanol, ethyl acetate, propyl acetate, ethylene glycol diethyl ether, propylene glycol methyl ether and the like are used as diluents.
The solvent type cigarette tipping paper ink is formed by volatilizing an organic solvent under the condition of high-temperature drying to obtain a required color effect, but the organic solvent can cause the large fluctuation of the organic solvent residue of a printed product and the product quality cannot be ensured due to the reasons of drying temperature, production condition humidity, subjectivity of operators and the like;
meanwhile, the organic solvent is a dangerous chemical, and causes certain occupational disease injury to the occupational health of on-site operators in safe production. Even by adding low-toxicity or nontoxic alcohol solvents as diluents, environmental pollution can be caused in the production process due to organic volatile matters.
Whereas the existing high temperature resistant materials can only withstand high temperatures of 100 to 150 ℃ at high temperatures, the prior art can cause the ink to become sticky and soft, resulting in weaker adhesion and mechanical strength.
The prior art means is to crosslink a small molecular weight polyol to obtain a modified resin to resist high temperature, for example, an aqueous polyurethane ink binder with the publication number of CN111471157A, and a preparation method and application thereof, wherein the oligomer polyol is selected from at least one of polyether polyol or polyester polyol with the molecular weight of 1000-3000, and the crosslinking density is overlarge, the molecular weight is too high and the emulsification is difficult due to the fact that the high molecular weight polyol is used for crosslinking, so that the dispersion crosslinking is difficult.
In addition, the high temperature resistant effect is achieved by the high bond energy of the siloxane bond through the crosslinking of the organosilicon, for example, the high temperature resistant printing ink with the publication number of CN109467975A and the preparation method thereof use the organosilicon resin as a main material to improve the high temperature resistant performance, but other components of the ink do not use macromolecular polyol as a framework for crosslinking, so that the mechanical strength is not high, and the chemical performance and the mechanical strength of the ink are greatly changed along with the change of temperature.
Disclosure of Invention
In view of the above, the invention provides a high temperature resistant aqueous ink for a cigarette tipping material, which can resist high temperature and prevent the ink from discoloring and adhering.
In order to solve the technical problems, the invention provides high-temperature-resistant water-based ink for a cigarette tipping material, which comprises the following materials:
aqueous acrylic emulsion dispersion, aqueous polyurethane emulsion dispersion, aqueous silicone resin emulsion, polyalcohol, ethanol, water, pigment, filler and auxiliary agent.
Further, the material consists of the following raw materials:
5-20 parts of aqueous acrylic emulsion dispersion, 20-30 parts of aqueous polyurethane emulsion dispersion, 10-30 parts of aqueous silicone resin emulsion, 1-3 parts of polyalcohol, 1-4 parts of ethanol, 20-40 parts of water, 0-30 parts of pigment, 0-30 parts of filler and 0.5-3 parts of auxiliary agent.
Further, the material consists of the following raw materials:
0-10 parts of aqueous acrylic emulsion dispersion, 10-30 parts of aqueous polyurethane emulsion dispersion and 20-50 parts of aqueous organic silicon resin emulsion; 1-3 parts of polyalcohol, 1-4 parts of ethanol, 10-20 parts of water, 0-30 parts of pigment, 0-30 parts of filler and 0.5-3 parts of auxiliary agent.
Further, the aqueous acrylic emulsion dispersion comprises one or more of Joncryl 7169, R-20 emulsion, A-1127 acrylic emulsion and 8804 emulsion;
the aqueous polyurethane emulsion dispersion comprises: PU-9214 emulsion, PU-601 emulsion, PU-8690 emulsion, PU-8805 emulsion;
the aqueous organic silicon resin emulsion comprises the following components: SH-9607 emulsion, RL-600 emulsion, 9608A emulsion, E22 emulsion, E32 emulsion;
the polyol is: one or more of dodecanol and tetradecanol.
Further, the pigment comprises: titanium pigment, PY13 pigment, PY83 pigment, PY150 pigment, PY151 pigment, PY180 pigment, PR2 pigment, PR48:2 pigment, PR 53:1 pigment, PR57:1 pigment, PR146 pigment, PR254 pigment, PB15:1 pigment, PB15:2 pigment, PB15:3 pigment, PB15:4 pigment, PG7 pigment, PV3 pigment, PV23 pigment, PBL7 pigment;
the filler is one or more of calcium carbonate, talcum powder and barium sulfate.
Further, the solvent is one or more of water, ethanol, polyalcohol and isopropanol;
the auxiliary agent is one or more of defoamer, dispersant, thickener and soft plasticizer.
The dispersing agent is one or more of 760W dispersing agent, 750W dispersing agent and BYK2012 dispersing agent;
the invention aims at applying the high-temperature-resistant water-based ink of the cigarette tipping material in tipping paper, aluminized paper and laser paper.
In summary, compared with the prior art, the method has at least one of the following beneficial technical effects:
1. the invention is based on the improvement of the existing high temperature resistant ink, obtains remarkable mechanical strength and high temperature resistant effect by crosslinking macromolecular polyol skeleton and organic silicon resin, adjusts the temperature resistant performance by adjusting the proportion of aqueous acrylic emulsion dispersion, aqueous polyurethane emulsion dispersion, aqueous organic silicon resin emulsion, polyol, ethanol, water, filler, auxiliary agent and soft plasticizer, so that the organic silicon group in the aqueous organic silicon resin emulsion and the polyol are crosslinked to form a coupling, the mechanical strength is increased, and the heat resistant performance of the organic silicon itself is also increased.
2. Compared with the prior art, the water-based acrylic emulsion dispersion, the water-based polyurethane emulsion dispersion and the water-based organic silicon resin emulsion which are selected in the invention are mixed with the polyalcohol, the pigment, the filler and the performance auxiliary agent to form the ink coating film which has the characteristic of good temperature resistance effect, so that the special temperature resistance requirement in the invention can be met: after the environment-friendly water-based ink is completely dried, the coating can have good adhesive force on tipping paper, aluminized paper and laser paper, can bear 1-5 seconds at 100-250 ℃ after being cured at normal temperature, and meanwhile, printed matters cannot be adhered together due to storage temperature and humidity. The invention can not produce the potential safety hazards of re-dissolution and color fading to produce finished product suction sanitation under the condition of not protecting gloss oil (containing saliva); the filler selected by the invention is dispersed in the resin, so that the high-temperature-resistant water-based ink has the advantages of excellent scratch resistance, no powder falling on the surface of the coating when the addition amount is high, and no powder falling phenomenon in fine punching processing, and therefore, the high-temperature-resistant water-based ink has the advantages of good temperature resistance, good scratch resistance and good coating surface effect.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more clear, the technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention. It will be apparent that the described embodiments are some, but not all, embodiments of the invention. All other embodiments, which are obtained by a person skilled in the art based on the described embodiments of the invention, fall within the scope of protection of the invention.
The raw materials of the invention are commercial products, and the specific preparation operation and test are conventional techniques.
The implementation method of the invention comprises the following implementation steps:
step 1, mixing polyol, ethanol and water in advance uniformly for standby.
Step 2, taking 40% of the mixed solution in the step 1, and adding aqueous acrylic emulsion dispersion, aqueous polyurethane emulsion dispersion and aqueous organic silicon resin emulsion;
compounds in which the organosilicon compound contains Si-C bonds and at least one organic group is directly bonded to a silicon atom, are also conventionally known as organosilicon compounds in which the organic group is bonded to the silicon atom by oxygen, sulfur, nitrogen or the like.
The organic silicon product takes silicon-oxygen (Si-O) bond as a main chain structure, the bond energy of C-C bond is 82.6 kcal/gram molecule, and the bond energy of Si-O bond is 121 kcal/gram molecule in organic silicon, so the organic silicon product has high thermal stability, and the chemical bond of the molecule is not broken and decomposed at high temperature (or irradiation). The organosilicon not only can resist high temperature, but also can resist low temperature, and can be used in a wide temperature range. The change with temperature is small, whether chemical or physical mechanical.
Adding the auxiliary agent, pigment and filler at the speed of 100-200rpm while dispersing;
step 3, after the step 2 is finished, dispersing for 30 minutes at a speed of 800rpm-1500 rpm;
step 4, after the step 3 is finished, conventional grinding is carried out for 2-4 times, the required fineness (less than or equal to 5 mu m) is achieved, and 300-mesh filtering is carried out;
and 5, adding the residual solvent into the semi-finished product obtained in the step 4, adding the auxiliary agent, and dispersing at the speed of 800rpm for 15 minutes to obtain the finished product original ink.
Spraying and printing the prepared tipping paper high-temperature-resistant water-based ink, using the tipping paper, aluminized paper and laser paper materials for cigarette cigarettes, pasting the printed ink by using an adhesive tape, and observing the ink adhered on the adhesive tape to obtain data.
Example 1
The embodiment is the influence of the filler ratio on the temperature resistance;
the materials of this example except the filler are collectively referred to as oil-blending, and the oil-blending formula is as follows: aqueous acrylic emulsion dispersion (22.5 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (15 parts): SH-9607 emulsion, polyol (1.5 parts): 1, 12-dodecanol, ethanol (4 parts), water (20 parts), pigment (15 parts) and auxiliary agent (2 parts): 760W dispersant.
In the embodiment, the oil mixing ratio is 95 parts, and the filler (calcium carbonate) is 5 parts;
example two
The difference between this embodiment and the first embodiment is that: 90 parts of oil mixing ratio and 10 parts of filler (calcium carbonate);
example III
The difference between this embodiment and the first embodiment is that: oil mixing ratio is 85 parts, and filler (calcium carbonate) is 15 parts;
example IV
The difference between this embodiment and the first embodiment is that: 80 parts of oil mixing ratio and 20 parts of filler (calcium carbonate);
example five
The difference between this embodiment and the first embodiment is that: mixing oil with 70 parts and filling (calcium carbonate) with 30 parts;
example six
The present example is the effect of vehicle component tuning on temperature resistance, wherein the vehicle is an aqueous acrylic emulsion dispersion, an aqueous polyurethane emulsion dispersion, an aqueous silicone resin emulsion, and the non-vehicle is a polyol (3 parts): 1, 12-dodecanol, ethanol (8 parts), water (30 parts), pigment (25 parts) and auxiliary agent (4 parts): 760W dispersant, filler (30 parts): calcium carbonate;
in this embodiment, the mass ratio of the connection and the disconnection is 50:50
The aqueous acrylic emulsion dispersion (20 parts) in this example: joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (10 parts): SH-9607 emulsion;
example seven
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (20 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (10 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (20 parts): SH-9607 emulsion;
example eight
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (20 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (0 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (30 parts): SH-9607 emulsion;
example nine
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (20 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (30 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (0 part): SH-9607 emulsion;
examples ten
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (30 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (0 part): SH-9607 emulsion;
example eleven
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (20 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (10 parts): SH-9607 emulsion;
example twelve
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (10 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (20 parts): SH-9607 emulsion;
example thirteen
The difference between this embodiment and the sixth embodiment is that: aqueous acrylic emulsion dispersion (0 parts): joncryl 7169 emulsion, aqueous polyurethane emulsion dispersion (20 parts): PU-9214 emulsion, aqueous organic silicon resin emulsion (30 parts): SH-9607 emulsion;
comparative example one
On the basis of the first embodiment, one of the three components (calcium carbonate, talcum powder and barium sulfate) is replaced by the filler according to the same mass ratio, and the rest components are unchanged, so that the printing gloss of the obtained printing ink coating is different from the refraction effect on aluminized paper and laser paper, the gloss of a printed matter is obviously reduced when the increase of the gloss is more than 50%, and the risk of powder falling is generated.
Comparative example two
On the basis of the first embodiment, the filler is reduced by less than 5 percent, the rest is unchanged, the ink is obtained, the surface drying speed is greatly reduced, the printing adaptability of the product is affected, and the phenomena of incomplete color and back adhesion (100 ℃ multiplied by 5 s) of the printed matter are caused.
Analysis
In examples one to five, the ratio of filler was compared, and the filler gave the best resistance to high temperatures at 30%.
In the sixth to ninth embodiments, the silicone resin and the aqueous polyurethane emulsion dispersion were adjusted, and it was shown that the high temperature resistance of the ink was the best when the aqueous silicone resin content was the greatest.
In the ten-thirteenth examples, the silicone resin and the aqueous acrylic emulsion dispersion were adjusted to show that the highest content of the aqueous silicone resin results in the best high temperature resistance of the ink.
When the water-based organic silicon resin emulsion is lower than 5%, the water-based organic silicon resin emulsion is unchanged, so that the tipping paper water-based temperature-resistant ink is obtained, the printing effect is poor, and meanwhile, the temperature resistance is rapidly reduced when the ink is transferred to the tipping paper in a coating mode. The printed matter has the phenomenon of printed matter after being baked at 85 ℃ and 8H and being opposite-sticking.
While the foregoing is directed to the preferred embodiments of the present invention, it will be appreciated by those skilled in the art that various modifications and adaptations can be made without departing from the principles of the present invention, and such modifications and adaptations are intended to be comprehended within the scope of the present invention.
Claims (11)
1. The high-temperature-resistant water-based ink for the cigarette tipping material is characterized by comprising the following materials:
aqueous acrylic emulsion dispersion, aqueous polyurethane emulsion dispersion, aqueous silicone resin emulsion, polyalcohol, ethanol, water, pigment, filler and auxiliary agent.
2. The high temperature resistant aqueous ink for cigarette tipping material according to claim 1, which is composed of the following raw materials:
0-20 parts of aqueous acrylic emulsion dispersion, 0-30 parts of aqueous polyurethane emulsion dispersion, 10-50 parts of aqueous silicone resin emulsion, 1-3 parts of polyalcohol, 1-4 parts of ethanol, 10-40 parts of water, 0-30 parts of pigment, 0-30 parts of filler and 0.5-3 parts of auxiliary agent.
3. The high temperature resistant aqueous ink for cigarette tipping material according to claim 2, which is composed of the following raw materials:
5-10 parts of aqueous acrylic emulsion dispersion, 10-30 parts of aqueous polyurethane emulsion dispersion and 20-50 parts of aqueous organic silicon resin emulsion; 1-3 parts of polyalcohol, 1-4 parts of ethanol, 10-20 parts of water, 0-30 parts of pigment, 0-30 parts of filler and 0.5-3 parts of auxiliary agent.
4. The high temperature resistant aqueous ink for a cigarette tipping material according to any one of claims 1 to 3, wherein said aqueous acrylic emulsion dispersion comprises one or more of Joncryl 7169, R-20 emulsion, a-1127 acrylic emulsion, 8804 emulsion;
the polyol is: one or more of dodecanol and tetrahydric alcohol.
5. The high temperature resistant aqueous ink for a cigarette tipping material according to claim 1, wherein said pigment comprises: titanium pigment, PY13 pigment, PY83 pigment, PY150 pigment, PY151 pigment, PY180 pigment, PR2 pigment, PR48:2 pigment, PR 53:1 pigment, PR57:1 pigment, PR146 pigment, PR254 pigment, PB15:1 pigment, PB15:2 pigment, PB15:3 pigment, PB15:4 pigment, PG7 pigment, PV3 pigment, PV23 pigment, PBL7 pigment.
6. The high temperature resistant aqueous ink for cigarette tipping material according to claim 1, wherein the auxiliary agent is one or more of defoamer, dispersant, thickener and softening plasticizer.
7. The dispersing agent is one or more of 760W dispersing agent, 750W dispersing agent and BYK2012 dispersing agent.
8. The high temperature resistant aqueous ink for a cigarette tipping material of claim 1, wherein said aqueous polyurethane emulsion dispersion comprises: PU-9214 emulsion, PU-601 emulsion, PU-8690 emulsion, and PU-8805 emulsion.
9. The high temperature resistant aqueous ink for a cigarette tipping material of claim 1, wherein said aqueous silicone resin emulsion is: SH-9607 emulsion, RL-600 emulsion, 9608A emulsion, E22 emulsion, and E32 emulsion.
10. The high temperature resistant aqueous ink for cigarette tipping material according to claim 1, wherein the filler is one or more of calcium carbonate, talc and barium sulfate.
11. The application of the high-temperature-resistant water-based ink of the cigarette tipping material in tipping paper, aluminized paper and laser paper.
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