CN116463888A - Environment-friendly aluminum-free moisture-preserving lining paper for cigarettes - Google Patents
Environment-friendly aluminum-free moisture-preserving lining paper for cigarettes Download PDFInfo
- Publication number
- CN116463888A CN116463888A CN202310238736.1A CN202310238736A CN116463888A CN 116463888 A CN116463888 A CN 116463888A CN 202310238736 A CN202310238736 A CN 202310238736A CN 116463888 A CN116463888 A CN 116463888A
- Authority
- CN
- China
- Prior art keywords
- paper
- cigarettes
- lining paper
- surface sizing
- lining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 86
- 238000004513 sizing Methods 0.000 claims abstract description 61
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004327 boric acid Substances 0.000 claims abstract description 24
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 23
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 23
- 230000014759 maintenance of location Effects 0.000 claims abstract description 21
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 20
- 230000003020 moisturizing effect Effects 0.000 claims abstract description 17
- 239000001110 calcium chloride Substances 0.000 claims abstract description 15
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 15
- 239000011121 hardwood Substances 0.000 claims abstract description 11
- 239000011122 softwood Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 7
- 230000005540 biological transmission Effects 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 47
- 239000011248 coating agent Substances 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 238000003756 stirring Methods 0.000 claims description 21
- 238000001035 drying Methods 0.000 claims description 13
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- 235000010413 sodium alginate Nutrition 0.000 claims description 10
- 239000000661 sodium alginate Substances 0.000 claims description 10
- 229940005550 sodium alginate Drugs 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 8
- 229920002907 Guar gum Polymers 0.000 claims description 7
- 238000003490 calendering Methods 0.000 claims description 7
- 235000010417 guar gum Nutrition 0.000 claims description 7
- 239000000665 guar gum Substances 0.000 claims description 7
- 229960002154 guar gum Drugs 0.000 claims description 7
- 230000035699 permeability Effects 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 6
- 229920001100 Polydextrose Polymers 0.000 claims description 6
- 235000013856 polydextrose Nutrition 0.000 claims description 6
- 239000001259 polydextrose Substances 0.000 claims description 6
- 229940035035 polydextrose Drugs 0.000 claims description 6
- 239000012744 reinforcing agent Substances 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 235000010980 cellulose Nutrition 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229920000159 gelatin Polymers 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 229940014259 gelatin Drugs 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000011859 microparticle Substances 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims 1
- 230000001502 supplementing effect Effects 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 abstract description 8
- 238000004537 pulping Methods 0.000 abstract description 3
- -1 alkyl ketene dimer Chemical compound 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 13
- 238000004806 packaging method and process Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000010907 mechanical stirring Methods 0.000 description 8
- 241000208125 Nicotiana Species 0.000 description 7
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000000903 blocking effect Effects 0.000 description 4
- 230000009977 dual effect Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000005524 ceramic coating Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000011002 quantification Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 102000020897 Formins Human genes 0.000 description 2
- 108091022623 Formins Proteins 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 238000013329 compounding Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- QRJOYPHTNNOAOJ-UHFFFAOYSA-N copper gold Chemical compound [Cu].[Au] QRJOYPHTNNOAOJ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008387 emulsifying waxe Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000000686 lactone group Chemical group 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 208000030159 metabolic disease Diseases 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000903 polyhydroxyalkanoate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/25—Cellulose
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
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- D—TEXTILES; PAPER
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/31—Gums
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/65—Acid compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/56—Rolls
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/64—Addition to the formed paper by contacting paper with a device carrying the material the material being non-fluent at the moment of transfer, e.g. in form of preformed, at least partially hardened coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Abstract
The invention relates to the field of pulping and papermaking, in particular to aluminum-free environment-friendly lining paper for cigarettes with a moisturizing function. The invention relates to a lining paper for cigarettes, which consists of a lining base paper and a sizing layer on the surface of the lining base paper, wherein the base paper is produced on a paper machine by softwood pulp, hardwood pulp, filler and auxiliary agent, the surface sizing layer is applied on the surface of the base paper by a surface sizing machine in the paper machine, and the components of the surface sizing agent comprise polyvinyl alcohol, alkyl ketene dimer, calcium chloride, boric acid and the like, and a multi-layer crosslinked structure is formed after the components are dried, so that the gas resistance and the moisture retention performance of paper sheets are improved. The aluminum-free environment-friendly moisturizing lining paper has gas transmission rate less than 2 x 10 7 ml/m 2 24 h.0.1 MPa, permeanceThe wet rate is less than 2500g/m 2 24 hours, the moisture retention performance is higher than that of common aluminized paper by more than 5 percent.
Description
Technical Field
The invention relates to the field of pulping and papermaking, in particular to aluminum-free environment-friendly lining paper for cigarettes with a moisturizing function.
Background
In the current trend of international tobacco packaging, the need for "environmental protection" is becoming more and more important. The environmental protection degree of the cigarette products of European and American large-scale nationwide companies is very high in each link. The use of environmentally friendly packaging products is a "green pass" for tobacco enterprises to go to the world market, both tobacco enterprises and tobacco packaging suppliers, increasingly recognizing the necessity and urgency of using and developing, producing environmentally friendly products. The production and use of "green-packaged" products will be the focus of development in the tobacco industry and the tobacco packaging industry for the next few years.
The lining paper for cigarettes is paper for packaging cigarettes and small boxes of the cigarettes, serves as an initial packaging layer of the cigarettes, plays roles in preserving fragrance, moistening, shading and the like for the cigarettes, can prevent the cigarettes from mildewing and emitting fragrance, can show attractive characteristics, and is an important cigarette packaging material. The existing lining paper for cigarettes is made by compounding base paper and aluminum foil or vacuum aluminizing, so that a large amount of metal aluminum is wasted; and the lining paper contains aluminum components, so that wastes cannot be naturally degraded, are difficult to recycle, and bring serious pollution to the environment. Aluminum can slowly accumulate in the human body and can also cause toxic reactions of metabolic disorders. In the process of storing cigarettes under different temperature and humidity conditions, especially after the cigarette case is unsealed, cigarettes have different degrees of water loss or moisture absorption, so that the smoking taste is affected. At present, the moisture of the cigarette product is mainly kept by packaging and forming cigarette lining paper, frame paper, small box packaging paper and transparent paper through packaging equipment so as to form a closed space, thereby avoiding moisture loss and moisturizing cigarettes; after the cigarette case is opened, the moisturizing effect is reduced. In order to save nonferrous metal aluminum materials with deficient resources, realize clean production and achieve the excellent fragrance and moisture preservation functions of the traditional process, the industry starts focusing the eyes on the aluminum-free lining paper.
Patent 202111419892.5 (application number, the same applies hereinafter) discloses a moisture-absorbing and balancing lining paper for cigarettes and a preparation method thereof, wherein the lining paper comprises base paper, an inner coating and a back coating. The inner coating layer is provided with a coating with moisture absorption balance function, and the coating weight is (1.5-2.5) g/m 2 Comprising: 30-40 parts of acrylic resin, 20-30 parts of polyurethane resin, 3-5 parts of gelatin, 1-2 parts of methacrylic acid, 2-4 parts of light curing agent, 10-20 parts of ethanol and 0.3-0.5 part of auxiliary agent, wherein the key point is that the light curing agent TPO and the light curing agent EDB are compounded according to a proper mass ratio. The coating can be cured only by ultraviolet irradiation (5-7 min), has no gas blocking effect, and can achieve the effects of gas blocking and moisture retention only by matching with the back coating. The technology has complex coating process, is not suitable for the production requirement of one-time coating of a roller coater, has low production efficiency and is not suitable for large-scale continuous production.
Patent 201910764324.5 disclosesA functional raw paper for the liner of cigarette is prepared through coating functional coating on raw paper. The functional coating comprises: 13 to 17 parts of blocking agent, 23 to 27 parts of clay, 13 to 17 parts of diatomite, 13 to 17 parts of titanium pigment, 8 to 12 parts of porcelain clay, 8 to 12 parts of water-based polyvinyl alcohol and 8 to 12 parts of acrylic resin copolymer, and the coating weight is (2 to 5) g/m 2 . The scheme has lower water vapor transmittance and air permeability, but the technical scheme does not have a moisturizing function at the same time.
Patent 201610845550.2 discloses an aluminum-free lining paper for cigarettes and a production method thereof, wherein a layer of coating is applied on base paper, and the components comprise: 20% -30% of papermaking porcelain clay; 2% -10% of adhesive; agar, 5% -15%; 30% -80% of deionized water; 1% -5% of water repellent agent; 0.1% -5% of dispersing agent; pearl powder, 0% -10%; coating by an air knife mode, wherein the coating weight is (9-13) g/m 2 . According to the technical scheme, aluminum is not used, and the finished paper has good gas barrier property. However, the technical proposal has no obvious moisturizing effect, can only be coated on one side at a time, and has lower production efficiency.
Patent 201610420008.2 discloses an environment-friendly cigarette package lining paper, which comprises base paper, a barrier layer and an adhesive layer between the base paper and the barrier layer. The components of the barrier layer are: 10-20% of polycaprolactone, 5-15% of polyhydroxyalkanoate, 5-10% of polyvinyl alcohol, 0.3-0.8% of emulsifying wax, 1-8% of montmorillonite, 1-8% of zinc stearate and the balance of water; the adhesive comprises: 10 to 25 percent of methyl acrylate, 10 to 25 percent of methyl methacrylate, 1 to 8 percent of methacrylic acid, 1 to 8 percent of methyl acetate, 1 to 8 percent of methyl tin mercaptide, 1 to 5 percent of bentonite and 1 to 3 percent of toughening agent. The lining paper obtained by the technical scheme has lower water vapor transmittance and air permeability, but the isolation layer of the technology is a resin layer, the recoverability of the finished paper is poor, the coating process is complex, and the coating amount and the moisture retention performance are not mentioned.
Patent 201210000823.5 discloses a method for producing lining paper for aluminum-free cigarettes, which comprises pulping softwood pulp and hardwood pulp to a certain beating degree, adding adjuvants such as starch, etcMaking paper, and carrying out calendaring after oxidized starch is applied to the surface of the paper to obtain base paper; printing modified polyvinyl alcohol or modified acrylic resin paint on the lining base paper for cigarettes through a three-color printing machine gravure technology, wherein the solid content of the paint is 30% -50%, and the coating weight is (2-5) g/m 2 . The regimen also does not mention moisturizing properties.
Patent 200610031404.2 discloses an environment-friendly lining paper for cigarettes, which is prepared by coating water-based ink on the surface of base paper, wherein the components are as follows: copper-gold powder, silver powder or other pigments for pigments account for 10 to 50 percent; purified water accounts for 3 to 6; the leveling agent accounts for 4 to 7; the defoamer accounts for 2 to 4; 3 to 6 percent of waterproof agent; the preservative accounts for 2 to 6; 3-11 parts of antioxidant; 15-20% of water-based resin. The pigment and the adhesive are used as main bodies to form a pigment coating, so that the lining paper is endowed with good gas barrier property, and the workshop environment is not polluted. However, this technical solution does not have a significant moisturizing effect. In the coating formed by the water-based ink, the inorganic pigment basically does not absorb water, the adhesive fills the pores among the pigments, and the coating amount is higher, so that the lining paper is endowed with better gas barrier property.
The patent 201810287809.5 discloses a flavoring and moisturizing cigarette packaging paper and a preparation method thereof, wherein a ceramic coating is coated on the inner packaging surface, the ceramic coating consists of a ceramic component, an adhesive (acrylic emulsion or styrene-acrylic emulsion) and a flavoring agent (plant extract or essential oil), the ceramic component accounts for 50% -70%, and the flavoring and moisturizing cigarette packaging paper comprises: 10-15% of purple clay powder, 10-15% of porcelain powder and the balance of ceramic powder. The technical scheme utilizes the moisture retention performance of the ceramic coating, reduces or even avoids the water absorption of the cigarette packaging paper, and improves the moisture retention effect of the cigarette product; but the effect of blocking gas cannot be improved, and meanwhile, the aroma fixing agent in the coating can destroy the aroma of cigarettes with different aroma types.
Patent 201810049181.5 discloses a moisture-preserving cigarette lining paper and a preparation method thereof, wherein a hot-melt sealing layer, a PET dumb silver composite film and varnish are sequentially arranged on the upper surface of a raw paper layer from inside to outside. Although the method has a moisturizing effect, the method uses a non-degradable PET film, is not friendly to the environment and cannot be realized on a paper machine.
Therefore, the existing technical scheme of the lining paper for the aluminum-free cigarettes is complex in coating process, and some schemes are low in production efficiency and not suitable for large-scale production. The scheme can not realize the dual effects of completing the functions of blocking gas and preserving moisture by one-time coating, and can be completed by two or more times of coating, so that the equipment investment is large, the production power consumption is high, the carbon emission is not easy to reduce, an energy-saving enterprise is built, and some schemes are not reusable and have the environmental protection problem. Therefore, development of a simple and easy-to-realize coating process is urgently needed, and an overall coating scheme with double effects of gas-blocking and moisture-preserving functions can be realized by one-time coating, so that the quality of products is obviously improved, the functional characteristics of gas-blocking and moisture-preserving are highlighted, the production efficiency is obviously improved, and the environment-friendly and recyclable requirements are met.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides the environment-friendly aluminum-free moisture-preserving lining paper for cigarettes, which is prepared by making raw paper and coating the surface of the raw paper once to form three functional structural layers, and comprises the following specific steps:
(1) Uniformly mixing softwood pulp, hardwood pulp, filler, retention and drainage aid, reinforcing agent, crosslinked sodium alginate, internal sizing agent and other auxiliary agents, feeding the mixture into a paper machine forming net for papermaking, and drying the mixture in a front drying part after dewatering in a pressing part to obtain a paper sheet with dryness of 85-99%; the mass ratio of the softwood pulp to the hardwood pulp is 35-40:60-65, and the addition amount of the filler, the retention and filter aid, the reinforcing agent, the crosslinked sodium alginate and the internal sizing agent is 20-25%, 0.02-0.03%, 0.7-0.8%, 0.6-0.8% and 0.2% of the total amount of the softwood pulp and the hardwood pulp.
(2) Preparation of a component A of a surface sizing agent: adding AKD, ASA, emulsified rosin, emulsion wax combination and water into a dissolving tank A, starting mechanical stirring, adding polyvinyl alcohol (PVA), continuing stirring (10-30) for min after the adding, starting heating, preserving heat (30-60) for min when the temperature reaches 90-95 ℃, adding the rest water, and preserving heat at 40-60 ℃ for later use; wherein the polyving akohol has a polymerization degree of 500-2600 and an alcoholysis degree of (88-99)%; the solid content of the component A of the surface sizing agent is (3-10)%, the viscosity is (4-100) cP, and the absolute dry mass ratio of AKD, ASA, emulsified rosin, emulsion wax combination and PVA is 0.5/99.5-10/90.
(3) Preparation of a component B of the surface sizing agent: adding a certain amount of boric acid and water into a dissolving tank B, and stirring to dissolve the boric acid and the water to obtain colorless transparent solution; adding a certain amount of calcium chloride into the boric acid solution, and stirring to obtain a calcium chloride solution of boric acid for later use; wherein the solid content of boric acid is (0.1-4)%, and the solid content of calcium chloride is (0.1-35)%;
(4) Preparation of a component C of the surface sizing agent: adding a certain amount of water into the dissolving tank C, starting mechanical stirring, adding one or more of polyvinyl alcohol (PVA), gelatin, xanthan gum, guar gum, cellulose derivatives, pregelatinized starch, polydextrose and derivatives thereof, continuing stirring (10-60) for a minute after the addition, starting heating, and preserving heat (10-90) for a minute at 90-95 ℃ for later use;
(5) Preparing a composite surface sizing solution: adding a proper amount of the component B of the surface sizing agent in the step (2) and the component C of the surface sizing agent in the step (3) into a mixing tank for mixing, and mechanically stirring for 5-60 min; adding the component A of the surface sizing agent in the step (1), and mechanically mixing for 5-30 min to obtain a composite surface sizing solution;
(6) And (3) pumping the composite surface sizing agent in the step (5) into a feeding groove of a surface sizing machine of a paper machine to carry out surface sizing on the front surface of the paper sheet in the step (1), and after drying in a drying part of the paper machine and calendaring finishing by a calendaring machine, curling to obtain the environment-friendly aluminum-free moisturizing lining paper.
The filler is calcium carbonate or talcum powder or kaolin; the retention and drainage aid is pure polyacrylamide or cationic starch or a combined system of the retention and drainage aid and bentonite and silica sol microparticles; the reinforcing agent is modified starch or polyacrylamide; the internal sizing agent is AKD or ASA or rosin size.
In the component B of the surface sizing agent, the solid content of the boric acid solution is (0.1-4)%; the calcium chloride is anhydrous calcium chloride or calcium chloride containing crystal water, and the content of the calcium chloride in the component B of the surface sizing agent is (0.1-35)%.
In the component C of the surface sizing agent, the solid content of one or more of polyvinyl alcohol (PVA), gelatin, xanthan gum, guar gum, cellulose derivatives, pregelatinized starch, polydextrose and derivatives thereof is (3-10)%, and the viscosity is (4-100) cP.
In the composite surface sizing agent, the absolute dry mass ratio of the components A, B, C is 40-98:1-35:1-25.
The roller type sizing machine adopts a film transfer or two-roller dipping mode, and can be arranged in the machine or outside the machine; the application amount of the composite surface sizing agent on the front surface of the paper sheet is (0.5-2.5) g/m 2 . The back surface can be coated with water, surface sizing starch glue, composite surface sizing agent, etc. with the coating amount of (0.2-2.5) g/m 2 。
The ration of the environment-friendly aluminum-free moisture-preserving tobacco lining paper is (40-100) g/m 2 Gas transmission rate is less than 2 x 10 7 ml/m 2 24 h.0.1 MPa, moisture permeability < 2500g/m 2 24 hours (38 ℃,92% RH), the moisture retention performance (based on the moisture content of the internal cigarettes after the cigarette case is opened for a period of time) is more than 5% higher than that of the common aluminized paper.
Compared with the prior art, the lining paper for cigarettes with good gas-blocking and moisture-preserving double effects is obtained by performing one-time coating on a conventional roller coating mode, such as a two-roller dipping sizing machine and a film transfer sizing machine. In addition, the coater has good running performance, and the problem of cylinder sticking and paper breakage can not occur. The coating machine can be arranged in the paper machine (called as in-machine coating) or outside the paper machine (called as out-machine coating), the coating process is simple, the production efficiency is high, the power consumption of one-time coating is correspondingly low, and the energy conservation and the environmental protection are realized. Because only one application is carried out on the base paper, the coating quantity is lower, and the dual effects of gas resistance and moisture retention can be achieved at the same time, thereby having good cost advantage.
The composite surface sizing agent applied on the base paper forms a multi-layer cross-linked coordination structure (shown in figure 1) when being dried, so that good dual effects of gas resistance and moisture retention are achieved: the part absorbed by the base paper/the part closest to the base paper is mainly a three-dimensional network structure formed by calcium chloride, fibers and crosslinked sodium alginate, wherein the calcium chloride is absorbed by the base paper and enters into pores of the base paper or is adhered to the surfaces of the fibers, and is subjected to partial condensation reaction with the crosslinked sodium alginate in the base paper to form a more tiny network structure; meanwhile, the formed micro-network structure can prevent excessive penetration of other components into paper, and the part of the micro-network structure is mainly one or more of polyvinyl alcohol (PVA), gelatin, xanthan gum, guar gum, cellulose derivatives, pregelatinized starch, polydextrose and derivatives thereof and boric acid, and in the drying process, as the concentration of the coating is increased, the complex (shown in figure 2) after the crosslinking reaction and a small amount of calcium chloride gradually occur, and the crosslinking structure complex of the PVA and the boric acid is preferentially adsorbed on the micro-network structure formed by fibers, crosslinked sodium alginate and calcium chloride, so that the micro-network structure surface pores can be further covered, and a certain gas barrier property is provided; the surface is the component of surface sizing agent A. In the preparation process of the component A of the surface sizing agent, polyvinyl alcohol (PVA), one or more of AKD, ASA, emulsified rosin, emulsion wax and the surface sizing agent are combined in solution to form a cross-linked substance, lactone rings of AKD and ASA are opened by heating and react with hydroxyl groups in polyvinyl alcohol (PVA) molecules to form a cross-linked structure complex (as shown in figure 3), and hydrophobic groups are provided. When the coating is dried, the coating is preferentially concentrated in the outermost layer due to certain hydrophobicity, so that a continuous, compact and hydrophobic film can be formed, and the gas-blocking function and the water vapor-blocking performance are provided. The three-layer structure has the functions of emphasis and mutual matching, thereby realizing the dual functions of air resistance and moisture retention of one-time surface sizing processing.
Drawings
Fig. 1 is a schematic diagram of a paper structure.
FIG. 2 is a cross-linked structure complex of PVA and boric acid.
FIG. 3 shows a PVA and AKD crosslinked structure complex, R is C 14 H 29 Or C 16 H 33 。
Detailed Description
The above and further technical features and advantages of the present invention will be described in more detail below with reference to examples and experimental data, but the present invention is not limited to the examples.
Example 1:
the softwood pulp and the hardwood pulp are respectively pulped to (60+/-3) °SR, pulp preparation is carried out according to the proportion of 40:60, and the added auxiliary agents (20 percent, the same applies to the total mass of the pulp) and AKD (0.2 percent), PAM (0.02 percent), starch in the pulp (0.7 percent) and crosslinked sodium alginate (0.6 percent) are added. Wherein the auxiliary agent is as follows: and (3) calcium carbonate.
Adding 30kg AKD, 5kg rosin emulsion, 2kg emulsion wax and 1500kg water into a dissolving tank A, starting mechanical stirring, adding 120kg PVA1799, continuing stirring for 30min after the addition, starting heating, preserving heat for 60min at 95 ℃, adding 1500kg water, and preserving heat at 60 ℃ for later use; adding 30kg of boric acid and 1000kg of water into a dissolving tank B, stirring to dissolve the boric acid, adding 60kg of calcium chloride into the boric acid solution, and stirring to obtain a calcium chloride solution of boric acid; 1000kg of water is added into a dissolving tank C, mechanical stirring is started, 50kg of PVA2099, 2kg of guar gum and 5kg of polydextrose are added, stirring is continued for 60min after the addition is finished, heating is started, and heat is preserved for 60min at 95 ℃; mixing 500kg of solution in a dissolving tank B with 500kg of solution in a dissolving tank C, mechanically stirring for 10min, adding 1500kg of solution in the dissolving tank A, and mixing for 10min to obtain the compound surface sizing solution with the solid content of 5% and the viscosity of 31cP.
Making paper pulp on a paper machine, squeezing, drying before, and performing surface sizing treatment with a film transfer sizing machine, wherein the application amount of the front composite surface sizing solution is 1.2g/m 2 Applying water to the back surface in an amount of 0.5g/m 2 And (5) drying, calendaring and curling to obtain the aluminum-free lining paper for cigarettes.
The paper forming index is as follows: quantification: 70.8g/m 2 Thickness of: 68.8 μm, gas permeation amount: 1.91*10 7 ml/m 2 24 h.0.1 MPa, moisture permeability: 2105g/m 2 ·24h。
Moisture retention performance experiment: wrapping cigarettes by using the aluminum-free lining paper, putting the cigarettes in a common cigarette case as an experimental group, wherein the paper surface of the base paper is close to the cigarettes, and the surface of the surface adhesive is close to the cigarette case; the cigarettes are wrapped by using traditional aluminized paper and are put into a common cigarette case to be used as a control group. The outside of the cigarette case is not provided with a plastic film, the opening of the case is closed, and the cigarette case is placed in a room temperature environment to detect the moisture content of cigarettes at different time points. The results are shown in Table 1:
table 1 moisture change table for cigarettes
It can be seen that in the storage process, the moisture of cigarettes in the experimental group at the same time point is obviously higher than that in the control group, and the moisture difference between the two groups is 5% -10.5%, so that the technical scheme has good moisturizing effect, and the taste of cigarettes inside the opened cigarette case can be well maintained.
Example 2:
the softwood pulp and the hardwood pulp are respectively pulped to (60+/-3) °SR, pulp preparation is carried out according to the proportion of 35:65, and the auxiliary agent (23%) and AKD (0.2%), PAM (0.03%), starch (0.8%) and crosslinked sodium alginate (0.6%) are added. The auxiliary agent is as follows: talc powder.
Adding 25kg ASA, 10kg surface sizing agent, 4kg emulsion wax and 1500kg water into a dissolving tank A, starting mechanical stirring, adding 150kg PVA1788, continuing stirring for 30min after the addition, starting heating, preserving heat for 60min at 95 ℃, adding 1500kg water, and preserving heat at 60 ℃ for later use; adding 35kg of boric acid and 1000kg of water into a dissolving tank B, stirring to dissolve the boric acid, adding 50kg of calcium chloride into the boric acid solution, and stirring to obtain a calcium chloride solution of boric acid; 1000kg of water is added into the dissolution tank C, mechanical stirring is started, 60kg of PVA2499, 1kg of xanthan gum and 5kg of polydextrose are added, stirring is continued for 60min after the addition is finished, heating is started, and heat is preserved for 60min at 95 ℃; mixing the solution in the dissolving tank B with the solution in the dissolving tank C, mechanically stirring for 10min, adding the solution in the dissolving tank A, and mixing for 15min to obtain the compound surface sizing solution with the solid content of 5.6% and the viscosity of 39cP.
The wet paper sheet is manufactured by the paper pulp through the net feeding, after being pressed and dried, the surface sizing treatment is carried out by using a gate roller sizing machine, and the application amount of the compound surface sizing liquid is 1.7g/m 2 The back surface is coated with a surface sizing starch glue solution with the coating quantity of 0.9g/m 2 And (5) drying, calendaring and curling to obtain the aluminum-free lining paper for cigarettes.
The paper forming index is as follows: quantification: 70.3g/m 2 Thickness of:66.1 μm, gas permeation amount: 1.28*10 7 ml/m 2 24 h.0.1 MPa, moisture permeability: 2013g/m 2 ·24h。
Moisture retention performance experiment: wrapping cigarettes by using the aluminum-free lining paper, putting the cigarettes in a common cigarette case as an experimental group, wherein the paper surface of the base paper is close to the cigarettes, and the surface of the surface adhesive is close to the cigarette case; the cigarettes are wrapped by using traditional aluminized paper and are put into a common cigarette case to be used as a control group. The outside of the cigarette case is not provided with a plastic film, the opening of the case is closed, and the cigarette case is placed in a room temperature environment to detect the moisture content of cigarettes at different time points. The results are shown in Table 2:
table 2 moisture change table for cigarettes
Example 3:
the softwood pulp and the hardwood pulp are respectively pulped to (60+/-3) SR, pulp preparation is carried out according to the proportion of 35:65, and auxiliary agents of talcum powder (23%), AKD (0.2%), PAM (0.03%), starch (0.8%) and crosslinked sodium alginate (0.8%) are added.
Adding 30kg AKD, 6kg emulsion wax and 1500kg water into a dissolving tank A, starting mechanical stirring, adding 130kg PVA2099, continuing stirring for 30min after the addition, starting heating, preserving heat for 60min at 95 ℃, adding 1500kg water, and preserving heat at 60 ℃ for later use; adding 15kg of boric acid and 1000kg of water into a dissolving tank B, stirring to dissolve the boric acid, adding 70kg of calcium chloride into a boric acid solution, and stirring to obtain a calcium chloride solution of boric acid; 1000kg of water is added into a dissolving tank C, mechanical stirring is started, 50kg of PVA2099, 23kg of PVA1588 and 8kg of cellulose derivative CMC are added, stirring is continued for 60min after the addition is finished, heating is started, and heat is preserved for 60min at 95 ℃; mixing the solution in the dissolving tank B with the solution in the dissolving tank C, mechanically stirring for 10min, adding the solution in the dissolving tank A, and mixing for 15min to obtain the compound surface sizing solution with the solid content of 4.1% and the viscosity of 21cP.
The paper pulp is manufactured by a forming wire, and is subjected to surface sizing treatment by a metering rod sizing machine after being pressed and pre-dried, wherein the application amount of the composite surface sizing liquid is 1.9g/m 2 Back side application ofSurface sizing starch glue solution with the application amount of 1.1g/m 2 And (5) drying, calendaring and curling to obtain the aluminum-free lining paper for cigarettes.
The paper forming index is as follows: quantification: 70.5g/m 2 Thickness of: 68.6 μm, gas permeation amount: 1.31*10 7 ml/m 2 24 h.0.1 MPa, moisture permeability: 1916g/m 2 ·24h。
Moisture retention performance experiment: wrapping cigarettes by using the aluminum-free lining paper, putting the cigarettes in a common cigarette case as an experimental group, wherein the paper surface of the base paper is close to the cigarettes, and the surface of the surface adhesive is close to the cigarette case; the cigarettes are wrapped by using traditional aluminized paper and are put into a common cigarette case to be used as a control group. The outside of the cigarette case is not provided with a plastic film, the opening of the case is closed, and the cigarette case is placed in a room temperature environment to detect the moisture content of cigarettes at different time points. The results are shown in Table 3:
table 3 moisture change table for cigarettes
The foregoing is merely illustrative of the present invention, and the present invention is not limited thereto, and any person skilled in the art will readily appreciate variations or alternatives within the scope of the present invention. Therefore, the protection scope of the invention is subject to the protection scope of the claims.
Claims (8)
1. The environment-friendly aluminum-free moisturizing lining paper for cigarettes is characterized in that three functional structural layers are formed by making base paper and coating the surface of the base paper once, and the environment-friendly aluminum-free moisturizing lining paper comprises the following steps:
(1) Heating and decocting a certain amount of one or more of AKD, ASA, emulsified rosin and emulsion wax and polyvinyl alcohol in water to obtain a component A of the surface sizing agent;
(2) Dissolving a certain amount of boric acid and calcium chloride into water to obtain a component B of the surface sizing agent, wherein the solid content of boric acid is (0.1-4)%, and the solid content of calcium chloride is (0.1-35)%;
(3) Decocting one or more of gelatin, xanthan gum, guar gum, cellulose derivative, pregelatinized starch, polydextrose, its derivative, and polyvinyl alcohol in hot water to obtain component C of the surface sizing agent;
(4) Mixing the component A, the component B and the component C of the surface sizing agent to obtain a composite surface sizing solution, wherein the absolute dry mass ratio of the component A, B, C is 40-98:1-35:1-25;
(5) Uniformly mixing softwood pulp, hardwood pulp, filler, retention and drainage aid, reinforcing agent, crosslinked sodium alginate and internal sizing agent, feeding the mixture into a paper machine forming net for papermaking, squeezing the mixture to dehydrate, and drying the mixture before drying; the dryness of the dried paper sheet reaches (85-99)%;
(6) The paper sheet passes through a surface sizing machine, and the front surface of the paper sheet is subjected to surface sizing by using a composite surface sizing solution;
(7) And (3) drying the paper after the paper is dried, performing secondary drying, and performing calendaring finishing through a calendar, and curling to obtain the environment-friendly aluminum-free moisturizing lining paper.
2. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the absolute dry mass ratio of one or more of AKD, ASA, emulsified rosin and emulsion wax in the step (1) to polyvinyl alcohol is 0.5: 99.5-10:90, and the solid content is 3-10%; the specific process of heating and boiling in water is stirring (10-30) for a minute, then heating to 90-95 ℃ and preserving heat (30-60) for a minute, supplementing residual water and preserving heat at 40-60 ℃ for standby.
3. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the coating weight of the front surface of the base paper is (0.5-2.5) g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the The back surface can be coated with water, starch and compound surface sizing solution, the coating amount is (0.2-2.5) g/m 2 。
4. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the coating mode used is a roll coating mode.
5. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the basis weight of the finished paper is (40-100) g/m 2 。
6. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the gas transmission of the paper produced by the method is < 2 x 10 7 ml/m 2 24 h.0.1 MPa, moisture permeability of < 2500g/m 2 ·24h。
7. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the filler is calcium carbonate or talcum powder or kaolin; the retention and drainage aid is polyacrylamide or cationic starch, guar gum or a combined system of the retention and drainage aid and bentonite and silica sol microparticles; the reinforcing agent is modified starch or polyacrylamide or guar gum; the internal sizing agent is AKD or ASA or rosin size.
8. The environmentally friendly aluminum-free moisture-retaining lining paper for cigarettes of claim 1, wherein the lining paper comprises the following components in percentage by weight: the mass ratio of the softwood pulp to the hardwood pulp is 35-40:60-65, and the addition amount of the filler, the retention and filter aid, the reinforcing agent, the crosslinked sodium alginate and the internal sizing agent is 20-25%, 0.02-0.03%, 0.7-0.8%, 0.6-0.8% and 0.2% of the total amount of the softwood pulp and the hardwood pulp.
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| CN106320061A (en) * | 2016-09-06 | 2017-01-11 | 镇江大东纸业有限公司 | Production method of aluminum-free inner liner paper for cigarettes |
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| CN113912869A (en) * | 2021-11-02 | 2022-01-11 | 盐城工学院 | Method for preparing polyvinyl alcohol/sodium alginate/active carbon composite gel |
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| JP2000328482A (en) * | 1999-05-20 | 2000-11-28 | Harima Chem Inc | Sizing agent for paper making and paper using the same |
| US20120034398A1 (en) * | 2009-04-03 | 2012-02-09 | Yongzhong Wang | Media for inkjet web press printing |
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