CN116445007A - Yellow disperse dye composition and preparation method and application thereof - Google Patents

Yellow disperse dye composition and preparation method and application thereof Download PDF

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Publication number
CN116445007A
CN116445007A CN202310274760.0A CN202310274760A CN116445007A CN 116445007 A CN116445007 A CN 116445007A CN 202310274760 A CN202310274760 A CN 202310274760A CN 116445007 A CN116445007 A CN 116445007A
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CN
China
Prior art keywords
component
disperse dye
dye composition
yellow disperse
yellow
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310274760.0A
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Chinese (zh)
Inventor
卢学江
阮燕燕
王春燕
章国海
崇秋明
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Zhejiang Fuming Chemical Co ltd
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Zhejiang Fuming Chemical Co ltd
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Priority to CN202310274760.0A priority Critical patent/CN116445007A/en
Publication of CN116445007A publication Critical patent/CN116445007A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046Mixtures of two or more azo dyes
    • C09B67/0051Mixtures of two or more azo dyes mixture of two or more monoazo dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0079Azoic dyestuff preparations
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/008Preparations of disperse dyes or solvent dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/18Azo dyes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The application discloses a yellow disperse dye composition, which comprises the following components: a component a represented by formula (1):r in the formula (1) 1 Is C 1 ~C 4 Alkyl of (a); a component B represented by the formula (2):a component C represented by formula (3):

Description

Yellow disperse dye composition and preparation method and application thereof
Technical Field
The application relates to the technical field of dyes, in particular to a yellow disperse dye composition, a preparation method and application thereof.
Background
The disperse dye is a dye with extremely poor water solubility, the molecular weight is small, water-soluble groups are not contained in molecules, the disperse dye is often a crystal with high melting point, special processing treatment is needed, so that the disperse dye can be dyed in water in the form of highly dispersed particles, the disperse dye belongs to a nonpolar organic compound structurally, the dye does not contain hydrophilic groups, the disperse dye is subjected to special processing treatment in a general way, namely, an auxiliary agent which is several times of the dye is added for grinding, the particle size of the disperse dye is ground to a certain range, the disperse dye is in a highly dispersed state, the addition of the printing and dyeing auxiliary agent is a mixture which is used for changing the state of the disperse dye and is introduced, the mixture needs to be peeled off from the surface of fibers after the dyeing process is finished, and the mixture enters water, and is one of main COD sources of the disperse dye in the printing and dyeing process.
The current market has huge demand for dye, and there is a need for a disperse dye with low cost, excellent performance and environmental friendliness. Based on this, the present application provides a yellow disperse dye composition and a preparation method thereof.
Disclosure of Invention
In order to improve the performance of the disperse dye, the application provides a yellow disperse dye composition, and a preparation method and application thereof.
In a first aspect, the present application provides a yellow disperse dye composition, which adopts the following technical scheme:
a yellow disperse dye composition comprising:
at least one component A represented by formula (1):
r in the formula (1) 1 Is C 1 ~C 4 Alkyl of (a);
a component B represented by the formula (2):
a component C represented by formula (3):
preferably, the content of the component A is 12-35% based on 100% of the total mass of the yellow disperse dye composition; the content of the component B is 22-56%; the content of the component C is 26-66%.
Preferably, the content of the component A is 15-32% based on 100% of the total mass of the yellow disperse dye composition; the content of the component B is 25-52%; the content of the component C is 30-62%.
Preferably, the C1-C4 alkyl group includes a straight chain alkyl group or a branched chain alkyl group.
Further, the C1-C4 alkyl group includes methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl.
In a second aspect, the present application also provides a method for preparing a yellow disperse dye composition, comprising the steps of: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Preferably, the auxiliary materials comprise an auxiliary agent and water.
Preferably, the mass ratio of the auxiliary agent to the yellow dye composition is 2-3: 1.
preferably, the auxiliary agent comprises one or more of dispersing agent, system stabilizer, dyeing auxiliary agent, surfactant and bactericide.
Preferably, the dispersant comprises one or more of naphthalene sulfonic acid formaldehyde condensate (dispersing agent NNO), alkyl naphthalene sulfonic acid formaldehyde condensate (dispersing agent MF), benzyl naphthalene sulfonic acid formaldehyde condensate (dispersing agent CNF), lignin sulfonate (83A, lignin 85A).
Preferably, the system stabilizer comprises any one or more of polyethylene glycol-400, caprolactam and triethanolamine.
In a third aspect, the use of a yellow disperse dye for dyeing, pad dyeing and/or printing fabrics.
In summary, the present application has the following beneficial effects:
the disperse dye has the advantages of low cost, high strength, economy, environmental protection, gorgeous color and luster, high cost performance, good color fastness, obvious advantages in particular to light fastness and rubbing fastness, and higher color retention of clothes and cloth.
Detailed Description
The present application is further illustrated below in connection with specific embodiments.
Example 1
This example proposes a yellow disperse dye composition comprising:
a component a represented by formula (1):wherein R is 1 Is C 2 H 5
A component B represented by the formula (2):
a component C represented by formula (3):
wherein the content of the component A is 12 percent based on 100 percent of the total mass of the yellow disperse dye composition; the content of the component B is 22%; the content of component C was 66%.
The preparation method of the yellow disperse dye composition in the embodiment comprises the following steps: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Wherein, the auxiliary materials comprise auxiliary agents and water, and the mass ratio of the auxiliary agents to the yellow dye composition is 2:1, the auxiliary agent comprises dispersant lignin 85A and system stabilizer polyethylene glycol-400, wherein the mass ratio of the dispersant to the system stabilizer is 1.5:1.
Typically, 1g of the yellow disperse dye composition product is taken to disperse into 500ml of water.
Example 2
This example proposes a yellow disperse dye composition comprising:
component A1:wherein R1 is CH 3
Component A2:wherein R is 1 Is C 2 H 5
The weight ratio of the component A1 to the component A2 is 1:1;
a component B represented by the formula (2):
a component C represented by formula (3):
wherein the content of the component A is 28 percent based on 100 percent of the total mass of the yellow disperse dye composition; the content of the component B is 32%; the content of the component C is 40%.
The preparation method of the yellow disperse dye composition in the embodiment comprises the following steps: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Wherein the auxiliary materials comprise auxiliary agents and water, and the mass ratio of the auxiliary agents to the yellow dye composition is 2.5:1, the auxiliary agent comprises a dispersing agent alkyl naphthalene sulfonic acid formaldehyde condensate MF and a system stabilizer polycaprolactam, wherein the mass ratio of the dispersing agent to the system stabilizer is 2:1.
Typically, 1g of the yellow disperse dye composition product is taken to disperse into 500ml of water.
Example 3
This example proposes a yellow disperse dye composition comprising:
component A1:wherein R1 is C 2 H 5
Component A2Wherein R is 1 Is C 3 H 7
The weight ratio of the component A1 to the component A2 is 2:1;
a component B represented by the formula (2):
a component C represented by formula (3):
wherein the content of the component A is 35 percent based on 100 percent of the total mass of the yellow disperse dye composition; the content of the component B is 48%; the content of component C was 17%.
The preparation method of the yellow disperse dye composition in the embodiment comprises the following steps: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Wherein, the auxiliary materials comprise auxiliary agents and water, and the mass ratio of the auxiliary agents to the yellow dye composition is 3:1, the auxiliary agent comprises dispersant lignin 85A and system stabilizer polyethylene glycol-400, wherein the mass ratio of the dispersant to the system stabilizer is 1.5:1.
Typically, 1g of the yellow disperse dye composition product is taken to disperse into 500ml of water.
Example 4
This example proposes a yellow disperse dye composition comprising:
a component a represented by formula (1):wherein R is 1 Is C 2 H 5
A component B represented by the formula (2):
a component C represented by formula (3):
wherein the content of the component A is 28 percent based on 100 percent of the total mass of the yellow disperse dye composition; the content of the component B is 32%; the content of the component C is 40%.
The preparation method of the yellow disperse dye composition in the embodiment comprises the following steps: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Wherein the auxiliary materials comprise auxiliary agents and water, and the mass ratio of the auxiliary agents to the yellow dye composition is 2.5:1, the auxiliary agent comprises a dispersing agent alkyl naphthalene sulfonic acid formaldehyde condensate MF and a system stabilizer polycaprolactam, wherein the mass ratio of the dispersing agent to the system stabilizer is 2:1.
Typically, 1g of the yellow disperse dye composition product is taken to disperse into 500ml of water.
Unlike example 2, component A in this example contains only one type.
Example 5
This example proposes a yellow disperse dye composition comprising:
a component a represented by formula (1):wherein R is 1 Is C 3 H 7
A component B represented by the formula (2):
a component C represented by formula (3):
wherein the content of the component A is 35 percent based on 100 percent of the total mass of the yellow disperse dye composition; the content of the component B is 48%; the content of component C was 17%. The preparation method of the yellow disperse dye composition in the embodiment comprises the following steps: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
Wherein, the auxiliary materials comprise auxiliary agents and water, and the mass ratio of the auxiliary agents to the yellow dye composition is 3:1, the auxiliary agent comprises dispersant lignin 85A and system stabilizer polyethylene glycol-400, wherein the mass ratio of the dispersant to the system stabilizer is 1.5:1.
Typically, 1g of the yellow disperse dye composition product is taken to disperse into 500ml of water.
Unlike example 3, component A in this example contains only one type.
Comparative example 1
Comparative example 1 the yellow disperse dye composition does not contain component B relative to example 2, component B is replaced by component a in its entirety, with the other conditions being identical.
Comparative example 2
Comparative example 2 the yellow disperse dye composition does not contain component C relative to example 2, component C is replaced by component a in its entirety, with the other conditions being identical.
Comparative example 3
Comparative example 3 the yellow disperse dye composition does not comprise component B and component C relative to example 2, components B and C are all replaced by component a, with the other conditions being the same.
Comparative example 4
Comparative example 4 the yellow disperse dye composition does not contain component B relative to example 1, component B is replaced by component a in its entirety, with the other conditions being identical.
Comparative example 5
Comparative example 5 the yellow disperse dye composition does not contain component C relative to example 1, component C is replaced by component a in its entirety, with the other conditions being identical.
Performance testing
To verify the performance of the samples in the examples and comparative examples of the present invention, the test method performed the national dye unification test criteria as shown in table 1:
TABLE 1
According to the requirements of GB/T2374-2007 dye dyeing measurement, the yellow dye composition is applied to flat screen printing, and the printing process comprises the following steps: textile, printing, drying, baking, finishing and printing to obtain a finished product, wherein: the baking temperature was 100deg.C for 10 minutes, the baking temperature was 200deg.C for 1min, and the performance test results of the printed products are shown in Table 2 below:
TABLE 2
As can be seen from table 2: the printed finished products in examples 1-5 of the application all have superior light fastness, washing fastness, rubbing fastness and hot-pressing fastness compared with the printed finished products in comparative examples 1-5.
In comparison with examples 2 to 3, the single type of A component was used in each of examples 1 and examples 4 to 5, and the light fastness was also relatively inferior to that of example 1.
In addition, comparative example 4 does not contain component B with respect to the yellow disperse dye composition in example 1, taking example 1 as a standard, and component B is replaced by component a in its entirety, with the other conditions being the same; comparative example 5 the yellow disperse dye composition does not contain component C relative to example 1, component C is replaced by component a in its entirety, with the other conditions being identical.
With respect to the yellow disperse dye composition in example 2, comparative example 1 does not contain component B, which is replaced by component a in its entirety, with the same other conditions, taking example 2 as a standard; comparative example 2 the yellow disperse dye composition does not comprise component C, which is replaced by component a in its entirety, with the same other conditions as in example 2; comparative example 3 the yellow disperse dye composition does not comprise component B and component C relative to example 2, components B and C are all replaced by component a, with the other conditions being the same.
Finally, the data of the light fastness, the washing fastness, the rubbing fastness and the hot-pressing fastness in the example 1 and the example 2 obtained by detection are more excellent; this also shows that the compatibility of component a, component B and component C can greatly affect the color fastness of the printed product.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.

Claims (10)

1. A yellow disperse dye composition, comprising:
a component a represented by formula (1):
r in the formula (1) 1 Is C 1 ~C 4 Alkyl of (a);
a component B represented by the formula (2):
a component C represented by formula (3):
2. a yellow disperse dye composition according to claim 1, wherein the content of the component A is 12-35% based on 100% of the total mass of the yellow disperse dye composition; the content of the component B is 22-56%; the content of the component C is 26-66%.
3. A yellow disperse dye composition according to claim 1, wherein the C1-C4 alkyl group comprises a linear or branched alkyl group.
4. A process for preparing a yellow disperse dye composition according to claims 1-3, characterized in that the steps comprise: mixing the dye components, and then carrying out granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials; or the dye components are respectively subjected to granulation treatment by a sand mill or a grinding machine in the presence of auxiliary materials, and then are mixed.
5. The method for preparing a yellow disperse dye composition according to claim 4, wherein the auxiliary materials comprise an auxiliary agent and water.
6. The method for preparing a yellow disperse dye composition according to claim 5, wherein the mass ratio of the auxiliary agent to the yellow dye composition is 2-3: 1.
7. the method for preparing a yellow disperse dye composition according to claim 5, wherein the auxiliary agent comprises one or more of dispersing agent, system stabilizer, dyeing auxiliary agent, surfactant and bactericide.
8. The method for preparing a yellow disperse dye composition according to claim 7, wherein the dispersant comprises one or a combination of more than two of naphthalene sulfonic acid formaldehyde condensate, alkyl naphthalene sulfonic acid formaldehyde condensate, benzyl naphthalene sulfonic acid formaldehyde condensate and lignin sulfonate.
9. The method for preparing a yellow disperse dye composition according to claim 7, wherein the system stabilizer comprises any one or more of polyethylene glycol-400, caprolactam and triethanolamine.
10. Use of a yellow disperse dye according to any one of claims 1 to 8 for dyeing, pad dyeing and/or printing textiles.
CN202310274760.0A 2023-03-21 2023-03-21 Yellow disperse dye composition and preparation method and application thereof Pending CN116445007A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310274760.0A CN116445007A (en) 2023-03-21 2023-03-21 Yellow disperse dye composition and preparation method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310274760.0A CN116445007A (en) 2023-03-21 2023-03-21 Yellow disperse dye composition and preparation method and application thereof

Publications (1)

Publication Number Publication Date
CN116445007A true CN116445007A (en) 2023-07-18

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310274760.0A Pending CN116445007A (en) 2023-03-21 2023-03-21 Yellow disperse dye composition and preparation method and application thereof

Country Status (1)

Country Link
CN (1) CN116445007A (en)

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