CN116438283A - Color care detergent composition - Google Patents
Color care detergent composition Download PDFInfo
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- CN116438283A CN116438283A CN202280007506.8A CN202280007506A CN116438283A CN 116438283 A CN116438283 A CN 116438283A CN 202280007506 A CN202280007506 A CN 202280007506A CN 116438283 A CN116438283 A CN 116438283A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
Abstract
The need for detergent compositions that provide reduced dye bleed from fabrics is met by formulating the compositions using a combination of branched nonionic surfactants and cationic polymers.
Description
Technical Field
Laundry detergent compositions, particularly liquid laundry detergent compositions or unit dose articles, provide improved colored fabric care.
Background
The laundry detergent composition is formulated to provide good cleaning of fabrics: the white fabric is kept white and the colored fabric is kept bright. Laundry detergent compositions are also typically formulated to remove stains and soils. However, in addition to removing soil, laundry detergent compositions are also known to remove dye from colored fabrics, resulting in the fading of colored fabrics. In addition, dyes can deposit onto other fabrics that are laundered in the same cycle, resulting in the decolorization of the co-laundered fabrics.
To limit dye transfer to co-laundered fabrics, dye Transfer Inhibition (DTI) polymers are often incorporated into commercially available detergent compositions for cleaning colored fabrics. Typical dye transfer inhibitors are generally based on polymers such as polyvinylpyrrolidone homopolymer (PVP), polyvinylpyrrolidone/polyvinylimidazole copolymer (PVP/PVI) and poly-4-vinylpyridine N-oxide (PVNO). However, while such DTI polymers reduce the transfer of dye to the co-laundered fabric, they do not prevent the dye from exuding from the fabric resulting in dye fading.
Thus, there remains a need to provide detergent compositions with reduced dye exudation from fabrics.
WO2010025116A1 relates to stable color maintenance and/or rejuvenation compositions comprising at least one cationic polymer and an anionic surfactant, and methods of providing the compositions. WO2013070560A1 relates to a surface treatment composition comprising certain cationic polymers, anionic surfactants, one or more shielding salts and a hydrophobic association breaker, the surface treatment composition comprising at least 6 wt% cationic polymers, at least 6 wt% anionic surfactants and at least 4 wt% shielding salts, the weight ratio of anionic surfactants to cationic polymers being between 0.5:1 and 4:1, the composition further having a weight ratio of shielding salts to cationic polymers between 0.3:1 and 3:1. WO01/72937A1 relates to a method of reducing dye loss during a laundry treatment of dyed fabrics using a laundry treatment composition comprising a water soluble or water dispersible rebuild agent for deposition onto fabrics during a treatment process, wherein the material undergoes a chemical change during the treatment process by which the affinity of the material for the fabric is increased. WO2014139577A1 relates to a two-component colour detergent composition for use at low temperature comprising or consisting of a first component comprising at least one nonionic surfactant and a second component comprising at least one percarbonate (bleach) and tetraacetylethylene diamine (TAED), a process for preparing such a two-component colour detergent composition and to their use for cleaning laundry items, in particular coloured laundry. WO2017/044749A1 relates to a laundry washing or cleaning composition comprising (i) from about 0.001 wt% to about 50 wt% of at least one cationic polymer selected from the group consisting of: polyacrylamidopropyl trimethylammonium chloride poly (APT AC), polydiallyl dimethylammonium chloride poly (DADMAC), copolymers of poly (APTAC), copolymers of poly (DADMAC), terpolymers of poly (APTAC), and/or terpolymers of poly (DADMAC); (ii) About 0.01 wt% to about 50 wt% of at least one nonionic surfactant; (iii) Optionally, about 0.001 wt% to about 5 wt% of at least one enzyme; and (iv) optionally, from about 0.01 wt% to about 25 wt% of at least one laundry washing or cleaning additive, wherein the composition is capable of exhibiting wash fastness or color retention.
Disclosure of Invention
The present invention relates to a laundry detergent composition comprising a surfactant system and a cationic polymer, wherein the surfactant system comprises: a branched nonionic surfactant, and wherein the cationic polymer is selected from the group consisting of: poly (diallyldimethylammonium chloride); copolymers of diallyldimethyl ammonium chloride and acrylic acid; acrylamide and methacrylamideCopolymers of propyl trimethyl ammonium chloride; copolymers of acrylamide and diallyldimethylammonium chloride; copolymers of methacrylate, methacrylamidopropyl trimethylammonium chloride and acrylic acid; copolymers of acrylamide, methacrylamidopropyl trimethylammonium chloride and acrylic acid; copolymers of acrylamide, diallyldimethylammonium chloride and acrylic acid; copolymers of acrylamide and N, N-trimethylaminoethyl acrylate; copolymers of diallyldimethylammonium chloride and vinyl alcohol and mixtures thereof, wherein the cationic polymer has a molecular weight of 1,000da to 1,250,000da, wherein the branched nonionic surfactant is selected from the group consisting of: formula I: R1-CH (R2) -O- (PO) x (EO) y (PO) z -H, wherein, in formula I: r1 is a C4 to C14 alkyl chain, preferably C4 to C8, more preferably C6, R2 is a C1 to C7 alkyl chain, preferably C1 to C5, more preferably C3 alkyl chain, x is 0 to 10, preferably 0 to 5, more preferably 0 to 3, y is 5 to 20, preferably 6 to 15, more preferably 7 to 12, z is 0 to 20, preferably 0 to 5, more preferably 0 to 3, eo represents ethoxylation, and PO represents propoxylation; formula II: R1-CH (R2) CH 2 -O-(PO) x (EO) y (PO) z -H, wherein in formula II: r1 is a C3 to C13 alkyl chain, preferably C3 to C7, more preferably C5, R2 is a C1 to C7 alkyl chain, preferably C1 to C5, more preferably C3 alkyl chain, x is 0 to 10, preferably 0 to 5, more preferably 0 to 3, y is 5 to 20, preferably 6 to 15, more preferably 7 to 12, z is 0 to 20, preferably 0 to 5, more preferably 0 to 3, eo represents ethoxylation, and PO represents propoxylation; and mixtures thereof.
The invention also relates to the use of a laundry detergent composition comprising a branched nonionic surfactant for improving the color protection, preferably the color retention, of colored fabrics during laundering.
Detailed Description
The detergent compositions of the present invention have been found to result in reduced dye fade during washing.
Unless otherwise indicated, all component or composition levels are in terms of the active portion of the component or composition and do not include impurities, such as residual solvents or byproducts, that may be present in commercially available sources of such components or compositions.
All percentages and ratios are by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
All measurements were performed at 25 ℃ unless otherwise indicated.
As used herein, the articles "a" and "an" when used in the claims should be understood to mean one or more of the substance that is claimed or described.
Laundry detergent composition
The laundry detergent composition may be in any suitable form, such as a liquid, paste, granule, solid, powder, or in combination with a carrier such as a substrate. Preferred laundry detergent compositions are liquid or granular, with liquid being most preferred.
As used herein, "liquid detergent composition" refers to a liquid detergent composition that is fluid and preferably capable of wetting and cleaning fabrics, such as clothing in a household washing machine. As used herein, "laundry detergent composition" refers to a composition suitable for washing clothes. The composition may comprise a solid or a gas in a suitably finely divided form, but the overall composition does not comprise a generally non-fluid product form, such as a tablet or a granule. The liquid laundry detergent composition preferably has a density in the range of from 0.9 g/cc to 1.3 g/cc, more specifically from 1.00 g/cc to 1.10 g/cc, excluding any solid additives, but including any air bubbles (if present).
The composition may be an aqueous liquid laundry detergent composition. For such aqueous liquid laundry detergent compositions, the water content may be present at a level of from 5.0% to 95%, preferably from 25% to 90%, more preferably from 50% to 85% by weight of the liquid detergent composition.
The pH of the detergent composition ranges from 6.0 to 8.9, preferably from 7 to 8.8.
The detergent composition may also be encapsulated in a water-soluble film to form a unit dose article. Such unit dose articles comprise the detergent composition of the present invention, wherein the detergent composition comprises less than 20%, preferably less than 15%, more preferably less than 10% by weight of water, and the detergent composition is encapsulated in a water-soluble or water-dispersible film. Such unit dose articles may be formed using any method known in the art. Suitable unit dose articles may comprise a compartment wherein the compartment comprises a liquid laundry detergent composition. Alternatively, the unit dose article may be a multi-compartment unit dose article wherein at least one compartment comprises a liquid laundry detergent composition.
Cationic polymers
The cationic polymer is selected from the group consisting of: poly (diallyldimethylammonium chloride) (polyquaternium 6); copolymers of diallyldimethyl ammonium chloride and acrylic acid (such as polyquaternium 22); copolymers of acrylamide and methacrylamidopropyl trimethylammonium chloride; copolymers of acrylamide and diallyldimethylammonium chloride (polyquaternium 7); copolymers of methacrylate, methacrylamidopropyl trimethylammonium chloride and acrylic acid (polyquaternium 47); copolymers of acrylamide, methacrylamidopropyl trimethylammonium chloride and acrylic acid (polyquaternium 53); copolymers of acrylamide, diallyldimethylammonium chloride and acrylic acid (polyquaternium 39); copolymers of acrylamide and N, N-trimethylaminoethyl acrylate; copolymers of diallyldimethyl ammonium chloride and vinyl alcohol; and mixtures thereof, preferably selected from the group consisting of: the cationic polymer is selected from: poly (diallyldimethylammonium chloride) (such as polyquaternium 6); copolymers of diallyldimethyl ammonium chloride and acrylic acid (such as polyquaternium 22); copolymers of methacrylate, methacrylamidopropyl trimethylammonium chloride and acrylic acid (such as polyquaternium 47); and mixtures thereof, more preferably the cationic polymer is a copolymer of diallyldimethylammonium chloride and acrylic acid (such as polyquaternium 22).
For copolymers of diallyldimethylammonium chloride and acrylic acid, the preferred ratio of diallyldimethylammonium chloride to acrylic acid is between about 90:10 and 50:50. The preferred cationic polymer is a copolymer of diallyldimethylammonium chloride and acrylic acid in a molar ratio of 65/35 having a molecular weight of about 450,000. Copolymers of diallyldimethylammonium chloride and acrylic acid can be further described by the use of polyquaternium-22 or PQ22, which are named in the International cosmetic ingredient nomenclature. Copolymers of acrylamide and diallyldimethylammonium chloride may be further described by the use of polyquaternium-7 or PQ7, which are named in the International cosmetic ingredient nomenclature.
Table 1 below includes the cationic charge density and monomer molecular weight of the selected cationic polymer.
The cationic polymer may be present at a level of from 0.1% to 10%, preferably from 0.5% to 5.0%, more preferably from 1.0% to 2.5% by weight of the composition.
The cationic polymer has a molecular weight of from 1,000Da to 1,250,000Da, preferably from 100,000Da to 1,000,000Da, more preferably from 250,000Da to 750,000 Da.
The cationic polymer may have a charge density in the range of 0.05meq/g to 25meq/g when calculated at pH 7. Without being bound by theory, the molecular weight, charge density, and the presence of hydrophobic units within the polymer structure of the cationic polymer can affect the ability of the shielding salt to effectively prevent the formation of polymer-surfactant complexes.
Furthermore, the charge density may be in the range of 0.05meq/g to 25meq/g when calculated at pH 7, or preferably below 7.0meq/g, more preferably below 5.0meq/g, and even more preferably below 3.0meq/g when calculated at pH 7. As used herein, "charge density" refers to the charge density of the final polymer and may be different from the monomer feed. The charge density can be calculated by dividing the net charge number per repeat unit by the molecular weight of the repeat unit and then multiplying by 1000. It should be noted that the positive charge may be located on the backbone of the cationic polymer and/or on the side chains of the cationic polymer. In the case of cationic polymers with amine monomers, the charge density depends on the pH of the carrier, and thus the charge density for comparison with the present disclosure should be measured at a pH of 7.
Surfactant system
The laundry composition comprises a surfactant system in an amount of from 2.5% to 60%, preferably from 5.0% to 25%, more preferably from 7.0% to 15% by weight of the composition.
As used herein, a suitable surfactant is a surfactant or mixture of surfactants that provide a cleaning, stain removal or wash benefit to soiled materials. Suitable detersive surfactants may be: anionic surfactants, nonionic surfactants, zwitterionic surfactants, and combinations thereof.
The surfactant system comprises a branched nonionic surfactant. The surfactant system may further comprise a surfactant selected from the group consisting of: anionic surfactants, amphoteric surfactants, and mixtures thereof. Thus, the surfactant system may comprise a combination of anionic and nonionic surfactants, more preferably a combination of anionic, nonionic and amphoteric surfactants.
Preferably, surfactants containing saturated alkyl chains are used.
Branched nonionic surfactants
The surfactant system may comprise a branched nonionic surfactant in an amount of from 0.1% to 12%, preferably from 0.5% to 10%, more preferably from 1.0% to 3.0% by weight of the composition.
Suitable branched nonionic surfactants may be derived from primary or secondary alcohols. The branched nonionic surfactant is selected from the group consisting of:
a) Formula I: R1-CH (R2) -O- (PO) x (EO) y (PO) z -H
In formula I, R1 is a C4 to C14 alkyl chain, preferably C4 to C8, more preferably C6; r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain; x is 0 to 10, preferably 0 to 5, more preferably 0 to 3; y is 5 to 20, preferably 6 to 15, more preferably 7 to 12; and z is from 0 to 20, preferably from 0 to 5, more preferably from 0 to 3, eo represents ethoxylation, and PO represents propoxylation;
b) Formula II: R1-CH (R2) CH 2 -O-(PO) x (E0) y (PO) z -H
In formula II: r1 is a C3 to C13 alkyl chain, preferably C3 to C7, more preferably C5; r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain; x is 0 to 10, preferably 0 to 5, more preferably 0 to 3; y is 5 to 20, preferably 6 to 15, more preferably 7 to 12; and z is from 0 to 20, preferably from 0 to 5, more preferably from 0 to 3, eo represents ethoxylation and PO represents propoxylation.
Preferred branched nonionic ethoxylates according to formula I are those available under the trade name
15-S are those having a degree of alkoxylation of 3 to 40. For example an average degree of alkoxylation of 20 +.>
15-S-20. Other suitable commercially available materials according to formula I are those which are available under the trade name +.>
Those obtained from the M and EP series.
Preferred branched nonionic surfactants according to formula II are Guerbet C10 alcohol ethoxylates having 7 or 8 EO, such as
1007 and 1008, and Guerbet C10 alcohol alkoxylated nonionic surfactant (which is ethoxylated and/or propoxylated) such as commercially available +.>
XL series (XL 50, XL70, etc.). Other exemplary alkoxylated branched nonionic surfactants include those available under the trade name: />
XP30、/>
XP-50
XP-80 was available from BASF Corporation. In general, it can be considered- >
XP-30 has 3 repeating ethoxy groups and can be considered +.>
XP-50 has 5 repeating ethoxy groups and can be considered +.>
XP-70 has 7 repeating ethoxy groups. Other suitable branched nonionic surfactants include oxo-branched nonionic surfactants, such as +.>
ON 50 (5 EO) and ∈ ->
ON70 (7 EO). Other suitable branched nonionic surfactants include +.>
SLF 170 (3 PO, 12EO, 15 PO). Also suitable are: derived from Fischer&The Tropsch reaction contains up to 50% branched ethoxylated fatty alcohols (40% methyl (mono or di), 10% cyclohexyl), such as from Sasol +.>
Those of alcohol production; ethoxylated fatty alcohols derived from oxo reactions, wherein at least 50% by weight of the alcohols are C2 isomers (methyl to pentyl), such as from +.>
Alcohol or +.>
Those of alcohol preparation.
Additional nonionic surfactant
The liquid detergent composition may comprise an additional nonionic surfactant. The additional nonionic surfactant may be present in the liquid detergent composition in an amount of less than 15 wt%, preferably less than 7.0 wt%, more preferably less than 5.0 wt%, and even more preferably less than 3.0 wt%. Most preferably, the composition is free of additional nonionic surfactant.
Suitable nonionic surfactants include, but are not limited to, linear C12-C18 alkyl ethoxylates ("AE") (including so-called narrow peak alkyl ethoxylates) and C6-C12 alkylphenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), block alkylene oxide condensates of C6-C12 alkylphenols, alkylene oxide condensates of C8-C22 alkanols, and ethylene oxide/propylene oxide block polymers (Pluronic-BASF Corp.), and semi-polar nonionic materials (e.g., amine oxides and phosphine oxides) may be used in the compositions of the present invention. A broad disclosure of these types of surfactants can be found in U.S. Pat. No. 3,929,678.
Alkyl polysaccharides such as those disclosed in U.S. Pat. No. 4,565,647 are also nonionic surfactants useful in the compositions of the present invention.
Also suitable are alkyl polyglucoside surfactants.
Additional nonionic surfactants used include the formula R 1 (OC 2 H 4 ) n Those of OH, wherein R 1 Is a linear C10-C16 alkyl group or a C8-C12 alkylphenyl groupA group, and n is preferably 3 to 80. In some embodiments, the nonionic surfactant can be a condensation product of a linear C12-C15 alcohol with 5 to 20 moles of ethylene oxide per mole of alcohol, for example, a C12-C13 alcohol condensed with 6.5 moles of ethylene oxide per mole of alcohol.
Anionic surfactants
The surfactant system may comprise anionic surfactant in an amount of from 1.4% to 52% by weight of the liquid laundry detergent composition, preferably from 4.4% to 20% by weight, more preferably from 5.9% to 11.5% by weight.
The surfactant system may further comprise an anionic surfactant, preferably selected from the group consisting of: sulfonate surfactants, sulfate surfactants, and mixtures thereof, more preferably wherein the anionic surfactants include sulfonate surfactants and sulfate surfactants. Suitable anionic surfactants also include fatty acids and their salts, which are typically added as builders. However, by its nature, every anionic surfactant known in the art of detergent compositions can be used, as disclosed in the "Surfactant Science Series" 7 th edition by w.m. linfield (Marcel Dekker). However, the composition preferably comprises at least a sulphonic acid surfactant, such as linear alkylbenzenesulphonic acid, but water soluble salt forms may also be used. Alkyl sulphates or mixtures thereof are also preferred. Combinations of linear alkylbenzene sulfonate and alkyl sulfate surfactants are particularly preferred, especially for improved detergency.
Suitable anionic sulfonate or sulfonic acid surfactants for use herein include the acid and salt forms of alkylbenzene sulfonate, alkyl ester sulfonate, alkane sulfonate, alkyl sulfonated polycarboxylic acid, and mixtures thereof. Suitable anionic sulfonate or sulfonate surfactants include: C5-C20 alkylbenzene sulfonate, more preferably C10-C16 alkylbenzene sulfonate, more preferably C11-C13 alkylbenzene sulfonate, C5-C20 alkyl ester sulfonate, C6-C22 primary or secondary alkane sulfonate, C5-C20 sulfonated polycarboxylic acid, and any mixtures thereof, but preferably C11-C13 alkylbenzene sulfonate. The surfactants described above can vary widely in their 2-phenyl isomer content.
Anionic sulfates suitable for use in the compositions of the present invention include primary and secondary alkyl sulfates having a linear or branched alkyl or alkenyl moiety containing from 9 to 22 carbon atoms or more preferably from 12 to 18 carbon atoms. Also useful are beta-branched alkyl sulfate surfactants or mixtures of commercially available materials having a weight average degree of branching (of the surfactant or mixture) of at least 50%.
Mid-chain branched alkyl sulphates or sulphonates are also suitable anionic surfactants for use in the compositions of the present invention. Mid-chain branched alkyl primary sulphates of C5-C22, preferably C10-C20 are preferred. When mixtures are used, suitable average total carbon number of the alkyl moiety is preferably in the range of greater than 14.5 to 17.5. Preferred monomethyl branched primary alkyl sulfates are selected from the group consisting of: 3-methyl to 13-methylpentadecyl sulfate, the corresponding cetyl sulfate, and mixtures thereof. Dimethyl derivatives with mild branching or other alkyl sulphates capable of biodegradation may similarly be used.
When used, the alkyl alkoxylated sulfate surfactant may be a blend of one or more alkyl ethoxylated sulfates. Suitable alkyl alkoxylated sulfates include C10-C18 alkyl ethoxylated sulfates, more preferably C12-C15 alkyl ethoxylated sulfates. The anionic surfactant may comprise an alkyl sulfate surfactant, wherein the alkyl sulfate surfactant has an average degree of ethoxylation of from 0.5 to 8.0, preferably from 1.0 to 5.0, more preferably from 2.0 to 3.5.
Alternatively, the anionic surfactant may comprise an alkyl sulfate surfactant, wherein the alkyl sulfate surfactant has a low degree of ethoxylation, has an average degree of ethoxylation of less than 0.5, preferably less than 0.1, and more preferably is free of ethoxylation. Preferred low ethoxylated alkyl sulfate surfactants do not include any further alkoxylation. Preferred low ethoxylated alkyl sulfate surfactants include branched alkyl sulfate surfactants. The branched alkyl sulfate surfactant may comprise at least 20%, preferably from 60% to 100%, more preferably from 80% to 90% of the 2-branched alkyl chain by weight of the alkyl chain of the branched alkyl sulfate surfactant. Such branched alkyl sulfates having a 2-branched alkyl chain may also be described as 2-alkyl alkanol sulfates or 2-alkyl sulfates. The branched alkyl sulfate may be neutralized with sodium, potassium, magnesium, lithium, calcium, ammonium, or any suitable amine (such as, but not limited to, monoethanolamine, triethanolamine, and monoisopropanolamine) or with any neutralizing metal or mixture of amines. Suitable branched alkyl sulfate surfactants may comprise alkyl chains containing from 10 to 18 carbon atoms (C10 to C18) or from 12 to 15 carbon atoms (C12 to C15), with 13 to 15 carbon atoms (C13 to C15) being most preferred. Branched alkyl sulfate surfactants can be produced using a process that includes a hydroformylation reaction to provide the desired level of 2-branching. Particularly preferred branched alkyl sulfate surfactants comprise 2-branching, wherein the 2-branching comprises 20% to 80%, preferably 30% to 65%, more preferably 40% to 50% by weight of the 2-branching of methyl branching, ethyl branching, and mixtures thereof.
Suitable low ethoxylated branched alkyl sulfate surfactants may be derived from alkyl alcohols, such as
145、
145, both of which are provided by Sasol, optionally blended with other alkyl alcohols to achieve the desired branching distribution.
When fabrics are laundered with the compositions of the invention comprising such low ethoxylated alkyl sulfate surfactants, especially when the low ethoxylated alkyl sulfate surfactants comprise 2-branching as described above, lower levels of dye removal from the fabric during laundering can be achieved while maintaining cleaning performance when the fabric is laundered at 30 ℃ or less.
The process of preparing such alkyl ether sulfate anionic surfactants can result in the presence of trace residual amounts of 1, 4-dioxane by-products. The amount of 1, 4-dioxane by-product in the alkoxylated (especially ethoxylated) alkyl sulfate can be reduced. Based on recent technological advances, further reduction of 1, 4-dioxane by-products can be achieved by subsequent stripping, distillation, evaporation, centrifugation, microwave irradiation, molecular sieves or catalytic or enzymatic degradation steps. An alternative is to use alkyl sulfate anionic surfactants which contain only low levels of ethoxylation, or even no ethoxylation. Thus, the alkyl sulfate surfactant may have a degree of ethoxylation of less than 1.0, or less than 0.5, or even be free of ethoxylation.
Other suitable anionic surfactants for use herein include fatty methyl ester sulfonates and/or alkyl polyalkoxylated carboxylates, such as Alkyl Ethoxylated Carboxylates (AEC).
Anionic surfactants are generally present in their salt form with alkanolamines or alkali metals such as sodium and potassium.
To improve stability and grease cleaning, the liquid detergent composition may comprise a combination of linear alkylbenzene sulfonate surfactant and alkyl sulfate surfactant, preferably such that the ratio of linear alkylbenzene sulfonate surfactant to alkyl alkoxylated sulfate surfactant is from 15:1 to 0.1:1, preferably from 10:1 to 0.3:1, more preferably from 5:1 to 1:1.
Amphoteric and/or zwitterionic surfactants
The surfactant system may comprise an amphoteric and/or zwitterionic surfactant in an amount of from 0.1 wt% to 2.0 wt%, preferably from 0.1 wt% to 1.0 wt%, more preferably from 0.1 wt% to 0.5 wt% of the liquid laundry detergent composition.
Suitable amphoteric surfactants include amine oxide surfactants. The amine oxide surfactant is an amine oxide having the formula: r is R 1 R 2 R 3 NO, where R 1 Is a hydrocarbon chain comprising from 1 to 30, preferably from 6 to 20, more preferably from 8 to 16 carbon atoms, and wherein R 2 And R is 3 Independently of 1 to 4 carbon atomsSaturated or unsaturated, substituted or unsubstituted, straight or branched hydrocarbon chains of atoms, preferably 1 to 3 carbon atoms, and more preferably methyl groups. R is R 1 May be a saturated or unsaturated, substituted or unsubstituted, straight or branched hydrocarbon chain.
Amine oxides suitable for use herein are preferably those available, for example, from Albright&Wilson commercially available C 12 -C 14 Dimethyl amine oxide (lauryl dimethylamine oxide), which can be used under the trade name
LA is available from Clariant or under the trade name
DMC C commercially available from AKZO Nobel 12 -C 14 And (3) amine oxide.
Suitable amphoteric or zwitterionic detersive surfactants include those which are known for use in hair care or other personal care cleaning. Non-limiting examples of suitable zwitterionic or amphoteric surfactants are described in U.S. Pat. nos. 5,104,646, 5,106,609. Suitable amphoteric detersive surfactants include those surfactants which are broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched and wherein one of the aliphatic substituents contains 8 to 18 carbon atoms and one contains an anionic group such as carboxy, sulfonate, sulfate, phosphate, or phosphonate. Amphoteric detersive surfactants suitable for use in the present invention include, but are not limited to: cocoyl amphoacetate, cocoyl amphodiacetate, lauroyl amphoacetate, lauroyl amphodiacetate, and mixtures thereof.
Optional ingredients
The detergent composition may further comprise one or more of the following optional ingredients: external structurants or thickeners, enzymes, enzyme stabilizers, cleaning polymers, bleach systems, optical brighteners, hueing dyes, particulate matter, perfumes and other odor control agents, hydrotropes, suds suppressors, fabric care benefit agents, pH adjusting agents, dye transfer inhibitors, dye fixing polymers, preservatives, non-fabric substantive dyes, and mixtures thereof. In a more preferred embodiment, the laundry detergent composition does not comprise a bleach.
External structurants or thickeners: preferred external structurants and thickeners are those that do not rely on charge-charge interactions to provide structuring benefits. Likewise, particularly preferred external structurants are uncharged external structurants, such as those selected from the group consisting of: non-polymeric crystalline hydroxy-functional structurants such as hydrogenated castor oil; microfibrillated cellulose; uncharged hydroxyethyl cellulose; uncharged hydrophobically modified hydroxyethyl cellulose; hydrophobically modified ethoxylated urethanes; hydrophobically modified nonionic polyols; and mixtures thereof.
Suitable polymeric structurants include polymeric structurants of natural origin and/or synthetic origin.
Examples of natural-derived polymeric structurants for use in the present invention include: microfibrillated cellulose, hydroxyethyl cellulose, hydrophobically modified hydroxyethyl cellulose, carboxymethyl cellulose, polysaccharide derivatives and mixtures thereof. Non-limiting examples of microfibrillated cellulose are described in WO 2009/101545 A1. Suitable polysaccharide derivatives include: pectin, alginate, arabinogalactan (gum arabic), carrageenan, gellan gum, xanthan gum, guar gum, and mixtures thereof.
Examples of synthetic polymeric structurants or thickeners for the present invention include: polycarboxylates, hydrophobically modified ethoxylated polyurethanes (HEUr), hydrophobically modified nonionic polyols, and mixtures thereof.
Preferably, the aqueous liquid detergent composition has a viscosity of 50 to 5,000mpa.s, preferably 75 to 1,000mpa.s, more preferably 100 to 500mpa.s, when measured at a shear rate of 100s-1 and a temperature of 20 ℃. In order to improve the phase stability and also to improve the stability of the suspended ingredients, the aqueous liquid detergent composition has a viscosity of 50 to 250,000mpa.s, preferably 5,000 to 125,000mpa.s, more preferably 10,000 to 35,000mpa.s, when measured at a shear rate of 0.05s "1 and a temperature of 20 ℃.
Cleaning polymer: the detergent composition preferably comprises a cleaning polymer. It is believed that such cleaning polymers at least partially remove stains from textile fibers and enable the enzyme system to more effectively break down complexes comprising mannans and other polysaccharides. Suitable cleaning polymers provide soil cleaning and/or soil suspension for a wide range of surfaces and fabrics. Non-limiting examples of suitable cleaning polymers include: amphiphilic alkoxylated grease cleaning polymers; clay soil cleaning polymers; a soil release polymer; a soil suspending polymer. Preferred cleaning polymers are obtainable by free radical copolymerization of: at least one compound of formula (I),
wherein n is a number equal to or greater than 3,
with at least one compound of formula (II),
wherein A is - Represents an anion, in particular selected from the group consisting of halogen ions (such as fluoride, chloride, bromide, iodide), sulphate, bisulphate, alkylsulphate such as methyl sulphate, and mixtures thereof. Such polymers are further described in EP3196283 A1.
For similar reasons, polyester-based soil release polymers, such as SRA300 provided by Clariant, are also particularly preferred.
Other useful cleaning polymers are described in US20090124528 A1. The detergent composition may comprise amphiphilic alkoxylated grease cleaning polymers which may have balanced hydrophilic and hydrophobic properties, which allows them to remove grease particles from fabrics and surfaces. Suitable amphiphilic alkoxylated grease cleaning polymers may include a core structure and a plurality of alkoxylate groups attached to the core structure. These may include, for example, alkoxylated polyalkyleneimines. Such compounds may include, but are not limited to, ethoxylated polyethyleneimines, ethoxylated hexamethylenediamine, and sulfated forms thereof. A polytropylated derivative may also be included. A variety of amines and polyalkyleneimines can be alkoxylated to various degrees. One useful example is a 600g/mol polyethyleneimine core, each NH of which is ethoxylated to 20 EO groups and is available from BASF. The alkoxylated polyalkyleneimines may have an internal polyethyleneoxy block and an external polypropyleneoxy block. The detergent composition may comprise from 0.1% to 10%, preferably from 0.1% to 8.0%, more preferably from 0.1% to 2.0% by weight of the detergent composition of the cleaning polymer.
Dye transfer inhibition polymer: the detergent composition may comprise one or more dye transfer inhibition polymers. However, preferred compositions do not include such dye transfer inhibiting polymers. It has been found that during laundering, many fabric dyes are distributed between the fabric and the wash liquor. Thus, it has been found that chelation of dye in wash liquor using DTI polymer increases removal of dye from fabric and hence increases dye fade.
When used, suitable dye transfer inhibition may be selected from the group consisting of: polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridine chloride, poly (2-hydroxypropyl dimethyl ammonium chloride), and mixtures thereof, preferably polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI), and mixtures thereof. Dye transfer inhibiting agents, if present, may be present at levels of from 0.05% to 5%, or from 0.1% to 3%, and alternatively from 0.2% to 2.5% by weight of the detergent composition.
Polyvinylpyrrolidone ("PVP") has an amphiphilic nature, wherein highly polar amide groups impart hydrophilic and polar attractive properties,and also has non-polar methylene and methane groups in the backbone and/or in the ring that impart hydrophobic properties. In dye molecules, these rings may also provide planar alignment with the aromatic rings. PVP is readily soluble in aqueous and organic solvent systems. PVP is commercially available in the form of several viscosity grades of powder or aqueous solutions. The compositions of the present invention preferably use copolymers of N-vinylpyrrolidone and N-vinylimidazole (also abbreviated herein as "PVPVI"). It has been found that copolymers of N-vinylpyrrolidone and N-vinylimidazole can provide excellent dye transfer inhibition properties. The copolymer of N-vinylpyrrolidone and N-vinylimidazole may have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of from 1:1 to 0.2:1, more preferably from 0.8:1 to 0.3:1, most preferably from 0.6:1 to 0.4:1. The copolymers of N-vinylpyrrolidone and N-vinylimidazole may be linear or branched. Particularly suitable polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) and copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI) may have a weight average molecular weight of from 5,000Da to 1,000,000Da, preferably from 5,000Da to 50,000Da, more preferably from 10,000Da to 20,000 Da. The number average molecular weight range is determined by light scattering as described in volume Chemical Analysis, volume 1, volume 13, of "Modern Methods of Polymer Characterization" of Barth j.h.g. and Mays j.w. Copolymers of poly (N-vinyl-2-pyrrolidone) and poly (N-vinyl-imidazole) are commercially available from a number of sources, including BASF. Preferred DTI is available under the trade name 
HP 56K is commercially available from BASF (BASF SE, germany).
Organic builders and/or chelating agents: the laundry detergent composition may comprise from 0.6 wt% to 10 wt%, preferably from 2 wt% to 7 wt% of one or more organic builders and/or chelants. Suitable organic builders and/or chelating agents are selected from the group consisting of: MEA citrate, citric acid, aminoalkylene poly (alkylene phosphonate), alkali metal ethane 1-hydroxy bisphosphonate, nitrilotrimethylene phosphonate (phosphinates), diethylenetriamine penta (methylene phosphonic acid) (DTPMP),ethylenediamine tetra (methylenephosphonic acid) (EDTMP), hexamethylenediamine tetra (methylenephosphonic acid), hydroxy-ethylene-1, 1-diphosphonic acid (HEDP), hydroxyethanedimethylene phosphonic acid, ethylenediamine disuccinic acid (EDDS), ethylenediamine tetraacetic acid (EDTA), hydroxyethylethylene diamine triacetate (HEDTA), nitrilotriacetate (NTA), methylglycine diacetate (MGDA), iminodisuccinate (IDS), hydroxyethyiiminodisuccinate (HIDS), hydroxyethyiiminodiacetate (HEIDA), glycine diacetate (GLDA), diethylenetriamine pentaacetic acid (DTPA), catechol sulfonates such as Tiron TM And mixtures thereof.
Enzyme: suitable enzymes provide cleaning performance and/or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, cutinases, reductases, oxidases, phenol oxidases, lipoxygenases, ligninases, pullulanases, tannase, pentosanases, mailanases, beta-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and known amylases, or combinations thereof. Preferred enzyme combinations comprise mixtures of conventional detersive enzymes such as proteases, lipases, cutinases and/or cellulases in combination with amylases. Detersive enzymes are described in more detail in U.S. Pat. No. 6,579,839.
Enzyme stabilizer: the enzymes may be stabilized using any known stabilizer system such as calcium and/or magnesium compounds, boron compounds and substituted boric acids, aromatic borates, peptides and peptide derivatives, polyols, low molecular weight carboxylic acid esters, relatively hydrophobic organic compounds [ e.g., certain esters, dialkyl glycol ethers, alcohols or alcohol alkoxylates ], alkyl ether carboxylates other than a calcium ion source, benzamidine hypochlorites, lower aliphatic alcohols and carboxylic acids, N-bis (carboxymethyl) serine salts; (meth) acrylic acid- (meth) acrylate copolymer and PEG; lignin compounds, polyamide oligomers, glycolic acid or salts thereof; polyhexamethylene biguanide or N, N-bis-3-aminopropyl dodecylamine or salt; and mixtures thereof.
Hueing dye: the detergent composition may comprise a fabric hueing agent (sometimes referred to as an opacifier, bluing agent or whitening agent). Toners generally provide a blue or violet hue to fabrics. Toners can be used alone or in combination to create a particular hueing tone and/or to hueing different fabric types. This may be provided, for example, by mixing red and cyan dyes to produce a blue or violet hue. The toner may be selected from any known chemical class of dyes including, but not limited to, acridine, anthraquinone (including polycyclic quinones), azine, azo (e.g., monoazo, disazo, trisazo, tetrazo, polyazo), including pre-metallized azo, benzodifuran and benzodifuranone, carotenoids, coumarin, cyanine, diazahemicyanine, diphenylmethane, formazan, hemicyanine, indigoids, methane, naphthalimide, naphthoquinone, nitro and nitroso, oxazine, phthalocyanine, pyrazoles, stilbene, styryl, triarylmethane, triphenylmethane, xanthene, and combinations thereof.
Optical brighteners: the detergent composition may comprise from 0.005% to 2.0%, preferably from 0.01% to 0.1% of fluorescent agent (optical brighteners), by weight of the total detergent composition. Fluorescent agents are well known and many are commercially available. Typically, these fluorescent agents are provided and used in the form of their alkali metal salts (e.g., sodium salts). Preferred classes of fluorescent agents are: distyrylbiphenyl compounds, e.g. 
CBS-X; diamine stilbenedisulfonic acid compounds, for example +.>
DMS pure Xtra and +.>
HRH; and pyrazoline compounds, such as +.>
SN. Preferred fluorescers are: 2- (4-benzene)Vinyl-3-sulfophenyl) -2H-naphthol [1,2-d]Triazole sodium, 4' -bis { [ (4-anilino-6- (N-methyl-N-2-hydroxyethyl) amino 1,3, 5-triazin-2-yl)]Amino } stilbene-2-2 '-disulphonic acid disodium salt, 4' -bis { [ (4-anilino-6-morpholino-1, 3, 5-triazin-2-yl)]Disodium amino } stilbene-2-2 '-disulfonate and disodium 4,4' -bis (2-sulfostyryl) biphenyl.
Hydrotropes: the detergent composition may comprise from 0% to 30%, preferably from 0.5% to 5%, more preferably from 1.0% to 3.0% of a hydrotrope, by weight of the total detergent composition, which may prevent liquid crystal formation. Thus, the addition of a hydrotrope aids in the clarity/clarity of the composition. Suitable hydrotropes include, but are not limited to, urea, benzenesulfonate, toluenesulfonate, xylenesulfonate, or isopropylbenzenesulfonate. Preferably, the hydrotrope is selected from the group consisting of: propylene glycol, xylene sulfonate, ethanol, and urea to provide optimal performance.
And (3) particles: the composition may also comprise particles, especially when the composition further comprises a structuring agent or thickener. The composition may comprise from 0.02% to 10%, preferably from 0.1% to 4.0%, more preferably from 0.25% to 2.5% of particles, by weight of the total composition. The particles include beads, pearlescing agents, capsules, and mixtures thereof.
Suitable capsules are typically formed by at least partially, preferably completely, surrounding the benefit agent with a wall material. Preferably, the capsule is a perfume capsule, wherein the benefit agent comprises one or more perfume raw materials. The capsule wall material may comprise: melamine, polyacrylamide, silicone, silica, polystyrene, polyurea, polyurethane, polyacrylate-based materials, gelatin, styrene maleic anhydride, polyamides, aromatic alcohols, polyvinyl alcohol, resorcinol-based materials, polyisocyanate-based materials, acetals (such as 1,3, 5-triol-benzene-glutaraldehyde and 1,3, 5-triol-benzene melamine), starch, cellulose acetate phthalate, and mixtures thereof. Preferably, the capsule wall comprises melamine and/or polyacrylate based material. The perfume capsule may be coated with a deposition aid, a cationic polymer, a nonionic polymer, an anionic polymer, or mixtures thereof. Preferably, the perfume encapsulates have a volume weighted median particle size of from 0.1 microns to 100 microns, preferably from 0.5 microns to 60 microns. Especially when the composition comprises a capsule having a shell formed at least in part from formaldehyde, the composition may further comprise one or more formaldehyde scavengers.
Process for preparing laundry detergent compositions：
The laundry detergent composition may be prepared using any suitable method known to the skilled person. Typically, the ingredients are blended together in any suitable order. Preferably, the detersive surfactant is added as part of a concentrated premix to which other optional ingredients are added. Preferably, the solvent is added last, or if the external structurant is added immediately before the external structurant, then the external structurant is added as the last ingredient.
Method for washing fabrics：
The laundry detergent compositions of the present invention are useful for laundering fabrics.
In particular, laundry detergent compositions comprising branched nonionic surfactants are useful for improving the color protection, preferably the color retention, of colored fabrics during laundering.
The laundry detergent compositions of the present invention are particularly useful for preventing the removal of fabric dyes from fabrics during the wash process, said fabric dyes being selected from the group consisting of: reactive dyes, disperse dyes, and mixtures thereof, preferably wherein the fabric dye is selected from the group consisting of: disperse dyes, reactive dyes, and mixtures thereof.
The composition of the invention is particularly effective for reducing the removal of dye from cotton-containing fabrics, especially cotton-containing fabrics having a dye selected from the group consisting of: reactive dyes, disperse dyes, direct dyes, vat dyes, and mixtures thereof; preferably, wherein the reactive dye is selected from the group consisting of: the reactive dye is selected from the group consisting of: reactive black 5, reactive red 239, reactive red 195, the direct dye being selected from the group consisting of: direct black 22, direct red 83, and the vat dye is selected from the group consisting of: indigo (vat blue 1), sulphur black 1, and mixtures thereof. The composition of the invention is particularly useful for reducing the removal of dye from cotton-containing fabrics having a dye selected from the group consisting of: reactive dyes, in particular reactive dyes selected from the group consisting of: reactive black 5, reactive red 239, and mixtures thereof.
The composition of the present invention is also effective in reducing the removal of dye from polyester-containing fabrics, particularly polyester-containing fabrics comprising disperse dyes selected from the group consisting of: disperse orange 30, disperse red 167, disperse blue 79, disperse red 60, and mixtures thereof, preferably disperse blue 79.
In such methods and uses, the laundry detergent composition may be diluted to provide a wash liquor having a total surfactant concentration of greater than 300ppm, preferably 400ppm to 2,500ppm, more preferably 600ppm to 1000 ppm. The fabric is then washed in a wash liquor, and preferably rinsed.
Method：
A) PH measurement：
The pH was measured at 25℃using a Santarius PT-10P pH meter with a gel filled probe (such as Toledo probe, part number 52 000 100) calibrated according to the instructions. The pH was measured at 10% dilution in deionized water (i.e., 1 part laundry detergent composition and 9 parts deionized water).
B) Method for measuring viscosity：
Viscosity was measured using an AR 2000 rheometer from TA instruments using a cone plate geometry with a diameter of 40mm and an angle of 1 °. Via a reaction at 20℃for a period of 3 minutes over a period of 0.1s -1 To 1200s -1 Is used to measure viscosity at different shear rates. At 0.05s -1 Low shear viscosity is measured at continuous shear rate.
Examples：
The following methods were used to evaluate the effect of branched and linear nonionic surfactants on dye exudation during washing.
As described below, a glass vial (4 ml size) was filled with 2ml of test detergent solution, followed by subsequent insertion of a thermal shaker at 40℃temperature 
Orbital oscillators). The solution was held at this temperature for 15 minutes in order to equilibrate the temperature.
The colored fabric samples described below were cut into pieces150±1mg(weighed using analytical balance). The sheets had an area of about 2.5X2.5 cm (depending on the fabric used). Additional identical pieces of fabric are added to achieve the target weight, if necessary.
Each piece of textile fabric was folded and then inserted into the vial using a disposable glass rod so that the fabric was completely covered with solution, and then the vial was returned to the thermal shaker.
The vials were continuously shaken (set using medium speed) at a temperature of 40 ℃ for 60 minutes.
The vials were then removed from the hot shaker and the fabric was removed from the test detergent solution. The solution was kept in the dark for the time required to reach room temperature (25 ℃).
Dye desorption quantification was as follows:
950 μl of each solution was placed in a semi-microplastic cuvette and their absorbance spectra were recorded using a UV-vis spectrophotometer (Cary UV-Vis Multicell Peltier, supplied by Agilent), and the absorbance between 300nm and 900nm was measured.
To each solution was added 50 μl of an aqueous solution of 20 wt% 2- [4- (2, 4-trimethylpent-2-yl) phenoxy ] ethanol (Triton X-100, supplied by Sigma Aldrich), and the absorbance spectrum between 300nm and 900nm was measured again. Triton X-100 was added because Triton X-100 was observed to strongly reduce the scattering of the tested surfactant in the region overlapping the dye absorption spectrum at the concentrations tested used.
The calibration curve for each dye used was obtained using the following procedure:
first, the following reference detergent solutions were prepared:
preparation of equal parts by weight of Linear C10-C13 Alkylbenzenesulfonic acid (HLAS), linear C12-C15 Alkylethoxy (3.0) sulfate (AE3.0S) and Linear C12-C14 EO7 (Loradac L726, supplied by Sasol) at a hardness of 2.67mmol CaCO 3 Equivalent (CaCl) 2 1.93mmol，MgCl 2 0.64mmol,15 gpg) of 350ppm of aqueous solution in water. The pH of the resulting solution was adjusted to 8.0 using ethanolamine.
2.0ml of the composition was placed in a glass vial together with 150mg of each fabric and washed using the procedure described above, but at a temperature of 92 ℃ for 15 minutes.
After cooling to room temperature in the dark, 950. Mu.l of the resulting solution containing the desorbing dye was mixed with 50. Mu.l of an aqueous solution of 20% by weight 2- [4- (2, 4-trimethylpent-2-yl) phenoxy ] ethanol (Triton X-100). The absorbance spectra were measured as described above and these solutions were arbitrarily fixed as 95% dye desorption. The solution was diluted in the following medium: 95% of the above reference detergent solution was mixed with 5% Triton X-100 (20% by weight) to obtain a calibration curve for each dye used.
The absorbance values (of the main peaks of the different dye samples) resulting from the desorption experiments were reported as a percentage of the value of the same dye desorbed using the reference detergent solution at 92 ℃ in the calibration procedure described above.
The effect of the following solutions on dye bleeding of both dyed cotton fabrics (cotton fabrics dyed with reactive black 5, supplied by CFT under product code AISE code 21) and dyed polyester fabrics (polyester fabrics dyed with disperse blue 79, supplied by CFT under product code AISE code 31) was evaluated, and the following results were given. The solutions used in the remaining groups contained 350ppm of surfactant, except for groups a and F (water).
Table 1: desorption (after 1 hour) at 40 ℃ relative to 92 ℃ for cotton fabric using the reference detergent solution
Desorption under
| Group of | Test solution | Desorption of reactive Black 5 dye from Cotton |
| A | Water and its preparation method 1 | 46.8 |
| B | Reference detergent solution 2 | 64.9 |
| C | Straight chain C12-C14 EO7 3 | 72.4 |
| D | 2-propyl-1-heptyl EO7 4 | 51.1 |
| E | 2-propyl-1-heptyl (PO) 3 (EO) 12 (PO) 15 5 | 47.4 |
1 Hardness 2.67mmol CaCO 3 Equivalent (15 gpg)
2 1:1:1 weight ratio of linear C10-C13 alkylbenzenesulfonic acid (HLAS), linear C12-C15 alkyl ethoxy (3.0) sulfuric acidSalt (AE3.0S) and linear C12-C14 EO7
L726 supplied by Sasol)
3 
L726 supplied by Sasol
4 
XP70, supplied by BASF
5 
SLF180 supplied by BASF
Table 2: desorption (after 1 hour) at 40 ℃ versus 92 using the reference detergent solution for polyester fabrics
Desorption at C
| Group of | Test solution | Desorption of disperse blue 79 dye from polyester |
| F | Water and its preparation method 1 | 8.5 |
| G | Reference detergent solution 2 | 50.3 |
| H | Straight chain C12-C14 EO7 3 | 65.7 |
| I | 2-propyl-1-heptyl EO7 4 | 10.3 |
| J | 2-propyl-1-heptyl (PO) 3 (EO) 12 (PO) 15 5 | 12.4 |
By comparing the dye desorption of group B and group a of cotton fabrics with the dye desorption of group G and group F of polyester fabrics, the effect of the detergent on dye exudation from the fabrics during laundering can be seen.
As can be seen by comparing the dye exudation of groups D and E with that of group C, the branched nonionic surfactant provides reduced dye exudation when washing cotton compared to the linear branched nonionic surfactant. Comparison of group I and group J with group H shows that the branched nonionic surfactant has the same benefit when washing polyester fabrics.
From groups B and G it can be seen that dye penetration is lower for both cotton and polyester fabrics when the wash temperature is reduced (from 92 ℃ to 40 ℃).
The following comparative tests demonstrate reduced dye bleed during washing when using the compositions of the present invention.
The following compositions were prepared by simple mixing.
Table 3: comparison of laundry liquid compositions (example A and example B) and laundry liquid sets of the invention
Compound (example 1)
| Example A | Example B | Example 1 | |
| Weight percent | Weight percent | Weight percent | |
| C10-C13 Linear alkylbenzene sulfonate | 3.6 | 3.6 | 3.6 |
| C12-C15AE3.0S | 2.5 | 2.5 | 2.5 |
| Straight chain C12-C14EO7 3 | 2.2 | 2.2 | -- |
| 2-propyl-1-heptyl EO7 4 | -- | -- | 2.2 |
| C12-C14 dimethylaminooxides | 0.33 | 0.33 | 0.33 |
| TPK fatty acids | 2.16 | 2.16 | 2.16 |
| Citric acid | 1.7 | 1.7 | 1.7 |
| Polyquaternium 22 6 | -- | 1.4 | 1.4 |
| PEG-PVAc polymers 7 | 0.5 | 0.5 | 0.5 |
| Enzymes | 0.006 | 0.006 | 0.006 |
| Ethylene diamine tetra (methylene phosphonic acid) (EDTMP) | 0.55 | 0.55 | 0.55 |
| Spice | 0.82 | 0.82 | 0.82 |
| Water and its preparation method | To 100% | To 100% | To 100% |
6 Cationic polymer Merquat 281, having a molecular weight of 450000Da, supplied by Lubrizol
7 Polyvinyl acetate grafted polyethylene oxide copolymers having a polyethylene oxide backbone and a plurality of polyvinyl acetate side chains, supplied by BASF, germany
Cotton fabric pre-dyed with activated red 239 (AISE 17, supplied by CFT) was cut into 6cm x 6cm pieces. If it is desired to avoid fraying of the fabric edges, the plastic edges are applied to the fabric squares under heat.
The terglometer tank was filled with 4.3grs of each example composition and water (hardness 2.67mmol CaCO) 3 Equivalent (15 gpg)) to form 1L of wash liquor. To each tergotometer pot the following fabric samples were added:
-3 samples of activated Red 239
Ballast of 5g black cotton
Ballast of 3g of black polyester
6X 6cm samples of the other colours until a total fabric load of 45g is reached
The terglometer tank was heated to a temperature of 60 ℃ and stirred at 300rpm for 40 minutes. After washing, the test fabric and ballast were spun at 1000rpm for 2 minutes, then rinsed twice in water at 20 ℃ and hardness of 2.67mmol CaCO3 equivalents (15 gpg) for 5 minutes, and the spin step after each rinse was 1000rpm for 2 minutes. In the final step, the fabric is drum dried. The washing cycle was repeated for a total of 5 cycles.
The color change of the test samples relative to the unwashed reference fabric was analyzed using a spectrophotometer (Konika Minolta CM-3610A) and measured on the Δecmc scale. The results are given in table 4 below.
Each tank contained three pieces of each test fabric (three internal replicates); each composition was added to two different tanks (two external replicates) and the Δe CMC readings for each treatment were averaged.
Table 4: Δecmc (lower value corresponds to less fading) for laundered fabrics relative to unwashed fabrics
| Reactive red 239 cotton fabric | |
| Example A (containing a linear nonionic surfactant and no cationic Polymer) | 4.6 |
| Example B (comprising a Linear nonionic surfactant and a cationic Polymer) | 4.2s* |
| Example 1 (comprising branched nonionic surfactant and cationic Polymer) | 3.9s* |
* The significance of the calculation was relative to example a via Anova HSD (where α=0.05)
From the above data, it can be seen that washing with the composition of the present invention (example 1) resulted in less dye fade than the comparative composition comprising cationic polymer and linear nonionic surfactant (example B) or no cationic polymer and nonionic surfactant.
Table 5: further examples of compositions of the invention。
| Example 2 | Example 3 | Example 4 | |
| Weight percent | Weight percent | Weight percent | |
| C10-C13 Linear alkylbenzene sulfonate | 5 | 3 | 3.6 |
| C12-C15AE3.0S | 2.2 | 3 | 2.2 |
| Straight chain C12-C14EO7 3 | -- | -- | -- |
| 2-propyl-1-heptyl EO7 4 | -- | 3 | -- |
| 2-propyl-1-heptyl (PO) 3 (EO) 12 (PO) 15 5 | 1.9 | 2.5 | |
| C12-C14 dimethylaminooxides | 0.5 | 0.1 | 0.4 |
| TPK fatty acids | 1 | 0.5 | 2 |
| Citric acid | 1 | 0.5 | 1.5 |
| Polyquaternium 22 6 | -- | -- | 1.5 |
| Polyquaternium 7 8 | 1 | 0.5 | -- |
| PEG-PVAc polymers 7 | 0.5 | 0.2 | 0.3 |
| Enzymes | 0.001 | 0.001 | 0.001 |
| Ethylene diamine tetra (methylene phosphonic acid) (EDTMP) | 0.5 | 0.4 | 0.3 |
| Spice | 1.0 | 0.8 | 1.2 |
| Water and its preparation method | To 100% | To 100% | To 100% |
8 Poly (diallyldimethylammonium chloride/acrylamide), merquat 740, molecular weight 100,000Da, supplied by Lubrizol
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Rather, unless otherwise indicated, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40mm" is intended to mean "about 40mm".
Claims (14)
1. A laundry detergent composition comprising a surfactant system and a cationic polymer, wherein
The surfactant system comprises: branched nonionic surfactant, and
wherein the cationic polymer is selected from the group consisting of: poly (diallyldimethylammonium chloride); copolymers of diallyldimethyl ammonium chloride and acrylic acid; copolymers of acrylamide and methacrylamidopropyl trimethylammonium chloride; copolymers of acrylamide and diallyldimethylammonium chloride; copolymers of methacrylate, methacrylamidopropyl trimethylammonium chloride and acrylic acid; copolymers of acrylamide, methacrylamidopropyl trimethylammonium chloride and acrylic acid; copolymers of acrylamide, diallyldimethylammonium chloride and acrylic acid; copolymers of acrylamide and N, N-trimethylaminoethyl acrylate; copolymers of diallyldimethylammonium chloride and vinyl alcohol, and mixtures thereof,
Wherein the cationic polymer has a molecular weight of 1,000da to 1,250,000da, wherein the branched nonionic surfactant is selected from the group consisting of:
a) Formula I: R1-CH (R2) -O- (PO) x (EO) y (PO) z -H
Wherein, in formula I:
r1 is a C4 to C14 alkyl chain, preferably C4 to C8, more preferably C6;
r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain;
x is 0 to 10, preferably 0 to 5, more preferably 0 to 3;
y is 5 to 20, preferably 6 to 15, more preferably 7 to 12;
z is 0 to 20, preferably 0 to 5, more preferably 0 to 3;
EO represents ethoxylation, and PO represents propoxylation;
b) Formula II: R1-CH (R2) CH 2 -O-(PO) x (EO) y (PO) z -H
Wherein in formula II:
r1 is a C3 to C13 alkyl chain, preferably C3 to C7, more preferably C5;
r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain;
x is 0 to 10, preferably 0 to 5, more preferably 0 to 3;
y is 5 to 20, preferably 6 to 15, more preferably 7 to 12;
z is 0 to 20, preferably 0 to 5, more preferably 0 to 3;
EO represents ethoxylation, and PO represents propoxylation;
c) And mixtures thereof.
2. The laundry detergent composition according to claim 1, wherein surfactant system comprises the branched nonionic surfactant in an amount of from 0.1% to 12%, preferably from 0.5% to 10%, more preferably from 1% to 3% by weight of the composition.
3. The laundry detergent composition according to any preceding claim, wherein the laundry composition comprises the surfactant system in an amount of from 1 wt% to 70 wt%, preferably from 10 wt% to 50 wt%, more preferably from 15 wt% to 35 wt%.
4. The laundry detergent composition according to any preceding claim, wherein the surfactant system further comprises an anionic surfactant, preferably selected from the group consisting of: sulfonate surfactants, sulfate surfactants, and mixtures thereof, more preferably wherein the anionic surfactants include sulfonate surfactants and sulfate surfactants.
5. The laundry detergent composition according to claim 4, wherein the anionic surfactant comprises an alkyl sulfate surfactant, wherein the alkyl sulfate surfactant has an average degree of ethoxylation of from 0.5 to 8.0, preferably from 1.0 to 5.0, more preferably from 2.0 to 3.5.
6. The laundry detergent composition according to claim 4, wherein the anionic surfactant comprises an alkyl sulfate surfactant, wherein the alkyl sulfate surfactant has an average degree of ethoxylation of less than 0.5, preferably wherein the alkyl sulfate surfactant comprises a branched alkyl sulfate surfactant, more preferably wherein the branched alkyl sulfate surfactant comprises at least 20% 2-branched alkyl chains by weight of the alkyl chains of the branched alkyl sulfate surfactant.
7. A laundry detergent composition according to any preceding claim, wherein the surfactant system comprises an amphoteric and/or zwitterionic surfactant, preferably an amphoteric surfactant selected from amine oxide surfactants, more preferably wherein the amine oxide surfactant is lauryl dimethylamine oxide.
8. The laundry detergent composition according to any preceding claim, wherein the cationic polymer is selected from the group consisting of: the cationic polymer is selected from: poly (diallyldimethylammonium chloride); copolymers of diallyldimethyl ammonium chloride and acrylic acid; copolymers of methacrylate, methacrylamidopropyl trimethylammonium chloride and acrylic acid; and mixtures thereof, preferably copolymers of diallyldimethylammonium chloride and acrylic acid.
9. The laundry detergent composition according to any preceding claim, wherein the diallyldimethylammonium chloride and co-acrylic monomer are present in a molar ratio of from 50:50 to 90:10, preferably from 55:45 to 85:15, more preferably from 60:40 to 70:30.
10. The laundry detergent composition according to any preceding claim, wherein the cationic polymer has a molecular weight of from 100,000da to 1,000,000da, more preferably from 250,000da to 750,000 da.
11. The laundry detergent composition according to any preceding claim, wherein the cationic polymer is present at a level of from 0.1% to 10%, preferably from 0.5% to 5.0%, more preferably from 1.0% to 2.5% by weight of the composition.
12. Use of a laundry detergent composition comprising a branched nonionic surfactant for improving the colour protection, preferably colour retention, of coloured fabrics during washing.
13. The use according to claim 12, wherein the branched nonionic surfactant is selected from the group consisting of:
a) Formula I: R1-CH (R2) -O- (PO) x (EO) y (PO) z -H
Wherein, in formula I:
r1 is a C4 to C14 alkyl chain, preferably C4 to C8, more preferably C6;
r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain;
x is 0 to 10, preferably 0 to 5, more preferably 0 to 3;
y is 5 to 20, preferably 6 to 15, more preferably 7 to 12;
z is 0 to 20, preferably 0 to 5, more preferably 0 to 3;
EO represents ethoxylation, and PO represents propoxylation;
b) Formula II: R1-CH (R2) CH 2 -O-(PO) x (EO) y (PO) z -H
R1 is a C3 to C13 alkyl chain, preferably C3 to C7, more preferably C5;
r2 is a C1 to C7 alkyl chain, preferably a C1 to C5, more preferably a C3 alkyl chain;
x is 0 to 10, preferably 0 to 5, more preferably 0 to 3;
y is 5 to 20, preferably 6 to 15, more preferably 7 to 12;
z is 0 to 20, preferably 0 to 5, more preferably 0 to 3;
EO represents ethoxylation and PO represents propoxylation.
14. The use according to any one of claims 12 to 13, wherein the fabric dye is selected from the group consisting of: reactive dyes, disperse dyes, and mixtures thereof, preferably wherein the fabric dye is selected from the group consisting of: disperse dyes, reactive dyes, and mixtures thereof.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21181313.4 | 2021-06-24 | ||
| EP21181313 | 2021-06-24 | ||
| EP22165838.8A EP4108748A1 (en) | 2021-06-24 | 2022-03-31 | Colour care detergent compositions |
| EP22165838.8 | 2022-03-31 | ||
| PCT/US2022/034639 WO2022271897A1 (en) | 2021-06-24 | 2022-06-23 | Colour care detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116438283A true CN116438283A (en) | 2023-07-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202280007506.8A Pending CN116438283A (en) | 2021-06-24 | 2022-06-23 | Color care detergent composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2023548360A (en) |
| CN (1) | CN116438283A (en) |
| CA (1) | CA3199892A1 (en) |
| WO (1) | WO2022271897A1 (en) |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2437090A1 (en) | 1974-08-01 | 1976-02-19 | Hoechst Ag | CLEANING SUPPLIES |
| DE3026090A1 (en) * | 1980-07-10 | 1982-02-18 | Henkel KGaA, 4000 Düsseldorf | LIQUID DETERGENT WITH A CONTENT OF DISABLING-INHIBITING |
| US4565647B1 (en) | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
| US5104646A (en) | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5106609A (en) | 1990-05-01 | 1992-04-21 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| BR0108513A (en) | 2000-02-23 | 2002-12-17 | Procter & Gamble | Liquid detergent compositions for washing fabrics with improved clay removal advantages |
| GB0007654D0 (en) | 2000-03-29 | 2000-05-17 | Unilever Plc | Laundry treatment for fabrics |
| WO2009061980A1 (en) | 2007-11-09 | 2009-05-14 | The Procter & Gamble Company | Cleaning compositions comprising a multi-polymer system comprising at least one alkoxylated grease cleaning polymer |
| WO2009101545A1 (en) | 2008-02-15 | 2009-08-20 | The Procter & Gamble Company | Liquid detergent composition comprising an external structuring system comprising a bacterial cellulose network |
| EP2318498B1 (en) | 2008-08-28 | 2015-06-24 | The Procter and Gamble Company | Fabric care compositions, process of making, and method of use |
| JP5969042B2 (en) | 2011-11-11 | 2016-08-10 | ザ プロクター アンド ギャンブル カンパニー | Surface treatment composition containing shield salts |
| EP2970823B1 (en) | 2013-03-14 | 2021-06-30 | Ecolab USA Inc. | Laundry detergent composition for low temperature washing |
| US9840682B2 (en) * | 2014-11-11 | 2017-12-12 | The Procter & Gamble Company | Cleaning compositions with improved sudsing profile comprising a cationic polymer and silicone mixture |
| EP3347446A4 (en) | 2015-09-11 | 2019-01-30 | ISP Investments LLC | A stable laundry or cleaning composition, process for preparing the same, and method of use |
| EP3196283B1 (en) | 2016-01-21 | 2018-06-20 | Henkel AG & Co. KGaA | Polymer agents which improve primary washing strength |
| JP6703334B2 (en) * | 2016-05-20 | 2020-06-03 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Detergent composition containing inclusion body and adhesion promoter |
| EP3771339A1 (en) * | 2019-07-29 | 2021-02-03 | The Procter & Gamble Company | Disinfectant composition |
-
2022
- 2022-06-23 JP JP2023526592A patent/JP2023548360A/en active Pending
- 2022-06-23 CA CA3199892A patent/CA3199892A1/en active Pending
- 2022-06-23 CN CN202280007506.8A patent/CN116438283A/en active Pending
- 2022-06-23 WO PCT/US2022/034639 patent/WO2022271897A1/en active Application Filing
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| CA3199892A1 (en) | 2022-12-29 |
| JP2023548360A (en) | 2023-11-16 |
| WO2022271897A1 (en) | 2022-12-29 |
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