CN116435008A - 10kV line spraying type quick-curing conductive paste - Google Patents
10kV line spraying type quick-curing conductive paste Download PDFInfo
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- CN116435008A CN116435008A CN202310187066.5A CN202310187066A CN116435008A CN 116435008 A CN116435008 A CN 116435008A CN 202310187066 A CN202310187066 A CN 202310187066A CN 116435008 A CN116435008 A CN 116435008A
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- conductive paste
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- grease
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- 238000005507 spraying Methods 0.000 title abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 19
- 239000004519 grease Substances 0.000 claims abstract description 17
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001856 Ethyl cellulose Substances 0.000 claims abstract description 13
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims abstract description 13
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920001249 ethyl cellulose Polymers 0.000 claims abstract description 13
- 235000019325 ethyl cellulose Nutrition 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- 229920001721 polyimide Polymers 0.000 claims abstract description 13
- 239000009719 polyimide resin Substances 0.000 claims abstract description 13
- 229920002545 silicone oil Polymers 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 20
- 239000004925 Acrylic resin Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000001023 inorganic pigment Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 229920006122 polyamide resin Polymers 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 5
- 230000007547 defect Effects 0.000 abstract description 12
- 238000010438 heat treatment Methods 0.000 abstract description 11
- 239000000969 carrier Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 125000000524 functional group Chemical group 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 238000011049 filling Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 230000008030 elimination Effects 0.000 description 5
- 238000003379 elimination reaction Methods 0.000 description 5
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- VRAIHTAYLFXSJJ-UHFFFAOYSA-N alumane Chemical compound [AlH3].[AlH3] VRAIHTAYLFXSJJ-UHFFFAOYSA-N 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- ALKZAGKDWUSJED-UHFFFAOYSA-N dinuclear copper ion Chemical compound [Cu].[Cu] ALKZAGKDWUSJED-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Conductive Materials (AREA)
Abstract
The invention discloses a 10kV line spray-type quick-curing conductive paste, which is a conductive composite material based on graphene and polymers, and is prepared into a high polymer compound with special functional groups by using organic carriers such as dimethylacetamide, synthetic grease, organic silicone oil, ethylene glycol butyl ether, ethylcellulose, polyimide resin, epoxy resin and the like and graphene (the particle size is 20-35 nanometers respectively), and is conductive paste with quick curability, sprayability, strong adhesiveness, ultra-large diameter-thickness ratio and excellent mechanical properties. The method can replace the conventional power outage overhaul defect eliminating mode, rapidly and efficiently treat the heating defect through electrified long-distance spraying or short-distance smearing, reduce power outage of a distribution network, increase power supply and reduce stop, and effectively ensure the safety of heating defect eliminating of live working personnel.
Description
Technical Field
The invention belongs to the field of power equipment connection contact coating, and particularly relates to a 10kV line spray-type quick-curing conductive paste and a preparation method thereof.
Background
The electric power conductive paste is applied to the field of electric power equipment connection contact coating. The connectivity of the power equipment is an important factor for the safe operation of the power grid, and is a key for reducing the connection heating faults of the power equipment. The electric conductive paste is an electric contact coating with good electric performance, is suitable for coating copper-copper, copper-aluminum and aluminum-aluminum faying surfaces, and can prevent oxidation and galvanic corrosion phenomena of the faying surfaces caused by the corrosion of atmosphere and corrosive agents, thereby stabilizing the contact resistance of the contact points and reducing the connection heating. As the connection point of the electric power equipment in operation is easy to swing by wind power and electric vibration, the connection point is loose and conductive paste falls off, so that the contact resistance is increased, and the connection point heats. Although the traditional electric conductive paste in the prior art can eliminate invisible electric gaps, the contact is tighter, and heating is reduced, when large electric gaps are filled in a blocky manner, the traditional electric conductive paste does not have conductivity, cannot be charged for secondary filling of heat defect elimination, and the traditional pure charged fastening defect elimination effect is poor and the danger coefficient is high, so that the number of electric defect elimination items caused by stopping heating is increased.
In order to ensure the safe operation of power grid equipment, reduce the thermal fault of equipment connection, relieve the workload of heat elimination and the power failure pressure caused by power failure elimination, develop the conductive paste coating which is suitable for filling large electric gaps in various climatic environments and has excellent conductivity, quick solidification, strong adhesiveness and strong adhesiveness, and become the problem to be solved urgently, so the technical research on the conductive paste coating block filling conductivity, quick solidification, adhesiveness and adhesiveness is particularly important.
In summary, the invention provides a conductive paste coating with excellent large electrical gap filling conductivity, rapid curability, strong adhesiveness and strong adhesiveness, which solves the technical problems of the conventional conductive paste that the conductive paste coating does not have conductivity, rapid curability, strong adhesiveness and strong adhesiveness when large electrical gap blocks are filled.
Disclosure of Invention
The invention aims to provide a 10kV line spray-type quick-curing conductive paste and a preparation method thereof. In order to solve the problems of bulk conductivity, quick curability, sprayability and strong adhesiveness of the traditional conductive paste, the invention researches and analyzes the conductive paste material, component combination and proportion, and prepares a high molecular compound with special functional groups by using organic carriers such as dimethylacetamide, synthetic grease, organic silicone oil, ethylene glycol butyl ether, ethylcellulose, polyimide resin, epoxy resin and the like and graphene (with particle diameters of 20-35 nanometers respectively), and the conductive paste has the advantages of quick curability, sprayability, strong adhesiveness, ultra-large diameter-thickness ratio and excellent mechanical properties. The method can replace the conventional power outage overhaul defect eliminating mode, rapidly and efficiently treat the heating defect through electrified long-distance spraying or short-distance smearing, reduce power outage of a distribution network, increase power supply and reduce stop, and effectively ensure the safety of heating defect eliminating of live working personnel.
In order to achieve the above purpose, the invention adopts the following technical scheme:
the 10kV line spray-type quick-curing conductive paste comprises the following raw materials in parts by weight: 20-30 parts of acrylic resin, 5-10 parts of polyamide resin, 5-10 parts of polyimide resin, 5-10 parts of epoxy resin, 2-5 parts of dimethylacetamide, 5-8 parts of synthetic grease, 10-15 parts of organic silicone oil, 5-8 parts of ethylene glycol butyl ether, 2-5 parts of ethylcellulose, 2-5 parts of graphene, 1-5 parts of inorganic pigment, 2-3 parts of dispersing agent, 1-2 parts of defoaming agent and 1-2 parts of leveling agent.
Further, the synthetic grease is grease for electric contact or conductive grease.
Further, the particle size of the graphene is 20-35nm.
A preparation method of a 10kV line spray-type quick-curing conductive paste comprises the following steps:
(1) Mixing acrylic resin, polyamide resin, polyimide resin and epoxy resin by a blending method to obtain modified acrylic resin;
(2) Adding a dispersing agent into the modified acrylic resin and uniformly stirring;
(3) Then adding dimethylacetamide, synthetic oil, organic silicone oil, ethylene glycol butyl ether, ethyl cellulose, graphene and inorganic pigment, and uniformly stirring;
(4) And finally adding a defoaming agent and a leveling agent, and uniformly stirring to obtain the conductive paste.
The invention has the advantages that:
1. the conductive paste with excellent large electrical gap filling conductivity, quick solidification, strong adhesiveness and strong adhesiveness is prepared by utilizing organic carriers such as dimethylacetamide, synthetic grease, organic silicone oil, ethylene glycol butyl ether, ethylcellulose, polyimide resin, epoxy resin and the like and graphene (the particle size is 20-35 nanometers respectively), and can realize quick solidification and adhesion under the high-temperature working condition by means of local filling and smearing, and the heating defect is rapidly treated.
2. The 10kV line filling type quick-curing conductive paste can effectively prevent harmful substances such as acid, alkali, salt fog and the like from corroding metal and nonmetal surfaces, and achieves the effect of long-acting high-quality conduction.
3. The conductive paste has the use temperature of-40-200 ℃, the contact resistance ratio of <1 and the curing time of less than 30 minutes.
4. Compared with the traditional conductive paste, the 10kV line spray-type quick-curing conductive paste can replace the traditional power failure maintenance defect eliminating mode, can be used for filling heating points through close-range coating, can be sprayed in a live-line and long-distance mode, improves the safety of hot-line operators in treating the heating defects of the connecting points, and ensures the safety of the operators.
Detailed Description
The following examples are provided to illustrate the above features and advantages of the present invention. The method of the invention is a conventional method in the art unless specifically stated otherwise.
Example 1
The 10kV line spray-type quick-curing conductive paste comprises the following raw materials in parts by weight: 25 parts of acrylic resin, 8 parts of polyamide resin, 8 parts of polyimide resin, 8 parts of epoxy resin, 3 parts of dimethylacetamide, 6 parts of synthetic oil, 13 parts of organic silicone oil, 7 parts of ethylene glycol butyl ether, 3 parts of ethylcellulose, 3 parts of graphene, 2 parts of inorganic pigment, 2 parts of dispersing agent, 1 part of defoaming agent and 1 part of leveling agent.
The synthetic grease is grease for electric contact. The particle size of the graphene is 20-35nm.
A preparation method of a 10kV line spray-type quick-curing conductive paste comprises the following steps:
(1) Mixing acrylic resin, polyamide resin, polyimide resin and epoxy resin by a blending method to obtain modified acrylic resin;
(2) Adding a dispersing agent into the modified acrylic resin and uniformly stirring;
(3) Then adding dimethylacetamide, synthetic oil, organic silicone oil, ethylene glycol butyl ether, ethyl cellulose, graphene and inorganic pigment, and uniformly stirring;
(4) And finally adding a defoaming agent and a leveling agent, and uniformly stirring to obtain the conductive paste.
Example 2
The 10kV line spray-type quick-curing conductive paste comprises the following raw materials in parts by weight: 20 parts of acrylic resin, 5 parts of polyamide resin, 5 parts of polyimide resin, 5 parts of epoxy resin, 2 parts of dimethylacetamide, 5 parts of synthetic oil, 10 parts of organic silicone oil, 5 parts of ethylene glycol butyl ether, 2 parts of ethylcellulose, 2 parts of graphene, 1 part of inorganic pigment, 2 parts of dispersing agent, 1 part of defoaming agent and 1 part of leveling agent.
The synthetic grease is conductive grease. The particle size of the graphene is 20-35nm.
A preparation method of a 10kV line spray-type quick-curing conductive paste comprises the following steps:
(1) Mixing acrylic resin, polyamide resin, polyimide resin and epoxy resin by a blending method to obtain modified acrylic resin;
(2) Adding a dispersing agent into the modified acrylic resin and uniformly stirring;
(3) Then adding dimethylacetamide, synthetic oil, organic silicone oil, ethylene glycol butyl ether, ethyl cellulose, graphene and inorganic pigment, and uniformly stirring;
(4) And finally adding a defoaming agent and a leveling agent, and uniformly stirring to obtain the conductive paste.
Example 3
The 10kV line spray-type quick-curing conductive paste comprises the following raw materials in parts by weight: 30 parts of acrylic resin, 10 parts of polyamide resin, 10 parts of polyimide resin, 10 parts of epoxy resin, 5 parts of dimethylacetamide, 8 parts of synthetic oil, 15 parts of organic silicone oil, 8 parts of ethylene glycol butyl ether, 5 parts of ethylcellulose, 5 parts of graphene, 5 parts of inorganic pigment, 3 parts of dispersing agent, 2 parts of defoaming agent and 2 parts of leveling agent.
The synthetic grease is conductive grease. The particle size of the graphene is 20-35nm.
A preparation method of a 10kV line spray-type quick-curing conductive paste comprises the following steps:
(1) Mixing acrylic resin, polyamide resin, polyimide resin and epoxy resin by a blending method to obtain modified acrylic resin;
(2) Adding a dispersing agent into the modified acrylic resin and uniformly stirring;
(3) Then adding dimethylacetamide, synthetic oil, organic silicone oil, ethylene glycol butyl ether, ethyl cellulose, graphene and inorganic pigment, and uniformly stirring;
(4) And finally adding a defoaming agent and a leveling agent, and uniformly stirring to obtain the conductive paste.
The main technical indexes of the conductive paste prepared in the embodiment 1 of the invention are shown in the following table:
detecting items | Actual measurement value | Test method |
State in container | No hard lump after stirring | GB/T9761-1988 |
Adhesion, grade: is less than or equal to 1 | 1 | GB/T9286-1998 |
Fineness: less than or equal to 30 mu m | 30 | GB/T6753.1-1986 |
The content of non-volatile matters is more than or equal to 80 percent | 90 | GB/T1725-2007 |
Surface drying (25+/-2) DEG C: less than or equal to 30min | 15 | GB/T1728-1989 |
Solid drying (25+ -4) deg.C: 24h | 12 | GB/T1728-1989 |
Flexibility: less than or equal to 2mm | 1 | GB/T1731-1993 |
Impact resistance, cm:50 | 50 | GB/T1732-1993 |
Surface resistance 1×10 5 Ω~1×10 9 Ω | 6.96×10 8 | GJB3007A-2009 |
Acid resistance (5%H) 2 SO 4 ,72h) | No change | GB/T9274-1988 |
Alkali resistance (10% NaOH,72 h) | No change | GB/T9274-1988 |
The foregoing description is only of the preferred embodiments of the invention, and all changes and modifications that come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (4)
1. A10 kV line spray-type quick-curing conductive paste is characterized in that: the raw materials comprise the following components in parts by weight: 20-30 parts of acrylic resin, 5-10 parts of polyamide resin, 5-10 parts of polyimide resin, 5-10 parts of epoxy resin, 2-5 parts of dimethylacetamide, 5-8 parts of synthetic grease, 10-15 parts of organic silicone oil, 5-8 parts of ethylene glycol butyl ether, 2-5 parts of ethylcellulose, 2-5 parts of graphene, 1-5 parts of inorganic pigment, 2-3 parts of dispersing agent, 1-2 parts of defoaming agent and 1-2 parts of leveling agent.
2. The 10kV line spray-type rapid-curing conductive paste of claim 1, wherein the conductive paste is further characterized by: the synthetic grease is grease for electric contact or conductive grease.
3. The 10kV line spray-type rapid-curing conductive paste of claim 1, wherein the conductive paste is further characterized by: the particle size of the graphene is 20-35nm.
4. The method for preparing the 10kV line spray-type rapid-curing conductive paste according to claim 1, which is characterized in that: the method comprises the following steps:
(1) Mixing acrylic resin, polyamide resin, polyimide resin and epoxy resin by a blending method to obtain modified acrylic resin;
(2) Adding a dispersing agent into the modified acrylic resin and uniformly stirring;
(3) Then adding dimethylacetamide, synthetic oil, organic silicone oil, ethylene glycol butyl ether, ethyl cellulose, graphene and inorganic pigment, and uniformly stirring;
(4) And finally adding a defoaming agent and a leveling agent, and uniformly stirring to obtain the conductive paste.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310187066.5A CN116435008A (en) | 2023-03-02 | 2023-03-02 | 10kV line spraying type quick-curing conductive paste |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310187066.5A CN116435008A (en) | 2023-03-02 | 2023-03-02 | 10kV line spraying type quick-curing conductive paste |
Publications (1)
Publication Number | Publication Date |
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CN116435008A true CN116435008A (en) | 2023-07-14 |
Family
ID=87084441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN202310187066.5A Pending CN116435008A (en) | 2023-03-02 | 2023-03-02 | 10kV line spraying type quick-curing conductive paste |
Country Status (1)
Country | Link |
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CN (1) | CN116435008A (en) |
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2023
- 2023-03-02 CN CN202310187066.5A patent/CN116435008A/en active Pending
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