CN116412301A - Composite pipe for multi-pipe-bundle high-barrier high-pressure-bearing hydrogen transportation and preparation method thereof - Google Patents
Composite pipe for multi-pipe-bundle high-barrier high-pressure-bearing hydrogen transportation and preparation method thereof Download PDFInfo
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 75
- 239000002131 composite material Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title description 3
- 238000004804 winding Methods 0.000 claims abstract description 138
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 70
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 70
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 35
- 239000004698 Polyethylene Substances 0.000 claims description 17
- -1 polyethylene Polymers 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 230000006835 compression Effects 0.000 claims description 6
- 238000007906 compression Methods 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229910000553 6063 aluminium alloy Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 238000005452 bending Methods 0.000 abstract description 9
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- 239000010410 layer Substances 0.000 description 134
- 229910000831 Steel Inorganic materials 0.000 description 16
- 239000010959 steel Substances 0.000 description 16
- 239000003365 glass fiber Substances 0.000 description 7
- 239000011261 inert gas Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 239000005030 aluminium foil Substances 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
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- 239000004831 Hot glue Substances 0.000 description 3
- 229910000792 Monel Inorganic materials 0.000 description 3
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- 229920000049 Carbon (fiber) Polymers 0.000 description 2
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- 239000004917 carbon fiber Substances 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/16—Rigid pipes wound from sheets or strips, with or without reinforcement
- F16L9/165—Rigid pipes wound from sheets or strips, with or without reinforcement of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/06—Protection of pipes or objects of similar shape against external or internal damage or wear against wear
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The invention belongs to the technical field of hydrogen pipelines, and particularly relates to a multi-tube-bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation and a preparation method thereof. Because the windable aluminum pipe can realize bending winding and can be compatible with hydrogen, and the pressure-resistant layer is used for bearing high-pressure hydrogen, the composite pipe meets the requirement of pipeline transportation of hydrogen, is suitable for long-distance laying, and is convenient to transport and lay by being wound by a coil. In order to meet the hydrogen conveying efficiency, under the condition of meeting the winding condition, a plurality of bundles of windable aluminum pipes are axially arranged in the pressure-resistant layer along the pressure-resistant layer, so that multichannel conveying is realized. The preparation method of the composite tube is simple, can be realized by adopting the existing winding, extruding and other equipment, and has low manufacturing cost and easier quality control.
Description
Technical Field
The invention belongs to the technical field of hydrogen pipelines, and particularly relates to a multi-tube-bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation and a preparation method thereof.
Background
The hydrogen energy is an important direction of energy transformation and upgrading, and is also an important way for realizing the aim of carbon neutralization, and in the whole hydrogen industrial chain, safe and efficient transportation is an important component part of the industrial chain, and in the industrial production process, hydrogen in a hydrogen storage device is required to be transported to a corresponding production unit through a hydrogen transportation pipe, so that the requirement of industrial production on hydrogen raw materials is met. The high-pressure gaseous hydrogen transportation is the most mature hydrogen energy transportation mode at the present stage, the transportation of hydrogen has a plurality of technologies, such as long tank trailers, liquid hydrogen tank cars and pipelines, and the pipeline transportation is a common transportation mode, so that the safety of the transportation process is high.
Existing gas delivery pipes, such as natural gas delivery pipes, are mainly seamless steel pipes made of steel. If the seamless steel pipes convey hydrogen for a long time, hydrogen atoms can diffuse and dissolve in the steel pipes, hydrogen embrittlement occurs, so that the mechanical properties of the seamless steel pipes are deteriorated, the pipelines are invalid, and safe and reliable conveying of the hydrogen cannot be realized. The term "hydrogen embrittlement" means that hydrogen dissolved in steel polymerizes into hydrogen molecules causing stress concentration beyond the strength limit of the steel, forming fine cracks inside the steel. Hydrogen embrittlement can only be prevented and once generated, can not be eliminated.
In order to solve the above technical problems, researchers in the field use alloy materials, such as Meng Naier (Monel) alloy, to manufacture the hydrogen delivery pipe, and the hydrogen delivery pipe made of Meng Naier alloy can effectively resist pitting corrosion and stress corrosion cracking of the delivery pipe body by hydrogen atoms.
However, the existing hydrogen delivery pipe manufactured by Meng Naier (Monel) alloy has at least the following technical problems: the cost of the seamless steel tube manufactured by Meng Naier (Monel) alloy is high, and the seamless steel tube is mainly used for ocean engineering, crude oil distiller and industrial heat exchanger. If a Meng Naier alloy hydrogen delivery pipe is adopted, the large-scale commercial application of hydrogen energy is hindered.
The Chinese patent discloses a processing method of a hydrogen transmission pipeline (publication No. CN 113103613A), which utilizes a primary plastic molding process and secondary pressurization rotational molding to form a larger pressure difference, so that an inner plastic layer in a high-elastic state is tightly pressed to the inner surface and micropores of a steel pipe, and the bonding effect between the inner plastic layer and the steel pipe is improved; meanwhile, the problem that the pressure is high and the input is difficult when the high-pressure medium is input can be avoided due to the fact that the temperature is cooled to be less than 100 ℃ after primary molding, the conveying hydrogen pipeline is protected against corrosion to the inner wall of the metal pipeline through the plastic layer, the protecting structure of the structural pipeline is small, the inner plastic layer cannot be guaranteed to be uniformly adhered to the inner wall of the steel pipe, the phenomenon that hydrogen permeates into the inner plastic layer exists is avoided, the problem of hydrogen embrittlement still occurs in the steel pipe after long-time use, a certain pipeline diameter is required to be guaranteed, the large-caliber steel pipeline cannot be wound and paved, only the section-by-section pipeline can be installed and paved, and the paving efficiency is low.
Chinese patent document CN115654227a discloses an intelligent hydrogen transfer pipeline with inert gas protection, including polyethylene work pipe and first adhesive linkage, the outside position department of first adhesive linkage is provided with the aluminium foil layer, the outside on aluminium foil layer is provided with the second adhesive linkage, the outside on second adhesive linkage is provided with glass fiber ribbon winding enhancement layer, the outside on glass fiber ribbon winding enhancement layer is provided with the interior protective layer of polyethylene inert gas, the outside of the interior protective layer of polyethylene inert gas is provided with the strengthening rib. The structure that above-mentioned patent adopted polyethylene, glass fiber tape and aluminium foil to combine has effectually solved the hydrogen embrittlement phenomenon, satisfies high pressure pipeline operation requirement simultaneously, and product low in cost moreover, aluminium matter material on aluminium foil layer has good anti intergranular corrosion ability and good compatibility with hydrogen, uses the aluminium foil as the pipeline barrier layer, can prevent the hydrogen leakage of polyethylene work pipe to glass fiber tape winding enhancement layer sets for the winding layer number according to pipeline demand pressure level, can satisfy the production demand of 0-40Mpa pipeline, has high tensile strength, and the quality is light, and can realize winding laying. However, the above-mentioned intelligent hydrogen-transporting pipe needs to use the aluminum foil layer as the pipe barrier layer to prevent the leakage of hydrogen gas from the polyethylene working pipe, the manufacturing method needs to weld the aluminum foil layer into a pipe and adhere the pipe to the outer side of the polyethylene working pipe, and in addition, a protective layer in polyethylene inert gas is arranged on the outer side of the glass fiber tape winding reinforcing layer, so that the production process is complex. And the aluminum foil layer thickness is thinner, and easy damage in the production process, the leakproofness of welding seam is difficult to detect simultaneously, so above-mentioned structure needs to set up the interior protective layer of polyethylene inert gas in the outside, and later stage uses and need lets in inert gas and carries out the protection transportation, has increased subsequent hydrogen transportation cost.
Disclosure of Invention
The invention aims to solve the problems and provide a multi-tube-bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation and a preparation method thereof. Because the windable aluminum pipe can realize bending winding and can be compatible with hydrogen, and the pressure-resistant layer is used for bearing high-pressure hydrogen, the composite pipe meets the requirement of pipeline transportation of hydrogen, is suitable for long-distance laying, and is convenient to transport and lay by being wound by a coil.
The technical problems to be solved by the invention are realized by adopting the following technical scheme: a multi-tube bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation comprises a windable aluminum tube, a pressure-resistant layer and a filling layer;
and a plurality of windable aluminum pipes are axially arranged in the pressure-resistant layer along the pressure-resistant layer, and a filling layer is arranged between the outer wall of the windable aluminum pipes and the inner wall of the pressure-resistant layer. The multi-tube-bundle pipeline can improve the utilization rate of the pipeline and convey more hydrogen in a limited space.
The technical scheme of the invention is as follows: the windable aluminum tube is a seamless aluminum tube. In order to improve the sealability of the windable aluminum pipe, the windable aluminum pipe is prepared by using a seamless aluminum pipe, and can bear larger pressure.
The technical scheme of the invention is as follows: the diameter of the windable aluminum pipe is 20-50mm, and the thickness is 2-4mm.
The technical scheme of the invention is as follows: the material of the windable aluminum pipe is pure aluminum, 5052 aluminum alloy or 6063 aluminum alloy.
The technical scheme of the invention is as follows: the withstand voltage layer includes the winding layer of more than two-layer, and the winding direction of adjacent winding layer is opposite, and every winding layer is non-overlapping and every winding layer's winding clearance is 0.5-1.2mm in winding process. More than two winding layers are used as pressure-resistant layers, the winding gap of each winding layer is 0.5-1.2mm, no overlapping occurs in the winding process of the winding layers, the requirement of larger bending radius of the composite pipe can be met, and if the winding layers overlap, the pipe diameters of the composite pipe are inconsistent, namely the outer surface of the pipeline forms a bulge to influence the bending of the composite pipe; in order to ensure the pressure resistance, the winding directions of the adjacent winding layers are opposite.
The technical scheme of the invention is as follows: the anti-wear coating also comprises an anti-wear layer, and the anti-wear layer is arranged on the outer side of the pressure-resistant layer. And the wear-resistant layer is arranged on the outer side of the pressure-resistant layer, so that the pipeline is not easy to wear, and the service life of the pipeline is prolonged.
The technical scheme of the invention is as follows: the filling layer and the wear-resistant layer are made of polyethylene materials.
The technical scheme of the invention is as follows: the windable aluminum tubes are arranged in a staggered structure along the radial direction of the pressure-resistant layer. The staggered structure arrangement can ensure that the outermost aluminum tubes are uniformly stressed, and the finally formed composite tubes for conveying hydrogen are wound on the conveying plate, so that the inner aluminum tubes can be prevented from bending and deforming due to uneven stress.
The technical scheme of the invention is as follows: the windable aluminum tubes are arranged in an in-line structure along the radial direction of the pressure-resistant layer. The straight-line structure arrangement can ensure that more windable aluminum pipes are arranged compared with the staggered structure arrangement under the condition that the outer diameters of the composite pipes are the same, thereby having larger hydrogen conveying capacity.
The invention also discloses a preparation method of the composite pipe for multi-pipe-bundle high-barrier high-pressure-bearing hydrogen transportation, which comprises the following steps:
s1, firstly arranging a plurality of groups of windable aluminum tubes according to the sequence requirement, and then mutually fixing the arranged windable aluminum tubes;
s2, dragging the windable aluminum pipe fixed in the step S1 through traction equipment, coating a filling layer through an extruder to form a core pipe, and winding the filled core pipe to an excessive large disc;
s3, winding the pressure-resistant layer on the core tube obtained in the step S2 through winding equipment, winding the winding layers on the outer wall of the core tube to obtain the pressure-resistant layer, wherein winding angles of adjacent winding layers are opposite, each winding layer is not overlapped in the winding process, and a winding gap of each winding layer is between 0.5 and 1.2 mm;
when the composite pipe only has the compression resistance requirement, the winding angle of each winding layer is a winding balance angle, and the number of winding layers is a multiple of 2;
when the composite pipe is required to meet the compression resistance requirement and the tensile strength requirement, one of the adjacent winding layers is wound at a large angle, namely a winding angle is larger than a winding balance angle, the other winding layer is wound at a small angle, namely a winding angle is smaller than the winding balance angle, the number of winding layers is a multiple of 4, and preferably, the innermost winding layer in the radial direction of the composite pipe is wound at a large angle;
and S4, finally, coating the pressure-resistant layer through an extruder to form a wear-resistant layer.
The winding balance angle is the balance angle of pipeline in the resistance to compression in-process, when filling pressure medium in the composite pipe, if the winding angle of the winding layer of withstand voltage layer is unbalanced angle, can cause composite pipe self to take place the kinking rotation, considers this, and the winding layer of adjacent layer adopts anticlockwise clockwise alternate winding when twining, avoids the same direction winding and appears the self rotatory problem of composite pipe because of the moment of torsion problem leads to.
In addition, in production, the tensile property of the composite pipe is considered, the winding layer is wound at a small angle, so that the better tensile property can be achieved, the composite pipe is wound at a simple large angle, and the composite pipe is stretched when being pressed.
When the tensile requirement is considered, the adjacent winding layers are alternately wound at a small angle and a large angle respectively, and the pressure bearing performance and the tensile performance of the composite pipe are balanced.
The winding balance angle is generally 54.73 degrees by combining the actual production process, and the winding balance angle is finely adjusted between 54 and 55 degrees in the actual production. Wherein, the winding angle of more than 50 degrees and less than 54 degrees is a relatively small angle, and the winding angle of less than 50 degrees is a small angle; the winding angle of more than 55 deg. and less than 60 deg. is a relatively large angle.
However, in actual production, the winding gap of the winding layer can be changed due to the influence of the pipe traction speed, the pipe winding outer diameter and the winding material in consideration of the process requirement, and the winding angle can be adjusted by adjusting the ratio of the rotating speed of the winding machine to the pulling speed of the traction machine in order to ensure that the winding gap is in a proper range and the winding angle is adjusted within 50-60 degrees.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, a plurality of bundles of windable aluminum pipes are axially arranged in the pressure-resistant layer along the pressure-resistant layer, and a filling layer is arranged between the outer wall of the windable aluminum pipes and the inner wall of the pressure-resistant layer and used for limiting and fixing the windable aluminum pipes. Because the windable aluminum pipe can realize bending winding and can be compatible with hydrogen, and the pressure-resistant layer is used for bearing high-pressure hydrogen, the composite pipe meets the requirement of pipeline transportation of hydrogen, is suitable for long-distance laying, and is convenient to transport and lay by being wound by a coil.
When the inner diameter of the windable aluminum pipe is too large, the bending radius is increased, the winding and the transportation are inconvenient, the hydrogen conveying efficiency is met, under the condition that the winding condition is met, a plurality of windable aluminum pipes are axially arranged in the pressure-resistant layer along the pressure-resistant layer, the bending radius of the composite pipe can be reduced, the requirement of the hydrogen conveying amount can be met through multi-channel conveying, and the hydrogen conveying efficiency is ensured.
The preparation method of the multi-tube-bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation is simple in process, the existing extrusion equipment and winding equipment can be realized, the manufacturing cost is low, welding seams are not formed on the side wall of the winding aluminum tube, the sealing quality is easy to control, and mass production popularization can be realized rapidly.
Drawings
FIG. 1 is a schematic structural diagram of a multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to embodiment 1 of the present invention;
FIG. 2 is a schematic structural diagram of a composite tube for transporting hydrogen with high barrier and high pressure bearing for a multi-tube bundle according to embodiment 2 of the present invention;
FIG. 3 is a schematic diagram of a structure of a voltage-resistant layer according to the present invention;
FIG. 4 is a perspective view of a multi-tube bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation according to the present invention;
in the figure, an aluminum pipe 1, a pressure-resistant layer 2, a filling layer 3 and a wear-resistant layer 4 can be wound;
21 winding layers.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention.
Example 1
As shown in fig. 1, a multi-tube bundle high-barrier high-pressure-bearing composite tube for hydrogen transportation comprises a windable aluminum tube 1, a pressure-resistant layer 2, a filling layer 3 and a wear-resistant layer 4.
7 bundles of windable aluminum tubes 1 are axially arranged in the pressure-resistant layer 2 along the pressure-resistant layer 2, the windable aluminum tubes 1 are seamless aluminum tubes, namely aluminum seamless coils, and in the cross section of the pressure-resistant layer 2, the windable aluminum tubes 1 are arranged in a staggered structure along the radial direction of the pressure-resistant layer 2, and specifically, as shown in fig. 1, the windable aluminum tubes 1 are arranged in a plum blossom shape. A filling layer 3 is arranged between the outer wall of the windable aluminum pipe 1 and the inner wall of the pressure-resistant layer 2.
And a wear-resistant layer 4 is arranged outside the pressure-resistant layer 2. The pressure-resistant layer 2, the filling layer 3 and the wear-resistant layer 4 can be wound in a bending manner.
Specifically, the diameter of the windable aluminum pipe 1 is 20mm, and the thickness is 2mm.
The windable aluminum pipe 1 is made of 5052 aluminum alloy.
As shown in fig. 3, the pressure-resistant layer 2 includes two winding layers 21, the winding directions of adjacent winding layers 21 are opposite, each winding layer 21 is not overlapped in the winding process, and the winding gap of each winding layer 21 is 0.5mm. The wrapping layer 21 is a carbon fiber tape.
The filling layer 3 and the wear-resistant layer 4 are made of polyethylene materials, and specifically high-density polyethylene.
The preparation method of the composite pipe for multi-pipe-bundle high-barrier high-pressure-bearing hydrogen transportation comprises the following steps:
s1, firstly arranging the windable aluminum tubes 1 in a staggered manner along the radial direction of the pressure-resistant layer 2 according to requirements, and then mutually fixing the arranged windable aluminum tubes 1 through hot melt adhesive or bundling through a binding belt.
S2, drawing the windable aluminum pipe 1 fixed in the step S1 through drawing equipment, coating the filling layer 3 through an extruder to form a core pipe, winding the filled core pipe to an excessive large plate, specifically, hot melting polyethylene particles, and extruding high-density polyethylene (HDPE) from the extruder to coat the outer wall of the windable aluminum pipe 1.
S3, winding the pressure-resistant layer 2 on the core tube obtained in the step S2 through winding equipment, winding the winding layers 21 on the outer wall of the core tube to obtain the pressure-resistant layer 2, wherein winding angles of adjacent winding layers 21 are opposite, each winding layer 21 is not overlapped in the winding process, and the winding gap of each winding layer 21 is 0.5mm.
The winding angle of each winding layer 21 is a winding balance angle, and the number of winding layers is 2. The winding layer 21 comprises a carbon fiber belt, polyester yarns, a glass fiber belt or a thin steel curtain belt, the winding layer 21 can be directly wound according to different required processes of materials, the glass fiber belt is baked by an oven, and the winding materials do not need hot melt adhesive.
Specifically, the pipeline formed in the step S2 is uniformly passed through a winding machine by means of a traction device, the compression-resistant layer material, namely the winding layer 21, is wound on the pipeline and bound and fixed by means of an adhesive tape, then the winding layer 21 is wound on the pipeline by means of a running device, the interval between the winding layers 21 is adjusted by adjusting the traction speed and the winding angle, so that the predetermined winding interval is reached, the section of pipeline fixed by means of the adhesive tape is unnecessary, and the section of pipeline is sawed off after the final coating is completed.
And S4, finally, coating the pressure-resistant layer 2 by an extruder to form the wear-resistant layer 4. The wear-resistant layer 4 is coated without coating hot melt adhesive on the outer surface of the pressure-resistant layer 2. Specifically, polyethylene particles are hot-melted, and high-density polyethylene (HDPE) is extruded from an extruder to coat the outer wall of the pressure-resistant layer 2.
Example 2
As shown in fig. 2, the difference from example 1 is that in the cross section of the pressure-resistant layer 2, the aluminum reelable tubes 1 are arranged in an in-line structure in the radial direction of the pressure-resistant layer 2. Specifically, as shown in fig. 2, 9 bundles of windable aluminum tubes 1 are arranged in the pressure-resistant layer 2 along the axial direction of the pressure-resistant layer 2, and the windable aluminum tubes 1 are arranged in a nine-grid pattern.
The invention has the advantages that:
1. the windable aluminum tubes 1 in the composite tube are arranged in a honeycomb shape or a nine-grid shape, as shown in fig. 4, the composite tube can be coiled and paved, the winding radius meets the requirement of the large-disc operation of the current actual production, the winding radius range is between 1m and 2m, hydrogen is conveyed through the windable aluminum tubes 1, the hydrogen embrittlement phenomenon on a plastic pipeline can be prevented, and in addition, the multiple windable aluminum tubes 1 meet the requirement of winding and paving, and meanwhile, the conveying capacity of the hydrogen is ensured.
2. The outer side of the windable aluminum pipe 1 is coated with polyethylene, and then two layers of reinforcing fibers are wound to serve as pressure-resistant layers 2, wherein the polyethylene serves as a filling layer 3 to play a role in supporting and positioning the windable aluminum pipe 1, pressure in the windable aluminum pipe 1 is transmitted to the pressure-resistant layers 2 on the outer side, the pressure-resistant layers 2 are used for enhancing the pressure resistance of a pipeline, and the highest bearing pressure of the pipeline can reach 25Mpa at present.
3. And a layer of polyethylene is coated outside the pressure-resistant layer 2, so that the pipeline is not easy to wear, and the service life of the pipeline is prolonged.
Claims (10)
1. The utility model provides a high resistant separates high pressure-bearing hydrogen of many tube bundles carries and uses compound pipe which characterized in that: comprises a windable aluminum pipe (1), a pressure-resistant layer (2) and a filling layer (3);
a plurality of windable aluminum pipes (1) are axially arranged in the pressure-resistant layer (2) along the pressure-resistant layer (2), and a filling layer (3) is arranged between the outer wall of the windable aluminum pipes (1) and the inner wall of the pressure-resistant layer (2).
2. The high-barrier high-pressure-bearing dynamic hydrogen delivery composite tube according to claim 1, wherein: the windable aluminum pipe (1) is a seamless aluminum pipe.
3. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the diameter of the windable aluminum pipe (1) is 20-50mm, and the thickness is 2-4mm.
4. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the material of the windable aluminum pipe (1) comprises pure aluminum, 5052 aluminum alloy or 6063 aluminum alloy.
5. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the pressure-resistant layer (2) comprises more than two winding layers (21), the winding directions of the adjacent winding layers (21) are opposite, each winding layer (21) is not overlapped in the winding process, and the winding gap of each winding layer (21) is 0.5-1.2mm.
6. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the anti-wear layer (4) is arranged on the outer side of the pressure-resistant layer (2).
7. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 6, wherein: the filling layer (3) and the wear-resistant layer (4) are made of polyethylene materials.
8. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the windable aluminum tubes (1) are arranged in a staggered structure along the radial direction of the pressure-resistant layer (2).
9. The multi-tube bundle high-barrier high-pressure-bearing hydrogen transportation composite tube according to claim 1, wherein: the windable aluminum tubes (1) are arranged in an in-line structure along the radial direction of the pressure-resistant layer (2).
10. The preparation method of the composite pipe for multi-pipe-bundle high-barrier high-pressure-bearing hydrogen transportation is characterized by comprising the following steps of:
s1, firstly arranging a plurality of groups of windable aluminum pipes (1) according to the sequence requirement, and then mutually fixing the arranged windable aluminum pipes (1);
s2, dragging the windable aluminum pipe (1) fixed in the step S1 through traction equipment, coating a filling layer (3) through an extruder to form a core pipe, and winding the filled core pipe to an excessive large disc;
s3, winding the pressure-resistant layer (2) on the core tube obtained in the step S2 through winding equipment, winding the winding layers (21) on the outer wall of the core tube to obtain the pressure-resistant layer (2), wherein the winding angles of adjacent winding layers (21) are opposite, each winding layer (21) is not overlapped in the winding process, and the winding gap of each winding layer (21) is between 0.5 and 1.2 mm;
when the composite pipe has only the compression resistance requirement, the winding angle of each winding layer (21) is a winding balance angle, and the number of winding layers is a multiple of 2;
when the composite pipe meets the compression resistance requirement and the tensile strength requirement, one of the adjacent winding layers (21) is wound at a large angle, namely, the winding angle is larger than the winding balance angle, the other winding layer (21) is wound at a small angle, namely, the winding angle is smaller than the winding balance angle, and the number of winding layers is a multiple of 4;
and S4, finally, coating the pressure-resistant layer (2) through an extruder to form the wear-resistant layer (4).
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