CN116377289A - High pressure cast aluminum alloy suitable for brazing - Google Patents

High pressure cast aluminum alloy suitable for brazing Download PDF

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Publication number
CN116377289A
CN116377289A CN202310371206.4A CN202310371206A CN116377289A CN 116377289 A CN116377289 A CN 116377289A CN 202310371206 A CN202310371206 A CN 202310371206A CN 116377289 A CN116377289 A CN 116377289A
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aluminum alloy
high pressure
pressure casting
brazing
casting aluminum
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CN202310371206.4A
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程帅
杜燕军
张跃波
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Dalian Yaming Automotive Parts Co ltd
Shuaiyichi New Material Group Co ltd
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Dalian Yaming Automotive Parts Co ltd
Shuaiyichi New Material Group Co ltd
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Priority to CN202310371206.4A priority Critical patent/CN116377289A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/28Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/286Al as the principal constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

The present application discloses a high pressure casting aluminum alloy suitable for brazing comprising up to 0.5 wt.% silicon; 0.5 to 2.0 wt% iron; 0.3 to 1.0 weight percent magnesium; 5.0 to 12.0 weight percent rare earth; wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.3 and 2.4.

Description

High pressure cast aluminum alloy suitable for brazing
Technical Field
The invention relates to the field of nonferrous metal materials, in particular to a high-pressure casting aluminum alloy suitable for brazing.
Background
Brazing refers to a welding method for connecting metals by filling gaps of solid workpieces with liquid brazing filler metal after the brazing filler metal below the melting point of a weldment and the weldment are heated to the melting temperature of the brazing filler metal at the same time. Because the aluminum alloy has the characteristics of better heat conduction, higher strength, light use and economy. Therefore, they are widely used as a material for their constituent parts in various fields such as automobiles, industrial machines, aircrafts, household electrical appliances, and others.
At present, a plurality of parts are required to be assembled by high-temperature brazing, in particular to the existing new energy automobile water cooling plate, and a product substrate is welded by thick processing of sectional materials, so that the cost is high and the efficiency is low. However, the existing high-efficiency high-pressure casting aluminum alloy has the problems that the melting point is low and the high-temperature brazing temperature cannot be reached, or the melting point is high but the casting fluidity is poor, the shrinkage is high and the like during brazing, so that the existing high-efficiency high-pressure casting aluminum alloy cannot be applied to the existing high-pressure casting.
Disclosure of Invention
An advantage of the present invention is to provide a high pressure casting aluminum alloy that is capable of brazing high thermal conductivity, wherein the high pressure casting aluminum alloy has a tensile yield limit rp0.2 of >100MPa while in an as-cast state, a breaking elongation a of >5.0%, and a tensile strength Rm of >200MPa, and particularly the high pressure casting aluminum alloy has a thermal conductivity of 140-180w/m·k, which is well suited for high temperature brazing.
To achieve at least one of the above advantages, the present invention provides a high pressure casting aluminum alloy suitable for brazing, comprising:
up to 0.5 wt% silicon;
0.5 to 2.0 wt% iron;
0.3 to 1.0 weight percent magnesium;
5.0 to 12.0 weight percent rare earth; wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.3 and 2.4.
According to an embodiment of the invention, rare earth: the weight percentage of 3 Fe is controlled between 1.5 and 2.0.
According to an embodiment of the present invention, the rare earth is implemented as at least one selected from lanthanum or cerium.
According to an embodiment of the invention, the proportion of iron in the high-pressure cast aluminum alloy is 1.0 to 2.0 wt.%.
According to an embodiment of the invention, the solderable high thermal conductivity high pressure casting aluminum alloy includes 8.0 to 10.0 weight percent rare earth.
According to an embodiment of the invention, the high pressure casting aluminum alloy suitable for brazing comprises at most 0.3 wt.% copper.
According to an embodiment of the invention, the high pressure casting aluminum alloy suitable for brazing comprises at most 0.3 wt.% zinc.
According to an embodiment of the invention, the high pressure casting aluminum alloy suitable for brazing comprises at most 0.2 wt.% manganese.
According to an embodiment of the invention, the high pressure casting aluminum alloy suitable for brazing comprises at most 0.2% by weight chromium.
According to an embodiment of the invention, the high pressure casting aluminum alloy suitable for brazing comprises at most 0.05 wt.% titanium.
Drawings
FIG. 1 shows a sampling golden phase diagram of a low-carbon aluminum alloy die-casting part body;
Detailed Description
The following description is presented to enable one of ordinary skill in the art to make and use the invention. The preferred embodiments in the following description are by way of example only and this summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter.
The high-pressure casting aluminum alloy capable of brazing and high in heat conduction comprises the following components:
up to 0.5 wt% silicon;
0.5 to 2.0 wt% iron;
up to 0.3 wt% copper;
up to 0.3 wt% zinc;
up to 0.2 wt% manganese;
up to 0.2 wt% chromium;
0.3 to 1.0 weight percent magnesium;
up to 0.05 wt% titanium;
5.0 to 12.0 weight percent rare earth; wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.3 and 2.4.
Preferably, rare earth: the weight percentage of 3 Fe is controlled between 1.5 and 2.0.
It is worth mentioning that the rare earth is implemented as at least one selected from lanthanum or cerium.
Preferably, the proportion of iron in the high-pressure cast aluminum alloy is 1.0 to 2.0 wt.%. The eutectic point of iron in aluminum alloy is 1.8%, and the fluidity and demolding capability of the material are ensured by utilizing the eutectic, but the heat conduction of the material is reduced due to the excessively high iron content.
In the conventional aluminum-silicon alloy, silicon mainly improves the flowability of the material, but the alloy mainly relies on Al-Fe eutectic, if excessive silicon is added, the solidus temperature of the material is reduced, the brazing is affected, the silicon and iron form an AlFeSi phase, the elongation of the material is reduced, electron movement is hindered, heat conduction is reduced, and the preferable silicon content is at most 0.3 wt%; preferably, the silicon content is at most 0.2 wt.%.
Mn can change the morphology of beta-Fe phase to alpha-AlFeSi. This is because Mn and Fe have similar atomic radii. Mn can therefore be replaced by Fe and the beta-Fe phase can be converted to alpha-AlFeSi. Adding a certain amount of Mn consumes eutectic Fe content, and reduces the fluidity of the material and the heat conduction of the material;
in addition, rare earth exists mainly in three forms in aluminum alloys, and is solid-dissolved in the matrix α (Al); the segregation is in phase boundaries, grain boundaries and dendrite boundaries; solid solutions in or in the form of compounds. The strengthening effect of the rare earth in the aluminum alloy mainly comprises fine crystal strengthening, limited solid solution strengthening, second phase strengthening of rare earth compounds and the like; 5.0 to 12.0 weight percent of rare earth is added in excess of the supersaturation state, the strengthening is mainly carried out after the addition, the recrystallization temperature of the alloy is improved, the aluminum matrix is thinned, the strength is increased, the electric conduction is reduced less, the effect of high heat conduction can be achieved, the existence form of an iron phase is changed, and the casting performance of the aluminum alloy is improved. Preferably, the solderable high thermal conductivity high pressure casting aluminum alloy includes 8% to 10.0% by weight rare earth.
The magnesium can enhance the strength and the hardness of the alloy when the proportion of the magnesium in the die-casting aluminum alloy is 0.3 to 1.0 weight percent, because the magnesium is mainly added into the aluminum-silicon alloy and is mainly added into the aluminum-silicon alloy 2 Si phase, 0.1% of magnesium is added, the yield strength can be increased by 5-10 Mpa, the element is obvious for improving the strength of aluminum alloy, and the price is equal to that of aluminumThe difference is small.
Rare earth: and 3, controlling the Fe to be 1.3-2.4. The proportion is below 1.3, the Fe phase cannot be changed to affect the electric conduction and/or other properties such as tensile strength, while the proportion is above 2.4, and excessive rare earth compounds obstruct the movement of electrons, so that the heat conduction requirement cannot be met.
According to another aspect of the present invention, there is provided a method for manufacturing a solderable high heat conduction high pressure cast aluminum alloy, wherein the method for manufacturing a high pressure cast aluminum alloy comprises:
s1, melting a reclaimed aluminum raw material, and controlling the temperature of an aluminum liquid to be between 710 and 730 ℃;
wherein the aluminum liquid comprises:
up to 0.5 wt% silicon;
0.5 to 2.0 wt% iron;
up to 0.3 wt% copper;
up to 0.3 wt% zinc;
up to 0.2 wt% manganese;
up to 0.2 wt% chromium;
0.3 to 1.0 weight percent magnesium;
up to 0.05 wt% titanium;
5.0 to 12.0 weight percent rare earth; wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.3 and 2.4.
S2, pressing the sodium-free aluminum alloy refining agent into the aluminum alloy through a deaerator for refining, and refining for a preset time to remove gas in the aluminum liquid;
s3, detecting the gas content by a hydrogen detector, and when the gas content is below 0.15ml/100g, performing die casting by an aluminum alloy high-pressure casting device to form the low-carbon high-pressure casting heat-treatment-free aluminum alloy.
Preferably, the method for manufacturing the solderable high-heat-conductivity aluminum alloy comprises the following steps:
s4, material preparation and furnace cleaning: preparing materials according to the proportion of alloy components, and cleaning the furnace after the materials are prepared.
It is worth mentioning that the alloying elements are added in the form of pure alloys or master alloys.
For example, fe element is added in the form of Al-Fe intermediate alloy, mg element is added in the form of pure Mg ingot, mn element is added in the form of Al-Mn intermediate alloy, ti element is added in the form of Al-Ti intermediate alloy, rare earth elements such as lanthanum, cerium, scandium element are added in the form of intermediate alloy.
In the process of melting aluminum ingots, after the surfaces of the reclaimed aluminum raw materials are clean, putting the pure aluminum ingots and rare earth intermediate alloy into a resistance crucible for heating and smelting, and controlling the temperature of aluminum liquid between 710 ℃ and 730 ℃;
in addition to the master alloy: when the temperature of the aluminum liquid reaches 720 ℃, adding the dried Al-Cu intermediate alloy, magnesium ingots, al-Ti and other intermediate alloys into the aluminum liquid, heating the aluminum liquid to 740 ℃, and preserving the heat for 15 minutes to ensure that the added intermediate alloy is completely melted;
when the temperature of the aluminum liquid is reduced to 710-730 ℃ during refining, the sodium-free refining agent of the aluminum alloy is pressed into the aluminum alloy by a movable rotary degassing machine to refine, and the aluminum-strontium intermediate alloy is added during refining to refine for a preset time. Preferably 10-30 minutes, then slagging off and standing. If the mixture is kept stand for 1 hour, an online hydrogen meter is used for detecting the gas content after the mixture is kept stand, and when the gas content is below 0.15ml/100g, die casting is carried out, and if the gas content does not meet the requirement, the refining, modification and degassing process is continued.
And (3) die casting production verification:
1) Production equipment and auxiliary accessories: 280T force die casting machine, automatic soup feeder, mould temperature machine, brand vacuum machine, special inlet release agent for die casting structural part on the market, inlet particle beads, 3mm 80mm 250mm homemade test piece mould (figure 1), 50mm punch and melting cup;
2) And (3) die casting process control: the temperature of the die casting aluminum liquid is controlled between 680 and 690 ℃, the temperature of a die temperature machine is controlled between 160 and 170 ℃, the high-speed is controlled between 2.7 and 2.9m/S, the vacuum degree is controlled between 10 and 40mbar, and the pressurizing pressure is 65Mpa;
3) The following is the test performance of the die-casting test piece with different component proportions according to GBT228 standard test piece wire cutting, using a three-Si tensile machine and an inlet extensometer.
The aluminum alloys for high pressure casting of five examples were manufactured by the above manufacturing processes, respectively, and the properties thereof were examined, and the following table 1 is concrete.
TABLE 1
Figure BDA0004168607850000041
Figure BDA0004168607850000051
It will be appreciated by persons skilled in the art that the embodiments of the invention described above and shown in the drawings are by way of example only and are not limiting. The advantages of the present invention have been fully and effectively realized. The functional and structural principles of the present invention have been shown and described in the examples and embodiments of the invention may be modified or practiced without departing from the principles described.

Claims (10)

1. A high pressure cast aluminum alloy suitable for brazing, characterized in that the high pressure cast aluminum alloy suitable for brazing comprises:
up to 0.5 wt% silicon;
0.5 to 2.0 wt% iron;
0.3 to 1.0 weight percent magnesium;
5.0 to 12.0 weight percent rare earth; wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.3 and 2.4.
2. The solderable high thermal conductivity high pressure cast aluminum alloy of claim 1 wherein the rare earth: the weight percentage of 3 Fe is controlled between 1.5 and 2.0.
3. The solderable high heat conductive high pressure casting aluminum alloy of claim 1 wherein the rare earth is implemented as at least one selected from lanthanum or cerium.
4. The high-pressure casting aluminum alloy capable of brazing according to claim 1, wherein the proportion of iron in the high-pressure casting aluminum alloy is 1.0-2.0 wt.%.
5. The high pressure braze alloy of claim 1, wherein the high pressure braze alloy comprises 8.0 to 10.0 wt.% rare earth.
6. The brazeable high thermal conductivity high pressure casting aluminum alloy of claim 1, wherein the high pressure casting aluminum alloy suitable for brazing comprises up to 0.3 weight percent copper.
7. The brazeable high thermal conductivity high pressure casting aluminum alloy of claim 1, wherein the high pressure casting aluminum alloy suitable for brazing comprises up to 0.3 weight percent zinc.
8. The brazeable high thermal conductivity high pressure casting aluminum alloy of claim 1, wherein the high pressure casting aluminum alloy suitable for brazing comprises up to 0.2 weight percent manganese.
9. The brazeable high thermal conductivity high pressure casting aluminum alloy of claim 1, wherein the high pressure casting aluminum alloy suitable for brazing comprises up to 0.2 weight percent chromium.
10. The brazeable high thermal conductivity high pressure casting aluminum alloy of claim 1, wherein the high pressure casting aluminum alloy suitable for brazing comprises up to 0.05 weight percent titanium.
CN202310371206.4A 2023-04-10 2023-04-10 High pressure cast aluminum alloy suitable for brazing Pending CN116377289A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117144203A (en) * 2023-09-20 2023-12-01 大连亚明汽车部件股份有限公司 High-pressure casting aluminum alloy with high heat conductivity coefficient and capable of being brazed
CN117165817A (en) * 2023-09-20 2023-12-05 大连亚明汽车部件股份有限公司 High-pressure casting aluminum alloy with high heat conductivity coefficient and capable of being brazed
CN117210725A (en) * 2023-09-20 2023-12-12 大连亚明汽车部件股份有限公司 Low-heat-conductivity high-pressure casting aluminum alloy capable of being brazed
CN117385225A (en) * 2023-09-20 2024-01-12 大连亚明汽车部件股份有限公司 Method for strengthening mechanical properties of high-temperature brazing die-casting aluminum alloy material

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117144203A (en) * 2023-09-20 2023-12-01 大连亚明汽车部件股份有限公司 High-pressure casting aluminum alloy with high heat conductivity coefficient and capable of being brazed
CN117165817A (en) * 2023-09-20 2023-12-05 大连亚明汽车部件股份有限公司 High-pressure casting aluminum alloy with high heat conductivity coefficient and capable of being brazed
CN117210725A (en) * 2023-09-20 2023-12-12 大连亚明汽车部件股份有限公司 Low-heat-conductivity high-pressure casting aluminum alloy capable of being brazed
CN117385225A (en) * 2023-09-20 2024-01-12 大连亚明汽车部件股份有限公司 Method for strengthening mechanical properties of high-temperature brazing die-casting aluminum alloy material

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