CN116376415A - Preparation method of wall paint with strong antibacterial and anti-stain effects - Google Patents

Preparation method of wall paint with strong antibacterial and anti-stain effects Download PDF

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CN116376415A
CN116376415A CN202310290506.XA CN202310290506A CN116376415A CN 116376415 A CN116376415 A CN 116376415A CN 202310290506 A CN202310290506 A CN 202310290506A CN 116376415 A CN116376415 A CN 116376415A
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stirring
chitosan
emulsion
wall paint
stirrer
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吴金友
胡爱国
覃世俊
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Guangdong Lushu Environmental Coating Technology Co ltd
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Guangdong Lushu Environmental Coating Technology Co ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B23/00Heating arrangements
    • F26B23/001Heating arrangements using waste heat
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C08F283/124Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
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    • C08G18/348Hydroxycarboxylic acids
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/64Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D151/085Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
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    • C09D175/04Polyurethanes
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract

The invention provides a preparation method of a wall paint with strong antibacterial and anti-stain effects. The preparation method of the wall paint with strong antibacterial and anti-stain effects comprises the following steps: citric acid acidifying chitosan, synthesizing polyurethane by using polyester polyol, adding the acidified chitosan for modification, preparing modified acrylic emulsion by using polysiloxane, and adding other auxiliary agents for mixing. According to the invention, the modified acrylic emulsion is prepared by mixing polysiloxane with active vinyl, methyl methacrylate and the like, and then the modified acrylic emulsion is mixed with the aqueous polyurethane emulsion to prepare the wall paint, so that the wall paint has a compact coating structure, and has better stain resistance, water resistance, weather resistance and stronger adhesive force.

Description

Preparation method of wall paint with strong antibacterial and anti-stain effects
Technical Field
The invention relates to the technical field of paint, in particular to a preparation method of a wall paint with strong antibacterial and anti-stain effects.
Background
The wall paint is one of main decorative materials for the wall in the home decoration, the water-based polyurethane is widely applied to the fields of paint, adhesives, fabrics and the like due to the excellent physical and chemical properties of the water-based polyurethane, and can be used for preparing the wall paint, however, the water-based polyurethane is poor in water resistance and easy to generate bacteria, and the antibacterial property of the wall paint is usually enhanced by adding an organic antibacterial agent, silver ions or nano metals and the like at present, but the antibacterial wall paint prepared in the mode is insufficient in durability, stain resistance and safety.
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide a preparation method of a wall paint with strong antibacterial and anti-stain effects.
A preparation method of a wall paint with strong antibacterial and anti-stain effects comprises the following steps:
s1: citric acid acidified chitosan
Adding citric acid and chitosan into an ethanol solution, stirring for reaction, performing centrifugal separation, and then washing and drying to obtain acidified chitosan;
s2: synthesis of polyurethane from polyester polyol
Under the high temperature condition, polytetrahydrofuran ether glycol, polyester polyol, isophorone diisocyanate and dimethylolbutyric acid are mixed for reaction to obtain a precursor;
s3: adding acidified chitosan for modification
Adding the acidified chitosan into the precursor, performing ball milling, performing heat preservation reaction, adding triethylamine to adjust the PH, and adding deionized water to emulsify to obtain chitosan modified polyurethane emulsion;
s4: preparation of modified acrylic emulsion with polysiloxane
Mixing methyl methacrylate, methacrylic acid, polysiloxane with active vinyl and an emulsifier, adding water for emulsification, and then adding an initiator for reaction to obtain modified acrylic emulsion;
s5: adding other auxiliary agents for mixing
Adding a defoaming agent, a leveling agent and a thickening agent into the chitosan modified polyurethane emulsion, stirring for 2-3 hours at the speed of 1200-1500r/min, uniformly mixing, adding a film forming additive and the modified acrylic emulsion, and continuously stirring for 1-1.5 hours at the speed of 800-1000r/min to obtain the wall paint.
Further, the citric acid-acidified chitosan of the step S1 specifically includes the following steps:
s1.1: adding citric acid and chitosan together into a reaction tank containing ethanol solution according to a molar ratio of 2-5:1, stirring for 0.5-1h, and reacting to obtain a solid-liquid mixture;
s1.2: starting a pressurizing pump, pressing the solid-liquid mixture into a centrifugal separator through a slide pipe, centrifuging the solid-liquid mixture for 15-30min at a speed of 5000-8000r/min by the centrifugal separator, performing solid-liquid separation, and discharging filtrate to obtain filter residues;
s1.3: washing the filter residue for 2-5 times by using absolute ethyl alcohol, and then placing the washed filter residue into a drying box for drying to obtain the acidified chitosan.
Further, the step S2 of synthesizing polyurethane by using polyester polyol specifically comprises the following steps:
s2.1: vacuum dehydrating polytetrahydrofuran ether glycol, adding the polytetrahydrofuran ether glycol and polyester polyol into a stirrer together according to the molar ratio of 1:2-3, heating to 50-70 ℃, stirring and mixing;
s2.2: adding isophorone diisocyanate into a stirrer, stirring uniformly, heating to 80-90 ℃, and reacting for 2-3h under heat preservation;
s2.3: adding the dimethylolbutyric acid into a stirrer, stirring at the speed of 200-300r/min for 1-2h, and performing chain extension reaction to obtain a precursor.
Further, the step S3 of adding the acidified chitosan for modification specifically comprises the following steps:
s3.1: adding the acidified chitosan into the precursor, ball-milling for 30-40min at a speed of 800-1200rpm by using a ball-milling device in a stirrer, keeping the temperature in the stirrer at 80-90 ℃, and continuing to react for 2-5h;
s3.2: regulating the temperature to 40-60 ℃, pumping triethylamine into a stirrer by using a hydraulic pump, stirring the triethylamine until a PH detector in the stirrer detects PH=7-8, stopping pumping the triethylamine, stopping stirring, standing and cooling to room temperature;
s3.3: and filling deionized water into a hydraulic pump of the stirrer, pressing the deionized water into the stirrer from small holes on stirring claws by the hydraulic pump, stirring at the same time, and emulsifying to obtain the chitosan modified polyurethane emulsion.
Further, the step S4 of preparing the modified acrylic emulsion by polysiloxane specifically comprises the following steps:
s4.1: adding methyl methacrylate, methacrylic acid, polysiloxane with active vinyl and an emulsifying agent into an emulsifying cylinder, adding water, and uniformly stirring to obtain a pre-emulsion;
s4.2: placing 1/5 of the pre-emulsion into a reactor, adding 1/3 of an initiator, uniformly stirring, heating to 60-70 ℃, and reacting for 1-2h;
s4.3: adding the residual pre-emulsion into a reactor, adding 1/2 of the residual initiator, heating to 70-80 ℃, and reacting for 2-3h;
s4.4: and adding all the rest initiator into the reactor, stirring for 40-50min, simultaneously carrying out heat preservation reaction, and cooling to room temperature to obtain the modified acrylic emulsion.
Further, the drying box is arranged on the inner wall of the reactor in the step S4.2, when the temperature in the reactor is raised for reaction, the temperature in the drying box is raised through the waste heat in the reactor, and the washed filter residues are dried.
Further, the emulsifier is prepared by mixing a T-02 emulsifier and an SDS emulsifier according to a volume ratio of 1-3:1.
Further, the volume ratio of the methyl methacrylate, the methacrylic acid and the polysiloxane with the active vinyl is 5-10:2-5:1.
Compared with the prior art, the invention has the advantages that:
1. according to the invention, the modified acrylic emulsion is prepared by mixing polysiloxane with active vinyl, methyl methacrylate and the like, and then the modified acrylic emulsion is mixed with the aqueous polyurethane emulsion to prepare the wall paint, so that the wall paint has a compact coating structure, and has better stain resistance, water resistance, weather resistance and stronger adhesive force.
2. According to the invention, the chitosan is acidified by citric acid to improve the water solubility of the chitosan, the polyurethane is modified by the acidified chitosan, and the wall paint prepared by taking the modified polyurethane emulsion as a raw material has strong antibacterial property, and is environment-friendly and pollution-free.
3. According to the invention, the residual heat generated during the reaction is utilized to heat the drying box, so that the filter residues are dried, the effect of fully and effectively utilizing resources is achieved, and the preparation time can be saved.
Drawings
FIG. 1 is a flow chart of a method for preparing a wall paint with potent antimicrobial and stain resistance used in an embodiment of the present invention.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
A preparation method of a wall paint with strong antibacterial and anti-stain effects is shown in figure 1, and comprises the following steps:
s1: citric acid acidified chitosan
Adding citric acid produced by the dry and Yao technology Co., ltd and chitosan produced by the Wuhan Ji chemical Co., ltd into a reaction tank containing ethanol solution according to a molar ratio of 2:1, stirring for 0.5h, reacting to obtain a solid-liquid mixture, starting a booster pump, pressing the solid-liquid mixture into a centrifugal separator through a slide tube, centrifuging the solid-liquid mixture at a speed of 5000r/min for 15min by the centrifugal separator, performing solid-liquid separation, discharging filtrate to obtain filter residues, washing the filter residues for 2 times by absolute ethanol, and then drying the washed filter residues in a drying box to obtain acidified chitosan;
s2: synthesis of polyurethane from polyester polyol
Vacuum dehydrating polytetrahydrofuran ether glycol produced by Jinan Guangyu chemical industry Co., ltd, adding the polytetrahydrofuran ether glycol and polyester polyol produced by Shandong Shuixin new material science and technology Co., ltd together in a molar ratio of 1:2 into a stirrer, heating to 50 ℃, stirring and mixing, adding isophorone diisocyanate produced by Hubei Chengfeng chemical industry Co., ltd into the stirrer, stirring uniformly, heating to 80 ℃, carrying out heat preservation and reaction for 2 hours, adding dimethylolbutyric acid produced by Cheng Mojia new material Co., ltd into the stirrer, stirring for 1 hour at a speed of 200r/min, and carrying out chain extension reaction to obtain a precursor;
s3: adding acidified chitosan for modification
Adding the acidified chitosan into the precursor, ball-milling for 30min at the speed of 800rpm by using a ball milling device in a stirrer, keeping the temperature in the stirrer at 80 ℃, continuously reacting for 2h, adjusting the temperature to 40 ℃, pumping triethylamine into the stirrer by using a hydraulic pump, stirring simultaneously until PH=7 is detected by a PH detector in the stirrer, stopping pumping triethylamine, stopping stirring, standing and cooling to room temperature, loading deionized water into the hydraulic pump of the stirrer, pressing the deionized water into the stirrer from small holes on stirring claws by using the hydraulic pump, stirring simultaneously, emulsifying to obtain chitosan modified polyurethane emulsion, modifying polyurethane by using the acidified chitosan, and preparing wall paint by using the modified polyurethane emulsion as a raw material, wherein the wall paint has strong antibacterial property, is green and environment-friendly;
s4: preparation of modified acrylic emulsion with polysiloxane
Adding methyl methacrylate produced by Jinan Runtai chemical industry Co., ltd, methacrylic acid produced by Shandong Mao national trade Co., ltd, active vinyl polysiloxane produced by Wuhan Hana white pharmaceutical chemical industry Co., ltd and an emulsifier prepared by mixing a T-02 emulsifier and an SDS emulsifier according to a volume ratio of 1:1 into an emulsifying tank together, adding water, stirring uniformly to obtain a pre-emulsion, then taking 1/5 of the pre-emulsion, placing the pre-emulsion into a reactor, adding 1/3 of an initiator, stirring uniformly, heating to 60 ℃, reacting for 1h, adding the rest of the pre-emulsion, adding 1/2 of the rest of the initiator, heating to 70 ℃, reacting for 2h, heating the drying tank by using waste heat in the reactor while heating reaction, finally adding the rest of the initiator into the reactor, stirring for 40min, cooling to room temperature, obtaining modified acrylic acid, preparing a modified acrylic acid emulsion with good weather resistance, and a high water resistance, and a modified acrylic acid emulsion, and a high weather resistance, and a modified acrylic acid emulsion, a high water resistance, and a modified acrylic acid emulsion, a modified acrylic acid emulsion, and a high-water resistance emulsion, and a high-resistance emulsion;
s5: adding other auxiliary agents for mixing
Adding a defoaming agent, a leveling agent and a thickening agent into the chitosan modified polyurethane emulsion, stirring for 2 hours at the speed of 1200r/min, uniformly mixing, adding a film forming auxiliary agent and the modified acrylic emulsion, and continuously stirring for 1 hour at the speed of 800r/min to obtain the wall paint.
Example 2
A preparation method of a wall paint with strong antibacterial and anti-stain effects is shown in figure 1, and comprises the following steps:
s1: citric acid acidified chitosan
Adding citric acid produced by the dry and Yao technology Co., ltd and chitosan produced by the Wuhan Ji chemical Co., ltd into a reaction tank containing ethanol solution according to a molar ratio of 5:1, stirring for 0.5h, reacting to obtain a solid-liquid mixture, starting a booster pump, pressing the solid-liquid mixture into a centrifugal separator through a slide tube, centrifuging the solid-liquid mixture at a speed of 8000r/min for 15min by the centrifugal separator, performing solid-liquid separation, discharging filtrate to obtain filter residues, washing the filter residues for 5 times by absolute ethanol, and then drying the washed filter residues in a drying box to obtain acidified chitosan;
s2: synthesis of polyurethane from polyester polyol
Vacuum dehydrating polytetrahydrofuran ether glycol produced by Jinan Guangyu chemical industry Co., ltd, adding the polytetrahydrofuran ether glycol and polyester polyol produced by Shandong Shuixin new material science and technology Co., ltd together in a molar ratio of 1:3 into a stirrer, heating to 70 ℃, stirring and mixing, adding isophorone diisocyanate produced by Hubei Chengfeng chemical industry Co., ltd into the stirrer, stirring uniformly, heating to 90 ℃, carrying out heat preservation and reaction for 2 hours, adding dimethylolbutyric acid produced by Cheng Mojia new material Co., ltd into the stirrer, stirring for 1 hour at a speed of 300r/min, and carrying out chain extension reaction to obtain a precursor;
s3: adding acidified chitosan for modification
Adding the acidified chitosan into the precursor, ball-milling for 30min at the speed of 1200rpm by using a ball milling device in a stirrer, keeping the temperature in the stirrer at 90 ℃, continuously reacting for 2h, adjusting the temperature to 60 ℃, pumping triethylamine into the stirrer by using a hydraulic pump, stirring simultaneously until PH=8 is detected by a PH detector in the stirrer, stopping pumping triethylamine, stopping stirring, standing and cooling to room temperature, loading deionized water into the hydraulic pump of the stirrer, pressing the deionized water into the stirrer from small holes on stirring claws by using the hydraulic pump, stirring simultaneously, emulsifying to obtain chitosan modified polyurethane emulsion, modifying polyurethane by using the acidified chitosan, and preparing wall paint by using the modified polyurethane emulsion as a raw material, wherein the wall paint has strong antibacterial property, is green and environment-friendly;
s4: preparation of modified acrylic emulsion with polysiloxane
Adding methyl methacrylate produced by Jinan Runtai chemical industry Co., ltd, methacrylic acid produced by Shandong Mao national trade Co., ltd, active vinyl polysiloxane produced by Wuhan Hana white pharmaceutical chemical industry Co., ltd and an emulsifier prepared by mixing a T-02 emulsifier and an SDS emulsifier according to a volume ratio of 3:1 into an emulsifying tank together, adding water, stirring uniformly to obtain a pre-emulsion, then taking 1/5 of the pre-emulsion, placing the pre-emulsion into a reactor, adding 1/3 of an initiator, stirring uniformly, heating to 70 ℃, reacting for 1h, adding the rest of the pre-emulsion, adding 1/2 of the rest of the initiator, heating to 80 ℃, reacting for 2h, heating the drying tank by using waste heat in the reactor while heating reaction, finally adding the rest of the initiator into the reactor, stirring for 40min, cooling to room temperature, obtaining modified acrylic acid, preparing a modified acrylic acid emulsion with good weather resistance, and a high water resistance, and a modified acrylic acid emulsion, and a high weather resistance, and a modified acrylic acid emulsion, a high water resistance, and a modified acrylic acid emulsion, a modified acrylic acid emulsion, and a high-water resistance emulsion, and a high-resistance emulsion;
s5: adding other auxiliary agents for mixing
Adding a defoaming agent, a leveling agent and a thickening agent into the chitosan modified polyurethane emulsion, stirring for 2 hours at the speed of 1500r/min, uniformly mixing, adding a film forming auxiliary agent and the modified acrylic emulsion, and continuously stirring for 1 hour at the speed of 1000r/min to obtain the wall paint.
Example 3
A preparation method of a wall paint with strong antibacterial and anti-stain effects is shown in figure 1, and comprises the following steps:
s1: citric acid acidified chitosan
Adding citric acid produced by the dry and blazed technology Co., ltd and chitosan produced by the Wuhan Ji chemical Co., ltd into a reaction tank containing ethanol solution according to a molar ratio of 2:1, stirring for 1h, reacting to obtain a solid-liquid mixture, starting a pressurizing pump, pressing the solid-liquid mixture into a centrifugal separator through a slide tube, centrifuging the solid-liquid mixture at a speed of 5000r/min for 30min by the centrifugal separator, performing solid-liquid separation, discharging filtrate to obtain filter residues, washing the filter residues for 5 times by absolute ethanol, and then drying the washed filter residues in a drying box to obtain acidified chitosan, wherein the water solubility of the chitosan is improved by using citric acid to acidify the chitosan;
s2: synthesis of polyurethane from polyester polyol
Vacuum dehydrating polytetrahydrofuran ether glycol produced by Jinan Guangyu chemical industry Co., ltd, adding the polytetrahydrofuran ether glycol and polyester polyol produced by Shandong Shuixin new material science and technology Co., ltd together in a molar ratio of 1:2 into a stirrer, heating to 50 ℃, stirring and mixing, adding isophorone diisocyanate produced by Hubei Chengfeng chemical industry Co., ltd into the stirrer, stirring uniformly, heating to 80 ℃, carrying out heat preservation reaction for 3 hours, adding dimethylolbutyric acid produced by Cheng Mojia new material Co., ltd into the stirrer, stirring for 2 hours at a speed of 200r/min, and carrying out chain extension reaction to obtain a precursor;
s3: adding acidified chitosan for modification
Adding the acidified chitosan into the precursor, ball-milling for 40min at the speed of 800rpm by using a ball milling device in a stirrer, keeping the temperature in the stirrer at 80 ℃, continuously reacting for 5h, adjusting the temperature to 40 ℃, pumping triethylamine into the stirrer by using a hydraulic pump, stirring simultaneously until PH=7 is detected by a PH detector in the stirrer, stopping pumping triethylamine, stopping stirring, standing and cooling to room temperature, loading deionized water into the hydraulic pump of the stirrer, pressing the deionized water into the stirrer from small holes on stirring claws by using the hydraulic pump, stirring simultaneously, emulsifying to obtain chitosan modified polyurethane emulsion, modifying polyurethane by using the acidified chitosan, and preparing wall paint by using the modified polyurethane emulsion as a raw material, wherein the wall paint has strong antibacterial property, is green and environment-friendly;
s4: preparation of modified acrylic emulsion with polysiloxane
Adding methyl methacrylate produced by Jinan Runtai chemical industry Co., ltd, methacrylic acid produced by Shandong Mao national trade Co., ltd, active vinyl polysiloxane produced by Wuhan Hana white pharmaceutical chemical industry Co., ltd and an emulsifier prepared by mixing a T-02 emulsifier and an SDS emulsifier according to a volume ratio of 1:1 into an emulsifying tank together, adding water, stirring uniformly to obtain a pre-emulsion, then taking 1/5 of the pre-emulsion, placing the pre-emulsion into a reactor, adding 1/3 of an initiator, stirring uniformly, heating to 60 ℃, reacting for 2h, adding the rest of the pre-emulsion, adding 1/2 of the rest of the initiator, heating to 70 ℃, reacting for 3h, heating the drying tank by using waste heat in the reactor while heating reaction, finally adding the rest of the initiator into the reactor, stirring for 50min, cooling to room temperature, obtaining modified acrylic acid, preparing a modified acrylic acid emulsion with good weather resistance, and a high water resistance, and a high weather resistance, and a modified acrylic acid emulsion, a high water resistance, a modified acrylic acid emulsion, a high-acrylic acid emulsion, and a high water resistance, and a modified acrylic acid emulsion, and a high-soluble polyurethane emulsion;
s5: adding other auxiliary agents for mixing
Adding a defoaming agent, a leveling agent and a thickening agent into the chitosan modified polyurethane emulsion, stirring for 3 hours at the speed of 1200r/min, uniformly mixing, adding a film forming additive and the modified acrylic emulsion, and continuously stirring for 1.5 hours at the speed of 800r/min to obtain the wall paint.
The above embodiments are merely illustrative of the principles of the present invention and its effectiveness, and are not intended to limit the invention. Modifications and variations may be made to the above-described embodiments by those skilled in the art without departing from the spirit and scope of the invention. Accordingly, it is intended that all equivalent modifications and variations of the invention be covered by the claims, which are within the ordinary skill of the art, be within the spirit and scope of the present disclosure.

Claims (8)

1. The preparation method of the wall paint with strong antibacterial and anti-stain effects is characterized by comprising the following steps of:
s1: citric acid acidified chitosan
Adding citric acid and chitosan into an ethanol solution, stirring for reaction, performing centrifugal separation, and then washing and drying to obtain acidified chitosan;
s2: synthesis of polyurethane from polyester polyol
Under the high temperature condition, polytetrahydrofuran ether glycol, polyester polyol, isophorone diisocyanate and dimethylolbutyric acid are mixed for reaction to obtain a precursor;
s3: adding acidified chitosan for modification
Adding the acidified chitosan into the precursor, performing ball milling, performing heat preservation reaction, adding triethylamine to adjust the PH, and adding deionized water to emulsify to obtain chitosan modified polyurethane emulsion;
s4: preparation of modified acrylic emulsion with polysiloxane
Mixing methyl methacrylate, methacrylic acid, polysiloxane with active vinyl and an emulsifier, adding water for emulsification, and then adding an initiator for reaction to obtain modified acrylic emulsion;
s5: adding other auxiliary agents for mixing
Adding a defoaming agent, a leveling agent and a thickening agent into the chitosan modified polyurethane emulsion, stirring for 2-3 hours at the speed of 1200-1500r/min, uniformly mixing, adding a film forming additive and the modified acrylic emulsion, and continuously stirring for 1-1.5 hours at the speed of 800-1000r/min to obtain the wall paint.
2. The method for preparing the wall paint with strong antibacterial and anti-stain effects according to claim 1, wherein the citric acid-acidified chitosan of the step S1 specifically comprises the following steps:
s1.1: adding citric acid and chitosan together into a reaction tank containing ethanol solution according to a molar ratio of 2-5:1, stirring for 0.5-1h, and reacting to obtain a solid-liquid mixture;
s1.2: starting a pressurizing pump, pressing the solid-liquid mixture into a centrifugal separator through a slide pipe, centrifuging the solid-liquid mixture for 15-30min at a speed of 5000-8000r/min by the centrifugal separator, performing solid-liquid separation, and discharging filtrate to obtain filter residues;
s1.3: washing the filter residue for 2-5 times by using absolute ethyl alcohol, and then placing the washed filter residue into a drying box for drying to obtain the acidified chitosan.
3. The method for preparing the wall paint with strong antibacterial and anti-stain effects according to claim 1, wherein the step S2 of synthesizing polyurethane by using polyester polyol specifically comprises the following steps:
s2.1: vacuum dehydrating polytetrahydrofuran ether glycol, adding the polytetrahydrofuran ether glycol and polyester polyol into a stirrer together according to the molar ratio of 1:2-3, heating to 50-70 ℃, stirring and mixing;
s2.2: adding isophorone diisocyanate into a stirrer, stirring uniformly, heating to 80-90 ℃, and reacting for 2-3h under heat preservation;
s2.3: adding the dimethylolbutyric acid into a stirrer, stirring at the speed of 200-300r/min for 1-2h, and performing chain extension reaction to obtain a precursor.
4. The method for preparing the wall paint with strong antibacterial and anti-stain effects according to claim 1, wherein the step S3 of adding the acidified chitosan for modification comprises the following steps:
s3.1: adding the acidified chitosan into the precursor, ball-milling for 30-40min at a speed of 800-1200rpm by using a ball-milling device in a stirrer, keeping the temperature in the stirrer at 80-90 ℃, and continuing to react for 2-5h;
s3.2: regulating the temperature to 40-60 ℃, pumping triethylamine into a stirrer by using a hydraulic pump, stirring the triethylamine until a PH detector in the stirrer detects PH=7-8, stopping pumping the triethylamine, stopping stirring, standing and cooling to room temperature;
s3.3: and filling deionized water into a hydraulic pump of the stirrer, pressing the deionized water into the stirrer from small holes on stirring claws by the hydraulic pump, stirring at the same time, and emulsifying to obtain the chitosan modified polyurethane emulsion.
5. The method for preparing the wall paint with strong antibacterial and anti-stain effects according to claim 2, wherein the step S4 of preparing the modified acrylic emulsion with polysiloxane specifically comprises the following steps:
s4.1: adding methyl methacrylate, methacrylic acid, polysiloxane with active vinyl and an emulsifying agent into an emulsifying cylinder, adding water, and uniformly stirring to obtain a pre-emulsion;
s4.2: placing 1/5 of the pre-emulsion into a reactor, adding 1/3 of an initiator, uniformly stirring, heating to 60-70 ℃, and reacting for 1-2h;
s4.3: adding the residual pre-emulsion into a reactor, adding 1/2 of the residual initiator, heating to 70-80 ℃, and reacting for 2-3h;
s4.4: and adding all the rest initiator into the reactor, stirring for 40-50min, simultaneously carrying out heat preservation reaction, and cooling to room temperature to obtain the modified acrylic emulsion.
6. The method for preparing a wall paint with strong antibacterial and anti-stain effects according to claim 5, wherein the drying box is installed on the inner wall of the reactor in the step S4.2, and when the temperature in the reactor is raised for reaction, the temperature in the drying box is raised by the waste heat in the reactor, and the washed filter residues are dried.
7. The method for preparing a wall paint with strong antibacterial and anti-stain effects according to claim 5, wherein the emulsifier is prepared by mixing a T-02 emulsifier and an SDS emulsifier according to a volume ratio of 1-3:1.
8. The method for preparing a wall paint with strong antibacterial and anti-stain effects according to claim 5, wherein the volume ratio of methyl methacrylate, methacrylic acid and polysiloxane with active vinyl is 5-10:2-5:1.
CN202310290506.XA 2023-03-22 2023-03-22 Preparation method of wall paint with strong antibacterial and anti-stain effects Pending CN116376415A (en)

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Publication number Priority date Publication date Assignee Title
CN101429407A (en) * 2008-12-08 2009-05-13 广州市科霖水性材料有限公司 Watersoluble polyurethane acrylic acid composite coating agent and method of producing the same
CN102924646A (en) * 2012-12-03 2013-02-13 陕西科技大学 Preparation method of waterproof and whiting-resistant silicon-acrylic composite emulsion for interior wall latex coatings
CN107236109A (en) * 2017-07-19 2017-10-10 陕西科技大学 Citrated chitin modified water polyurethane and preparation method thereof
CN108977051A (en) * 2018-06-29 2018-12-11 安徽天锦云漆业有限公司 A kind of water-fast stain-resistant exterior wall coating
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof
CN112409867A (en) * 2020-11-11 2021-02-26 惠州市惠阳区嘉泰涂料有限公司 Water-based wear-resistant paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429407A (en) * 2008-12-08 2009-05-13 广州市科霖水性材料有限公司 Watersoluble polyurethane acrylic acid composite coating agent and method of producing the same
CN102924646A (en) * 2012-12-03 2013-02-13 陕西科技大学 Preparation method of waterproof and whiting-resistant silicon-acrylic composite emulsion for interior wall latex coatings
CN107236109A (en) * 2017-07-19 2017-10-10 陕西科技大学 Citrated chitin modified water polyurethane and preparation method thereof
CN108977051A (en) * 2018-06-29 2018-12-11 安徽天锦云漆业有限公司 A kind of water-fast stain-resistant exterior wall coating
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof
CN112409867A (en) * 2020-11-11 2021-02-26 惠州市惠阳区嘉泰涂料有限公司 Water-based wear-resistant paint and preparation method thereof

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