CN116376332A - Super-smooth inorganic zinc-rich coating - Google Patents
Super-smooth inorganic zinc-rich coating Download PDFInfo
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- CN116376332A CN116376332A CN202310352260.4A CN202310352260A CN116376332A CN 116376332 A CN116376332 A CN 116376332A CN 202310352260 A CN202310352260 A CN 202310352260A CN 116376332 A CN116376332 A CN 116376332A
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- inorganic zinc
- rich coating
- smooth
- rich
- ultra
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 112
- 238000000576 coating method Methods 0.000 title claims abstract description 107
- 239000011248 coating agent Substances 0.000 title claims abstract description 103
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 100
- 239000011701 zinc Substances 0.000 title claims abstract description 100
- 239000010687 lubricating oil Substances 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 239000010702 perfluoropolyether Substances 0.000 claims description 8
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 230000001680 brushing effect Effects 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229910001200 Ferrotitanium Inorganic materials 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 229910021485 fumed silica Inorganic materials 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- KKYDYRWEUFJLER-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6,7,7,10,10,10-heptadecafluorodecyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F KKYDYRWEUFJLER-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229940089951 perfluorooctyl triethoxysilane Drugs 0.000 claims description 3
- 238000007761 roller coating Methods 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- PMQIWLWDLURJOE-UHFFFAOYSA-N triethoxy(1,1,2,2,3,3,4,4,5,5,6,6,7,7,10,10,10-heptadecafluorodecyl)silane Chemical compound CCO[Si](OCC)(OCC)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F PMQIWLWDLURJOE-UHFFFAOYSA-N 0.000 claims description 3
- AVYKQOAMZCAHRG-UHFFFAOYSA-N triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F AVYKQOAMZCAHRG-UHFFFAOYSA-N 0.000 claims description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- 229910000831 Steel Inorganic materials 0.000 description 13
- 239000010959 steel Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 238000005536 corrosion prevention Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 241000208720 Nepenthes Species 0.000 description 1
- 239000004110 Zinc silicate Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an ultra-smooth inorganic zinc-rich coating, which comprises an inorganic zinc-rich coating and an ultra-smooth coating, wherein the inorganic zinc-rich coating is prepared from nano modified inorganic zinc-rich coating, and the ultra-smooth coating is formed by pouring low-surface-energy lubricating oil on the surface of the inorganic zinc-rich coating. The super-smooth inorganic zinc-rich coating solves the problem that the inorganic zinc-rich coating has poor anti-corrosion effect under the conditions of high humidity and water contact by introducing the super-smooth coating technology, and further improves the anti-corrosion performance of the inorganic zinc-rich coating.
Description
Technical Field
The invention discloses an ultra-smooth inorganic zinc-rich coating, and belongs to the technical field of metal corrosion prevention.
Background
Steel is used as engineering material widely applied and is spread over the aspects of people's production and life. Statistics show that the steel loss caused by corrosion is up to 10% of the total yield worldwide each year, and the economic loss caused by steel corrosion accounts for about 3.5% of the total national production value. Therefore, it is necessary to apply corrosion protection measures to steel products, wherein applying corrosion protection paint is the most efficient, economical and common practice.
The alcohol-soluble inorganic zinc-rich paint takes tetraethoxysilane as a film forming substance, forms an iron-zinc silicate complex coating by cross-linking reaction with zinc powder and surface iron atoms, covers the surface of steel, protects the steel together through electrochemical protection and shielding, and has excellent corrosion resistance. However, because of the high zinc powder content in the coating, the coating has a porous structure, and meanwhile, the coating has hydrophilicity, water and corrosive media dissolved in the water can be easily contacted with the steel substrate, so that the coating cannot be directly used in the corrosion prevention field under the high humidity or water contact environment.
The super-slip coating is a new bionic material. The concept of liquid infusion of porous surfaces was first proposed by the university of harvard Aizenberg subject group 2011, simulating the principle of nepenthes predating insects on smooth surfaces. The porous structure is infused with the liquid with low surface energy, and the air film in the porous solid is replaced by a liquid film, so that a more stable solid/liquid composite film layer is formed. Because of the low surface energy of the liquid, the environmental liquid has a large contact angle and a small sliding angle on the surface, and is difficult to adhere to or invade the surface, so the surface is also called a super-sliding surface. The liquid film on the ultra-smooth surface can effectively prevent corrosive medium from invading the coating, so that the coating has high-efficiency anticorrosion effect.
The inorganic zinc-rich coating has a porous structure, and if the inorganic zinc-rich coating can be combined with the ultra-smooth coating technology, the coating can effectively prevent the invasion of liquid corrosive medium, and the anti-corrosion effect of the coating under the environment of high humidity and water contact is improved.
Disclosure of Invention
Based on the problems existing in the prior art, the invention provides an ultra-smooth inorganic zinc-rich coating, and aims to solve the problem that the inorganic zinc-rich coating has poor anti-corrosion effect under the conditions of high humidity and water contact by introducing an ultra-smooth coating technology, so that the anti-corrosion performance of the inorganic zinc-rich coating is further improved.
The invention aims at realizing the following technical scheme:
an ultra-smooth inorganic zinc-rich coating is characterized in that: the super-smooth inorganic zinc-rich coating comprises an inorganic zinc-rich coating and a super-smooth coating; the inorganic zinc-rich coating is prepared from nano modified inorganic zinc-rich coating, and the ultra-smooth coating is formed by pouring low surface energy lubricating oil on the surface of the inorganic zinc-rich coating.
Further, the nano modified inorganic zinc-rich paint is obtained by mixing and uniformly stirring a component A and a component B containing hydrophobic nano particles.
Further: the component A comprises the following raw materials in percentage by mass: 10-30% of tetraethoxysilane, 5-10% of small molecular hydrophobe, 0.5-2% of hydrophobic nano particles, 5-20% of filler and 48-76.5% of solvent. And the component B is zinc powder. The mass ratio of the component A to the component B is 1:2-4.
Preferably, the low surface energy lubricating oil is a perfluoropolyether.
Preferably, the small molecular hydrophobic agent in the component A is one or more of perfluorooctyl triethoxysilane, tridecafluorooctyl trimethoxysilane, heptadecafluorodecyl triethoxysilane and heptadecafluorodecyl trimethoxysilane.
Preferably, the hydrophobic nano particles in the component A are hydrophobically modified fumed silica, and the particle size distribution is 10-500 nanometers.
Preferably, the filler in the component A is one or more of zinc oxide, titanium dioxide, mica powder, talcum powder and ferrotitanium powder.
Preferably, the solvent in the component A is one or two of absolute ethyl alcohol and isopropanol.
Preferably, the zinc powder in the component B is 500 mesh zinc powder.
Preferably, the inorganic zinc-rich coating is prepared by stirring and mixing the nano modified inorganic zinc-rich coating component A and the nano modified inorganic zinc-rich coating component B and then brushing, roller coating or spraying.
The beneficial effects of the invention are mainly as follows:
the super-smooth inorganic zinc-rich coating solves the problem that the inorganic zinc-rich coating has poor anti-corrosion effect under the conditions of high humidity and water contact by introducing the super-smooth coating technology, and further improves the anti-corrosion performance of the inorganic zinc-rich coating, and the specific mechanism is as follows: the lubricating oil with low surface energy can be stably stored in micropores of the inorganic zinc-rich coating through nano modification; the existence of the low-surface-energy lubricating oil can effectively prevent the corrosive medium from penetrating the coating, especially under the high-humidity or water-contact environment, so that the corrosion resistance of the coating is improved; the presence of the low surface energy lubricating oil reduces the adhesion of contaminants to the surface of the coating, providing the coating with self-cleaning capabilities. The preparation process of the ultra-smooth inorganic zinc-rich coating is simple and is suitable for large-area construction.
Detailed Description
The following examples of the present invention are described in detail, and are given by taking the technical scheme of the present invention as a premise, and the detailed implementation and specific operation procedures are given, but the protection scope of the present invention is not limited to the following examples.
Example 1
Preparing a nano modified inorganic zinc-rich coating component A: 0.5g of hydrophobic fumed silica (particle size 100 nanometers), 13g of tetraethoxysilane, 5g of perfluorooctyl triethoxysilane, 5g of zinc oxide and 4g of mica powder are added into 50g of absolute ethyl alcohol, and the mixture is mechanically stirred for 30 minutes, so that the nano modified inorganic zinc-rich coating component A is obtained.
Preparing nano modified inorganic zinc-rich paint: 15g of component A is taken, 30g of 500-mesh zinc powder is added into the component A under stirring, and stirring is continued for 15 minutes, so that the usable nano modified inorganic zinc-rich paint is obtained.
Preparing an inorganic zinc-rich coating: the nano modified inorganic zinc-rich paint prepared above was sprayed 2 times on a clean steel plate through an air gun with a pressure of 40psi at a distance of 20cm and a speed of 8cm/s, and then the steel plate was cured at room temperature to obtain an inorganic zinc-rich coating.
Preparing an ultra-smooth inorganic zinc-rich coating: brushing the surface of the inorganic zinc-rich coating obtained in the previous step with perfluoropolyether, and standing for 2 hours to enable the perfluoropolyether oil to fully enter micropores of the inorganic zinc-rich coating, thereby obtaining the ultra-smooth inorganic zinc-rich coating.
The super-smooth inorganic zinc-rich coating is subjected to neutral salt spray resistance test according to GB/T1771-2007, and the coating has no problems of foaming, cracking, peeling, rusting and the like after 2000 hours of test. Contact and sliding angles were measured according to ISO19403-2-2017 and ISO19403-7-2017 and were 133 ° and 4 °, respectively.
Example 2
Preparing a nano modified inorganic zinc-rich coating component A: 1.0g of hydrophobic fumed silica (particle size of 30 nanometers), 20g of tetraethoxysilane, 8g of heptadecafluorodecyl triethoxysilane and 7g of titanium dioxide are added into 60g of isopropanol, and the mixture is mechanically stirred for 30 minutes, so that the nano modified inorganic zinc-rich coating component A is obtained.
Preparing nano modified inorganic zinc-rich paint: 10g of component A is taken, 30g of 500-mesh zinc powder is added into the component A under stirring, and stirring is continued for 15 minutes, so that the usable nano modified inorganic zinc-rich paint is obtained.
Preparing an inorganic zinc-rich coating: the nano modified inorganic zinc-rich coating prepared in the above way is brushed on a clean steel plate for 2 times, and then the steel plate is solidified at room temperature to obtain the inorganic zinc-rich coating.
Preparing an ultra-smooth inorganic zinc-rich coating: brushing the surface of the inorganic zinc-rich coating obtained in the previous step with perfluoropolyether, and standing for 2 hours to enable the perfluoropolyether oil to fully enter micropores of the inorganic zinc-rich coating, thereby obtaining the ultra-smooth inorganic zinc-rich coating.
The above inorganic zinc-rich coating and the ultra-smooth inorganic zinc-rich coating were subjected to neutral salt spray resistance test according to GB/T1771-2007: after 2000 hours of testing, the inorganic zinc-rich coating has the problem of rust, and the ultra-smooth inorganic zinc-rich coating has no problems of foaming, cracking, peeling, rust and the like. Contact angle and sliding angle tests were performed according to ISO19403-2-2017 and ISO 19403-7-2017: the contact angle and the sliding angle of the ultra-smooth inorganic zinc-rich coating are 138 degrees and 3 degrees respectively; the inorganic zinc-rich coating layer shows hydrophilicity, and water drops directly penetrate into the coating layer, so that the contact angle and the sliding angle cannot be measured.
Example 3
Preparing a nano modified inorganic zinc-rich paint component A1: 1.0g of hydrophobic fumed silica (particle size 500 nanometers), 25g of tetraethoxysilane, 6g of heptadecafluorodecyl trimethoxysilane, 2g of tridecafluorooctyl trimethoxysilane, 3g of talcum powder and 3g of ferrotitanium powder are added into a mixed solution of 30g of isopropyl alcohol and 30g of absolute ethyl alcohol, and the mixture is mechanically stirred for 30 minutes, so that the nano modified inorganic zinc-rich paint component A1 is obtained.
Preparing a nano modified inorganic zinc-rich paint component A2: 25g of tetraethoxysilane, 3g of talcum powder and 3g of ferrotitanium powder are added into a mixed solution of 30g of isopropyl alcohol and 30g of absolute ethyl alcohol, and the mixture is mechanically stirred for 30 minutes, so that the nano modified inorganic zinc-rich paint component A2 is obtained.
Preparing nano modified inorganic zinc-rich paint: 10g of component A1 is taken, 40g of 500-mesh zinc powder is added into the component A1 under stirring, and stirring is continued for 15 minutes, so that the nano modified inorganic zinc-rich paint N1 which can be used is obtained.
Preparing an inorganic zinc-rich coating: 10g of component A2 was taken, 40g of 500 mesh zinc powder was added to the stirred component A2, and stirring was continued for 15 minutes to obtain a usable inorganic zinc-rich paint N2.
Preparing an inorganic zinc-rich coating: the nano modified inorganic zinc-rich paint N1 and the inorganic zinc-rich paint N2 prepared above are respectively rolled on a clean steel plate by 2 times of roller coating, and then the steel plate is solidified at room temperature to obtain inorganic zinc-rich coatings C1 and C2.
Preparing an ultra-smooth inorganic zinc-rich coating: brushing the perfluoropolyether on the surfaces of the inorganic zinc-rich coatings C1 and C2 obtained in the previous step, and standing for 2 hours to enable the perfluoropolyether oil to fully enter micropores of the inorganic zinc-rich coatings, so as to obtain ultra-smooth inorganic zinc-rich coatings S1 and S2.
The super-smooth inorganic zinc-rich coating S1 and the super-smooth inorganic zinc-rich coating S2 are subjected to neutral salt spray resistance test according to GB/T1771-2007, and the super-smooth inorganic zinc-rich coating S1 after 2000 hours of test has no problems of bubbling, cracking, peeling, rusting and the like, and the super-smooth inorganic zinc-rich coating S2 has rusting problems. Contact angle and slip angle tests were performed according to ISO19403-2-2017 and ISO19403-7-2017, with the super-slip inorganic zinc-rich coating S1 contact angle and slip angle being 126 ° and 6 °, respectively, and the super-slip inorganic zinc-rich coating S2 contact angle and slip angle being 132 ° and 8 °, respectively.
The above description is illustrative of the invention and is not intended to be limiting, but is to be construed as being included within the spirit and scope of the invention.
Claims (10)
1. An ultra-smooth inorganic zinc-rich coating, which is characterized in that: the super-smooth inorganic zinc-rich coating comprises an inorganic zinc-rich coating and a super-smooth coating; the inorganic zinc-rich coating is prepared from nano modified inorganic zinc-rich coating, and the ultra-smooth coating is formed by pouring low surface energy lubricating oil on the surface of the inorganic zinc-rich coating.
2. The ultra-smooth inorganic zinc-rich coating according to claim 1, wherein: the nano modified inorganic zinc-rich paint is prepared by mixing and uniformly stirring a component A and a component B containing hydrophobic nano particles.
3. The ultra-smooth inorganic zinc-rich coating according to claim 2, wherein: the component A comprises the following raw materials in percentage by mass: 10-30% of tetraethoxysilane, 5-10% of small molecular hydrophobe, 0.5-2% of hydrophobic nano particles, 5-20% of filler and 48-76.5% of solvent; the component B is zinc powder; the mass ratio of the component A to the component B is 1:2-4.
4. The ultra-smooth inorganic zinc-rich coating according to claim 1, wherein: the low surface energy lubricating oil is perfluoropolyether.
5. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the small molecular hydrophobic agent is one or more of perfluorooctyl triethoxysilane, tridecafluorooctyl trimethoxysilane, heptadecafluorodecyl triethoxysilane and heptadecafluorodecyl trimethoxysilane.
6. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the hydrophobic nano particles are hydrophobic fumed silica, and the particle size distribution is 10-500 nanometers.
7. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the filler is one or more of zinc oxide, titanium dioxide, mica powder, talcum powder and ferrotitanium powder.
8. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the solvent is one or two of absolute ethyl alcohol and isopropanol.
9. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the zinc powder is 500-mesh zinc powder.
10. The ultra-smooth inorganic zinc-rich coating according to claim 3, wherein: the preparation method of the inorganic zinc-rich coating is brushing, roller coating or spraying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310352260.4A CN116376332A (en) | 2023-04-04 | 2023-04-04 | Super-smooth inorganic zinc-rich coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310352260.4A CN116376332A (en) | 2023-04-04 | 2023-04-04 | Super-smooth inorganic zinc-rich coating |
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| Publication Number | Publication Date |
|---|---|
| CN116376332A true CN116376332A (en) | 2023-07-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310352260.4A Pending CN116376332A (en) | 2023-04-04 | 2023-04-04 | Super-smooth inorganic zinc-rich coating |
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| CN (1) | CN116376332A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN1498252A (en) * | 2001-03-21 | 2004-05-19 | ŵ�����˹ɷ�����˾ | Anti-fouling compositions with fluorinated alkyl-or alkoxy-containing polymer or oligomer |
| US20170058130A1 (en) * | 2015-08-28 | 2017-03-02 | Battelle Memorial Institute | Paintable hydrophobic and lubricant-infused surface coatings and processes for making and using same |
| WO2018008728A1 (en) * | 2016-07-06 | 2018-01-11 | 関西ペイント株式会社 | Inorganic zinc-rich paint |
| US20190136073A1 (en) * | 2017-11-08 | 2019-05-09 | King Fahd University Of Petroleum And Minerals | Substrate with a superhydrophobic coating and a method of fabricating thereof |
-
2023
- 2023-04-04 CN CN202310352260.4A patent/CN116376332A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN1498252A (en) * | 2001-03-21 | 2004-05-19 | ŵ�����˹ɷ�����˾ | Anti-fouling compositions with fluorinated alkyl-or alkoxy-containing polymer or oligomer |
| US20170058130A1 (en) * | 2015-08-28 | 2017-03-02 | Battelle Memorial Institute | Paintable hydrophobic and lubricant-infused surface coatings and processes for making and using same |
| WO2018008728A1 (en) * | 2016-07-06 | 2018-01-11 | 関西ペイント株式会社 | Inorganic zinc-rich paint |
| US20190136073A1 (en) * | 2017-11-08 | 2019-05-09 | King Fahd University Of Petroleum And Minerals | Substrate with a superhydrophobic coating and a method of fabricating thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郑翔翔等: "醇溶性无机富锌底漆的研制", 《现代涂料与涂装》, vol. 23, no. 11, pages 8 - 10 * |
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