CN116332560A - Anti-cracking waterproof composite additive for concrete and preparation method and application thereof - Google Patents

Anti-cracking waterproof composite additive for concrete and preparation method and application thereof Download PDF

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Publication number
CN116332560A
CN116332560A CN202310254010.7A CN202310254010A CN116332560A CN 116332560 A CN116332560 A CN 116332560A CN 202310254010 A CN202310254010 A CN 202310254010A CN 116332560 A CN116332560 A CN 116332560A
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China
Prior art keywords
parts
concrete
composite additive
waterproof composite
cracking
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Pending
Application number
CN202310254010.7A
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Chinese (zh)
Inventor
吴莉萍
邹丹
田正宏
沈雷
宋杰
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Jiangsu Tongyu New Material Technology Co ltd
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Jiangsu Tongyu New Material Technology Co ltd
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Priority to CN202310254010.7A priority Critical patent/CN116332560A/en
Publication of CN116332560A publication Critical patent/CN116332560A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/65Water proofers or repellants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an anti-cracking waterproof composite additive for concrete, and a preparation method and application thereof, wherein the anti-cracking waterproof composite additive for concrete comprises the following components in parts by weight: 30-40 parts of mica powder, 10-20 parts of attapulgite powder, 3-5 parts of coupling agent, 10-20 parts of polyamide fiber, 5-10 parts of 4-isopropylbenzene sodium sulfonate, 10-15 parts of sodium dodecyl benzene sulfonate, 2-4 parts of ammonium sulfate, 1-2 parts of carboxymethyl cellulose ether and 12-15 parts of calcium sulfoaluminate; the anti-cracking waterproof composite additive for concrete is compounded by the raw materials, can fill gaps in a concrete matrix when being added into the concrete, simultaneously performs various complex reactions, reduces anisotropism among the raw materials, further improves the anti-cracking and waterproof performances of the prepared concrete, and remarkably improves the application field of the concrete.

Description

Anti-cracking waterproof composite additive for concrete and preparation method and application thereof
Technical Field
The invention relates to the technical field of concrete, in particular to an anti-cracking waterproof composite additive for concrete, and a preparation method and application thereof.
Background
With the progress of society and the improvement of living standard of people, the requirements of people on the quality and the functions of modern building materials are higher and higher, and especially the cracking resistance, the waterproof performance and the durability of concrete are higher and higher. Cracking of concrete is mainly caused by the following reasons: 1. cracking and water seepage phenomena caused by deformation due to temperature shrinkage and drying shrinkage in the hydration hardening process of the concrete can seriously influence the durability of the concrete; 2. fine air holes are uniformly distributed in the formed concrete, and the concrete can have water seepage phenomenon due to hydrostatic pressure and capillary action, so that water seepage can be greatly influenced on the concrete and mortar and even building structures. Therefore, the waterproof effect has an important influence on engineering quality, and solving the problems of cracking and water seepage is one of important directions for people to study concrete.
At present, the performance of concrete is improved mainly by adding an anti-cracking waterproof additive, and the waterproof agent can be divided into an inorganic waterproof agent, an organic waterproof agent and an inorganic-organic composite concrete waterproof agent according to chemical components. The inorganic waterproofing agent mainly reduces the pores in concrete by inorganic compounds (such as chloride salts of iron or aluminum) and improves the compactness and the impermeability. The organic waterproof agent mainly forms a hydrophobic surface on the surface of concrete through organic compounds (such as stearic acid) and improves the impermeability. The inorganic-organic composite concrete waterproof agent is an inorganic-organic composite system and has the functions of waterproof, plasticizing and the like.
The existing anti-cracking waterproof additive is single in general effect and poor in waterproof and anti-cracking performance, so that an additive capable of better improving the anti-cracking and waterproof performance of concrete is needed.
Disclosure of Invention
The invention aims to provide an anti-cracking waterproof composite additive for concrete, a preparation method and application thereof.
In order to achieve the above object of the present invention, the following technical solutions are specifically adopted:
the invention provides an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
30-40 parts of mica powder, 10-20 parts of attapulgite powder, 3-5 parts of coupling agent, 10-20 parts of polyamide fiber, 5-10 parts of 4-isopropylbenzene sodium sulfonate, 10-15 parts of sodium dodecyl benzene sulfonate, 2-4 parts of ammonium sulfate, 1-2 parts of carboxymethyl cellulose ether and 12-15 parts of calcium sulfoaluminate.
Preferably, the anti-cracking waterproof composite additive for concrete consists of the following components in parts by weight:
35 parts of mica powder, 15 parts of attapulgite powder, 4 parts of a coupling agent, 15 parts of polyamide fibers, 8 parts of sodium 4-isopropylbenzene sulfonate, 12 parts of sodium dodecyl benzene sulfonate, 3 parts of ammonium sulfate, 2 parts of carboxymethyl cellulose ether and 13 parts of calcium sulfoaluminate.
Preferably, the mesh size of the attapulgite powder is 500-2000 mesh.
Preferably, the coupling agent is hexadecyltrimethoxysilane.
Preferably, the polyamide fiber has a diameter of 10 to 20 μm and a length of 1 to 3cm.
The second aspect of the invention provides a preparation method of the anti-cracking waterproof composite additive for concrete, which comprises the following steps:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring uniformly to obtain a mixture;
(c) Heating the mixture to 60-80 ℃ and stirring at high speed to obtain the anti-cracking waterproof composite additive for the concrete.
Preferably, in the step (b), the stirring speed is 100-200 r/min, and the stirring time is 5-10 min;
in the step (c), the high-speed stirring speed is 500-800 r/min, and the stirring time is 5-10 min.
The invention provides an application of the anti-cracking waterproof composite additive for concrete in improving anti-cracking and/or waterproof performance of the concrete.
The fourth aspect of the invention provides anti-cracking waterproof concrete, which comprises the anti-cracking waterproof composite additive for the concrete.
Preferably, the amount of the anti-cracking waterproof composite additive for concrete in each cubic meter of the anti-cracking waterproof concrete is 0.5-1 kg.
Compared with the prior art, the invention has the beneficial effects that at least:
the anti-cracking waterproof composite additive for concrete is compounded by the raw materials, can fill gaps in a concrete matrix when being added into the concrete, simultaneously performs various complex reactions, reduces anisotropism among the raw materials, further improves the anti-cracking and waterproof performances of the prepared concrete, and remarkably improves the application field of the concrete.
Detailed Description
Embodiments of the technical scheme of the present invention will be described in detail below with reference to the embodiments. The following examples are only for more clearly illustrating the technical aspects of the present invention, and thus are merely examples, and are not intended to limit the scope of the present invention.
It is noted that unless otherwise indicated, technical or scientific terms used herein should be given the ordinary meaning as understood by one of ordinary skill in the art to which this invention pertains.
Example 1
The embodiment is an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
30 parts of mica powder, 20 parts of attapulgite powder, 3 parts of a coupling agent, 20 parts of polyamide fibers, 5 parts of 4-isopropylbenzene sodium sulfonate, 10 parts of sodium dodecyl benzene sulfonate, 4 parts of ammonium sulfate, 1 part of carboxymethyl cellulose ether and 12 parts of calcium sulfoaluminate, wherein the mesh granularity of the attapulgite powder is 2000 meshes;
the coupling agent is hexadecyl trimethoxy silane;
the diameter of the polyamide fiber is 10-20 mu m, and the length is 1-3 cm.
The anti-cracking waterproof composite additive for the concrete is prepared by the following method:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring at 100r/min for 10min to obtain a mixture;
(c) Heating the mixture to 80 ℃, and stirring at a high speed of 800r/min for 5min to obtain the anti-cracking waterproof composite additive for the concrete.
Example 2
The embodiment is an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
40 parts of mica powder, 10 parts of attapulgite powder, 5 parts of a coupling agent, 10 parts of polyamide fibers, 10 parts of sodium 4-isopropylbenzene sulfonate, 15 parts of sodium dodecyl benzene sulfonate, 2 parts of ammonium sulfate, 2 parts of carboxymethyl cellulose ether and 15 parts of calcium sulfoaluminate, wherein the mesh granularity of the attapulgite powder is 2000 meshes;
the coupling agent is hexadecyl trimethoxy silane;
the diameter of the polyamide fiber is 10-20 mu m, and the length is 1-3 cm.
The anti-cracking waterproof composite additive for the concrete is prepared by the following method:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring for 5min at 200r/min to obtain a mixture;
(c) Heating the mixture to 60 ℃, and stirring at a high speed of 500r/min for 10min to obtain the anti-cracking waterproof composite additive for the concrete.
Example 3
The embodiment is an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
35 parts of mica powder, 15 parts of attapulgite powder, 4 parts of a coupling agent, 15 parts of polyamide fibers, 8 parts of 4-sodium cumene sulfonate, 12 parts of sodium dodecyl benzene sulfonate, 3 parts of ammonium sulfate, 2 parts of carboxymethyl cellulose ether and 13 parts of calcium sulfoaluminate, wherein the mesh granularity of the attapulgite powder is 2000 meshes;
the coupling agent is hexadecyl trimethoxy silane;
the diameter of the polyamide fiber is 10-20 mu m, and the length is 1-3 cm.
The anti-cracking waterproof composite additive for the concrete is prepared by the following method:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring at 150r/min for 8min to obtain a mixture;
(c) Heating the mixture to 70 ℃, and stirring at a high speed of 600r/min for 8min to obtain the anti-cracking waterproof composite additive for the concrete.
Comparative example 1
The comparative example is an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
35 parts of mica powder, 15 parts of attapulgite powder, 4 parts of a coupling agent, 15 parts of polyamide fibers, 10 parts of sodium 4-isopropylbenzene sulfonate, 12 parts of sodium dodecyl benzene sulfonate, 3 parts of ammonium sulfate and 13 parts of calcium sulfoaluminate, wherein the mesh granularity of the attapulgite powder is 2000 meshes;
the coupling agent is hexadecyl trimethoxy silane;
the diameter of the polyamide fiber is 10-20 mu m, and the length is 1-3 cm.
The anti-cracking waterproof composite additive for the concrete is prepared by the following method:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring at 150r/min for 8min to obtain a mixture;
(c) Heating the mixture to 70 ℃, and stirring at a high speed of 600r/min for 8min to obtain the anti-cracking waterproof composite additive for the concrete.
Comparative example 2
The comparative example is an anti-cracking waterproof composite additive for concrete, which comprises the following components in parts by weight:
35 parts of mica powder, 15 parts of attapulgite powder, 4 parts of a coupling agent, 15 parts of polyamide fibers, 12 parts of sodium dodecyl benzene sulfonate, 3 parts of ammonium sulfate, 10 parts of carboxymethyl cellulose ether and 13 parts of calcium sulfoaluminate, wherein the mesh granularity of the attapulgite powder is 2000 meshes;
the coupling agent is hexadecyl trimethoxy silane;
the diameter of the polyamide fiber is 10-20 mu m, and the length is 1-3 cm.
The anti-cracking waterproof composite additive for the concrete is prepared by the following method:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring at 150r/min for 8min to obtain a mixture;
(c) Heating the mixture to 70 ℃, and stirring at a high speed of 600r/min for 8min to obtain the anti-cracking waterproof composite additive for the concrete.
Experimental example
Respectively obtaining and comparing the anti-cracking waterproof composite additive for the concrete prepared in the example 3 and the comparative examples 1-2;
then adding the anti-cracking waterproof composite additive for concrete into concrete per cubic meter
0.8kg was added, and then the obtained concrete sample was tested, and the test results are shown in table 1:
TABLE 1
Group of Example 3 Comparative example 1 Comparative example 2
Height of water penetration/cm 3.8 6.4 7.3
Impervious grade/MPa 23 16 18
Crack resistance rating Grade 1 or more Not less than two-stage Not less than two-stage
Crack reduction coefficient/% 88 63 69
Waterproof protection period/year 150 82 67
As can be seen from table 1:
the anti-cracking waterproof composite additive for concrete prepared by the embodiment 3 and the comparative examples 1-2 can improve the waterproof and anti-cracking performances of concrete, and compared with the comparative examples, the anti-cracking waterproof composite additive for concrete prepared by the embodiment of the invention can obviously improve the waterproof and anti-cracking performances of concrete.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention, and are intended to be included within the scope of the appended claims and description.

Claims (10)

1. The anti-cracking waterproof composite additive for the concrete is characterized by comprising the following components in parts by weight:
30-40 parts of mica powder, 10-20 parts of attapulgite powder, 3-5 parts of coupling agent, 10-20 parts of polyamide fiber, 5-10 parts of 4-isopropylbenzene sodium sulfonate, 10-15 parts of sodium dodecyl benzene sulfonate, 2-4 parts of ammonium sulfate, 1-2 parts of carboxymethyl cellulose ether and 12-15 parts of calcium sulfoaluminate.
2. The anti-cracking waterproof composite additive for concrete according to claim 1, which is characterized by comprising the following components in parts by weight:
35 parts of mica powder, 15 parts of attapulgite powder, 4 parts of a coupling agent, 15 parts of polyamide fibers, 8 parts of sodium 4-isopropylbenzene sulfonate, 12 parts of sodium dodecyl benzene sulfonate, 3 parts of ammonium sulfate, 2 parts of carboxymethyl cellulose ether and 13 parts of calcium sulfoaluminate.
3. The crack-resistant waterproof composite additive for concrete according to claim 1, wherein the mesh size of the attapulgite powder is 500-2000 mesh.
4. The crack-resistant waterproof composite additive for concrete according to claim 1, wherein the coupling agent is hexadecyltrimethoxysilane.
5. The crack-resistant waterproof composite additive for concrete according to claim 1, wherein the polyamide fiber has a diameter of 10 to 20 μm and a length of 1 to 3cm.
6. The method for preparing the anti-cracking waterproof composite additive for concrete according to any one of claims 1 to 5, which is characterized by comprising the following steps:
(a) Weighing the raw materials according to parts by weight;
(b) Mixing the raw materials and stirring uniformly to obtain a mixture;
(c) Heating the mixture to 60-80 ℃ and stirring at high speed to obtain the anti-cracking waterproof composite additive for the concrete.
7. The method according to claim 6, wherein in the step (b), the stirring speed is 100 to 200r/min and the stirring time is 5 to 10min;
in the step (c), the high-speed stirring speed is 500-800 r/min, and the stirring time is 5-10 min.
8. Use of the crack-resistant waterproof composite additive for concrete according to any one of claims 1 to 5 for improving crack resistance and/or waterproof performance of concrete.
9. An anti-cracking waterproof concrete which is characterized by comprising the anti-cracking waterproof composite additive for concrete according to any one of claims 1 to 5.
10. The anti-crack waterproof concrete according to claim 9, wherein the amount of the anti-crack waterproof composite additive for concrete in each cubic meter of the anti-crack waterproof concrete is 0.5-1 kg.
CN202310254010.7A 2023-03-16 2023-03-16 Anti-cracking waterproof composite additive for concrete and preparation method and application thereof Pending CN116332560A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170008810A1 (en) * 2015-07-06 2017-01-12 Premier Magnesia, Llc Methods for producing concrete having improved crack resistance
CN109485299A (en) * 2018-12-13 2019-03-19 武汉京宁好帮手科技有限公司 A kind of multiple-effect concrete structure self-waterproofing additive with self-reparing capability
CN111268933A (en) * 2018-12-04 2020-06-12 扬州携砼新材料科技有限公司 Novel concrete anti-cracking waterproof durable additive and preparation method thereof
CN111268938A (en) * 2018-12-05 2020-06-12 扬州携砼新材料科技有限公司 Concrete anti-cracking waterproof powder additive and preparation method thereof
CN112341040A (en) * 2020-11-23 2021-02-09 北京富瑞勒斯科技开发有限公司 Concrete anti-cracking waterproof agent and preparation method thereof
KR102423871B1 (en) * 2021-12-16 2022-07-25 더본드 주식회사 Crack resisting hybrid fiber-reinforced cementitious mortar composition having excellent repairing method using the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170008810A1 (en) * 2015-07-06 2017-01-12 Premier Magnesia, Llc Methods for producing concrete having improved crack resistance
CN111268933A (en) * 2018-12-04 2020-06-12 扬州携砼新材料科技有限公司 Novel concrete anti-cracking waterproof durable additive and preparation method thereof
CN111268938A (en) * 2018-12-05 2020-06-12 扬州携砼新材料科技有限公司 Concrete anti-cracking waterproof powder additive and preparation method thereof
CN109485299A (en) * 2018-12-13 2019-03-19 武汉京宁好帮手科技有限公司 A kind of multiple-effect concrete structure self-waterproofing additive with self-reparing capability
CN112341040A (en) * 2020-11-23 2021-02-09 北京富瑞勒斯科技开发有限公司 Concrete anti-cracking waterproof agent and preparation method thereof
KR102423871B1 (en) * 2021-12-16 2022-07-25 더본드 주식회사 Crack resisting hybrid fiber-reinforced cementitious mortar composition having excellent repairing method using the same

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