CN116322618A - Cleansing cosmetic composition comprising surfactant - Google Patents
Cleansing cosmetic composition comprising surfactant Download PDFInfo
- Publication number
- CN116322618A CN116322618A CN202180069201.5A CN202180069201A CN116322618A CN 116322618 A CN116322618 A CN 116322618A CN 202180069201 A CN202180069201 A CN 202180069201A CN 116322618 A CN116322618 A CN 116322618A
- Authority
- CN
- China
- Prior art keywords
- weight
- composition
- composition according
- total weight
- relative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a cosmetic composition comprising, in a cosmetically acceptable medium: an aqueous phase; at least one amphoteric surfactant selected from betaines; at least one anionic surfactant selected from alkyl sulfates; and a glycerol stearate in an amount strictly greater than 2% and strictly less than 6% by weight relative to the total weight of the composition, wherein the amount of alkyl sulfate is greater than the amount of glycerol stearate, which in turn is greater than the amount of betaine.
Description
Technical Field
The present invention relates to cosmetic compositions, in particular cleansing cosmetic compositions for the skin and appendages, preferably body washes or cleansing products for the face, body, hands and/or hair, comprising a combination of specific surfactants and an aqueous phase.
Background
Skin cleansing is very important for skin care. It should provide as high a performance as possible, since fat residues, such as excess sebum or residues of cosmetics used daily, can accumulate in folds of the skin and can clog pores of the skin, leading to acne. One method of properly cleansing the skin is to use a foaming cleansing product.
Currently commercially available lathering cleansing products have either a block form, a gel form or a lathering liquid form. They often contain soaps, which have the advantage of generating a rich and large amount of foam, but can lead to tightening due to their excessive detergency; or they contain synthetic detergent-type lathering surfactants and stabilizers, which are bonded to each other. Furthermore, the use of currently commercially available lathering cleansing products can cause stinging and/or irritation to the eyes or skin.
Users increasingly seek new cleansing cosmetics and/or products for keratinous tissue (preferably skin) that have an attractive visual appearance, particularly a pearl appearance, and therefore a degree of opacity. Such opacity is particularly attractive in the case of sanitary products such as body washes.
Thus, there is a need for cleansing and/or care compositions for keratinous tissue, preferably skin, that are opaque, have good ocular and skin tolerability, have foaming capabilities, are stable, and provide protection and/or moisturization to the skin.
Disclosure of Invention
The object of the present invention is to provide such a composition which does not have the disadvantages of the prior art and which has good in-use properties (foaming capacity, consistency, rinsing speed, skin moisturizing effect after drying), as well as good ocular and skin tolerability, and also has an opaque appearance.
The inventors have demonstrated that compositions comprising an amphoteric surfactant selected from betaines, an anionic surfactant selected from alkyl sulphates and glyceryl stearate lead to cosmetic compositions, in particular body washes, which meet these needs whilst being stable. The composition according to the invention has good quality of use and has an opaque and/or pearly appearance.
A composition having an "opaque and/or pearlescent" appearance refers to a composition that is neither transparent nor clear as determined by the naked eye.
More particularly, the present invention relates to a cosmetic composition comprising, in a cosmetically acceptable medium:
an aqueous phase;
at least one amphoteric surfactant selected from betaines;
at least one anionic surfactant selected from alkyl sulfates; and
glycerol stearate in an amount strictly greater than 2% and strictly less than 6% by weight relative to the total weight of the composition,
wherein the amount of alkyl sulfate is greater than the amount of glyceryl stearate, which in turn is greater than the amount of betaine.
The invention also relates to a method for cleansing keratinous tissue, in particular body skin or facial skin or hair or hands, comprising applying to said keratinous tissue a cosmetic composition as defined above.
The term "keratinous tissue" refers to skin (body, face, surrounding eyes), hair, eyelashes, eyebrows, body hair, nails, lips, and/or mucous membranes.
The term "cosmetically acceptable medium" refers to any medium compatible with the skin and/or its coverings, having a pleasant color, smell and texture, and which does not cause unacceptable discomfort (stinging, tightening, redness) that prevents the consumer from using the composition.
Aqueous phase
The composition according to the invention comprises at least one aqueous phase.
The aqueous phase comprises water.
The water used may be sterile demineralised water and/or vegetation water, such as rose water, cornflower water, chamomile water or basswood water, and/or spring water or natural mineral water, such as: vittel water, water from the Vichy basin, uria water, roche Posay water, bourdoule water, enghien-les-Bains water, saint Gervais-les-Bains water, neris-les-Bains water, allevar-les-Bains water, digne water, maizire water, neyrac-les-Bains water, lons-le-Saunier water, eaux Bonnes, rochefort water, saint Christ water, fumades water, tercis-les-Bains water, and Ave ne water.
The aqueous phase may comprise at least one organic solvent that is soluble or miscible with water.
Suitable water-soluble or water-miscible solvents for use in the present invention include short chain monohydric alcohols, e.g., C1-C4 alcohols, such as ethanol, isopropanol; polyhydric alcohols, such as glycerol, ethylene glycol, 1, 2-propanediol, 1, 3-butanediol, pentanediol, hexanediol, diethylene glycol, dipropylene glycol, 2-ethoxyethanol, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, sorbitol; and mixtures thereof.
Preferably, the aqueous phase of the composition according to the invention comprises at least one organic solvent, preferably at least one polyol, which is soluble or miscible with water.
Preferably, the aqueous phase comprises from 20% to 97% by weight, preferably from 30% to 95% by weight, even more preferably from 40% to 90% by weight of the total weight of the composition.
Preferably, the composition according to the invention comprises at least 30% by weight, preferably at least 40% by weight, preferably from 42% to 90% by weight of water.
Preferably, the composition according to the invention comprises from 0.1% to 15% by weight, preferably from 0.5% to 10% by weight, preferably from 0.7% to 5% by weight, of a water-soluble or water-miscible organic solvent.
Betaine type amphoteric surfactant
The composition according to the invention further comprises at least one amphoteric surfactant chosen from betaines.
The betaine-type zwitterionic or amphoteric surfactant according to the invention is preferably selected from:
alkylbetaines, in particular laurylbetaines, e.g. GEN of CLARIANTAGEN
Products, or cocobetaines, e.g. Dehaton +.of BASF>
30 or Evonik Goldschmidt GmbH TEGO Betaiin AB 1214;
n-alkylamide betaines and derivatives thereof, in particular cocamidopropyl betaines (e.g. LEBON of SANYO)
EMPIGEN of HG or ALBRIGHT ET WILSON->
Or Dehyton PK 45); lauramidopropyl betaine (e.g. REWOTERIC +.>
) Or the N-disodium salt of N-carboxyethoxyethyl N-cocoamidoethylamino acetic acid (INCI name: cocoamphodiacetic acid disodium salt; MIRANOL C2M CONCENTRE->
)；
Sulfobetaines, such as cocamidopropyl hydroxysulfobetaine (e.g., cronataine C-500 of CRODA); and
mixtures thereof.
Preferably, the betaine type amphoteric surfactant is selected from the group consisting of alkyl betaines and N-alkyl amidobetaines, preferably from the group consisting of N-alkyl amidobetaines, more preferably coco amidopropyl betaine, coco betaine, and mixtures thereof.
The content of active substances of the amphoteric surfactant selected from the alkyl betaines is preferably comprised between 1% and 20% by weight, preferably between 1.2% and 10% by weight, preferably between 1.5% and 5% by weight, relative to the total weight of the composition.
Anionic surfactants selected from alkyl sulphates
The composition according to the invention further comprises at least one anionic surfactant chosen from alkyl sulphates.
Among the alkyl sulfate type anionic surfactants, alkyl sulfates and mixtures thereof are preferably used, in particular in the form of alkali metal (Na or K) salts or alkaline earth metal (e.g. Mg) salts, or ammonium, amine or amino alkoxides, and mixtures thereof.
Preferably, the anionic surfactant is selected from ammonium salts.
Advantageously, the anionic surfactant is ammonium lauryl sulfate.
Ammonium lauryl sulfate is an ammonium salt of lauryl sulfate, which is generally of the formula CH 3 (CH 2 ) 10 CH 2 OSO 3 NH 4 。
INCI name is ammonium lauryl sulfate.
Preferred ammonium lauryl sulfates according to the present invention are those sold by ZSCHIMMER & SCHWARZ under the names SULFETAL LA B-RSPO-MB or SULFETAL LA B, by PCC EXOL under the names ROSLFAN A MB or ROSLFAN A, or by INNOSPEC ACTIVE CHEMICALS under the names EMPICOL AL 30/FL3/MB or EMPICOL AL 30/FL 3.
The content of active substances of the alkyl sulphate anionic surfactant is preferably at least equal to 5% by weight, preferably between 5% and 20% by weight, preferably between 6% and 15% by weight, relative to the total weight of the composition.
Glyceryl stearate
The composition according to the invention further comprises glycerol stearate.
The glyceryl stearate may be selected from glyceryl monostearate, glyceryl distearate, glyceryl tristearate, and mixtures thereof.
It is worth mentioning that the glyceryl stearate sold by Cognis under the name CUTINA GMS V, or the Tegin M tubes sold by Goldschmidt, or the mixture of glyceryl monostearate and glyceryl distearate sold by STEARINERIE DUBOIS under the name DUB GMS 50/50.
Preferably, the composition according to the invention comprises a mixture of glyceryl monostearate, glyceryl distearate and glyceryl tristearate (e.g. Tegin M Pellets MB).
According to the invention, the glyceryl stearate is present in an amount strictly greater than 2% by weight and strictly less than 6% by weight, relative to the total weight of the composition.
Preferably, the glycerol stearate is present in an amount of between 2.1% and 5.5% by weight, preferably between 2.5% and 5% by weight, preferably between 2.7% and 4% by weight, relative to the total weight of the composition.
Furthermore, in the composition according to the invention, the amount of alkyl sulphate anionic surfactant is greater than the amount of glyceryl stearate, which in turn is greater than the amount of betaine amphoteric surfactant.
Preferably, the composition according to the invention comprises, with respect to the total weight of the composition:
an alkyl sulfate anionic surfactant in an amount between 5.5% and 20% by weight, preferably between 6% and 15% by weight of active material;
the content of active substance is between 2.1% and 5.5% by weight, preferably between 2.5% and 5% by weight, preferably between 2.7% and 4% by weight of glyceryl stearate, relative to the total weight of the composition; and
the content of active substance is between 1% and 5% by weight, preferably between 1.2% and 4% by weight, preferably between 1.5% and 3.5% by weight, relative to the total weight of the composition, of an amphoteric surfactant selected from alkyl betaines.
Preferably, in the composition according to the invention, the total amount of active substances of the surfactant is between 6% and 30% by weight, preferably between 8% and 25% by weight, preferably between 10% and 20% by weight, relative to the total weight of the composition.
According to one embodiment, the cosmetic composition according to the present invention may comprise a salt, i.e. an electrolyte.
The electrolyte may be selected from sodium chloride or sodium sulfate. The electrolyte is preferably sodium chloride.
Preferably, the content of active substance of the electrolyte is between 0.2% and 5% by weight, preferably between 0.5% and 3% by weight, preferably between 0.7% and 2% by weight, relative to the total weight of the composition.
The composition according to the invention may further comprise conventional cosmetic additives, for example selected from preservatives, fragrances, pH adjusters, oils, ionic or nonionic thickeners, moisturizers, antifoaming agents, active ingredients, fillers, propellants or any other ingredient commonly used in the cosmetic and/or dermatological field.
As oils, mention may be made of vegetable oils, such as olive oil, safflower oil, cumin oil, in particular cumin oil (black grass), sweet almond oil, or essential oils, such as peppermint or peppermint essential oils. These oils may be present in an amount of between 0.0001% and 1% by weight, preferably between 0.001% and 0.5% by weight of active substance.
For ionic or nonionic thickeners, for example, mention may be made of:
polysaccharide biopolymers, such as pectin, locust bean gum, gum arabic, xanthan gum, guar gum and derivatives thereof, such as hydroxypropyl guar gum, in particular the products sold by the company rhodoia under the name Jaguar HP105, scleroglucan, derivatives of chitin and chitosan, carrageenan, which may be mixtures of iota, lambda and kappa carrageenan, gellan gum, alginate, starch or modified cellulose, such as microcrystalline cellulose, carboxymethyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose and hydroxyethyl cellulose, such as the products sold by Aqualon under the name Natrosol 250 HHR;
modified or unmodified carboxyvinyl polymers, such as those sold by Goodrich under the names Carbopol (CTFA name: carbomer) and Pemulen (CTFA name: acrylate/C10-30 alkyl acrylate cross-linked polymer);
polyacrylamide;
polymers and copolymers of 2-acrylamido-2-methylpropanesulfonic Acid (AMPS) may be crosslinked and/or neutralized, such as poly (2-acrylamido-2-methylpropanesulfonic acid) sold by Hoechst under the name "Hostacerin AMPS" (CTFA name: ammonium polyacryl dimethyl taurate);
crosslinked anionic copolymers of acrylamide and AMPS in the form of W/H emulsions, such as those sold by SEPPIC under the names SEPIGEL 305 (CTFA name: polyacrylamide/C13-14 isoparaffin/laureth-7) and SIMULGEL 600 (CTFA name: acrylamide/sodium acryloyldimethyl taurate copolymer/isohexadecane/polysorbate 80);
copolymers of AMPS and vinylpyrrolidone or vinylformamide, such as the ammonium acryloyldimethyl taurate/VP copolymer sold by Clariant under the name Aristoflex AVC; and
mixtures thereof.
It will be apparent to those skilled in the art that the optional supplemental compounds and/or amounts thereof described hereinabove may be carefully selected so that the beneficial properties inherently associated with the compositions of the present invention are not or substantially not impaired by the envisaged addition.
Unless otherwise indicated, the expressions "between … … and … …" and "range from … … to … …" are to be understood to include the endpoints.
Detailed Description
The following examples illustrate the invention but do not limit it in any way. In these examples, the content of the ingredients is given in weight% of the active substance relative to the total weight of the composition.
Examples
Example 1: preparation of a composition according to the invention
The compositions C1 to C3 according to the invention are prepared by mixing the individual components in water.
Specifically, the glyceryl stearate is first heated and then all ingredients are mixed into water.
TABLE 1
Example 2: preparation and evaluation of the compositions according to the invention and of the comparative compositions
1. Glyceryl stearate with varying content
The same composition as composition C2 of the present invention was prepared according to the protocol described in example 1, but containing 2 wt%, 4 wt% or 6 wt% of glyceryl stearate (instead of 3 wt% of composition C2), respectively, relative to the total weight of the composition.
The stability of each composition was evaluated according to the following protocol:
each composition was placed in a kiln at 4 different temperatures: 4 ℃, ambient temperature, 37 ℃ and 45 ℃.
For each temperature, sensory checks of appearance, color and smell were performed.
For each temperature, physical and chemical tests of pH and viscosity were performed.
The results are shown below:
a comparative composition containing 2 wt% glyceryl stearate: the resulting stability is not satisfactory because the resulting gel is cloudy and not opaque.
Composition C2 of the invention (3% by weight of glyceryl stearate): the resulting stability is satisfactory because the resulting gel is opaque.
The composition of the invention contains 4% by weight of glyceryl stearate: the resulting stability is satisfactory because the resulting gel is opaque.
Comparative composition containing 6% by weight of glyceryl stearate: the resulting stability is not satisfactory because a phase shift of the gel is observed.
These results indicate that only the compositions of the present invention comprising strictly greater than 2% by weight and strictly less than 6% by weight of glyceryl stearate, relative to the total weight of the composition, are stable and opaque.
2. Ingredients containing non-glyceryl stearate
The same composition as composition C2 of the present invention was prepared according to the protocol described in example 1, but including the following ingredients instead of glyceryl stearate.
The stability of each composition was evaluated according to the protocol described above.
The results are shown below:
comparative composition containing 1% by weight of sunflower oil (the composition being emulsified with this oil): the composition was unstable and creaming was observed.
Comparative compositions containing 5 wt.% cetyl alcohol, or 10 wt.% cetyl alcohol, or 5 wt.% stearyl alcohol, or 10 wt.% stearyl alcohol (total of 4 compositions): it is difficult to repeat the preparation method and foam failure is formed.
Containing 0.5 wt% of kaolin
Opaque, imarys) is included in the composition: the composition is unstable; this filler was observed to have specks and precipitates.
To this comparative composition comprising kaolin, a gelling agent (0.2% or 0.5% xanthan, or 0.2% or 0.5% carrageenan; total of 4 compositions) was added to form a network and keep the filler in suspension: these compositions are unstable.
Comprises 1 wt% or 1.7 wt% of microcrystalline cellulose
PC611 microcrystalline cellulose): these compositions are unstable; creaming was observed.
To these comparative compositions comprising microcrystalline cellulose, a gelling agent (0.2% or 0.5% xanthan, or 0.2% or 0.5% carrageenan; total 4 compositions) was added: these compositions are unstable.
Comparative composition containing 0.6 wt% ethylcellulose: the composition is unstable.
Comparative composition containing 3% by weight of glyceryl caprylate: the composition is unstable.
These results indicate that only the composition according to the invention comprising glyceryl stearate is stable.
Claims (14)
1. A cosmetic composition comprising, in a cosmetically acceptable medium:
an aqueous phase;
at least one amphoteric surfactant selected from betaines;
at least one anionic surfactant selected from alkyl sulfates; and
glycerol stearate in an amount strictly greater than 2% and strictly less than 6% by weight relative to the total weight of the composition,
wherein the amount of alkyl sulfate is greater than the amount of glyceryl stearate, which in turn is greater than the amount of betaine.
2. The composition according to claim 1, characterized in that the aqueous phase comprises water and at least one organic solvent which is soluble or miscible with water, preferably at least one polyol.
3. Composition according to claim 1 or 2, characterized in that the amphoteric surfactant is selected from alkyl betaines and N-alkylamide betaines, preferably from N-alkylamide betaines.
4. A composition according to any one of claims 1 to 3, wherein the amphoteric surfactant is selected from cocamidopropyl betaine, coco betaine and mixtures thereof.
5. Composition according to any one of claims 1 to 4, characterized in that the amphoteric surfactant is present in a content of active substance of between 1 and 20% by weight, preferably between 1.2 and 10% by weight, preferably between 1.5 and 5% by weight, relative to the total weight of the composition.
6. Composition according to any one of claims 1 to 5, characterized in that the anionic surfactant is selected from the group consisting of alkali metal or alkaline earth metal salts, ammonium salts, amine salts, amino alkoxides and mixtures thereof.
7. The composition according to any one of claims 1 to 6, wherein the anionic surfactant is selected from ammonium salts.
8. The composition according to any one of claims 1 to 7, wherein the anionic surfactant is ammonium lauryl sulfate.
9. Composition according to any one of claims 1 to 8, characterized in that the anionic surfactant is present in a content of at least 5% by weight of active substance, preferably between 5% and 20% by weight, preferably between 6% and 15% by weight, relative to the total weight of the composition.
10. Composition according to any one of claims 1 to 9, characterized in that the glycerol stearate is present in an amount comprised between 2.1% and 5.5% by weight, preferably between 2.5% and 5% by weight, relative to the total weight of the composition.
11. The composition according to any one of claims 1 to 10, characterized in that said glyceryl stearate is present in an amount comprised between 2.7% and 4% by weight relative to the total weight of the composition.
12. The composition according to any one of claims 1 to 11, characterized in that it comprises, with respect to the total weight of the composition:
an alkyl sulfate anionic surfactant having an active content of between 5.5% and 20% by weight;
the content of active substance is between 2.1% and 5.5% by weight, preferably between 2.5% and 5% by weight of glyceryl stearate, relative to the total weight of the composition; and
the content of active substance is between 1% and 5% by weight, preferably between 1.2% and 4% by weight, relative to the total weight of the composition, of an amphoteric surfactant selected from alkyl betaines.
13. The composition according to any one of claims 1 to 12, characterized in that it comprises, with respect to the total weight of the composition:
an alkyl sulfate anionic surfactant having an active content of between 6 wt% and 15 wt%;
a content of active substance between 2.7% and 4% by weight of glyceryl stearate, relative to the total weight of the composition; and
the content of active substance is between 1.5% and 3.5% by weight, relative to the total weight of the composition, of an amphoteric surfactant selected from alkyl betaines.
14. A method for cleansing keratinized tissue comprising applying the cosmetic composition of any one of claims 1-13 to the keratinized tissue.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FRFR2010641 | 2020-10-16 | ||
| FR2010641A FR3115197B1 (en) | 2020-10-16 | 2020-10-16 | Cosmetic cleansing composition comprising surfactants |
| PCT/EP2021/078673 WO2022079276A1 (en) | 2020-10-16 | 2021-10-15 | Cleansing cosmetic composition comprising surfactants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116322618A true CN116322618A (en) | 2023-06-23 |
Family
ID=73793467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202180069201.5A Pending CN116322618A (en) | 2020-10-16 | 2021-10-15 | Cleansing cosmetic composition comprising surfactant |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP4228592A1 (en) |
| CN (1) | CN116322618A (en) |
| FR (1) | FR3115197B1 (en) |
| WO (1) | WO2022079276A1 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0955355A3 (en) * | 1998-04-28 | 2000-08-02 | Ciba SC Holding AG | Antioxidants for the stabilization of formulations comprising surfactants |
| DE10224022A1 (en) * | 2002-05-31 | 2003-12-11 | Beiersdorf Ag | Mild care shampoo |
| RO127269B1 (en) * | 2010-10-04 | 2013-10-30 | Liviu Andronovici | Hydroalcoholic rose solution |
| FR3049855A1 (en) * | 2016-04-12 | 2017-10-13 | Oleon Nv | MULTIPLE EMULSION |
| CN108066230A (en) * | 2016-11-08 | 2018-05-25 | 徐锋 | A kind of skin-moisturizing, skin shower cream |
-
2020
- 2020-10-16 FR FR2010641A patent/FR3115197B1/en active Active
-
2021
- 2021-10-15 WO PCT/EP2021/078673 patent/WO2022079276A1/en unknown
- 2021-10-15 EP EP21789769.3A patent/EP4228592A1/en active Pending
- 2021-10-15 CN CN202180069201.5A patent/CN116322618A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2022079276A1 (en) | 2022-04-21 |
| FR3115197B1 (en) | 2024-02-02 |
| FR3115197A1 (en) | 2022-04-22 |
| EP4228592A1 (en) | 2023-08-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60109337T2 (en) | Composition for cleaning keratin substances based on a slightly ethoxylated sorbitan ester | |
| ES2272239T3 (en) | FOAMING OLEAGINOUS COMPOSITIONS. | |
| DE60218253T3 (en) | A copolymer of methacrylic acid and an oil-containing cosmetic compositions and their uses | |
| US20030228272A1 (en) | Novel antidandruff conditioning shampoo | |
| JPS6320253B2 (en) | ||
| DE3044738A1 (en) | Hair treatment compsn. - contg. amphoteric polymer contg. basic nitrogen and acid gps., and cationic polymer contg. poly:amine or quat. ammonium gps. | |
| WO2012052536A2 (en) | Cosmetic composition comprising aloe vera and an isethionic acid derivative | |
| FR2883744A1 (en) | DETERGENT COSMETIC COMPOSITIONS COMPRISING THREE SURFACTANTS AND A FATTY ESTER AND USE THEREOF | |
| WO2013039086A1 (en) | Shampoo composition | |
| BRPI1005097A2 (en) | cleaning composition and process for cleaning a keratin material | |
| JP2000504706A (en) | Composition containing antifungal and sulfur compound | |
| DE602004001957T2 (en) | Cosmetic use of phytantriol as an agent to prevent or reduce the adherence of microorganisms on the surface of the skin and / or mucous membranes | |
| WO2006005561A1 (en) | Use of combinations containing oxocarboxylic acids for deodorising skin and hair | |
| EP0713382A1 (en) | Hair-cleaning agent with good hair-hold characteristics | |
| DE69819692T3 (en) | Compositions for the treatment of keratin substances containing a zwitterionic polymer in combination with a non-water-soluble, non-volatile silicone | |
| WO2003084499A2 (en) | Gel cleaning preparations comprising pre-gelatinised, cross-linked starch derivatives and polyacrylates | |
| EP1422288B1 (en) | Liquid cleaning composition containing soaps and synthetic surfactants; its use for cleaning human keratinous materials | |
| DE3644097A1 (en) | COSMETIC AGENT BASED ON CHITOSAN AND AMPHOLYTIC COPOLYMERISATES AND A NEW CHITOSAN / POLYAMPHOLYT SALT | |
| EP3458018A1 (en) | Cosmetic composition comprising anionic surfactants, amphoteric surfac-tants, cationic polymers and liquid fatty substances chosen from fatty alco-hols and fatty esters, and cosmetic treatment process | |
| CN116322618A (en) | Cleansing cosmetic composition comprising surfactant | |
| ZA200109519B (en) | Skin cleaning method for eliminating comedones and scales from parts of the skin subjected to the proliferation of candida albicans. | |
| JPH07101836A (en) | Hair treating agent | |
| FR3106753A1 (en) | Aqueous cosmetic composition comprising two surfactants and a diol | |
| WO1996027363A1 (en) | Hair- and skin-treatment agent | |
| WO2003066011A1 (en) | Perfume preparation containing 2- methyl-1, 3- propanediol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |