CN116287807A - Preparation method of short-process alloy forging - Google Patents
Preparation method of short-process alloy forging Download PDFInfo
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- CN116287807A CN116287807A CN202310289822.5A CN202310289822A CN116287807A CN 116287807 A CN116287807 A CN 116287807A CN 202310289822 A CN202310289822 A CN 202310289822A CN 116287807 A CN116287807 A CN 116287807A
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- 239000000956 alloy Substances 0.000 title claims abstract description 98
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 94
- 238000005242 forging Methods 0.000 title claims abstract description 86
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 71
- 239000002994 raw material Substances 0.000 claims abstract description 62
- 230000006698 induction Effects 0.000 claims abstract description 33
- 238000002844 melting Methods 0.000 claims abstract description 23
- 230000008018 melting Effects 0.000 claims abstract description 23
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 238000011282 treatment Methods 0.000 claims abstract description 16
- 230000032683 aging Effects 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- 238000001354 calcination Methods 0.000 claims abstract description 6
- 238000000265 homogenisation Methods 0.000 claims abstract description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 66
- 229910052786 argon Inorganic materials 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 23
- 238000005266 casting Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000005086 pumping Methods 0.000 claims description 7
- 238000003723 Smelting Methods 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract description 9
- 238000005204 segregation Methods 0.000 abstract description 8
- 238000007711 solidification Methods 0.000 abstract description 7
- 230000008023 solidification Effects 0.000 abstract description 7
- 229910001338 liquidmetal Inorganic materials 0.000 abstract description 2
- 238000007712 rapid solidification Methods 0.000 abstract description 2
- 230000000630 rising effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 6
- 241000519995 Stachys sylvatica Species 0.000 description 4
- 238000004321 preservation Methods 0.000 description 3
- 238000005275 alloying Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000009416 shuttering Methods 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
- B21J5/02—Die forging; Trimming by making use of special dies ; Punching during forging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
- B21J1/06—Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
- B21K29/00—Arrangements for heating or cooling during processing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/06—Vacuum casting, i.e. making use of vacuum to fill the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/04—Influencing the temperature of the metal, e.g. by heating or cooling the mould
- B22D27/045—Directionally solidified castings
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Abstract
The invention discloses a preparation method of a short-flow alloy forging, which relates to the field of alloy forging preparation, and comprises the steps of carrying out solution treatment, calcining and melting alloy materials in a vacuum furnace, preserving heat for two hours, carrying out directional solidification on the treated alloy blank according to a direction from top to bottom by a directional cooling technology, carrying out homogenization treatment to obtain the short-flow alloy homogenized blank, carrying out primary aging treatment on the alloy to a deformation mold, carrying out hot forging deformation under the condition that the deformation amount is 20% -30%, obtaining the deformed alloy blank, carrying out die forging on the deformed alloy blank to a die forging mold, carrying out subsequent heat treatment after die forging, carrying out rapid solidification by taking away a large amount of heat of a solidification part by liquid metal, thereby effectively ensuring the purity, metallurgical defect and segregation degree of the complex alloy material, and accurately calculating the heating power of a furnace body by extracting parameters of the added raw materials, and ensuring the uniform temperature rising of the raw materials in the vacuum induction furnace.
Description
Technical Field
The invention relates to the field of alloy forging preparation, in particular to a preparation method of a short-flow alloy forging.
Background
At present, an electrode rod is mainly prepared by Vacuum Induction Melting (VIM), a ton-grade cast ingot is prepared by duplex (VIM+VAR, VIM+ESR) or triple melting (VIM+ESR+VAR), element segregation of the cast ingot is reduced by high-temperature diffusion heat treatment, as-cast crystal grains are crushed by large forging equipment, casting defects are closed, the diameter of the cast ingot is thinned and the length of the cast ingot is increased by pressure processing in the process, a slender bar is obtained, and blank preparation can be completed by cutting and blanking according to the weight of a forging. The whole process has large energy consumption, high equipment investment and long production flow, and only a few large enterprises in China have the production capacity of alloy cogging forging at present. Particularly, for difficult-to-deform alloy with total content of Al+Ti+Nb+Ta of more than 10%, dendrite segregation of ton-grade industrial ingot is strong, the probability of macroscopic defects such as white spots and black spots of VAR and ESR is high, the material hot working interval is narrow, in the large ingot type cogging forging process, the process of cogging a forging piece is long, heat preservation measures are difficult to fully cover, forging cracks are easy to occur, the conventional technology generally finishes alloying by simply vacuum induction melting, and then vacuum self-consumption and/or electroslag remelting is carried out, because a deeper molten pool aggravates solidification segregation of the material, even causes black spots and/or white spots defects, and the blank is not suitable for being directly forged into a blank, and is also forged into a blank.
In order to solve the problem, the invention provides a preparation method of a short-flow alloy forging.
Disclosure of Invention
Aiming at the defects of the prior art, the main purpose of the invention is to provide a preparation method of a short-flow alloy forging, which can effectively solve the problems in the background art: particularly, for difficult-to-deform alloy with total content of Al+Ti+Nb+Ta of more than 10%, dendrite segregation of ton-grade industrial ingot is strong, the probability of macroscopic defects such as white spots and black spots of VAR and ESR is high, the material hot working interval is narrow, in the large ingot type cogging forging process, the process of cogging a forging piece is long, heat preservation measures are difficult to fully cover, forging cracks are easy to occur, the conventional technology generally finishes alloying by simply vacuum induction melting, and then vacuum self-consumption and/or electroslag remelting can aggravate material solidification segregation due to a deeper molten pool, even black spots and/or white spot defects are caused, and the blank is not suitable for being directly forged into a blank, and is also forged into a blank. The specific technical scheme of the invention is as follows:
the preparation method of the short-flow alloy forging specifically comprises the following preparation steps:
the first step: adding raw materials of an alloy forging into a vacuum induction furnace for melting, casting an alloy melt into a spindle in a film shell, heating up under the conditions of 30kW of high-temperature electric furnace power and 25-35 ℃/min of heating speed, starting an argon protection device when the temperature is raised to 500 ℃, continuously heating up to the melting temperature of 1420-1450 ℃ under the conditions of 25-50 ml/s of argon flow, smelting for 2 hours, and carrying out homogenization treatment after directionally solidifying the treated alloy blank from top to bottom by using a directional cooling technology to obtain a short-flow alloy homogenized blank;
and a second step of: continuously introducing argon after the first step, carrying out air cooling to a primary aging temperature of 1070-1090 ℃ under the condition of 25-50 ml/s of flow rate, keeping the primary aging temperature of 1070-1090 ℃ for four hours, continuously introducing argon, carrying out air cooling for 3 minutes under the condition of 25-50 ml/s of flow rate, carrying out air cooling, conveying the treated alloy to a deformation die, carrying out hot forging deformation at the temperature of 950-980 ℃ to reach 20-30% of deformation, and obtaining deformed alloy blanks;
and a third step of: conveying the deformed alloy blank subjected to the second step to a die forging die for die forging and forging, closing an argon protection device, raising the temperature of a high-temperature electric furnace to 800-850 ℃ at a heating rate of 5-15 ℃/min for die forging, and preserving the temperature for 24 hours at the temperature to obtain a secondary treatment alloy forging, and carrying out subsequent heat treatment on the secondary treatment alloy forging to obtain a short-flow alloy forging finished product;
the alloy forging comprises, by mass, 12.0% -13.0% of Cr, 8.5% -9.5% of Co, 0.06% -0.10% of C, 1.65% -2.15% of Mo, 3.85% -4.50% of W, 3.85% -4.50% of Ta, 3.15% -3.60% of Al, 3.75% -4.20% of Ti, 0.01% -0.02% of B, 0.01% -0.05% of Zr, S not more than 0.0015%, P not more than 0.0015%, si not more than 0.2%, mn not more than 0.15%, fe not more than 0.5%, cu not more than 0.1%, bi not more than 0.00005%, pb not more than 0.0005%, se not more than 0.0003%, ag not more than 0.0005%, 3.85% -4.45% of Ta, 4% -6% of N and the balance O.
The invention is further improved in that in the first step, the temperature of the vacuum induction furnace is raised under the condition that the heating speed is 25 ℃/min-35 ℃/min by a furnace body heating strategy, and the furnace body heating strategy comprises the following specific steps:
s101, extracting the volume of added raw materials and the specific heat capacity of corresponding raw materials, simultaneously extracting the density of each raw material and the temperature of the raw materials when the raw materials are added, simultaneously extracting the diameter and depth data of a furnace body, and respectively setting the data as follows: c k ，V k ，ρ k ，T k D and h, wherein c k Specific heat of the kth raw material added to the raw material, V k For the volume of the kth raw material added to the raw material ρ k To add the density of the kth material in the material, T k The temperature of the kth raw material added into the raw material, D is the diameter of the furnace body, and h is the depth of the furnace body;
s102, substituting the extracted data into a furnace body heating formula to calculate the primary heating power of the vacuum induction furnace,
wherein c i To add the specific heat capacity ρ of the ith feedstock to the feedstock i To add the density of the ith material in the material, V i For adding the volume of the ith raw material in the raw materials, < > I->
The heating speed of the furnace body is 25-35 ℃ per minute, eta is the heat of a heater in the furnace bodyTransfer efficiency;
s103, calculating the secondary heating power of the vacuum induction furnace working under the condition of introducing 25ml/S-50ml/S argon and continuously heating to the melting temperature of 1420-1450 ℃, wherein the formula of the secondary heating power of the vacuum induction furnace working is as follows:
wherein c yq Specific heat capacity of argon, s yq The flow rate of argon is 25ml/s-50ml/s, ρ yq The density of argon is that the heating temperature in unit time is delta T, namely 25-35 ℃;
and S104, the controller controls the operation of the heater through the calculated primary heating power and the calculated secondary heating power, so that the raw materials in the vacuum induction furnace are heated.
The invention further improves that the deformation mode of the hot forging deformation in the second step adopts an accumulated deformation mode to reach 20% -30% of total deformation, wherein single deformation is 5% -8%, the alloy is deformed by alternative forging in different directions, namely, after the alloy is deformed by 5% -8% in two opposite directions, the overturning material is deformed again in the other two opposite directions, and 6 faces are alternately deformed by the similar method.
The invention is further improved in that before the raw materials of the alloy forging are added into a vacuum induction furnace for calcining and melting in the first step, the furnace body needs to be subjected to vacuum pumping operation, and the vacuum degree of the vacuum pumping is lower than 10 -3 pa。
The invention is further improved in that in the first step, the alloy blank is poured into the die shell, and the temperature range of poured alloy melt is as follows: 1440-1500 ℃, the temperature range of the mould shell is: 890-920 deg.c.
Compared with the prior art, the invention has the following beneficial effects:
1. because the invention adopts the directional solidification technology to obtain a straight solid-liquid interface, which is different from the traditional solid-liquid interface and a wider pasty area which are formed by vacuum induction melting, vacuum consumable remelting and electroslag remelting, the solid-liquid interface has no obvious convection, so that the solidification segregation degree is lower, no macrosegregation exists, and the loosening defect is less; by controlling the growth rate of the solid-liquid interface, the higher melt temperature above the solid-liquid interface can be ensured, and a large amount of heat of the solidification part is taken away by the liquid metal below the solid-liquid interface to realize rapid solidification, so that the purity, metallurgical defects and segregation degree of the complex alloy material are effectively ensured;
2. according to the invention, the heating power of the furnace body is accurately calculated by extracting the parameters of the added raw materials, so that the raw materials in the vacuum induction furnace are uniformly heated, and the production quality of the alloy is ensured.
3. According to the invention, the deformation mode of the set hot forging deformation adopts a multiple accumulated deformation mode, after the alloy is deformed by 5% -8% in two opposite directions, the overturning material is deformed again in the other two opposite directions, and the like, 6 surfaces are alternately deformed, so that the deformation effect is good, and the total deformation amount of 20% -30% is achieved.
4. The invention is characterized in that the alloy material is put in a vacuum furnace for calcination and melting, after heat preservation is carried out for two hours, the processed alloy blank is directionally solidified and homogenized according to the direction from top to bottom by a directional cooling technology, thus obtaining a short-flow alloy homogenized blank, after primary aging treatment, the alloy is conveyed to a deformation mould, hot forging deformation is carried out under the condition that the deformation is 20% -30%, the deformed alloy blank is obtained, the deformed alloy blank is conveyed to a die forging mould for die forging, and after die forging, the subsequent heat treatment is carried out.
Drawings
FIG. 1 is a schematic flow chart of a method for manufacturing a short-flow alloy forging of the present invention.
Detailed Description
In order that the above-recited objects, features and advantages of the present invention will become more readily apparent, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the appended drawings.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, but the present invention may be practiced in other ways other than those described herein, and persons skilled in the art will readily appreciate that the present invention is not limited to the specific embodiments disclosed below.
Further, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic can be included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
Example 1
The raw materials of this example were prepared from 12.18% Cr, 1.91% Mo, 8.76% Co, 3.84% Ti, 4.40% Ta, 0.02% Zr, 4.16% W, 0.5% Fe, 3.59% Al, 0.016% B, 0.098% C, 5% N, 0.0015% S and the balance O;
the preparation method of the short-flow alloy forging specifically comprises the following preparation steps:
the first step: adding raw materials of an alloy forging into a vacuum induction furnace for melting, casting an alloy melt into a spindle in a film shell, heating up under the conditions of 30kW of high-temperature electric furnace power and 25 ℃/min-35 ℃/min of heating speed, starting an argon protection device when the temperature is raised to 500 ℃, continuously heating up to the melting temperature of 1420-1450 ℃ under the conditions of 25ml/s-50ml/s of argon flow, smelting for 2 hours, and carrying out homogenization treatment after directionally solidifying the treated alloy blank in the top-down direction by using a directional cooling technology to obtain a short-flow alloy homogenized blank;
and a second step of: continuously introducing argon after the first step, carrying out air cooling to a primary aging temperature of 1070-1090 ℃ under the condition of 25-50 ml/s of flow rate, keeping the primary aging temperature of 1070-1090 ℃ for four hours, continuously introducing argon, carrying out air cooling for 3 minutes under the condition of 25-50 ml/s of flow rate, carrying out air cooling, conveying the treated alloy to a deformation die, carrying out hot forging deformation at the temperature of 950-980 ℃ to reach 20-30% of deformation, and obtaining deformed alloy blanks;
and a third step of: conveying the deformed alloy blank subjected to the second step to a die forging die for die forging and forging, closing an argon protection device, raising the temperature of a high-temperature electric furnace to 800-850 ℃ at a heating rate of 5-15 ℃/min for die forging, and preserving the temperature for 24 hours at the temperature to obtain a secondary treatment alloy forging, and carrying out subsequent heat treatment on the secondary treatment alloy forging to obtain a short-flow alloy forging finished product;
in the first step, the temperature of the vacuum induction furnace is raised under the condition that the heating speed is 25 ℃/min-35 ℃/min through a furnace body heating strategy, and the furnace body heating strategy comprises the following specific steps:
s101, extracting the volume of added raw materials and the specific heat capacity of corresponding raw materials, simultaneously extracting the density of each raw material and the temperature of the raw materials when the raw materials are added, simultaneously extracting the diameter and depth data of a furnace body, and respectively setting the data as follows: c k ，V k ，ρ k ，T k D and h, wherein c k Specific heat of the kth raw material added to the raw material, V k For the volume of the kth raw material added to the raw material ρ k To add the density of the kth material in the material, T k The temperature of the kth raw material added into the raw material, D is the diameter of the furnace body, and h is the depth of the furnace body;
s102, substituting the extracted data into a furnace body heating formula to calculate the primary heating power of the vacuum induction furnace,
wherein c i To add the specific heat capacity ρ of the ith feedstock to the feedstock i To add the density of the ith material in the material, V i For adding the volume of the ith raw material in the raw materials, < > I->
Taking the heating speed of 25-35 ℃/min as the heating speed of the furnace body, wherein eta is the heat transfer efficiency of a heater in the furnace body;
s103, calculating the secondary heating power of the vacuum induction furnace working under the condition of introducing 25ml/S-50ml/S argon and continuously heating to the melting temperature of 1420 ℃ -1450 ℃, wherein the formula of the secondary heating power of the vacuum induction furnace working is as follows:
wherein c yq Specific heat capacity of argon, s yq The flow rate of argon is 25ml/s-50ml/s, ρ yq The density of argon is that the heating temperature in unit time is delta T, namely 25-35 ℃;
s104, the controller controls the operation of the heater through the calculated primary heating power and the calculated secondary heating power, so as to heat the raw materials in the vacuum induction furnace;
the second step adopts a cumulative deformation mode to reach 15% -18% of total deformation, wherein single deformation is 5% -8%, the alloy is deformed by alternative forging in different directions, namely, after the alloy is deformed by 5% -8% in two opposite directions, the overturning material is deformed again in the other two opposite directions, and 6 surfaces are alternately deformed in the same way;
in the first step, before raw materials of the alloy forging are added into a vacuum induction furnace for calcining and melting, the furnace body is required to be subjected to vacuum pumping operation, and the vacuum degree of vacuum pumping is lower than 10 -3 pa; in the first step, casting a forging piece in a die shell by using an alloy blank, wherein the casting alloy melt has the following temperature range: 1440 ℃, the temperature range of the shuttering is: 890 ℃.
The room temperature tensile strength of the material obtained by the implementation is 1026MPa, the yield strength is 942MPa, the elongation is 6.8%, the area shrinkage is 15%, the permanent life is 102.3h under the conditions of 760 ℃ and 662MPa, the elongation is 4.3%, the area shrinkage is 19.7%, the permanent life is 73.2h under the conditions of 982 ℃ and 186MPa, the elongation is 8.7% and the area shrinkage is 13.5%.
Example 2
The raw materials of this example were prepared from 12.35% Cr, 1.89% Mo, 8.76% Co, 4.04% Ti, 3.94% Ta, 0.02% Zr, 4.10% W, 3.54% Al, 0.016% B, 0.097% C, 5.9% N, 0.0015% S and the balance O;
the preparation method of the short-flow alloy forging specifically comprises the following preparation steps:
the first step: adding raw materials of an alloy forging into a vacuum induction furnace for melting, casting an alloy melt into a spindle in a film shell, heating up under the conditions of 30kW of high-temperature electric furnace power and 25-35 ℃/min of heating speed, starting an argon protection device when the temperature is raised to 500 ℃, continuously heating up to the melting temperature of 1420-1450 ℃ under the conditions of 25-50 ml/s of argon flow, smelting for 2 hours, and carrying out homogenization treatment after directionally solidifying the treated alloy blank from top to bottom by using a directional cooling technology to obtain a short-flow alloy homogenized blank;
and a second step of: continuously introducing argon after the first step, carrying out air cooling to a primary aging temperature of 1070-1090 ℃ under the condition of 25-50 ml/s of flow rate, keeping the primary aging temperature of 1070-1090 ℃ for four hours, continuously introducing argon, carrying out air cooling for 3 minutes under the condition of 25-50 ml/s of flow rate, carrying out air cooling, conveying the treated alloy to a deformation die, carrying out hot forging deformation at the temperature of 950-980 ℃ to reach 20-30% of deformation, and obtaining deformed alloy blanks;
and a third step of: conveying the deformed alloy blank subjected to the second step to a die forging die for die forging and forging, closing an argon protection device, raising the temperature of a high-temperature electric furnace to 800-850 ℃ at a heating rate of 5-15 ℃/min for die forging, and preserving the temperature for 24 hours at the temperature to obtain a secondary treatment alloy forging, and carrying out subsequent heat treatment on the secondary treatment alloy forging to obtain a short-flow alloy forging finished product;
in the first step, the temperature of the vacuum induction furnace is raised under the condition that the heating speed is 25 ℃/min-35 ℃/min through a furnace body heating strategy, and the furnace body heating strategy comprises the following specific steps:
s101, extracting the volume of added raw materials and the specific heat capacity of corresponding raw materials, simultaneously extracting the density of each raw material and the temperature of the raw materials when the raw materials are added, simultaneously extracting the diameter and depth data of a furnace body, and respectively setting the data as follows: c k ，V k ，ρ k ，T k D and h, wherein c k Specific heat of the kth raw material added to the raw material, V k For the volume of the kth raw material added to the raw material ρ k To add the density of the kth material in the material, T k To addThe temperature of the kth raw material in the raw materials, D, h and h are the diameters of the furnace body;
s102, substituting the extracted data into a furnace body heating formula to calculate the primary heating power of the vacuum induction furnace,
wherein c i To add the specific heat capacity ρ of the ith feedstock to the feedstock i To add the density of the ith material in the material, V i For adding the volume of the ith raw material in the raw materials, < > I->
Taking the heating speed of 25-35 ℃/min as the heating speed of the furnace body, wherein eta is the heat transfer efficiency of a heater in the furnace body;
s103, calculating the secondary heating power of the vacuum induction furnace working under the condition of introducing 25ml/S-50ml/S argon and continuously heating to the melting temperature of 1420 ℃ -1450 ℃, wherein the formula of the secondary heating power of the vacuum induction furnace working is as follows:
wherein c yq Specific heat capacity of argon, s yq The flow rate of argon is 25ml/s-50ml/s, ρ yq The density of argon is that the heating temperature in unit time is delta T, namely 25-35 ℃;
s104, the controller controls the operation of the heater through the calculated primary heating power and the calculated secondary heating power, so as to heat the raw materials in the vacuum induction furnace;
the second step adopts a cumulative deformation mode to reach 20% -30% of total deformation, wherein single deformation is 5% -8%, the alloy is deformed by alternative forging in different directions, namely, after the alloy is deformed by 5% -8% in two opposite directions, the overturning material is deformed again in the other two opposite directions, and 6 surfaces are alternately deformed in the same way;
in the first step, before raw materials of the alloy forging are added into a vacuum induction furnace for calcining and melting, vacuum air suction is needed to be carried out on the furnace bodyOperating, the vacuum degree of the vacuum pumping is lower than 10 -3 pa; in the first step, casting a forging piece in a die shell by using an alloy blank, wherein the casting alloy melt has the following temperature range: 1440 ℃, the temperature range of the shuttering is: 890 ℃.
The room temperature tensile strength of the material obtained by the implementation is 895MPa, the yield strength is 850MPa, the elongation is 8.1%, the area shrinkage is 21.4%, the long-lasting life is 96h under the condition of 760 ℃ and 662MPa, the elongation is 5.4%, the area shrinkage is 7.8%, the long-lasting life is 45.7h under the condition of 982 ℃ and 186MPa, the elongation is 8.4%, and the area shrinkage is 15.4%.
The foregoing has shown and described the basic principles and main features of the present invention and the advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that the above embodiments and descriptions are merely illustrative of the principles of the present invention, and various changes and modifications may be made without departing from the spirit and scope of the invention, which is defined in the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (5)
1. A preparation method of a short-flow alloy forging is characterized by comprising the following steps: the preparation method specifically comprises the following preparation steps:
the first step: adding raw materials of an alloy forging into a vacuum induction furnace for melting, casting an alloy melt into a spindle in a film shell, heating up under the conditions of 30kW of high-temperature electric furnace power and 25-35 ℃/min of heating speed, starting an argon protection device when the temperature is raised to 500 ℃, continuously heating up to the melting temperature of 1420-1450 ℃ under the conditions of 25-50 ml/s of argon flow, smelting for 2 hours, and carrying out homogenization treatment after directionally solidifying the treated alloy blank from top to bottom by using a directional cooling technology to obtain a short-flow alloy homogenized blank;
and a second step of: continuously introducing argon after the first step, carrying out air cooling to a primary aging temperature of 1070-1090 ℃ under the condition of 25-50 ml/s of flow rate, keeping the primary aging temperature of 1070-1090 ℃ for four hours, continuously introducing argon, carrying out air cooling for 3 minutes under the condition of 25-50 ml/s of flow rate, carrying out air cooling, conveying the treated alloy to a deformation die, carrying out hot forging deformation at the temperature of 950-980 ℃ to reach 20-30% of deformation, and obtaining deformed alloy blanks;
and a third step of: conveying the deformed alloy blank subjected to the second step to a die forging die for die forging and forging, closing an argon protection device, raising the temperature of a high-temperature electric furnace to 800-850 ℃ at a heating rate of 5-15 ℃/min for die forging, and preserving the temperature for 24 hours at the temperature to obtain a secondary treatment alloy forging, and carrying out subsequent heat treatment on the secondary treatment alloy forging to obtain a short-flow alloy forging finished product;
the alloy forging comprises, by mass, 12.0% -13.0% of Cr, 8.5% -9.5% of Co, 0.06% -0.10% of C, 1.65% -2.15% of Mo, 3.85% -4.50% of W, 3.85% -4.50% of Ta, 3.15% -3.60% of Al, 3.75% -4.20% of Ti, 0.01% -0.02% of B, 0.01% -0.05% of Zr, S not more than 0.0015%, P not more than 0.0015%, si not more than 0.2%, mn not more than 0.15%, fe not more than 0.5%, cu not more than 0.1%, bi not more than 0.00005%, pb not more than 0.0005%, se not more than 0.0003%, ag not more than 0.0005%, 3.85% -4.45% of Ta, 4% -6% of N and the balance O.
2. The method for manufacturing a short-process alloy forging according to claim 1, wherein the method comprises the following steps: in the first step, the temperature of the vacuum induction furnace is raised under the condition that the heating speed is 25 ℃/min-35 ℃/min through a furnace body heating strategy, and the furnace body heating strategy comprises the following specific steps:
s101, extracting the volume of the added raw materials and the specific heat capacity of the corresponding raw materials, simultaneously extracting the density of each raw material and the temperature of the raw materials when the raw materials are added, and simultaneously extracting the diameter and depth data of a furnace body;
s102, substituting the extracted data into a furnace body heating formula to calculate primary heating power of the vacuum induction furnace;
s103, calculating the secondary heating power of the vacuum induction furnace which is continuously heated to the melting temperature of 1420-1450 ℃ under the condition of introducing 25-50 ml/S of argon;
and S104, the controller controls the operation of the heater through the calculated primary heating power and the calculated secondary heating power, so that the raw materials in the vacuum induction furnace are heated.
3. The method for manufacturing a short-process alloy forging according to claim 2, wherein the method comprises the following steps: the deformation mode of the hot forging deformation in the second step adopts an accumulated deformation mode to reach 20% -30% of total deformation, wherein single deformation is 5% -8%, the alloy is deformed by alternative forging in different directions, namely, after the alloy is deformed by 5% -8% in two opposite directions, the overturning material is deformed again in the other two opposite directions, and 6 surfaces are alternately deformed by the similar steps.
4. A method of making a short-process alloy forging in accordance with claim 3, wherein: before raw materials of the alloy forging are added into a vacuum induction furnace for calcining and melting in the first step, a furnace body needs to be subjected to vacuum pumping operation, and the vacuum degree of vacuum pumping is lower than 10 -3 pa。
5. The method for manufacturing a short-process alloy forging according to claim 4, wherein the method comprises the following steps: in the first step, casting a forging piece in a mould shell by using an alloy blank, wherein the casting alloy melt has the following temperature range: 1440-1500 ℃, the temperature range of the mould shell is: 890-920 deg.c.
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| CN117564200A (en) * | 2023-12-29 | 2024-02-20 | 江苏美特林科特殊合金股份有限公司 | Preparation method of short-process alloy forging |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102703794A (en) * | 2012-06-20 | 2012-10-03 | 江苏美特林科特殊合金有限公司 | Method for vacuum induction argon bottom blowing smelting high-performance magnetic material |
| CN103128256A (en) * | 2013-03-14 | 2013-06-05 | 哈尔滨工业大学 | Preparation method for GH 4133 nickel-base superalloy semisolid blank |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102703794A (en) * | 2012-06-20 | 2012-10-03 | 江苏美特林科特殊合金有限公司 | Method for vacuum induction argon bottom blowing smelting high-performance magnetic material |
| CN103128256A (en) * | 2013-03-14 | 2013-06-05 | 哈尔滨工业大学 | Preparation method for GH 4133 nickel-base superalloy semisolid blank |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117564200A (en) * | 2023-12-29 | 2024-02-20 | 江苏美特林科特殊合金股份有限公司 | Preparation method of short-process alloy forging |
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