CN116285631A - Water-based heat insulation coating for color steel tiles and preparation method thereof - Google Patents
Water-based heat insulation coating for color steel tiles and preparation method thereof Download PDFInfo
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- CN116285631A CN116285631A CN202310428653.9A CN202310428653A CN116285631A CN 116285631 A CN116285631 A CN 116285631A CN 202310428653 A CN202310428653 A CN 202310428653A CN 116285631 A CN116285631 A CN 116285631A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 45
- 239000010959 steel Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 238000009413 insulation Methods 0.000 title claims abstract description 10
- 239000011248 coating agent Substances 0.000 title claims description 25
- 238000000576 coating method Methods 0.000 title claims description 25
- 239000003973 paint Substances 0.000 claims abstract description 30
- 239000013538 functional additive Substances 0.000 claims abstract description 22
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 12
- 239000003755 preservative agent Substances 0.000 claims abstract description 10
- 230000002335 preservative effect Effects 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 9
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 9
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 9
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 6
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 80
- 238000006243 chemical reaction Methods 0.000 claims description 73
- 239000000463 material Substances 0.000 claims description 63
- 238000003756 stirring Methods 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 38
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 32
- 239000011159 matrix material Substances 0.000 claims description 32
- 235000019441 ethanol Nutrition 0.000 claims description 23
- 239000007864 aqueous solution Substances 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011324 bead Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 238000004321 preservation Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 6
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000011812 mixed powder Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000005286 illumination Methods 0.000 claims description 5
- 238000003760 magnetic stirring Methods 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 239000011343 solid material Substances 0.000 claims description 5
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 claims description 3
- 244000248349 Citrus limon Species 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- MECMQNITHCOSAF-UHFFFAOYSA-N manganese titanium Chemical compound [Ti].[Mn] MECMQNITHCOSAF-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 102200082943 rs35424040 Human genes 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000010215 titanium dioxide Nutrition 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000032683 aging Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract description 3
- 230000004224 protection Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 description 5
- 230000006750 UV protection Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- QDCHWIWENYCPIL-UHFFFAOYSA-L disodium;4-hydroxy-5-(2-hydroxy-4-methoxy-5-sulfonatobenzoyl)-2-methoxybenzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC(S([O-])(=O)=O)=C(OC)C=C1O QDCHWIWENYCPIL-UHFFFAOYSA-L 0.000 description 3
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 3
- UYZZHENGTKPYMN-UHFFFAOYSA-N 4-hydroxy-5-(2-hydroxy-4-methoxy-5-sulfobenzoyl)-2-methoxybenzenesulfonic acid Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC(S(O)(=O)=O)=C(OC)C=C1O UYZZHENGTKPYMN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of paint production, in particular to a heat-insulating paint for water-based color steel tiles and a preparation method thereof, wherein the heat-insulating paint comprises the following components in parts by weight: 35 to 45 parts of acrylic emulsion, 45 to 60 parts of polyurethane emulsion, 0.2 to 0.35 part of polydimethylsiloxane, 0.12 to 0.2 part of fluorosilicone, 1.6 to 2.3 parts of sodium hexametaphosphate, 2 to 4.5 parts of propylene glycol methyl ether acetate, 2.5 to 3.8 parts of nano silicon dioxide, 1.8 to 2.5 parts of nano zinc oxide, 2.0 to 3.5 parts of sericite, 1.5 to 2.5 parts of precipitated barium sulfate, 8 to 15 parts of functional additive, 0.7 to 1.2 parts of pigment, 0.5 to 0.8 part of thickener, 0.3 to 0.7 part of preservative, 0.3 to 0.6 part of ultraviolet absorber and 10 to 30 parts of deionized water; the heat-insulating paint for the water-based color steel tile prepared by the invention has good ageing resistance, good heat insulation performance, good protection effect on the color steel tile and prolonged service life to a certain extent.
Description
Technical Field
The invention relates to the technical field of paint production, in particular to a heat-insulating paint for water-based color steel tiles and a preparation method thereof.
Background
The color steel tile is also called color profiling tile, which is a profiled plate made of color coated steel plate by rolling and cold bending into various wave patterns. The decorative material is mainly suitable for the decoration of roofs, walls, inner walls and the like of industrial and civil buildings, warehouses, special buildings and large-span steel structure houses, has the characteristics of light weight, high strength, rich color, convenient and quick construction, earthquake resistance, fire resistance, rain resistance, long service life, no maintenance and the like, and has been widely popularized and applied. When the color steel tile is installed, the middle part of the tile is stepped on as much as possible, the edge of the tile is prevented from being stepped on, and the color steel tile is carefully installed in severe weather.
In daily life, a layer of paint is often required to be sprayed on the surface of the color steel tile, and the purpose of the paint is to protect the color steel tile to a certain extent, so that the color steel tile is prevented from being corroded due to long-time wind and sun exposure. The service life of the water heater is prolonged to a certain extent. However, although the coating on the market can play a certain role in protecting the color steel tile, the function of the coating is relatively single, such as the heat insulation performance of the coating is relatively insufficient, the ultraviolet resistance of the coating is relatively poor, the paint film of the coating can be aged to different degrees after being exposed to sunlight for a long time, and the service life of the coating is shortened to a certain extent. Based on the above, the invention provides a heat-insulating coating for water-based color steel tiles and a preparation method thereof, so as to solve the technical problem.
Disclosure of Invention
The invention aims to provide the heat-insulating paint for the water-based color steel tile and the preparation method thereof, and the prepared heat-insulating paint for the water-based color steel tile has good ageing resistance, good heat-insulating property, good protection effect on the color steel tile and prolonged service life to a certain extent.
In order to achieve the above purpose, the present invention provides the following technical solutions:
the heat-insulating coating for the water-based color steel tile comprises the following components in parts by weight: 35 to 45 parts of acrylic emulsion, 45 to 60 parts of polyurethane emulsion, 0.2 to 0.35 part of polydimethylsiloxane, 0.12 to 0.2 part of fluorosilicone, 1.6 to 2.3 parts of sodium hexametaphosphate, 2 to 4.5 parts of propylene glycol methyl ether acetate, 2.5 to 3.8 parts of nano silicon dioxide, 1.8 to 2.5 parts of nano zinc oxide, 2.0 to 3.5 parts of sericite, 1.5 to 2.5 parts of precipitated barium sulfate, 8 to 15 parts of functional additive, 0.7 to 1.2 parts of pigment, 0.5 to 0.8 part of thickener, 0.3 to 0.7 part of preservative, 0.3 to 0.6 part of ultraviolet absorber and 10 to 30 parts of deionized water.
Further, the preparation method of the functional additive comprises the following steps:
i, putting a matrix material into a proper amount of ethanol aqueous solution according to a material ratio of 0.06-0.15 g/mL, mixing and stirring uniformly, adding a modifier with the mass of 30-40% of that of the ethanol aqueous solution into the mixture, performing ultrasonic dispersion for 1-2 h, and performing magnetic stirring and dispersion for 2-3 h; after the dispersion is finished, soaking the mixture for 10 to 15 hours at room temperature; then sequentially carrying out suction filtration and acetone washing treatment, transferring the obtained filter material into a vacuum drying oven, drying the filter material for 7-9 h under the conditions that the temperature is 45-55 ℃ and the vacuum degree is 1.0MP, and storing the obtained solid powder for later use after the drying is finished;
wherein the concentration of the ethanol water solution is 50-70%, and the ethanol solution also comprises 2.5-3.8% of octyl phenol polyoxyethylene ether and 8-15% of 2-hydroxy 4-methoxybenzophenone sulfonic acid by mass;
II, under the water bath condition of 30-40 ℃, slowly injecting a proper amount of methacrylic acid monomer into a reaction container containing the solid powder obtained in the step I in 2-3 h under stirring according to the dosage ratio of 0.02-0.03 g/mL, after the material mixing is finished, heating the obtained mixed material liquid to 35-50 ℃, and preserving heat at the temperature for reaction for 5-8 h; then the reaction temperature is raised to 65-80 ℃, and the reaction is carried out for 8-12 h at the temperature; after the reaction is finished, the obtained product components are stored for standby;
III, transferring the product component obtained in the step II into reaction equipment, slowly adding a reaction promoter with the mass of 1.2-4.5% of that of the matrix material at the stirring rate of 160-200 r/min, and then carrying out illumination and microwave treatment on the mixture in the reaction equipment; wherein the power of the microwave treatment is set to 2500W; mixing materials for 40-60 min at the speed of 120-200 r/min; after the material mixing is finished, the mixed material liquid in the reaction equipment is moved into a reaction kettle and stirred and reacts for 2 to 4 hours at the temperature of 50 to 70 ℃; after the reaction is finished, carrying out vacuum suction filtration on the components of the products in the reaction kettle; then respectively washing the obtained filter material with acetone, ethanol, toluene or ethyl acetate; finally, the obtained filter material is dried for 5 to 8 hours under the conditions of 0.8 to 1MPa and 45 to 60 ℃ in vacuum, and the obtained solid material is the finished functional additive.
Further, the preparation method of the matrix material comprises the following steps: tetrabutyl titanate, absolute ethyl alcohol and glacial acetic acid are mixed according to the weight ratio of 12-15: 3 to 5:1, and then mixing and stirring uniformly according to the volume ratio of 2:1, dripping the obtained mixed solution into an aqueous solution of absolute ethyl alcohol with the concentration of 70-80% while stirring, then adjusting the pH value of the obtained mixed component to 3.2-4.0, and carrying out heat preservation reaction on the obtained mixed component at the temperature of 40-55 ℃ for 50-80 min; after the reaction is finished, adding hollow glass beads with the volume of 7-9 times and the particle size of 5-12 mu m into the obtained sol, and stirring and mixing for 60-90 min; after being uniformly mixed, the mixture is kept stand and aged for 10 to 15 hours, and is dried at the temperature of 90 to 100 ℃, after the drying is finished, the mixture is calcined at the high temperature of 500 to 580 ℃ for 2 to 3 hours, and then the mixture is naturally cooled to the room temperature, thus obtaining the finished product of the matrix material.
Further, the modifier is any one of gamma- (methacryloyloxy) propyl trimethoxy silane, gamma-glycidol ether oxypropyl trimethoxy silane and 3-aminopropyl triethoxy silane.
Further, the reaction promoter is any one of 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl ] -1-acetone and 1-hydroxycyclohexyl phenyl ketone.
Further, the thickener is selected from any one of TT-935 of American Dow chemical thickener, 425 of Haimines and 450 of American Dow chemical thickener.
Further, the preservative is selected from K40, A28S preservative manufactured by German and Shumei company or LX150, R640 preservative manufactured by American Dow chemical industry.
Further, the pigment is any one of lemon yellow, phthalocyanine green, titanium white, titanium manganese brown, cobalt blue and titanium nickel yellow.
Further, the ultraviolet absorber is selected from any one of benzotriazole mixture UV-1130 and hindered amine UV-123.
The preparation method of the heat-insulating coating for the water-based color steel tile comprises the following steps:
firstly, accurately weighing all materials according to the formula amount, and then transferring sericite, precipitated barium sulfate and pigment into a grinding machine for grinding and dispersing until the fineness is less than or equal to 25 mu m; the obtained mixed powder is preserved for standby;
and step two, sequentially adding deionized water, sodium hexametaphosphate, polydimethylsiloxane and fluorosilicone into mixing equipment, uniformly mixing and stirring, adding the mixed powder obtained in the step one, uniformly mixing and stirring, adding the rest materials, continuously mechanically stirring uniformly, and filtering the mixture by using silk cloth with 120-150 meshes, wherein the obtained slurry is the finished product of the water-based heat-insulating paint for the color steel tile after the filtering is finished.
Compared with the prior art, the invention has the beneficial effects that:
in the invention, tetrabutyl titanate, absolute ethyl alcohol, glacial acetic acid, hollow glass beads and the like are used as raw materials, and a layer of nano powder, namely a base material finished product, is densely coated on the surfaces of the hollow glass beads through a specific chemical process. The prepared matrix material not only has better heat insulation performance, but also has certain ultraviolet resistance. Then taking the obtained matrix material as a starting material, uniformly dispersing the matrix material in an ethanol aqueous solution containing octyl phenol polyoxyethylene ether and 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -disulfonic acid sodium, and reducing the agglomeration phenomenon of the matrix material under the action of the octyl phenol polyoxyethylene ether so as to uniformly disperse the matrix material in the ethanol aqueous solution. Meanwhile, the 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -disulfonic acid sodium salt can be uniformly retained on the surface of the collective material. After the mixture is uniformly dispersed, a proper amount of modifier is added, the matrix material is bonded with the modifier through chemical reaction, and finally the matrix material and the modifier are connected in a chemical bond mode, so that the 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -disulfonic acid sodium salt remained on the surface of the matrix material is effectively fixed, and the ultraviolet resistance of the matrix material is effectively improved.
And then, the methacrylic acid monomer is subjected to chemical reaction under the action of a reaction accelerator, so that the methacrylic acid monomer is grafted on the surface of a base material through the chemical reaction, and finally, a dense three-dimensional network structure taking a modifier and the methacrylic acid monomer as raw materials is formed on the surface of the base material, so that further ' fixing ' of 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -disulfonic acid sodium is realized, and finally, the functional additive finished product is prepared. The functional additive is used as the raw material for preparing the heat-insulating paint for the water-based color steel tile, so that the heat-insulating property and the ageing resistance of the paint can be effectively improved, the mechanical property of the paint can be effectively improved, and the quality and the performance of the prepared heat-insulating paint can be effectively ensured.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
The heat-insulating coating for the water-based color steel tile comprises the following components in parts by weight: 35 parts of acrylic emulsion, 45 parts of polyurethane emulsion, 0.2 part of polydimethylsiloxane, 0.12 part of fluorosilicone, 1.6 parts of sodium hexametaphosphate, 2 parts of propylene glycol methyl ether acetate, 2.5 parts of nano silicon dioxide, 1.8 parts of nano zinc oxide, 2.0 parts of sericite, 1.5 parts of precipitated barium sulfate, 8 parts of functional additive, 0.7 part of lemon yellow, 0.5 part of TT-935 thickener of American Dow chemical, 0.3 part of K40 preservative produced by Germany and Shumei company, 0.3 part of benzotriazole mixture UV-1130 ultraviolet absorber and 10 parts of deionized water.
The preparation method of the functional additive comprises the following steps:
i, putting a matrix material into a proper amount of ethanol aqueous solution according to a material ratio of 0.06g/mL, uniformly mixing and stirring, adding gamma- (methacryloyloxy) propyl trimethoxysilane with the mass of 30% of that of the ethanol aqueous solution into the mixture, performing ultrasonic dispersion for 1h, and performing magnetic stirring and dispersion for 2h; after the dispersion is finished, soaking the mixture for 10 hours at room temperature; then sequentially carrying out suction filtration and acetone washing treatment, transferring the obtained filter material into a vacuum drying oven, drying the filter material for 7 hours under the conditions that the temperature is 45 ℃ and the vacuum degree is 1.0MP, and after the drying is finished, preserving the obtained solid powder for later use;
wherein the concentration of the ethanol water solution is 50%, and the ethanol solution also comprises 2.5% of octyl phenol polyoxyethylene ether and 8% of 2-hydroxy 4-methoxybenzophenone sulfonic acid by mass;
II, under the water bath condition of 30 ℃, slowly injecting a proper amount of methacrylic acid monomer into a reaction container containing the solid powder obtained in the step I in 2h under stirring according to the dosage ratio of 0.02g/mL, after the material mixing is finished, heating the obtained mixed material liquid to 35 ℃, and carrying out heat preservation reaction for 5h at the temperature; then the reaction temperature is increased to 65 ℃, and the reaction is carried out for 8 hours at the temperature; after the reaction is finished, the obtained product components are stored for standby;
III, transferring the product component obtained in the step II into reaction equipment, slowly adding 2-hydroxy-2-methyl-1-phenyl-1-acetone with the mass being 1.2% of that of a matrix material at the stirring rate of 160r/min, and then carrying out illumination and microwave treatment on the mixture in the reaction equipment; wherein the power of the microwave treatment is set to 2500W; mixing materials for 40min at the speed of 120 r/min; after the material mixing is finished, transferring the mixed material liquid in the reaction equipment into a reaction kettle, and stirring and reacting for 2 hours at the temperature of 50 ℃; after the reaction is finished, carrying out vacuum suction filtration on the components of the products in the reaction kettle; then respectively washing the obtained filter material with acetone, ethanol, toluene or ethyl acetate; finally, the obtained filter material is dried for 5 hours under the conditions of 0.8MPa and 45 ℃ in vacuum, and the obtained solid material is the finished functional additive.
The preparation method of the matrix material comprises the following steps: tetrabutyl titanate, absolute ethyl alcohol and glacial acetic acid are mixed according to a ratio of 12:3:1, and then mixing and stirring uniformly according to the volume ratio of 2:1, dripping the obtained mixed solution into an aqueous solution of absolute ethyl alcohol with the concentration of 70% while stirring, then adjusting the pH value of the obtained mixed component to 3.2, and carrying out heat preservation reaction on the obtained mixed component at the temperature of 40 ℃ for 50min; after the reaction is finished, adding hollow glass beads with the volume of 7 times and the particle size of 5 mu m into the obtained sol, and stirring and mixing for 60min; after being uniformly mixed, the mixture is kept stand and aged for 10 hours, and is dried at the temperature of 90 ℃, after the drying is finished, the mixture is calcined at the high temperature of 500 ℃ for 2 hours, and then the mixture is naturally cooled to the room temperature, thus obtaining the finished product of the matrix material.
The preparation method of the heat-insulating coating for the water-based color steel tile comprises the following steps:
firstly, accurately weighing all materials according to the formula amount, and then transferring sericite, precipitated barium sulfate and pigment into a grinding machine for grinding and dispersing until the fineness is 25 mu m; the obtained mixed powder is preserved for standby;
and step two, sequentially adding deionized water, sodium hexametaphosphate, polydimethylsiloxane and fluorosilicone into mixing equipment, uniformly mixing and stirring, adding the mixed powder obtained in the step one, uniformly mixing and stirring, adding the rest materials, continuously mechanically stirring uniformly, and filtering the mixture by using 120-mesh silk cloth as a filter hole, wherein the obtained slurry is the finished product of the water-based heat-insulating paint for the color steel tile after the filtering is finished.
Example 2
The preparation method of the heat-insulating coating for the water-based color steel tile in the embodiment is the same as that in the embodiment 1, and the difference is that: the proportion of the raw materials, the preparation methods of the functional additives and the matrix materials are slightly different, and the preparation methods are as follows:
the heat-insulating coating for the water-based color steel tile comprises the following components in parts by weight: 40 parts of acrylic emulsion, 50 parts of polyurethane emulsion, 0.3 part of polydimethylsiloxane, 0.16 part of fluorosilicone, 2.0 parts of sodium hexametaphosphate, 3.6 parts of propylene glycol methyl ether acetate, 3.2 parts of nano silicon dioxide, 2.0 parts of nano zinc oxide, 3.0 parts of sericite, 2.0 parts of precipitated barium sulfate, 12 parts of functional additive, 1.0 part of titanium dioxide, 0.6 part of 425 thickener produced by Hammins, 0.5 part of A28S preservative produced by Germany and Shumei company, 0.4 part of hindered amine UV-123 ultraviolet absorber and 20 parts of deionized water.
The preparation method of the functional additive comprises the following steps:
i, putting a matrix material into a proper amount of ethanol aqueous solution according to a material ratio of 0.1g/mL, uniformly mixing and stirring, adding gamma-glycidol ether oxypropyl trimethoxysilane with the mass of 35% of that of the ethanol aqueous solution into the mixture, performing ultrasonic dispersion for 1.5h, and performing magnetic stirring and dispersion for 2h; after the dispersion is finished, soaking the mixture for 12 hours at room temperature; then sequentially carrying out suction filtration and acetone washing treatment, transferring the obtained filter material into a vacuum drying oven, drying the filter material for 8 hours under the conditions that the temperature is 50 ℃ and the vacuum degree is 1.0MP, and after the drying is finished, preserving the obtained solid powder for later use;
wherein the concentration of the ethanol water solution is 60%, and the ethanol solution also comprises 3.0% of octyl phenol polyoxyethylene ether and 12% of 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -disulfonic acid sodium salt;
II, under the water bath condition of 35 ℃, slowly injecting a proper amount of methacrylic acid monomer into a reaction container containing the solid powder obtained in the step I in the 3h time under stirring according to the dosage ratio of 0.025g/mL, after the material mixing is finished, heating the obtained mixed material liquid to 45 ℃, and carrying out heat preservation reaction for 6h at the temperature; then the reaction temperature is raised to 70 ℃, and the reaction is kept at the temperature for 10 hours; after the reaction is finished, the obtained product components are stored for standby;
III, transferring the product component obtained in the step II into reaction equipment, slowly adding 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl ] -1-acetone with the mass accounting for 3.0% of that of a matrix material at the stirring rate of 180r/min, and then carrying out illumination and microwave treatment on the mixture in the reaction equipment; wherein the power of the microwave treatment is set to 2500W; mixing materials for 50min at the speed of 160 r/min; after the material mixing is finished, transferring the mixed material liquid in the reaction equipment into a reaction kettle, and stirring and reacting for 3 hours at the temperature of 60 ℃; after the reaction is finished, carrying out vacuum suction filtration on the components of the products in the reaction kettle; then respectively washing the obtained filter material with acetone, ethanol, toluene or ethyl acetate; finally, the obtained filter material is dried for 6 hours under the conditions of 0.9MPa and 55 ℃ in vacuum, and the obtained solid material is the finished functional additive product.
The preparation method of the matrix material comprises the following steps: tetrabutyl titanate, absolute ethyl alcohol and glacial acetic acid are mixed according to the following weight ratio of 14:4:1, and then mixing and stirring uniformly according to the volume ratio of 2:1, dripping the obtained mixed solution into an aqueous solution of absolute ethyl alcohol with the concentration of 75 percent while stirring, then adjusting the pH value of the obtained mixed component to 3.6, and carrying out heat preservation reaction on the obtained mixed component at the temperature of 50 ℃ for 70 minutes; after the reaction is finished, adding hollow glass beads with the volume of 8 times and the particle size of 10 mu m into the obtained sol, and stirring and mixing for 80min; after being uniformly mixed, the mixture is kept stand and aged for 12 hours, and is dried at the temperature of 95 ℃, after the drying is finished, the mixture is calcined at the high temperature of 550 ℃ for 3 hours, and then the mixture is naturally cooled to the room temperature, thus obtaining the finished product of the matrix material.
Example 3
The preparation method of the heat-insulating coating for the water-based color steel tile in the embodiment is the same as that in the embodiment 1, and the difference is that: the proportion of the raw materials, the preparation methods of the functional additives and the matrix materials are slightly different, and the preparation methods are as follows:
the heat-insulating coating for the water-based color steel tile comprises the following components in parts by weight: 45 parts of acrylic emulsion, 60 parts of polyurethane emulsion, 0.35 part of polydimethylsiloxane, 0.2 part of fluorosilicone, 2.3 parts of sodium hexametaphosphate, 4.5 parts of propylene glycol methyl ether acetate, 3.8 parts of nano silicon dioxide, 2.5 parts of nano zinc oxide, 3.5 parts of sericite, 2.5 parts of precipitated barium sulfate, 15 parts of functional additive, 1.2 parts of titanium manganese brown, 0.8 part of 450 thickener produced by Hamming, 0.7 part of LX150 preservative produced by American Dow chemical, 0.6 part of benzotriazole mixture UV-1130 ultraviolet absorber and 10-30 parts of deionized water.
The preparation method of the functional additive comprises the following steps:
i, putting a matrix material into a proper amount of ethanol aqueous solution according to a material ratio of 0.15g/mL, uniformly mixing and stirring, adding 3-aminopropyl triethoxysilane with the mass of 30-40% of that of the ethanol aqueous solution into the mixture, performing ultrasonic dispersion for 2 hours, and performing magnetic stirring and dispersion for 3 hours; after the dispersion is finished, soaking the mixture for 15 hours at room temperature; then sequentially carrying out suction filtration and acetone washing treatment, transferring the obtained filter material into a vacuum drying oven, drying the filter material for 9 hours under the conditions that the temperature is 55 ℃ and the vacuum degree is 1.0MP, and after the drying is finished, preserving the obtained solid powder for later use;
wherein the concentration of the ethanol water solution is 70%, and the ethanol solution also comprises 3.8% of octyl phenol polyoxyethylene ether and 15% of 2-hydroxy 4-methoxybenzophenone sulfonic acid by mass;
II, under the water bath condition of 40 ℃, slowly injecting a proper amount of methacrylic acid monomer into a reaction container containing the solid powder obtained in the step I in 3 hours under stirring according to the dosage ratio of 0.03g/mL, after the material mixing is finished, heating the obtained mixed material liquid to 50 ℃, and carrying out heat preservation reaction for 8 hours at the temperature; then the reaction temperature is increased to 80 ℃, and the reaction is kept at the temperature for 12 hours; after the reaction is finished, the obtained product components are stored for standby;
III, transferring the product component obtained in the step II into reaction equipment, slowly adding 1-hydroxycyclohexyl phenyl ketone with the mass accounting for 4.5% of that of the matrix material at the stirring rate of 200r/min, and then carrying out illumination and microwave treatment on the mixture in the reaction equipment; wherein the power of the microwave treatment is set to 2500W; mixing materials at the speed of 200r/min for 60min; after the material mixing is finished, transferring the mixed material liquid in the reaction equipment into a reaction kettle, and stirring and reacting for 4 hours at the temperature of 70 ℃; after the reaction is finished, carrying out vacuum suction filtration on the components of the products in the reaction kettle; then respectively washing the obtained filter material with acetone, ethanol, toluene or ethyl acetate; finally, the obtained filter material is dried for 8 hours under the conditions of 1MPa and 60 ℃ in vacuum, and the obtained solid material is the finished functional additive product.
The preparation method of the matrix material comprises the following steps: tetrabutyl titanate, absolute ethyl alcohol and glacial acetic acid are mixed according to the weight ratio of 15:5:1, and then mixing and stirring uniformly according to the volume ratio of 2:1, dripping the obtained mixed solution into an aqueous solution of absolute ethyl alcohol with the concentration of 80 percent while stirring, then adjusting the pH value of the obtained mixed component to 4.0, and carrying out heat preservation reaction on the obtained mixed component at the temperature of 55 ℃ for 80 minutes; after the reaction is finished, adding hollow glass beads with the volume of 9 times and the particle size of 12 mu m into the obtained sol, and stirring and mixing for 90min; after being uniformly mixed, the mixture is kept stand and aged for 15 hours, and is dried at the temperature of 100 ℃, after the drying is finished, the mixture is calcined at the high temperature of 580 ℃ for 3 hours, and then the mixture is naturally cooled to the room temperature, thus obtaining the finished product of the matrix material.
Comparative example 1 differs from example 1 in that: an equivalent amount of matrix material in this example replaces the functional additive;
comparative example 2 differs from example 1 in that: in the embodiment, the equivalent hollow glass beads are directly used for replacing the functional additive;
performance test: the quality of the heat-insulating paint for water-based color steel tiles prepared in examples 1 to 3 and comparative examples 1 to 2 was measured, and the obtained data are recorded in the following table:
1. and (3) testing heat insulation performance: the thermal insulation performance of the paint is tested by adopting a hot box method, a wire rod coater is used for uniformly coating paint samples on a 160mm multiplied by 80mm multiplied by 5mm cement asbestos board to prepare a sample plate to be tested, and the thickness of the coating film is 300 mu m. A polystyrene foam hot box with a wall thickness of 100mm and a size of 200mm×200mm×400mm was prepared, and a rectangular hole with a top center position of 150mm×70mm was used for placing a sample plate to be tested. And 1 infrared lamp with the power of 500W is respectively arranged at the position about 30cm above the hole of the hot box, the temperatures of the front surface and the back surface of the sample plate are respectively tested by using a thermocouple thermometer, the temperature change condition is recorded until the equilibrium temperature is reached, the test is repeated for 2 times, and the obtained data are recorded in the following table:
2. tensile property test: tensile properties of each set of paint samples were tested using astm d7264 standard and the data obtained are recorded in the following table:
3. impact strength: the impact strength of each group of paint samples was tested using the GB/T1451 standard and the data obtained are reported in the following table:
4. ultraviolet resistance test: the ultraviolet shielding rate of each group of paint samples was tested by an ultraviolet spectrophotometer, and the obtained data are recorded in the following table:
as can be seen from the comparison and analysis of the related data in the table, compared with the comparative example, the heat insulation coating for the water-based color steel tile prepared by the invention has better ageing resistance, better heat insulation performance, better protection effect on the color steel tile and longer service life to a certain extent. Therefore, the heat-insulating coating for the water-based color steel tile and the preparation method thereof have wider market prospect and are more suitable for popularization.
In the description of the present specification, the descriptions of the terms "one embodiment," "example," "specific example," and the like, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended only to assist in the explanation of the invention. The preferred embodiments are not exhaustive or to limit the invention to the precise form disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best understand and utilize the invention. The invention is limited only by the claims and the full scope and equivalents thereof.
Claims (10)
1. The heat-insulating coating for the water-based color steel tile is characterized by comprising the following components in parts by weight: 35 to 45 parts of acrylic emulsion, 45 to 60 parts of polyurethane emulsion, 0.2 to 0.35 part of polydimethylsiloxane, 0.12 to 0.2 part of fluorosilicone, 1.6 to 2.3 parts of sodium hexametaphosphate, 2 to 4.5 parts of propylene glycol methyl ether acetate, 2.5 to 3.8 parts of nano silicon dioxide, 1.8 to 2.5 parts of nano zinc oxide, 2.0 to 3.5 parts of sericite, 1.5 to 2.5 parts of precipitated barium sulfate, 8 to 15 parts of functional additive, 0.7 to 1.2 parts of pigment, 0.5 to 0.8 part of thickener, 0.3 to 0.7 part of preservative, 0.3 to 0.6 part of ultraviolet absorber and 10 to 30 parts of deionized water.
2. The heat-insulating coating for the water-based color steel tile according to claim 1, wherein the preparation method of the functional additive comprises the following steps:
i, putting a matrix material into a proper amount of ethanol aqueous solution according to a material ratio of 0.06-0.15 g/mL, mixing and stirring uniformly, adding a modifier with the mass of 30-40% of that of the ethanol aqueous solution into the mixture, performing ultrasonic dispersion for 1-2 h, and performing magnetic stirring and dispersion for 2-3 h; after the dispersion is finished, soaking the mixture for 10 to 15 hours at room temperature; then sequentially carrying out suction filtration and acetone washing treatment, transferring the obtained filter material into a vacuum drying oven, drying the filter material for 7-9 h under the conditions that the temperature is 45-55 ℃ and the vacuum degree is 1.0MP, and storing the obtained solid powder for later use after the drying is finished;
wherein the concentration of the ethanol aqueous solution is 50-70%, and the ethanol solution also comprises 2.5-3.8% of octyl phenol polyoxyethylene ether and 8-15% of 2,2' -dihydroxy-4, 4' -dimethoxy benzophenone-5, 5' -sodium disulfonate by mass;
II, under the water bath condition of 30-40 ℃, slowly injecting a proper amount of methacrylic acid monomer into a reaction container containing the solid powder obtained in the step I in 2-3 h under stirring according to the dosage ratio of 0.02-0.03 g/mL, after the material mixing is finished, heating the obtained mixed material liquid to 35-50 ℃, and preserving heat at the temperature for reaction for 5-8 h; then the reaction temperature is raised to 65-80 ℃, and the reaction is carried out for 8-12 h at the temperature; after the reaction is finished, the obtained product components are stored for standby;
III, transferring the product component obtained in the step II into reaction equipment, slowly adding a reaction promoter with the mass of 1.2-4.5% of that of the matrix material at the stirring rate of 160-200 r/min, and then carrying out illumination and microwave treatment on the mixture in the reaction equipment; wherein the power of the microwave treatment is set to 2500W; mixing materials for 40-60 min at the speed of 120-200 r/min; after the material mixing is finished, the mixed material liquid in the reaction equipment is moved into a reaction kettle and stirred and reacts for 2 to 4 hours at the temperature of 50 to 70 ℃; after the reaction is finished, carrying out vacuum suction filtration on the components of the products in the reaction kettle; then respectively washing the obtained filter material with acetone, ethanol, toluene or ethyl acetate; finally, the obtained filter material is dried for 5 to 8 hours under the conditions of 0.8 to 1MPa and 45 to 60 ℃ in vacuum, and the obtained solid material is the finished functional additive.
3. The heat-insulating coating for the water-based color steel tile according to claim 1, wherein the preparation method of the matrix material is as follows: tetrabutyl titanate, absolute ethyl alcohol and glacial acetic acid are mixed according to the weight ratio of 12-15: 3 to 5:1, and then mixing and stirring uniformly according to the volume ratio of 2:1, dripping the obtained mixed solution into an aqueous solution of absolute ethyl alcohol with the concentration of 70-80% while stirring, then adjusting the pH value of the obtained mixed component to 3.2-4.0, and carrying out heat preservation reaction on the obtained mixed component at the temperature of 40-55 ℃ for 50-80 min; after the reaction is finished, adding hollow glass beads with the volume of 7-9 times and the particle size of 5-12 mu m into the obtained sol, and stirring and mixing for 60-90 min; after being uniformly mixed, the mixture is kept stand and aged for 10 to 15 hours, and is dried at the temperature of 90 to 100 ℃, after the drying is finished, the mixture is calcined at the high temperature of 500 to 580 ℃ for 2 to 3 hours, and then the mixture is naturally cooled to the room temperature, thus obtaining the finished product of the matrix material.
4. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the modifier is selected from any one of gamma- (methacryloyloxy) propyl trimethoxy silane, gamma-glycidol ether oxypropyl trimethoxy silane and 3-aminopropyl triethoxy silane.
5. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the reaction promoter is any one of 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2-hydroxy-2-methyl-1- [4- (2-hydroxy ethoxy) phenyl ] -1-acetone and 1-hydroxy cyclohexyl phenyl ketone.
6. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the thickener is selected from one of TT-935 of American Dow chemical and 425 and 450 of Haimin.
7. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the preservative is selected from K40 and A28S produced by German and Shumei company or LX150 and R640 produced by American Dow chemical industry.
8. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the pigment is any one of lemon yellow, phthalocyanine green, titanium white, titanium manganese brown, cobalt blue and titanium nickel yellow.
9. The heat-insulating paint for the water-based color steel tile, according to claim 1, is characterized in that: the ultraviolet absorber is selected from any one of benzotriazole mixture UV-1130 and hindered amine UV-123.
10. The method for preparing the heat insulation coating for the water-based color steel tile according to any one of claims 1 to 9, which is characterized by comprising the following steps:
firstly, accurately weighing all materials according to the formula amount, and then transferring sericite, precipitated barium sulfate and pigment into a grinding machine for grinding and dispersing until the fineness is less than or equal to 25 mu m; the obtained mixed powder is preserved for standby;
and step two, sequentially adding deionized water, sodium hexametaphosphate, polydimethylsiloxane and fluorosilicone into mixing equipment, uniformly mixing and stirring, adding the mixed powder obtained in the step one, uniformly mixing and stirring, adding the rest materials, continuously mechanically stirring uniformly, and filtering the mixture by using silk cloth with 120-150 meshes, wherein the obtained slurry is the finished product of the water-based heat-insulating paint for the color steel tile after the filtering is finished.
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