CN116273785A - Production process for realizing impact resistance of resin lens through hardening process - Google Patents

Production process for realizing impact resistance of resin lens through hardening process Download PDF

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Publication number
CN116273785A
CN116273785A CN202310322519.0A CN202310322519A CN116273785A CN 116273785 A CN116273785 A CN 116273785A CN 202310322519 A CN202310322519 A CN 202310322519A CN 116273785 A CN116273785 A CN 116273785A
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China
Prior art keywords
hardening
substrate
coating
lens
drying
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Pending
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CN202310322519.0A
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Chinese (zh)
Inventor
征平干
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Jiangsu Green Stone Optical Co ltd
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Jiangsu Green Stone Optical Co ltd
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Priority to CN202310322519.0A priority Critical patent/CN116273785A/en
Publication of CN116273785A publication Critical patent/CN116273785A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065After-treatment
    • B05D3/067Curing or cross-linking the coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/584No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00Polymeric substrate or laminate
    • B05D2201/02Polymeric substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2518/00Other type of polymers
    • B05D2518/10Silicon-containing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • B05D2601/24Titanium dioxide, e.g. rutile

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Surface Treatment Of Optical Elements (AREA)

Abstract

The invention discloses a production process for realizing the shock resistance of a resin lens through a hardening process, which comprises the following steps: providing a PR resin solidified and molded substrate, putting the substrate into a cleaning tank, treating the lens by a sodium hydroxide solvent, and drying the lens in a drying tunnel; the dried substrate sequentially enters a first hardening groove, a second hardening groove and a fourth hardening groove; the dried substrate is sent into a coating machine to coat a silicon dioxide film; putting the substrate plated with the film into a spin coater, spin-coating a photo-curing protective layer with the thickness of 3um, and putting the substrate under an ultraviolet lamp for photo-curing after spin coating; and (3) carrying out ultrasonic cleaning on the lens after the light fixation, and drying to obtain a finished lens product. According to the invention, three times of prime coating hardening and one time of surface coating hardening are adopted, and then vacuum coating and spin coating curing are matched, so that the resin lens has impact resistance, and the safety of the resin lens in the wearing process is improved.

Description

Production process for realizing impact resistance of resin lens through hardening process
Technical Field
The invention belongs to the technical field of resin lenses, and particularly relates to a production process for realizing the impact resistance of a resin lens through a hardening process.
Background
Resin lenses in the current market have certain impact safety performance compared with glass lenses, but have weaker impact resistance compared with PC lenses, and are still not safe enough in severe sports (such as basketball) and sudden anomalies (such as stones flying to the eyeballs). At present, film hardening is usually carried out on the surface of the lens, the film on the surface of the lens is also continuously updated, a silicon dioxide film material with the refractive index of 1.46 is mainly used in the domestic market, an organosilicon hardening liquid is prepared, the lens is subjected to vacuum ion coating after being treated, zirconium oxide, silicon oxide, aluminum fluoride and the like are mainly plated, but the plated film is low in durability, easy to oxidize, insufficient in durability and low in efficiency.
Aiming at the situation, the common resin lens has impact resistance through a plurality of hardening processes.
Disclosure of Invention
In view of the above, the technical problem to be solved by the present invention is to provide a production process for realizing the impact resistance of a resin lens by a hardening process, so as to avoid the trouble of single hardening method and insufficient impact resistance of the resin lens in the past.
In order to solve the technical problems, the invention discloses a production process for realizing the shock resistance of a resin lens through a hardening process, which comprises the following steps:
pre-hardening to provide a PR resin solidified and formed substrate, putting the substrate into a cleaning tank, treating the lens by a sodium hydroxide solvent, and drying the lens in a drying tunnel;
b, hardening once, wherein the dried substrate enters a first hardening groove, a first base coating hardening liquid is stored in the first hardening groove, and the substrate is subjected to base coating, uniform-speed lifting and drying, and then enters a drying tunnel for drying;
c, secondarily hardening, namely, putting the dried substrate into a second hardening groove, storing second primary coating hardening liquid in the second hardening groove, carrying out primary coating on the substrate, carrying out uniform-speed lifting, and then putting the substrate into a drying tunnel for drying;
step d, hardening for three times, wherein the dried lenses enter a third hardening groove, a third primary coating hardening liquid is stored in the third hardening groove, and the primary coating is uniformly pulled for the substrate, and then enters a drying tunnel for drying;
step e, hardening for four times, putting the dried lens into a fourth hardening groove, storing a fourth surface hardening liquid in the fourth hardening groove, carrying out uniform lifting on the substrate surface, and then putting the substrate surface into a drying tunnel for drying;
step f, vacuum coating, namely, feeding the dried substrate into a coating machine to coat a silicon dioxide film;
step g, spin coating and curing, namely placing the substrate plated with the film into a spin coater, spin coating a light curing protective layer with the thickness of 3um, and placing the substrate under an ultraviolet lamp for light curing after spin coating;
and h, cleaning, namely performing ultrasonic cleaning on the lens subjected to light fixation, and drying to obtain a finished lens product.
According to an embodiment of the present invention, the first primer hardening liquid comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent, and 10-50 parts of methanol, which are uniformly mixed.
According to an embodiment of the invention, the second primer hardening liquid is added with a mixed solution of titanium oxide nano particles and ultraviolet absorbent powder in the first primer hardening liquid, and the mass ratio of the mixed solution to the first primer hardening liquid is 1:6.
According to an embodiment of the present invention, the third primer hardening liquid and the first primer hardening liquid have the same composition.
According to an embodiment of the present invention, the fourth surface coating hard liquid comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent, 10-50 parts of methanol, and 6-25 parts of titanium oxide nanoparticle solution.
According to an embodiment of the present invention, the temperature of the hardening tank in the steps b to e is 50-60 ℃.
According to an embodiment of the present invention, any one or more of an antireflection film layer, a blue light preventing film layer, and an infrared preventing film layer is further plated in the step f.
Compared with the prior art, the invention can obtain the following technical effects:
the resin lens has shock resistance by adopting three times of primary coating hardening and one time of primary coating hardening, and then combining vacuum coating and spin coating curing, so that the safety of the resin lens in the wearing process is improved.
Of course, it is not necessary for any one product embodying the invention to achieve all of the technical effects described above at the same time.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention and do not constitute a limitation on the invention. In the drawings:
FIG. 1 is a flow chart of a process for producing impact resistance of a resin lens by a hardening process according to an embodiment of the present invention.
Detailed Description
The following detailed description of embodiments of the present invention will be given with reference to the accompanying drawings and examples, by which the implementation process of how the present invention can be applied to solve the technical problems and achieve the technical effects can be fully understood and implemented.
Referring to fig. 1, fig. 1 is a flow chart of a production process for realizing impact resistance of a resin lens by a hardening process according to an embodiment of the invention.
As shown in the drawing, a process for producing resin lenses having impact resistance by hardening includes:
pre-hardening to provide a PR resin solidified and formed substrate, putting the substrate into a cleaning tank, treating the lens by a sodium hydroxide solvent, and drying the lens in a drying tunnel;
b, hardening once, wherein the dried substrate enters a first hardening groove, a first base coating hardening liquid is stored in the first hardening groove, and the substrate is subjected to base coating, uniform-speed lifting and drying, and then enters a drying tunnel for drying;
c, secondarily hardening, namely, putting the dried substrate into a second hardening groove, storing second primary coating hardening liquid in the second hardening groove, carrying out primary coating on the substrate, carrying out uniform-speed lifting, and then putting the substrate into a drying tunnel for drying;
step d, hardening for three times, wherein the dried lenses enter a third hardening groove, a third primary coating hardening liquid is stored in the third hardening groove, and the primary coating is uniformly pulled for the substrate, and then enters a drying tunnel for drying;
step e, hardening for four times, putting the dried lens into a fourth hardening groove, storing a fourth surface hardening liquid in the fourth hardening groove, carrying out uniform lifting on the substrate surface, and then putting the substrate surface into a drying tunnel for drying;
step f, vacuum coating, namely, feeding the dried substrate into a coating machine to coat a silicon dioxide film;
step g, spin coating and curing, namely placing the substrate plated with the film into a spin coater, spin coating a light curing protective layer with the thickness of 3um, and placing the substrate under an ultraviolet lamp for light curing after spin coating;
and h, cleaning, namely performing ultrasonic cleaning on the lens subjected to light fixation, and drying to obtain a finished lens product.
In one embodiment of the invention, PR resin substrates are solidified and molded by PR resin materials, after demolding, the PR resin substrates are sent into a cleaning tank with sodium hydroxide solvent cleaning agent for surface cleaning, grease oil stains are taken out, then the PR resin substrates are dried and sent into a hardening machine, the hardening machine is provided with a plurality of hardening tanks, different hardening liquids are stored, and the hardening treatment of the surfaces of the substrates is completed through three times of bottom coating and one time of top coating. And (3) carrying out vacuum coating after hardening is finished, improving the functionality of the substrate, finally spin-coating a photo-curing protective layer to protect a surface film layer, and finally cleaning, packaging and leaving a warehouse.
In a preferred embodiment, the first primer hardening liquid comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent and 10-50 parts of methanol which are uniformly mixed. Further, 25 parts of silica sol, 15 parts of acetic acid, 10 parts of silane coupling agent and 35 parts of methanol are uniformly mixed to prepare first-grade base coating hardening liquid, the first-grade base coating hardening liquid is uniformly lifted in a hardening groove and fully soaked, so that a layer of compact hardening coating is attached to the surface of a lens, the silicon atoms can improve the hardness, and then the lens is dried to strengthen the adhesion.
The second primer hardening liquid is added with a mixed solution of titanium oxide nano particles and ultraviolet absorber powder in the first primer hardening liquid, the titanium oxide nano particles can be added to further improve the hardness of the lens, the adhesiveness is improved on the basis of the first primer hardening liquid, and the ultraviolet absorber powder can improve the radiation resistance of the substrate and is better in protection. Preferably, the mass ratio of the mixed solution to the first primer hardening liquid is 1:6.
The third primer hardening liquid and the first primer hardening liquid have the same components and are used for protecting the middle second primer hardening liquid, and simultaneously, the three layers of primers greatly enhance the shock resistance of the substrate.
The fourth surface coating hardening liquid comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent, 10-50 parts of methanol and 6-25 parts of titanium oxide nanoparticle solution. Preferably, 25 parts of silica sol, 12 parts of acetic acid, 9 parts of silane coupling agent, 35 parts of methanol and 12 parts of titanium oxide nanoparticle solution can be selected, and the silica sol is matched with the titanium oxide to realize the reinforcement of the hardness of the substrate and enhance the shock resistance.
The hardening groove temperature from step b to step e is 50-60 ℃, so that the attaching efficiency of the coating is improved.
And in the step f, any one or more of an antireflection film layer, a blue light prevention film layer and an infrared prevention film layer are also plated, so that the functionality is further enhanced.
In summary, the invention adopts three times of prime coating and one time of prime coating and then combines vacuum coating and spin coating curing to ensure that the resin lens has shock resistance and improve the safety of the resin lens in the wearing process.
While the foregoing description illustrates and describes the preferred embodiments of the present invention, it is to be understood that the invention is not limited to the forms disclosed herein, but is not to be construed as limited to other embodiments, and is capable of numerous other combinations, modifications and environments and is capable of changes or modifications within the scope of the inventive concept as described herein, either as a result of the foregoing teachings or as a result of the knowledge or technology in the relevant art. And that modifications and variations which do not depart from the spirit and scope of the invention are intended to be within the scope of the appended claims.

Claims (7)

1. A production process for realizing impact resistance of a resin lens by a hardening process, which is characterized by comprising the following steps:
pre-hardening to provide a PR resin solidified and formed substrate, putting the substrate into a cleaning tank, treating the lens by a sodium hydroxide solvent, and drying the lens in a drying tunnel;
b, hardening once, wherein the dried substrate enters a first hardening groove, a first base coating hardening liquid is stored in the first hardening groove, and the substrate is subjected to base coating, uniform-speed lifting and drying, and then enters a drying tunnel for drying;
c, secondarily hardening, namely, putting the dried substrate into a second hardening groove, storing second primary coating hardening liquid in the second hardening groove, carrying out primary coating on the substrate, carrying out uniform-speed lifting, and then putting the substrate into a drying tunnel for drying;
step d, hardening for three times, wherein the dried lenses enter a third hardening groove, a third primary coating hardening liquid is stored in the third hardening groove, and the primary coating is uniformly pulled for the substrate, and then enters a drying tunnel for drying;
step e, hardening for four times, putting the dried lens into a fourth hardening groove, storing a fourth surface hardening liquid in the fourth hardening groove, carrying out uniform lifting on the substrate surface, and then putting the substrate surface into a drying tunnel for drying;
step f, vacuum coating, namely, feeding the dried substrate into a coating machine to coat a silicon dioxide film;
step g, spin coating and curing, namely placing the substrate plated with the film into a spin coater, spin coating a light curing protective layer with the thickness of 3um, and placing the substrate under an ultraviolet lamp for light curing after spin coating;
and h, cleaning, namely performing ultrasonic cleaning on the lens subjected to light fixation, and drying to obtain a finished lens product.
2. The process for producing resin lenses with impact resistance according to claim 1, wherein the primary coating hardening liquid comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent and 10-50 parts of methanol which are uniformly mixed.
3. The process for producing the resin lens with impact resistance through the hardening process according to claim 2, wherein the second primer hardening liquid is added with a mixed solution of titanium oxide nano particles and ultraviolet absorbent powder in the first primer hardening liquid, and the mass ratio of the mixed solution to the first primer hardening liquid is 1:6.
4. The process for producing an impact resistance of a resin lens by a hardening process according to claim 2, wherein the third primer hardening liquid and the first primer hardening liquid have the same composition.
5. The process for producing impact resistance of resin lenses by hardening according to claim 1, wherein said four-sided coating solution comprises 5-30 parts of silica sol, 4-20 parts of acetic acid, 3-15 parts of silane coupling agent, 10-50 parts of methanol, and 6-25 parts of titanium oxide nanoparticle solution.
6. The process for producing resin lenses having impact resistance by hardening according to claim 1, wherein the hardening bath temperature in steps b to e is 50 to 60 ℃.
7. The process for producing resin lenses with impact resistance by hardening according to claim 1, wherein any one or more of an antireflection film layer, a blue light preventing film layer and an infrared preventing film layer are further plated in the step f.
CN202310322519.0A 2023-03-30 2023-03-30 Production process for realizing impact resistance of resin lens through hardening process Pending CN116273785A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107300728A (en) * 2017-07-31 2017-10-27 江苏淘镜有限公司 Shock resistance ultra-toughness polyurethane-base eyeglass
CN110632691A (en) * 2019-09-11 2019-12-31 江苏淘镜有限公司 Middle-folding blue-light-resistant impact-resistant lens and manufacturing process thereof
CN111732750A (en) * 2020-04-28 2020-10-02 南京米兰达视光科学研究院有限公司 Hardening method for medium and high refractive index resin lens
CN112578576A (en) * 2020-12-02 2021-03-30 明月镜片股份有限公司 Resin lens with high-hardness film layer structure and preparation method thereof
CN115521495A (en) * 2022-10-28 2022-12-27 上海康耐特光学有限公司 Impact-resistant photochromic resin lens and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107300728A (en) * 2017-07-31 2017-10-27 江苏淘镜有限公司 Shock resistance ultra-toughness polyurethane-base eyeglass
CN110632691A (en) * 2019-09-11 2019-12-31 江苏淘镜有限公司 Middle-folding blue-light-resistant impact-resistant lens and manufacturing process thereof
CN111732750A (en) * 2020-04-28 2020-10-02 南京米兰达视光科学研究院有限公司 Hardening method for medium and high refractive index resin lens
CN112578576A (en) * 2020-12-02 2021-03-30 明月镜片股份有限公司 Resin lens with high-hardness film layer structure and preparation method thereof
CN115521495A (en) * 2022-10-28 2022-12-27 上海康耐特光学有限公司 Impact-resistant photochromic resin lens and preparation method thereof

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