CN116254017A - Stretchable composite conductive ink and preparation method thereof - Google Patents
Stretchable composite conductive ink and preparation method thereof Download PDFInfo
- Publication number
- CN116254017A CN116254017A CN202310450339.0A CN202310450339A CN116254017A CN 116254017 A CN116254017 A CN 116254017A CN 202310450339 A CN202310450339 A CN 202310450339A CN 116254017 A CN116254017 A CN 116254017A
- Authority
- CN
- China
- Prior art keywords
- conductive ink
- melting
- low
- composite conductive
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 62
- 239000000956 alloy Substances 0.000 claims abstract description 62
- 239000002245 particle Substances 0.000 claims abstract description 32
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000009210 therapy by ultrasound Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 229910001152 Bi alloy Inorganic materials 0.000 claims description 34
- -1 indium chromium tin lead bismuth Chemical compound 0.000 claims description 17
- 229910052738 indium Inorganic materials 0.000 claims description 15
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- PSMFTUMUGZHOOU-UHFFFAOYSA-N [In].[Sn].[Bi] Chemical group [In].[Sn].[Bi] PSMFTUMUGZHOOU-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 229910000846 In alloy Inorganic materials 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- 230000005496 eutectics Effects 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052733 gallium Inorganic materials 0.000 claims description 6
- LBFKBYSVICSFQW-UHFFFAOYSA-N [In][Sn][Pb][Bi] Chemical compound [In][Sn][Pb][Bi] LBFKBYSVICSFQW-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000758 substrate Substances 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000012776 electronic material Substances 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 38
- 229910052797 bismuth Inorganic materials 0.000 description 13
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 11
- 229910052718 tin Inorganic materials 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 5
- 239000011231 conductive filler Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000001376 precipitating effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002042 Silver nanowire Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/12—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Parts Printed On Printed Circuit Boards (AREA)
- Conductive Materials (AREA)
Abstract
The invention discloses stretchable composite conductive ink and a preparation method thereof, and relates to the technical field of electronic material preparation. The stretchable composite conductive ink comprises the following raw materials in parts by weight: 50-75 parts of liquid metal and 25-50 parts of low-melting-point alloy particles. The preparation method comprises the following steps: firstly, preparing low-melting-point alloy particles by ultrasonic treatment; and then uniformly mixing the low-melting-point alloy particles with liquid metal to prepare the stretchable composite conductive ink. According to the invention, the low-melting-point alloy particles are added into the liquid metal, so that the surface tension of the liquid metal is obviously reduced while the good conductivity is ensured, and the prepared stretchable composite conductive ink can directly form conductive patterns on a flexible substrate, has good stretchability and conductivity and can adapt to various deformations. The material of the invention has simple preparation process, low production cost, easy process grasping and easy realization of large-scale production, and has great practical value.
Description
Technical Field
The invention relates to the technical field of electronic material preparation, in particular to stretchable composite conductive ink and a preparation method thereof.
Background
With the rapid development of current science and technology, it has been difficult for conventional rigid electronic devices to meet the needs of people, and flexible electronic devices capable of being in close contact with human bodies and highly fused are gradually moving into the lives of people. The flexible electronic device mainly comprises a flexible matrix and a flexible integrated circuit, and can still normally operate under the deformation of stretching, bending and the like compared with the traditional rigid electronic device, and has good application prospect in the fields of wearable electronic equipment, biomedicine and the like.
Integrated circuits in conventional rigid electronic devices often use high modulus metals such as copper and gold as conductive materials that are prone to cracking during deformation, resulting in circuit failure. Currently, integrated circuits in flexible electronic devices are mostly made of stretchable conductive inks as conductive materials by printing to build conductive paths on flexible substrates. Stretchable conductive ink is a composite material that is both stretchable and conductive. Conventional stretchable conductive inks typically incorporate conductive fillers (e.g., silver nanowires, silver nanoplates, carbon nanotubes, etc.) into elastomeric polymers to build continuous conductive paths within the polymer using the mutual contact between the conductive fillers. The stretchable conductive ink prepared by the method has good binding force with the flexible matrix due to the addition of the polymer, and is beneficial to forming a conductive path on the surface of the flexible matrix; however, it is difficult to maintain stable contact of the conductive filler during the tensile deformation, resulting in poor tensile conductive stability of the circuit; meanwhile, the common conductive filler has higher tensile modulus, and can limit the tensile property of the whole conductive ink.
The liquid metal has excellent conductivity and fluidity, is an excellent stretchable conductive material, and has great application potential in the aspect of flexible integrated circuits. However, the liquid metal has a large surface tension, which hinders wetting of the surface of the flexible substrate, thereby making it difficult to form a stable circuit pattern on the surface of the flexible substrate; meanwhile, the viscosity of the liquid metal is too low, and leakage is liable to occur. In order to solve the above problems, there are researchers that disperse liquid metal into fine particles coated with oxide film by ultrasonic treatment, then print the liquid metal fine particles onto the surface of a flexible substrate by inkjet printing, and then selectively sinter (mechanical sintering, laser sintering) to destroy the oxide film on the surface of the liquid metal, thereby forming a conductive pattern. The method can obtain very fine conductive patterns, and the liquid metal and the surface of the flexible matrix have better binding force, but the method has the advantages of multiple process steps, complex equipment and high manufacturing cost.
Therefore, developing a conductive ink which has high conductivity, stretchability, good binding force with a flexible substrate and can simply construct a circuit on the flexible substrate and a preparation method thereof are the problems which are needed to be solved in the technical field.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, provides stretchable composite conductive ink and a preparation method thereof, and effectively solves the problems that the stretchability and the conductivity of the conventional stretchable conductive ink are difficult to be compatible, and liquid metal is difficult to be directly patterned on the surface of a flexible matrix.
The invention solves the technical problems and adopts the following technical scheme:
the stretchable composite conductive ink comprises the following raw materials in parts by weight: 50-75 parts of liquid metal and 25-50 parts of low-melting-point alloy particles.
Also provided is a method for preparing the stretchable composite conductive ink, comprising the following steps:
(1) Preparation of low-melting-point alloy particles: heating the low-melting-point alloy to be melted, adding the low-melting-point alloy into an organic solvent, carrying out ultrasonic treatment, and then sequentially standing, filtering and drying to obtain low-melting-point alloy particles;
(2) Preparation of stretchable composite conductive ink: and (3) uniformly mixing the liquid metal and the low-melting-point alloy particles prepared in the step (1) to prepare the stretchable composite conductive ink.
Based on the technical scheme, the invention can also be improved as follows:
preferably, in the step (1), the low melting point alloy is indium tin bismuth alloy, indium chromium tin lead bismuth alloy, indium tin lead bismuth alloy, chromium lead bismuth alloy or chromium tin lead bismuth alloy.
Preferably, in the step (1), the low melting point alloy is indium tin bismuth alloy.
Preferably, the mass ratio of indium, tin and bismuth in the indium-tin-bismuth alloy is 50-55:30-35:15-20.
Preferably, the indium, tin and bismuth in the indium tin bismuth alloy have a mass ratio of 51:32.5:16.5.
preferably, the mass ratio of indium, chromium, tin, lead and bismuth in the indium-chromium-tin-lead-bismuth alloy is 18-20:4-6:7-9:20-25:40-50.
Preferably, the mass ratio of indium, chromium, tin, lead and bismuth in the indium-chromium-tin-lead-bismuth alloy is 19:5:8:23:45.
preferably, the mass ratio of indium, tin, lead and bismuth in the indium tin lead bismuth alloy is 20-22:10-15:15-20:47-50.
Preferably, the mass ratio of indium, tin, lead and bismuth in the indium tin lead bismuth alloy is 21:12:18:49.
preferably, the mass ratio of chromium, lead and bismuth in the chromium-lead-bismuth alloy is 5-10:38-42:50-55.
Preferably, the mass ratio of chromium, lead and bismuth in the chromium-lead-bismuth alloy is 8:40:52.
preferably, the mass ratio of chromium, tin, lead and bismuth in the chromium-tin-lead-bismuth alloy is 8-12:10-15:25-30:48-52.
Preferably, the mass ratio of chromium, tin, lead and bismuth in the chromium-tin-lead-bismuth alloy is 10:13:27:50.
preferably, in the step (1), when the low melting point alloy is indium tin bismuth alloy, the alloy is heated to be molten under the condition of 55-65 ℃.
Preferably, in the step (1), when the low melting point alloy is indium tin bismuth alloy, the alloy is heated to be melted at 60 ℃.
Preferably, in the step (1), when the low-melting-point alloy is indium-chromium-tin-lead-bismuth alloy, the alloy is heated to be molten at the temperature of 45-50 ℃.
Preferably, in the step (1), when the low-melting-point alloy is indium-chromium-tin-lead-bismuth alloy, the alloy is heated to be melted at 47 ℃.
Preferably, in the step (1), when the low-melting-point alloy is indium tin lead bismuth alloy, the alloy is heated to be molten at 57-65 ℃.
Preferably, in the step (1), when the low-melting-point alloy is indium-chromium-tin-lead-bismuth alloy, the alloy is heated to be melted at 57 ℃.
Preferably, in the step (1), when the low-melting-point alloy is chromium-lead-bismuth alloy, the alloy is heated to be molten at 92-100 ℃.
Preferably, in the step (1), when the low-melting-point alloy is chromium-lead-bismuth alloy, the alloy is heated to be melted at 92 ℃.
Preferably, in the step (1), when the low-melting-point alloy is chromium-tin-lead-bismuth alloy, the alloy is heated to be molten at the temperature of 70-80 ℃.
Preferably, in the step (1), when the low-melting-point alloy is chromium-tin-lead-bismuth alloy, the alloy is heated to be molten at 70 ℃.
Preferably, in step (1), the organic solvent is ethanol, isopropanol or methanol.
Preferably, in step (1), the organic solvent is ethanol.
Preferably, in step (1), the ultrasonic treatment is performed under heating.
Preferably, in step (1), the heating temperature is the same as the temperature at which the low melting point alloy is melted.
Preferably, in the step (1), the ultrasonic time is 20min, and the ultrasonic power is 500-700W.
Preferably, in the step (1), the mixture is kept stand for 20 to 30 hours.
Preferably, in the step (1), the mixture is dried at the temperature of 40-50 ℃ for 2.5-3.5 hours.
Preferably, in the step (2), the liquid metal is eutectic gallium-indium alloy, and the mass ratio of gallium to indium in the eutectic gallium-indium alloy is 70-80:20-30.
Preferably, in the step (2), the mass ratio of gallium to indium in the eutectic gallium-indium alloy is 75.5:24.5.
preferably, in the step (2), the mass ratio of the liquid metal to the low-melting-point alloy particles prepared in the step (1) is 50-75:25-50.
The invention also provides application of the stretchable composite conductive ink in preparation of flexible electronic devices.
The invention has the following beneficial effects:
1. according to the invention, the low-melting-point alloy particles are mixed in the liquid metal, so that the surface tension of the liquid metal is effectively reduced, the viscosity of the liquid metal is increased, the wetting effect of the liquid metal on the surface of the flexible substrate is improved, and a fine circuit pattern can be constructed on the surface of the flexible substrate through a simple printing process.
2. The stretchable conductive ink provided by the invention has excellent conductivity and stretchability, can ensure good conductive stability in the stretching deformation process, and overcomes the defect of poor conductive stability of the traditional stretchable conductive ink during stretching.
3. The material of the invention has simple preparation process, low production cost, easy process grasping and easy realization of large-scale production, and has great practical value.
Drawings
FIG. 1 is a flow chart of the preparation of the stretchable composite conductive ink of example 1;
FIG. 2 is an SEM image of low-melting alloy particles of example 1;
FIG. 3 is an SEM image of the stretchable composite conductive ink prepared in example 1;
FIG. 4 is a flexible integrated circuit of the stretchable composite conductive ink prepared in example 1;
fig. 5 is a graph showing the comparison of the tensile properties of the tensile composite conductive ink prepared in example 1 before and after the tensile properties.
Detailed Description
The principles and features of the present invention are described below with reference to the drawings, the examples are illustrated for the purpose of illustrating the invention and are not to be construed as limiting the scope of the invention. The specific conditions are not noted in the examples and are carried out according to conventional conditions or conditions recommended by the manufacturer. The reagents or apparatus used were conventional products commercially available without the manufacturer's attention.
Example 1:
the preparation method of the stretchable composite conductive ink comprises the following steps: (flow chart see FIG. 1)
(1) Heating indium-tin-bismuth alloy (the mass ratio of indium to tin to bismuth is 51:32.5:16.5) at 60 ℃ to melt, adding the alloy into ethanol solution, performing ultrasonic treatment for 20min at 60 ℃ under the conditions of heating and ultrasonic power of 600W, dispersing the alloy into particles, standing for 24h, completely precipitating the alloy particles, filtering, and drying at 45 ℃ for 3h to obtain low-melting-point alloy particles;
(2) Eutectic gallium-indium alloy (the mass ratio of gallium to indium is 75.5:24.5) and the low-melting-point alloy particles prepared in the step (1) are mixed according to the mass ratio of 3:1, stirring and mixing uniformly for multiple times rapidly to obtain the stretchable composite conductive ink.
Example 2:
the preparation method of the stretchable composite conductive ink comprises the following steps:
(1) Heating an indium-tin-bismuth alloy (the mass ratio of indium to tin to bismuth is 55:30:15) at 65 ℃ to melt, adding the alloy into an ethanol solution, performing ultrasonic treatment for 10min at the temperature of 65 ℃ and the ultrasonic power of 700W, dispersing the alloy into particles, standing for 30h, completely precipitating the alloy particles, filtering, and drying at 50 ℃ for 2.5h to obtain low-melting-point alloy particles;
(2) Eutectic gallium-indium alloy (the mass ratio of gallium to indium is 80:20) and the low-melting-point alloy particles prepared in the step (1) are mixed according to the mass ratio of 2:1, stirring and mixing uniformly for multiple times rapidly to obtain the stretchable composite conductive ink.
Example 3:
the preparation method of the stretchable composite conductive ink comprises the following steps:
(1) Heating an indium-tin-bismuth alloy (the mass ratio of indium to tin to bismuth is 50:30:20) at 55 ℃ to melt, adding the alloy into an ethanol solution, performing ultrasonic treatment at 55 ℃ and ultrasonic power of 500W for 10min, dispersing the alloy into particles, standing for 20h, completely precipitating the alloy particles, filtering, and drying at 40 ℃ for 3.5h to obtain low-melting-point alloy particles;
(2) Eutectic gallium-indium alloy (the mass ratio of gallium to indium is 70:30) and the low-melting-point alloy particles prepared in the step (1) are mixed according to the mass ratio of 1:1, stirring and mixing uniformly for multiple times rapidly to obtain the stretchable composite conductive ink.
Example 4:
the preparation method of the stretchable composite conductive ink comprises the following steps:
in the step (2), the mass ratio is 2:1, the remainder was the same as in example 1, to prepare a stretchable composite conductive ink.
Example 5:
the preparation method of the stretchable composite conductive ink comprises the following steps:
in the step (2), the mass ratio is 1:1, the remainder was the same as in example 1, to prepare a stretchable composite conductive ink.
Test examples
1. SEM examination was performed on the low melting point alloy particles and the stretchable composite conductive ink prepared in example 1, respectively, and the results are shown in fig. 2 to 3.
As can be seen from FIG. 2, the low melting point alloy particles prepared according to the present invention have a size of 1-5 microns.
As can be seen from fig. 3, the liquid metal and the low-melting-point alloy particles in the stretchable composite conductive ink prepared by the invention are well combined, and the low-melting-point alloy particles are uniformly dispersed in the liquid metal.
2. The stretchable composite conductive ink prepared in example 1 was patterned on a substrate by stencil printing, and then electronic components (resistors, LEDs, operational amplifiers) were mounted to prepare a flexible integrated circuit, the result of which is shown in fig. 4.
As can be seen from fig. 4, the stretchable composite conductive ink prepared by the present invention can be used to prepare conductive patterns on a flexible substrate by a simple printing process, and is well suited for application to flexible integrated circuits.
3. The stretchable composite conductive ink (3 cm) prepared in example 1 was attached to a flexible substrate and then stretched (20 cm), the results of which are shown in FIG. 5.
As can be seen from FIG. 5, the tensile composite conductive ink prepared by the invention has tight combination with the flexible substrate and stable morphology without generating defects such as cracks under the tensile strain of nearly 600%, which indicates that the tensile composite conductive ink prepared by the invention has excellent combination ability and good tensile property with the flexible substrate.
The foregoing description of the preferred embodiments of the invention is not intended to limit the invention to the precise form disclosed, and any such modifications, equivalents, and alternatives falling within the spirit and scope of the invention are intended to be included within the scope of the invention.
Claims (7)
1. The stretchable composite conductive ink is characterized by comprising the following raw materials in parts by weight: 50-75 parts of liquid metal and 25-50 parts of low-melting-point alloy particles.
2. The method of preparing a stretchable composite conductive ink according to claim 1, comprising the steps of:
(1) Preparation of low-melting-point alloy particles: heating the low-melting-point alloy to be melted, adding the low-melting-point alloy into an organic solvent, carrying out ultrasonic treatment, and then sequentially standing, filtering and drying to obtain low-melting-point alloy particles;
(2) Preparation of stretchable composite conductive ink: and (3) uniformly mixing the liquid metal and the low-melting-point alloy particles prepared in the step (1) to prepare the stretchable composite conductive ink.
3. The method of producing stretchable composite conductive ink according to claim 2, wherein in step (1), the low melting point alloy is indium tin bismuth alloy, indium chromium tin lead bismuth alloy, indium tin lead bismuth alloy, chromium lead bismuth alloy or chromium tin lead bismuth alloy.
4. The method of producing stretchable composite conductive ink according to claim 2, wherein in step (1), the organic solvent is ethanol, isopropanol or methanol.
5. The method of preparing a stretchable composite conductive ink according to claim 2, wherein in step (1), the ultrasonic treatment is performed under heating.
6. The method for preparing stretchable composite conductive ink according to claim 2, wherein in the step (2), the liquid metal is eutectic gallium-indium alloy, and the mass ratio of gallium to indium in the eutectic gallium-indium alloy is 70-80:20-30.
7. The method for preparing the stretchable composite conductive ink according to claim 2, wherein in the step (2), the mass ratio of the liquid metal to the low-melting-point alloy particles prepared in the step (1) is 50-75:25-50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310450339.0A CN116254017B (en) | 2023-04-24 | 2023-04-24 | Stretchable composite conductive ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310450339.0A CN116254017B (en) | 2023-04-24 | 2023-04-24 | Stretchable composite conductive ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN116254017A true CN116254017A (en) | 2023-06-13 |
| CN116254017B CN116254017B (en) | 2024-02-02 |
Family
ID=86688229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310450339.0A Active CN116254017B (en) | 2023-04-24 | 2023-04-24 | Stretchable composite conductive ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116254017B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118123886A (en) * | 2024-05-06 | 2024-06-04 | 四川大学 | Flexible clamping jaw with sensing function and clamping method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107578838A (en) * | 2017-08-17 | 2018-01-12 | 北京梦之墨科技有限公司 | Recyclable electrocondution slurry of a kind of low cost and preparation method thereof |
| CN108085519A (en) * | 2016-11-21 | 2018-05-29 | 云南科威液态金属谷研发有限公司 | A kind of method and its application that micro-nano granules are adulterated into liquid metal |
| CN108384327A (en) * | 2018-04-27 | 2018-08-10 | 国家纳米科学中心 | It stretches and causes the conductive electrically conductive ink based on liquid metal particle, preparation method and application |
| CN111863308A (en) * | 2019-04-30 | 2020-10-30 | 北京梦之墨科技有限公司 | Colored conductive paste, preparation method thereof and electronic device |
| US20210324219A1 (en) * | 2019-01-18 | 2021-10-21 | Henkel IP & Holding GmbH | Stretchable electrically conductive ink compositions |
-
2023
- 2023-04-24 CN CN202310450339.0A patent/CN116254017B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085519A (en) * | 2016-11-21 | 2018-05-29 | 云南科威液态金属谷研发有限公司 | A kind of method and its application that micro-nano granules are adulterated into liquid metal |
| CN107578838A (en) * | 2017-08-17 | 2018-01-12 | 北京梦之墨科技有限公司 | Recyclable electrocondution slurry of a kind of low cost and preparation method thereof |
| CN108384327A (en) * | 2018-04-27 | 2018-08-10 | 国家纳米科学中心 | It stretches and causes the conductive electrically conductive ink based on liquid metal particle, preparation method and application |
| US20210324219A1 (en) * | 2019-01-18 | 2021-10-21 | Henkel IP & Holding GmbH | Stretchable electrically conductive ink compositions |
| CN111863308A (en) * | 2019-04-30 | 2020-10-30 | 北京梦之墨科技有限公司 | Colored conductive paste, preparation method thereof and electronic device |
Non-Patent Citations (1)
| Title |
|---|
| WANG, JX, ET AL: "Printable Superelastic Conductors with Extreme Stretchability and Robust Cycling Endurance Enabled by Liquid-Metal Particles", ADVANCED MATERIALS, vol. 30, no. 16, pages 1 - 7, XP055546517, DOI: 10.1002/adma.201706157 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118123886A (en) * | 2024-05-06 | 2024-06-04 | 四川大学 | Flexible clamping jaw with sensing function and clamping method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116254017B (en) | 2024-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108384327B (en) | Stretching-induced conductive liquid metal particle-based conductive ink, and preparation method and application thereof | |
| CN116254017B (en) | Stretchable composite conductive ink and preparation method thereof | |
| CN106928773B (en) | Graphene composite conductive ink for ink-jet printing and preparation method thereof | |
| TWI420540B (en) | Conductive material formed using light or thermal energy and method for manufacturing the same, and nano-scale composition | |
| JP6563811B2 (en) | Transparent electrode and manufacturing method thereof | |
| WO2018098852A1 (en) | Low-temperature curable nano-metal ink, preparation method therefor and application thereof | |
| WO2020151346A1 (en) | Composite conductive silver paste and preparation method therefor | |
| CN109080281B (en) | Method for preparing flexible transparent conductive film based on wetting substrate fine ink-jet printing | |
| WO2022041518A1 (en) | Electrically conductive carbon paste for flexible pressure sensor and preparation method therefor, and pressure sensor | |
| CN108102464B (en) | Water-based nano-silver conductive ink capable of being sintered at room temperature, and preparation and application thereof | |
| JP2004247572A (en) | Method for forming fine wiring pattern | |
| CN115101237A (en) | Silver electrode conductive paste, silver electrode prepared from silver electrode conductive paste and electrothermal film | |
| CN102044309A (en) | Conductive material shaped through optical energy or heat energy, method for preparing conductive material and conductive composition | |
| US20220277866A1 (en) | Conductive paste, preparation method thereof, and preparation method of conductive film | |
| CN114833336B (en) | Printable liquid metal emulsion colloid and preparation method and application thereof | |
| CN113683921A (en) | Method for preparing microcircuit by printing liquid metal ink with commercial ink-jet printer and application thereof | |
| CN117866484B (en) | Liquid metal printing ink and preparation method thereof | |
| CN113284672B (en) | Preparation method of silver nanowire conductive paste | |
| JP5072228B2 (en) | Method for producing metal coating | |
| JP2010165594A (en) | Conductive paste and manufacturing method thereof, and circuit wiring using the same and manufacturing method thereof | |
| CN111570822A (en) | Nano silver powder and preparation method thereof | |
| CN113897096A (en) | Conductive printing ink for super-stretching material based on liquid metal-micron metal sheet and application thereof | |
| Fang et al. | Preparation and characterization of low temperature curing conductive silver paste for screen printing | |
| CN115881340A (en) | Flexible stretchable electrode with high conductive stability and preparation method thereof | |
| CN113539548A (en) | Preparation method of hollow silver nanotube conductive paste |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |