CN116221682A - String lamp and manufacturing method thereof - Google Patents

String lamp and manufacturing method thereof Download PDF

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Publication number
CN116221682A
CN116221682A CN202310122226.8A CN202310122226A CN116221682A CN 116221682 A CN116221682 A CN 116221682A CN 202310122226 A CN202310122226 A CN 202310122226A CN 116221682 A CN116221682 A CN 116221682A
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CN
China
Prior art keywords
sheath
parts
conductive pins
lamp
flame retardant
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Pending
Application number
CN202310122226.8A
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Chinese (zh)
Inventor
高荣庆
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Individual
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Individual
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Priority to CN202310122226.8A priority Critical patent/CN116221682A/en
Publication of CN116221682A publication Critical patent/CN116221682A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21SNON-PORTABLE LIGHTING DEVICES; SYSTEMS THEREOF; VEHICLE LIGHTING DEVICES SPECIALLY ADAPTED FOR VEHICLE EXTERIORS
    • F21S4/00Lighting devices or systems using a string or strip of light sources
    • F21S4/10Lighting devices or systems using a string or strip of light sources with light sources attached to loose electric cables, e.g. Christmas tree lights
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V25/00Safety devices structurally associated with lighting devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V25/00Safety devices structurally associated with lighting devices
    • F21V25/12Flameproof or explosion-proof arrangements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21YINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
    • F21Y2115/00Light-generating elements of semiconductor light sources
    • F21Y2115/10Light-emitting diodes [LED]

Abstract

The invention relates to a decorative string lamp, which comprises a plurality of lamp beads with at least two conductive pins, an electric wire for connecting the lamp beads, a separation block arranged between the at least two conductive pins of the lamp beads, and a sheath wrapping the joint of the at least two conductive pins and the electric wire. The sheath is a flexible sheath, and the raw materials of the sheath comprise the following components: 40-74 parts of ethylene-vinyl acetate copolymer or polyethylene resin or a mixture of the two, 5-20 parts of filler, 0.1-5 parts of ultraviolet initiator, 0.1-5 parts of cross-linking agent, 0.1-1 part of light stabilizer, 20-50 parts of flame retardant and 0.1-5 parts of lubricant. According to the sheath of the string lamp, the proportion of the ethylene-vinyl acetate copolymer or the polyethylene resin, the cross-linking agent, the light stabilizer, the flame retardant and the lubricant is reasonably configured, so that the voltage resistance of the prepared sheath reaches 1500V, and the flame retardant grade reaches above SC-1.

Description

String lamp and manufacturing method thereof
Technical Field
The invention relates to a decorative string lamp, in particular to a decorative string lamp and a manufacturing method thereof.
Background
The decorative string lamp is a strip-shaped decorative lamp composed of a plurality of lamp beads connected by wires, and is widely used for decoration of various holiday and shops and stores. The string light is flexible and bendable, so that the string light is very convenient to use. Meanwhile, the existing string lamp mostly adopts LED lamp beads, and generates heat greatly when in use, so that the requirements on connection between wires and pins of the lamp beads and protection devices are relatively high. The connection and protection device needs to be resistant to high pressure and flame. Existing connection and protection devices have both rigid and flexible sheaths. Wherein the flexible sheath cannot pass a 1500V voltage breakdown experiment, and the flame retardant grade is also insufficient.
Disclosure of Invention
The invention aims to provide a string lamp with a sheath with a withstand voltage reaching 1500V and a flame retardant grade reaching SC-1 and a manufacturing method thereof.
A string lamp comprises a plurality of lamp beads with at least two conductive pins, wires for connecting the lamp beads, a separation block arranged between the at least two conductive pins of the lamp beads, and a sheath wrapping the joint of the at least two conductive pins and the wires. The sheath is a flexible sheath, and the raw materials of the sheath comprise the following components:
40-74 parts of ethylene-vinyl acetate copolymer or polyethylene resin or a mixture of the two;
5-20 parts of filler;
0.1-5 parts of ultraviolet initiator;
0.1-5 parts of cross-linking agent;
0.1-1 part of light stabilizer;
20-50 parts of flame retardant;
0.1-5 parts of lubricant.
By adopting the technical scheme, the sheath can pass a 1500V voltage breakdown experiment, and the flame retardant grade reaches above SC-1. The sheath is not easy to crack after long-time use, and the service life is long.
The filler is used for improving the strength of the product and reducing the cost, and calcium carbonate, talcum powder and the like can be adopted.
The ultraviolet initiator determines the curing rate and the curing degree of the sheath, and has very important influence on the performance of the sheath. The ultraviolet initiator can be an organic carbonyl compound.
The crosslinking agent may be an allyl crosslinking agent.
The light stabilizer may be a hindered amine or piperidine compound.
The flame retardant can be one or more halogen-free environment-friendly flame retardants with nano aluminum hydroxide, nano magnesium hydroxide and bromine-antimony compounded flame retardant system and phosphorus nitrogen as flame retardant elements.
The lubricant may be one of stearic acid, a mixture of pentaerythritol mono/distearate, oxidized polyethylene wax.
As one embodiment, the raw materials of the sheath further comprise 0.1-5 parts of coupling agent. The coupling agent employs a silane coupling agent having a functional group such as at least one of vinyl, acryl, amino, chlorine, and phenoxy.
As one embodiment, the raw materials of the sheath can further comprise 0.1-5 parts of antioxidant.
The antioxidant can be hindered phenol antioxidant or phosphite antioxidant or both.
As one embodiment, the uv initiator is a cationic or free radical uv initiator.
A method of manufacturing a string light, comprising the steps of:
s1, providing an electric wire with a bare cell section, a lamp bead with at least two conductive pins, an isolation block and a sheath subjected to secondary expansion;
s2, electrically and physically connecting the conductive pins of the lamp beads with the corresponding exposed core sections of the wires;
s3, fixing the isolation block between at least two conductive pins of each lamp bead to prevent circuit breaking;
s4, cutting a sheath with preset length and sleeving the sheath at the joint of the lamp bead and the wire; and
s5, heating the sheath to shrink and tightly wrap the joint of the lamp bead and the wire.
Wherein the raw materials of the sheath are the same as the raw materials of the sheath.
As one embodiment, the method of providing the secondarily expanded sheath comprises:
s11, mixing the raw materials of the sheath and stirring uniformly to obtain a mixture; extruding the mixture into granules;
s12, extruding the particles into a hollow tubular object;
s13, performing cross-linking and curing on the hollow tubular object by utilizing ultraviolet light to form a primary sheath;
and S14, heating the primary sheath, and applying internal pressure to the primary sheath to expand the primary sheath in the radial direction to form the sheath subjected to secondary expansion.
As one embodiment, the heating temperature in step S14 and step S5 is 80-120 degrees.
According to the sheath of the string lamp, the proportion of the ethylene-vinyl acetate copolymer or the polyethylene resin to the filler, the cross-linking agent, the light stabilizer, the flame retardant and the lubricant is reasonably configured, so that the voltage resistance of the prepared sheath reaches 1500V, the flame retardant grade reaches SC-1 or above, and the UL certification standard in the United states is met.
Drawings
Fig. 1 is a schematic diagram of a string light according to an embodiment of the invention.
Fig. 2 is a cross-sectional view of the lamp bulb and a portion of the wire of the string light of fig. 1.
Description of the embodiments
The present invention will now be described in detail with reference to the drawings and examples, which are only preferred embodiments of the present invention and are not limiting thereof.
Referring to fig. 1, an LED string lamp mainly includes a power plug 10, an electric wire 20 with two ends electrically connected to the power plug 10, and a plurality of light emitting devices 30 electrically connected to the electric wire 20. Wherein the light emitting device 30 mainly comprises a lamp bead 31, a spacer 33 and a sheath 34.
The lamp bead 31 may include a chip and an LED lamp mounted on the chip, and two conductive pins 32 electrically connected to the chip and extending from one end of the lamp bead 32 are connected to the wires 20 and physically. The conductive pins 32 of the lamp beads 31 may be directly welded to the core wires of the electric wires 20, or may be connected together by a conductive fixture. The isolating block 33 is made of a non-conductive plastic material, and is disposed between the conductive pins 32 of the lamp bead 31, so that the two conductive pins 32 are electrically isolated from each other, and meanwhile, the connection portions of the two wires and the two conductive pins 32, and the exposed core wires of the two wires are electrically isolated from each other, so that the lamp bead 31 can normally light up without occurrence of a short circuit phenomenon when the wires 20 are electrified.
The sheath 34 is a heat-shrinkable flexible sheath, is non-conductive, is sleeved at the joint of the lamp bead 31 and the electric wire 20, tightly wraps all of the conductive pin 32 and the isolation block 33 and plays roles of insulating, fixing and preventing abrasion of the joint of the conductive pin 32 and the electric wire 20. It will be appreciated that the wire 20 is stripped from the conductive pin 32 and the sheath 34 should encapsulate all of the stripped exposed core wire and even a portion of the stripped wire to ensure the insulation of the circuit. Because the heat-shrinkable flexible sheath is adopted, the sheath 34 is tightly wrapped on the outer side, and the situation that the lamp beads fall off or the wires are torn off in the process of using the string lamp can be effectively prevented.
In the various examples and comparative examples, the raw material components of the sheath were calculated in terms of weight parts as shown in table 1.
The sheath is a sheath subjected to secondary expansion, and the manufacturing method thereof comprises the following steps S11 to S14.
S11, mixing the raw materials of the sheath, stirring uniformly to obtain a mixture, and processing the mixture into particles through extrusion.
S12, extruding the particles obtained in the step S11 into a hollow tubular object, wherein the wall thickness of the tubular object is between 0.2 and 0.4 mm.
And S13, performing cross-linking and curing on the hollow tubular object obtained in the step S12 by utilizing ultraviolet light to form a primary sheath.
S14, heating the primary sheath obtained in the step S13 to a temperature of about 100 ℃, and applying internal pressure to the primary sheath to expand the primary sheath in the radial direction to form a sheath subjected to secondary expansion.
The manufacturing method of the string light comprises steps S1 to S5.
S1, providing an electric wire with a bare core line segment, a lamp bead with two conductive pins, an isolation block and a sheath subjected to secondary expansion.
S2, electrically and physically connecting the conductive pins of the lamp beads with corresponding exposed core line segments of the electric wires.
S3, inserting the isolation block between the two conductive pins of each lamp bead to prevent circuit breaking.
S4, cutting a sheath with preset length and sleeving the sheath at the joint of the lamp bead and the electric wire.
S5, heating the sheath to shrink and tightly wrap the joint of the lamp bead and the wire. The heating temperature is about 110 ℃.
TABLE 1 jacket formulation table
Composition of the components Example 1 Example 2 Example 3 Example 4 Comparative example 1 Comparative example 2
Ethylene-vinyl acetate copolymer 63 50 40 40 40 36
Polyethylene resin 0 7 10 5 37 0
Filler (B) 10 10 5 5 5 5
Ultraviolet initiator 3 3 3 3 3 3
Crosslinking agent 0.5 1 1 1 2 2
Light stabilizers 1 0.5 0.5 0.5 0.5 2
Flame retardant 20 26 38 43 10 51
Lubricant 1 1 1 1 1 0.3
Coupling agent 1 1 1 1 1 0.3
Antioxidant 0.5 0.5 0.5 0.5 0.5 0.4
TABLE 2 sheath Voltage breakdown and flame retardance test Meter
Breakdown voltage (Tv) Flame retardant rating
Example 1 3491V Reach SC-1 grade
Example 2 2980V Reach SC-1 grade
Example 3 2573V Reach SC-1 grade
Example 4 1723V Reach SC-1 grade
Comparative example 1 4220V Can not reach the SC-1 grade
Comparative example 2 1230V Can not reach the SC-1 grade
Therefore, the voltage resistance of the jacket of the formula of the invention reaches 1500V, the flame retardant rating reaches SC-1 or above, and the UL certification standard in the United states is satisfied.
While the invention has been described in conjunction with the specific embodiments above, it is evident that many alternatives, modifications and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, all such alternatives, modifications, and variations are included within the spirit and scope of the following claims.

Claims (10)

1. A string light comprises a plurality of lamp beads with at least two conductive pins, electric wires for connecting the lamp beads, a separation block arranged between the at least two conductive pins of the lamp beads, and a sheath wrapping the connection part of the at least two conductive pins and the electric wires; the sheath is characterized by being a flexible sheath, and the raw materials of the sheath comprise the following components:
40-74 parts of ethylene-vinyl acetate copolymer or polyethylene resin or a mixture of the two;
5-20 parts of filler;
0.1-5 parts of ultraviolet initiator;
0.1-5 parts of cross-linking agent;
0.1-1 part of light stabilizer;
20-50 parts of flame retardant;
0.1-5 parts of lubricant.
2. The string light of claim 1, wherein the raw material of the sheath further comprises 0.1-5 parts of a coupling agent.
3. The string light of claim 1, wherein the raw material of the sheath further comprises 0.1-5 parts of an antioxidant.
4. The cluster of claim 1 wherein the uv initiator is a cationic uv initiator.
5. A method of manufacturing a string light, comprising the steps of:
s1, providing an electric wire with a bare core line segment, a lamp bead with at least two conductive pins, an isolation block and a sheath subjected to secondary expansion;
s2, electrically and physically connecting the conductive pins of the lamp beads with corresponding exposed core line segments of the electric wires;
s3, fixing the isolation block between at least two conductive pins of each lamp bead to prevent circuit breaking;
s4, cutting a sheath with preset length and sleeving the sheath at the joint of the lamp bead and the wire;
s5, heating the sheath to shrink and tightly wrap the joint of the lamp bead and the wire;
wherein the raw materials of the sheath comprise the following components:
40-74 parts of ethylene-vinyl acetate copolymer or polyethylene resin or a mixture of the two;
5-20 parts of filler
0.1-5 parts of ultraviolet initiator;
0.1-5 parts of cross-linking agent;
0.1-1 part of light stabilizer;
20-50 parts of flame retardant;
0.1-5 parts of lubricant.
6. The method of claim 5, wherein the starting material for the sheath further comprises 0.1-5 parts of a coupling agent.
7. The method of claim 1, wherein the raw material of the sheath further comprises 0.1-5 parts of an antioxidant.
8. The method of claim 1, wherein the ultraviolet initiator is a cationic ultraviolet initiator.
9. The method of claim 5, wherein the method of providing the secondarily expanded sheath comprises:
s11, mixing the raw materials of the sheath, uniformly stirring to obtain a mixture, and processing the mixture into particles by using an extruder;
s12, extruding the particles into a hollow tubular object;
s13, performing cross-linking and curing on the hollow tubular object by utilizing ultraviolet light to form a primary sheath;
and S14, heating the primary sheath, and applying internal pressure to the primary sheath to expand the primary sheath in the radial direction to form the sheath subjected to secondary expansion.
10. The method according to claim 10, wherein the heating temperature in step S14 and step S5 is 80-120 degrees.
CN202310122226.8A 2023-02-16 2023-02-16 String lamp and manufacturing method thereof Pending CN116221682A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310122226.8A CN116221682A (en) 2023-02-16 2023-02-16 String lamp and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310122226.8A CN116221682A (en) 2023-02-16 2023-02-16 String lamp and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN116221682A true CN116221682A (en) 2023-06-06

Family

ID=86586797

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310122226.8A Pending CN116221682A (en) 2023-02-16 2023-02-16 String lamp and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN116221682A (en)

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