CN116200733A - Metal material for plastic working - Google Patents
Metal material for plastic working Download PDFInfo
- Publication number
- CN116200733A CN116200733A CN202310185445.0A CN202310185445A CN116200733A CN 116200733 A CN116200733 A CN 116200733A CN 202310185445 A CN202310185445 A CN 202310185445A CN 116200733 A CN116200733 A CN 116200733A
- Authority
- CN
- China
- Prior art keywords
- film
- metal material
- acid
- plastic working
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007769 metal material Substances 0.000 title claims abstract description 92
- 239000004033 plastic Substances 0.000 title claims abstract description 43
- 229920003023 plastic Polymers 0.000 title claims abstract description 43
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 18
- 150000003839 salts Chemical class 0.000 claims abstract description 18
- 150000002978 peroxides Chemical class 0.000 claims abstract description 14
- 239000002344 surface layer Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims description 44
- 239000011248 coating agent Substances 0.000 claims description 43
- 238000003786 synthesis reaction Methods 0.000 claims description 13
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 150000003863 ammonium salts Chemical group 0.000 claims description 2
- 229910003002 lithium salt Inorganic materials 0.000 claims description 2
- 159000000002 lithium salts Chemical class 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims 1
- 150000003891 oxalate salts Chemical class 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 230000004927 fusion Effects 0.000 abstract description 12
- 238000003466 welding Methods 0.000 abstract description 11
- 238000000034 method Methods 0.000 description 49
- 239000012756 surface treatment agent Substances 0.000 description 31
- -1 alkali metal salt Chemical class 0.000 description 28
- 238000001035 drying Methods 0.000 description 28
- 239000003795 chemical substances by application Substances 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 20
- 238000004140 cleaning Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000007747 plating Methods 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000008399 tap water Substances 0.000 description 8
- 235000020679 tap water Nutrition 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- 238000005242 forging Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- KVZUCOGWKYOPID-UHFFFAOYSA-N 2,4,5-Trimethoxybenzoic acid Chemical compound COC1=CC(OC)=C(C(O)=O)C=C1OC KVZUCOGWKYOPID-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 229940039748 oxalate Drugs 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 238000005491 wire drawing Methods 0.000 description 4
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000013527 degreasing agent Substances 0.000 description 3
- 238000005237 degreasing agent Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- QENJZWZWAWWESF-UHFFFAOYSA-N 2,4,5-trimethylbenzoic acid Chemical compound CC1=CC(C)=C(C(O)=O)C=C1C QENJZWZWAWWESF-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
- LBKFGYZQBSGRHY-UHFFFAOYSA-N 3-hydroxy-4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1O LBKFGYZQBSGRHY-UHFFFAOYSA-N 0.000 description 2
- SKBDLRWFSRLIPP-UHFFFAOYSA-N 4,5-Dimethoxy-1,2-benzenedicarboxylic acid Chemical compound COC1=CC(C(O)=O)=C(C(O)=O)C=C1OC SKBDLRWFSRLIPP-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ILUJQPXNXACGAN-UHFFFAOYSA-N O-methylsalicylic acid Chemical compound COC1=CC=CC=C1C(O)=O ILUJQPXNXACGAN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- CMMUKUYEPRGBFB-UHFFFAOYSA-L dichromic acid Chemical compound O[Cr](=O)(=O)O[Cr](O)(=O)=O CMMUKUYEPRGBFB-UHFFFAOYSA-L 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000007603 infrared drying Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- JMSVCTWVEWCHDZ-UHFFFAOYSA-N syringic acid Chemical compound COC1=CC(C(O)=O)=CC(OC)=C1O JMSVCTWVEWCHDZ-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
- PUCYIVFXTPWJDD-UHFFFAOYSA-N 1,6-dihydroxycyclohexa-2,4-dienecarboxylic acid Chemical compound OC1C=CC=CC1(O)C(O)=O PUCYIVFXTPWJDD-UHFFFAOYSA-N 0.000 description 1
- FODBVCSYJKNBLO-UHFFFAOYSA-N 2,3-dimethoxybenzoic acid Chemical compound COC1=CC=CC(C(O)=O)=C1OC FODBVCSYJKNBLO-UHFFFAOYSA-N 0.000 description 1
- FFFIRKXTFQCCKJ-UHFFFAOYSA-N 2,4,6-trimethylbenzoic acid Chemical compound CC1=CC(C)=C(C(O)=O)C(C)=C1 FFFIRKXTFQCCKJ-UHFFFAOYSA-N 0.000 description 1
- DSIWIQXUFAAPJH-UHFFFAOYSA-N 2-(carboxymethyl)benzoic acid Chemical compound OC(=O)CC1=CC=CC=C1C(O)=O.OC(=O)CC1=CC=CC=C1C(O)=O DSIWIQXUFAAPJH-UHFFFAOYSA-N 0.000 description 1
- OWBVULKHVZHYPN-UHFFFAOYSA-N 3,4,5-trimethylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC(C)=C1C OWBVULKHVZHYPN-UHFFFAOYSA-N 0.000 description 1
- DAUAQNGYDSHRET-UHFFFAOYSA-N 3,4-dimethoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1OC DAUAQNGYDSHRET-UHFFFAOYSA-N 0.000 description 1
- QNUWEXSGZVBMDV-UHFFFAOYSA-N 3-(carboxymethyl)benzoic acid Chemical compound OC(=O)CC1=CC=CC(C(O)=O)=C1 QNUWEXSGZVBMDV-UHFFFAOYSA-N 0.000 description 1
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 1
- REIDAMBAPLIATC-UHFFFAOYSA-N 4-methoxycarbonylbenzoic acid Chemical compound COC(=O)C1=CC=C(C(O)=O)C=C1 REIDAMBAPLIATC-UHFFFAOYSA-N 0.000 description 1
- NJESAXZANHETJV-UHFFFAOYSA-N 4-methylsalicylic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1 NJESAXZANHETJV-UHFFFAOYSA-N 0.000 description 1
- KNKSRGZIOIPESF-UHFFFAOYSA-N 4-oxalobenzoic acid terephthalic acid Chemical compound C(=O)(O)C(=O)C1=CC=C(C(=O)O)C=C1.C(C1=CC=C(C(=O)O)C=C1)(=O)O KNKSRGZIOIPESF-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GPVDHNVGGIAOQT-UHFFFAOYSA-N Veratric acid Natural products COC1=CC=C(C(O)=O)C(OC)=C1 GPVDHNVGGIAOQT-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 229940021013 electrolyte solution Drugs 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 238000009778 extrusion testing Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229960005219 gentisic acid Drugs 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000002363 hafnium compounds Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- AWKHTBXFNVGFRX-UHFFFAOYSA-K iron(2+);manganese(2+);phosphate Chemical compound [Mn+2].[Fe+2].[O-]P([O-])([O-])=O AWKHTBXFNVGFRX-UHFFFAOYSA-K 0.000 description 1
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- 229910000159 nickel phosphate Inorganic materials 0.000 description 1
- JOCJYBPHESYFOK-UHFFFAOYSA-K nickel(3+);phosphate Chemical compound [Ni+3].[O-]P([O-])([O-])=O JOCJYBPHESYFOK-UHFFFAOYSA-K 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 102200082907 rs33918131 Human genes 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- IZUPJOYPPLEPGM-UHFFFAOYSA-M sodium;hydron;phthalate Chemical compound [Na+].OC(=O)C1=CC=CC=C1C([O-])=O IZUPJOYPPLEPGM-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002335 surface treatment layer Substances 0.000 description 1
- YIBXWXOYFGZLRU-UHFFFAOYSA-N syringic aldehyde Natural products CC12CCC(C3(CCC(=O)C(C)(C)C3CC=3)C)C=3C1(C)CCC2C1COC(C)(C)C(O)C(O)C1 YIBXWXOYFGZLRU-UHFFFAOYSA-N 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 description 1
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- OSKILZSXDKESQH-UHFFFAOYSA-K zinc;iron(2+);phosphate Chemical compound [Fe+2].[Zn+2].[O-]P([O-])([O-])=O OSKILZSXDKESQH-UHFFFAOYSA-K 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/22—Carboxylic acids or their salts
- C10M105/28—Carboxylic acids or their salts having only one carboxyl group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/22—Carboxylic acids or their salts
- C10M105/30—Carboxylic acids or their salts having more than one carboxyl group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
- Lubricants (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The technical problem of the present invention is to provide a metal material for plastic working having excellent resistance to fusion welding. The above-described problems can be solved by the metal material for plastic working of the present invention, which comprises a1 st film on the surface of the metal material, a2 nd film on the surface or surface of the 1 st film, wherein the 2 nd film is a surface layer, and the 2 nd film comprises a compound having a benzene ring directly bonded to at least 1 carboxyl group, or a salt thereof, or a peroxide thereof.
Description
The present application is a divisional application of the patent application of the invention with the application number 201980014024.3, the application date of the original application is 2019, 2 and 22, and the name of the present application is "metal material for plastic working".
Technical Field
The present invention relates to a metal material for plastic working, which has a coating film required for plastic working such as forging (including cold, warm, hot forging), wire drawing, and tube drawing of a steel material or other metal material.
Background
In plastic working of a metal material, fusion welding may occur between a die and the metal material for plastic working. Not only can the intended molded article not be obtained by fusion welding, but also the size of the mold is changed due to the influence of the fusion welded metal, so that the usable times of the mold are shortened. Therefore, the mold has to be remanufactured, resulting in a cost-effective reduction. Therefore, a metal material for plastic working having excellent weld resistance is required.
For example, patent document 1 discloses a lubricant for warm plastic working and thermoplastic working, which contains an alkali metal salt of an aromatic carboxylic acid compound having 2 or more carboxyl groups, several water-soluble polymer compounds, and water.
Patent document 2 discloses a lubricant for warm forging and hot forging, which contains a specific compound obtained by bonding 2 aromatic rings having 2 carboxyl groups located in ortho-positions.
Patent document 3 discloses a lubricant composition for aqueous cold plastic working, which contains an aromatic carboxylate having a melting point of 90 ℃ or higher, which is formed of sodium hydroxide or potassium hydroxide, a water-soluble polymer compound and/or wax, and water.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open No. 2015-89938;
patent document 2: japanese patent laid-open No. 2015-89939;
patent document 3: japanese patent application laid-open No. 2015-17171.
Disclosure of Invention
Problems to be solved by the invention
The purpose of the present invention is to provide a metal material for plastic working that has excellent fusion welding resistance.
Solution for solving the problem
The present inventors have made intensive studies to solve the above problems, and as a result, have found a metal material for plastic working having excellent fusion welding resistance, which has a1 st film on the surface or the surface of the metal material, a2 nd film on the surface or the surface of the 1 st film, the 2 nd film being a surface layer, and the 2 nd film comprising a compound having a benzene ring directly bonded to at least 1 carboxyl group or a salt thereof, or a peroxide thereof, thereby completing the present invention.
The invention (1) is a metal material for plastic working,
which has a1 st film on the surface or surface of a metal material,
the 1 st film has a2 nd film on the surface or the surface,
the 2 nd coating is a surface layer,
the 2 nd film contains a compound having a benzene ring directly bonded to at least 1 carboxyl group or a salt thereof, or a peroxide thereof.
Effects of the invention
According to the present invention, it is possible to provide a metal material for plastic working that is excellent in the effect of preventing fusion welding (fusion welding resistance) caused by friction between a mold and a metal material for forming working, which occurs during plastic working.
Drawings
Fig. 1 is a graph showing the evaluation criteria for the fusion welding resistance of the test piece subjected to the workability evaluation test (using photographs as the drawing).
Detailed Description
The following describes the present invention in detail.
< Metal Material for Plastic working >
The metal material for plastic working according to an embodiment of the present invention includes: the metal material, the 1 st film on the surface or surface of the metal material, and the 2 nd film on the surface or surface of the 1 st film, wherein the 2 nd film comprises a compound having a benzene ring directly bonded to at least 1 carboxyl group or a salt thereof, or a peroxide thereof. Further, between the 1 st film and the 2 nd film, a single layer or a plurality of layers of laminated films may be provided, as long as the 2 nd film is present in the surface layer.
The plastic working in the present specification is not particularly limited as long as it is a known plastic working, and examples thereof include: forging (cold, warm, hot), extrusion processing, wire drawing processing, tube drawing processing, rolling processing, bending processing, joining processing, shearing processing, shaping processing, and the like. Among them, the metal material for plastic working of the present invention is preferably used for plastic working such as forging, wire drawing and tube drawing, in which a load applied to the metal material is particularly large.
1. Composition of metal material for plastic working
1-1 metallic Material
The metal material is not particularly limited, and is generally a metal material used for plastic working. Examples thereof include: iron, iron alloy (steel, stainless steel, etc.), aluminum alloy, magnesium alloy titanium, titanium alloys, copper alloys, tin alloys, zinc alloys, and the like.
The metal material may be a plating material having a plating film as long as the effect of the present invention is not impaired. The material of the plating film is not particularly limited, and for example, can be used: metals such as nickel, iron, aluminum, manganese, chromium, magnesium, cobalt, lead, zinc, tin, and antimony, or alloys of a plurality of metals, and further, metals containing unavoidable impurities or alloys of a plurality of metals can be used.
In the case of artificially forming a plating film, a known method can be used as a forming method thereof, and examples thereof include: electroplating (electrolytic plating, electroplating), electroless plating, hot dip plating, vapor phase plating, mechanical plating, thermal spraying, and the like.
The thickness of the plating film is not particularly limited, and is, for example, 0.1 μm or more and 1000 μm or less.
Further, an oxide film may be formed on the surface of the metal material. The oxide film is not particularly limited, and may be a natural oxide film naturally generated in the atmosphere or an artificially formed oxide film.
The method for forming the artificial oxide film is not particularly limited, and examples thereof include: a method of anodic oxidation by energizing a metal material as an anode in an electrolyte solution, a method of immersing in a strongly acidic liquid, a method of utilizing electrolytic polishing, a method of utilizing plasma electrolysis, and the like. The oxide film may be subjected to sealing treatment by a steam method, a pure water boiling method, a nickel acetate method, a dichromate method, a sodium silicate method, or the like.
The thickness of the oxide film is not particularly limited, and is, for example, 0.001 μm or more and 100 μm or less.
The shape of the metal material is not limited to a blank shape such as a bar-shaped material or a block-shaped material, and may be a processed shape (such as a gear or a shaft), and is not particularly limited.
1-2. 1 st film
The 1 st film is not particularly limited, and for example, a chemical synthetic film, a coating film, or the like can be used.
1-2-1 chemical synthetic film
Examples of the film deposition mechanism of the chemical synthesis treatment are as follows. When the metal material is brought into contact with the chemical synthesis treating agent, the surface of the metal material is treated as H of an acid component (etching component) in the chemical synthesis treating agent + Ion etching (dissolution) thereby increases the pH near the surface. The pH in the vicinity of the surface increases, and thus, the etched metal component and the component contained in the chemical synthesis processing liquid in the metal material in the vicinity of the surface are precipitated as insoluble salts on the surface of the metal material. The insoluble salt forms a coating.
The chemical composition film is not particularly limited, and is composed of, for example, a phosphate, an oxalate, an aluminate, a chromate, a molybdate, a zirconium compound, a titanium compound, a vanadium compound, a hafnium compound, or the like. In addition, they may be composed of a single salt or may be composed of a plurality of salts. The chemical synthetic film is preferably composed of phosphate, oxalate, or aluminate, more preferably zinc phosphate, or iron oxalate.
The phosphate is not particularly limited, and examples thereof include: zinc phosphate, zinc iron phosphate, nickel phosphate, manganese phosphate, iron manganese phosphate, calcium phosphate, cobalt phosphate, magnesium phosphate, aluminum phosphate, sodium phosphate, potassium phosphate, ammonium phosphate, and the like. In the case where the metal material is steel, stainless steel or the like, the phosphate is preferable.
The oxalate is not particularly limited, and examples thereof include: sodium oxalate, potassium oxalate, iron oxalate, ammonium oxalate, and the like. In the case where the metal material is stainless steel or the like, the oxalate is preferable.
The aluminate is not particularly limited, and examples thereof include: lithium aluminate, sodium aluminate, potassium aluminate, magnesium aluminate, calcium aluminate, and the like. In the case where the metal material is aluminum or an aluminum alloy, the aluminate is preferable.
The amount of the chemical synthetic film to be adhered is not particularly limited, and is, for example, 0.5g/m 2 Above and 20.0g/m 2 Hereinafter, it is preferably 2.0g/m 2 Above and 10.0g/m 2 The following is given. The amount of the adhesion can be adjusted by changing the composition, concentration, etc. of the chemical synthesis treatment agent, or changing the contact conditions such as the contact method, the contact temperature, the contact time, etc.
1-2-2. Film coating
The coating film is a film formed by applying a coating agent to the surface of a metal material.
The material of the coating film is not particularly limited as long as it can be formed on the surface or the surface of the metal material of the present embodiment and the 2 nd coating film can be formed on the surface or the surface. Examples of the coating film formed using the coating agent include: a coating film formed by performing a coating type chromate treatment with a treatment liquid containing chromic acid, dichromic acid or a salt thereof as a main component; a coating film formed by a coating type chromate-free treatment without chromic acid or dichromic acid; a coating film formed from a silane coupling agent monomer; a coating film of silica, silica colloid, or the like modified with a silane coupling agent or the like; organic resin films including urethane resins, epoxy resins, acrylic resins, olefin resins such as polyethylene, polypropylene and ethylene-acrylic acid copolymers, styrene resins such as polystyrene, polyesters, copolymers or modified products thereof, and the like; inorganic films (except for plated films and oxide films) containing lithium silicate, glass such as sodium silicate, metal oxysalt, metal hydroxide, metal phosphate, fluorinated metal compound, and the like; a coating film obtained by dispersing a lubricant in a solvent such as water or oil or a base polymer comprising a copolymer of styrene and maleic acid/maleic anhydride.
The solid lubricant is not particularly limited, and examples thereof include: waxes such as polyethylene wax and polypropylene wax; layered clay minerals such as montmorillonite, vermiculite, mica, brittle mica, pyrophyllite, and kaolinite; polytetrafluoroethylene; fatty acid metal soaps and fatty acid amides; molybdenum disulfide; tungsten disulfide; graphite; melamine cyanurate, and the like.
1-3 nd film
1-3-1. Material
The 2 nd film of the present embodiment includes at least one or more of the following: a compound having a benzene ring directly bonded to at least 1 carboxyl group in the structure, or a salt thereof, or a peroxide thereof. In this specification, a compound having a benzene ring directly bonded to at least 1 carboxyl group is sometimes described as an aromatic carboxylic acid compound.
The benzene ring in the present invention refers to a compound having 1 benzene ring alone as in the case of a benzene compound, but is not limited thereto, and includes a condensed polycyclic aromatic hydrocarbon in which a plurality of benzene rings are directly condensed, such as naphthalene and anthracene.
The aromatic carboxylic acid compound is not particularly limited as long as the effect of the present invention is not impaired, and examples thereof include: pyromellitic acid, xylenoic acid, mellitic acid, trimesic acid (mesitylenic acid), 2,3, 4-trimethylbenzoic acid (prehnitic acid), durylic acid (durylic acid), beta-isodurylic acid, alpha-isodurylic acid, anisoic acid, o-methylsalicylic acid (o-cresotylic acid), meta-methylsalicylic acid, p-methylsalicylic acid, o-pyrocatecholic acid, beta-resorcinol acid (beta-resorcylic acid), gentisic acid, gamma-resorcinol acid, protocatechuic acid, alpha-resorcinol acid, vanillic acid, isovanillic acid, veratric acid, 2, 3-dimethoxybenzoic acid, glycosidic acid, meta-hemi-pinic acid (m-hemi-acrylic acid), gallic acid, syringic acid, asaronic acid (asaronic acid), homophthalic acid (homophthalic acid), homoisophthalic acid, homoterephthalic acid, phthalamic acid, isophthalic acid, terephthalic acid (terephthalonic acid), terephthalic acid, benzoic acid, salicylic acid (Wu Weite), benzoic acid, etc. These may be contained alone or in combination.
Among the salts of the aromatic carboxylic acid compounds, ammonium salts, sodium salts, lithium salts, and potassium salts of the above aromatic carboxylic acid compounds are more preferable, which are excellent in the effect of preventing fusion welding (fusion welding resistance) at the time of plastic working.
In addition, in the case where a plurality of carboxyl groups are directly bonded to the benzene ring, at least a part of the salt of the aromatic carboxylic acid compound may be formed, or all of the salt may be formed. For example, in the case of the sodium salt of phthalic acid having two carboxyl groups, sodium hydrogen phthalate in which one-side carboxyl groups are salified with sodium, and disodium phthalate in which both-side carboxyl groups are salified with sodium may be contained.
The peroxide of the aromatic carboxylic acid compound is a compound having a peroxide structure in at least one of carboxyl groups directly bonded to a benzene ring of the aromatic carboxylic acid compound. For example, in the case where the aromatic carboxylic acid compound is benzoic acid, the peroxide thereof is benzoic acid peroxide.
In the case where a plurality of carboxyl groups are directly bonded to the benzene ring, at least a part of the peroxide of the aromatic carboxylic acid compound may have a peroxide structure.
The aromatic carboxylic acid compound, the salt thereof, or the peroxide thereof is not necessarily contained in the raw material, and may be contained in the formed 2 nd film. For example, an acid anhydride of a carboxylic acid directly bonded to a benzene ring (for example, phthalic anhydride) is reacted with water or an alcohol to produce a compound having a benzene ring bonded to a carboxyl group.
The content of the aromatic carboxylic acid compound in the 2 nd film is not particularly limited, and the 2 nd film may contain a compound other than the aromatic carboxylic acid compound, for example, other resins, within a range that does not impair the effects of the present invention. When the 2 nd film contains a compound other than the aromatic carboxylic acid compound, the content of the aromatic carboxylic acid compound in the 2 nd film may be 0.5 wt% or more, preferably 10 wt% or more. The 2 nd film may be formed of only the aromatic carboxylic acid compound.
1-4. A coating comprised between the 1 st coating and the 2 nd coating
The metal material for plastic working may include a film in which a single layer or a plurality of layers are laminated between the 1 st film and the 2 nd film.
The type, material, combination of materials, combination of film treatment methods, number of layers, thickness of each film, and the like included between the 1 st film and the 2 nd film are not particularly limited as long as the effects of the present invention are not impaired.
The film included between the 1 st film and the 2 nd film may include a chemical synthetic film, a coating film, a plating film, an oxide film, and the like. For example, a vapor phase plating such as vapor deposition may be used to form a plated film on the 1 st film, and then further form an chemical synthetic film on the plated film.
2. Method for producing metal material for plastic working
A method for producing a metal material for plastic working according to another embodiment of the present invention includes: a1 st film forming step of forming a1 st film on at least the surface or the surface of the metal material; and a2 nd film forming step of forming a2 nd film on the surface or the surface of the 1 st film.
The washing step may be included before and after each step in the 1 st film forming step, or the drying step may be included after the 1 st film is formed. In the 2 nd film forming step, the water washing step may be included before and after each step, or the drying step may be included after the 2 nd film is formed. Further, when the surface treatment layer is formed between the 1 st film and the 2 nd film, a water washing step may be included between the steps, or a drying step may be included after the film is formed.
Further, the method may include a step of forming a single-layer or multi-layer laminated film after the 1 st film is formed and before the 2 nd film is formed, as necessary.
Further, the cleaning step may be included before and after each step. The cleaning step may be performed a plurality of times.
2-1. Step 1 film formation step
The 1 st film forming step may include at least one of a chemical composition film forming step and a coating film forming step.
2-1-1 chemical synthetic film Forming step
The chemical synthesis film forming step includes at least a contact step of: the chemical synthesis treating agent is brought into contact with the surface of the metal material to form a1 st film as a chemical synthesis film. As the contact method, a known method can be used, and is not particularly limited. Examples thereof include: electrolytic treatment by applying an electric current, and treatment by immersing, spraying, sprinkling, or the like without applying an electric current.
The (contact) temperature of the metal material and the chemical synthesis treating agent is not particularly limited, for example: preferably 10℃to 98℃and more preferably 20℃to 50 ℃.
The contact time is not particularly limited, and is preferably, for example, 30 to 300 seconds, more preferably 60 to 180 seconds.
2-1-2 step of Forming coating film
The coating film forming step includes at least the steps of: the 1 st coating film is formed as a coating film by bringing a treating agent for forming a coating film into contact with the surface or on the surface of a metal material. As the contact method, a known method can be used, and is not particularly limited. The coating film can be formed by applying, for example, a roll method, a dipping method, a flow coating method, a spray method, a brush coating method, an electrostatic coating liquid method, a bar coating, a powder coating, or the like. More specifically, for example, when the metal material is in the form of a sheet, a roll coating method or a spray coating method is preferably performed. In addition, if the metal material is a molded article, the impregnation method is preferably performed. In the case where the raw material contains a solid, the solid raw material may be dissolved or dispersed in a solvent such as water or an organic solvent, and then the treatment agent may be prepared.
The adhesion amount of the coating film is not particularly limited, and is, for example, 0.5g/m 2 Above and 50.0g/m 2 Hereinafter, it is preferably 2.0g/m 2 Above and 20.0g/m 2 Hereinafter, it is more preferably 2.0g/m 2 Above and 10.0g/m 2 The following is given. The amount of the adhesion can be adjusted by changing the composition, concentration, etc. of the treating agent, or changing the contact conditions such as the contact method, contact temperature, contact time, etc.
The contact condition of the treating agent is not particularly limited. For example, the temperature of the treating agent when the treating agent is contacted is 10 ℃ or more and 80 ℃ or less, preferably 25 ℃ or more and 75 ℃ or less, more preferably 25 ℃ or more and 60 ℃ or less, but the treating agent is not limited to these temperatures. The contact time can be appropriately set, and is usually 2 seconds or more and 180 seconds or less.
The 1 st film forming step may include a drying step as needed. The drying method may be any known method, and is not particularly limited. Examples thereof include: natural drying, reduced pressure drying, convection heating drying (e.g., natural convection heating drying, forced convection heating drying), radiation drying (e.g., near infrared drying, far infrared drying), ultraviolet curing drying, electron beam curing drying, vapor curing (vapor cure), and the like. In addition, a plurality of them may be used in combination.
In addition, the drying time may be appropriately selected according to the composition of the treating agent. The drying time is preferably in the range of 1 second to 1800 seconds, more preferably in the range of 10 seconds to 1200 seconds.
The drying temperature may be any ordinary drying temperature, and the metal peak temperature (PMT) of the metal material is preferably 60 ℃ or higher and 150 ℃ or lower, more preferably 80 ℃ or higher and 150 ℃ or lower. When the drying temperature is less than 60 ℃, moisture as a main solvent of the surface treatment agent may remain, and the coating film may not be fixed on the surface of the metal material. In this case, too, the temperature can be maintained at a temperature of less than 60 ℃ until the moisture volatilizes. The drying temperature of 60℃or higher is preferable since the productivity is lowered by the continuous drying until the moisture volatilizes.
2-2. Method for Forming film comprised between 1 st film and 2 nd film
The method for producing a film contained between the 1 st film and the 2 nd film includes a film forming step of: a desired single-layer or multi-layer laminated film is formed on the surface of the 1 st film. The film forming step is not particularly limited, and a known method corresponding to a film to be formed can be used. Examples thereof include: a chemical synthesis treatment step of forming a chemical synthesis film, a contact step and a drying step of a treating agent for forming a coating film and a metal material on which a1 st film is formed, a plating treatment step of forming a plating film, and the like. The treatment conditions of each step are not particularly limited, and treatment conditions suitable for each film and the method of forming the film can be used.
2-3. 2 nd film formation step
The 2 nd film forming step includes the steps of: the treatment agent for forming the 2 nd film is brought into contact with the surface or the surface of the 1 st film formed on the surface or the surface of the metal material. The contact method is not particularly limited, and a method similar to the contact method in the above-described coating film forming step can be used. In the case where the raw material contains a solid, the solid raw material may be dissolved or dispersed in a solvent such as water or an organic solvent, and then the treatment agent may be prepared.
The contact condition of the treating agent is not particularly limited. For example, the temperature of the treating agent when the treating agent is contacted is 10 ℃ or more and 80 ℃ or less, preferably 25 ℃ or more and 75 ℃ or less, more preferably 25 ℃ or more and 60 ℃ or less, but the treating agent is not limited to these temperatures. The contact time can be set appropriately, but is usually 2 seconds or more and 180 seconds or less.
The 2 nd film forming step may include a drying step as needed. The drying method is not limited to the contact method of the coating film, and the same method as the drying method of the coating film can be used.
The drying time may be appropriately selected depending on the composition of the treating agent, but is preferably in the range of 1 second to 1800 seconds, more preferably in the range of 10 seconds to 1200 seconds, from the viewpoints of productivity and film formability.
The drying temperature may be any ordinary drying temperature, and the metal peak temperature (PMT) of the metal material is preferably 60 ℃ or higher and 150 ℃ or lower, more preferably 80 ℃ or higher and 150 ℃ or lower. When the drying temperature is 60 ℃ or higher, water as a main solvent of the surface treatment agent is less likely to remain, and the coating film is easily fixed on the surface of the metal material, which is also preferable in terms of corrosion resistance.
The amount of the 2 nd film to be adhered is not particularly limited, and is, for example, 0.1g/m 2 Above and 20.0g/m 2 Hereinafter, it is preferably 2.0g/m 2 Above and 15.0g/m 2 The following is given. The amount of the adhesion can be adjusted by changing the composition, concentration, etc. of the treating agent, or changing the contact conditions such as the contact method, contact temperature, contact time, etc.
2-4 cleaning procedure
The cleaning step is a step of cleaning the surfaces of the metal material, the 1 st film, and the films included between the 1 st film and the 2 nd film by, for example, washing with water (e.g., hot water), solvent washing, alkali degreasing washing, acid washing, or the like.
The cleaning step is performed for the purpose of removing oil, dirt, and scale adhering to the surfaces or surfaces of the metal material, the 1 st film, and the films included between the 1 st film and the 2 nd film during the operation. In addition, the surface or the surface of the metal material may be coated with a rust preventive oil for rust prevention, and in this case, the purpose includes removal of the rust preventive oil. By performing the cleaning step, the surface or the surface can be cleaned, and the treatment agent or the like of the film laminated on the surface or the surface can be brought into uniform contact with the surface. In addition, when the surface or the surface is free from oil or dirt and the chemical synthesis treatment agent and the paint can be brought into uniform contact with each other, the cleaning step is not particularly required.
3. Plastic working method
The plastic working method of the present embodiment is not particularly limited, and examples thereof include known methods such as forging, extrusion, wire drawing, tube drawing, rolling, bending, joining, shearing, and shaping.
Examples
The effects of the present invention will be specifically described below by way of examples and comparative examples of the present invention. In addition, the present invention is not limited to these examples.
(1-1) metallic materials the metallic materials used in examples 1 to 19 and comparative examples 1 to 4 were barrel-shaped in shape having an upsetting ratio of 45% used in the ball reducing extrusion friction test method disclosed in reference (Gao Qiaozhao century, jokul, xiaoshanjin, wang Zhigang: 62 th symposium on plastic working, 2011, 89-90).
As the material of the above-mentioned metal material, S10C material was used in examples 1 to 10 and comparative examples 1, 3 and 4, and SUS430 material was used in examples 11 to 19 and comparative example 2.
(1-2) preparation of various surface treating Agents
Surface treatment agents for forming the 1 st film and the 2 nd film of examples 1 to 19 were prepared in the combinations shown in table 1. Hereinafter, the surface treatment agent for forming the 1 st film will be referred to as a surface treatment agent a, and the surface treatment agent for forming the 2 nd film will be referred to as a surface treatment agent B.
Surface treatment agent A
Surface treatment agents a of examples 1 to 10 were prepared. First, palbond 181XM (manufactured by Nippon Kagaku Co., ltd.) was added to deionized water so that the concentration became 90.0 g/L. Then, the value of total acidity obtained by titration was divided by the value of free acidity obtained by the same method, and the ratio of acid (total acidity/free acidity) was determined to be 6.5.
Next, the concentration (unit: point) of the accelerator using the accelerator 131 (manufactured by Nippon Kagaku Co., ltd.) was adjusted to 2.5 points.
The concentration of accelerator 131 was measured using a glass instrument called a glycometer (capacity 50 mL). In the concentration measurement, a surface treatment agent containing an accelerator was filled into a sugar meter, and 5g of a reagent 205 (manufactured by Nippon Temminck Co., ltd.) which reacted with the accelerator contained in the surface treatment agent was added. At this time, if the surface treatment agent contains an accelerator, gas is generated. The volume of the generated gas represents the concentration of the accelerator, and if the amount of the generated gas is 1mL, the concentration (unit: point) of the accelerator contained in the surface treatment agent is 1 point.
Surface treatment agent a of examples 11 to 19 was prepared. First, felbond A1 and Felbond A2 (both manufactured by Nippon Kagaku Co., ltd.) were added to deionized water so that the concentration of the former was 40.0g/L and the concentration of the latter was 20.0 g/L. Next, the concentration of the accelerator 16 (manufactured by Nippon Kagaku Co., ltd.) was adjusted to 1.0 point.
The concentration of promoter 16 was titrated as follows: the surface treatment liquid was collected in a beaker with a 25mL whole pipette, and 50mL of deionized water, 25.0mL of reagent 54 (manufactured by Nipponica) and indicator 10 (manufactured by Nipponica) were added, followed by titration with a titration liquid 53 (manufactured by Nipponica) until the liquid became dark blue. The amount of the above-mentioned titration solution 53 required up to this point was used as the accelerator concentration (unit: dot).
Surface treatment agent B
The surface treatment agent B was prepared by adding the aromatic carboxylic acid compound described in table 1, or a salt thereof, or a peroxide thereof to distilled water. The concentration of the aromatic carboxylic acid compound, or a salt or peroxide thereof in the surface treatment agent B is controlled so that the adhesion amount of the 2 nd film formed from the surface treatment agent B is 4.0g/m 2 、8.0g/m 2 、12g/m 2 。
As the surface treatment agent for forming a single film in comparative examples 1 to 4, the following surface treatment agent was used.
Surface treatment agent in comparative example 1: surface treatment agent a of examples 1 to 10.
Surface treatment agent in comparative example 2: surface treatment agent A of examples 11 to 19.
Surface treatment agent in comparative example 3: mineral oil (paraffin mineral oil 8cst at 40 ℃).
Surface treatment agent in comparative example 4: surface treatment agent B of examples 2 and 12
(1-3) cleaning treatment of metallic Material
The surfaces of the metal materials used in the above examples and comparative examples were cleaned by the following methods.
A commercially available degreasing agent (Fine cleaning E6400, manufactured by Nippon Kagaku Co., ltd.) was adjusted to a concentration of 20g/L by using tap water, and heated to 60℃to maintain a constant temperature. The metal material was immersed in the degreasing agent for 10 minutes, and degreasing was performed. Subsequently, the degreasing agent, dirt, etc. remaining after immersing in tap water at 25 ℃ for 20 seconds are washed away with water. Then, the metal material after washing was immersed in 17.5% hydrochloric acid at 25℃for 10 minutes to remove dirt which could not be removed by washing. Further, the metal material was immersed in tap water at 25℃for 20 seconds to wash off hydrochloric acid adhering to the metal material.
(1-4) methods for Forming the 1 st film and the 2 nd film of examples 1 to 19
The 1 st film and the 2 nd film were formed on the metal material subjected to the above-mentioned cleaning treatment by the following methods.
Examples 1 to 10
The metal material thus cleaned was immersed in the surface treatment agent a adjusted to 80 ℃ for 10 minutes to form a1 st coating film. Subsequently, the metal material having the 1 st coating film formed thereon was immersed in tap water at 25 ℃ for 30 seconds, and washed with water. Table 1 shows the amounts of the 1 st film of examples 1 to 10. The adhesion amount was calculated by measuring the weight of the metal material before and after the formation of the 1 st film, and dividing the difference by the surface area of the original metal material.
Further, the metal material on which the 1 st film was formed was immersed in the surface treatment agent B heated to 60 ℃ for 15 seconds, taken out, and naturally dried to form the 2 nd film, which was the metal material for plastic working of examples 1 to 10. Table 1 shows the amount of film deposition of the 2 nd film. The adhesion amount was calculated by measuring the weight of the metal material before and after the formation of the 2 nd film, and dividing the difference by the surface area of the original metal material as the adhesion weight.
Examples 11 to 19
The metal material after the cleaning was immersed in the surface treatment agent a adjusted to 90 ℃ for 10 minutes to form a1 st coating film. Subsequently, the metal material having formed the 1 st film was immersed in tap water at 25 ℃ for 30 seconds, and washed with water. Table 1 shows the amounts of the 1 st film of examples 11 to 19. The amount of adhesion was calculated in the same manner as in examples 1 to 10.
Further, the metal material on which the 1 st film was formed was immersed in the surface treatment agent B heated to 60 ℃ for 15 seconds, taken out, and naturally dried to form the 2 nd film, which was the metal material for plastic working of examples 11 to 19. Table 1 shows the amounts of the 2 nd films of examples 11 to 19. The amount of adhesion was calculated in the same manner as in examples 1 to 10.
(1-5) method for Forming Single coating film of comparative examples 1 to 4
In comparative example 1, a single film was formed by the same method as the 1 st film forming method in examples 1 to 10, and then, a metal material was immersed in tap water at 25 ℃ for 30 seconds, and washed with water, to obtain a metal material for plastic working of comparative example 1.
In comparative example 2, a single film was formed by the same method as the method of forming the 1 st film in examples 11 to 19, and then, the metal material was immersed in tap water at 25 ℃ for 30 seconds, and washed with water, to obtain a metal material for plastic working of comparative example 2.
In comparative example 3, the resulting mixture was immersed in mineral oil heated to 40℃for 10 seconds, and then taken out, and excess mineral oil was scraped off to give a deposit amount (g/m) 2 ) Becomes 4.0g/m 2 As the metal material for plastic working of comparative example 3.
In comparative example 4, a single film was formed by the same method as the method of forming the 2 nd film in examples 2 and 12, and then, the metal material was immersed in tap water at 25 ℃ for 30 seconds, and washed with water, to obtain a metal material for plastic working of comparative example 4.
Table 1 shows the amounts of the single films of comparative examples 1 to 4.
(1-6) evaluation test
(1-6-1) ball reducing extrusion test
Evaluation of fusion welding resistance and lubricity was performed based on the ball reducing extrusion friction test method disclosed in the above references.
The evaluation test was performed as follows: after the film was formed, the barrel-shaped test piece was subjected to a reducing extrusion process (forced tooling) using 3 spherical molds (SUJ-2 bearing balls having a diameter of 10 mm) with respect to the protruding side surface portions. The evaluation of the weld resistance of each test piece was determined by visually checking the appearance of the latter half of the reduced extrusion process in which the surface area was enlarged, based on the evaluation criterion (a is optimal) shown in fig. 1. The lubricity of each test piece was evaluated based on the following evaluation criteria.
In addition, in the present embodiment, there is no difference in corrosion resistance before and after plastic working (comparison of rust conditions in equivalent environments), and therefore, it can be considered that: the 2 nd film remains after plastic working and protects the 1 st film.
< evaluation criteria for lubricity >
The lubrication properties were evaluated by comparing the maximum load value obtained during the reducing extrusion with the range of the maximum load value described below as an evaluation criterion. The smaller the maximum load value, the more excellent the lubricity.
A: the maximum load value is less than 38kN.
B: the maximum load value is 38kN or more and less than 40kN.
C: the maximum load value is 40kN or more and less than 42kN.
D: the maximum load value is 42kN or more.
TABLE 1
TABLE 1
TABLE 2
TABLE 2
It will be apparent to those skilled in the art that the present invention has been described in detail with reference to specific embodiments, but that various changes and modifications can be made without departing from the spirit and scope of the invention.
Claims (3)
1. A metal material for plastic working, comprising a1 st film on the surface or surface of the metal material and a2 nd film on the surface or surface of the 1 st film,
the 1 st coating is a chemical synthesis coating,
the 2 nd leather film is a surface layer,
the 2 nd film is formed of only a peroxide of a compound having a benzene ring directly bonded to at least 1 carboxyl group, or a salt of a compound having a benzene ring directly bonded to at least 1 carboxyl group, or a compound having a benzene ring directly bonded to at least 1 carboxyl group.
2. The metal material for plastic working according to claim 1, wherein the 1 st film is a film containing at least 1 or more components selected from the group consisting of phosphates, oxalates and aluminates.
3. The metal material for plastic working according to claim 1 or 2, wherein the salt of the compound having a benzene ring directly bonded to at least 1 carboxyl group is an ammonium salt, a sodium salt, a lithium salt or a potassium salt.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018-035966 | 2018-02-28 | ||
| JP2018035966 | 2018-02-28 | ||
| CN201980014024.3A CN111771014A (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
| PCT/JP2019/006682 WO2019167816A1 (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201980014024.3A Division CN111771014A (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116200733A true CN116200733A (en) | 2023-06-02 |
Family
ID=67805770
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310185445.0A Pending CN116200733A (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
| CN201980014024.3A Pending CN111771014A (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201980014024.3A Pending CN111771014A (en) | 2018-02-28 | 2019-02-22 | Metal material for plastic working |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP7132321B2 (en) |
| KR (1) | KR102513657B1 (en) |
| CN (2) | CN116200733A (en) |
| TW (1) | TW201938842A (en) |
| WO (1) | WO2019167816A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0716982A (en) * | 1993-07-06 | 1995-01-20 | Sumitomo Metal Ind Ltd | Steel plate covered with more than one organic layer |
| TW200406505A (en) * | 2002-10-31 | 2004-05-01 | Nihon Parkerizing | Surface treatment composition, surface treatment liquid, surface treatment method and metallic article |
| JP2007229743A (en) * | 2006-02-28 | 2007-09-13 | Kobe Steel Ltd | Metallic material for plastic working |
| CN105658843A (en) * | 2013-10-22 | 2016-06-08 | 日本帕卡濑精株式会社 | Non-phosphorus chemical conversion treatment agent and treatment liquid for plastic working, chemical conversion coating, and metal material having chemical conversion coating |
| TW201715083A (en) * | 2015-09-04 | 2017-05-01 | 日本帕卡瀨精股份有限公司 | Chemical treatment agent, method for producing coating film, metal material with coating film and coated metal material |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0825553A (en) * | 1994-07-16 | 1996-01-30 | Sumitomo Metal Ind Ltd | Film-treated al-zn alloy plated steel sheet |
| JP2005343119A (en) * | 2004-06-07 | 2005-12-15 | Sdc Technologies Asia Kk | Manufacturing method of coated plastic article, coated plastic article and photo-curable coating liquid composition |
| JP5549957B1 (en) | 2013-07-10 | 2014-07-16 | 大同化学工業株式会社 | Lubricant composition for aqueous cold plastic working |
| JP6203604B2 (en) | 2013-11-07 | 2017-09-27 | 株式会社シダーブライト | Lubricant composition for warm and hot plastic working |
| JP6200283B2 (en) | 2013-11-07 | 2017-09-20 | 株式会社シダーブライト | Lubricants for warm and hot forging |
| JP6566798B2 (en) * | 2015-09-04 | 2019-08-28 | 日本パーカライジング株式会社 | Surface treatment agent, surface treatment method and surface treatment metal material |
-
2019
- 2019-02-22 JP JP2020503460A patent/JP7132321B2/en active Active
- 2019-02-22 CN CN202310185445.0A patent/CN116200733A/en active Pending
- 2019-02-22 KR KR1020207023022A patent/KR102513657B1/en active IP Right Grant
- 2019-02-22 WO PCT/JP2019/006682 patent/WO2019167816A1/en active Application Filing
- 2019-02-22 TW TW108106115A patent/TW201938842A/en unknown
- 2019-02-22 CN CN201980014024.3A patent/CN111771014A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0716982A (en) * | 1993-07-06 | 1995-01-20 | Sumitomo Metal Ind Ltd | Steel plate covered with more than one organic layer |
| TW200406505A (en) * | 2002-10-31 | 2004-05-01 | Nihon Parkerizing | Surface treatment composition, surface treatment liquid, surface treatment method and metallic article |
| JP2007229743A (en) * | 2006-02-28 | 2007-09-13 | Kobe Steel Ltd | Metallic material for plastic working |
| CN105658843A (en) * | 2013-10-22 | 2016-06-08 | 日本帕卡濑精株式会社 | Non-phosphorus chemical conversion treatment agent and treatment liquid for plastic working, chemical conversion coating, and metal material having chemical conversion coating |
| TW201715083A (en) * | 2015-09-04 | 2017-05-01 | 日本帕卡瀨精股份有限公司 | Chemical treatment agent, method for producing coating film, metal material with coating film and coated metal material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111771014A (en) | 2020-10-13 |
| KR20200106187A (en) | 2020-09-11 |
| WO2019167816A1 (en) | 2019-09-06 |
| KR102513657B1 (en) | 2023-03-23 |
| JPWO2019167816A1 (en) | 2021-02-18 |
| TW201938842A (en) | 2019-10-01 |
| JP7132321B2 (en) | 2022-09-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2608390C (en) | Method for preparing metallic workpieces for cold forming | |
| JP5760355B2 (en) | Steel plate for containers | |
| JP5186814B2 (en) | Steel plate for containers and manufacturing method thereof | |
| JP5729230B2 (en) | Steel plate for container and method for producing the same | |
| JP5186817B2 (en) | Steel plate for containers | |
| CA2855673A1 (en) | Method for passivation of strip black plate | |
| JP2013522466A (en) | Method for producing a coated metal strip | |
| JP5186816B2 (en) | Steel plate for containers and manufacturing method thereof | |
| US4102678A (en) | Metal coating by a powder metallurgy technique | |
| CN116200733A (en) | Metal material for plastic working | |
| JP2016199794A (en) | Steel sheet and method for manufacturing the same | |
| JP6216208B2 (en) | Non-phosphating agent for plastic working, treatment liquid, chemical film and metal material having chemical film | |
| RU2684803C2 (en) | Method of processing metallic material with layer of non-phosphate coating for cold-heading plastic treatment | |
| JP2017071848A (en) | Heat treatment method for black plate covered with conversion coating | |
| JP2007229743A (en) | Metallic material for plastic working | |
| CN105951070A (en) | Phosphating solution for steel surface treatment and preparation method thereof | |
| US3698932A (en) | Articles having a low friction surface and process of making same | |
| JP6629979B2 (en) | Method for producing a steel product having a Zn coating and a tribologically active layer deposited on the coating, and a steel product produced according to the method | |
| JP4143493B2 (en) | Coated stainless steel and method for producing the same | |
| US1378439A (en) | Coating ferrous metals | |
| WO2019004163A1 (en) | Rust prevention member and method for producing same | |
| JPH0713306B2 (en) | Zinc-based plated steel sheet excellent in press workability and method for producing the same | |
| WO2021112175A1 (en) | Metal surface pre-treatment agent | |
| JPH01136952A (en) | Alloyed hot dip galvanized sheet steel having excellent press formability | |
| JP2000080481A (en) | Resin chromate treated metallic sheet excellent in lubricity, chromium hardly soluble in water and its production |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |