CN116183754A - VOC continuous detection system - Google Patents

VOC continuous detection system Download PDF

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Publication number
CN116183754A
CN116183754A CN202211736380.6A CN202211736380A CN116183754A CN 116183754 A CN116183754 A CN 116183754A CN 202211736380 A CN202211736380 A CN 202211736380A CN 116183754 A CN116183754 A CN 116183754A
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CN
China
Prior art keywords
gas
module
sampling
valve
temperature
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Pending
Application number
CN202211736380.6A
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Chinese (zh)
Inventor
杨效
李涛涛
赖月
余斌
黄辉
何睿
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Zhejiang University Mingquan Technology Co ltd
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Zhejiang University Mingquan Technology Co ltd
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Priority to CN202211736380.6A priority Critical patent/CN116183754A/en
Publication of CN116183754A publication Critical patent/CN116183754A/en
Pending legal-status Critical Current

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B5/00—Cleaning by methods involving the use of air flow or gas flow
    • B08B5/02—Cleaning by the force of jets, e.g. blowing-out cavities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027—Cleaning the internal surfaces; Removal of blockages
    • B08B9/032—Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing
    • B08B9/0321—Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing using pressurised, pulsating or purging fluid
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01D—MEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D21/00—Measuring or testing not otherwise provided for
    • G01D21/02—Measuring two or more variables by means not covered by a single other subclass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The invention discloses a VOC continuous detection system which comprises an MCU, a gas sampling position, a sampling subsystem, a monitoring subsystem, a gas discharge position, a gas source auxiliary subsystem, a data acquisition and transmission subsystem and a data receiving terminal; the VOC continuous detection system provided by the invention has the advantages of simple structure, reasonable design, accurate detection, convenient data storage and convenient data calling.

Description

VOC continuous detection system
Technical Field
The invention relates to a fixed pollution source waste monitoring system, in particular to a VOC continuous detection system.
Background
VOCs are short for English of volatile organic compounds, and the volatile organic compounds comprise substances such as ethylene glycol, esters and the like, when the VOC reaches a certain concentration, symptoms such as headache, nausea, vomit, hypodynamia and the like can be caused, and even convulsions, coma, liver, kidney, brain and nervous system injury, hypomnesis and the like are caused; thus, VOC detectors are designed to continuously measure toxic and hazardous organic VOC gases in hazardous or industrial environments.
In the detection process of the VOC detector, the accuracy of a final detection result can be influenced by the changes of pressure, humidity and temperature; therefore, a calibration module with standard gas needs to be arranged to ensure the long-term accuracy of measurement; meanwhile, when the VOC gas reaches the measuring module through the pipeline, the VOC gas remains in the pipeline along the way and in the measuring module, if the standard gas is introduced at the moment for detection, the detection value of the standard gas is wrong, and the final detection result is influenced; therefore, a back-blowing module is also needed to blow away the residual VOC gas in the pipeline and in the measurement module before the standard gas is introduced into the pipeline and in the measurement module.
Meanwhile, the data storage obtained by detection is also a problem; because the detection sites are mostly in the flue of factories or in the chimney and the like, the VOC detectors mostly need to perform flow detection; if the monitored data is always stored on the VOC detector or a storage device such as a mobile hard disk, the situation of data loss or the situation of troublesome data calling is unavoidable.
Disclosure of Invention
The VOC continuous detection system overcomes the defects of the prior art, and has the advantages of simple structure, reasonable design, accurate detection, convenient data storage and convenient data calling.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the VOC continuous detection system comprises an MCU, a gas sampling position, a sampling subsystem, a monitoring subsystem, a gas discharge position, an air source auxiliary subsystem, a data acquisition and transmission subsystem and a data receiving terminal;
the MCU is connected with the sampling subsystem, the monitoring subsystem, the air source auxiliary subsystem and the data acquisition and transmission subsystem; the air source auxiliary subsystem is connected with the monitoring subsystem;
the monitoring subsystem comprises an analysis cabinet, a preprocessing module and a measuring module, wherein the preprocessing module and the measuring module are arranged in the analysis cabinet; the pretreatment module is connected with the measurement module and the gas discharge part; the measuring module is also connected with the gas discharge part;
the sampling subsystem comprises a sampling probe, a heat tracing pipe, a calibration module and a blowback module; the sampling probe is provided with a valve and a collection cavity, and is arranged at a gas sampling position; the heat tracing pipe comprises a sampling conveying pipe and a standard gas conveying pipe, the standard gas conveying pipe is connected with the sampling probe and the calibration module, and the sampling conveying pipe is connected with the sampling probe and the pretreatment module; the calibration module is also connected with the preprocessing module and the measurement module; the back-blowing module is connected with the sampling probe;
the data acquisition and transmission subsystem comprises a data acquisition instrument and a network transmission module, the data acquisition instrument is connected with the MCU and the measurement module, the network transmission module is connected with the MCU and the data receiving terminal, and the network transmission module transmits data acquired by the data acquisition instrument to the data receiving terminal;
the monitoring subsystem also comprises a temperature and oxygen monitoring module and a temperature and pressure monitoring module; the temperature and oxygen monitoring module and the temperature and pressure monitoring module are connected with a data acquisition instrument; the temperature oxygen monitoring module comprises Wen Yangyi and a temperature oxygen content signal wire, the temperature oxygen meter is arranged at the gas sampling position, and the temperature oxygen content signal wire is connected with Wen Yangyi and the data acquisition meter; the temperature and pressure monitoring module comprises a temperature and pressure flow integrated machine and a temperature and pressure flow signal line, and the temperature and pressure flow signal line is connected with the temperature and pressure flow integrated machine and a data acquisition instrument;
the air source auxiliary subsystem is connected with the measuring module.
Further, the pretreatment module comprises a back-blowing stop valve, a filter, a sampling pump, a wet oxygen monitor, a needle valve and a sample injection valve; one end of the back-blowing stop valve is connected with the sampling conveying pipe, the other end of the back-blowing stop valve is connected with one end of the filter, the other end of the filter is connected with one end of the sampling pump, and the other end of the sampling pump is connected with one end of the wet oxygen monitor and one end of the sample injection valve; the other end of the wet oxygen monitor is connected with one end of a needle valve, and the other end of the needle valve is connected with a gas discharge part; the other end of the sample injection valve is connected with the measuring module.
Further, the calibration module comprises a standard gas bottle, a standard gas flowmeter, a whole-range standard gas valve and a half-range standard gas valve which are stored with standard gas; the gas marking cylinder is connected with one end of the gas marking flowmeter, and the other end of the gas marking flowmeter is connected with one end of the whole-range gas marking valve and one end of the half-range gas marking valve; the other end of the whole-course air marking valve is connected with the air marking conveying pipe, and the other end of the half-course air marking valve is connected with the sample injection valve and the measuring module.
Further, the measurement module comprises an online chromatograph, wherein the online chromatograph comprises an air inlet interface, an air outlet interface, a carrier gas interface, an air interface, a driving interface and a hydrogen interface; the half-range gas marking valve and the sample injection valve are connected with the gas inlet interface; the air outlet interface is connected with the air discharge part.
Further, the air source auxiliary subsystem comprises a zero air generator, a hydrogen generator, a water tank, a nitrogen cylinder and an air compressor; the nitrogen cylinder is connected with the carrier gas interface, the air interface and the driving interface; the zero gas generator is connected with the carrier gas interface, the air interface and the driving interface; the air compressor is connected with the zero gas generator; the hydrogen generator is connected with the water tank and the hydrogen interface.
Further, the back-blowing module comprises a back-blowing valve and a back-blowing pipeline, one end of the back-blowing valve is connected with one end of the back-blowing pipeline, and the other end of the back-blowing pipeline is connected with the air compressor; the other end of the blowback valve is connected with the sampling probe.
Further, the network transmission module comprises a wired transmission module and a wireless transmission module; the wired transmission module is connected with the MCU and the data receiving terminal; the wireless transmission module comprises a communication server, the MCU is connected with the communication server, and the communication server is connected with the data receiving terminal.
Further, the device also comprises a high-temperature box with a heater arranged inside; the high-temperature box is arranged in the analysis cabinet; the pretreatment module is arranged in the high-temperature box.
Further, the zero gas generator, the hydrogen generator, the air compressor and the online chromatograph are all arranged in the analysis cabinet.
The beneficial effects of the invention are as follows:
according to the invention, through the arrangement of the calibration module, the standard gas can be detected in a staged manner in the detection process, then the detection value of the VOC gas is compared with the detection value of the standard gas, and the long-term accuracy of measurement is ensured through the comparison result; meanwhile, through the arrangement of the back blowing module, VOC gas residues in the sampling module are cleaned, so that influence of the VOC gas residues on detection values of standard gas is reduced to the greatest extent; meanwhile, through the arrangement of the data acquisition instrument and the network transmission module, the data acquisition instrument can upload monitoring data from the measurement module, the temperature and oxygen monitoring module and the temperature and pressure monitoring module to the data receiving terminal through the network transmission module, so that the data can be stored and called more conveniently.
In the detection process, the emission environment of some VOC gases is high temperature, but the temperature of the VOC gases is reduced in the collection and detection processes, so that the detection structure is affected; in the invention, the temperature change is reduced by the arrangement of the high-temperature box, so that the influence on the final detection result is reduced to the greatest extent.
Drawings
FIG. 1 is a schematic representation of the use of the present invention.
Fig. 2 is a schematic diagram of the overall gas circuit of the present invention.
Fig. 3 is a block diagram of a sampling probe of the present invention disposed at a corresponding sampling site.
Fig. 4 is a block diagram of a sampling probe according to the present invention.
Fig. 5 is a cross-sectional view of fig. 4.
FIG. 6 is a block diagram of a package of the sampling probe of the present invention.
Fig. 7 is a block diagram of the mounting of the probe mounting cartridge in cooperation with the sampling probe.
FIG. 8 is a block diagram of the probe cartridge in cooperation with a mounting flange and a handle.
Fig. 9 is a block diagram of the cartridge cover and handle mating.
FIG. 10 is a cross-sectional view of the probe cartridge mated with a mounting flange.
Fig. 11 is a cross-sectional view of the cartridge housing.
Fig. 12 is a state transition structure diagram of the on-line chromatograph of the present invention.
Detailed Description
The invention will be further described with reference to the drawings and specific examples. It should be noted that the examples are only specific to the present invention and are for the purpose of better understanding of the technical solutions of the present invention to those skilled in the art, and should not be construed as limiting the present invention.
Examples:
the VOC continuous detection system comprises an MCU, a gas sampling position, a sampling subsystem, a monitoring subsystem, a gas discharge position, an air source auxiliary subsystem, a data acquisition and transmission subsystem and a data receiving terminal; the MCU is connected with the sampling subsystem, the monitoring subsystem, the air source auxiliary subsystem and the data acquisition and transmission subsystem; the air source auxiliary subsystem is connected with the monitoring subsystem; the monitoring subsystem comprises an analysis cabinet, a preprocessing module and a measuring module, wherein the preprocessing module and the measuring module are arranged in the analysis cabinet; the pretreatment module is connected with the measurement module and the gas discharge part; the measuring module is also connected with the gas discharge part; the sampling subsystem comprises a sampling probe, a heat tracing pipe, a calibration module and a blowback module; the sampling probe is provided with a valve and a collection cavity, and is arranged at a gas sampling position; the heat tracing pipe comprises a sampling conveying pipe and a standard gas conveying pipe, the standard gas conveying pipe is connected with the sampling probe and the calibration module, and the sampling conveying pipe is connected with the sampling probe and the pretreatment module; the calibration module is also connected with the preprocessing module and the measurement module; the back-blowing module is connected with the sampling probe; the data acquisition and transmission subsystem comprises a data acquisition instrument and a network transmission module, the data acquisition instrument is connected with the MCU and the measurement module, the network transmission module is connected with the MCU and the data receiving terminal, and the network transmission module transmits data acquired by the data acquisition instrument to the data receiving terminal; the monitoring subsystem also comprises a temperature and oxygen monitoring module and a temperature and pressure monitoring module; the temperature and oxygen monitoring module and the temperature and pressure monitoring module are connected with a data acquisition instrument; the temperature oxygen monitoring module comprises Wen Yangyi and a temperature oxygen content signal wire, the temperature oxygen meter is arranged at the gas sampling position, and the temperature oxygen content signal wire is connected with Wen Yangyi and the data acquisition meter; the temperature and pressure monitoring module comprises a temperature and pressure flow integrated machine and a temperature and pressure flow signal line, and the temperature and pressure flow signal line is connected with the temperature and pressure flow integrated machine and a data acquisition instrument; the air source auxiliary subsystem is connected with the measuring module.
According to the invention, through the arrangement of the calibration module, the standard gas can be detected in a staged manner in the detection process, then the detection value of the VOC gas is compared with the detection value of the standard gas, and the long-term accuracy of measurement is ensured through the comparison result; meanwhile, through the arrangement of the back blowing module, VOC gas residues in the sampling module are cleaned, so that influence of the VOC gas residues on detection values of standard gas is reduced to the greatest extent; meanwhile, through the arrangement of the data acquisition instrument and the network transmission module, the data acquisition instrument can upload monitoring data from the measurement module, the temperature and oxygen monitoring module and the temperature and pressure monitoring module to the data receiving terminal through the network transmission module, so that the data can be stored and called more conveniently.
In this embodiment, the pretreatment module includes a blowback stop valve, a filter, a sampling pump, a wet oxygen monitor, a needle valve, and a sample injection valve; one end of the back-blowing stop valve is connected with the sampling conveying pipe, the other end of the back-blowing stop valve is connected with one end of the filter, the other end of the filter is connected with one end of the sampling pump, and the other end of the sampling pump is connected with one end of the wet oxygen monitor and one end of the sample injection valve; the other end of the wet oxygen monitor is connected with one end of a needle valve, and the other end of the needle valve is connected with a gas discharge part; the other end of the sample injection valve is connected with the measuring module.
In this embodiment, the calibration module includes a standard gas cylinder storing standard gas, a standard gas flowmeter, a whole-range standard gas valve and a half-range standard gas valve; the gas marking cylinder is connected with one end of the gas marking flowmeter, and the other end of the gas marking flowmeter is connected with one end of the whole-range gas marking valve and one end of the half-range gas marking valve; the other end of the whole-course air marking valve is connected with the air marking conveying pipe, and the other end of the half-course air marking valve is connected with the sample injection valve and the measuring module.
In this embodiment, the measurement module includes an online chromatograph, where the online chromatograph includes an air inlet interface, an air outlet interface, a carrier gas interface, an air interface, a driving interface, and a hydrogen interface; the half-range gas marking valve and the sample injection valve are connected with the gas inlet interface; the air outlet interface is connected with the air discharge part.
In this embodiment, the air source auxiliary subsystem includes a zero air generator, a hydrogen generator, a water tank, a nitrogen cylinder and an air compressor; the nitrogen cylinder is connected with the carrier gas interface, the air interface and the driving interface; the zero gas generator is connected with the carrier gas interface, the air interface and the driving interface; the air compressor is connected with the zero gas generator; the hydrogen generator is connected with the water tank and the hydrogen interface.
In this embodiment, the back-blowing module includes a back-blowing valve and a back-blowing pipeline, one end of the back-blowing valve is connected with one end of the back-blowing pipeline, and the other end of the back-blowing pipeline is connected with the air compressor; the other end of the blowback valve is connected with the sampling probe.
Specifically, the sampling probe includes a mounting portion 1 and a sampling conveying portion 2; the sampling conveying part 2 comprises a sampling probe rod 3 and a probe body 4; a sampling cavity 41 is arranged in the probe main body 4, and a conveying channel 31 is arranged in the sampling probe rod 3; the sampling probe rod 3 is connected with the probe body 4, and the conveying channel 31 is communicated with the sampling cavity 41; the mounting part 1 comprises a pre-assembly 5 and a mounting piece 6, wherein the pre-assembly 5 is fixed on a flue wall 12 of a sampling place, and the mounting piece 6 is connected with the probe main body 4; the preassembly 5 and the mounting 6 are connected in a matched manner, and the sampling probe rod 3 enters the flue 11 of the sampling place.
Under the general condition, the sampling probes are arranged at the corresponding sampling positions in a direct assembly mode, in order to avoid the damage of acting force generated in the assembly process to the structure and the device inside the sampling probes, operators generally adopt an assembly mode with smaller influence on the sampling probes, so that the possibility that the structure and the device inside the sampling probes are damaged by the acting force is reduced, but the mode can cause the conditions of low assembly strength of the sampling probes, easy shaking and the like, and further influence the stability of VOC gas collection; in the invention, the whole installation of the invention is realized through the installation part 1, the installation part 1 comprises a pre-assembly 5 and an installation piece 6, the pre-assembly 5 is fixed on a flue wall 12 of a sampling place, and the installation piece 6 is connected with the probe main body 4; since the pre-assembly 5 is fixed on the flue wall 12 of the sampling place in advance, the pre-assembly 5 can be fixed and assembled in the most firm and stable mode by the operator during the fixed and assembling of the pre-assembly 5, and the probe body 4 is matched with the pre-assembly 5 through the mounting piece 6, so that the VOC gas can be stably collected, and the detection accuracy of the VOC detector assembled with the invention is higher.
In this embodiment, the pre-assembly 5 comprises a pre-assembled tube 51 and a pre-assembled flange 52, the pre-assembled flange 52 being connected to one end of the pre-assembled tube 51; the preassembling pipe 51 is provided with a preassembling channel 53 penetrating through two ends thereof, and the preassembling flange 52 is provided with a preassembling through hole 54 corresponding to the preassembling channel 53; the flue wall 12 of the sampling place is provided with a mounting hole 13, and the preassembled pipe 51 is arranged in the mounting hole 13; preassembled screw holes 55 matched with the mounting piece 6 are arranged on the preassembled flange 52; the flue wall 12 at the sampling position is provided with a mounting hole 13, a pre-loading pipe 51 is arranged in the mounting hole 13, stable assembly of the pre-loading component 5 is realized, and stable assembly with the mounting component 6 is realized through the pre-loading flange 52 and the pre-loading screw holes 55 on the pre-loading flange 52; simultaneously, the sampling probe 3 can penetrate through the preassembling component 5 to enter the flue 11 at the sampling position for sampling through the preassembling channel 53 arranged in the preassembling pipe 51 and the preassembling through holes 54 arranged on the preassembling flange 52.
In this embodiment, the probe body 4 includes a probe mounting box 7, and the mounting member 6 includes a mounting flange 61, and the mounting flange 61 is fixed on the outer surface of the probe mounting box 7; one side surface of the mounting flange 61 is attached to the probe mounting box 7, and the other side surface of the mounting flange 61 is contacted with the surface of the preassembled flange 52 away from the preassembled pipe 51; the mounting flange 61 is provided with a mounting screw hole 62 corresponding to the preassembly screw hole 55, and bolts penetrate through the preassembly screw hole 55 and the mounting screw hole 62 to enable the preassembly flange 52 to be matched with the mounting flange 61; the stable assembly of the probe body 4 is achieved by the cooperation of the bolts with the pre-installation screw holes 55 and the installation screw holes 62.
In this embodiment, the preassembly screw holes 55 are distributed and arranged on the same circular path, and the intervals between the preassembly screw holes 55 are equal; correspondingly, the installation screw holes 62 are distributed and arranged on the same circular path, and the intervals among the installation screw holes 62 are equal; the distribution of the preassembly screw holes 55 and the installation screw holes 62 is more uniform, and the assembly stability is improved.
In this embodiment, the number of the preassembly screw holes 55 and the installation screw holes 62 is 4, so that when the preassembly flange 52 and the installation flange 61 are matched through bolts, a diagonal screwing mode can be adopted, and the preassembly flange 52 and the installation flange 61 can be assembled more firmly and tightly.
In this embodiment, the probe body 4 includes a probe cartridge 8; the sampling cavity 41 is arranged in the probe filter element 8; an installation space 71 is arranged in the probe installation box 7, and the probe filter element 8 is arranged in the installation space 71; a mounting box opening 72 is formed in the probe mounting box 7, and one end of the probe filter element 8 is connected with the surface of the probe mounting box 7, which is attached to the surface, through the mounting box opening 72 and the mounting flange 61; the mounting flange 61 is provided with a gas passage hole 63 communicating with the sampling chamber 41; an adapter 64 is further provided on the surface of the mounting flange 61 contacting the pre-installed flange 52, an adapter space 65 is provided inside the adapter 64, and a first opening 66 and a second opening 67 are provided at both ends of the adapter 64; one end of the sampling probe rod 3 is assembled at the first opening 66, and the conveying channel 31 is communicated with the switching space 65; the second opening 67 is arranged corresponding to the gas passing hole 63, the inner diameter of the second opening 67 is larger than the inner diameter of the gas passing hole 63, the second opening 67 surrounds the gas passing hole 63, and the sampling cavity 41 is communicated with the switching space 65 through the second opening 67 and the gas passing hole 63; through the arrangement of the adapter 64 and the adapter space 65 in the adapter 64, the conveying channel 31 is communicated with the sampling cavity 41, and the collection and conveying of VOC gas are realized.
In this embodiment, the diameters of the adapter 64 and the sampling probe 3 are smaller than the inner diameters of the preassembly channel 53 and the preassembly through hole 54; after the preassembly flange 52 and the mounting flange 61 are matched, the sampling probe rod 3 passes through the preassembly channel 53 to enter the flue 11 at the sampling position, and the adapter 64 passes through the preassembly through hole 54 to enter the preassembly channel 53, so that the preassembly flange 52 and the mounting flange 61 are more attached, and the assembly strength and the assembly stability of the preassembly flange 52 and the mounting flange 61 are improved.
In some preferred forms, a sealing ring is provided between the pre-load flange 52 and the mounting flange 61, which surrounds the adapter 64 and the pre-load through-hole 54, thereby improving the sealing between the pre-load flange 52 and the mounting flange 61.
In this embodiment, the probe cartridge 8 includes a cartridge housing 81, an inner core 82, and a cartridge cover 83; the sampling cavity 41 is arranged in the filter element housing 81, and one end of the filter element housing 81 is connected with the surface of the probe mounting box 7, which is attached to the probe mounting box, through the mounting box opening 72 and the mounting flange 61; the inner core 82 is disposed in the sampling cavity 41; the sampling cavity 41 includes a first region 42 and a second region 43, wherein the first region 42 is located on a side near the adapter 64, and the inner core 82 is located in the first region 42; a cartridge mounting opening 811 communicating with the sampling chamber 41 is provided at one end of the cartridge housing 81 corresponding to the second region 43; the cartridge cover 83 fits over the second region 43 through the cartridge mounting opening 811; the two ends of the filter element cover 83 are respectively provided with a first closed end 831 and a second closed end 832, and the diameters of the first closed end 831 and the second closed end 832 correspond to the inner diameter of the second area 43; after the cartridge cover 83 is assembled, the first closed end 831 is positioned at an end of the second region 43 adjacent to the first region 42, the second closed end 832 is positioned at the cartridge mounting opening 811, and the second region 43 is closed by the first closed end 831 and the second closed end 832; the region of the filter element cover 83 between the first closed end 831 and the second closed end 832 is a joint region 833, and the diameter of the joint region 833 is smaller than the inner diameter of the second region 43; an inner space 834 is arranged in the filter element cover 83, and a connecting port 835 communicated with the inner space 834 is arranged on the filter element cover 83; the connecting port 835 is arranged at the first closed end 831, and the inner core 82 is connected with the filter core cover 83 through the connecting port 835; a gas flow hole 836 for communicating the inner space 834 with the second region 43 is further provided on the cartridge cover 83, the gas flow hole 836 being provided at the joint region 833; a gas flow opening 812 is provided in the cartridge housing 81, the gas flow opening 812 being provided corresponding to the location of the second region 43, and the gas flow opening 812 communicating with the second region 43; a conduit connector 813 is provided at the gas flow opening 812, and a conduit 816 is connected to the conduit connector 813 so that the second region 43 communicates with the conduit 816; large particles or garbage and the like in the VOC gas collected by the sampling probe rod 3 are filtered through the inner core 82, so that the gas path of the VOC detector is prevented from being blocked; an inner space 834 is arranged in the filter core cover 83, a connecting port 835 communicated with the inner space 834 is arranged on the filter core cover 83, and the inner core 82 is connected with the filter core cover 83 through the connecting port 835, so that VOC gas filtered by the inner core 82 enters the inner space 834; the VOC gas filtered by the inner core 82 in the inner space 834 is made to enter the second region 43 through the gas flow holes 836 provided on the cartridge cover 83; the VOC gas filtered by the inner core 82 in the second area 43 is sent to the VOC detector for detection through the gas flowing opening 812 and the pipeline connector 813 arranged on the filter element shell 81; thereby improving the detection accuracy.
In this embodiment, the tubing connector 813 includes an inlet connector 814 and an outlet connector 815; the lines 816 include a sense gas delivery line 817 and a blowback purge line 818; the back-blowing cleaning pipeline 818 is connected with the air inlet joint 814 and the air compressor, and the detection gas conveying pipeline 817 is connected with the air outlet joint 815 and the gas detector; the probe mounting box 7 is provided with a pipeline through hole 73, and a detection gas conveying pipeline 817 and a back blowing cleaning pipeline 818 pass through the pipeline through hole 73 and are connected with an inlet joint 814 and an outlet joint 815; the back-blowing cleaning pipeline 818 is connected with the air inlet connector 814 and the air compressor, so that after the VOC detector finishes detection, the air compressor can be started to blow out residual VOC gas in the probe filter element 8 from the direction of the conveying channel 31 or from the direction of the detection gas conveying pipeline 817, and further the condition that no VOC gas residue exists in the VOC detector is realized basically, so that the invention can reduce detection errors in the next detection.
In this embodiment, a handle 84 is further disposed on the outer surface of the filter element cover 83, and the handle 84 is disposed to facilitate the application of force by the handle 84, so as to detach the filter element cover 83 or clean and replace the inner core 82; a limit rod 85 is also arranged on the outer surface of the filter element shell 81; the setting direction of the limiting rod 85 is consistent with that of the handle 84; one end of the limiting rod 85 is connected with the outer surface of the filter element shell 81, and the other end of the limiting rod 85 faces away from the adapter 64; the handle 84 includes a first straight rod 841 and a second straight rod 842, one end of the first straight rod 841 is connected with the outer surface of the second closed end 832, and the other end of the first straight rod 841 faces away from the adapter 64 and is connected with the second straight rod 842; the first straight rod 841 and the second straight rod 842 are perpendicular to each other; a limiting piece 86 is sleeved on the first straight rod 841, and the limiting piece 86 can rotate; the limiting rod 85 comprises a first limiting rod 851 and a second limiting rod 852, the first limiting rod 851 and the second limiting rod 852 are respectively arranged on two sides of the filter element housing 81, and the first limiting rod 851, the second limiting rod 852 and the first straight rod 841 are positioned on the same straight line; a first limit groove 861 and a second limit groove 862 are arranged at two ends of the limit piece 86, and openings of the first limit groove 861 and the second limit groove 862 are respectively arranged at two sides of the limit piece 86; the first limiting rod 851 is positioned on the movable path of the first limiting groove 861, and the second limiting rod 852 is positioned on the movable path of the second limiting groove 862; the lengths of the first limiting rod 851 and the second limiting rod 852 are consistent, a limiting block 853 is arranged at one end of the first limiting rod 851 and one end of the second limiting rod 852, which are far away from the adapter 64, and the diameter of the limiting block 853 is larger than the inner diameters of the first limiting groove 861 and the second limiting groove 862; when the first limit rod 851 and the second limit rod 852 enter the first limit groove 861 and the second limit groove 862, the limit block 853 is positioned at one side of the limit piece 86 away from the adapter 64; the cooperation of the limiting rod 85 and the limiting piece 86 strengthens the assembly strength of the filter element cover 83, so that the condition that the filter element cover 83 falls off when the VOC detector works is avoided; the first limiting rod 851, the second limiting rod 852 and the first straight rod 841 are on the same straight line, openings of the first limiting groove 861 and the second limiting groove 862 are respectively arranged on two sides of the limiting piece 86, the limiting piece 86 rotates to a certain extent along one direction, the first limiting rod 851 and the second limiting rod 852 simultaneously enter the first limiting groove 861 and the second limiting groove 862, the lengths of the first limiting rod 851 and the second limiting rod 852 are consistent, one ends, far away from the adapter 64, of the first limiting rod 851 and the second limiting rod 852 are provided with limiting blocks 853, and the diameter of each limiting block 853 is larger than the inner diameters of the corresponding first limiting groove 861 and the corresponding second limiting groove 862, and the handle 84 and the filter element cover 83 are prevented from moving towards the direction far away from the filter element shell 81 through the arrangement of the limiting blocks 853.
In general, the flue 11 at the sampling place is vertical to the horizontal plane, and the VOC gas in the flue 11 moves upwards, if the sampling probe rod 3 also enters upwards, the condition of less collection amount can occur when the VOC gas is collected, so that the detection structure is misaligned; in this embodiment, the mounting hole 13 and the preassembled channel 53 are parallel with respect to a horizontal plane, and when the sampling probe 3 is located in the flue 11 at the sampling site, the sampling inlet of the sampling probe 3 can perform normal sampling.
In some other ways, the mounting holes 13 and the pre-installed passages 53 may be inclined, and the ends of the mounting holes 13 and the pre-installed passages 53 near the flue 11 are inclined downward at an angle of 10 °.
In this embodiment, the network transmission module includes a wired transmission module and a wireless transmission module; the wired transmission module is connected with the MCU and the data receiving terminal; the wireless transmission module comprises a communication server, the MCU is connected with the communication server, and the communication server is connected with the data receiving terminal.
In the embodiment, the device also comprises a high-temperature box internally provided with a heater; the high-temperature box is arranged in the analysis cabinet; the pretreatment module is arranged in the high-temperature box.
In this embodiment, the zero gas generator, the hydrogen gas generator, the air compressor and the on-line chromatograph are all disposed in the analysis cabinet.
In this embodiment, the control method for VOC gas sampling detection is as follows:
(1) Placing a sampling probe into a gas sampling position, and opening a valve of the sampling probe;
(2) Starting a sampling pump, opening a back-flushing stop valve, and opening a sample injection valve; the back-blowing valve and the whole-course air marking valve are in a closed state; the sampling gas passes through a sampling probe, a sampling conveying pipe, a blowback stop valve, a filter, a sampling pump and a sampling valve to reach an online chromatograph from an air inlet interface; meanwhile, the sampled gas passes through a sampling probe, a sampling conveying pipe, a blowback stop valve, a filter, a sampling pump, a wet oxygen monitor and a needle valve to reach a gas discharge position;
(3) The online chromatograph, the air compressor, the zero gas generator and the hydrogen generator work, and the nitrogen cylinder is opened to provide nitrogen, air and hydrogen for the online chromatograph;
(4) The on-line chromatograph leaves the detected gas from the gas outlet port to the gas discharge.
In the embodiment, the calibration module is connected with the standard gas conveying pipe and the pretreatment module at the same time; the control method of the calibration module comprises a whole-course ventilation mode of reaching the measurement module through the sampling module and the preprocessing module and a half-course ventilation mode of reaching the measurement module directly, so that two calibration modes exist in the invention, data obtained through the two calibration modes are compared with detection values of VOC gas, and the accuracy of VOC gas measurement is higher through comparison results;
the whole ventilation mode control method comprises the following steps:
(1) Closing a valve of the sampling probe;
(2) The standard gas cylinder is opened, the whole-process standard gas valve is opened, the back-blowing stop valve is opened, and the sample injection valve is opened; the half-way air marking valve and the back flushing valve are in a closed state; standard gas passes through a standard gas flowmeter, a whole-course standard gas valve, a standard gas conveying pipe, a sampling probe, a sampling conveying pipe, a back-blowing stop valve, a filter, a sampling pump and a sample injection valve to reach an online chromatograph from an air inlet interface;
the half-way ventilation mode control method comprises the following steps:
(1) The standard gas cylinder is opened, and the half-way standard gas valve is opened; the half-way gas marking valve and the sample injection valve are in a closed state; standard gas passes through a standard gas flowmeter, a half-way standard gas valve and reaches an online chromatograph from an air inlet interface.
In this embodiment, the control method of the blowback module is as follows:
(1) Opening a valve of the sampling probe;
(2) The reversing valve is opened; the whole-process air marking valve and the back-blowing stop valve are in a closed state;
(3) The air compressor is started, and air generated by the air compressor passes through the sampling probe and the sampling conveying pipe, and the detection gas residues in the sampling probe and the sampling conveying pipe are blown to a gas sampling position.
In this embodiment, the gas circuit control system includes a high temperature box in which a heater is provided, and the pretreatment module is disposed in the high temperature box.
In the detection process, the emission environment of some VOC gases is high temperature, but the temperature of the VOC gases is reduced in the collection and detection processes, so that the detection structure is affected; in the invention, the temperature change is reduced by the arrangement of the high-temperature box, so that the influence on the final detection result is reduced to the greatest extent.
The state conversion structure of the specific online chromatograph comprises a ten-way valve, a six-way valve and a detector; the ten-way valve and the six-way valve are connected through a pipeline to form a sample conveying line and a carrier conveying line, and the carrier conveying line is connected with the detector.
The ten-way valve and the six-way valve are used for realizing back-and-forth switching and sending the sample into the chromatographic column for separation. The specific sample conveying line comprises a sample input end, wherein the sample input end is connected with a No. 9 port of a ten-way valve, the No. 9 port of the ten-way valve is connected with a No. 8 port of the ten-way valve through a pipeline, the No. 8 port of the ten-way valve is connected with a No. 1 port of the ten-way valve through a pipeline, the No. 1 port of the ten-way valve is connected with a No. 10 port of the ten-way valve through a pipeline, the No. 10 port of the ten-way valve is connected with a No. 5 port of a six-way valve through a pipeline, the No. 5 port of the six-way valve is connected with a No. 4 port of the six-way valve through a pipeline, the No. 4 port of the six-way valve is connected with a No. 1 port of the six-way valve through a pipeline, and the No. 1 port of the six-way valve is connected with a No. 6 port of the six-way valve through a pipeline; the sample conveying line comprises a sample output end, and a No. 6 port of the six-way valve is connected with the sample output end.
The carrier transmission line comprises a carrier input end, wherein the carrier input end comprises a first carrier input end, a second carrier input end and a third carrier input end; the first carrier input end is connected with a No. 7 port of the ten-way valve, the No. 7 port of the ten-way valve is connected with a No. 6 port of the ten-way valve through a pipeline, the No. 6 port of the ten-way valve is connected with a No. 2 port of the ten-way valve through a pipeline, and the No. 2 port of the ten-way valve is connected with a No. 3 port of the ten-way valve through a pipeline; the carrier wave conveying line comprises a vent, and the port 3 of the ten-way valve is connected with the vent; the second carrier input end is connected with a No. 4 port of the ten-way valve, the No. 4 port of the ten-way valve is connected with a No. 5 port of the ten-way valve through a pipeline, and the No. 5 port of the ten-way valve is connected with the total hydrocarbon column through a pipeline; the second carrier input end is connected with a No. 3 port of the six-way valve, the No. 3 port of the six-way valve is connected with a No. 2 port of the six-way valve through a pipeline, and the No. 2 port of the six-way valve is connected with the total hydrocarbon column through a pipeline; the total hydrocarbon column is connected to a detector.
According to the scheme, through the ten-way valve and the six-way valve, the sample is sent into the chromatographic column for separation by back-and-forth switching, the detection efficiency is greatly improved, and multiple groups of pushing detection are realized.
It should be noted that other technical solutions of the present invention, which are not described in detail, belong to the prior art, and are not described in detail.
The foregoing is merely a preferred embodiment of the present invention, and it should be noted that modifications and adaptations to those skilled in the art may be made without departing from the concept of the present invention, and such modifications and adaptations are intended to be comprehended within the scope of the present invention.

Claims (9)

  1. The VOC continuous detection system is characterized by comprising an MCU, a gas sampling position, a sampling subsystem, a monitoring subsystem, a gas discharge position, a gas source auxiliary subsystem, a data acquisition and transmission subsystem and a data receiving terminal;
    the MCU is connected with the sampling subsystem, the monitoring subsystem, the air source auxiliary subsystem and the data acquisition and transmission subsystem; the air source auxiliary subsystem is connected with the monitoring subsystem;
    the monitoring subsystem comprises an analysis cabinet, a preprocessing module and a measuring module, wherein the preprocessing module and the measuring module are arranged in the analysis cabinet; the pretreatment module is connected with the measurement module and the gas discharge part; the measuring module is also connected with the gas discharge part;
    the sampling subsystem comprises a sampling probe, a heat tracing pipe, a calibration module and a blowback module; the sampling probe is provided with a valve and a collection cavity, and is arranged at a gas sampling position; the heat tracing pipe comprises a sampling conveying pipe and a standard gas conveying pipe, the standard gas conveying pipe is connected with the sampling probe and the calibration module, and the sampling conveying pipe is connected with the sampling probe and the pretreatment module; the calibration module is also connected with the preprocessing module and the measurement module; the back-blowing module is connected with the sampling probe;
    the data acquisition and transmission subsystem comprises a data acquisition instrument and a network transmission module, the data acquisition instrument is connected with the MCU and the measurement module, the network transmission module is connected with the MCU and the data receiving terminal, and the network transmission module transmits data acquired by the data acquisition instrument to the data receiving terminal;
    the monitoring subsystem also comprises a temperature and oxygen monitoring module and a temperature and pressure monitoring module; the temperature and oxygen monitoring module and the temperature and pressure monitoring module are connected with a data acquisition instrument; the temperature oxygen monitoring module comprises Wen Yangyi and a temperature oxygen content signal wire, the temperature oxygen meter is arranged at the gas sampling position, and the temperature oxygen content signal wire is connected with Wen Yangyi and the data acquisition meter; the temperature and pressure monitoring module comprises a temperature and pressure flow integrated machine and a temperature and pressure flow signal line, and the temperature and pressure flow signal line is connected with the temperature and pressure flow integrated machine and a data acquisition instrument;
    the air source auxiliary subsystem is connected with the measuring module.
  2. 2. The continuous VOC detection system of claim 1, wherein the pretreatment module comprises a blowback shut-off valve, a filter, a sampling pump, a wet oxygen monitor, a needle valve, and a sample injection valve; one end of the back-blowing stop valve is connected with the sampling conveying pipe, the other end of the back-blowing stop valve is connected with one end of the filter, the other end of the filter is connected with one end of the sampling pump, and the other end of the sampling pump is connected with one end of the wet oxygen monitor and one end of the sample injection valve; the other end of the wet oxygen monitor is connected with one end of a needle valve, and the other end of the needle valve is connected with a gas discharge part; the other end of the sample injection valve is connected with the measuring module.
  3. 3. The continuous VOC detection system of claim 2, wherein the calibration module comprises a standard gas cylinder having a standard gas therein, a standard gas flow meter, a full range standard gas valve, and a half range standard gas valve; the gas marking cylinder is connected with one end of the gas marking flowmeter, and the other end of the gas marking flowmeter is connected with one end of the whole-range gas marking valve and one end of the half-range gas marking valve; the other end of the whole-course air marking valve is connected with the air marking conveying pipe, and the other end of the half-course air marking valve is connected with the sample injection valve and the measuring module.
  4. 4. The continuous VOC detection system of claim 3, wherein the measurement module comprises an online chromatograph comprising an inlet gas interface, an outlet gas interface, a carrier gas interface, an air interface, a drive interface, and a hydrogen interface; the half-range gas marking valve and the sample injection valve are connected with the gas inlet interface; the air outlet interface is connected with the air discharge part.
  5. 5. The continuous VOC detection system of claim 4, wherein the gas source auxiliary subsystem comprises a zero gas generator, a hydrogen gas generator, a water tank, a nitrogen gas cylinder, and an air compressor; the nitrogen cylinder is connected with the carrier gas interface, the air interface and the driving interface; the zero gas generator is connected with the carrier gas interface, the air interface and the driving interface; the air compressor is connected with the zero gas generator; the hydrogen generator is connected with the water tank and the hydrogen interface.
  6. 6. The VOC continuous detection system of claim 5, wherein the blowback module comprises a blowback valve and a blowback line, one end of the blowback valve is connected to one end of the blowback line, and the other end of the blowback line is connected to the air compressor; the other end of the blowback valve is connected with the sampling probe.
  7. 7. The VOC continuous detection system of claim 1, wherein the network transmission module comprises a wired transmission module and a wireless transmission module; the wired transmission module is connected with the MCU and the data receiving terminal; the wireless transmission module comprises a communication server, the MCU is connected with the communication server, and the communication server is connected with the data receiving terminal.
  8. 8. The VOC continuous detection system of claim 1, further comprising a high temperature cabinet having a heater disposed therein; the high-temperature box is arranged in the analysis cabinet; the pretreatment module is arranged in the high-temperature box.
  9. 9. The continuous VOC detection system of claim 5, wherein the zero gas generator, the hydrogen gas generator, the air compressor, and the on-line chromatograph are all disposed within an analysis cabinet.
CN202211736380.6A 2022-12-31 2022-12-31 VOC continuous detection system Pending CN116183754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211736380.6A CN116183754A (en) 2022-12-31 2022-12-31 VOC continuous detection system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211736380.6A CN116183754A (en) 2022-12-31 2022-12-31 VOC continuous detection system

Publications (1)

Publication Number Publication Date
CN116183754A true CN116183754A (en) 2023-05-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211736380.6A Pending CN116183754A (en) 2022-12-31 2022-12-31 VOC continuous detection system

Country Status (1)

Country Link
CN (1) CN116183754A (en)

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