CN116040974A - Method for preparing superfine powder cement admixture - Google Patents

Method for preparing superfine powder cement admixture Download PDF

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Publication number
CN116040974A
CN116040974A CN202310272089.6A CN202310272089A CN116040974A CN 116040974 A CN116040974 A CN 116040974A CN 202310272089 A CN202310272089 A CN 202310272089A CN 116040974 A CN116040974 A CN 116040974A
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Prior art keywords
slag
cement
parts
powder
superfine powder
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CN202310272089.6A
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Chinese (zh)
Inventor
解婧秋
解增信
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Individual
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Priority to CN202310272089.6A priority Critical patent/CN116040974A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0481Other specific industrial waste materials not provided for elsewhere in C04B18/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/062Purification products of smoke, fume or exhaust-gases
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a method for preparing an ultrafine powder cement admixture, which is prepared from the following raw materials in parts by weight: 30-50 parts of water slag, 40-65 parts of fly ash and 5-10 parts of industrial desulfurization slag, and the materials are mixed together according to the weight proportion and ground into the powder with the specific surface area of 700-880m 2 The invention has the advantages that the powder of/Kg is: 1. the mixed ingredients of the granulated slag, the fly ash and the industrial desulfurization slag are adopted to replace mineral powder to be added into the cement, so that the strength of the cement is effectively improved, and the production cost of the cement is reduced; 2. the activity of the cement product is also effectively improved by reasonably mixing the water slag, the fly ash and the industrial desulfurization slag.

Description

Method for preparing superfine powder cement admixture
Technical Field
The invention relates to a manufacturing method of an admixture, in particular to a manufacturing method of a cement admixture.
Background
Cement is a powdery hydraulic inorganic cementing material. The water is added and stirred to form slurry, which can be hardened in air or water and firmly bond sand, stone and other materials together to form concrete. The existing ordinary Portland cement is difficult to meet the requirement of part of high concrete strength, and a method of blending mineral powder into cement is generally adopted to improve the concrete strength. However, the price of the mineral powder is high, and the strength of the concrete is improved to a certain extent after the mineral powder is blended into the cement, but the production cost of the cement is also improved. The market popularization is limited.
Disclosure of Invention
The invention aims to solve the defects and provide a preparation method of the superfine powder cement admixture, which has low production cost, can effectively increase the cement strength and the activity, and can also improve the cement performance.
The technical solution adopted by the invention for solving the technical problems is as follows:
the preparation method of the superfine powder cement admixture comprises the following raw materials in parts by weight: 30-50 parts of water slag, 40-65 parts of fly ash and 5-10 parts of industrial desulfurization slag, and the materials are mixed together according to the weight proportion and ground into the powder with the specific surface area of 700-880m 2 Powder per Kg.
Preferably, the water slag is iron-making blast furnace slag.
Preferably, the industrial desulfurization slag is replaced by phosphogypsum, and the phosphogypsum is dried until the water content is 7-8% for use.
The beneficial effects achieved by adopting the technical proposal of the invention are as follows:
1. the mixed ingredients of the granulated slag, the fly ash and the industrial desulfurization slag are adopted to replace mineral powder to be added into the cement, so that the strength of the cement is effectively improved, and the production cost of the cement is reduced.
2. The activity of the cement product is also effectively improved by reasonably mixing the water slag, the fly ash and the industrial desulfurization slag.
3. The workability of the concrete is improved, the water demand of the concrete is reduced, the hydration heat is reduced, and the cracking phenomenon of the concrete can be effectively prevented.
Detailed Description
Example 1: the preparation method of the superfine powder cement admixture comprises the following raw materials by weight: 30 kg of iron-making blast furnace slag, 65 kg of fly ash and 5 kg of industrial desulfurization slag are mixed together according to the weight proportion and ground into the powder with the specific surface area of 880m 2 Powder per Kg.
Figure BDA0004135083690000021
As can be seen from the analysis of the above table, the specific surface area is 880m when the above weight ratio is adopted 2 In the case of/Kg, when the amount of the admixture is 50%, the product manufactured by the method has the best compression resistance and activity index performance.
Note that: the base sample is the relevant data of the additive amount of the mineral powder with corresponding percentage content; the sample is the relevant data of the corresponding percentage of superfine powder admixture.
Example 2: the preparation method of the superfine powder cement admixture comprises the following raw materials in parts by weight: 50 kg of iron-making blast furnace slag, 40 kg of fly ash and 10 kg of industrial desulfurization slag are mixed together according to the weight proportion and ground into the powder with the specific surface area of 850m 2 Powder per Kg.
Figure BDA0004135083690000031
As can be seen from the analysis of the above table, the specific surface area was 850m when the above weight ratio was used 2 In the case of/Kg, when the amount of the admixture is 50%, the product manufactured by the method has the best compression resistance and activity index performance.
Note that: the base sample is the relevant data of the additive amount of the mineral powder with corresponding percentage content; the sample is the relevant data of the corresponding percentage of superfine powder admixture.
Example 3: the preparation method of the superfine powder cement admixture comprises the following raw materials in parts by weight: 33 kg of iron-making blast furnace slag, 52 kg of fly ash and 8 kg of industrial desulfurization slag are mixed together according to the weight proportion and ground into the specific surface area of 800m 2 Powder per Kg.
Figure BDA0004135083690000032
As is clear from the analysis of the above table, the specific surface area was 800m when the above weight ratio was used 2 In the case of/Kg, when the amount of the admixture is 40%,the product manufactured by the method has the best compression resistance and activity index performance.
Note that: the base sample is the relevant data of the additive amount of the mineral powder with corresponding percentage content; the sample is the relevant data of the corresponding percentage of superfine powder admixture.
Example 4: the preparation method of the superfine powder cement admixture comprises the following raw materials in parts by weight: 46 kg of iron-making blast furnace slag, 50 kg of fly ash and 6 kg of phosphogypsum are mixed together according to the weight proportion and ground into the powder with the specific surface area of 700m 2 Powder per Kg. The phosphogypsum is dried until the water content is 7-8 percent for use.
Figure BDA0004135083690000041
As can be seen from the analysis of the above table, the specific surface area was 700m when the above weight ratio was used 2 Under the condition of/Kg, when the content of the admixture is 30%, the product manufactured by the method has the best compression resistance and activity index performance.
Note that: the base sample is the relevant data of the additive amount of the mineral powder with corresponding percentage content; the sample is the relevant data of the corresponding percentage of superfine powder admixture.

Claims (3)

1. The preparation method of the superfine powder cement admixture is characterized by comprising the following raw materials in parts by weight: 30-50 parts of water slag, 40-65 parts of fly ash and 5-10 parts of industrial desulfurization slag, and the materials are mixed together according to the weight proportion and ground into the powder with the specific surface area of 700-880m 2 Powder per Kg.
2. The method for preparing the superfine powder cement admixture according to claim 1, which is characterized in that: the water slag is iron-making blast furnace slag.
3. The method for preparing the superfine powder cement admixture according to claim 1, which is characterized in that: the industrial desulfurization slag is replaced by phosphogypsum, and the phosphogypsum is dried until the water content is 7-8 percent, so that the industrial desulfurization slag can be used.
CN202310272089.6A 2023-03-20 2023-03-20 Method for preparing superfine powder cement admixture Pending CN116040974A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1401607A (en) * 2002-07-25 2003-03-12 中国建筑材料科学研究院 Composite low-heat-release high-active superfine powder concrete admixture and making method thereof
CN104030594A (en) * 2014-05-30 2014-09-10 山东众森科技股份有限公司 Nickel slag and manganese slag concrete compound admixture and preparation method thereof
CN106082753A (en) * 2016-06-12 2016-11-09 陕西建业环保科技有限公司 Superfine powder concrete admixture
CN110407492A (en) * 2019-08-21 2019-11-05 山东鲁碧建材有限公司 A kind of modified superfine fly ash aggregate
CN115432951A (en) * 2022-10-07 2022-12-06 江苏金木土科技有限公司 Preparation method of mineral admixture for commercial concrete
CN115466069A (en) * 2022-09-09 2022-12-13 安徽工业大学 Full-solid waste composite powder for cementing material and preparation method thereof
CN115490449A (en) * 2022-10-07 2022-12-20 江苏金木土科技有限公司 Preparation method of superfine mineral admixture

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1401607A (en) * 2002-07-25 2003-03-12 中国建筑材料科学研究院 Composite low-heat-release high-active superfine powder concrete admixture and making method thereof
CN104030594A (en) * 2014-05-30 2014-09-10 山东众森科技股份有限公司 Nickel slag and manganese slag concrete compound admixture and preparation method thereof
CN106082753A (en) * 2016-06-12 2016-11-09 陕西建业环保科技有限公司 Superfine powder concrete admixture
CN110407492A (en) * 2019-08-21 2019-11-05 山东鲁碧建材有限公司 A kind of modified superfine fly ash aggregate
CN115466069A (en) * 2022-09-09 2022-12-13 安徽工业大学 Full-solid waste composite powder for cementing material and preparation method thereof
CN115432951A (en) * 2022-10-07 2022-12-06 江苏金木土科技有限公司 Preparation method of mineral admixture for commercial concrete
CN115490449A (en) * 2022-10-07 2022-12-20 江苏金木土科技有限公司 Preparation method of superfine mineral admixture

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