CN115993435A - Method for improving accuracy of coal quality of boiler coal blending by utilizing primary mixed coal physical property analysis technology - Google Patents
Method for improving accuracy of coal quality of boiler coal blending by utilizing primary mixed coal physical property analysis technology Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及燃煤锅炉安全运行技术领域,更具体涉及一种利用初混煤物性分析技术提升锅炉掺煤煤质精准性的方法。The invention relates to the technical field of safe operation of coal-fired boilers, and more specifically relates to a method for improving the accuracy of coal quality of coal mixed in boilers by utilizing the physical property analysis technology of primary mixed coal.
背景技术Background technique
煤价直接决定了燃煤电厂的经营状况,在上网电价一定的情况下,燃煤价格是燃煤电厂赢利的关键,因此许多燃煤电厂都采用了掺烧低价劣质煤这一技术,以降低整体燃料成本。许多燃煤电厂锅炉长期处于非设计煤种燃烧状态下,燃煤电厂的锅炉设计是基于设计煤种和校核煤种的,若燃用设计煤种,锅炉的表现良好;但如果燃用非设计煤种,会使燃烧效果变差,运行稳定性下降,低负荷调峰困难,锅炉热效率降低,出现结焦、结渣、过热器超温,脱硫系统不适应,污染排放超标等问题。由于煤质偏离设计煤种,使得锅炉的煤炭热能利用率降低,造成了巨大的能源浪费。在煤种复杂多变,安全高效生产和国家政策的多重压力下,国内越来越多的燃煤电厂开展了混煤掺烧工作,以缓解锅炉燃烧非设计煤种引发的诸多问题。Coal price directly determines the operation status of coal-fired power plants. Under the condition of fixed on-grid electricity price, coal price is the key to the profit of coal-fired power plants. Lower overall fuel costs. Many coal-fired power plant boilers have been in the combustion state of non-design coal for a long time. The boiler design of coal-fired power plants is based on the design coal and check coal. If the design coal is used, the boiler performance is good; but if it is not Designing the type of coal will make the combustion effect worse, the operation stability will decrease, the low load peak regulation will be difficult, the thermal efficiency of the boiler will decrease, coking, slagging, overheating of the superheater will occur, the desulfurization system will not adapt, and the pollution discharge will exceed the standard. Because the coal quality deviates from the designed coal type, the coal heat utilization rate of the boiler is reduced, resulting in huge energy waste. Under the multiple pressures of complex and changeable coal types, safe and efficient production, and national policies, more and more coal-fired power plants in China have carried out blending coal blending to alleviate many problems caused by boilers burning non-design coal types.
燃煤电厂为降低燃料成本,普遍采用混煤掺烧模式,但是传统混煤掺配的方法中,所采用的煤质基础数据来源都为单一煤种煤质信息,掺配计算基础都是依托各个单一煤种,进行算法计算,得出掺配结果。而实际电厂来煤并非单一煤种或同一煤矿的直供煤源,大部分来煤已由单一煤种进行了初次掺混,以满足发热量、含硫量等几个数值参数要求,从而发生单一煤源无法准确溯源的现实问题,最终结果会导致掺配结果不理想,进而引发锅炉运行效率低、炉内结焦、高温腐蚀、受热面管壁超温、脱硫脱硝能耗高等一系列问题。In order to reduce fuel costs, coal-fired power plants generally adopt the blending mode of coal blending. However, in the traditional blending method, the basic data source of coal quality used is the information of a single type of coal, and the blending calculation basis is based on Each single coal type is calculated by algorithm to obtain the blending result. However, the actual incoming coal of the power plant is not a single type of coal or the direct supply coal source of the same coal mine. Most of the incoming coal has been blended with a single type of coal for the first time to meet the requirements of several numerical parameters such as calorific value and sulfur content. The actual problem that a single coal source cannot be accurately traced will eventually lead to unsatisfactory blending results, which will lead to a series of problems such as low boiler operation efficiency, coking in the furnace, high-temperature corrosion, overtemperature of the heating surface tube wall, and high energy consumption for desulfurization and denitrification.
鉴于目前混煤掺烧存在来煤结构复杂,大部分来煤已由不同单一煤种进行初混或者多个煤种进行初混,从而导致煤质无法准确溯源的现实问题,需进行提高燃煤电厂掺烧煤种煤质精准度的研究。In view of the fact that the current coal blending has a complex incoming coal structure, most of the incoming coal has been initially mixed with different single coal types or multiple coal types, resulting in the practical problem that the coal quality cannot be accurately traced, and it is necessary to improve the coal combustion. Research on coal quality accuracy of blended coal in power plants.
发明内容Contents of the invention
本发明需要解决的技术问题是提供一种利用初混煤物性分析技术提升锅炉掺煤煤质精准性的方法,以解决实际电厂来煤已由单一煤种进行了初次掺混,单一煤源无法准确溯源,而导致掺配结果不理想,引发锅炉运行安全性的问题。The technical problem to be solved in the present invention is to provide a method for improving the accuracy of boiler coal blending coal quality by using the analysis technology of the primary coal mixture, so as to solve the problem that the actual power plant incoming coal has been initially blended by a single coal type, and the single coal source cannot Accurate traceability leads to unsatisfactory blending results and causes problems in boiler operation safety.
为解决上述技术问题,本发明所采取的技术方案如下。In order to solve the above technical problems, the technical solutions adopted by the present invention are as follows.
利用初混煤物性分析技术提升锅炉掺煤煤质精准性的方法,包括以下步骤:The method for improving the accuracy of boiler coal blending coal quality by using the primary mixed coal physical property analysis technology includes the following steps:
S1、制成可供分析的标准煤样;S1, make the standard coal sample available for analysis;
S2、初混煤样品反射率分析:依托岩相分析方法分析电厂初混煤结构;S2. Reflectance analysis of primary mixed coal samples: relying on petrographic analysis methods to analyze the structure of primary mixed coal in power plants;
S3、初混煤样品工业分析化验,分别检测出不同初混煤样品的成分及各项指标;S3. Industrial analysis and testing of primary mixed coal samples to detect the components and various indicators of different primary mixed coal samples;
S4、初混煤样品元素分析化验;S4. Elemental analysis and testing of primary mixed coal samples;
S5、结合燃煤工业分析、元素分析数据,确定初混煤的特性关系,形成初混煤燃烧物性特性,获得初混煤质基础信息;S5. Combining the coal-fired industrial analysis and elemental analysis data, determine the characteristic relationship of the primary mixed coal, form the combustion physical properties of the primary mixed coal, and obtain the basic information of the primary mixed coal quality;
S6、根据准确的初混煤质基础信息,制定适合锅炉的掺配方案。S6. Formulate a blending scheme suitable for the boiler according to the accurate primary coal quality basic information.
进一步优化技术方案,所述步骤S2中,分析电厂初混煤结构包括以下方面:To further optimize the technical solution, in the step S2, analyzing the initial mixed coal structure of the power plant includes the following aspects:
鉴别初混煤类别;Identify the type of primary coal mixture;
判断煤样是否为单一混煤或多种混煤;Judging whether the coal sample is a single mixed coal or multiple mixed coals;
分析煤样不同煤种的成分比例。Analyze the composition ratio of different coal types in coal samples.
进一步优化技术方案,所述步骤S2中,初混煤结构主要依据测试混煤镜质组的平均最大反射率Rmax和镜质组反射率分布图进行判断的,通过平均最大反射率Rmax判断初混煤类别,通过镜质组反射率分布图判断煤的变质程度及混煤类别。To further optimize the technical solution, in the step S2, the primary mixed coal structure is mainly judged based on the average maximum reflectance Rmax of the tested coal vitrinite and the distribution map of the vitrinite reflectance, and the primary mixed coal structure is judged by the average maximum reflectance Rmax Coal type, the metamorphic degree of coal and the type of mixed coal can be judged by the vitrinite reflectance distribution map.
进一步优化技术方案,所述初混煤类别包括:无烟煤、贫煤、贫瘦煤、瘦煤、焦煤、肥煤、气肥煤、气煤、弱黏煤、长焰煤、褐煤。To further optimize the technical solution, the primary mixed coal categories include: anthracite, lean coal, lean coal, lean coal, coking coal, fat coal, gas fat coal, gas coal, weakly sticky coal, long-flame coal, and lignite.
进一步优化技术方案,通过镜质组反射率分布图判断煤的混煤类别的判别依据为:To further optimize the technical scheme, the basis for judging the coal blending type of coal through the vitrinite reflectance distribution map is:
从镜质组反射率分布图统计凹口数,根据镜质体反射率标准差和反射率频率分布图中的凹口数,并按照商品煤反射率分布图编码系统的规定对应商品煤的混煤类型进行判别。The number of notches is counted from the vitrinite reflectance distribution map, according to the standard deviation of vitrinite reflectance and the number of notches in the reflectance frequency distribution map, and according to the provisions of the coding system of commercial coal reflectance distribution map, it corresponds to the coal blending type of commercial coal Make a judgment.
进一步优化技术方案,所述步骤S3中,通过燃煤工业分析,分别检测出不同初混煤样品的水分、挥发分、灰分和固定碳成分,以及硫含量和热值各项指标。To further optimize the technical solution, in the step S3, the moisture, volatile matter, ash and fixed carbon components of different primary mixed coal samples, as well as indicators of sulfur content and calorific value are detected respectively through coal-fired industrial analysis.
由于采用了以上技术方案,本发明所取得技术进步如下。Due to the adoption of the above technical solutions, the technological progress achieved by the present invention is as follows.
本发明利用岩相分析方法并依据镜质组平均最大反射率和分布图来分析电厂初混煤结构,同时结合燃煤工业分析、元素分析数据,确定初混煤的挥发分,灰熔点等特性关系,形成初混煤燃烧物性特性,获得初混煤质基础信息,用于指导混煤掺配方案,提高了掺配合理性,满足了锅炉燃烧需求,解决了锅炉安全问题,提升了燃煤锅炉掺烧煤种煤质精准性,降低了生产成本,提高了机组的安全稳定性。The present invention uses the lithofacies analysis method and according to the average maximum reflectance and distribution map of vitrinite to analyze the structure of primary mixed coal in the power plant, and at the same time combines the coal-fired industrial analysis and elemental analysis data to determine the characteristics of the primary mixed coal such as volatile matter and ash melting point relationship, form the combustion physical properties of the initial mixture coal, obtain the basic information of the initial mixture coal quality, and use it to guide the blending scheme of coal blending, improve the blending rationality, meet the boiler combustion needs, solve the boiler safety problem, and improve the quality of coal-fired boilers. The accuracy of coal quality by blending coal types reduces production costs and improves the safety and stability of the unit.
本发明有效缓解了由于煤质不准导致掺烧不合理引的发锅炉燃烧安全问题,如炉膛结焦、高温腐蚀、管壁超温等。The invention effectively alleviates the boiler combustion safety problems caused by unreasonable mixed combustion due to inaccurate coal quality, such as coking in the furnace, high-temperature corrosion, overtemperature of the pipe wall, and the like.
本发明通过依据准确的煤质数据进行合理掺配,降低了锅炉污染物生成量,缓解了烟气污染物排放的压力。The invention reduces the amount of pollutants generated by boilers and relieves the pressure of flue gas pollutants by performing reasonable blending based on accurate coal quality data.
本发明通过依据准确的煤质数据进行合理掺配,提高了锅炉经济性,扩宽煤种适应范围,使燃煤采购更加灵活,减少了发电成本。The invention improves the economical efficiency of the boiler, widens the adaptable range of coal types, makes the purchasing of coal more flexible, and reduces the cost of power generation by performing reasonable blending based on accurate coal quality data.
附图说明Description of drawings
图1为本发明的流程示意图;Fig. 1 is a schematic flow sheet of the present invention;
图2为本发明商品煤反射率分布图编码系统相应的典型分布图。Fig. 2 is a typical distribution diagram corresponding to the encoding system of commercial coal reflectance distribution diagram according to the present invention.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
利用初混煤物性分析技术提升锅炉掺煤煤质精准性的方法,包括以下步骤:The method for improving the accuracy of boiler coal blending coal quality by using the primary mixed coal physical property analysis technology includes the following steps:
S1、针对用于燃煤锅炉掺烧的不同初混煤进行标准化采样,统一分组编号,制成可供分析的标准煤样。S1. Carry out standardized sampling for different primary mixed coals used for blending in coal-fired boilers, and unify the group numbers to make standard coal samples available for analysis.
S2、初混煤样品反射率分析。本发明利用岩相分析方法并依据镜质组平均最大反射率和分布图来分析电厂初混煤结构,岩相分析方法是通过岩相分析仪对初混煤的结构进行分析辨别。S2. Analysis of the reflectance of the primary mixed coal sample. The invention uses a lithofacies analysis method to analyze the structure of primary mixed coal in a power plant according to the average maximum reflectance and distribution diagram of vitrinite. The lithofacial analysis method uses a lithofacies analyzer to analyze and distinguish the structure of primary mixed coal.
步骤S2中,分析电厂初混煤结构包括以下方面:In step S2, analyzing the initial coal mix structure of the power plant includes the following aspects:
鉴别初混煤类别,初混煤类别包括无烟煤、贫煤、贫瘦煤、瘦煤、焦煤、肥煤、气肥煤、气煤、弱黏煤、长焰煤、褐煤等。Identify the type of primary coal mixture, which includes anthracite, lean coal, lean coal, lean coal, coking coal, fat coal, gas fat coal, gas coal, weakly sticky coal, long-flame coal, lignite, etc.
判断煤样是否为单一混煤或多种混煤。Determine whether the coal sample is a single coal blend or multiple coal blends.
分析煤样不同煤种的成分比例。Analyze the composition ratio of different coal types in coal samples.
依托岩相分析方法并通过岩相分析仪来对初混煤的结构进行分析辨别,主要依据测试混煤镜质组的两个指标来判断。初混煤结构主要依据测试混煤镜质组的平均最大反射率Rmax和镜质组反射率分布图进行判断的,通过平均最大反射率Rmax判断初混煤类别,通过镜质组反射率分布图判断煤的变质程度及混煤类别。Relying on the petrographic analysis method and using the petrographic analyzer to analyze and identify the structure of the primary mixed coal, it is mainly judged based on the two indicators of the vitrinite of the mixed coal. The primary mixed coal structure is mainly judged based on the average maximum reflectance Rmax of the vitrinite and the distribution map of the vitrinite reflectance of the tested coal mixture. Judging the metamorphic degree of coal and the type of mixed coal.
1.平均最大反射率Rmax1. Average maximum reflectance Rmax
镜质组反射率测试原理:一束入射光照射到煤岩光片的抛光表面,其中镜质组颗粒上的546nm反射光进入光电转换器,由光信号转换成微弱的电信号,经仪器放大后由精密仪器测出,再与标准物质所得数据进行对比计算,结果即为镜质组反射率,用Rmax来表示。The principle of vitrinite reflectance test: a beam of incident light is irradiated on the polished surface of the coal rock optical film, and the 546nm reflected light on the vitrinite particles enters the photoelectric converter, and the optical signal is converted into a weak electrical signal, which is amplified by the instrument After that, it is measured by precision instruments, and then compared with the data obtained by the standard substance, the result is the vitrinite reflectance, which is expressed by Rmax.
最大反射率平均值Rmax与煤种的对应关系如下表所示:The corresponding relationship between the maximum reflectance average value Rmax and the coal type is shown in the following table:
2.镜质组反射率分布图2. Vitrinite reflectance distribution map
根据煤的镜质组反射率及其分布图,判断煤的变质程度及其混煤状况。图像分析法是依据图像灰度级与反射率的相关性,通过灰度测定煤中包括镜质组在内的所有组分的反射率,采用特殊的处理方法去掉非镜质组反射率,得到镜质组平均反射率及其分布图。测定时先将煤样品制成粉煤光片,测定前用标准片进行仪器标定。According to the vitrinite reflectance and distribution map of coal, the metamorphic degree of coal and its mixed coal status can be judged. The image analysis method is based on the correlation between the gray level of the image and the reflectance, and the reflectance of all components in the coal including the vitrinite is measured through the gray scale, and the reflectance of the non-vitrinite is removed by a special processing method to obtain The average reflectance of vitrinite and its distribution map. During the measurement, the coal sample is first made into a pulverized coal light sheet, and the standard sheet is used to calibrate the instrument before the measurement.
本发明镜质组反射率分布图的绘制过程为:以反射率间隔0.05%为半阶,分别统计各间隔的测点数并计算出频率(f)。以频率为纵坐标,随机反射率(Rran)为横坐标绘制出镜质组反射率分布图。The drawing process of the vitrinite reflectance distribution diagram of the present invention is as follows: take the reflectivity interval of 0.05% as the half order, respectively count the number of measuring points in each interval and calculate the frequency (f). Taking the frequency as the vertical axis and the random reflectance (Rran) as the horizontal axis, the vitrinite reflectance distribution diagram is drawn.
通过镜质组反射率分布图判断煤的混煤类别的判别依据为:从镜质体反射率间隔为0.05%的镜质组反射率分布图统计“凹口数”,根据镜质体反射率标准差和反射率频率分布图中的凹口数,并按照表1所示的商品煤反射率分布图编码系统的规定对应商品煤的混煤类型进行判别。商品煤反射率分布图编码系统相应的典型分布图如图2所示。According to the vitrinite reflectance distribution map, the basis for judging the coal blending type of coal is: the "notch number" is counted from the vitrinite reflectance distribution map with a vitrinite reflectance interval of 0.05%, and according to the vitrinite reflectance standard The difference and the number of notches in the frequency distribution map of reflectance, and according to the provisions of the coding system of the reflectance distribution map of commercial coal shown in Table 1, are used to distinguish the type of mixed coal of commercial coal. The corresponding typical distribution diagram of the commercial coal reflectance distribution diagram coding system is shown in Fig. 2.
表1商品煤反射率分布图编码系统Table 1 Coding system of commercial coal reflectance distribution map
注:具编码1特性的反射率分布图也可能为高阶烟煤、无烟煤的单一煤层煤。Note: The reflectance distribution map with the characteristics of
S3、初混煤样品工业分析化验,通过燃煤工业分析,分别检测出不同初混煤样品的水分、挥发分、灰分和固定碳等成分,以及硫含量和热值等各项指标S3. Industrial analysis and testing of primary mixed coal samples. Through industrial analysis of coal combustion, the moisture, volatile matter, ash, fixed carbon and other components of different primary mixed coal samples, as well as various indicators such as sulfur content and calorific value, were detected.
S4、初混煤样品元素分析化验。对不同初混煤样品的元素含量进行检测和分析,包括常规的C、H、O、N、S、Al、Si、Fe、Ca等元素含量,还可检测煤中的痕量元素包括Ti、Na、K等。元素分析是研究煤的变质程度,计算煤的发热量,估算煤的干馏产物的重要指标,也是工业中以煤作燃料时进行热量计算的基础。S4. Elemental analysis and testing of primary mixed coal samples. Detect and analyze the element content of different primary mixed coal samples, including conventional C, H, O, N, S, Al, Si, Fe, Ca and other element contents, and also detect trace elements in coal including Ti, Na, K, etc. Elemental analysis is an important indicator for studying the degree of metamorphism of coal, calculating the calorific value of coal, and estimating the carbonization products of coal. It is also the basis for calorie calculation when coal is used as fuel in industry.
S5、初混煤样燃烧物性特性分析,依托岩相分析方法,分析电厂初混煤煤种及比例,同时结合燃煤工业分析、元素分析数据,确定初混煤的的挥发分,灰熔点等特性关系,形成初混煤燃烧物性特性,获得初混煤质基础信息。S5. Analysis of the combustion properties of primary mixed coal samples. Relying on petrographic analysis methods, analyze the coal types and proportions of primary mixed coal in power plants, and combine coal industry analysis and elemental analysis data to determine the volatile content and ash melting point of primary mixed coal, etc. Characteristic relationship, forming the combustion physical properties of the primary mixture coal, and obtaining the basic information of the primary mixture coal quality.
S6、根据准确的初混煤质基础信息,为混煤掺烧提供较为准确的煤质数据支持,再根据不同锅炉燃烧方式及特性和掺配需求制定适合锅炉安全稳定经济的掺配方案。S6. According to the accurate primary coal quality basic information, provide more accurate coal quality data support for coal blending, and then formulate a safe, stable and economical blending plan for boilers according to different boiler combustion methods and characteristics and blending requirements.
本发明利用岩相分析方法并依据镜质组平均最大反射率和分布图来分析电厂初混煤结构,同时结合燃煤工业分析、元素分析数据,确定初混煤的挥发分,灰熔点等特性关系,形成初混煤燃烧物性特性,获得初混煤质基础信息,用于指导混煤掺配方案,提高了掺配合理性,满足了锅炉燃烧需求,解决了锅炉安全问题,提升了燃煤锅炉掺烧煤种煤质精准性,降低了生产成本,提高了机组的安全稳定性。The present invention uses the lithofacies analysis method and according to the average maximum reflectance and distribution map of vitrinite to analyze the structure of primary mixed coal in the power plant, and at the same time combines the coal-fired industrial analysis and elemental analysis data to determine the characteristics of the primary mixed coal such as volatile matter and ash melting point relationship, form the combustion physical properties of the initial mixture coal, obtain the basic information of the initial mixture coal quality, and use it to guide the blending scheme of coal blending, improve the blending rationality, meet the boiler combustion needs, solve the boiler safety problem, and improve the quality of coal-fired boilers. The accuracy of coal quality by blending coal types reduces production costs and improves the safety and stability of the unit.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.
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