CN115961414A - Persistent antibacterial anti-mite antistatic wool fabric and production method thereof - Google Patents

Persistent antibacterial anti-mite antistatic wool fabric and production method thereof Download PDF

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Publication number
CN115961414A
CN115961414A CN202211717028.8A CN202211717028A CN115961414A CN 115961414 A CN115961414 A CN 115961414A CN 202211717028 A CN202211717028 A CN 202211717028A CN 115961414 A CN115961414 A CN 115961414A
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antibacterial
fiber
mite
fabric
metal ions
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刘文博
王耀民
张正乐
胡雪丽
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Shanghai Liangfeng Leading Technology Development Co ltd
Shanghai Liangfeng New Material Technology Co ltd
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Shanghai Liangfeng Leading Technology Development Co ltd
Shanghai Liangfeng New Material Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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Abstract

The invention relates to the technical field of textiles and provides a durable antibacterial anti-mite antistatic velvet fabric and a production method thereof, wherein 3-10wt% of natural mineral antibacterial filaments and other yarns are knitted at intervals to obtain antibacterial grey cloth with a looped pile or cut pile structure; the natural mineral antibacterial filament is prepared by acquiring positively charged metal ions from natural minerals and then spinning the metal ions and a chemical fiber carrier or a regenerated fiber carrier in a pressure spinning mode, wherein the positively charged metal ions account for 0.5-2wt% of the fiber carrier; and dyeing and post-finishing the antibacterial gray fabric to obtain the durable antibacterial, anti-mite and antistatic velvet fabric. The natural mineral antibacterial fiber wool fabric has lasting antibacterial and anti-mite performances, is soft and comfortable, and has excellent antibacterial and anti-mite performances which can last to be washed for more than 50 times; can also eliminate static trouble and keep the product clean, has washing fastness, ecological safety and the like, and is beneficial to application.

Description

Persistent antibacterial anti-mite antistatic velvet fabric and production method thereof
Technical Field
The invention relates to the technical field of textiles, in particular to a durable antibacterial, anti-mite and antistatic velvet fabric and a production method thereof.
Background
At present, people have strong demand for antibacterial performance of textiles, and put higher demands on the antibacterial performance of the textiles, and consumers pursuing 'durability and comfort' of the functions of the textiles are increasing. In addition, with the enhancement of environmental awareness of people, the environmental requirements of the textile industry are more strict, and the functional textiles develop towards durability and washability.
The textile fabric has two main approaches for realizing the antibacterial function, namely, antibacterial fiber is adopted; firstly, the antibacterial auxiliary agent is adopted for finishing and processing. The mode of finishing by adopting the antibacterial auxiliary agent is a simpler and direct mode, and the cost is relatively low. However, in addition to the common problem of antimicrobial durability, various antimicrobial aids also have problems with each type of antimicrobial aid. The antibacterial fiber includes natural antibacterial fiber, regenerated antibacterial fiber and synthetic antibacterial fiber. The wash durability of the antimicrobial function can be substantially solved by using the antimicrobial fiber, but there is a limitation. Natural antimicrobial fibers are of few species relative to synthetic fibers. The fibrilia is a common natural antibacterial fiber, but the fibrilia is rigid and has poor cohesion; the fabric has the advantages of rough hand feeling, non-slip and comfortable wearing, easy wrinkling, poor drapability and limited application.
For the soft and comfortable hand feeling of the velvet textiles, the velvet textiles are knitted fabrics with structures such as terry or cut velvet, and are mainly used at home in winter at present. Due to the use scenes and technical limitations, the existing velvet fabrics (including face yarns and ground yarns) basically have no antibacterial and anti-mite functions; even if the antibacterial and anti-mite function is realized, the antibacterial and anti-mite function is mainly realized by adding a chemical auxiliary agent through a padding technology, the general antibacterial action can only be maintained for about 10 times, and the durable antibacterial action is difficult to achieve (the antibacterial action is qualified after 50 times of water washing). Compared with light and thin textiles such as silk cloth and the like, the velvet fabric has the problems of being troublesome to wash and dry, not easy to dry and the like, so people usually have relatively few washing times, and are more easy to cause breeding of bacteria and mites. The washing frequency of the velvet fabric is reduced due to the trouble of washing the velvet fabric, so that bacteria and mites are easy to breed on the velvet fabric, and a plurality of hidden dangers in the aspect of sanitation are brought.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the durable antibacterial anti-mite antistatic wool fabric and the production method thereof.
The invention provides a durable antibacterial anti-mite antistatic velvet fabric which comprises 3-10wt% of natural mineral antibacterial fibers, wherein the natural mineral antibacterial fibers are prepared by acquiring positively charged metal ions from natural minerals and then spinning the positively charged metal ions with a chemical fiber carrier or a regenerated fiber carrier, and the positively charged metal ions account for 0.5-2wt% of the fiber carrier.
The functional velvet fabric provided by the invention can simultaneously meet the requirements of softness and comfort, antibiosis and mite prevention of products, keeping of cleanness of the products and the like, has washing fastness, and has excellent antibiosis and mite prevention performance which can last for more than 50 times of washing, thereby effectively solving the trouble in the aspect of the prior art.
In some embodiments of the invention, the natural mineral antimicrobial fiber is low stretch yarn or fully drawn yarn, the fiber carrier component is terylene and/or nylon, and the fiber fineness is between 30D and 150D.
In some embodiments of the invention, the natural mineral antimicrobial fibers are staple fibers and the fibrous carrier component is polyester or viscose.
The velvet fabric product provided by the embodiment of the invention adopts natural mineral substance antibacterial short fibers or long fibers in a certain proportion; the natural mineral antibacterial functional fiber is prepared by acquiring positively charged metal ions (preferably positively charged silver ions) from natural minerals and then carrying out pressure spinning with a chemical fiber carrier or a regenerated fiber carrier, namely, the natural mineral antibacterial component is permanently implanted into the fiber in the yarn making stage. In the embodiment of the invention, the antibacterial and anti-mite fiber is directly woven or is woven after mixed spinning, so that the antibacterial and anti-mite function for a long time is added into the velvet fabric, and the soft and comfortable hand feeling of the fabric can be maintained.
In the natural mineral antibacterial fiber, positively charged metal ions account for 0.5-2wt% of the fiber carrier, preferably 0.8-1.5%; for example, positively charged silver ions are permanently implanted into the fiber, and the positively charged silver ions generally account for about 1% of the fiber support. In the embodiment of the invention, the functional fiber yarn has two choices of filament and staple; filaments, also known as continuous filaments, are a type of morphology of chemical fibers, whereas chemical fiber staple fibers are processed by spinning processes. Preferably, the natural mineral antibacterial fiber filament comprises terylene and/or nylon as main fiber components, has a fiber fineness of 30D-150D, and can be DTY low stretch yarn or FDY fully drawn yarn. Preferably, the main fiber component of the natural mineral antibacterial short fiber comprises terylene and viscose, the fineness of the short fiber is 1-6D, the length specification is generally 38-64mm, and the specific example is 1.5D 38mm.
The natural mineral antibacterial fiber filament and the short fiber can be added into the fabric by different methods, the antibacterial filament can be directly used for weaving the fabric together with other fibers, and the antibacterial short fiber is used for weaving the fabric after being blended with other fibers and re-spun. Specifically, the blending proportion is determined according to the type and weaving process of the fabric and the final antibacterial requirement, the thickness of the yarn is between 20 and 80S, and the yarn can be ring spinning, siro spinning, tight-match spinning or vortex spinning. Finally, the natural mineral antibacterial fiber component accounts for 3-10% of the mass of the whole fabric, so that the antibacterial effect meets the test requirement, and the soft hand feeling is ensured. Preferably, the durable antibacterial anti-mite antistatic wool fabric comprises 3.5-9wt% of natural mineral antibacterial fibers.
In addition, most of the existing velvet fabric is terylene, so that the conductivity is poor, and static trouble and low wearing comfort are caused by static electricity easily generated due to environmental drying in dry winter; in the market, the antistatic function is generally increased by padding an antistatic auxiliary agent or adding conductive yarns and other technologies, the static trouble caused by drying in winter is eliminated, but the performance is weakened or even disappears as the washing times are increased to about 10 times.
In a preferred embodiment of the invention, the durable antibacterial anti-mite antistatic velvet fabric further comprises conductive filaments (also called antistatic filaments or yarns), the titer is 20D-40D, and the main fiber component is terylene and/or nylon. The invention also realizes the superposition of the antibacterial anti-mite and the lasting antistatic effects on the woolen fabric, and simultaneously maintains the soft and comfortable hand feeling of the woolen fabric.
The antistatic yarns are generally rough, and are always spaced in the ground yarns in the specific embodiment of the invention so as not to influence the hand feeling of the woolen fabric. The conductive fiber filament according to the embodiment of the invention is a conductive fiber obtained by melt spinning a high-concentration conductive slice containing conductive particles and a polyester or nylon material. The thickness of the single conductive fiber is between 20D and 40D, the strength of the single conductive fiber is insufficient, and the single conductive fiber is suitable for weaving only by doubling and plying with other yarns. In the embodiment of the invention, the conductive fibers generally account for 1-3% of the whole mass of the fabric.
The embodiment of the invention selects the organic conductive fiber taking carbon as a conductive substance, the organic conductive substance is blended with fiber carrier substances such as polyester and the like, and the bicomponent blended melt-spun composite filament has good performances of washing resistance, wear resistance, bending resistance and the like, overcomes the defect that inorganic conductive fibers such as metal fibers and carbon fibers are not bending-resistant, and is permanently antistatic. The fiber fineness of the conductive filament is 20-40D, and the main component of the fiber is terylene or nylon, so that the flexibility of the fabric yarn is not damaged. The conductive filaments are generally applied and spaced in the ground filaments, the fiber number is selected according to the fabric and the process, and the application proportion in the fabric is controlled to be between 1 and 5cm of the spacing between the conductive filaments.
The durable antibacterial anti-mite antistatic wool fabric can be dyed or printed, and the color fastness of the product is 3-4 grade or above; the gram weight of the finished fabric product can be 180-800g/m 2 In the meantime. In some embodiments of the invention, the main component of the fabric is polyester, the proportion of the antibacterial fiber is 3.5%, and the proportion of the conductive fiber is 2%; the velvet fabric has a structure with one side plain woven and the other side looped pile. In other embodiments of the invention, the main components of the fabric are polyester and spandex, the proportion of the antibacterial fiber is 4%, and the proportion of the conductive fiber is 1%.
The embodiment of the invention provides a production method of a durable antibacterial, anti-mite and antistatic velvet fabric, which comprises the following steps:
knitting 3-10wt% of natural mineral antibacterial filament yarn and other yarns at intervals to obtain antibacterial grey cloth with a looped pile or cut pile structure; the number of weaving equipment is 30-180, and the rotating speed range of the weaving machine is 50-200 r/min. The natural mineral antibacterial filament is prepared by acquiring positively charged metal ions from natural minerals and then spinning the metal ions and a chemical fiber carrier or a regenerated fiber carrier in a pressure spinning mode, wherein the positively charged metal ions account for 0.5-2wt% of the fiber carrier;
and dyeing and post-finishing the antibacterial gray fabric to obtain the durable antibacterial, anti-mite and antistatic velvet fabric.
The embodiment of the invention provides the preparation method of the durable antibacterial anti-mite anti-static wool fabric, and the obtained antibacterial fabric has excellent performances of softness, comfort, safety, environmental protection, broad-spectrum antibacterial anti-mite property, good washing fastness, difficult deformation and the like, and has a good market prospect.
The embodiment of the invention can adopt the antibacterial filament, the conductive yarn and the common yarn, and the antibacterial grey cloth is obtained by weaving the antibacterial filament, the conductive yarn and the common yarn by a conventional knitting structure of a knitting loom; the structure comprises a loop or cut pile. The common yarn is mainly made of terylene or nylon synthetic fiber, and can also comprise spandex filaments; the thickness of the yarn count is between 50 and 300D, and the thickness of the spandex is between 20 and 70D.
The antibacterial filament is made by acquiring positively charged metal ions from natural minerals and then spinning the metal ions with a chemical fiber carrier or a regenerated fiber carrier in a spinning mode, wherein the positively charged metal ions account for 0.5-2wt% of the fiber carrier; the embodiment of the invention adopts corresponding commercial fiber products. In the weaving process of the fabric provided by the embodiment of the invention, different from other existing velvet fabrics, the antibacterial and anti-mite yarns are arranged in the middle of the common fiber yarns at intervals according to the content of 3-10 wt%; the antibacterial fiber can be added to the surface yarn or the bottom yarn. When the antibacterial fiber is used for the surface yarn, the distance between the antibacterial fiber and the common fiber is 0.5-2cm, and when the antibacterial fiber is used for the bottom yarn, the distance between the antibacterial fiber and the common fiber is 0.2-1cm.
The embodiment of the invention weaves the antibacterial filament and other yarns together to form a fabric; the other yarns comprise conductive filaments and ordinary chemical fiber filaments, wherein the conductive filaments are generally spaced in the ground yarns, and the spacing between the conductive filaments is preferably controlled to be between 1cm and 5cm. The conductive filament is obtained by performing double-component melting composite spinning on high-concentration conductive slices containing conductive particles and a polyester and nylon material; the embodiment of the invention adopts a corresponding commercially available conductive fiber product, the fineness of the conductive fiber product is 20D-40D, and the main fiber component is terylene and/or nylon.
Specifically, the conductive filament preferably accounts for 1-3% of the mass of the antibacterial grey cloth. According to the embodiment of the invention, the antibacterial filament yarns and the antistatic yarns can be directly woven into the bottom yarn part in a spaced mode; alternatively, the antimicrobial filament yarns are woven directly into the veil portions in a spaced apart manner, above and below the antistatic yarns. That is, the antimicrobial filaments may be spaced between the ground filaments or between the face filaments. The application proportion of the invention is controlled to be 3-10% of the antibacterial fiber, which can achieve good antibacterial effect and anti-mite effect, and simultaneously ensure the hand feeling of the fabric. In addition, the common chemical fiber filament includes but is not limited to: polyester such as conventional spun terylene, nylon (chinlon) and spandex.
After the antibacterial gray fabric is obtained, the embodiment of the invention sequentially performs dyeing and after-finishing, thereby producing the durable antibacterial anti-mite antistatic velvet fabric.
Meanwhile, according to different fiber forms of natural mineral antibacterial fibers, the embodiment of the invention provides another production method of a durable antibacterial anti-mite antistatic velvet fabric, which comprises the following steps:
blending natural mineral antibacterial short fibers and other short fibers into antibacterial composite yarns, and then knitting to obtain antibacterial grey cloth with a looped pile or cut pile structure; the natural mineral antibacterial short fiber is prepared by acquiring positively charged metal ions from natural minerals and then spinning the metal ions and a chemical fiber carrier or a regenerated fiber carrier in a pressure spinning mode, wherein the positively charged metal ions account for 0.5-2wt% of the fiber carrier; the natural mineral antibacterial short fibers account for 3-10% of the mass of the antibacterial gray fabric;
and dyeing and post-finishing the antibacterial gray fabric to obtain the durable antibacterial, anti-mite and antistatic velvet fabric.
The antibacterial short fiber provided by the embodiment of the invention has the same function with the natural mineral antibacterial filament related to the above, and only has certain difference in fiber form, carrier and the like; the antibacterial staple fiber contains terylene and viscose, and the fiber is generally 1-2D 28-44mm. After the antibacterial fiber short fibers and other fibers (preferably including conductive fibers) are mixed and spun, all the antibacterial fiber short fibers can be woven into ground yarns or surface yarns to form a fabric; the blending proportion is determined according to the category and weaving process of the fabric and the final antibacterial requirement, the thickness of the yarn is between 20 and 80S, and the antibacterial composite yarn can be prepared by ring spinning, siro spinning, tight match spinning or vortex spinning.
According to the embodiment of the invention, the prepared antibacterial composite yarn, spandex yarn, conductive yarn and other yarns are woven by a conventional knitting structure through a knitting loom to obtain the antibacterial gray fabric. Similarly, other yarns are basically mainly made of terylene or nylon synthetic fibers, the yarn count is 50-300D, and the thickness of spandex is 20-70D.
Further, the antibacterial grey cloth is subjected to dyeing and post-finishing procedures to obtain the durable antibacterial anti-mite antistatic wool fabric.
The embodiment of the invention has no special limitation on the dyeing and finishing processes; the dyeing treatment may be performed by a high-temperature high-pressure dyeing process using a disperse dye. In the embodiment of the invention, the dyeing is carried out according to the process curve shown in fig. 1, the oil can be refined and removed from 40 ℃, then the temperature is raised to 50 ℃, the disperse dye, the dyeing auxiliary agent, the anhydrous sodium sulphate and the glacial acetic acid are added, the temperature is raised to 130 ℃, the dyeing is carried out for 4 hours, after the dyeing is finished, the softening treatment can be carried out at 80-90 ℃, and finally the soaping is carried out at 60 ℃. Taking out of the vat, dehydrating, scutching and drying, wherein the drying temperature can be 150 ℃; and then adding a napping auxiliary agent, namely napping oil and a fluffing agent into the setting machine, wherein the napping oil is generally dimethyl silicone oil, and the fluffing agent is mainly amino modified organic silicon emulsion.
In a specific embodiment of the invention, the post-finishing process comprises the steps of napping, carding, shearing, pilling, tentering and setting in sequence to obtain the finished product of the velvet fabric. The post-finishing process flow is operated under conventional conditions, and finally, tentering and setting are preferably carried out at the temperature of 150-170 ℃ to obtain the finished antibacterial fabric.
Compared with the prior art, the natural mineral antibacterial fiber wool fabric has lasting antibacterial and anti-mite performances, is soft and comfortable, and can be washed for more than 50 times continuously due to the excellent antibacterial and anti-mite performances. The fabric with lasting antibacterial, anti-mite and durable antistatic effects, prepared by the embodiment of the invention, is soft and comfortable in hand feeling, can eliminate static troubles and keep the requirement of product cleanness, has washing resistance, ecological safety and the like, and has good market prospect.
Drawings
FIG. 1 is a graph of a dyeing process in some embodiments of the present invention;
fig. 2 is a front view of some antibacterial, anti-mite and anti-static lint in accordance with embodiments of the present invention.
Detailed Description
The technical solutions in the embodiments of the present application are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
In order to better understand the technical content of the present invention, specific examples are provided below to further illustrate the durable antibacterial, anti-mite and anti-static wool fabric and the production method thereof. In the following examples, the natural mineral antibacterial fiber is polyester or nylon fiber containing silver mineral, the silver mineral is mainly silver oxide or salt compound or mixture of the two, such as silver oxide, silver nitrate, silver sulfate, etc., and the silver ion content is 0.5-2wt% of the fiber. In the examples, the antibacterial fiber is specifically polyester fiber containing silver oxide ore, 75D, and the silver ion content is 1%. The conductive fiber is nylon or terylene containing carbon, the content of the carbon accounts for 0.1 to 0.5 percent of the fiber, and the carbon is mainly one or more of conductive carbon black, graphite and carbon fiber. In the embodiment, the conductive fiber is polyester fiber taking carbon as a conductive substance, 50D, and the carbon content is 0.3%.
The fabric performance test method comprises the following steps:
and (4) washing by adopting a GB/T8629-2017A type washing machine 4N method, and detecting the washing size change rate of the finished product.
Evaluation of antibacterial properties of textile by GBT 20944.3-2008, part 3: and (4) detecting the antibacterial performance of the finished fabric by an oscillation method. And the antibacterial property after washing refers to the result of testing after washing for 50 times according to the 4N method of a GB/T8629-2017A type washing machine, and the qualified antibacterial property is the lasting antibacterial property. "antibacterial qualified" is referred to standard GB/T20944.3-2008 as 12.5.
And (4) testing the anti-mite performance of the fabric by adopting the GBT 24253-2009 textile anti-mite performance evaluation. And the washed anti-mite means that the anti-mite is qualified and is the lasting anti-mite according to the result of a test after being washed for 50 times by a 4N method of a GB/T8629-2017A type washing machine.
Evaluation of electrostatic Properties of textiles using GB/T12703.3-2009 section 3: and (4) evaluating the antistatic performance of the fabric according to the charge quantity, and determining that the test data is less than or equal to 0.6, namely the fabric is in compliance. After washing, the antistatic performance means that the antistatic performance is qualified and is the lasting antistatic performance according to the result of a test after washing for 15 times by a GB/T8629-2017A type washing machine 4N method.
Example 1
In the embodiment, the natural mineral antibacterial fiber is 70D/36F terylene DTY filament, and the conductive fiber is (terylene 50D FDY + chinlon 20D) composite conductive fiber. The surface yarn adopts 150D/288F superfine polyester filament, and the bottom yarn adopts 100D/36F polyester fiber.
The circular knitting machine was a circular weft knitting machine with a 30 inch diameter cylinder with 22 needles per inch. The 72-path surface yarn is 150D/288F superfine polyester yarn. 32 paths of bottom yarns are arranged, common 100D/36F yarns and antibacterial yarns are arranged at intervals of 70D/36F, the conductive yarns are bound on the 100D/36F yarns and then are sequenced with the bottom yarns, the proportion of the antibacterial fibers is 3.5%, and the proportion of the conductive fibers is 2%. Enough yarn bobbins are directly hung on a creel of a weaving machine for weaving without warping. The weaving density is 1594 mm/turn of the face yarn length and 660 mm/turn of the ground yarn length. The woven antibacterial grey cloth is in a structure with one plain side and one looped side; the weight of the greige goods was controlled at 23.5kgs.
The antibacterial grey cloth is treated as follows:
cloth preparation and cylinder entry: the blank is sewn together every 8 pieces and the uniform wool direction is maintained. The cloth is fed into the dye vat to achieve that each tube is 8 pieces, and the uniform cloth feeding direction is that the cloth is fed into the vat along the wool.
Refining, rinsing, and dyeing at 120 deg.C by high temperature and high pressure method using EF series dye of disperse dye Dystar. And (4) dewatering, scutching and drying after the mixture is taken out of the vat at the drying temperature of 150 ℃. Then adding gigging oil dimethyl silicone oil and a fluffing agent (R30 fluffing agent of Tiger textile auxiliary) into the setting machine, and drying at 120 ℃.
And (3) after finishing: the method comprises the steps of napping the plain weave surface and the loop surface, and then carding and shearing the plain weave surface and the loop surface. Then, the granulation is carried out at the temperature of 60 ℃ for 30 minutes. And finally, high-temperature setting is carried out, wherein the setting temperature is 150 ℃, and the speed of the setting machine is 40 m/min.
The gram weight of the finished fabric product in the embodiment is 280g/m 2 (ii) a The color fastness of the product is above 3-4 grade. Fig. 2 is a front view of the antibacterial, anti-mite and anti-static suede, which shows the suede shape of the fabric.
Example 2
In the embodiment, the natural mineral antibacterial fiber is 70D/36F terylene DTY filament, and the conductive fiber is (terylene 50D FDY + chinlon 20D) composite conductive fiber. The surface yarn adopts 75D/144F superfine polyester filament, the bottom yarn adopts 50D/36F polyester fiber, and 40D spandex is added in the weft direction.
The weaving machine is a warp knitting machine with 32 needles per inch. 75D/144F's superfine fibre filament face yarn and 70D/36F's antibiotic yarn warns to 4 pan heads, and antibiotic yarn interval is in the middle of the superfine face yarn who washes the fibre filament, and the interval is 0.5cm. The terylene ground yarn and the composite conductive fiber are warped to the other 4 pan heads, the conductive fiber is arranged between the terylene ground yarn at intervals of 4cm. The ratio of the antibacterial fiber is 4%, and the ratio of the conductive fiber is 1%. The spandex yarn 40D is not required to be warped, and is woven into the grey cloth in the weft direction, and the proportion of the spandex yarn is 5%. Cutting velvet in the middle of the woven grey cloth into two pieces of grey cloth with the A surface and the B surface; the weight of the grey cloth is controlled to be about 20 kgs.
The grey cloth is processed as follows:
1. the grey cloth is shaped at high temperature, the shaping temperature is 200 ℃, and the speed of the shaping machine is 25 m/min. And then carrying out front napping, and then carrying out front polishing and shearing twice. And then the semi-finished product is shaped, the temperature of the shaping machine is 190 ℃, and the speed of the vehicle is 35 m/min.
2. Cloth preparation and cylinder entry: the grey cloth is sewn together every 8 pieces, and the uniform wool direction is kept. The cloth is fed into the dye vat to achieve that each tube is 8 pieces, and the uniform cloth feeding direction is that the cloth is fed into the vat along the wool. Dyeing by adopting a high-temperature high-pressure method and using a disperse dye. Heating to 130 ℃, dyeing for 4 hours, and adding amino silicone oil to keep the temperature at 85 ℃ for 30min. And (4) dewatering and drying after taking out of the cylinder, wherein the drying temperature is 180 ℃, and the speed of the setting machine is 32 m/min.
3. And (3) after finishing: and (4) napping the back, ironing the front side and the back side at 150 ℃, and shearing. Finally, the finished product is shaped, the temperature of the shaping machine is 170 ℃, and the vehicle speed is 30 m/min.
The gram weight of the finished fabric product in the embodiment is 300g/m 2 (ii) a The color fastness of the product is above 3-4 grade.
Example 3
Compared with the embodiment 1, the distance between the conductive fibers is 8CM in the embodiment, and other processes are not changed.
Comparative example 1
In comparative example 1, compared with example 1, the antibacterial fiber is not added, 30g/L of silver ion antibacterial finishing agent is added into a setting machine, the liquid carrying rate after dipping is 80%, and the drying temperature is 120 ℃. The other processes are unchanged.
The other processes are unchanged.
Comparative example 2
Compared with the embodiment 1, the embodiment does not add conductive fiber, 10g/L of polyoxyethylene-resistant electrostatic auxiliary agent is added into the setting machine, the liquid carrying rate after dipping is 80%, and the drying temperature is 120 ℃. The other processes are unchanged.
Specific test results are shown in table 1:
table 1 results of performance tests on products of examples of the invention
Figure BDA0004025808070000091
Figure BDA0004025808070000101
According to the embodiment, the natural mineral antibacterial fiber wool fabric has lasting antibacterial and anti-mite performances, is soft and comfortable, and has excellent antibacterial and anti-mite performances which can last for more than 50 times of water washing. The fabric with lasting antibacterial, anti-mite and durable antistatic effects, prepared by the embodiment of the invention, is soft and comfortable in hand feeling, can eliminate static troubles and keep the product clean, has washing resistance, ecological safety and the like, and is beneficial to application. It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
The principles and embodiments of the present invention are explained herein using specific examples, which are presented only to assist in understanding the method and its core concepts of the present invention. The foregoing is only a preferred embodiment of the present invention, and it should be noted that there are objectively infinite specific structures due to the limited character expressions, and it will be apparent to those skilled in the art that a plurality of modifications, decorations or changes may be made without departing from the principle of the present invention, and the technical features described above may be combined in a suitable manner; such modifications, variations, or combinations, or other applications of the inventive concepts and solutions as may be employed without such modifications, are intended to be included within the scope of the present invention.

Claims (10)

1. The durable antibacterial anti-mite antistatic wool fabric is characterized by comprising 3-10wt% of natural mineral antibacterial fibers, wherein the natural mineral antibacterial fibers are prepared by acquiring positively charged metal ions from natural minerals and then spinning the positively charged metal ions with a chemical fiber carrier or a regenerated fiber carrier, and the positively charged metal ions account for 0.5-2wt% of the fiber carrier.
2. The durable antibacterial anti-mite anti-static wool fabric as claimed in claim 1, wherein the natural mineral antibacterial fibers are low stretch yarns or fully drawn yarns, the fiber carrier component is terylene and/or nylon, and the fiber fineness is 30D-150D.
3. The durable antibacterial anti-mite antistatic velvet fabric according to claim 1, wherein the natural mineral antibacterial fiber is short fiber, and the fiber carrier component is terylene or viscose.
4. The durable antibacterial anti-mite anti-static wool fabric according to any one of claims 1 to 3, wherein the durable antibacterial anti-mite anti-static wool fabric further comprises conductive filaments, the fineness of the conductive filaments is 20D-40D, and the main fiber component is terylene and/or nylon.
5. A production method of a durable antibacterial, anti-mite and antistatic velvet fabric is characterized by comprising the following steps:
knitting 3-10wt% of natural mineral antibacterial filaments and other yarns at intervals to obtain antibacterial grey cloth with a looped pile or cut pile structure; the natural mineral antibacterial filament is prepared by acquiring positively charged metal ions from natural minerals and then spinning the metal ions and a chemical fiber carrier or a regenerated fiber carrier in a pressure spinning mode, wherein the positively charged metal ions account for 0.5-2wt% of the fiber carrier;
and dyeing and post-finishing the antibacterial gray fabric to obtain the durable antibacterial, anti-mite and antistatic velvet fabric.
6. The method of claim 5, wherein the other yarns comprise conductive filaments and staple fibers; the conductive filaments are spaced in the ground filament, and the distance between the conductive filaments is controlled to be 1-5 cm.
7. The production method of claim 6, wherein the titer of the conductive filament is 20D-40D, and the main fiber component is terylene and/or nylon; the conductive filament accounts for 1-3% of the mass of the antibacterial grey cloth.
8. A production method of a durable antibacterial anti-mite antistatic velvet fabric is characterized by comprising the following steps:
blending natural mineral antibacterial short fibers and other short fibers into antibacterial composite yarns, and then knitting to obtain antibacterial grey cloth with a looped pile or cut pile structure; the natural mineral antibacterial short fiber is prepared by acquiring positively charged metal ions from natural minerals and then spinning the positively charged metal ions with a chemical fiber carrier or a regenerated fiber carrier in a pressure spinning mode, wherein the positively charged metal ions account for 0.5 to 2wt% of the fiber carrier; the natural mineral antibacterial short fibers account for 3-10% of the mass of the antibacterial gray fabric;
and dyeing and post-finishing the antibacterial gray fabric to obtain the durable antibacterial, anti-mite and antistatic velvet fabric.
9. The production method according to any one of claims 5 to 8, wherein the dyeing is carried out by a high temperature and high pressure dyeing process using a disperse dye.
10. The production method according to any one of claims 5 to 8, characterized in that the post-finishing process comprises the steps of napping, carding, shearing, pilling, tentering and setting in sequence to obtain the finished velvet fabric.
CN202211717028.8A 2022-12-29 2022-12-29 Persistent antibacterial anti-mite antistatic wool fabric and production method thereof Pending CN115961414A (en)

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