CN115895082A - Composite material for touch pen conductive pen point, touch pen conductive pen point and preparation method thereof - Google Patents

Composite material for touch pen conductive pen point, touch pen conductive pen point and preparation method thereof Download PDF

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Publication number
CN115895082A
CN115895082A CN202211390172.5A CN202211390172A CN115895082A CN 115895082 A CN115895082 A CN 115895082A CN 202211390172 A CN202211390172 A CN 202211390172A CN 115895082 A CN115895082 A CN 115895082A
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conductive
powder
composite material
pen
polyethylene
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请求不公布姓名
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Guangzhou Zhongyuan Intelligent Technology Co ltd
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Guangzhou Zhongyuan Intelligent Technology Co ltd
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Abstract

The invention relates to a composite material for a conductive pen point of a touch pen, the conductive pen point of the touch pen and a preparation method of the conductive pen point. The composite material for the conductive pen point of the touch pen comprises conductive powder, carbon powder, polyethylene, a coupling agent and a binder. The embodiment of the invention takes the polyethylene as the main material, the polyethylene material has stable chemical property, good weather resistance, aging resistance and wear resistance and excellent processing characteristics, and the polyethylene with single molecular weight is used, so that the control of production parameters in the production process is facilitated, and the producibility is better; meanwhile, the polyethylene is in a space conjugate structure, and further is matched with conductive powder added in the formula, so that the conductivity of the manufactured pen point can be effectively improved, the writing sensitivity is improved, the internal porosity is high and the pore size distribution is uniform after the composite material is molded, the structure can play a role in reducing the whole weight of the pen point material and absorbing sound and shock, and meanwhile, the screen impact sound during writing can be effectively reduced due to proper hardness, so that better writing experience is achieved.

Description

Composite material for touch pen conductive pen point, touch pen conductive pen point and preparation method thereof
Technical Field
The invention relates to the technical field of touch control, in particular to a composite material for a conductive pen point of a touch control pen, the conductive pen point of the touch control pen and a preparation method of the conductive pen point of the touch control pen.
Background
With the popularization of touch screens in life and work of people, touch pens with the advantages of high touch precision, rich expanded functions, accordance with the use habits of consumers and the like have gradually become one of mainstream human-computer interaction modes.
Aiming at a capacitance pen, the principle is to simulate the touch effect of a finger, a pen point is made of a conductive material and can cause capacitance change of a touch screen matrix when contacting with a touch screen, and the conductive pen point materials of the touch pen popular in the market at present comprise conductive foam, metal, conductive fibers, conductive silica gel or conductive cloth and the like. Wherein electrically conductive bubble is cotton, conductive fiber and electrically conductive cloth material all have the problem that wear resistance is not enough to a certain extent, and the nib of metal class is scraped the touch screen easily and is colored and striking the screen when writing sound great, and electrically conductive silica gel can effectively avoid the problem that wear resistance is not enough and damage the screen, and the screen impact sound is little, but is subject to the characteristic of material itself, and electrically conductive silica gel class nib damping is great when writing, writes not smooth enough, uses easy fatigue for a long time.
Disclosure of Invention
Based on the above, the invention aims to provide a composite material for a conductive pen point of a touch pen, and the conductive pen point of the touch pen prepared from the composite material has the advantages of high writing smoothness, good wear resistance, small screen impact sound, no damage to a screen, good conductivity and the like.
The composite material for the conductive pen point of the touch pen comprises the following raw material components in parts by weight:
Figure BDA0003931703060000011
the polyethylene has a single molecular weight of 140 to 300 ten thousand.
The composite material for the conductive pen point of the touch pen takes polyethylene as a main material, the polyethylene material has stable chemical property, good weather resistance, aging resistance and wear resistance and excellent processing characteristics, and the polyethylene with single molecular weight is used and the molecular weight of the polyethylene is controlled, so that the control of production parameters in the production process is facilitated, and the producibility is better; meanwhile, the polyethylene is of a space conjugate structure and has certain electron conduction capability, and the conductivity of the prepared pen point can be effectively improved by further matching with the conductive powder added in the formula, so that the writing sensitivity is improved; in addition, the surface friction coefficient of the polyethylene base material can be reduced by controlling the pressure and the particle size of the powder particles, and the smoothness of writing of the pen point is improved by utilizing the bearing effect of the conductive powder; the porosity and the pore size of the composite material for the conductive pen point of the touch pen can be adjusted by matching with conductive powder materials with different particle sizes, so that the overall hardness and the dead weight of the manufactured pen point are adjusted, the porosity of the inner part of the composite material is high after the composite material is formed, the pore size is uniformly distributed, the structure can play a role in reducing the overall weight of the pen point material, absorbing sound and shock, and meanwhile, the screen impact sound during writing can be effectively reduced due to proper hardness, so that better writing experience is achieved.
Furthermore, the conductive powder is spherical conductive powder, the particle size range of the conductive powder is 8-30 mu m, so that the porosity and the pore size of the composite material for the conductive pen point of the touch pen are adjusted, and the overall hardness and the self weight of the manufactured pen point are further adjusted.
Furthermore, the conductive powder is selected from one or more of silver powder, copper powder, aluminum powder, carbon fiber powder, carbon nano tubes and graphene, and has good conductivity, so that the conductivity of the composite material is enhanced.
Further, the coupling agent is a silane coupling agent selected from one or more of a silane coupling agent KH540, a silane coupling agent KH550 and a silane coupling agent K560.
Further, the binder is a low molecular weight thermoplastic or low temperature thermoset.
Further, the binder is linear low-density polyethylene or double-component thermosetting glue.
In addition, the embodiment of the invention also provides a touch pen conductive pen tip which is prepared from the composite material for the touch pen conductive pen tip.
The conductive pen point of the touch pen provided by the embodiment of the invention has the advantages of good conductivity, high writing sensitivity, high smoothness and appropriate hardness, is beneficial to reducing screen impact sound during writing, has light self weight, and can achieve better writing experience.
In addition, the embodiment of the invention also provides a preparation method of the conductive pen point of the touch pen, which comprises the following specific operation steps:
s1, weighing conductive powder, carbon powder, polyethylene, a coupling agent and a binder according to any one of the formulas for later use;
s2, adding conductive powder, carbon powder, polyethylene and a coupling agent into a mixer, stirring and mixing under a room temperature environment while adding a binder for multiple times, and uniformly mixing for later use;
and S3, filling the mixture obtained in the step S2 into a nib mold cavity with a preset shape, pressurizing, heating, exhausting, pressure maintaining and forming, then cooling to room temperature, demolding and finishing to obtain the conductive nib of the touch pen.
The conductive pen point of the touch pen is processed in a solid-state hot press forming mode, the process control is simple, the yield is high, the quality of a finished product is stable, and the requirement of industrial batch production is met.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the following more detailed description. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
The invention aims to provide a composite material for a conductive pen point of a touch pen, and the prepared conductive pen point of the touch pen has the advantages of high writing smoothness, good wear resistance, small impact sound of a screen, no damage to the screen, good conductivity and the like.
The composite material for the conductive pen point of the touch pen comprises the following raw material components in parts by weight:
Figure BDA0003931703060000031
the polyethylene has a single molecular weight of 140 to 300 ten thousand.
The composite material for the conductive pen point of the touch pen takes polyethylene as a main material, the polyethylene material has stable chemical property, good weather resistance, aging resistance and wear resistance and excellent processing characteristics, and the polyethylene with single molecular weight is used and the molecular weight of the polyethylene is controlled, so that the control of production parameters in the production process is facilitated, and the producibility is better; meanwhile, the polyethylene is of a space conjugate structure and has certain electron conduction capability, and the conductivity of the prepared pen point can be effectively improved by further matching with the conductive powder added in the formula, so that the writing sensitivity is improved; in addition, the surface friction coefficient of the polyethylene base material can be reduced by controlling the pressure and the particle size of the powder particles, and the smoothness of writing of the pen point is improved by utilizing the bearing effect of the conductive powder; the porosity and the pore size of the composite material for the conductive pen point of the touch pen can be adjusted by further matching with conductive powder with different particle sizes, so that the overall hardness and the self weight of the manufactured pen point can be adjusted, the porosity of the composite material after molding is high, the pore size distribution is uniform, the structure can play a role in reducing the overall weight of the pen point material, absorbing sound and absorbing shock, and meanwhile, the screen impact sound during writing can be effectively reduced due to proper hardness, so that better writing experience is achieved.
The conductive powder is spherical, the particle size of the conductive powder ranges from 8 to 30 mu m, so that the porosity and the pore size of the composite material for the conductive pen point of the touch pen are adjusted, and the overall hardness and the self weight of the manufactured pen point are further adjusted.
Further preferably, the conductive powder is selected from one or more of silver powder, copper powder, aluminum powder, carbon fiber powder, carbon nanotubes and graphene, and the conductive powder has good conductivity and is beneficial to enhancing the conductivity of the composite material.
The coupling agent is a silane coupling agent and is selected from one or more of a silane coupling agent KH540, a silane coupling agent KH550 and a silane coupling agent K560.
The binder is a low molecular weight thermoplastic material, such as linear low density PE, or a low temperature thermoset material, such as a two-part thermoset glue.
The invention will be described in further detail below with reference to specific examples and comparative examples, and the composition of each example of the composite material for the nib of the capacitive pen of the invention and the composition of the other comparative examples of the nib material are shown in table 1 below:
TABLE 1 (unit: parts by weight)
Figure BDA0003931703060000041
/>
Example 4
The preparation method of the conductive pen tip composite material for the touch pen in the embodiment 4 of the invention comprises the following specific operation steps:
s1, weighing 3 parts of conductive powder, 7 parts of carbon powder, 110 parts of polyethylene, 1 part of coupling agent and 2 parts of binder according to the parts by weight in the formula for later use, wherein the conductive powder is silver powder, copper powder and graphene, the coupling agent is a silane coupling agent KH540, and the binder is linear low-density polyethylene;
s2, adding conductive powder, carbon powder, polyethylene and a coupling agent into a mixer, stirring and mixing under a room temperature environment while adding a binder for multiple times, and uniformly mixing for later use;
and S3, filling the mixture obtained in the step S2 into a pen point mold cavity in a preset shape, pressurizing, heating, exhausting, maintaining pressure, forming, cooling to room temperature, demolding, and finishing to obtain the conductive pen point of the touch pen.
Example 5
The preparation method of the conductive pen tip composite material for the touch pen in the embodiment 5 of the invention comprises the following specific operation steps:
s1, weighing 4 parts of conductive powder, 8 parts of carbon powder, 120 parts of polyethylene, 2 parts of coupling agent and 3 parts of binder according to the parts by weight in the formula for later use, wherein the conductive powder is aluminum powder and carbon fiber powder, the coupling agent is silane coupling agent K560, and the binder is double-component thermosetting glue;
s2, adding conductive powder, carbon powder, polyethylene and a coupling agent into a mixer, stirring and mixing under a room temperature environment while adding a binder for multiple times, and uniformly mixing for later use;
and S3, filling the mixture obtained in the step S2 into a nib mold cavity with a preset shape, pressurizing, heating, exhausting, pressure maintaining and forming, then cooling to room temperature, demolding and finishing to obtain the conductive nib of the touch pen.
Example 6
The preparation method of the conductive pen tip composite material for the touch pen in the embodiment 6 of the invention comprises the following specific operation steps:
s1, weighing 5 parts of conductive powder, 9 parts of carbon powder, 130 parts of polyethylene, 3 parts of coupling agent and 4 parts of binder according to the parts by weight in the formula for later use, wherein the conductive powder is aluminum powder, carbon nano tubes and graphene, the coupling agent is a silane coupling agent KH550 and a silane coupling agent K560, and the binder is double-component thermosetting glue;
s2, adding the conductive powder, the carbon powder, the polyethylene and the coupling agent into a mixer, stirring and mixing under a room temperature environment, adding the binder for multiple times, and uniformly mixing for later use;
and S3, filling the mixture obtained in the step S2 into a pen point mold cavity in a preset shape, pressurizing, heating, exhausting, maintaining pressure, forming, cooling to room temperature, demolding, and finishing to obtain the conductive pen point of the touch pen.
Example 7
Inventive example 7 performance tests were conducted using various stylus tips obtained by the methods described in any of examples 4-6 prepared from the materials of examples 1-3 and comparative examples 1-2, and the test results are given in table 2 below:
TABLE 2
Figure BDA0003931703060000051
From the above table, the conductive pen point of the touch pen provided by the embodiment of the invention has the advantages of good wear resistance, proper hardness, drop resistance, good conductivity, high writing sensitivity, small writing resistance, small screen impact sound during writing and good writing experience.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.

Claims (8)

1. The composite material for the conductive pen point of the touch pen is characterized by comprising the following raw material components in parts by weight:
Figure FDA0003931703050000011
the polyethylene has a single molecular weight of 140 to 300 ten thousand.
2. The composite material for a conductive tip of a stylus according to claim 1, wherein: the conductive powder is spherical conductive powder, and the particle size range of the conductive powder is 8-30 mu m.
3. The composite material for a conductive tip of a stylus according to claim 1, wherein: the conductive powder is selected from one or more of silver powder, copper powder, aluminum powder, carbon fiber powder, carbon nano tubes and graphene.
4. The composite material for a conductive tip of a stylus according to claim 1, wherein: the coupling agent is a silane coupling agent and is selected from one or more of a silane coupling agent KH540, a silane coupling agent KH550 and a silane coupling agent K560.
5. The composite material for a conductive tip of a stylus according to claim 1, wherein: the binder is a low molecular weight thermoplastic material or a low temperature thermoset material.
6. The composite material for a conductive tip of a stylus according to claim 5, wherein: the binder is linear low-density polyethylene or double-component thermosetting glue.
7. A conductive nib for a stylus, comprising: prepared from the composite material for the conductive pen tip of the touch pen as claimed in any one of claims 1 to 6.
8. A preparation method of a conductive pen point of a touch pen is characterized by comprising the following specific operation steps:
s1, weighing conductive powder, carbon powder, polyethylene, a coupling agent and a binder according to the formula of any one of claims 1 to 6 for later use;
s2, adding conductive powder, carbon powder, polyethylene and a coupling agent into a mixer, stirring and mixing under a room temperature environment while adding a binder for multiple times, and uniformly mixing for later use;
and S3, filling the mixture obtained in the step S2 into a nib mold cavity with a preset shape, pressurizing, heating, exhausting, pressure maintaining and forming, then cooling to room temperature, demolding and finishing to obtain the conductive nib of the touch pen.
CN202211390172.5A 2022-11-08 2022-11-08 Composite material for touch pen conductive pen point, touch pen conductive pen point and preparation method thereof Withdrawn CN115895082A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102053737A (en) * 2010-12-27 2011-05-11 清华大学 Touch pen
CN109957165A (en) * 2019-03-28 2019-07-02 广州视源电子科技股份有限公司 Touch-control pen tip composite material, stylus and its pen tip forming method
CN110607072A (en) * 2019-09-12 2019-12-24 广州视源电子科技股份有限公司 Pen point composite material of capacitive pen, passive capacitive pen and pen point preparation method thereof
CN112416150A (en) * 2020-11-19 2021-02-26 深圳普力美科技有限公司 High-wear-resistance low-noise plastic pen point with conductive filler and production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102053737A (en) * 2010-12-27 2011-05-11 清华大学 Touch pen
CN109957165A (en) * 2019-03-28 2019-07-02 广州视源电子科技股份有限公司 Touch-control pen tip composite material, stylus and its pen tip forming method
CN110607072A (en) * 2019-09-12 2019-12-24 广州视源电子科技股份有限公司 Pen point composite material of capacitive pen, passive capacitive pen and pen point preparation method thereof
CN112416150A (en) * 2020-11-19 2021-02-26 深圳普力美科技有限公司 High-wear-resistance low-noise plastic pen point with conductive filler and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
罗河胜 编: "《塑料材料手册》", 广东科技出版社, pages: 155 - 156 *

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Application publication date: 20230404