CN115843817A - Preparation method of anticorrosive paint - Google Patents
Preparation method of anticorrosive paint Download PDFInfo
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- CN115843817A CN115843817A CN202211647185.6A CN202211647185A CN115843817A CN 115843817 A CN115843817 A CN 115843817A CN 202211647185 A CN202211647185 A CN 202211647185A CN 115843817 A CN115843817 A CN 115843817A
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- CN
- China
- Prior art keywords
- parts
- dcoit
- mildew
- anticorrosive paint
- murrayone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 9
- IISMOXLSZASLDD-UHFFFAOYSA-N 7-methoxy-8-(3-methyl-2-oxobut-3-enyl)chromen-2-one Chemical compound C1=CC(=O)OC2=C(CC(=O)C(C)=C)C(OC)=CC=C21 IISMOXLSZASLDD-UHFFFAOYSA-N 0.000 claims abstract description 42
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000000576 coating method Methods 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- 239000002518 antifoaming agent Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- -1 alcohol ester Chemical class 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 244000005700 microbiome Species 0.000 abstract description 11
- 230000002195 synergetic effect Effects 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 230000005764 inhibitory process Effects 0.000 abstract description 6
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 230000006866 deterioration Effects 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000001018 virulence Effects 0.000 description 6
- 235000008734 Bergera koenigii Nutrition 0.000 description 4
- 241000079253 Byssochlamys spectabilis Species 0.000 description 4
- 240000002393 Murraya koenigii Species 0.000 description 4
- IFPMZBBHBZQTOV-UHFFFAOYSA-N 1,3,5-trinitro-2-(2,4,6-trinitrophenyl)-4-[2,4,6-trinitro-3-(2,4,6-trinitrophenyl)phenyl]benzene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(C=2C(=C(C=3C(=CC(=CC=3[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)C(=CC=2[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)=C1[N+]([O-])=O IFPMZBBHBZQTOV-UHFFFAOYSA-N 0.000 description 3
- 241000228245 Aspergillus niger Species 0.000 description 3
- 241001465318 Aspergillus terreus Species 0.000 description 3
- 241000223678 Aureobasidium pullulans Species 0.000 description 3
- 241001515917 Chaetomium globosum Species 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 241001136494 Talaromyces funiculosus Species 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- BLKPFVWYBFDTPX-UHFFFAOYSA-N 2-(6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)acetaldehyde Chemical compound C1C2C(C)(C)C1CC=C2CC=O BLKPFVWYBFDTPX-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000001899 Murraya exotica Species 0.000 description 1
- 235000008766 Murraya exotica Nutrition 0.000 description 1
- 235000009696 Murraya paniculata Nutrition 0.000 description 1
- 240000008607 Opuntia megacantha Species 0.000 description 1
- 235000002840 Opuntia megacantha Nutrition 0.000 description 1
- 235000006538 Opuntia tuna Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 238000000611 regression analysis Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a manufacturing method of an anticorrosive coating. A mildewproof composition comprises DCOIT and murrayone. The mildew-proof composition disclosed by the invention consists of DCOIT and murrayone, the DCOIT and the murrayone show a synergistic effect on various moulds when being used in a combined manner, and compared with a single DCOIT, the mildew-proof composition can improve the inhibition effect on various moulds, further reduce the using amount of mildew-proof components and the cost, and is beneficial to protecting the life health and safety of people. The mildew-proof composition is added in the process of manufacturing the anticorrosive paint, so that the resistance of the anticorrosive paint to external microorganisms is improved, the anticorrosive paint is prevented from being invaded and polluted by the microorganisms, and the production, the storage and the use of the paint are further ensured not to generate putrefaction and deterioration.
Description
Technical Field
The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a manufacturing method of an anticorrosive coating.
Background
Latex paints, resin emulsions, and waterborne coatings all contain organic materials that provide the basic conditions for the growth and proliferation of microorganisms. Under proper conditions, the growth and the propagation of a large amount of microorganisms can be promoted, and in the process, metabolic products such as enzymes and organic acids generated by the microorganisms can cause the change of the smell, the color, the viscosity and the like of the coating, so that the product is deteriorated.
The mildew inhibitor can inhibit the growth of microorganisms, and a proper amount of preservative can be added into the product to effectively prevent the invasion of the microorganisms. There are a number of preservatives currently on the market, such as BCM, OIT, IPBC, IPN (CLT) and DCOIT. Wherein DCOIT is 4,5-dichloro-2-n-octyl-7-isothiazolin-3-one, and the structural formula is as follows:
DCOIT can be used for dry film mildew resistance and can also be used for in-tank corrosion resistance, and is a broad-spectrum efficient corrosion, mildew and algae resistant agent. However, with the long-term use of DCOIT, many microorganisms have developed resistance to it, resulting in a gradual decrease in the inhibitory effect on their various molds. In production, although the inhibiting effect on microorganisms such as bacteria, fungi, algae and the like can be improved by adding the additive amount, DCOIT has larger skin irritation and is a chlorine-containing product, and the increase of the dosage can cause the application amount to exceed the standard and cause damage to human bodies.
In the paint industry, different anticorrosive components can be combined and compounded in different proportions, and the synergistic effect can improve the mould inhibition effect, reduce the dosage and reduce the cost. CMIT/MIT + FR is a very common combination compound which has high-efficiency broad-spectrum bactericidal action, but can not achieve the effect of synergistic action by combining and compounding any two or more antiseptic components.
The inventor discovers that the DCOIT and the murrayone can improve the inhibition effect on various moulds when being combined and used according to a certain mass ratio through an indoor synergistic test, so that the consumption of antiseptic components can be reduced, the cost can be reduced, and the life health safety of people can be protected. Chinese patent CN202210498785.1 discloses a preparation method of an architectural coating, and particularly discloses that when isothiazolinone and murrayone are used in combination, the inhibition effect on mold can be improved. At present, no report on the combined use of DCOIT and murrayone is found.
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Disclosure of Invention
The invention aims to provide a preparation method of an anticorrosive paint, which aims to solve the problem existing when DCOIT is singly used as a mildew preventive.
In order to achieve the purpose, the invention provides the following technical scheme:
the first purpose of the invention is to provide a mildew-proof composition, which consists of DCOIT and murrayone.
Preferably, the mass ratio of DCOIT to murrayone is 1-10:15-1.
The second purpose of the invention is to provide an anticorrosive paint which comprises the mildewproof composition.
Preferably, the anticorrosive paint is prepared from the following components in parts by weight: 180-200 parts of styrene-acrylic emulsion, 6-10 parts of dispersant, 8-10 parts of thickener, 10-15 parts of film-forming assistant, 3-8 parts of defoamer, 1-5 parts of mildew-proof composition, 150-200 parts of filler, 100-120 parts of pigment, 11-15 parts of propylene glycol and 300-350 parts of deionized water.
Preferably, the dispersant is a nopinaceae SN5040 dispersant; the thickening agent is 250HBR; the film-forming additive is Istmann alcohol ester twelve; the antifoaming agent is nopptam 7060 antifoaming agent of nopinaceae; the filler is 800-mesh heavy calcium carbonate; the pigment is 800-mesh rutile titanium dioxide.
The third purpose of the invention is to provide a preparation method of the anticorrosive paint, which comprises the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 15-20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 60-100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
Compared with the prior art, the invention has the following beneficial effects:
the mildew-proof composition disclosed by the invention consists of DCOIT and murrayone, the DCOIT and the murrayone show a synergistic effect on various moulds when being used in a combined manner, and compared with a single DCOIT, the mildew-proof composition can improve the inhibition effect on various moulds, further reduce the using amount of mildew-proof components and the cost, and is beneficial to protecting the life health and safety of people. The mildew-proof composition is added in the process of manufacturing the anticorrosive paint, so that the resistance of the anticorrosive paint to external microorganisms is improved, the anticorrosive paint is prevented from being invaded and polluted by the microorganisms, and the production, the storage and the use of the paint are further ensured not to generate putrefaction and deterioration.
Detailed Description
In the following, the technical solutions of the present invention will be described clearly and completely, and it is obvious that the described embodiments are some, not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the following examples, styrene-acrylic emulsions were purchased from Condits chemical (Hubei) Inc. at a purity of 99%.
Example 1
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nepal SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Eschmann alcohol ester dodeca, 3-8kg of Nopal NOPTAM 7060 defoaming agent, 1-5kg of mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein the mildew-proof composition is prepared from DCOIT and murrayone according to the weight ratio of 1:15 in mass ratio.
The preparation method of the anticorrosive paint comprises the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
Example 2
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nopulidae SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Esomerman alcohol ester dodeca, 3-8kg of Nopulidae NOPTAM 7060 defoaming agent, 1-5kg of the mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile type titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein, the sterilization and mildew-proof agent is prepared from DCOIT and murrayone according to the weight ratio of 1:7.5 in mass ratio.
The preparation method of the anticorrosive paint is the same as that of example 1.
Example 3
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nopulidae SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Esomerman alcohol ester dodeca, 3-8kg of Nopulidae NOPTAM 7060 defoaming agent, 1-5kg of the mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile type titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein, the sterilization and mildew-proof agent is prepared from DCOIT and murrayone according to the weight ratio of 10:1, in terms of mass ratio.
The preparation method of the anticorrosive paint is the same as that of example 1.
Example 4: DCOIT and Murraya koenigii Ketone synergy test
1. Test for mold
6 strains detected in appendix B of chemical industry Standard HG/T3950-2007 antibacterial paint of the people's republic of China are taken as test molds, and the test molds are specifically shown in the following table 1.
TABLE 1 test molds
2. Test agents: 99% of DCOIT (Wuhan daoyer Biotech Co., ltd.) and 98% of murrayone (Shanghai-source leaf Biotech Co., ltd.), the DCOIT and the murrayone are dissolved by DMSO, then 0.1% of Tween-80 aqueous solution is used for preparing single-dose mother liquor of the dissolved murrayone of the DCOIT respectively, a plurality of groups of proportions are set, and each single dose and each group of proportions are diluted into 6 mass concentration gradients by 0.1% of Tween-80 aqueous solution according to an equal proportion method for later use.
3. Test method
A hypha growth rate method is adopted. 1mL of the test agent was mixed with 9mL of the thawed PDA medium, and the mixture was poured into a sterile petri dish to prepare a drug-containing plate. After the medium had solidified, 1 mold cake (5 mm in diameter) was placed in the center of the drug-containing plate, and 5 replicates of each treatment setup were run against 0.1% tween-80 in water. Placing into an incubator, culturing at 28 + -1 deg.C for 3d, measuring the growth diameter of mold colony by cross method, and calculating the inhibition rate.
4. Data analysis
Performing regression analysis on the test agent concentration logarithm value and the hypha growth inhibition rate probability value by using DPS software, and calculating the EC of each treatment agent 50 And the synergistic effect was evaluated according to the wadleley method.
SR is more than or equal to 1.5, which shows that the composition has a synergistic effect; SR < 0.5 shows antagonistic action; 0.5 < SR < 1.5 indicates additive effect, and the results are shown in tables 2-7.
TABLE 2 virulence of the combination of DCOIT (A) and Murraya koenigii Ketone (B) against Aspergillus niger
TABLE 3 virulence of DCOIT and Murraya koenigii (Aspergillus terreus)
TABLE 4 virulence of DCOIT and murrayone paired Paecilomyces variotii (Paecilomyces variotii)
TABLE 5 virulence of DCOIT and murrayone paired Penicillium funiculosum
TABLE 6 virulence of DCOIT and Murraya paniculata (Aureobasidium Pullulans) paired
TABLE 7 virulence of DCOIT and Murraya koenigii Ketone Complex paired Chaetomium globosum
As can be seen from tables 2 to 7, when DCOIT and murrayone are used in combination, they exhibit synergistic effects on a variety of fungi such as Aspergillus niger (Aspergillus niger), aspergillus terreus (Aspergillus terreus), paecilomyces variotii (Paecilomyces variotii), penicillium funiculosum (Penicillium funiculosum), aureobasidium Pullulans (Aureobasidium Pullulans) and Chaetomium globosum (Chaetomium globosum).
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.
Claims (6)
1. A mold-resistant composition, wherein said mold-resistant composition comprises DCOIT and murrayone.
2. The mildewcide composition according to claim 1, wherein the mass ratio of DCOIT to murrayone is 1 to 10:15-1.
3. An anticorrosive paint characterized by comprising the mildewproof composition according to any one of claims 1 to 2.
4. The anticorrosive paint according to claim 3, characterized in that the anticorrosive paint is prepared from the following components in parts by weight: 180-200 parts of styrene-acrylic emulsion, 6-10 parts of dispersant, 8-10 parts of thickener, 10-15 parts of film-forming assistant, 3-8 parts of defoamer, 1-5 parts of mildew-proof composition, 150-200 parts of filler, 100-120 parts of pigment, 11-15 parts of propylene glycol and 300-350 parts of deionized water.
5. The anticorrosive coating of claim 4, wherein the dispersant is nopinaceae SN5040 dispersant; the thickening agent is 250HBR; the film-forming auxiliary agent is Istmann alcohol ester twelve; the antifoaming agent is nopptam 7060 antifoaming agent of nopinaceae; the filler is 800-mesh heavy calcium carbonate; the pigment is 800-mesh rutile titanium dioxide.
6. A preparation method of the anticorrosive paint according to claim 4, characterized by comprising the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 15-20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 60-100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105340892A (en) * | 2015-11-23 | 2016-02-24 | 江苏省中国科学院植物研究所 | Applications of natural compound Murrayone as agricultural bactericide |
CN114672210A (en) * | 2022-05-09 | 2022-06-28 | 广西南宁维一防腐科技有限公司 | Method for preparing building coating |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105340892A (en) * | 2015-11-23 | 2016-02-24 | 江苏省中国科学院植物研究所 | Applications of natural compound Murrayone as agricultural bactericide |
CN114672210A (en) * | 2022-05-09 | 2022-06-28 | 广西南宁维一防腐科技有限公司 | Method for preparing building coating |
Non-Patent Citations (1)
Title |
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PING-PING SONG 等: "Evaluation of antifungal activities and structure–activity relationships of coumarin derivatives", 《PEST MANAG SCI 》, vol. 73, pages 94 * |
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