CN115843817A - Preparation method of anticorrosive paint - Google Patents

Preparation method of anticorrosive paint Download PDF

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CN115843817A
CN115843817A CN202211647185.6A CN202211647185A CN115843817A CN 115843817 A CN115843817 A CN 115843817A CN 202211647185 A CN202211647185 A CN 202211647185A CN 115843817 A CN115843817 A CN 115843817A
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parts
dcoit
mildew
anticorrosive paint
murrayone
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CN115843817B (en
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李金庆
李国华
黄扎纲
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Guangxi Weiyi Paint Manufacturing Co ltd
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Guangxi Weiyi Paint Manufacturing Co ltd
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Abstract

The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a manufacturing method of an anticorrosive coating. A mildewproof composition comprises DCOIT and murrayone. The mildew-proof composition disclosed by the invention consists of DCOIT and murrayone, the DCOIT and the murrayone show a synergistic effect on various moulds when being used in a combined manner, and compared with a single DCOIT, the mildew-proof composition can improve the inhibition effect on various moulds, further reduce the using amount of mildew-proof components and the cost, and is beneficial to protecting the life health and safety of people. The mildew-proof composition is added in the process of manufacturing the anticorrosive paint, so that the resistance of the anticorrosive paint to external microorganisms is improved, the anticorrosive paint is prevented from being invaded and polluted by the microorganisms, and the production, the storage and the use of the paint are further ensured not to generate putrefaction and deterioration.

Description

Preparation method of anticorrosive paint
Technical Field
The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a manufacturing method of an anticorrosive coating.
Background
Latex paints, resin emulsions, and waterborne coatings all contain organic materials that provide the basic conditions for the growth and proliferation of microorganisms. Under proper conditions, the growth and the propagation of a large amount of microorganisms can be promoted, and in the process, metabolic products such as enzymes and organic acids generated by the microorganisms can cause the change of the smell, the color, the viscosity and the like of the coating, so that the product is deteriorated.
The mildew inhibitor can inhibit the growth of microorganisms, and a proper amount of preservative can be added into the product to effectively prevent the invasion of the microorganisms. There are a number of preservatives currently on the market, such as BCM, OIT, IPBC, IPN (CLT) and DCOIT. Wherein DCOIT is 4,5-dichloro-2-n-octyl-7-isothiazolin-3-one, and the structural formula is as follows:
Figure BDA0004010191000000011
DCOIT can be used for dry film mildew resistance and can also be used for in-tank corrosion resistance, and is a broad-spectrum efficient corrosion, mildew and algae resistant agent. However, with the long-term use of DCOIT, many microorganisms have developed resistance to it, resulting in a gradual decrease in the inhibitory effect on their various molds. In production, although the inhibiting effect on microorganisms such as bacteria, fungi, algae and the like can be improved by adding the additive amount, DCOIT has larger skin irritation and is a chlorine-containing product, and the increase of the dosage can cause the application amount to exceed the standard and cause damage to human bodies.
In the paint industry, different anticorrosive components can be combined and compounded in different proportions, and the synergistic effect can improve the mould inhibition effect, reduce the dosage and reduce the cost. CMIT/MIT + FR is a very common combination compound which has high-efficiency broad-spectrum bactericidal action, but can not achieve the effect of synergistic action by combining and compounding any two or more antiseptic components.
The inventor discovers that the DCOIT and the murrayone can improve the inhibition effect on various moulds when being combined and used according to a certain mass ratio through an indoor synergistic test, so that the consumption of antiseptic components can be reduced, the cost can be reduced, and the life health safety of people can be protected. Chinese patent CN202210498785.1 discloses a preparation method of an architectural coating, and particularly discloses that when isothiazolinone and murrayone are used in combination, the inhibition effect on mold can be improved. At present, no report on the combined use of DCOIT and murrayone is found.
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Disclosure of Invention
The invention aims to provide a preparation method of an anticorrosive paint, which aims to solve the problem existing when DCOIT is singly used as a mildew preventive.
In order to achieve the purpose, the invention provides the following technical scheme:
the first purpose of the invention is to provide a mildew-proof composition, which consists of DCOIT and murrayone.
Preferably, the mass ratio of DCOIT to murrayone is 1-10:15-1.
The second purpose of the invention is to provide an anticorrosive paint which comprises the mildewproof composition.
Preferably, the anticorrosive paint is prepared from the following components in parts by weight: 180-200 parts of styrene-acrylic emulsion, 6-10 parts of dispersant, 8-10 parts of thickener, 10-15 parts of film-forming assistant, 3-8 parts of defoamer, 1-5 parts of mildew-proof composition, 150-200 parts of filler, 100-120 parts of pigment, 11-15 parts of propylene glycol and 300-350 parts of deionized water.
Preferably, the dispersant is a nopinaceae SN5040 dispersant; the thickening agent is 250HBR; the film-forming additive is Istmann alcohol ester twelve; the antifoaming agent is nopptam 7060 antifoaming agent of nopinaceae; the filler is 800-mesh heavy calcium carbonate; the pigment is 800-mesh rutile titanium dioxide.
The third purpose of the invention is to provide a preparation method of the anticorrosive paint, which comprises the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 15-20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 60-100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
Compared with the prior art, the invention has the following beneficial effects:
the mildew-proof composition disclosed by the invention consists of DCOIT and murrayone, the DCOIT and the murrayone show a synergistic effect on various moulds when being used in a combined manner, and compared with a single DCOIT, the mildew-proof composition can improve the inhibition effect on various moulds, further reduce the using amount of mildew-proof components and the cost, and is beneficial to protecting the life health and safety of people. The mildew-proof composition is added in the process of manufacturing the anticorrosive paint, so that the resistance of the anticorrosive paint to external microorganisms is improved, the anticorrosive paint is prevented from being invaded and polluted by the microorganisms, and the production, the storage and the use of the paint are further ensured not to generate putrefaction and deterioration.
Detailed Description
In the following, the technical solutions of the present invention will be described clearly and completely, and it is obvious that the described embodiments are some, not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the following examples, styrene-acrylic emulsions were purchased from Condits chemical (Hubei) Inc. at a purity of 99%.
Example 1
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nepal SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Eschmann alcohol ester dodeca, 3-8kg of Nopal NOPTAM 7060 defoaming agent, 1-5kg of mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein the mildew-proof composition is prepared from DCOIT and murrayone according to the weight ratio of 1:15 in mass ratio.
The preparation method of the anticorrosive paint comprises the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
Example 2
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nopulidae SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Esomerman alcohol ester dodeca, 3-8kg of Nopulidae NOPTAM 7060 defoaming agent, 1-5kg of the mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile type titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein, the sterilization and mildew-proof agent is prepared from DCOIT and murrayone according to the weight ratio of 1:7.5 in mass ratio.
The preparation method of the anticorrosive paint is the same as that of example 1.
Example 3
The anticorrosive paint is prepared from the following components: 180-200kg of styrene-acrylic emulsion, 6-10kg of Nopulidae SN5040 dispersing agent, 8-10kg of Suppon hydroxyethyl cellulose 250HBR, 10-15kg of Esomerman alcohol ester dodeca, 3-8kg of Nopulidae NOPTAM 7060 defoaming agent, 1-5kg of the mildew-proof composition, 150-200kg of 800-mesh heavy calcium carbonate, 100-120kg of 800-mesh rutile type titanium dioxide pigment, 11-15kg of propylene glycol and 300-350kg of deionized water; wherein, the sterilization and mildew-proof agent is prepared from DCOIT and murrayone according to the weight ratio of 10:1, in terms of mass ratio.
The preparation method of the anticorrosive paint is the same as that of example 1.
Example 4: DCOIT and Murraya koenigii Ketone synergy test
1. Test for mold
6 strains detected in appendix B of chemical industry Standard HG/T3950-2007 antibacterial paint of the people's republic of China are taken as test molds, and the test molds are specifically shown in the following table 1.
TABLE 1 test molds
Figure BDA0004010191000000051
2. Test agents: 99% of DCOIT (Wuhan daoyer Biotech Co., ltd.) and 98% of murrayone (Shanghai-source leaf Biotech Co., ltd.), the DCOIT and the murrayone are dissolved by DMSO, then 0.1% of Tween-80 aqueous solution is used for preparing single-dose mother liquor of the dissolved murrayone of the DCOIT respectively, a plurality of groups of proportions are set, and each single dose and each group of proportions are diluted into 6 mass concentration gradients by 0.1% of Tween-80 aqueous solution according to an equal proportion method for later use.
3. Test method
A hypha growth rate method is adopted. 1mL of the test agent was mixed with 9mL of the thawed PDA medium, and the mixture was poured into a sterile petri dish to prepare a drug-containing plate. After the medium had solidified, 1 mold cake (5 mm in diameter) was placed in the center of the drug-containing plate, and 5 replicates of each treatment setup were run against 0.1% tween-80 in water. Placing into an incubator, culturing at 28 + -1 deg.C for 3d, measuring the growth diameter of mold colony by cross method, and calculating the inhibition rate.
Figure BDA0004010191000000052
4. Data analysis
Performing regression analysis on the test agent concentration logarithm value and the hypha growth inhibition rate probability value by using DPS software, and calculating the EC of each treatment agent 50 And the synergistic effect was evaluated according to the wadleley method.
SR is more than or equal to 1.5, which shows that the composition has a synergistic effect; SR < 0.5 shows antagonistic action; 0.5 < SR < 1.5 indicates additive effect, and the results are shown in tables 2-7.
TABLE 2 virulence of the combination of DCOIT (A) and Murraya koenigii Ketone (B) against Aspergillus niger
Figure BDA0004010191000000061
TABLE 3 virulence of DCOIT and Murraya koenigii (Aspergillus terreus)
Figure BDA0004010191000000062
TABLE 4 virulence of DCOIT and murrayone paired Paecilomyces variotii (Paecilomyces variotii)
Figure BDA0004010191000000071
TABLE 5 virulence of DCOIT and murrayone paired Penicillium funiculosum
Figure BDA0004010191000000072
TABLE 6 virulence of DCOIT and Murraya paniculata (Aureobasidium Pullulans) paired
Figure BDA0004010191000000073
TABLE 7 virulence of DCOIT and Murraya koenigii Ketone Complex paired Chaetomium globosum
Figure BDA0004010191000000081
As can be seen from tables 2 to 7, when DCOIT and murrayone are used in combination, they exhibit synergistic effects on a variety of fungi such as Aspergillus niger (Aspergillus niger), aspergillus terreus (Aspergillus terreus), paecilomyces variotii (Paecilomyces variotii), penicillium funiculosum (Penicillium funiculosum), aureobasidium Pullulans (Aureobasidium Pullulans) and Chaetomium globosum (Chaetomium globosum).
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.

Claims (6)

1. A mold-resistant composition, wherein said mold-resistant composition comprises DCOIT and murrayone.
2. The mildewcide composition according to claim 1, wherein the mass ratio of DCOIT to murrayone is 1 to 10:15-1.
3. An anticorrosive paint characterized by comprising the mildewproof composition according to any one of claims 1 to 2.
4. The anticorrosive paint according to claim 3, characterized in that the anticorrosive paint is prepared from the following components in parts by weight: 180-200 parts of styrene-acrylic emulsion, 6-10 parts of dispersant, 8-10 parts of thickener, 10-15 parts of film-forming assistant, 3-8 parts of defoamer, 1-5 parts of mildew-proof composition, 150-200 parts of filler, 100-120 parts of pigment, 11-15 parts of propylene glycol and 300-350 parts of deionized water.
5. The anticorrosive coating of claim 4, wherein the dispersant is nopinaceae SN5040 dispersant; the thickening agent is 250HBR; the film-forming auxiliary agent is Istmann alcohol ester twelve; the antifoaming agent is nopptam 7060 antifoaming agent of nopinaceae; the filler is 800-mesh heavy calcium carbonate; the pigment is 800-mesh rutile titanium dioxide.
6. A preparation method of the anticorrosive paint according to claim 4, characterized by comprising the following steps:
s1, adding a dispersing agent, 1/2 of a defoaming agent, a mildew-proof composition and propylene glycol into deionized water, and stirring and mixing for 15-20min;
s2, slowly adding the filler and the pigment, and stirring and mixing for 60-100min;
and S3, sequentially adding the styrene-acrylic emulsion, the residual defoaming agent, the film-forming assistant and the thickening agent, and uniformly stirring and mixing to obtain the anticorrosive coating.
CN202211647185.6A 2022-12-21 2022-12-21 Method for preparing anti-corrosion paint Active CN115843817B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105340892A (en) * 2015-11-23 2016-02-24 江苏省中国科学院植物研究所 Applications of natural compound Murrayone as agricultural bactericide
CN114672210A (en) * 2022-05-09 2022-06-28 广西南宁维一防腐科技有限公司 Method for preparing building coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105340892A (en) * 2015-11-23 2016-02-24 江苏省中国科学院植物研究所 Applications of natural compound Murrayone as agricultural bactericide
CN114672210A (en) * 2022-05-09 2022-06-28 广西南宁维一防腐科技有限公司 Method for preparing building coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PING-PING SONG 等: "Evaluation of antifungal activities and structure–activity relationships of coumarin derivatives", 《PEST MANAG SCI 》, vol. 73, pages 94 *

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