CN115819110A - Metallized porous ceramic composite material and preparation method thereof - Google Patents
Metallized porous ceramic composite material and preparation method thereof Download PDFInfo
- Publication number
- CN115819110A CN115819110A CN202211625299.0A CN202211625299A CN115819110A CN 115819110 A CN115819110 A CN 115819110A CN 202211625299 A CN202211625299 A CN 202211625299A CN 115819110 A CN115819110 A CN 115819110A
- Authority
- CN
- China
- Prior art keywords
- powder
- ceramic
- composite material
- porous ceramic
- ceramic composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 92
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 51
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 238000010438 heat treatment Methods 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 18
- 239000011812 mixed powder Substances 0.000 claims abstract description 18
- 238000005245 sintering Methods 0.000 claims abstract description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 238000003825 pressing Methods 0.000 claims abstract description 11
- 238000000498 ball milling Methods 0.000 claims abstract description 10
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011521 glass Substances 0.000 claims abstract description 10
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000863 Ferronickel Inorganic materials 0.000 claims abstract description 7
- 239000006004 Quartz sand Substances 0.000 claims abstract description 7
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 7
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000007873 sieving Methods 0.000 claims abstract description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 13
- 239000011148 porous material Substances 0.000 claims description 11
- 239000010453 quartz Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 5
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 abstract description 18
- 229910052751 metal Inorganic materials 0.000 abstract description 15
- 239000002184 metal Substances 0.000 abstract description 15
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 14
- 230000008569 process Effects 0.000 abstract description 9
- 239000003921 oil Substances 0.000 abstract description 5
- 229910001092 metal group alloy Inorganic materials 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 18
- 238000005452 bending Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 8
- 238000000889 atomisation Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 2
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000009766 low-temperature sintering Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003571 electronic cigarette Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/10—Devices using liquid inhalable precursors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/04—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/34—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention relates to the field of ceramic materials, in particular to a metallized porous ceramic composite material and a preparation method thereof, wherein the preparation method of the metallized porous ceramic composite material comprises the following steps: (A) Carrying out dry ball milling on high-purity quartz sand or silicon carbide, then sieving to obtain superfine powder, adding ferronickel powder, boron oxide, a sintering aid, glass powder and a pore-forming agent, and carrying out low-speed ball milling and fully mixing to obtain mixed powder; (B) Mixing the mixed powder with a polyvinyl alcohol aqueous solution, and forming by adopting a dry pressing method to obtain a ceramic green body; (C) And drying the ceramic green body in a drying box, then preserving heat in a program temperature-controlled box type furnace, and cooling to room temperature along with the furnace. The dry pressing method adopted by the invention has simple process, the metal alloy powder is added to form a metal phase in the ceramic, the metal phase is combined with the ceramic to improve the strength of the three-dimensional framework of the ceramic, the matrix can form metallurgical bonding with the heating layer, the strength is improved, and the oil guiding speed of the metallized porous ceramic is accelerated.
Description
Technical Field
The invention relates to the field of ceramic materials, in particular to a metallized porous ceramic composite material and a preparation method thereof.
Background
In the existing partial atomizing heating structure, for example, an atomizing core in an aerosol generating device, a porous ceramic material is used as a base, a heating film is disposed on the base, and an atomizing substrate absorbed by the base is heated and atomized by the heating film to generate aerosol. The porous ceramic material is adopted as the matrix, so that the atomized matrix is uniformly distributed on the matrix, and the heating effect is better.
At present, diatomite is mostly used as a base material of the porous ceramic material, and the diatomite has micro pores, so that native partial pores can be reserved after sintering, and the porous ceramic material can be sintered and formed by adding a binder and a pore-forming agent. Due to the micropores of the diatomite, the porosity of the porous ceramic material formed after sintering can reach the standard, but the diatomite needs to be sintered at high temperature, the preparation process is complex, the preparation flow is long, most of silicon dioxide components contained in the diatomite belong to amorphous silicon dioxide, the strength for crystal form transformation and increase in the high-temperature firing process is limited, so that the three-dimensional framework of the porous ceramic material is fragile and poor in toughness, and a matrix made of the porous ceramic material is easy to break when other parts are assembled, so that the powder falling phenomenon is generated, and the service life and the safety of the matrix are influenced; meanwhile, the porous ceramic material substrate has poor binding force with the metal heating film, and the film substrate is easy to separate and layer in the atomization process, so that burnt flavor is easy to generate, and the taste of aerosol is influenced. According to the technical scheme of the existing porous ceramic, diatomite is mainly used as a main substrate material, the diatomite has micropores, the original part of the micropores can be reserved after sintering, and sintering forming is carried out by adding a certain bonding agent and a certain pore-forming agent.
On one hand, due to the micro pores of the diatomite, the porosity after sintering is ensured, but the main SiO2 component in the diatomite belongs to amorphous SiO2, the strength for crystal form transformation and increase in the high-temperature firing process is limited, and the ceramic matrix is easy to break and generate the powder falling phenomenon during assembly.
On the other hand, the bonding force between the ceramic substrate taking the diatomite as the main body and the metal heating film is poor, a stable metallurgical bonding layer cannot be formed between the heating film and the substrate, and the film substrate is easily separated from the layering in the atomization process, so that the burnt smell is generated, and the use experience of the product is influenced.
Chinese patent application document CN114988903A discloses a high-strength low-shrinkage porous ceramic and a preparation method thereof, and the high-strength low-shrinkage porous ceramic comprises 6-12 parts of a framework material A, 48-54 parts of a framework material B, 15-24 parts of a first pore-forming agent, 15-24 parts of a second pore-forming agent and 1-2 parts of a binder. The porous ceramic is prepared by adopting a pore-forming agent adding method, and meanwhile, the two pore-forming agents, namely the first pore-forming agent and the second pore-forming agent, are added, so that the temperature range of gas released by the pore-forming agent during combustion is widened, the shrinkage rate of the porous ceramic is reduced, and the porous ceramic product with higher porosity and bending strength is obtained. However, the preparation process of the porous ceramic applied by the patent of the invention is relatively complex, and the bending strength of the prepared porous ceramic product is still insufficient and is only 14.56-15.96MPa.
The Chinese invention patent application document CN115180932A discloses an in-situ synthesized mullite porous ceramic based on high-sodium industrial alumina and a preparation method thereof, and the technical scheme is as follows: mixing high-sodium industrial alumina fine powder and tertiary alumina fine powder in a mass ratio of 1: 2.3-3.3 in a ball mill to obtain a mixture; adding a polyvinyl alcohol solution with the weight percent of 10-20% of the mixture, and mixing to obtain ceramic powder; pressing the ceramic powder under the condition of 80-150 MPa, and drying at the temperature of 100-110 ℃; then placing the mixture into a muffle furnace, preserving the heat for 2 to 3 hours under the conditions of air atmosphere and 1550 to 1650 ℃, and cooling to obtain the mullite porous ceramic synthesized in situ on the basis of the high-sodium industrial alumina. The porosity of the porous ceramic prepared by the patent application of the invention is 33-40%, the bending strength is 90-110MPa, and the strength and the air permeability are insufficient.
Disclosure of Invention
In order to overcome the defects of long flow and complex process of the preparation process in the prior art; the prepared porous ceramic material has the defects of poor combination of a heating film and a substrate, short service life, insufficient strength, insufficient toughness, powder falling phenomenon and the like.
In order to achieve the purpose, the technical scheme provided by the invention is as follows:
the invention provides a preparation method of a metallized porous ceramic composite material, which is applied to an electronic cigarette atomizer and can also be applied to other ceramic atomization related fields. The method comprises the following specific steps:
(A) Pretreatment and powder mixing
Mixing high-purity quartz sand or silicon carbide and zirconia balls according to the mass ratio of 1: performing dry ball milling at the ratio of 0.5-1.5, then sieving with a 200-600 mesh sieve to obtain superfine quartz powder or silicon carbide powder, adding ferronickel alloy powder, boron oxide (B2O 3), a sintering aid, glass powder and a pore-forming agent into the superfine powder, wherein the softening point of the glass powder is 500-800 ℃, and fully and uniformly mixing the glass powder by low-speed ball milling to obtain mixed powder;
(B) Porous ceramic forming
Mixing the mixed powder with a polyvinyl alcohol aqueous solution, stirring and uniformly mixing, and forming by adopting a dry pressing method to obtain a ceramic green body;
(C) Sintering and forming of metallized porous ceramics
Drying the ceramic green body in a drying box, heating the ceramic green body in a program temperature-controlled box furnace at the speed of 2-10 ℃/min to reach 1100-1180 ℃, preserving the heat for 0.5-1h, and cooling the ceramic green body to room temperature along with the furnace to obtain the metallized porous ceramic composite material.
Preferably, the mixed powder comprises, by mass, 40-50% of silicon carbide or quartz powder, 3-5% of boron oxide (B2O 3), 3-6% of a sintering aid, 8-15% of glass powder, 3-8% of nickel-iron alloy powder and 30-40% of a pore-forming agent.
Preferably, the SiO2 content in the adopted quartz sand is more than 99 percent, or the purity of the silicon carbide is more than 99 percent.
Preferably, the nickel-iron alloy powder contains 50-65% of nickel and the balance of iron by mass percent, and the mesh number is 300-400 meshes.
Preferably, the sintering aid is CaCO3; the pore-forming agent is one or all of PMMA (polymethyl methacrylate) and PS (polystyrene), and the particle size is 50-200um.
Preferably, the mass percentage concentration of the polyvinyl alcohol aqueous solution is 0.9-1.0%, and the mass of the polyvinyl alcohol aqueous solution is 5-7% of the mass of the mixed powder.
Preferably, the pressure of the dry pressing molding is 400-600MPa, and the dwell time is 5-10min.
Preferably, the temperature in the drying oven is 70-90 ℃, and the drying time in the drying oven is 4-6h.
Preferably, the boron oxide (B2O 3) is all in the form of particles or powder, and the mesh number is 300-400.
The metallized porous ceramic composite material prepared by the method has the advantages of apparent porosity of 50-60%, pore diameter of 16-40um and bending strength of 130-200MPa.
The dry pressing method adopted by the invention has simple process, the metal alloy powder is added to form a metal phase in the ceramic, the metal phase is combined with the ceramic to improve the three-dimensional framework strength of the ceramic, meanwhile, the matrix can also form metallurgical combination with the heating layer, the service life is prolonged, and the oil guiding speed of the metallized porous ceramic is accelerated. The ceramic is metallized by adding the ferronickel alloy into the ceramic powder, the three-dimensional framework in the matrix is jointly composed of a ceramic phase and a metal phase, compared with a single ceramic phase, the formation of the metal phase changes the original heat conductivity coefficient and thermal expansion coefficient of the ceramic matrix, the performance of the metallized composite material is changed from the typical brittleness and hardness of the ceramic phase to the toughness and toughness of the metal phase, the comprehensive mechanical property is greatly improved, the original mechanical adhesion and combination between the heating film and the matrix is changed into metallurgical combination, the single ceramic phase and the heating film cause the matrix to break during atomization due to the great difference of the thermal expansion coefficients, and the change of the heat conductivity coefficient and the thermal expansion coefficient of the composite material can better match the heating film and the metallurgical combination layer formed by the heating film, so that the service life is obviously prolonged.
The metalized porous ceramic composite material prepared by the invention has obviously improved strength, can meet the manufacturing and assembling requirements under various composite stress conditions, forms metallurgical bonding with the heating layer of the thick film printing and thin film coating, greatly prolongs the service life of the atomizing core, meets the high-power atomizing requirement, and accelerates the oil guiding speed of the metalized porous ceramic composite material.
Detailed Description
In terms of explanation, the terms "ultrafine powder", "ultrafine quartz powder" and "ultrafine silicon carbide powder" as used in the present specification and claims refer to respective powders having a particle size of 2 to 90 μm.
The following describes specific embodiments of the present invention in terms of material composition, mixture ratio, specific preparation steps, test results, and the like.
The porosity, the pore diameter of the through hole and the bending strength value of the metallized porous ceramic composite material prepared in all the examples are measured.
Porosity: the apparent porosity, i.e. porosity, of the porous ceramic was tested according to the national standard GB/T1996-1996. The percentage of the volume of open pores in a porous material to the total volume of the material is called the apparent porosity and the standard specifies their formula for calculation as follows:
q-apparent porosity of sample,%;
m 1-drying quality of the sample;
m 2-mass of saturated sample in air;
m 3-mass of saturated sample in water;
wherein the saturated sample can be prepared by vacuum pumping or boiling.
Through hole diameter: the pore diameter of the porous ceramic material is measured according to a test method of the pore diameter of the porous ceramic according to the national standard GB/T1967-1996, and the specific operation is that a porous ceramic sample is immersed in test liquid (distilled water) and then immersed in the test liquid, gas (air or nitrogen) is slowly introduced into the porous ceramic sample, the pressure is gradually increased on the porous ceramic sample, so that the test gas is forced to pass through the porous ceramic sample in saturated water, the minimum pressure required when first bubbles are formed on the surface of the porous ceramic sample is obtained, and the maximum capillary pore diameter of the porous ceramic sample can be calculated.
Bending strength: the ceramic material was tested for flexural strength according to the national standard GB/T4741-1999. The standard specifies that the room temperature bending strength of ceramic materials is measured by a three-point load method, and a bending strength tester is used for testing the bending strength.
Example 1:
1. composition and proportion of mixed powder
2. The concrete preparation steps
(A) Pretreatment and powder mixing
(a) Mixing quartz sand and zirconia balls according to the mass ratio of 1:1, performing dry ball milling for 2 hours, and sieving with a 300-mesh sieve to obtain superfine quartz powder;
(b) Adding a sintering aid CaCO3, ferronickel powder, boron oxide, glass powder and a pore-forming agent PMMA into the superfine quartz powder, and fully and uniformly mixing the materials through low-speed ball milling to obtain mixed powder;
(B) Porous ceramic forming
(a) Mixing the mixed powder with a polyvinyl alcohol aqueous solution, wherein the mass percentage concentration of the polyvinyl alcohol aqueous solution is 1.0 percent, the mass of the polyvinyl alcohol aqueous solution is 6 percent of the mass of the mixed powder, and stirring and mixing
Mixing uniformly;
(b) Forming by dry pressing method under 400-600MPa for 5-10min to obtain ceramic green body;
(C) Low temperature sintering
(a) Drying the ceramic green body in a drying oven at 85 ℃ for 4 hours;
(b) Then heating up in a program temperature control box type furnace at the speed of 5 ℃/min to achieve 1120 ℃ and preserving heat for 0.5h;
(c) Cooling to room temperature along with the furnace.
3. Test results
The basic properties of the prepared metallized porous ceramic composite material are determined as follows:
example 2:
1. composition and proportion of mixed powder
2. The concrete preparation steps
(A) Pretreatment and powder mixing
(a) Mixing quartz sand and zirconia balls according to the mass ratio of 1:1, performing dry ball milling for 2 hours, and sieving with a 300-mesh sieve to obtain superfine quartz powder;
(b) Adding a sintering aid CaCO3, ferronickel powder, boron oxide, glass powder and a pore-forming agent PMMA into the superfine quartz powder, and fully and uniformly mixing the materials through low-speed ball milling to obtain mixed powder;
(B) Porous ceramic forming
(a) Mixing the mixed powder with a polyvinyl alcohol aqueous solution, wherein the mass percentage concentration of the polyvinyl alcohol aqueous solution is 1.0 percent, and the mass of the polyvinyl alcohol aqueous solution is 6 percent of the mass of the mixed powder, stirring and mixing
Mixing uniformly;
(b) Forming by dry pressing method under 400-600MPa for 5-10min to obtain ceramic green body;
(C) Low temperature sintering
(a) Drying the ceramic green body in a drying oven at 85 ℃ for 4 hours;
(b) Then heating up in a program temperature control box type furnace at the speed of 5 ℃/min to achieve 1120 ℃ and preserving heat for 0.5h;
(c) Cooling to room temperature along with the furnace.
3. Test results
The basic properties of the prepared metallized porous ceramic composite material are determined as follows:
| porosity of the material | Aperture of through hole | Bending strength |
| 53.15％ | 21.26um | 172MPa |
The preparation method adopts a dry pressing process which is simple, the melting temperature of the nickel-iron alloy is obviously reduced by adding boron oxide, the nickel, iron and boron elements and the Si element in the ceramic powder form a NiFeBSi amorphous alloy metal phase in the high-temperature sintering process and are connected with the matrix through non-covalent bonds and covalent bonds, a continuous metal phase is formed in the porous ceramic three-dimensional framework after sintering, the metal phase is combined with the ceramic phase to improve the strength of the ceramic three-dimensional framework, meanwhile, the matrix can also form metallurgical combination with the heating layer to improve the service life, and the oil guiding speed of the metallized porous ceramic is accelerated. The ceramic is metallized by adding the ferronickel alloy into the ceramic powder body, the three-dimensional framework in the matrix is jointly formed by the ceramic phase and the metal phase, compared with a single ceramic phase, the formation of the metal phase changes the original heat conductivity coefficient and thermal expansion coefficient of the ceramic matrix, the performance of the metallized composite material is changed from the typical brittleness and hardness of the ceramic phase to the toughness and toughness of the metal phase, the comprehensive mechanical property is greatly improved, the original mechanical adhesion and combination between the heating film and the matrix is changed into metallurgical combination, the single ceramic phase and the heating film cause the matrix to break during atomization due to the great difference of the thermal expansion coefficients, the change of the heat conductivity coefficient and the thermal expansion coefficient of the composite material can better match the heating film and the metallurgical combination layer formed by the heating film, the service life can be obviously prolonged, and the requirement of high-power atomization on the whole atomization core is also met.
The metalized porous ceramic composite material prepared by the invention has obviously improved strength, can meet the manufacturing and assembling requirements under various composite stress conditions, forms metallurgical bonding with the heating layer of the thick film printing and thin film coating, greatly prolongs the service life of the atomizing core, meets the high-power atomizing requirement, and accelerates the oil guiding speed of the metalized porous ceramic composite material.
Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and modifications and variations of the present invention are also intended to fall within the scope of the appended claims. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (10)
1. A preparation method of a metallized porous ceramic composite material comprises the following steps:
(A) Pretreatment and powder mixing
Mixing high-purity quartz sand or silicon carbide and zirconia balls according to the mass ratio of 1: performing dry ball milling at the ratio of 0.5-1.5, then sieving with a 200-600 mesh sieve to obtain superfine quartz powder or silicon carbide powder, adding ferronickel alloy powder, boron oxide, a sintering aid, glass powder and a pore-forming agent into the superfine powder, wherein the softening point of the glass powder is 500-800 ℃, and performing low-speed ball milling and fully mixing to obtain mixed powder;
(B) Porous ceramic forming
Mixing the mixed powder with a polyvinyl alcohol aqueous solution, stirring and mixing uniformly, and forming by adopting a dry pressing method to obtain a ceramic green body;
(C) Sintering and forming of metallized porous ceramics
Drying the ceramic green body in a drying box, then heating in a program temperature-controlled box furnace at the speed of 2-10 ℃/min to reach 1100-1180 ℃, preserving heat for 0.5-1h, and cooling to room temperature along with the furnace.
2. The method for preparing the ceramic composite material according to claim 1, wherein the mixed powder comprises, by mass, 40-50% of silicon carbide or quartz powder, 3-5% of boron oxide, 3-6% of a sintering aid, 8-15% of glass powder, 3-8% of nickel-iron alloy powder and 30-40% of a pore-forming agent.
3. The method for preparing a ceramic composite material according to claim 1 or 2, wherein the quartz sand used has a SiO2 content of more than 99% or a silicon carbide purity of more than 99%.
4. The method for preparing a ceramic composite material according to claim 1 or 2, wherein the nickel-iron alloy powder contains 50 to 65 mass percent of nickel and the balance of iron, and the mesh number is 300 to 400.
5. The method for preparing the ceramic composite material as claimed in claim 1 or 2, wherein the sintering aid is CaCO3, and the pore-forming agent is one or both of polymethyl methacrylate and polystyrene.
6. The preparation method of the ceramic composite material according to claim 1 or 2, wherein the mass percentage concentration of the polyvinyl alcohol aqueous solution is 0.9-1.0%, and the mass of the polyvinyl alcohol aqueous solution is 5-7% of the mass of the mixed powder.
7. The method for preparing a ceramic composite material according to claim 1 or 2, wherein the pressure for the dry-pressing molding is 400 to 600MPa, and the dwell time is 5 to 10min.
8. The method of claim 1 or 2, wherein the temperature in the drying oven is 70-90 ℃ and the drying time in the drying oven is 4-6h.
9. The method of claim 1 or 2, wherein the boron oxide is entirely in the form of particles or powder, and has a mesh size of 300 to 400 mesh.
10. A metallized porous ceramic composite material prepared by the method of any one of claims 1-9, having a porosity of 50-60%, a pore size of 16-40um, and a flexural strength of 130-200MPa.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211625299.0A CN115819110A (en) | 2022-12-16 | 2022-12-16 | Metallized porous ceramic composite material and preparation method thereof |
| PCT/CN2023/093139 WO2024124786A1 (en) | 2022-12-16 | 2023-05-10 | Metalized porous ceramic composite material and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211625299.0A CN115819110A (en) | 2022-12-16 | 2022-12-16 | Metallized porous ceramic composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115819110A true CN115819110A (en) | 2023-03-21 |
Family
ID=85516369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211625299.0A Pending CN115819110A (en) | 2022-12-16 | 2022-12-16 | Metallized porous ceramic composite material and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN115819110A (en) |
| WO (1) | WO2024124786A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116752025A (en) * | 2023-06-12 | 2023-09-15 | 深圳市吉迩科技有限公司 | Metal and porous ceramic biphase composite material and preparation method thereof |
| WO2024124786A1 (en) * | 2022-12-16 | 2024-06-20 | 深圳市吉迩技术有限公司 | Metalized porous ceramic composite material and preparation method therefor |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118580089B (en) * | 2024-08-06 | 2024-10-11 | 尊龙新材料(山东)有限公司 | High-strength silicon carbide refractory material and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5214011A (en) * | 1991-08-30 | 1993-05-25 | Bfd, Incorporated | Process for preparing ceramic-metal composite bodies |
| CN104388725A (en) * | 2014-12-11 | 2015-03-04 | 成都明日星辰科技有限公司 | Preparation method of high-performance SiC/Al composite material used for electronic packaging |
| CN105130481A (en) * | 2015-07-10 | 2015-12-09 | 汕头大学 | Metal-ceramic composite base plate and preparation technology of same |
| CN107805057A (en) * | 2017-10-12 | 2018-03-16 | 天津大学 | A kind of Metal toughened ceramic base boule composite |
| CN114213139A (en) * | 2021-12-31 | 2022-03-22 | 深圳市吉迩科技有限公司 | Preparation method of ceramic heating element and ceramic heating element |
| CN114394849A (en) * | 2021-12-29 | 2022-04-26 | 深圳市吉迩科技有限公司 | Porous ceramic composite material and preparation method thereof |
| CN114524615A (en) * | 2021-12-31 | 2022-05-24 | 深圳市吉迩科技有限公司 | Quartz sand microcrystalline porous ceramic and preparation method thereof |
| CN114634372A (en) * | 2022-03-25 | 2022-06-17 | 山东国瓷功能材料股份有限公司 | Porous ceramic material for atomizing core, porous ceramic body, ceramic atomizing core, preparation method and electronic cigarette |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5735332A (en) * | 1992-09-17 | 1998-04-07 | Coors Ceramics Company | Method for making a ceramic metal composite |
| CN115819110A (en) * | 2022-12-16 | 2023-03-21 | 深圳市吉迩技术有限公司 | Metallized porous ceramic composite material and preparation method thereof |
-
2022
- 2022-12-16 CN CN202211625299.0A patent/CN115819110A/en active Pending
-
2023
- 2023-05-10 WO PCT/CN2023/093139 patent/WO2024124786A1/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5214011A (en) * | 1991-08-30 | 1993-05-25 | Bfd, Incorporated | Process for preparing ceramic-metal composite bodies |
| CN104388725A (en) * | 2014-12-11 | 2015-03-04 | 成都明日星辰科技有限公司 | Preparation method of high-performance SiC/Al composite material used for electronic packaging |
| CN105130481A (en) * | 2015-07-10 | 2015-12-09 | 汕头大学 | Metal-ceramic composite base plate and preparation technology of same |
| CN107805057A (en) * | 2017-10-12 | 2018-03-16 | 天津大学 | A kind of Metal toughened ceramic base boule composite |
| CN114394849A (en) * | 2021-12-29 | 2022-04-26 | 深圳市吉迩科技有限公司 | Porous ceramic composite material and preparation method thereof |
| CN114213139A (en) * | 2021-12-31 | 2022-03-22 | 深圳市吉迩科技有限公司 | Preparation method of ceramic heating element and ceramic heating element |
| CN114524615A (en) * | 2021-12-31 | 2022-05-24 | 深圳市吉迩科技有限公司 | Quartz sand microcrystalline porous ceramic and preparation method thereof |
| CN114634372A (en) * | 2022-03-25 | 2022-06-17 | 山东国瓷功能材料股份有限公司 | Porous ceramic material for atomizing core, porous ceramic body, ceramic atomizing core, preparation method and electronic cigarette |
Non-Patent Citations (2)
| Title |
|---|
| 古一等: "涂层与基底的热膨胀系数差对垂直界面的微裂纹的影响", 《湖南有色金属》, vol. 23, no. 3, pages 33 - 36 * |
| 王莉莉等: "掺杂Ni /Al 对热障涂层抗高温氧化性和结合强度的影响", 《人工晶体学报》, vol. 45, no. 7, pages 1981 - 1985 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024124786A1 (en) * | 2022-12-16 | 2024-06-20 | 深圳市吉迩技术有限公司 | Metalized porous ceramic composite material and preparation method therefor |
| CN116752025A (en) * | 2023-06-12 | 2023-09-15 | 深圳市吉迩科技有限公司 | Metal and porous ceramic biphase composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2024124786A1 (en) | 2024-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN115819110A (en) | Metallized porous ceramic composite material and preparation method thereof | |
| CN108623322B (en) | Porous ceramic, preparation method thereof, atomizing core and electronic cigarette | |
| CN113511886B (en) | Ceramic atomizing core and preparation method thereof | |
| CN113603503B (en) | Microporous ceramic atomizing core and preparation method thereof | |
| CN110713379A (en) | Porous ceramic atomizing core and preparation method thereof | |
| JP2023553454A (en) | Nanoporous ceramics for atomization core and manufacturing method thereof | |
| CN111138175B (en) | Porous ceramic substrate, preparation method thereof and atomizing core | |
| CN109437875A (en) | Micropore ceramics, ceramic heating element and its preparation method and application | |
| CN104625071B (en) | A kind of preparation method of powder injection-molded surface pore material | |
| Su et al. | A new Al 2 O 3 porous ceramic prepared by addition of hollow spheres | |
| CN100548604C (en) | Strong magnetic-weak magnetic gradient material formed by slip casting preparation method in the pulsed magnetic field | |
| CN112624793A (en) | Preparation method of alumina-based porous ceramic material | |
| CN103397256A (en) | Sintered Fe-Al-based porous alloy material with high-temperature oxidization resistance and filtering element | |
| CN112409000A (en) | Mullite push plate for ceramic metallization furnace and preparation method thereof | |
| CN114394849A (en) | Porous ceramic composite material and preparation method thereof | |
| CN111423247A (en) | Porous ceramic, preparation method and heating element thereof | |
| CN110252157A (en) | A kind of reinforced metal composite ceramic film and preparation method thereof | |
| CN104496522A (en) | Method for preparing aluminum oxide/mullite foamed ceramic | |
| CN101786139A (en) | Polymer-modified silicasol and manufacturing method thereof | |
| CN111876625B (en) | AlNMg composite material and preparation method thereof | |
| US20240002294A1 (en) | Alkaline porous ceramic matrix and preparation method thereof, electronic-cigarette vaporization core, and electronic cigarette | |
| CN105272264B (en) | A kind of preparation method of double interpenetrating phase SiC/Si composite materials | |
| CN108751998B (en) | Silicon nitride and silicon carbide combined ceramic filter and preparation method thereof | |
| CN113105224B (en) | Mullite ceramic with high strength and low shrinkage performance and preparation method thereof | |
| CN116496069A (en) | Preparation method of fiber porous ceramic and fiber porous ceramic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20230321 |