CN115746639A - Acrylic acid super-hydrophobic coating capable of being heated by microwave and preparation method thereof - Google Patents

Acrylic acid super-hydrophobic coating capable of being heated by microwave and preparation method thereof Download PDF

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CN115746639A
CN115746639A CN202211257266.5A CN202211257266A CN115746639A CN 115746639 A CN115746639 A CN 115746639A CN 202211257266 A CN202211257266 A CN 202211257266A CN 115746639 A CN115746639 A CN 115746639A
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microwave
heated
acrylic
acrylic acid
substrate layer
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CN115746639B (en
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彭超
胡雨冬
杨汉能
徐方
刘雅峰
吴天昊
刘航
阮迪
阳东锦
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China University of Geosciences
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Abstract

The invention discloses an acrylic acid super-hydrophobic coating capable of being heated by microwave, which consists of a substrate layer suitable for an asphalt pavement and a micro-nano structure constructed on the substrate layer; the base layer is formed by mixing and curing acrylic paint and an acrylic curing agent for a road; the micro-nano structure is formed by uniformly dispersing carbon nanotubes on the surface of a substrate layer; the thickness of the substrate layer is 1-2 mm; the pipe diameter of the carbon nano tube is 5-15 nm; the length is 2-8 μm; the specific surface area is more than or equal to 250m 2 (ii)/g; the resistivity is 100m omega cm; the coating imitates a super-hydrophobic structure on the surface of lotus leaf,combining the microwave heating principle to obtain an acrylic acid super-hydrophobic coating which is suitable for the asphalt pavement and can be heated by microwaves; the invention also discloses the asphalt pavement capable of being heated by the microwave and a road deicing method.

Description

Acrylic acid super-hydrophobic coating capable of being heated by microwave and preparation method thereof
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to an acrylic acid super-hydrophobic coating capable of being heated by microwaves and a preparation method thereof.
Background
Transportation is the basis and the leader of national economy development, and the development level of transportation and the development of national economy have very important relation. As China is in the subao-European plate, and the breadth of the population is wide, the climate is complex. Except for a small part of regions, most regions have the temperature condition of zero in winter, which has great influence on the road traffic safety of China. If ice layers and accumulated snow on the road surface are not processed in time, the driving safety of citizens is seriously threatened. Meanwhile, the phenomenon of accumulated snow and icing on the road surface can also damage the road surface structure, cause traffic jam and seriously influence national economy, so that the research on the method for preventing/removing the ice on the asphalt road surface has practical significance and economic benefit.
In order to eliminate the potential safety hazard brought by the icing of the asphalt pavement. At present, aiming at the problem of snow accumulation and icing of the asphalt pavement in winter, the main anti-icing and deicing methods at present comprise an artificial deicing method, a mechanical deicing method, a snow-melting agent method, a thermal snow-melting and deicing method, a self-stress elastic pavement deicing method and the like. However, the above methods for preventing and removing ice all have the problems of environmental pollution and high cost. With the development of the times and the progress of the society, the sustainable development consciousness of saving resources and protecting the environment is strengthened in the heart of people. In order to meet the development concept of environmental protection, a method for removing ice and snow on the road surface, which has the advantages of good ice-preventing and deicing performance, no damage to the road surface structure, environmental protection and durable snow and ice melting and deicing functions, needs to be researched urgently. Therefore, the research on the ice and snow removing technology with simple process, high cost performance and low energy consumption has important significance for ice prevention and ice removal of the asphalt pavement of the highway.
The super-hydrophobic coating can promote water drops to roll off, delay the icing time of the water drops and reduce the adhesive force between an ice layer and the surface of the coating. But when the temperature is low in winter and rain and snow are large. The rain and snow on the road surface can not be discharged in time, and the road icing phenomenon can still occur. A method for actively removing the ice layer on the road surface is needed. Microwave heating is achieved by the absorption of microwaves by a polar dielectric material, thereby converting the electromagnetic energy of the microwaves into thermal energy of the dielectric. The microwave heating has the advantages of high thermal response speed, less heat conduction process, selective heating and the like.
Disclosure of Invention
The invention aims to provide a microwave-heatable acrylic acid super-hydrophobic coating and a preparation method thereof, the coating imitates a super-hydrophobic structure on the surface of lotus leaves, and combines the microwave heating principle to obtain the acrylic acid super-hydrophobic coating which is suitable for asphalt pavement and can be heated by microwaves; the invention also aims to provide a novel method for solving the problems of ice prevention and ice removal of the asphalt pavement of the highway.
In order to achieve the purpose, the technical scheme is as follows:
an acrylic acid super-hydrophobic coating capable of being heated by microwave, which consists of a substrate layer suitable for asphalt pavement and a micro-nano structure constructed on the substrate layer;
the base layer is formed by mixing and curing acrylic paint and an acrylic curing agent for a road;
the micro-nano structure is formed by uniformly dispersing carbon nanotubes on the surface of the substrate layer.
According to the scheme, the thickness of the substrate layer is 1-2 mm.
According to the scheme, the pipe diameter of the carbon nano tube is 5-15 nm; the length is 2-8 mu m; the specific surface area is more than or equal to 250m 2 (ii)/g; the resistivity was 100 m.OMEGA.cm.
The preparation method of the acrylic acid super-hydrophobic coating capable of being heated by microwave comprises the following steps:
uniformly mixing acrylic paint and an acrylic curing agent, and then brushing to prepare a basal layer; and spraying the ethanol dispersion liquid of the carbon nano tube on the substrate layer by using an air pump spray gun, so that the carbon nano tube particles are uniformly distributed on the surface of the uncured substrate layer in an aerosol form, and curing to obtain the acrylic acid super-hydrophobic coating capable of being heated by microwave.
According to the scheme, the ethanol dispersion liquid of the carbon nano tube comprises 1 part by weight of carbon nano tube particles and 18-22 parts by weight of carbon nano tube particles.
According to the scheme, the spraying amount of the ethanol dispersion liquid of the carbon nano tube is 55mL/m 2 ~65mL/m 2
The asphalt pavement capable of being heated by microwaves consists of an asphalt concrete pavement and the acrylic acid super-hydrophobic coating which is constructed on the asphalt concrete pavement and can be heated by microwaves.
According to the scheme, the gradation of the asphalt concrete pavement is AC-16.
A method of deicing a road comprising the steps of:
paving a road with the asphalt pavement capable of being heated by the microwave; and (4) heating and deicing by adopting microwave after the ice layer is covered.
Compared with the prior art, the invention has the following beneficial effects:
the acrylic acid super-hydrophobic coating capable of being heated by microwaves has good super-hydrophobic, anti-icing, anti-aging and wear-resistant performances, and can meet the performance requirements of the pavement.
The acrylic acid super-hydrophobic coating capable of being heated by microwaves has good microwave heating performance, and the acrylic acid coating has strong heat insulation performance, so that the heat on the surface of the coating is difficult to be conducted into the interior of an asphalt pavement during microwave heating, and the damage caused by heating is avoided.
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FIG. 1: the invention discloses a schematic diagram of an asphalt pavement capable of being heated by microwaves.
Detailed Description
The following examples further illustrate the technical solutions of the present invention, but should not be construed as limiting the scope of the present invention.
The specific embodiment provides a acrylic acid super-hydrophobic coating capable of being heated by microwaves, and the coating consists of a substrate layer suitable for asphalt pavement and a micro-nano structure constructed on the substrate layer; the base layer is formed by mixing and curing acrylic paint and an acrylic curing agent for a road; the micro-nano structure is formed by uniformly dispersing carbon nanotubes on the surface of the substrate layer.
Specifically, the diameter of the carbon nano tube is 5-15 nm; the length is 2-8 mu m; the specific surface area is more than or equal to 250m 2 (ii)/g; the resistivity was 100 m.OMEGA.cm.
When the base layer is applied to the asphalt pavement, the thickness of the base layer is 1-2 mm.
The specific embodiment also provides a preparation method of the acrylic acid super-hydrophobic coating capable of being heated by microwave, which comprises the following steps:
uniformly mixing acrylic paint and an acrylic curing agent, and then brushing to prepare a basal layer; and spraying the ethanol dispersion liquid of the carbon nano tube on the substrate layer by using an air pump spray gun, so that the carbon nano tube particles are uniformly distributed on the surface of the uncured substrate layer in an aerosol form, and curing to obtain the acrylic acid super-hydrophobic coating capable of being heated by microwave.
Specifically, the ethanol dispersion liquid of the carbon nano tube comprises 1 part by weight of carbon nano tube particles and 18-22 parts by weight of carbon nano tube particles; the spraying amount is 55mL/m 2 ~65mL/m 2
The specific embodiment also provides a microwave-heatable asphalt pavement, which consists of an asphalt concrete pavement and the acrylic acid super-hydrophobic coating capable of being heated by microwaves, and is constructed on the asphalt concrete pavement, and the reference figure 1 shows the following steps.
Specifically, the asphalt concrete pavement is graded as AC-16.
The invention also provides a road deicing method, which comprises the steps of paving a road on the asphalt pavement capable of being heated by the microwaves; and (4) heating and deicing by adopting microwave after the ice layer is covered.
The acrylic paint in the following examples is TS300 super black acrylic polyurethane matte finish paint produced by Swan paint (Wuhan) science and technology, inc.; the acrylic acid curing agent is a curing agent for acrylic polyurethane finish paint produced by Swan paint (Wuhan) science and technology, inc. Hereinafter referred to simply as acrylic acid and curing agent. The base layer is formed by mixing and curing acrylic paint and an acrylic curing agent for road. The shear strength of the substrate layer was 25MPa and the curing time was <4h.
Example 1:
the invention relates to an acrylic acid super-hydrophobic coating with a microwave heating function, which is prepared by the following steps:
taking 3 parts of road acrylic paint and 1 part of acrylic curing agent by weight. Dispersing an acrylic acid curing agent in acrylic paint, and stirring at a low speed for 1 minute to completely fuse the acrylic paint and the acrylic acid curing agent to prepare a substrate layer. And uniformly coating a substrate layer on the surface of the asphalt pavement. Weighing 1 part of carbon nano tube particles and 18-22 parts of absolute ethyl alcohol according to parts by weight. Dispersing carbon nano tube particles in absolute ethyl alcohol, and slowly stirring for 10-15 min to prepare the micro-nano structure. And spraying the dispersion liquid on the substrate layer by using an air pump spray gun to ensure that the carbon nano tube particles are uniformly distributed on the surface of the uncured coating in an aerial fog mode, and preparing the acrylic acid super-hydrophobic coating with the microwave heating function after the coating is completely cured.
The hydrophobic coating with microwave heating prepared in this example was prepared by measuring the contact angle and rolling angle of a water droplet with the coating using an optical contact angle measuring instrument model SDC-100 and a manual angle station model GFSG 60-35; testing the icing rate of the water drop on the surface of the sample by using a DT-610B thermocouple; using a 800w Supor household microwave oven to test the temperature change and microwave deicing condition of the sample after microwave heating; the anti-skid pendulum value of the road surface is measured by using a test method for measuring the friction coefficient of the road surface by using a T0964-2008 pendulum instrument. In addition, the coating was subjected to an indoor load-wheel compaction test to determine the wear resistance of the coating. In the indoor load wheel rolling experiment, an SYD-0755 type load wheel rolling tester is adopted to roll the test sample repeatedly for 500 times, and the load mass is adjusted to be 56.7kg in the experiment and is equal to the grounding pressure of standard axle load BZZ-100. And comparing the measured result with a common asphalt mixture test piece and an asphalt mixture test piece coated with an acrylic acid coating, wherein the results are as follows:
wherein the common asphalt mixture test piece is a blank control group; the spraying amount of the carbon nano tube is 0ml/m for the asphalt mixture test piece coated with the acrylic acid coating 2 The asphalt mixture test piece; the spraying amount of the carbon nano tube of the asphalt mixture test piece coated with the acrylic acid super-hydrophobic coating with the microwave heating function is 20mL/m 2 The asphalt mixture test piece.
The contact angle refers to the angle between the solid-liquid interface and the gas-liquid interface passing through the interior of the liquid, and represents the degree of wetting of the solid surface. The rolling angle is the critical angle of inclination at which the surface liquid droplet starts to roll off under the action of gravity when the solid surface is slowly inclined, and represents the difficulty of the liquid droplet rolling on the solid surface. The test results of the contact angle and the rolling angle of the water drop on the surfaces of different coatings are shown in table 1.
TABLE 1
Figure BDA0003890081840000041
1ml of deionized water is respectively dripped on the surfaces of a common asphalt mixture test piece, an asphalt mixture test piece coated with an acrylic acid coating and an asphalt mixture test piece coated with a super-hydrophobic coating in a certain quantity, the 3 mixture test pieces are put into a special test box of a material testing machine, the refrigeration temperature is set to be-10 ℃, when the temperature of the test box is reduced to 0 ℃, an initial temperature of water drops is measured by using a DT-610B type contact thermocouple thermodetector, then the temperature of the water drops is measured once every 3min until the water drops on the surface of the mixture form an opaque ice-water mixture, the water drops are regarded as reaching the freezing temperature, and the freezing time of the water drops on the surface of the mixture is recorded as shown in a table 2.
TABLE 2
Figure BDA0003890081840000042
Respectively putting a common asphalt mixture test piece, an asphalt mixture test piece coated with an acrylic acid coating and an asphalt mixture test piece coated with a super-hydrophobic coating into a Supor household microwave oven (the heating power is 800 w) for carrying out microwave heating for multiple times. The heating time per microwave was determined to be 20 seconds. After heating each asphalt mixture in a microwave oven for 20 seconds, photographs were taken by an infrared camera and the temperature after each microwave heating was recorded. The asphalt mixture is then immediately transferred to a microwave oven for the next microwave heating. After 160s of microwave heating, the temperature change conditions of the surfaces of the three test pieces are analyzed, and the microwave heat absorption rates of the three test pieces can be obtained. The results of the microwave heating test on the various test pieces are shown in Table 3.
TABLE 3
Figure BDA0003890081840000051
Respectively putting a common asphalt mixture test piece with an ice layer with the thickness of 10mm, an asphalt mixture test piece coated with an acrylic acid coating and an asphalt mixture test piece coated with a super-hydrophobic coating into a microwave oven (the heating power is 800 w) for carrying out microwave heating for multiple times. The heating time per microwave was determined to be 20 seconds. After heating each asphalt mixture in a microwave oven for 20 seconds, photographs were taken by an infrared camera and the temperature after each microwave heating was recorded. The asphalt mixture is then immediately transferred to a microwave oven for the next microwave heating. The microwave heating is carried out until the ice layer can be naturally removed, and the time for removing the ice layer on the surfaces of the three test pieces is analyzed, so that the microwave deicing efficiency of the three test pieces can be obtained, and is shown in table 4.
TABLE 4
Figure BDA0003890081840000052
A section of AC-16 asphalt concrete pavement is selected as the test pavement. A plain AC-16 asphalt concrete pavement was used as a blank control. And respectively coating a common acrylic acid coating and the super-hydrophobic coating obtained in the example 1 on the AC-16 asphalt concrete pavement, and carrying out a water permeability coefficient test and a pavement pendulum value test on the common acrylic acid coating and the super-hydrophobic coating. The water permeability coefficient of the pavement is measured by referring to a T0971-2017 asphalt pavement water permeability coefficient test method in JTG E60-2019 (road foundation and pavement site test regulations). The test results are shown in Table 5.
TABLE 5
Figure BDA0003890081840000053
In the pavement pendulum value test result, the measured average pendulum value needs to be converted into a pendulum value with the standard temperature of 20 ℃ to evaluate the skid resistance of the super-hydrophobic asphalt pavement in a wet state, and the calculation is carried out according to a formula (T0964-1) in the road subgrade and pavement site test regulations (JTG 3450-2019). The skid resistance pendulum value of a first-grade road asphalt pavement is specified to be greater than or equal to 45 in the road asphalt pavement design Specification (JTJ 014-97). The swing values for different road surfaces are shown in table 6.
TABLE 6
Figure BDA0003890081840000054
Figure BDA0003890081840000061
And (3) performing an indoor load wheel rolling test by referring to T0755-2011 in test highway engineering asphalt and asphalt mixture test procedure JTG E20-2011. The test is carried out by adopting a SYD-0755 load wheel rolling tester produced by Shanghai Changji geological instruments company. The experimental procedure of the load wheel rolling test is as follows. Firstly, a rectangular asphalt mixture with the thickness of 405mm multiplied by 75mm multiplied by 20mm is prepared, and an acrylic acid super-hydrophobic coating with a microwave heating function is uniformly coated on the surface of the asphalt mixture. And fixing the asphalt mixture after the coating is solidified on a test bed of a load wheel rolling tester. And adjusting the wheel load until the wheel pressure of a load wheel on the asphalt mixture is 0.7MPa. The loading wheel rolls back and forth 500 times on the surface of the asphalt mixture. Finally, the contact angle and the microwave heating performance of the surface of the asphalt mixture coated with the acrylic acid super-hydrophobic coating before and after rolling are tested. The contact angle and microwave heating temperature change test results of the acrylic acid super-hydrophobic asphalt mixture surface before and after rolling are shown in table 7.
TABLE 7
Figure BDA0003890081840000062

Claims (9)

1. An acrylic acid super-hydrophobic coating capable of being heated by microwave is characterized in that the coating consists of a substrate layer suitable for asphalt pavement and a micro-nano structure constructed on the substrate layer;
the base layer is formed by mixing and curing acrylic paint and an acrylic curing agent for a road;
the micro-nano structure is formed by uniformly dispersing carbon nanotubes on the surface of a substrate layer.
2. A microwave heatable acrylic superhydrophobic coating according to claim 1, wherein the substrate layer has a thickness of 1 to 2mm.
3. The acrylic acid super-hydrophobic coating capable of being heated by microwave as claimed in claim 1, wherein the tube diameter of the carbon nanotube is 5-15 nm; the length is 2-8 mu m; the specific surface area is more than or equal to 250m 2 (ii)/g; the resistivity was 100 m.OMEGA.cm.
4. The method for preparing the acrylic superhydrophobic coating capable of being heated by microwave according to claim 1, characterized by comprising the steps of:
uniformly mixing acrylic paint and an acrylic curing agent, and then brushing to prepare a basal layer; and spraying the ethanol dispersion liquid of the carbon nano tube on the substrate layer by using an air pump spray gun, so that the carbon nano tube particles are uniformly distributed on the surface of the uncured substrate layer in an aerosol form, and curing to obtain the acrylic acid super-hydrophobic coating capable of being heated by microwave.
5. The method for preparing the acrylic acid super-hydrophobic coating capable of being heated by microwave as claimed in claim 4, wherein the ethanol dispersion of the carbon nanotube accounts for 1 part and 18-22 parts by weight of the carbon nanotube particles.
6. The method for preparing the acrylic superhydrophobic coating capable of being heated by microwave according to claim 4, wherein the spraying amount of the ethanol dispersion of the carbon nanotubes is 55mL/m 2 ~65mL/m 2
7. A microwaveable asphalt pavement comprising an asphalt concrete pavement and a microwave-heatable acrylic superhydrophobic coating according to claim 1 built thereon.
8. A microwave heatable bituminous pavement according to claim 7 wherein said bituminous concrete pavement is graded as AC-16.
9. A road deicing method is characterized by comprising the following steps:
paving a road with the asphalt pavement capable of being heated by the microwave; and (4) heating the ice layer by using microwave to remove ice after the ice layer is covered.
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Citations (4)

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CN112194973A (en) * 2020-09-30 2021-01-08 华北电力大学(保定) Preparation method of anti-icing super-hydrophobic coating with self-repairing performance
CN114773997A (en) * 2022-05-31 2022-07-22 东华大学 Preparation method of super-hydrophobic and oleophobic coating

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Publication number Priority date Publication date Assignee Title
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CN112194973A (en) * 2020-09-30 2021-01-08 华北电力大学(保定) Preparation method of anti-icing super-hydrophobic coating with self-repairing performance
CN112194984A (en) * 2020-10-10 2021-01-08 重庆大学 Microwave deicing road surface functional coating and manufacturing method thereof
CN114773997A (en) * 2022-05-31 2022-07-22 东华大学 Preparation method of super-hydrophobic and oleophobic coating

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