CN115678325A - Antifouling wear-resistant coating for protecting surface of inorganic artificial stone and preparation and use methods thereof - Google Patents
Antifouling wear-resistant coating for protecting surface of inorganic artificial stone and preparation and use methods thereof Download PDFInfo
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Abstract
The invention discloses an antifouling wear-resistant coating for protecting the surface of an inorganic artificial stone and a preparation method and a using method thereof, which solve the technical problems of high labor and time cost and poor wear resistance and corrosion resistance of surface protective substances due to the fact that the surface method of the artificial stone plate in the prior art mostly adopts impervious sealing agents such as fine polishing or crystal paste, glaze sealing agent and the like. It comprises 50-80% of silicate solution, 0.5-5% of silane coupling agent, 20-30% of distilled water, 0.01-0.5% of defoaming agent, 0.05-0.1% of flatting agent and 0.5-3% of water repellent. The invention has the flexibility of organic matters and the high mechanical strength of inorganic matters, thereby endowing the artificial stone slab with longer service life.
Description
Technical Field
The invention belongs to the technical field of functional coatings, relates to a preparation method of a surface protective coating of an artificial stone plate, and particularly relates to an antifouling wear-resistant coating and preparation and use methods thereof.
Background
The artificial stone board can not be polluted and corroded by various polluted liquids in daily life application environments, wherein the artificial stone board not only comprises common liquids such as soy sauce, milk, cola and red wine, but also comprises various acidic liquids which are corrosive to alkaline boards, such as table vinegar, lactic acid, citric acid and the like. At present, most of protection measures adopted on the surface of an artificial stone plate are finish polishing treatment or treatment by using anti-permeability blocking agents such as crystal paste, glaze sealing agent and the like, for example, CN112694834A discloses an anti-permeability blocking agent and a preparation method and application thereof, wherein, in parts by weight, the anti-permeability blocking agent is prepared from 60 to 70 parts by weight of methylalkoxysilane A; 10-15 parts of methylalkoxysilane B; 10-12 parts of isopropanol; 5-10 parts of methyl silicate; 3-5 parts of titanate; 1-3 parts of polydimethylsiloxane oil; 1-3 parts of silane coupling agent. Can avoid the surface of the artificial stone to directly contact with other pollution sources, improve the stain resistance and permeability of the artificial stone, improve the chemical corrosion resistance of the artificial stone and expand the application of the artificial stone.
CN113211193A discloses a cleaning method for inorganic artificial stone, comprising the following steps: A. cutting and thicknessing the inorganic artificial stone; B. roughly polishing the surface of the inorganic artificial stone by using a diamond grinding block; C. finely polishing the surface of the roughly polished inorganic artificial stone by using a silicon carbide grinding block; D. using a fiber grinding block to clean residues left on the surface of the inorganic artificial stone after the fine polishing; E. coating a cleaning agent on the surface of the cleaned inorganic artificial stone to form a nano-scale protective layer; the cleaning agent comprises 20-35 parts of nano-grade abrasive, 10-15 parts of silica sol, 5-15 parts of acetic resin, 4-10 parts of brightening powder and 7-13 parts of mixed group agent. The technology provides a cleaning method of the inorganic artificial stone, the surface of the stone is polished, and meanwhile, the surface of the inorganic artificial stone is coated by adopting a cleaning agent, so that the performance of the surface of the stone is changed, and the treated inorganic artificial stone has compact and bright surface and good waterproof and antifouling performances.
However, the prior treatment by using a fine polishing treatment or a impervious sealant such as a crystal paste and a glaze sealant has the defects of regular maintenance, high labor and time cost and the like, and the antifouling and corrosion resistant effects are not ideal. The possible reasons for the defects are that the wear resistance of impervious sealing agents such as crystal paste, glaze sealing agent and the like is not outstanding, the bonding force with the surface of the artificial stone is not strong enough, and as the application time is prolonged, partial surface substances are scratched due to the increase of the friction times and even fall off, so that the artificial stone body is exposed. The contaminated liquid is infiltrated into the contact artificial stone body through the defects, thereby causing contamination and corrosion. The partially crystallized paste and the glaze sealant may even react with acidic substances to be corroded, and the protective layer may be damaged.
Disclosure of Invention
Aiming at the defects that in the prior art, anti-permeability sealing agents such as crystal paste, glaze sealing agent and the like are mostly adopted in the surface method of the artificial stone plate, the labor and time cost is high, and the wear resistance and corrosion resistance of surface protection substances are poor, the invention provides the anti-fouling wear-resistant coating based on the artificial stone surface protection and the preparation method thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides an antifouling wear-resistant coating for protecting the surface of an inorganic artificial stone, which comprises the following materials in parts by weight: 50 to 80 percent of silicate solution, 0.5 to 5 percent of silane coupling agent, 20 to 30 percent of distilled water, 0.01 to 0.5 percent of defoaming agent, 0.05 to 0.1 percent of flatting agent and 0.5 to 3 percent of water repellent.
Further, the silicate solution comprises one or more of sodium methyl silicate, potassium methyl silicate, sodium silicate, potassium silicate, magnesium silicate and aluminum silicate.
Further, the silane coupling agent comprises one or more of KH-540, KH-550, KH-560, KH-570, KH-580 and KH-590.
Further, the defoaming agent is polyether modified organic silicon defoaming agent, the leveling agent is alkyl modified organic silicon defoaming agent, and the water repellent is fluorocarbon water repellent.
The invention provides a preparation method of an antifouling wear-resistant coating for protecting the surface of an inorganic artificial stone, which comprises the following steps:
s1: diluting the silicate solution with distilled water;
s2: sequentially adding a silane coupling agent, a defoaming agent, a water repellent and a flatting agent into the silicate solution under the mechanical stirring state, and stirring for reacting for 1-4 hours;
s3: and adding a proper amount of silane coupling agent dropwise for reaction for 1-4 h to obtain the coating.
Further, in the step S1, the silicate solution is diluted to 10 to 40% solid content with distilled water.
The invention provides a use method of an antifouling and wear-resistant coating for protecting the surface of an inorganic artificial stone, which comprises the following steps:
the method comprises the following steps: washing the inorganic artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min, and drying the washed matrix in a forced air drying box to ensure that no free water remains in pores of the matrix;
step two: spraying the prepared and synthesized coating on the surface of the inorganic artificial stone cleaned in the step one to form a hybrid film on the surface of the plate;
step three: and (5) placing the hybrid film obtained in the step two into a forced air drying oven with a set fixed temperature for high-temperature curing, and spraying a thin film to obtain the antifouling wear-resistant coating.
Further, in the third step, after the film is sprayed, the film is naturally cured for 1 hour at room temperature and then is put into an air-blowing drying oven to be heated and cured.
Further, in the third step, the temperature of the air drying oven is 50-100 ℃, and the curing time is 2-6 h.
Based on the technical scheme, the embodiment of the invention can at least produce the following technical effects:
(1) Compared with impervious sealants such as crystal paste, glaze sealant and the like, the antifouling wear-resistant coating for protecting the surface of the inorganic artificial stone, provided by the invention, has a good antifouling effect on polluted liquids such as milk, cola, coffee, methyl violet and the like, and has a more effective corrosion resistance on acidic liquids such as table vinegar and the like.
(2) The antifouling wear-resistant coating for protecting the surface of the inorganic artificial stone and the preparation and use methods thereof have the flexibility of organic matters and the high mechanical strength of inorganic matters, so that the artificial stone plate has longer service life.
Detailed Description
It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. In addition, the technical solutions in the embodiments may be combined with each other, but must be based on the realization of the technical solutions by those skilled in the art, and when the technical solutions are contradictory or cannot be realized, the technical solutions should be considered that the combination does not exist, and the technical solutions are not within the protection scope of the present invention.
Example 1 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly, diluting a sodium silicate solution to 20% of solid content by using distilled water, then dropwise adding 0.5% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent in sequence under a mechanical stirring state to react for 1 hour, and finally, additionally dropwise adding 0.5% of silane coupling agent to react for 1 hour to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, placing the organic-inorganic hybrid film obtained in the step 3 into a 50 ℃ forced air drying oven for curing for 6 hours to obtain the antifouling wear-resistant coating.
Example 2 an antifouling and abrasion resistant coating based on the protection of the surface of an artificial stone, comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 30% of solid content by using distilled water, then sequentially dropwise adding 1% of silane coupling agent, 0.05% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent under a mechanical stirring state for reacting for 2 hours, and finally, additionally dropwise adding 1% of silane coupling agent for reacting for 2 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, placing the organic-inorganic hybrid film obtained in the step 3 into a60 ℃ forced air drying oven for curing for 5 hours to obtain the antifouling wear-resistant coating.
Example 3 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 40% of solid content by using distilled water, then dropwise adding 1.5% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent in sequence under a mechanical stirring state for reacting for 3 hours, and finally, dropwise adding 1% of silane coupling agent for reacting for 3 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into a 70 ℃ forced air drying oven for curing for 4 hours to obtain the antifouling wear-resistant coating.
Example 4 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 50% of solid content by using distilled water, then sequentially dropwise adding 2% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent under a mechanical stirring state for reacting for 2 hours, and finally, additionally dropwise adding 1% of silane coupling agent for reacting for 2 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into an air drying oven at 80 ℃ for curing for 3h to obtain the antifouling wear-resistant coating.
Example 5 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly, diluting a sodium silicate solution to 30% of solid content by using distilled water, then sequentially dropwise adding 3% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent under a mechanical stirring state for reaction for 4 hours, and finally, additionally dropwise adding 1% of silane coupling agent for reaction for 4 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, curing the organic-inorganic hybrid film obtained in the step 3 in a 90 ℃ forced air drying oven for 3 hours to obtain the antifouling wear-resistant coating.
Example 6 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 30% by using distilled water, then sequentially dropwise adding 4% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent under a mechanical stirring state for reaction for 4 hours, and finally, additionally dropwise adding 1% of silane coupling agent for reaction for 4 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into a forced air drying oven at 100 ℃ for curing for 3h to obtain the antifouling wear-resistant coating.
Example 7 an antifouling and abrasion resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 30% by using distilled water, then dropwise adding 3% of silane coupling agent, 0.01% of defoaming agent, 0.05% of flatting agent and 0.5% of water repellent in sequence under a mechanical stirring state to react for 4 hours, and finally, dropwise adding 2% of silane coupling agent in a supplementary manner to react for 4 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into a forced air drying oven at 100 ℃ for curing for 6 hours to obtain the antifouling wear-resistant coating.
Comparative example 1 an antifouling wear resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: firstly diluting a sodium silicate solution to 10% by using distilled water, then sequentially dropwise adding 0.1% of silane coupling agent, 0.06% of defoaming agent, 0.2% of flatting agent and 0.1% of water repellent under a mechanical stirring state for reaction for 1h, and finally, additionally dropwise adding 1% of silane coupling agent for reaction for 1h to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, placing the organic-inorganic hybrid film obtained in the step 3 into a forced air drying oven at 40 ℃ for curing for 6 hours to obtain the antifouling wear-resistant coating.
Comparative example 2 an antifouling wear resistant coating based on the protection of an artificial stone surface comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: diluting a sodium silicate solution to 10% by using distilled water, then sequentially dropwise adding 10% of a silane coupling agent, 0.01% of a defoaming agent, 0.05% of a flatting agent and 0.5% of a water repellent under a mechanical stirring state for reacting for 2 hours, and finally, additionally dropwise adding 1% of the silane coupling agent for reacting for 2 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into a 110 ℃ forced air drying oven for curing for 3 hours to obtain the antifouling wear-resistant coating.
Comparative example 3 an antifouling and abrasion resistant coating based on the protection of the surface of an artificial stone, comprising the following steps:
step 1, synthesizing an organic-inorganic hybrid coating: diluting a sodium silicate solution to 60% by using distilled water, then sequentially dropwise adding 0.1% of silane coupling agent, 0.1% of defoaming agent, 0.01% of flatting agent and 5% of water repellent under a mechanical stirring state for reacting for 4 hours, and finally, additionally dropwise adding 10% of silane coupling agent for reacting for 4 hours to obtain the organic-inorganic hybrid coating;
step 2, washing the artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min;
step 3, spraying the organic-inorganic hybrid coating synthesized in the step 1 on the surface of the artificial stone cleaned in the step 2 to form an organic-inorganic hybrid film on the surface of the plate;
and 4, putting the organic-inorganic hybrid film obtained in the step 3 into an air drying oven at 80 ℃ for curing for 3h to obtain the antifouling wear-resistant coating.
The antifouling and wear-resistant coatings prepared in the above examples 1 to 7 have similar performance, and the coatings prepared in the following examples 1 and 3 are subjected to comprehensive tests of various performance indexes by taking only example 1, and the results are as follows:
(1) The antifouling wear-resistant coating is a colorless transparent uniform coating, has high glossiness and has no influence on the patterns and the color of the artificial stone body. The antifouling and wear-resistant coating of comparative example 2, however, was cured at a high temperature of over 100 ℃ and not only damaged the organic components in the coating network, but also discolored at a high temperature to give a whitish appearance and fine cracks.
(2) The antifouling wear-resistant coating has good antifouling performance because the components comprise organic silicon with good lyophobic performance, and the surface of the coating can achieve a good antifouling effect with the color difference value delta E less than 10 after being cleaned by using pollution liquid such as methyl violet and the like as an antifouling test. Compared with the coating prepared in comparative example 1, the color difference value before and after the pollution test is as high as 20, and the good antifouling effect is shown.
(3) The antifouling and wear-resistant coating is synthesized by an organic-inorganic hybrid technology, not only has good flexibility of a polymer, but also has high mechanical strength of an inorganic substance, so that the coating is endowed with good wear resistance, the coating keeps integral integrity after a friction test of 1000 times of friction under the load of 1kg, and the antifouling performance is not influenced. Compared with the antifouling and wear-resistant coating prepared in the comparative example 3, the coating is damaged even falls off after 500 times of friction, and the antifouling and wear-resistant coating has good anti-friction effect.
While the preferred embodiments of the present invention have been described in detail, it will be understood by those skilled in the art that the invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention and various changes and modifications may be made without departing from the spirit and scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. An antifouling wear-resistant coating for protecting the surface of an inorganic artificial stone is characterized in that the antifouling wear-resistant coating comprises the following materials in percentage by weight,
50-80% of silicate solution;
0.5 to 5 percent of silane coupling agent;
20 to 30 percent of distilled water;
0.01 to 0.5 percent of defoaming agent;
0.05 to 0.1 percent of flatting agent;
0.5 to 3 percent of water repellent.
2. The antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone as claimed in claim 1, wherein: the silicate solution comprises one or more of sodium methyl silicate, potassium methyl silicate, sodium silicate, potassium silicate, magnesium silicate and aluminum silicate.
3. The antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone as claimed in claim 1, wherein: the silane coupling agent comprises one or more of KH-540, KH-550, KH-560, KH-570, KH-580 and KH-590.
4. The antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone as claimed in claim 1, wherein: the defoaming agent is polyether modified organic silicon defoaming agent, the leveling agent is alkyl modified organic silicon defoaming agent, and the water repellent is fluorocarbon water repellent.
5. The preparation method of the antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone is characterized by comprising the following steps of:
s1: diluting the silicate solution with distilled water;
s2: sequentially adding a silane coupling agent, a defoaming agent, a water repellent and a flatting agent into the silicate solution under a mechanical stirring state, and stirring for reaction for 1-4 hours;
s3: and adding a proper amount of silane coupling agent dropwise for reaction for 1-4 h to obtain the antifouling and wear-resistant coating.
6. The preparation method of the antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone as claimed in claim 5, wherein the preparation method comprises the following steps: in step S1, the silicate solution is diluted to 10-40% solid content with distilled water.
7. The use method of the antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone is characterized by comprising the following steps:
the method comprises the following steps: washing the inorganic artificial stone matrix with distilled water and absolute ethyl alcohol respectively for three times, wherein each time is not less than 1min, and drying the washed matrix in a blast drying oven to ensure that no free water remains in pores of the matrix;
step two: spraying the prepared and synthesized coating on the surface of the inorganic artificial stone cleaned in the step one to form a hybrid film on the surface of the plate;
step three: and (3) placing the hybrid film obtained in the step two into a forced air drying oven with a set fixed temperature for high-temperature curing, and spraying a film to obtain the antifouling wear-resistant coating.
8. The use method of the antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone, according to claim 7, is characterized in that: and in the third step, after the film is sprayed, the film is naturally cured for 1 hour at room temperature and then is placed into an air-blast drying oven to be heated and cured.
9. The use method of the antifouling and wear-resistant coating for protecting the surface of the inorganic artificial stone, according to claim 7, is characterized in that: in the third step, the temperature of the air drying oven is 50-100 ℃, and the curing time is 2-6 h.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084925A (en) * | 2016-07-20 | 2016-11-09 | 中科院广州化学有限公司南雄材料生产基地 | A kind of containing high antifouling inorganic silicate coating of organosilicon and its preparation method and application |
| CN108276812A (en) * | 2018-01-22 | 2018-07-13 | 华南理工大学 | High-hard, transparent hydrophobic coating easy to clean for timber, metal and frosting |
| CN110054918A (en) * | 2019-05-09 | 2019-07-26 | 平顶山学院 | A kind of cracking resistance inorganic heat preservation coating |
| CN114605881A (en) * | 2020-12-07 | 2022-06-10 | 立邦涂料（中国）有限公司 | Coating composition for surface treatment of marked line and preparation method thereof |
-
2022
- 2022-10-13 CN CN202211254792.6A patent/CN115678325A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084925A (en) * | 2016-07-20 | 2016-11-09 | 中科院广州化学有限公司南雄材料生产基地 | A kind of containing high antifouling inorganic silicate coating of organosilicon and its preparation method and application |
| CN108276812A (en) * | 2018-01-22 | 2018-07-13 | 华南理工大学 | High-hard, transparent hydrophobic coating easy to clean for timber, metal and frosting |
| CN110054918A (en) * | 2019-05-09 | 2019-07-26 | 平顶山学院 | A kind of cracking resistance inorganic heat preservation coating |
| CN114605881A (en) * | 2020-12-07 | 2022-06-10 | 立邦涂料（中国）有限公司 | Coating composition for surface treatment of marked line and preparation method thereof |
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