CN115670227A - Non-stick pan and manufacturing method thereof - Google Patents

Abstract

Disclosed are a non-stick pan and a method of manufacturing the same, the non-stick pan comprising: a pot body including an inner surface and an outer surface opposite to the inner surface, and having a groove recessed from the inner surface toward the outer surface to form a structure including a plurality of grooves and a plurality of protrusions on the inner surface; and a titanium alloy layer formed on the plurality of grooves and the plurality of protrusions, wherein the titanium alloy layer includes an amorphous structure. The non-stick cookware according to the present disclosure has improved non-stick properties.

Description

Non-stick pan and manufacturing method thereof

Technical Field

The application relates to a non-stick pan and a manufacturing method thereof.

Background

The non-stick pan is popular with people at present, the appearance of the non-stick pan brings great convenience to the life of people, and people do not worry about the problem of cooking, cooking and burning the pan.

In the existing tableware, a frying pan and the like are generally provided with toxic Teflon coatings or slightly toxic ceramic coatings in order to obtain a non-stick effect, and the coatings can fall off after being used for a long time and finally harm human bodies. Titanium alloys have many excellent physical properties such as high toughness, high strength, high yield strength, high fatigue strength, high melting point, low coefficient of expansion, good chemical stability, corrosion resistance, good processability, etc., and are therefore a very good choice for cookware and tableware.

How to combine the titanium alloy with the inner surface of the pan body to improve the non-stick property of the pan body is a technical problem which is continuously addressed by the technical personnel in the field.

Disclosure of Invention

In view of the above problems, the present application provides an improvement to a non-stick pan, and provides a non-stick pan that can improve non-stick property of an inner surface of a pan body.

In accordance with a disclosed embodiment, a non-stick pan comprises: a pot body including an inner surface and an outer surface opposite to the inner surface, and having a plurality of grooves recessed from the inner surface toward the outer surface to form a structure including a plurality of grooves and a plurality of protrusions on the inner surface; and a titanium alloy layer formed on the plurality of grooves and the plurality of protrusions, wherein the titanium alloy layer includes an amorphous structure. Therefore, the macroscopic grooves and protrusions (i.e., the concave-convex structure) can form a macroscopic and microscopic double-layer concave-convex structure with the microscopic concave-convex structure of the titanium alloy layer itself including the amorphous structure, thereby achieving good adhesion resistance in cooperation with an oil film.

According to disclosed embodiments, the thickness of the titanium alloy layer may be in the range of 0.01mm-0.13 mm. When the thickness of the titanium alloy layer is within the range, the non-stick pan has excellent anti-sticking performance and does not influence the heat conduction of the pan body.

According to disclosed embodiments, the pot body may include a bottom and a sidewall extending from the bottom, wherein a thickness of the titanium alloy layer formed on the bottom may be greater than a thickness of the titanium alloy layer formed on the sidewall. The thickness of the titanium alloy layer at the bottom of the non-stick pan is relatively large, so that the non-stick effect of the non-stick pan bottom, in which oil and food are mainly concentrated, can be ensured, and meanwhile, the titanium alloy layer on the side wall is relatively thin, so that the cost can be reduced.

According to the disclosed embodiments, the titanium alloy layer may include a titanium alloy having an amorphous structure. Therefore, the titanium alloy layer can have a microscopic concave-convex structure, so that an anti-adhesion effect is achieved by matching an oil film.

According to the disclosed embodiments, a depth of the recess of each groove from the inner surface toward the outer surface may be in a range of 0.07mm to 0.15mm, a distance between centers of the grooves adjacent to each other among the plurality of grooves may be in a range of 1.0mm to 5.0mm, a width of each groove in a direction perpendicular to a direction in which each groove is recessed may be in a range of 0.5mm to 3.0mm, and a coverage of the plurality of grooves in an area of the pan body having a radius of 10mm may be in a range of 15% to 30%. When the depth of the groove, the distance between the centers of the adjacent grooves, the width of the groove and the coverage rate of the groove meet the above conditions, the macroscopic concave-convex structure has a good oil storage function, namely, a stable oil film can be formed, the anti-sticking property of the non-stick pot can be improved, and meanwhile, the subsequent pot is easy to clean.

According to the disclosed embodiments, the depth of the recess of each groove from the inner surface toward the outer surface may be 0.09mm to 0.11mm, the distance between the centers of the grooves adjacent to each other among the plurality of grooves may be 1.5mm to 4.0mm, the width of each groove in a direction perpendicular to a direction in which each groove is recessed may be 1.0mm to 1.5mm, and the coverage of the plurality of grooves in an area of the pan body having a radius of 10mm may be 20% to 25%. When the depth of the grooves, the distance between the centers of adjacent grooves, the width of the grooves and the coverage of the grooves are preferably the above values, the adhesion resistance is optimal and the subsequent cleaning of the pot is easy.

According to the disclosed embodiment, among the plurality of grooves, six grooves adjacent to one groove are arranged in a hexagonal shape centering on the one groove. The grooves distributed in a hexagonal shape can enable the oil film to be uniform, so that the non-adhesion of the cookware is improved.

According to disclosed embodiments, each groove may have a circular shape in plan view. When the groove has a circular shape, the continuity of the oil film can be improved, thereby improving the anti-sticking property of the pot.

According to the disclosed embodiments, the pot body may include an outer layer, an inner layer, and a middle layer disposed between the outer layer and the inner layer, the plurality of grooves and the plurality of protrusions are formed in the inner layer, and the titanium alloy layer contacts the inner layer. Therefore, a double-layer concave-convex structure in which the microscopic concave-convex of the titanium alloy layer is combined with the macroscopic concave-convex including the grooves and the protrusions can be formed, thereby improving the adhesion resistance of the cookware.

According to a disclosed embodiment, a method of manufacturing a non-stick pan comprises the steps of: preparing a pot body, wherein the pot body comprises an inner surface and an outer surface opposite to the inner surface, and the pot body is provided with a plurality of grooves recessed from the inner surface to the outer surface so as to form a structure comprising a plurality of grooves and a plurality of bulges on the inner surface; and spraying a titanium alloy on the inner surface of the pot body by using a spray gun so as to form a titanium alloy layer on the plurality of grooves and the plurality of bulges. The titanium alloy layer is formed on the inner surface with the grooves and the protrusions, so that a double-layer concave-convex structure combining the microscopic concave-convex of the titanium alloy layer and the macroscopic concave-convex comprising the grooves and the protrusions can be realized, and the anti-sticking performance of the cooker is improved.

The macroscopic concave-convex structure (namely, the dot etching structure) of the protrusions and the grooves formed on the inner surface of the pot body according to the disclosed embodiment can be combined with the microscopic concave-convex structure of the titanium alloy layer with the amorphous structure to form a macroscopic and microscopic double-layer concave-convex structure, so that the non-adhesiveness of the pot body is improved.

Drawings

The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention without limiting the invention. In the drawings:

FIGS. 1 and 2 are each a partial cross-sectional view of a pan body according to the disclosed embodiments;

FIG. 3 is a top view of a pan body showing a groove distribution in accordance with the disclosed embodiments; and

FIG. 4 is a diagram illustrating a method of calculating groove coverage, according to a disclosed embodiment.

Detailed Description

The inventive concept will now be described more fully hereinafter with reference to the accompanying examples, which, however, may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.

The present disclosure provides a non-stick pan having a concavo-convex structure of protrusions and grooves on the inner surface of a pan body, the macro concavo-convex structure is combined with the micro concavo-convex structure of a titanium alloy layer (e.g., a titanium alloy cladding layer) itself coated thereon to form a macro and micro double-layer concavo-convex structure, so that the anti-sticking property of the pan is improved.

The non-stick pan will be described in detail below in connection with exemplary embodiments.

Fig. 1 and 2 are each a partial cross-sectional view of a pan body according to the disclosed embodiments.

Referring to fig. 1 and 2, a non-stick pan according to the disclosed embodiments includes a pan body that may include an outer layer 1, an inner layer 3, and a middle layer 2 disposed between the outer layer 1 and the inner layer 3, the inner layer 3 of the pan body forming an inner surface for carrying items, the outer layer 1 of the pan body forming an outer surface opposite the inner surface. Wherein the outer layer 1 may comprise 430 stainless steel, the middle layer 2 may comprise an aluminum alloy, and the inner layer 3 may comprise 304 stainless steel for food contact. The titanium alloy layer 4 is formed on the inner surface formed by the inner layer 3.

FIG. 3 is a top view of a pan body showing a groove distribution according to the disclosed embodiments.

Referring to fig. 3 and fig. 1 and 2, the pot body may have a plurality of grooves 5 recessed from the inner surface toward the outer surface to form a structure including a plurality of grooves 5 and a plurality of protrusions 6 on the inner surface, wherein the titanium alloy layer 4 is formed on the plurality of grooves 5 and the plurality of protrusions 6.

In embodiments, the thickness of the titanium alloy layer may be 0.01mm to 0.13mm, for example, 0.02mm to 0.12mm, 0.03mm to 0.11mm, 0.04mm to 0.10mm, 0.05mm to 0.09mm, or 0.06mm to 0.08mm. When the titanium alloy layer is excessively thick, for example, more than 0.13mm, the heat conductive property is lowered and the cost is increased. When the titanium alloy layer is too thin, for example, less than 0.01mm, the blocking resistance is greatly reduced. Therefore, when the thickness of the titanium alloy layer is 0.01mm-0.13mm, good anti-sticking performance can be ensured, and the heat conduction of the pot body is not influenced.

In an embodiment, the pot body includes a bottom and a sidewall extending from the bottom, and a thickness of the titanium alloy layer formed on the bottom may be greater than a thickness of the titanium alloy layer formed on the sidewall. Specifically, the thickness of the titanium alloy layer formed on the bottom may be in the range of 0.04mm to 0.12mm, for example, may be in the range of 0.05mm to 0.11mm, 0.06mm to 0.10mm, or 0.07mm to 0.09 mm. The thickness of the titanium alloy layer formed on the side wall may be in the range of 0.03mm to 0.08mm, for example, may be in the range of 0.04mm to 0.07mm or 0.05 to 0.06 mm. In this case, the thickness of the titanium alloy layer on the non-stick pan bottom is formed to be relatively large in the thickness range satisfying 0.01mm to 0.13mm, so that the non-stick effect of the non-stick pan bottom in which oil and food are mainly concentrated can be secured, while the titanium alloy layer on the side wall is formed to be relatively thin, so that the cost can be reduced.

In an embodiment, the titanium alloy layer may have an amorphous structure, and the titanium alloy layer having the amorphous structure itself has a microscopic concave-convex structure, and can be matched with an oil film to achieve an anti-sticking effect. Specifically, the titanium alloy layer may include a titanium alloy having an amorphous structure. Titanium alloys have high toughness, high strength, high yield strength, high fatigue strength, high melting point, low expansion coefficient, good chemical stability, corrosion resistance, good workability, and the like, and titanium does not contain heavy metals, and therefore, it is preferable to form a titanium alloy layer using a titanium alloy.

In an embodiment, the recess may be recessed from the inner surface towards the outer surface to a depth of 0.07mm to 0.15mm, for example 0.08mm to 0.12mm, preferably 0.09mm to 0.11mm, more preferably 0.10mm. When the depth of the groove is too deep, for example, more than 0.15mm, the groove is easy to store dirt and is not beneficial to cleaning the subsequent pot. When the depth of the groove is too shallow, for example, less than 0.07mm, the oil storage property is not good, resulting in deterioration of the anti-sticking effect. When the depth of the groove is within the range of 0.07mm-0.15mm, the oil storage performance is good, the subsequent cleaning of the cooker is easy, and when the depth of the groove is within the range of 0.09mm-0.11mm, the oil storage performance is best, and the anti-sticking performance is best.

In an embodiment, the distance between the centers of the grooves adjacent to each other among the grooves may be 1.0mm to 5.0mm, for example, 1.0mm to 4.5mm, 1.0mm to 4.0mm, preferably 1.5mm to 4.0mm, and more preferably 2.4mm. When the distance between the centers of the grooves adjacent to each other is excessively large, for example, more than 5.0mm, the formed oil film is easily broken to be discontinuous, resulting in deterioration of the blocking resistance. When the distance between the centers of the adjacent grooves is too small, for example, less than 1.0mm, the grooves are distributed too densely, which results in the waste of edible oil and is easy to store dirty and dirty, which is not beneficial to the cleaning of the subsequent pot. When the distance between the grooves adjacent to each other is in the range of 1.0mm to 5.0mm, a continuous and uniform oil film can be formed, the sticking resistance of the pot can be improved, and the subsequent washing of the pot is facilitated, and the sticking resistance is optimal when the distance between the grooves adjacent to each other is in the range of 1.5mm to 4.0mm (e.g., 2.4 mm).

In the embodiment, the width of the groove in the direction perpendicular to the direction in which the groove is recessed is in the range of 0.5mm to 3.0mm, specifically, when the groove is formed into a circular shape (for example, by dot etching) in a plan view parallel to the direction perpendicular to the direction in which the groove is recessed, the diameter of the groove is 0.5mm to 3.0mm, for example, 0.5mm to 2.5mm, 0.5mm to 2.0mm,0.5mm to 1.5mm, preferably 1.0mm to 1.5mm, and more preferably 1.2mm. When the width of the groove is too large, for example, more than 3.0mm, the oil storage is too much, which results in the waste of the edible oil. When the width of the groove is too small, for example, less than 0.5mm, the oil-storing property is lowered, the adhesion resistance is deteriorated, and the subsequent spraying of the titanium alloy layer is not facilitated. When the width of the groove is in the range of 0.5mm-3.0mm, the oil storage effect is good, the anti-adhesion property is good, the subsequent spraying of the titanium alloy layer is facilitated, and when the width of the groove is in the range of 1.0mm-1.5mm (for example, 1.2 mm), the anti-adhesion property is best.

In an embodiment, six grooves adjacent to one groove are hexagonally arranged with the one groove as a center, for example, six grooves may be located at six vertices of the hexagon, respectively, and one groove is located at the center of the hexagon. When the grooves are distributed in a hexagonal shape, the oil film can be uniform, and a relatively stable and continuous oil film is formed, so that the anti-sticking property of the cookware can be improved.

FIG. 4 is a diagram illustrating a method of calculating groove coverage, according to a disclosed embodiment.

Referring to FIG. 4, a circle of radius 10mm is randomly selected, for example, 314.159mm in area ² The area of the round excluding the groove is 245.081mm ² The groove coverage can be calculated according to the following formula: groove coverage (%) = (area of circle-area of circle excluding groove)/area of circle, and the coverage of groove is about 22% by calculation. When the coverage of the groove is 15% -30%, a uniform and continuous oil film can be formed, so that the sticking resistance of the pot can be improved, and when the coverage of the groove is in the range of 20% -25% (e.g., 22%), the sticking resistance is optimal and the subsequent washing of the pot is easy.

Therefore, the macro concave-convex structure (i.e., the dot etching structure) having the protrusions and the grooves formed on the inner surface of the pot body according to the embodiment may be combined with the micro concave-convex structure of the titanium alloy layer (e.g., the titanium alloy cladding layer) itself having the amorphous structure to form the macro and micro double-layer concave-convex structure, so that the non-stick property of the pot body is improved.

The non-stick pan is described in detail above with reference to the embodiments. Hereinafter, a method of manufacturing the non-stick pan will be described in detail with reference to examples.

The manufacturing method of the non-stick pan according to the disclosed embodiment may be implemented by the following steps: (1) Preparing a pot body which can comprise a 304 stainless steel inner layer for food contact, an aluminum alloy middle layer and a 430 stainless steel outer layer; (2) Performing dot etching on the inner surface of the pot body to form a groove which is recessed from the inner surface towards the outer surface so as to form a concave-convex structure comprising a protrusion and a groove on the inner surface; (3) And spraying titanium alloy on the inner surface of the pot body by using a spray gun so as to form a titanium alloy layer on the grooves and the protrusions.

According to an embodiment, in the step (2), the inner surface of the pot body may be wet-etched using a chemical solution to form a concave-convex structure including grooves and protrusions on the inner surface. The depth of the recess from the inner surface toward the outer surface may be in the range of 0.07mm to 0.15mm, preferably 0.09mm to 0.11mm, the width of the recess in the direction perpendicular to the direction in which the recess is recessed is in the range of 0.5mm to 3.0mm, specifically, when the recess is formed into a circular shape by dot etching, the diameter of the recess may be in the range of 0.5mm to 3.0mm, preferably 1.0mm to 1.5mm (e.g., 1.2 mm), the distance between the centers of the recesses adjacent to each other may be in the range of 1.0mm to 5.0mm, preferably 1.5mm to 4.0mm (e.g., 2.4 mm), and six recesses adjacent to one recess are hexagonally arranged centering on one recess. However, the present disclosure is not limited thereto, and other etching methods such as dry etching by physical etching may be employed as long as grooves having the size and distribution required by the present disclosure can be obtained or, alternatively, a pot body meeting the requirements may be directly purchased.

After step (2) is completed, a sand blasting process may also be performed: the inner surface of the pot body is sandblasted so that the roughness of the inner surface of the pot body is increased, for example, to a roughness of 2 μm to 4 μm. When the roughness of the inner surface of the pot body is smaller, the adhesion force between the titanium alloy and the surface of the pot body is lower, the titanium alloy is easy to fall off, and after the inner surface of the pot body is subjected to sand blasting treatment, the adhesion force and the combination degree between the titanium alloy and the inner surface of the pot body can be improved.

In the step (3), after the titanium alloy is heated and melted, titanium alloy powder is filled into a designated container and is conveyed into a spray gun through an automatic device, a material spraying outlet of a plasma spray gun moves towards the edge of the pot body by taking the center of the inner surface of the pot body as a base point and the central axis of the inner surface of the pot body as a base line, the pot body rotates around the central axis, and a plasma layer is formed by hot spraying raw materials of a titanium alloy composition on the inner surface of the pot body. Wherein, after the plasma spraying is finished, the thickness of the titanium alloy layer at the bottom of the inner surface of the pot body is in the range of 0.04mm-0.12mm, and the thickness of the titanium alloy layer at the wall part is in the range of 0.03mm-0.08 mm. The titanium alloy layers with different thicknesses can be obtained by regulating and controlling different process parameters.

The foregoing describes a non-stick pan and method of making the same according to the disclosed embodiments. Hereinafter, the disclosed advantageous effects will be described in detail with reference to specific embodiments.

Example 1

Preparing a pot body, wherein the pot body sequentially comprises a 304 stainless steel inner layer, an aluminum alloy middle layer and a 430 stainless steel outer layer from top to bottom for food contact.

Dot etching is performed on the inner surface of the pot body using a chemical etchant (for example, mainly ferric trichloride) to form a groove having a circular shape to form a concavo-convex structure having a groove and a protrusion on the inner surface of the pot body, wherein the depth of the groove is 0.10mm, the diameter of the groove is 1.2mm, and the distance between the centers of the grooves adjacent to each other is 2.4mm, and six grooves adjacent to one groove are hexagonally arranged centering on one groove.

Thereafter, the inner surface of the pot body (specifically, the grooves and protrusions) was subjected to sand blasting so that the roughness of the inner surface of the pot body was 3 μm.

Then, titanium alloy powder is filled into a designated container and is conveyed into a spray gun through automatic equipment, a material spraying outlet of a plasma spray gun takes the center of the inner surface of the pot body as a base point and takes the central axis of the inner surface of the pot body as a base line and moves towards the edge of the pot body, the pot body rotates around the central axis of the pot body, and a plasma layer is formed by covering the inner surface of the pot body with the titanium alloy powder through thermal spraying.

After the plasma spraying is finished, the thickness of the titanium alloy layer at the bottom of the inner surface of the pot body is 0.08mm, and the thickness of the titanium alloy layer at the side wall is 0.05mm.

Example 2

The pot according to example 2 was manufactured in the same manner as example 1, except that the depth of the groove was 0.09 mm.

Example 3

The pot according to example 3 was manufactured in the same manner as example 1, except that the depth of the groove was 0.11 mm.

Example 4

The pot according to embodiment 4 was manufactured in the same method as embodiment 1 except that the distance between the centers of the grooves adjacent to each other was 1.0 mm.

Example 5

The pot according to embodiment 5 was manufactured in the same method as embodiment 1, except that the distance between the centers of the grooves adjacent to each other was 5.0 mm.

Comparative example 1

A pot according to comparative example 1 was manufactured in the same manner as the method of example 1, except that the depth of the groove was 0.05mm.

Comparative example 2

A pot according to comparative example 2 was manufactured in the same manner as the method of example 1, except that the depth of the groove was 0.20 mm.

Comparative example 3

A pot according to comparative example 3 was manufactured in the same manner as in example 1, except that the diameter of the groove was 0.3 mm.

Comparative example 4

A pot according to comparative example 4 was manufactured in the same manner as in example 1, except that the diameter of the groove was 3.5 mm.

Comparative example 5

A pot according to comparative example 5 was manufactured in the same manner as the method of example 1, except that the distance between the centers of the grooves adjacent to each other was 0.5 mm.

Comparative example 6

A pot according to comparative example 6 was manufactured in the same manner as the method of example 1, except that the distance between the centers of the grooves adjacent to each other was 5.5 mm.

Comparative example 7

A pot according to comparative example 7 was manufactured in the same manner as example 1, except that the grooves having a diameter of 1.2mm and a depth of 0.10mm in example 1 were randomly etched.

The pot manufactured by the above reference examples 1 to 5 and comparative examples 1 to 7 was subjected to a performance test according to the non-stick test of fried egg of the national standard GB/T32095.2-20154.2.1, specifically, a) a proper amount of vegetable oil was poured into the pot, and a non-stick surface was wiped with a soft cloth until the coating was uniform; b) Washing with warm water at 60 deg.C or higher and neutral detergent, cleaning with clear water, and wiping; c) Placing the pan body on an electric furnace with the rated voltage of 220V and the output power of 1kW for heating, measuring by using a surface thermometer with the accuracy of not less than 2.5 grade, when the surface temperature of an inner coating reaches 150-170 ℃, placing a fresh egg which meets the SB/T10277-1997 regulation 2 grade (the weight is 50g-60 g) into the pan body after breaking the shell, and waiting for the protein to be basically solidified (the surface temperature of the inner coating does not exceed 210 ℃ in the whole cooking process); d) Taking out the eggs completely by using a plastic shovel with the edge thickness of 0.2mm-0.5 mm. If the egg residues are attached, lightly wiping off the residues by using a wet sponge or gauze; e) Repeating the steps c) and d) for 3 times, and observing. The pots of examples 1 to 5 and comparative examples 1 to 7 were evaluated according to the evaluation of the non-stickiness test results of the fried eggs in the following Table 1. The evaluation results are shown in table 2.

TABLE 1

TABLE 2

Serial number	Non-tackiness
		Example 1	Class I
Example 2	Class I
		Example 3	Class I
Example 4	Class I
		Example 5	Class I
Comparative example 1	Class II
		Comparative example 2	Class II
Comparative example 3	Class II
		Comparative example 4	Class II
Comparative example 5	Class II
		Comparative example 6	Class II
Comparative example 7	Class II

As can be seen from Table 2, the non-stickiness test results of the pan-fried eggs manufactured according to examples 1-5 were all class I, while the non-stickiness test results of the pan-fried eggs manufactured according to comparative examples 1-7 were all class II.

According to the non-stick pan disclosed by the embodiment of the disclosure, the concave and convex macroscopic concave-convex structures are formed on the inner surface of the pan body, and the titanium alloy layer is formed on the macroscopic concave-convex structures on the inner surface of the pan body by using the plasma spraying process. Because the microscopic concave-convex structure of the titanium alloy and the macroscopic concave-convex structure of the inner surface of the pot body form a double-layer concave-convex structure. Therefore, the oil storage performance of the pan body can be improved, thereby improving the anti-sticking property of the inner surface of the pan body. Meanwhile, the sticking resistance of the inner surface of the pot body can be further improved by adjusting the depth of the grooves on the inner surface of the pot body, the distance between the centers of the adjacent grooves, the width (such as the diameter) of the grooves in the direction vertical to the direction along which the grooves are recessed, the coverage rate and the distribution form of the grooves and the like.

Although the present invention has been described with reference to the above embodiments, it will be understood by those skilled in the art or persons having general knowledge in the art that various modifications and changes may be made to the present invention without departing from the spirit and technical field of the present invention described in the claims. Therefore, the technical scope of the invention should not be limited to what is described in the detailed description of the specification, and the claimed invention should be defined by the claims.

Claims (10)

1. A non-stick pan, characterized in that the non-stick pan comprises:

a pan body including an inner surface and an outer surface opposite to the inner surface, and having a plurality of grooves recessed from the inner surface toward the outer surface to form a structure including the plurality of grooves and a plurality of protrusions on the inner surface; and

a titanium alloy layer formed on the plurality of grooves and the plurality of protrusions,

wherein the titanium alloy layer comprises an amorphous structure.

2. The non-stick pan of claim 1, wherein the titanium alloy layer has a thickness in the range of 0.01mm to 0.13 mm.

3. The non-stick pan of claim 2 wherein the pan body includes a bottom and side walls extending from the bottom,

wherein a thickness of the titanium alloy layer formed on the bottom is greater than a thickness of the titanium alloy layer formed on the sidewalls.

4. The non-stick pan of claim 1, wherein the titanium alloy layer comprises a titanium alloy having an amorphous structure.

5. The non-stick pan of claim 1, wherein each groove is recessed from the inner surface toward the outer surface to a depth in the range of 0.07mm to 0.15mm,

a distance between centers of the grooves adjacent to each other among the plurality of grooves is in a range of 1.0mm to 5.0mm,

the width of each groove in a direction perpendicular to a direction in which each groove is recessed is in a range of 0.5mm to 3.0mm, and

the coverage rate of the grooves in the area with the radius of 10mm of the pot body is in the range of 15% -30%.

6. The non-stick pan of claim 5, wherein each groove is recessed from the inner surface toward the outer surface to a depth of 0.09mm to 0.11mm,

the distance between the centers of the grooves adjacent to each other among the plurality of grooves is 1.5mm to 4.0mm,

each groove has a width in a direction perpendicular to a direction in which each groove is recessed of 1.0mm to 1.5mm, and

the coverage rate of the grooves in the area with the radius of 10mm of the pot body is 20% -25%.

7. The non-stick pan of claim 1 wherein six of the plurality of grooves adjacent to one groove are hexagonally arranged centered on the one groove.

8. The non-stick pan of claim 1, wherein each groove has a circular shape in plan view.

9. The non-stick pan of claim 1 wherein the pan body comprises an outer layer, an inner layer, and a middle layer disposed between the outer layer and the inner layer,

the plurality of grooves and the plurality of projections are formed in the inner layer, and

the titanium alloy layer contacts the inner layer.

10. A method of manufacturing a non-stick pan, the method comprising the steps of:

preparing a pot body which includes an inner surface and an outer surface opposite to the inner surface, and which has a plurality of grooves recessed from the inner surface toward the outer surface to form a structure including the plurality of grooves and a plurality of protrusions on the inner surface; and

and spraying titanium alloy on the inner surface of the pot body by using a spray gun to form a titanium alloy layer on the grooves and the bulges.

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