CN115651621A - High-permeability thickened oil blocking remover, preparation method thereof and blocking removal construction method - Google Patents

High-permeability thickened oil blocking remover, preparation method thereof and blocking removal construction method Download PDF

Info

Publication number
CN115651621A
CN115651621A CN202211473699.4A CN202211473699A CN115651621A CN 115651621 A CN115651621 A CN 115651621A CN 202211473699 A CN202211473699 A CN 202211473699A CN 115651621 A CN115651621 A CN 115651621A
Authority
CN
China
Prior art keywords
permeability
mixed material
amino acid
acid type
type surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202211473699.4A
Other languages
Chinese (zh)
Other versions
CN115651621B (en
Inventor
窦军
杨豫新
丛日凯
邵洋洋
张岩
王竹青
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KARAMAY XINKEAO PETROLEUM TECHNOLOGICAL CO Ltd
Original Assignee
KARAMAY XINKEAO PETROLEUM TECHNOLOGICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KARAMAY XINKEAO PETROLEUM TECHNOLOGICAL CO Ltd filed Critical KARAMAY XINKEAO PETROLEUM TECHNOLOGICAL CO Ltd
Priority to CN202211473699.4A priority Critical patent/CN115651621B/en
Publication of CN115651621A publication Critical patent/CN115651621A/en
Application granted granted Critical
Publication of CN115651621B publication Critical patent/CN115651621B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention relates to the technical field of thickened oil blocking remover, in particular to a high-permeability thickened oil blocking remover, a preparation method and a blocking removal construction method thereof, wherein the high-permeability thickened oil blocking remover comprises kerosene, an amide solvent, a penetrating agent and an amino acid type surfactant as raw materials, and is obtained by the following steps: and (2) uniformly mixing the penetrating agent and the amino acid type surfactant to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the mixed material II is completely dissolved to obtain the oil-in-water emulsion. The high-permeability heavy oil blocking remover disclosed by the invention is matched with a high-pressure low-displacement pump injection blocking removal construction method, so that the viscosity of crude oil can be well reduced, the blocking of a heavy oil well is effectively solved, an oil sleeve annular circulation channel is established, and the high-permeability heavy oil blocking remover has the characteristics of good permeability, high viscosity reduction performance and high safety performance. Meanwhile, the demulsifier has good compatibility with the field demulsifier, and does not influence the dehydration of crude oil.

Description

High-permeability thickened oil blocking remover, preparation method thereof and blocking removal construction method
Technical Field
The invention relates to the technical field of thickened oil blocking removers, in particular to a high-permeability thickened oil blocking remover, a preparation method and a blocking removal construction method thereof.
Background
The thickened oil steam huff-and-puff well is influenced by the properties of thickened oil products in the process of exploitation and the temperature and the pressure in the process of exploitation, when the temperature and the pressure are reduced, the thickened oil loses fluidity, so that an oil sleeve annulus is blocked by the thickened oil, the blockage is difficult to be removed by adopting conventional measures, the oil well can not be normally produced, the cost is increased for solving the problem by subsequent blockage removal, and the safety risk is improved.
The thickened oil steam huff and puff well has the problems of annular blockage of an oil sleeve and no circulation channel of an oil well due to the fact that the temperature is reduced and the fluidity of crude oil is reduced, and brings great difficulty to production and maintenance of the oil well. At present, aiming at the problems, the main methods for thick oil blockage removal construction comprise: 1) Steam is injected at high pressure for heating, the viscosity of crude oil is reduced, and the crude oil is discharged outside and then injected and discharged again; 2) The viscosity reducer is injected into the high-pressure pump truck for viscosity reduction and blockage removal or the paraffin removal and blockage removal agent is used for blockage removal, the process conditions are limited, when the agent is injected after the pump truck starts the pump, because the discharge capacity is large, the pressure rises instantly and exceeds the pressure of wellhead equipment, potential safety hazards can be caused, the agent cannot be injected or the injected agent cannot be fully mixed with the thickened oil for reaction, and the purpose of blockage removal cannot be achieved.
Disclosure of Invention
The invention provides a high-permeability thickened oil blocking remover, a preparation method thereof and a blocking removal construction method, overcomes the defects of the prior art, and can effectively solve the problems that the existing thickened oil blocking remover is poor in blocking removal performance, cannot reduce the viscosity of crude oil and cannot establish an annular space channel of an oil jacket.
One of the technical schemes of the invention is realized by the following measures: the high-permeability heavy oil blocking remover comprises 35-40% of kerosene, 35-40% of amide solvent, 5-10% of penetrating agent and the balance of amino acid type surfactant.
The following is a further optimization or/and improvement of one of the above-mentioned technical solutions of the invention:
the amide solvent is N, N-dimethylacetamide.
The penetrating agent is oil-soluble azone.
The amino acid type surfactant is one of an N-alkyl amino acid type surfactant and an N-acyl amino acid type surfactant.
The high-permeability thickened oil blocking remover is obtained by the following steps: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
The second technical scheme of the invention is realized by the following measures: a preparation method of a high-permeability thickened oil blocking remover comprises the following steps: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
The third technical scheme of the invention is realized by the following measures: a blockage removal construction method of a high-permeability thickened oil blockage removal agent comprises the following steps:
firstly, verifying the rated pressure of the Christmas tree;
then injecting a high-permeability thickened oil blocking remover into a wellhead, and controlling the pump injection construction pressure to be 0MPa to 10MPa and the pump discharge capacity to be 0.83kg/min to 10kg/min;
and finally, observing the change of the pump injection construction pressure and the pump discharge capacity, and gradually increasing the pump discharge capacity for construction when the pump injection construction pressure is reduced in the process of injecting the high-permeability thickened oil blocking remover by the pump until the pump injection construction pressure is stable and unchanged, so that the blocking removal is successful.
The invention has the beneficial effects that:
the raw material amide solvent is N, N-dimethylacetamide, and the solvent and kerosene are mixed to achieve a good thickened oil dilution effect; the raw material penetrant of the invention adopts oil-soluble azone, which can improve the permeability of the medicament in thick oil, accelerate the reaction time of the medicament and play the role of an active agent; the raw material amino acid type surfactant adopts N-alkyl amino acid type surfactant or N-acyl amino acid type surfactant, so that the viscosity reduction effect can be achieved; the invention has the advantages of easily obtained raw materials and good compatibility among the components.
The high-permeability thick oil blocking remover disclosed by the invention belongs to an oil-soluble viscosity reducer, can well reduce the viscosity of thick oil by reacting with the thick oil, and has the characteristics of good permeability and high viscosity reduction performance. In the subsequent well flushing process, because the high-permeability thick oil blocking remover has good compatibility with thick oil of an oil well, and the blocking removal construction method, also called a high-pressure low-displacement pump injection blocking removal construction method, is matched, in the blocking removal construction process, a small-discharge high-pressure pump or (a pump truck) is adopted to slowly inject the high-permeability thick oil blocking remover through pressure control, and the high-permeability thick oil blocking remover permeates into thick oil under the condition of injection of the high-pressure pump, so that the contact area of a medicament is increased, the viscosity of crude oil is reduced, and the problems of annular blocking of an oil sleeve and no circulation channel can be quickly solved.
In a word, the high-permeability thick oil blocking remover is matched with a high-pressure low-displacement pump injection blocking removal construction method, so that the viscosity of crude oil can be well reduced, the blocking of a thick oil well is effectively solved, an oil sleeve annular circulation channel is established, and the high-permeability thick oil blocking remover has the characteristics of good permeability, high viscosity reduction performance and high safety performance. Meanwhile, the demulsifier has good compatibility with the field demulsifier, and does not influence the dehydration of crude oil.
Detailed Description
The present invention is not limited by the following examples, and specific embodiments may be determined according to the technical solutions and practical situations of the present invention. The various chemical reagents and chemical articles mentioned in the invention are all the chemical reagents and chemical articles which are well known and commonly used in the prior art, unless otherwise specified; the percentages in the present invention are all mass percentages unless otherwise specified.
The invention is further described below with reference to the following examples:
example 1: the high-permeability thickened oil blocking remover comprises 35-40% of kerosene, 35-40% of amide solvent, 5-10% of penetrating agent and the balance of amino acid type surfactant.
Example 2: the high-permeability thickened oil blocking remover comprises 35% or 40% of kerosene, 35% or 40% of amide solvent, 5% or 10% of penetrating agent and the balance of amino acid type surfactant.
Example 3: as optimization of the above embodiment, the amide solvent is N, N-dimethylacetamide.
Example 4: as an optimization of the above embodiment, the penetrant is oil-soluble azone.
Example 5: as optimization of the above embodiment, the amino acid type surfactant is one of an N-alkyl amino acid type surfactant and an N-acyl amino acid type surfactant.
Example 6: as the optimization of the embodiment, the high-permeability thickened oil blocking remover is obtained by the following steps: uniformly mixing a required amount of penetrating agent and amino acid type surfactant, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing a required amount of kerosene and amide solvent to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the mixed material II is completely dissolved to obtain the high-permeability thick oil blocking remover.
Example 7: the high-permeability thickened oil blocking remover comprises 40% of kerosene, 35% of N, N-dimethylacetamide, 10% of oil-soluble azone and 15% of N-alkyl amino acid type surfactant according to weight percentage, and is obtained by the following steps: uniformly mixing oil-soluble azone and N-alkyl amino acid type surfactant with required amount, stirring until the oil-soluble azone and the N-alkyl amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing kerosene and N, N-dimethylacetamide with required amount to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the N, N-dimethylacetamide are completely dissolved to obtain the high-permeability thick oil blocking remover.
Example 8: the high-permeability thickened oil blocking remover comprises 40% of kerosene, 35% of N, N-dimethylacetamide, 10% of oil-soluble azone and 15% of N-acyl amino acid type surfactant according to weight percentage, and is obtained by the following steps: uniformly mixing oil-soluble azone and N-acyl amino acid type surfactant in required amount, stirring until the oil-soluble azone and the N-acyl amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing kerosene and N, N-dimethylacetamide in required amount to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the N, N-dimethylacetamide are completely dissolved to obtain the high-permeability thickened oil blocking remover.
Example 9: the high-permeability thickened oil blocking remover comprises 35% of kerosene, 40% of N, N-dimethylacetamide, 5% of oil-soluble azone and 15% of N-alkyl amino acid type surfactant in balance by weight percent, and is obtained by the following steps: uniformly mixing oil-soluble azone and N-alkyl amino acid type surfactant in required amount, stirring until the oil-soluble azone and the N-alkyl amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing kerosene and N, N-dimethylacetamide in required amount to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the N, N-dimethylacetamide are completely dissolved to obtain the high-permeability thickened oil blocking remover.
Example 10: the high-permeability thickened oil blocking remover comprises 35% of kerosene, 40% of N, N-dimethylacetamide, 5% of oil-soluble azone and 15% of N-acyl amino acid type surfactant in balance by weight percent, and is obtained by the following steps: uniformly mixing oil-soluble azone and N-acyl amino acid type surfactant in required amount, stirring until the oil-soluble azone and the N-acyl amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing kerosene and N, N-dimethylacetamide in required amount to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the N, N-dimethylacetamide are completely dissolved to obtain the high-permeability thickened oil blocking remover.
Comparative example 1: and (4) injecting steam (without a blocking remover, and performing viscosity reduction and blocking removal).
Comparative example 2: the mixed benzene wax-removing and blocking-removing agent is sold in the market.
Comparative example 3: commercially available surfactant type deblocking agents.
Example 11: the deblocking construction method of the high-permeability heavy oil deblocking agent is carried out according to the following method:
firstly, verifying the rated pressure of the Christmas tree;
then, injecting a high-permeability thickened oil blocking remover into a wellhead, controlling the pump injection construction pressure to be 0MPa to 10MPa, and controlling the pump discharge capacity to be 0.83kg/min to 10kg/min;
and finally, observing the change of the pump injection construction pressure and the pump discharge capacity, and gradually increasing the pump discharge capacity for construction when the pump injection construction pressure is reduced in the process of injecting the high-permeability thickened oil blocking remover by the pump until the pump injection construction pressure is stable and unchanged, so that the blocking removal is successful.
Example 12: the blockage removal construction method of the high-permeability thickened oil blockage removal agent comprises the following specific implementation steps:
the first step is as follows: the high-permeability thickened oil blocking remover is prepared for later use.
A second step; and (3) preparing before plugging removal construction, judging whether the well mouth is intact and each connecting piece is complete and effective, and verifying the rated pressure of the Christmas tree (the rated pressure of the Christmas tree of the steam huff-puff well is 14 MPa).
The third step: and connecting the ground pipeline and the on-site construction equipment, carrying out pressure test on the ground pipeline, and carrying out the next step after the pressure test is qualified.
The fourth step: opening an oil pipe and a casing gate, starting a pump to slowly inject a high-permeability thickened oil blocking remover into a well mouth, controlling the construction pressure of the pump injection to be 0MPa to 10MPa, controlling the pump discharge capacity to be 0.83kg/min to 10kg/min, stabilizing the pump discharge capacity when starting construction, slowly increasing the construction pressure, observing whether the pressure gauge has fluctuation and whether the pump normally operates, and when the pressure gauge and the pump cannot normally operate (the construction pressure cannot meet the requirement, the pump discharge capacity is high, and a medicament cannot be injected), increasing the pressure, reducing the discharge capacity, continuing the steps until the pressure gauge data has fluctuation, stabilizing the current pressure and the discharge capacity, and continuously injecting the high-permeability thickened oil blocking remover.
And fifthly, continuously observing the change of the pump injection pressure and the pump discharge capacity, gradually increasing the discharge capacity for construction when the pressure is reduced in the process of injecting the high-permeability thickened oil blocking remover by the pump, repeating the steps until the pressure is stable and unchanged, increasing the pressure fluctuation of the pump injection discharge capacity to quickly rise, and indicating that the blocking removal is successful when a numerical value is stabilized.
And a sixth step: and successfully removing the blockage, recovering the wellhead and waiting for next measures.
Example 13: the high-permeability thickened oil blocking remover obtained in the embodiments 7 to 10 of the invention is used for testing steam huff and puff blocked wells in Xinjiang oil fields, and the test comprises the field construction pressure (MPa), the blocking removal time (h), the produced fluid viscosity (mPa & s) after the blocking removal, and the field extraction of the pipe column condition and the dehydration compatibility condition of the produced fluid in the process of repairing after the blocking removal is successful. The dehydration compatibility condition of the produced liquid comprises the produced liquid water content (%), the produced liquid dehydration rate (%) for 2 hours, the produced liquid dehydration rate (%) for 4 hours and the produced liquid demulsification condition, and meanwhile, comparative examples 1 to 3 of the invention are used as controls. The site construction method is carried out according to the blockage removal construction method in the embodiment 12 of the invention.
The on-site construction pressure (MPa), the time (h) required for deblocking, the viscosity (mPa · s) of the produced fluid after deblocking and the test results of the conditions of on-site extraction of the tubular column in the test are shown in Table 1, and it can be seen from Table 1 that when the invention is used for on-site construction in comparative example 1, the on-site construction pressure is high and the time required for deblocking is long; when the comparative example 2 of the invention is used for field construction, the field construction pressure and the time required by the construction are similar to those of the examples 7 to 10, but the medicament (the commercial mixed benzene paraffin removal and blockage removal agent) of the comparative example 2 of the invention has higher risk; when the invention is used for site construction, the blockage removal fails in the comparative example 3. Therefore, when the high-permeability heavy oil blocking remover obtained in the embodiments 7 to 10 of the invention is used for field construction, the field construction pressure is low, the time required by blocking removal is short, the viscosity of produced liquid after blocking removal is low, and a pipe column is pulled out cleanly on the field. It is shown that the high-permeability heavy oil blocking remover obtained in the embodiments 7 to 10 of the invention can effectively solve the blockage of a heavy oil well by matching with a small-displacement high-pressure low-displacement pump injection blocking removal construction method.
The test results of the dehydration compatibility of the produced fluid in the test are shown in table 2, and it can be seen from table 2 that both the high-permeability thickened oil blocking remover obtained in examples 7 to 10 of the present invention and the comparative example 2 of the present invention show better compatibility with the on-site demulsifier, and do not affect the dehydration of the produced fluid. The comparative example 3 of the invention has poor compatibility with the on-site demulsifier, and influences the dehydration of the produced fluid.
In conclusion, the high-permeability thick oil blocking remover disclosed by the invention can be matched with a high-pressure low-displacement pump injection blocking removal construction method, so that the viscosity of crude oil can be well reduced, the blockage of a thick oil well can be effectively solved, an oil sleeve annular circulation channel is established, and the high-permeability thick oil blocking remover has the characteristics of good permeability, high viscosity reduction performance and high safety performance. Meanwhile, the demulsifier has good compatibility with the field demulsifier, and does not influence the dehydration of crude oil.
The technical characteristics form an embodiment of the invention, which has strong adaptability and implementation effect, and unnecessary technical characteristics can be increased or decreased according to actual needs to meet the requirements of different situations.
Figure DEST_PATH_IMAGE001

Claims (10)

1. The high-permeability heavy oil blocking remover is characterized by comprising 35-40% of kerosene, 35-40% of amide solvent, 5-10% of penetrating agent and the balance of amino acid type surfactant in percentage by weight.
2. The high-permeability heavy oil blocking remover according to claim 1, wherein the amide solvent is N, N-dimethylacetamide.
3. The heavy oil blocking remover according to claim 1 or 2, wherein the penetrant is oil-soluble azone.
4. The high penetration thick oil deblocking agent according to claim 1 or 2, characterized in that the amino acid type surfactant is one of an N-alkyl amino acid type surfactant and an N-acyl amino acid type surfactant.
5. The high penetration thick oil deblocking agent according to claim 3, characterized in that the amino acid type surfactant is one of an N-alkyl amino acid type surfactant and an N-acyl amino acid type surfactant.
6. The high-permeability thickened oil blocking remover according to claim 1, 2 or 5, is characterized by being obtained by the following steps: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
7. The high-permeability thickened oil blocking remover according to claim 3, is characterized by being obtained by the following steps: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
8. The high-permeability thickened oil blocking remover according to claim 4, is characterized by being obtained by the following steps: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
9. A method for preparing the high-permeability heavy oil blocking remover according to any one of claims 1 to 5, which is characterized by comprising the following steps of: uniformly mixing the penetrating agent and the amino acid type surfactant in required amounts, stirring until the penetrating agent and the amino acid type surfactant are completely dissolved to obtain a mixed material I, uniformly mixing the kerosene and the amide solvent in required amounts to obtain a mixed material II, adding the mixed material II into the mixed material I, and stirring until the kerosene and the amide solvent are completely dissolved to obtain the high-permeability thick oil blocking remover.
10. The deblocking construction method of the high-permeability heavy oil deblocking agent according to any one of claims 1 to 5, characterized by comprising the following steps:
firstly, verifying the rated pressure of the Christmas tree;
then, injecting a high-permeability thickened oil blocking remover into a wellhead, controlling the pump injection construction pressure to be 0MPa to 10MPa, and controlling the pump discharge capacity to be 0.83kg/min to 10kg/min;
and finally, observing the change of the pump injection construction pressure and the pump discharge capacity, and gradually increasing the pump discharge capacity for construction when the pump injection construction pressure is reduced in the process of injecting the high-permeability thickened oil blocking remover by the pump until the pump injection construction pressure is stable and unchanged, so that the blocking removal is successful.
CN202211473699.4A 2022-11-23 2022-11-23 High-permeability thickened oil blocking remover, preparation method thereof and blocking removing construction method Active CN115651621B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211473699.4A CN115651621B (en) 2022-11-23 2022-11-23 High-permeability thickened oil blocking remover, preparation method thereof and blocking removing construction method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211473699.4A CN115651621B (en) 2022-11-23 2022-11-23 High-permeability thickened oil blocking remover, preparation method thereof and blocking removing construction method

Publications (2)

Publication Number Publication Date
CN115651621A true CN115651621A (en) 2023-01-31
CN115651621B CN115651621B (en) 2023-10-31

Family

ID=85018865

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211473699.4A Active CN115651621B (en) 2022-11-23 2022-11-23 High-permeability thickened oil blocking remover, preparation method thereof and blocking removing construction method

Country Status (1)

Country Link
CN (1) CN115651621B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1498939A (en) * 2002-10-30 2004-05-26 大庆高新区鑫诺精细化工有限公司 Formulary system of amino acid type surfactant and application in tertiary oil recovery
CN102746838A (en) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 Blocking remover for gas well shaft
CN108690589A (en) * 2018-05-31 2018-10-23 中国石油天然气股份有限公司 Oil well blocking remover and preparation method and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1498939A (en) * 2002-10-30 2004-05-26 大庆高新区鑫诺精细化工有限公司 Formulary system of amino acid type surfactant and application in tertiary oil recovery
CN102746838A (en) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 Blocking remover for gas well shaft
CN108690589A (en) * 2018-05-31 2018-10-23 中国石油天然气股份有限公司 Oil well blocking remover and preparation method and application thereof

Also Published As

Publication number Publication date
CN115651621B (en) 2023-10-31

Similar Documents

Publication Publication Date Title
CN103032056B (en) A kind of method and apparatus being applicable to the viscosity reducing of super heavy oil recovery
US4605066A (en) Oil recovery method employing carbon dioxide flooding with improved sweep efficiency
CA2837475C (en) Improving recovery from a hydrocarbon reservoir
US10202540B2 (en) Zirconium gel particle combination flooding system and preparation method thereof
US8980801B2 (en) Zero-leakoff gel
CN110593806B (en) Large-dose multi-slug water plugging method
CN109826590A (en) A kind of old well water blockoff fracturing process of hypotonic oil gas field High water cut
CN115785940A (en) Demulsification cleanup additive for fracture acidizing and preparation method and use method thereof
EP2867327A1 (en) Petroleum recovery process and system
CN115651621A (en) High-permeability thickened oil blocking remover, preparation method thereof and blocking removal construction method
CN111810102B (en) Method for controlling bottom water channeling by utilizing gas water lock effect
US20200040682A1 (en) Method for lowering oil pipe in gas well without well-killing, soluble bridge plug and material preparation method thereof
CN108865107A (en) A kind of low frictional resistance deep acidizing acid liquid for acid fracturing of oil/gas well
CN109294544B (en) Non-oxidized polymer chemical blockage removal gel breaker and preparation method thereof
CN108300435B (en) Embedded high-pressure-bearing plugging agent
CN113464096B (en) Shaft acidizing and plug removing method for high-temperature and high-pressure gas well of carbonate rock
CN111303855A (en) Nano emulsion miscible oil displacement agent and preparation method thereof
CN111592867B (en) Oil-based selective temporary plugging agent
CN115717062B (en) Low-density foam workover fluid for reducing low-pressure gas well workover loss and application thereof
CN113464095B (en) Acidizing and blockage removing method for sandstone high-temperature and high-pressure gas well shaft
CN112480888B (en) Underground gel valve and preparation method thereof
CN118308080A (en) High flash point oil well paraffin removal agent and preparation method and application thereof
CN117287166A (en) Method for realizing lateral opening of new cracks of old well of low-permeability oil reservoir
CN117821040A (en) Wellbore drilling-free recovery preparation and preparation method and application thereof
CN114439439A (en) Method for reducing viscosity of heavy oil in heavy oil reservoir and application

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant