CN115595002A - Corrosion-resistant belt for marine steel facilities - Google Patents

Corrosion-resistant belt for marine steel facilities Download PDF

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Publication number
CN115595002A
CN115595002A CN202211366316.3A CN202211366316A CN115595002A CN 115595002 A CN115595002 A CN 115595002A CN 202211366316 A CN202211366316 A CN 202211366316A CN 115595002 A CN115595002 A CN 115595002A
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Prior art keywords
corrosion
coating
marine steel
resistant belt
woven fabric
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Chinese (zh)
Inventor
张冉
徐亚茜
李佳润
李莹
苗乐
倪双忠
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Qingdao Dean Teshang Nuclear New Material Technology Co ltd
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Qingdao Dean Teshang Nuclear New Material Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses an anti-corrosion belt for an ocean steel facility, and belongs to the technical field of anti-corrosion belts. The application additionally introduces raw materials such as 4-methyl-1-pentene, ferrocene powder, a modifier and the like, and plays a role in improving the comprehensive performance of the corrosion-resistant belt of the marine steel facility. Through analysis, various components in the modifier greatly enhance the adhesive force of the corrosion-resistant belt to the surface of the substrate and enhance the coating tightness and displacement following performance; meanwhile, the compounded ferrocene powder is added, so that a good corrosion inhibition effect is obtained, the corrosion rate of the composite material in a corrosive environment is reduced, and the enhanced corrosion resistance is further obtained.

Description

Corrosion-resistant belt for marine steel facilities
Technical Field
The invention belongs to the technical field of corrosion-resistant belts, and particularly relates to a corrosion-resistant belt for an ocean steel facility.
Background
Since mineral grease has plasticity and excellent anticorrosive effect, oily substances and anticorrosive tapes are widely used as anticorrosive materials for overground or underground buildings such as pipes, stands, pillars, tanks, etc. The corrosion of the steel structures such as foundation piles, trestles, revetments and the like of oil extraction platforms built in water bodies such as oceans, rivers, lakes and the like is particularly serious at the parts in spray splashing areas, so that the mineral fat series anticorrosive material is applied as a coating method. However, it is difficult to achieve a sufficient corrosion-resistant state for steel facilities in a water body by this method. Therefore, a petrolatum anticorrosive material is desired which can maintain an anticorrosive effect in water for a long period of time and does not require maintenance and management. The corrosion-resistant tape used so far is one in which a mixture of a rust inhibitor such as tannic acid added to mineral fat is impregnated in a nonwoven fabric, and is suitable only for protecting steel structures on the ground and underground, and it is difficult to maintain the corrosion-resistant effect for a long time for steel structures in the ocean, and the main reason is that the corrosion-resistant tape is affected by the severe ocean environment, and particularly in the upper part of the tidal range, the surface temperature of the corrosion-resistant tape rises due to sunlight irradiation, and low melting point components contained in the mineral fat evaporate, thereby deteriorating the corrosion-resistant effect and making it difficult to protect for a long period of time.
For example, chinese patent, application No.: CN202210366263.9, discloses an anticorrosion strip for marine steel facilities and a production method thereof, and the technical scheme is as follows:
the corrosion-resistant belt comprises a corrosion-resistant belt body, wherein an anti-skid layer is fixedly connected to the top inside the corrosion-resistant belt body, a waterproof layer is fixedly connected to the lower surface of the anti-skid layer, a wear-resistant layer is fixedly connected to the lower surface of the waterproof layer, an anti-aging layer is fixedly connected to the lower surface of the wear-resistant layer, an anti-corrosion layer is fixedly connected to the lower surface of the anti-aging layer, a reinforcing layer is fixedly connected to the lower surface of the anti-corrosion layer, a first reinforcing rib is fixedly connected to one side inside the reinforcing layer, a second reinforcing rib is fixedly connected to the other side inside the reinforcing layer, and glass fibers are fixedly connected to the inner side surfaces of the first reinforcing rib and the second reinforcing rib.
In order to enable the corrosion-resistant belt for the marine steel facility and the production method thereof to achieve the effect of convenient heat insulation, as a preferable preference of the invention, the lower surface of the reinforcing layer is fixedly connected with an elastic memory layer, and the lower surface of the elastic memory layer is fixedly connected with a heat insulation layer.
In order to enable the corrosion-resistant belt for the marine steel facility and the production method thereof to achieve an antibacterial effect, the lower surface of the heat-insulating layer is fixedly connected with a heat-insulating layer, and the lower surface of the heat-insulating layer is fixedly connected with an antibacterial layer.
In order to enable the corrosion-resistant belt for the marine steel facility and the production method thereof to achieve the effect of convenient adhesion, as a preferable preference of the invention, the lower surface of the antibacterial layer is fixedly connected with the adhesive layer, and the lower surface of the adhesive layer is fixedly connected with the release layer.
In order to enable the corrosion-resistant belt for the marine steel facility and the production method thereof to achieve the effect of enhancing the sealing property of connection, preferably, both sides of the outer surface of the corrosion-resistant belt body are fixedly connected with the edge covers.
In order to enable the corrosion-resistant belt for the marine steel facility and the production method thereof to achieve the effect of convenient rolling, as a preferable mode of the invention, one end of the outer surface of the corrosion-resistant belt body is fixedly connected with gummed paper, and the inner side surface of the gummed paper is adhered with a cylinder.
In order to achieve the effect of improving the neatness of the corrosion-resistant belt for the marine steel facility and the production method thereof, the inner side surface of the cylindrical column is preferably movably connected with a supporting rod, and two ends of the supporting rod are fixedly connected with a fixed disc.
In order to enable the marine steel facility corrosion-resistant belt and the production method thereof to achieve the effect of conveniently adjusting the position of the sliding block, as a preferred choice of the invention, a sliding groove is formed in one side inside the fixed disc, an adjusting rod is rotatably connected to one side of the inner wall of the sliding groove, and the sliding block is connected to the outer surface of the adjusting rod in a threaded manner.
In order to enable the marine steel facility corrosion-resistant belt and the production method thereof to achieve the effect of conveniently compacting the corrosion-resistant belt body, the invention is preferably characterized in that the outer surface of the sliding block is fixedly connected with a connecting plate, the inner side surface of the connecting plate is fixedly connected with a spring, and one end of the spring is fixedly connected with a rubber pressing plate.
A production method of an anticorrosion belt for a marine steel facility comprises the following steps:
s1: the plastic film is prepared by mixing plastic particles and corresponding additives as raw materials, blowing the plastic film into a plastic film substrate in a film blowing mode, discharging the substrate by an unwinding mechanism, and carrying out corona treatment on the surface of the substrate by a corona device.
S2: weighing raw materials such as common polytetrafluoroethylene fibers, diaminodiphenyl ether, pyromellitic dianhydride, glass fibers, carbon nanofibers, dimethylacetamide, PVC resin powder, ceramic fibers and an antioxidant in corresponding parts by weight for later use, and then adding materials with different purposes into different reaction kettles to be stirred and mixed uniformly.
S3: and the extruder is used for forming a plurality of functional layers at one time by the mixed raw materials through a distributor and a co-extrusion die head, and the functional layers are compounded with one surface of the base material subjected to corona treatment through a compounding device and cooled to form a primary anti-corrosion belt.
S4: and (3) conveying the primary anti-corrosion tape into an edge sealing device, sealing two sides of the primary anti-corrosion tape, conveying the primary anti-corrosion tape into a gluing device, coating the other side of the substrate with pressure-sensitive adhesive, attaching release paper to the bottom of the adhesive side to form the anti-corrosion tape together with the primary anti-corrosion tape, and rolling the anti-corrosion tape by a rolling mechanism.
S5: and cutting the wound mother roll by a cutting and forming device so as to cut and process the mother roll into a finished product with the required finished product width.
Disclosure of Invention
1. Problems to be solved
Aiming at the problems in the prior art, the invention provides the marine steel facility corrosion-resistant belt with excellent performance and multiple functions, the process is simple, and the invention additionally introduces raw materials such as 4-methyl-1-pentene, ferrocene powder, a modifier and the like, thereby playing a role in improving the comprehensive performance of the marine steel facility corrosion-resistant belt. Through analysis, various components in the modifier greatly enhance the adhesive force of the corrosion-resistant belt to the surface of the substrate and enhance the coating tightness and displacement following performance; meanwhile, the compounded ferrocene powder is added, so that a good corrosion inhibition effect is obtained, the corrosion rate of the composite material in a corrosive environment is reduced, and the enhanced corrosion resistance is further obtained.
2. Technical scheme
In order to solve the problems, the technical scheme provided by the invention is as follows:
an anticorrosion belt for a marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000031
the corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000032
the corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000033
Figure BDA0003919744690000041
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
The particle size of the magnesium stearate of the marine steel facility corrosion prevention belt is 1000 meshes.
The thickness range of the coating applied to the HDPE non-woven fabric adhesive tape of the marine steel facility corrosion-resistant belt is 1.5mm-2.4mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
A preparation method of an anticorrosion strip for a marine steel facility comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
3. Advantageous effects
The application additionally introduces raw materials such as 4-methyl-1-pentene, ferrocene powder, a modifier and the like, and plays a role in improving the comprehensive performance of the corrosion-resistant belt of the marine steel facility. Through analysis, various components in the modifier greatly enhance the adhesive force of the corrosion-resistant belt to the surface of the substrate and enhance the coating tightness and displacement following performance; meanwhile, the compounded ferrocene powder is added, so that a good corrosion inhibition effect is obtained, the corrosion rate of the ferrocene powder in a corrosive environment is reduced, and the enhanced corrosion resistance is further obtained.
Detailed Description
The invention is further described with reference to specific examples.
Example 1
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000042
Figure BDA0003919744690000051
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the coating is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
Example 2
The marine steel facility corrosion-resistant belt comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000052
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion-resistant belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the thickness range of the coating coated on the HDPE non-woven fabric adhesive tape is 2.4mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
Example 3
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000061
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the coating is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the corrosion-resistant belt of the marine steel facility comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
Example 4
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000071
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion-resistant belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the thickness range of the coating coated on the HDPE non-woven fabric adhesive tape is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
Example 5
The marine steel facility corrosion-resistant belt comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000081
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion-resistant belt, the ferrocene powder is processed by linseed oil.
The particle size of the magnesium stearate of the marine steel facility corrosion prevention belt is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the HDPE non-woven fabric adhesive tape is 2.4mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
Comparative example 1
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000082
Figure BDA0003919744690000091
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the marine steel facility corrosion-resistant belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the coating is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding ferrocene powder, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
Comparative example 2
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000092
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
in the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the coating is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the marine steel facility corrosion-resistant belt comprises the following steps:
adding 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
Comparative example 3
The marine steel facility corrosion-resistant belt comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000101
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 1:1:1:1:1.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the HDPE non-woven fabric adhesive tape is 2.4mm.
The marine steel facility corrosion-resistant belt is characterized in that the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the corrosion-resistant belt of the marine steel facility comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
Comparative example 4
The marine steel facility corrosion-resistant belt comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000111
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 1:7:3:5.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
In the corrosion-resistant belt for the marine steel facility, the granularity of the magnesium stearate is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the HDPE non-woven fabric adhesive tape is 2.4mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the corrosion-resistant belt of the marine steel facility comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
Comparative example 5
The corrosion-resistant belt for the marine steel facility comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure BDA0003919744690000121
the marine steel facility corrosion-resistant belt comprises a modifier, a modifier and a corrosion inhibitor, wherein the modifier comprises guanidine hydrochloride, sodium citrate and hexadecyl trimethyl ammonium bromide;
the mass ratio of the guanidine hydrochloride, the sodium citrate and the hexadecyl trimethyl ammonium bromide is 2:1:3.
in the marine steel facility corrosion prevention belt, the ferrocene powder is processed by linseed oil.
The particle size of the magnesium stearate of the marine steel facility corrosion prevention belt is 1000 meshes.
In the marine steel facility corrosion-resistant belt, the coating is coated on the HDPE non-woven fabric adhesive tape, and the thickness range of the coating is 1.5mm.
In the corrosion-resistant belt for the marine steel facility, the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
The preparation method of the corrosion-resistant belt of the marine steel facility comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding the mineral oil with the same mass, and stirring and mixing.
The test scheme is as follows:
the products prepared in examples 1 to 5 and the products prepared in comparative examples 1 to 5 were selected and subjected to the following tests:
the prepared product was tested for the adhesion between the corrosion resistant tape and the substrate (stainless steel 304) using a peel strength tester.
At the same time, the test piece was placed in a YP-90 salt spray test box 64d, and the corrosion tape was peeled off and the corrosion was recorded.
TABLE 1
Figure BDA0003919744690000122
Figure BDA0003919744690000131
As shown in Table 1, raw materials such as 4-methyl-1-pentene, ferrocene powder, a modifier and the like are additionally introduced, so that the comprehensive performance of the corrosion-resistant belt for the marine steel facility is improved. Through analysis, various components in the modifier greatly enhance the adhesive force of the corrosion-resistant belt to the surface of the substrate and enhance the coating tightness and displacement following performance; meanwhile, the compounded ferrocene powder is added, so that a good corrosion inhibition effect is obtained, the corrosion rate of the ferrocene powder in a corrosive environment is reduced, and the enhanced corrosion resistance is further obtained.
The present invention and its embodiments have been described above schematically, but the description is not limited thereto, and the embodiment shown is only one of the embodiments of the present invention, and the actual structure is not limited thereto. Therefore, if the person skilled in the art receives the teaching, without departing from the spirit of the invention, the person skilled in the art shall not inventively design the similar structural modes and embodiments to the technical solution, but shall fall within the scope of the invention.

Claims (9)

1. An anti-corrosion belt for an ocean steel facility, which is characterized in that,
the HDPE non-woven fabric adhesive tape comprises an HDPE non-woven fabric adhesive tape and a coating, wherein the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure FDA0003919744680000011
2. the corrosion protection belt for marine steel facilities according to claim 1,
the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure FDA0003919744680000012
3. the corrosion protection belt for marine steel facilities according to claim 2,
the coating is uniformly coated on the side surface of the HDPE non-woven fabric adhesive tape;
the coating comprises the following components in parts by weight:
Figure FDA0003919744680000013
4. the corrosion protection belt for marine steel facilities according to claim 3,
the modifier comprises guanidine hydrochloride, sodium citrate, phthalate, hexadecyl trimethyl ammonium bromide and calcium carbonate;
the mass ratio of the guanidine hydrochloride, the sodium citrate, the phthalate, the hexadecyl trimethyl ammonium bromide and the calcium carbonate is 2:1:7:3:5.
5. the corrosion protection belt for marine steel facilities according to claim 3,
the ferrocene powder is processed by linseed oil.
6. The corrosion protection belt for marine steel facilities according to claim 3,
the granularity of the magnesium stearate is 1000 meshes.
7. Corrosion resistant belt for marine steel facilities according to claim 3,
the thickness range of the coating which is smeared on the HDPE non-woven fabric adhesive tape is 1.5mm-2.4mm.
8. Corrosion resistant belt for marine steel facilities according to claim 3,
the petrolatum is a petrolatum mixture containing 10% of paraffin by mass.
9. A preparation method of an anticorrosion strip for an ocean steel facility is characterized in that,
the preparation method of the coating comprises the following steps:
adding ferrocene powder, 4-methyl-1-pentene, beeswax, nano silicon dioxide and magnesium stearate into a stirring kettle, heating to 105 ℃, and uniformly stirring to obtain a basic viscous coating;
and then adding the petrolatum and the modifier into the stirring kettle, dispersing at a high speed to obtain the modified viscous coating, cooling to 70 ℃, adding mineral oil with the same mass, and stirring and mixing to obtain the coating.
CN202211366316.3A 2022-11-01 2022-11-01 Corrosion-resistant belt for marine steel facilities Pending CN115595002A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101078126A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Anti-corrosion belt for ocean steel facilities
CN101078125A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Anti-corrosion plaster for ocean steel facilities
CN101078124A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Coating and anti-corrosion method for steel products
CN109337454A (en) * 2018-10-31 2019-02-15 青岛迪恩特新材料科技有限公司 A kind of anti-corrosion anti-corrosion plaster of height and its preparation method and application suitable for naval air environment
CN109355900A (en) * 2018-10-31 2019-02-19 青岛迪恩特新材料科技有限公司 A kind of height suitable for naval air environment sticks anti-corrosion belt and its preparation method and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101078126A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Anti-corrosion belt for ocean steel facilities
CN101078125A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Anti-corrosion plaster for ocean steel facilities
CN101078124A (en) * 2006-05-26 2007-11-28 株式会社那卡波技工 Coating and anti-corrosion method for steel products
CN109337454A (en) * 2018-10-31 2019-02-15 青岛迪恩特新材料科技有限公司 A kind of anti-corrosion anti-corrosion plaster of height and its preparation method and application suitable for naval air environment
CN109355900A (en) * 2018-10-31 2019-02-19 青岛迪恩特新材料科技有限公司 A kind of height suitable for naval air environment sticks anti-corrosion belt and its preparation method and application

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Application publication date: 20230113