CN115593068A - Anti-doodling leather filling paper - Google Patents
Anti-doodling leather filling paper Download PDFInfo
- Publication number
- CN115593068A CN115593068A CN202110774739.8A CN202110774739A CN115593068A CN 115593068 A CN115593068 A CN 115593068A CN 202110774739 A CN202110774739 A CN 202110774739A CN 115593068 A CN115593068 A CN 115593068A
- Authority
- CN
- China
- Prior art keywords
- crosslinking
- paper
- polyolefin
- parts
- polyolefin layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010985 leather Substances 0.000 title description 9
- 238000011049 filling Methods 0.000 title description 2
- 229920000098 polyolefin Polymers 0.000 claims abstract description 34
- 239000010410 layer Substances 0.000 claims abstract description 26
- 238000004132 cross linking Methods 0.000 claims abstract description 24
- 239000012790 adhesive layer Substances 0.000 claims abstract description 7
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 6
- -1 polyethylene Polymers 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 6
- 239000000758 substrate Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- UBJVUCKUDDKUJF-UHFFFAOYSA-N Diallyl sulfide Chemical compound C=CCSCC=C UBJVUCKUDDKUJF-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention provides an anti-doodling leatherette paper, which structurally comprises: paper base; an adhesive layer; a polyolefin layer. The polyolefin layer comprises 100 parts of polyolefin, 0.1-10 parts of polyorganosiloxane and 0.01-5 parts of auxiliary crosslinking agent. After the polyolefin layer is subjected to irradiation crosslinking, polyolefin with the crosslinking degree of 10% -90% and polyorganosiloxane form a compact network structure through irradiation crosslinking, the coating is endowed with the scrawling resistance by an organic silicon structure with low surface energy, and the polyorganosiloxane is not easy to migrate due to the effect of crosslinking chemical bonds, so that a homogeneous and tough surface is obtained, and the scrawling-resistant leatherette paper with better performance is obtained.
Description
Technical Field
The invention belongs to the technical field of packaging materials, and particularly relates to anti-graffiti leatherette paper.
Background
The leather-filled paper is formed by attaching a resin layer on the surface of a paper base. Because of its flexibility and skin feel, it is widely used as a packaging material.
The leatherette paper can comprise polyvinyl chloride (PVC) leatherette paper, polyurethane (PU) leatherette paper, ethylene-vinyl acetate copolymer (EVA) leatherette paper and the like according to material distinction. The resin on the surface of the paper base has the functions of decorating and protecting the paper base, reducing the retention of dirt on the surface of the leather-filled paper or enabling the surface of the leather-filled paper to be easier to clean, and the surface of the coating is required to have lower surface tension, so that the self-cleaning property of the surface of an object is improved, and the anti-graffiti effect is generated.
At present, the anti-graffiti technology obtains a certain use effect based on the anti-graffiti performance of low surface energy resin such as organic silicon or fluorocarbon or inorganic mineral particles. Organic silicon, fluorine resin or inorganic mineral particles are mixed with other resins (such as acrylic resin) or physical solution of auxiliary agent to obtain oil-soluble paint product based on organic solvent. Although the method is simple and practical and has low cost, the components are only physically combined and lack necessary chemical bond connection, a homogeneous and tough coating film is difficult to obtain, and the active ingredients playing the anti-graffiti role are easy to free and migrate out of the film, so that the anti-graffiti performance is obviously reduced along with the prolonging of time, and even the anti-graffiti performance is completely lost. Although some anti-graffiti coatings attempt to solve this problem by using a treatment that chemically cross-links the coating, which overcomes the migration of the active ingredients to some extent, the large amount of organic solvents in the coating formulation is very harmful to the surrounding environment during production and use.
Therefore, the search for a leather-filled paper with graffiti performance becomes the focus of research.
Disclosure of Invention
In order to solve the technical problem, the invention provides an anti-doodling leatherette paper, which comprises the following structures: a paper base; an adhesive layer; a polyolefin layer. The polyolefin layer comprises 100 parts of polyolefin, 0.1-10 parts of polyorganosiloxane and 0.01-5 parts of auxiliary crosslinking agent. After the polyolefin layer is subjected to irradiation crosslinking, the crosslinking degree is 10-90 percent
The polyolefin used in the invention can form reactive free radicals in the radiation crosslinking process as active crosslinking points to perform crosslinking reaction with active groups in the polyorganosiloxane, the auxiliary crosslinking agent increases the reactivity to form a three-dimensional network structure with higher crosslinking density, the polyorganosiloxane material and the polyolefin material form chemical bond connection through crosslinking, and the organic silicon component playing a graffiti-resistant role is not easy to migrate because of the chemical bond connection with the main chain of the polymer, so that a homogeneous and tough surface is obtained, and the graffiti-resistant leatherette paper with better performance is obtained.
Detailed Description
In order to make the objects, technical solutions and advantageous technical effects of the present invention more clear, the present invention is described in detail with reference to specific embodiments below. It should be understood that the embodiments described in this specification are only for the purpose of explaining the present invention and are not intended to limit the present invention.
For the sake of brevity, only some numerical ranges are explicitly disclosed herein. However, any lower limit may be combined with any upper limit to form ranges not explicitly recited; and any lower limit may be combined with any other lower limit to form a range not explicitly recited, and similarly any upper limit may be combined with any other upper limit to form a range not explicitly recited. Also, although not explicitly recited, each point or individual value between endpoints of a range is encompassed within the range. Thus, each point or individual value can form a range not explicitly recited as its own lower or upper limit in combination with any other point or individual value or in combination with other lower or upper limits.
In the description herein, it is to be noted that, unless otherwise specified, "above" and "below" are inclusive, and "one or more" of "plural" means two or more.
The above summary of the present invention is not intended to describe each disclosed embodiment or every implementation of the present invention. The following description more particularly exemplifies illustrative embodiments. At various points throughout this application, guidance is provided through a list of embodiments that can be used in various combinations. In various embodiments, the lists are provided as representative groups and should not be construed as exhaustive.
The invention provides an anti-doodling leatherette paper, which structurally comprises: paper base; an adhesive layer; a polyolefin layer. The polyolefin layer comprises 100 parts of polyolefin, 50-100 parts of rubber elastomer, 1-10 parts of reactive siloxane and 0.1-5 parts of auxiliary crosslinking agent. After the polyolefin layer is subjected to irradiation crosslinking, the crosslinking degree is 10% -90%.
In the leathered paper of the present invention, the paper substrate may employ a base for leathered paper known in the art. The paper substrate generally has suitable strength and toughness, which can be selected by one skilled in the art according to actual needs.
In some embodiments, the polyolefin is selected from one or more of polyethylene, ethylene and alpha-olefin copolymer, polypropylene, propylene and alpha-olefin copolymer.
In some embodiments, the polyorganopolysiloxane has a molecular weight greater than 500 and may have pendant chains that are one or more of alkyl, epoxy, alkenyl, hydroxyl, amino, or acrylate groups.
In some embodiments, the co-crosslinking agent is selected from one or more of diallylamine, diallyl sulfide, N-methylene bisacrylamide, ethylene glycol dimethacrylate, triallyl cyanurate, triallyl isocyanurate, trimethylolpropane trimethacrylate, tetramethylolmethane tetraacrylate.
In some embodiments, the adhesive layer material is a blend of EVA and a tackifying resin, the tackifying resin including one or more of rosin, rosin derivatives, terpene resins, terpene phenolic resins, C5-C9 petroleum resins, dicyclopentadiene resins.
The invention also provides a preparation method of the leather-filled paper. The leatherette paper can be prepared according to the preparation method. The preparation method of the leather-covered paper provided by the embodiment of the invention comprises the steps of modified polyolefin layer preparation, attaching and irradiation crosslinking.
In the preparation step of the polyolefin layer, all raw materials of the polyolefin layer can be uniformly mixed and then subjected to double-layer co-extrusion casting with an adhesive layer on the surface of the paper base to form the modified polyolefin layer. The modified polyolefin layer preparation step may be performed using equipment known in the art, such as an extruder. The extruder may employ a T-shaped flat die.
In some embodiments, the adhesive layer is pressure or heat bonded to the paper substrate to achieve a secure bond between the polyolefin layer and the paper substrate. The pressure for pressure bonding may be 0.1MPa to 2.5MPa.
In some embodiments, a heated roll may be used on the paper-based side. The temperature of the hot roll can be 80-200 ℃. By preheating the paper base, the adhesive force between the paper base and the polyolefin layer can be improved.
The crosslinking step comprises crosslinking the polyolefin of the polyolefin layer. In some embodiments, the leatherette paper preform may be radiation crosslinked. This gives the polyolefin layer the desired degree of crosslinking, i.e. the polyolefin layer is a radiation crosslinked polyolefin layer. Radiation crosslinking may be performed using alpha rays, beta rays, gamma rays, X rays, or neutron rays.
In some embodiments, the leathered paper is crosslinked by irradiation, the degree of crosslinking after irradiation being from 10% to 90%.
Examples
The present disclosure is more particularly described in the following examples that are intended as illustrations only, since various modifications and changes within the scope of the present disclosure will be apparent to those skilled in the art. Unless otherwise indicated, all parts, percentages, and ratios reported in the following examples are on a weight basis, and all reagents used in the examples are commercially available or synthesized according to conventional methods and can be used directly without further treatment, and the equipment used in the examples is commercially available.
The polyolefins used in the following examples were selected from:
polypropylene: atactic polypropylene, designation LG chemical R3410;
polyethylene: low density polyethylene, LDPE, designation LG chemical FB3050;
ethylene-butene copolymer: LG chemical LC875;
ethylene-octene copolymer: brand dow chemical 8411.
The reactive siloxanes used in the following examples were selected from:
anhui Ai Yaoda, IOTA253, divinyl-terminated phenyl silicone oil, molecular weight 600;
anhui Ai Yaoda, IOTA2031, acrylate modified polysiloxane, molecular weight 2000;
anhui Ai Yaoda, IOTA105-4, epoxy mono-terminated polysiloxane, molecular weight 1500;
jinanrong, a chemical industry, polyamino siloxane, molecular weight 500;
jinan Rong Guang chemical industry, polydimethylsiloxane, molecular weight 10000.
Examples 1-4 and comparative examples 1-3 were carried out according to the formulation in table 1: and the obtained leatherette paper is subjected to a scrawl resistance test, the result is shown in table 2, and the test is carried out according to the following method:
the anti-graffiti property test method comprises the following steps: after drying the mark, "#" was written on the leather coating using a common oil-based marker at 20 ℃ under 50% humidity, the mark was wiped with dry pure cotton cloth, and the result after wiping was recorded.
Degree of crosslinking: DIN EN ISO-10147.
As can be seen from the data of the examples, the polyurethane coatings of the present invention provide better graffiti resistance to leather products.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto. Those skilled in the art can easily conceive of various equivalent modifications or substitutions within the technical scope of the present disclosure, and such modifications or substitutions are intended to be included within the scope of the present disclosure. Therefore, the protection scope of the present invention shall be subject to the protection scope defined by the claims.
TABLE 1 examples and comparative examples in which the components are in parts by weight
Table 2 test results of examples and comparative examples
Claims (4)
1. An anti-doodling leatherette paper sequentially comprises a paper base layer, an adhesive layer and a polyolefin layer from bottom to top. The polyolefin layer comprises 100 parts of polyolefin, 0.1-10 parts of polyorganosiloxane and 0.01-5 parts of auxiliary crosslinking agent. After the polyolefin layer is subjected to irradiation crosslinking, the crosslinking degree is 10-90%.
2. The anti-graffiti leatherette paper according to claim 1, wherein the polyolefin material is selected from one or more of polyethylene, ethylene-alpha-olefin copolymer, polypropylene, propylene-alpha-olefin copolymer.
3. The anti-graffiti leatherette paper according to claim 1, wherein the polyorganopolysiloxane has a molecular weight greater than 500.
4. The graffiti-resistant leatherette paper as claimed in claim 1, wherein the laminated leatherette paper has a degree of crosslinking of 10% to 90% after radiation crosslinking.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110774739.8A CN115593068B (en) | 2021-07-08 | 2021-07-08 | Anti-doodling kraft paper |
| JP2023580353A JP2024525017A (en) | 2021-07-08 | 2021-11-18 | Artificial leather and its manufacturing method |
| EP21949110.7A EP4342670A1 (en) | 2021-07-08 | 2021-11-18 | Artificial leather and manufacturing method therefor |
| PCT/CN2021/131505 WO2023279625A1 (en) | 2021-07-08 | 2021-11-18 | Artificial leather and manufacturing method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110774739.8A CN115593068B (en) | 2021-07-08 | 2021-07-08 | Anti-doodling kraft paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115593068A true CN115593068A (en) | 2023-01-13 |
| CN115593068B CN115593068B (en) | 2024-04-09 |
Family
ID=84841566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110774739.8A Active CN115593068B (en) | 2021-07-08 | 2021-07-08 | Anti-doodling kraft paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115593068B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004307848A (en) * | 2003-03-26 | 2004-11-04 | Mitsui Chemicals Inc | Aqueous resin composition |
| JP2012021201A (en) * | 2010-07-16 | 2012-02-02 | Dainippon Printing Co Ltd | Method for producing water-repellent coating film and releasing paper |
| CN110709483A (en) * | 2017-05-22 | 2020-01-17 | Ppg工业俄亥俄公司 | Polyolefin silicon coating composition |
-
2021
- 2021-07-08 CN CN202110774739.8A patent/CN115593068B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004307848A (en) * | 2003-03-26 | 2004-11-04 | Mitsui Chemicals Inc | Aqueous resin composition |
| JP2012021201A (en) * | 2010-07-16 | 2012-02-02 | Dainippon Printing Co Ltd | Method for producing water-repellent coating film and releasing paper |
| CN110709483A (en) * | 2017-05-22 | 2020-01-17 | Ppg工业俄亥俄公司 | Polyolefin silicon coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115593068B (en) | 2024-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102005686B1 (en) | Semiconductor wafer surface protective film and method of manufacturing semiconductor device | |
| CN103525324B (en) | Adhesive tape for surface protection of a semiconductor wafer and method of producing a semiconductor wafer | |
| CN105339168B (en) | The manufacturing method of protective film formation composite sheet, the chip with protective film and the chip with protective film | |
| JP2013177645A (en) | Biaxially oriented polypropylene film and method for producing the same | |
| EP0584947B1 (en) | Method of using epoxysilicone release composition | |
| CN104508798B (en) | The manufacture method of semiconductor wafer processing adhesive tape and semiconductor wafer processing adhesive tape | |
| EP2794263B2 (en) | Pressure-sensitive label structures, and methods of making same | |
| EP3380317B1 (en) | Adhesive formulations for fabric/poe adhesion | |
| KR20080059950A (en) | Surface protective film | |
| KR102513675B1 (en) | Silicone based adhesive protective film and optical member comprising the same | |
| TW200528508A (en) | Resin composition for use in release film and release film produced therefrom | |
| CN110023085A (en) | Polymer composition for binder application | |
| CN105492558A (en) | Sheet for processing semiconductor | |
| CN111466015A (en) | Solid crystal film, dicing solid crystal sheet and method for manufacturing semiconductor chip | |
| PH12015501197B1 (en) | Protective - membrane - forming - film | |
| CN111139654B (en) | Synthetic leather and method for producing the same | |
| KR102644397B1 (en) | Water repellent composition, water repellent textile product and method for producing water repellent textile product | |
| TW201807146A (en) | Adhesive composition and adhesive tape | |
| CN115593068A (en) | Anti-doodling leather filling paper | |
| JP2022000904A (en) | Kit and method for manufacturing semiconductor chip | |
| CN106463371A (en) | Dicing-sheet base film and dicing sheet | |
| JP2014523355A (en) | Multilayer film with high tear propagation resistance and low shrinkage | |
| KR20010014638A (en) | Sheet coated with silicon based compounds highly effective in preventing adhesion of stains and process for preparing the same | |
| KR20200129727A (en) | Silicone based adhesive protective film and optical member comprising the same | |
| JP7033237B2 (en) | How to manufacture kits and semiconductor chips |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |