CN115505324A - Formula of waterborne polyurethane high-performance anti-UV finish paint - Google Patents

Formula of waterborne polyurethane high-performance anti-UV finish paint Download PDF

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Publication number
CN115505324A
CN115505324A CN202110628657.2A CN202110628657A CN115505324A CN 115505324 A CN115505324 A CN 115505324A CN 202110628657 A CN202110628657 A CN 202110628657A CN 115505324 A CN115505324 A CN 115505324A
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CN
China
Prior art keywords
water
polyurethane
waterborne polyurethane
performance
waterborne
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110628657.2A
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Chinese (zh)
Inventor
刘倩
童飞
徐楠娇
杜蓓
徐盛成
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Shanghai Tuguan Hi Tech Co ltd
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Shanghai Tuguan Hi Tech Co ltd
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Priority to CN202110628657.2A priority Critical patent/CN115505324A/en
Publication of CN115505324A publication Critical patent/CN115505324A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a formula of a waterborne polyurethane high-performance anti-UV finish paint, which comprises the following raw materials: the water-based polyurethane comprises a water-based polyurethane material A, a water-based polyurethane material B, a UV additive and deionized water, wherein the water-based polyurethane material A comprises the following components in percentage by weight: the water-based polyurethane material B comprises the following components in percentage by weight: diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and a cosolvent. The formula of the waterborne polyurethane high-performance UV-resistant finish paint has the advantages of no pollution, safety, reliability, excellent mechanical property, good compatibility and easiness in modification, is simple to produce and operate, has small smell, can be used on the inner wall and the outer wall of a building, and can convert ultraviolet rays into harmless rays in other wave bands to achieve the UV-resistant effect.

Description

Formula of waterborne polyurethane high-performance anti-UV finish paint
Technical Field
The invention relates to the technical field of wall paint, in particular to a formula of a waterborne polyurethane high-performance anti-UV paint.
Background
The wall paint is one of main decorative materials for wall decoration in home decoration, the wall paint is also divided into two types for an outer wall and an inner wall, the existing wall paint for the outer wall can prevent water, stain and weather change, the wall paint for the inner wall has the advantages of antibiosis, strong adhesiveness, environmental protection and no peculiar smell, and the waterborne polyurethane is a novel polyurethane system which takes water as a dispersion medium instead of an organic solvent, is more environment-friendly than the traditional polyurethane, and has the advantages of no pollution, safety, reliability, excellent mechanical property, good compatibility, easy modification and the like.
With the continuous use of the wall paint, the following problems are found in the practical construction process of coating the wall paint on the inner wall and the outer wall:
the existing exterior wall finish and interior wall finish need to be distinguished and used and cannot be mixed, but in the actual construction process, the condition of worker mixing or wrong use often occurs, the performance of the exterior wall finish and the interior wall finish is single, the environmental protection performance of a polyurethane raw material used by the traditional wall finish is lower than that of waterborne polyurethane, and the traditional polyurethane wall finish has the defects of large smell, complex production and processing and difficult cleaning.
Therefore, the formula of the waterborne polyurethane high-performance UV-resistant finish paint needs to be designed aiming at the problems.
Disclosure of Invention
The invention aims to provide a formula of a high-performance UV-resistant waterborne polyurethane finish, which aims to solve the problems that the exterior wall finish and the interior wall finish of the existing polyurethane wall finish in the prior art are easy to be mixed or used wrongly, the performances of the exterior wall finish and the interior wall finish are single, the environmental protection performance of a polyurethane raw material used by the traditional wall finish is lower than that of waterborne polyurethane, and the traditional polyurethane wall finish has the defects of large smell, complex production and processing and difficult cleaning.
In order to achieve the purpose, the invention provides the following technical scheme: a formula of a waterborne polyurethane high-performance anti-UV finishing paint comprises the following raw materials: the water-based polyurethane comprises a water-based polyurethane material A, a water-based polyurethane material B, a UV additive and deionized water, wherein the water-based polyurethane material A comprises the following components in percentage by weight: 60-80% of water-based polyether monomer, 0.5-1% of water-based dispersant, 0.2-0.5% of water-based leveling agent, 0.5-1% of thickening agent, 0.1-0.3% of defoaming agent, 0.2-1% of film-forming assistant, 10-15% of filler, 0.1-1% of pH regulator and 0-10% of pigment, wherein the water-based polyurethane B material comprises the following components in percentage by weight: 20% of diphenylmethane diisocyanate, 20-60% of polyphenyl polymethylene polyisocyanate, 10-40% of deionized water and 10-20% of cosolvent, wherein the preparation process of the formula of the waterborne polyurethane high-performance anti-UV finish paint comprises the following steps:
the method comprises the following steps:
quantitatively taking out a water-based polyether monomer, a water-based dispersing agent, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by the preparation of the water-based polyurethane A material, pouring the mixture into a stirring kettle, and stirring at a temperature of between 25 and 30 ℃ at a speed of more than or equal to 2000r/min for 40 to 60min to obtain the water-based polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, the polyphenyl polymethylene polyisocyanate, the deionized water and the cosolvent required by preparing the waterborne polyurethane B material, then pouring the waterborne polyurethane A material prepared in the step one into a stirring kettle, immediately pouring the diphenylmethane diisocyanate, the polyphenyl polymethylene polyisocyanate, the deionized water and the cosolvent into the stirring kettle, and stirring at the temperature of 25-30 ℃ at the speed of 3500-4000r/min for 1.5-2.0h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 40-50 ℃, preserving the heat for 6-12h, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
Preferably, the overall weight ratio of the waterborne polyurethane A material to the waterborne polyurethane B material to the UV additive to the deionized water is 2-6:1:0.1-0.3:5.
preferably, the aqueous dispersant in the aqueous polyurethane A is polyethylene glycol type polyol, and the aqueous dispersant is aqueousThe flatting agent is polyether modified siloxane, the thickening agent is polyether polyurethane, the defoaming agent is mineral oil liquid containing hydrophobic silicon dioxide, the film-forming additive is ethylene glycol phenyl ether or 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, and the filler is modified kaolin and nanoscale Al 2 O 3 And SiO 2 One or more of them, and the pH regulator is ammonia water.
Preferably, the cosolvent is propylene glycol methyl ether acetate or ethyl acetate.
Preferably, the UV additive is 2-hydroxy-4-n-octoxybenzophenone or n-hexadecyl 3, 5-di-tert-butyl-4-hydroxybenzoate.
Compared with the prior art, the invention has the beneficial effects that:
the invention adopts reasonable raw material proportion, so that the product quality is stable, the invention has the advantages of no pollution, safety, reliability, excellent mechanical property, good compatibility and easy modification, the production and the operation are simple, the smell is less, the invention can be used on the inner wall and the outer wall of a building, and simultaneously, ultraviolet rays can be converted into harmless rays of other wave bands, thereby achieving the anti-UV effect.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
The invention provides a technical scheme that:
example 1:
the method comprises the following steps:
quantificationally taking out a water-based polyether monomer, a water-based dispersing agent, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by preparing a water-based polyurethane A material, wherein the mass ratio of the components is as follows: 60:0.5:0.2:0.5:0.1:0.2:10:0.1:0, pouring the mixture into a stirring kettle, and stirring at the temperature of 25 ℃ at the speed of 2000r/min for 40min to obtain a waterborne polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and cosolvent required by preparing the waterborne polyurethane B material, wherein the mass ratio is as follows: 1:3:4:2, pouring the waterborne polyurethane A prepared in the first step into a stirring kettle, and immediately pouring diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and a cosolvent, wherein the overall weight ratio of the waterborne polyurethane A to the waterborne polyurethane B to the UV additive to the deionized water is 2:1:0.1:5, stirring at the temperature of 25 ℃ at the speed of 3500r/min for 1.5h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 40 ℃, preserving the heat for 6 hours, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
Example 2:
the method comprises the following steps:
quantitatively taking out a water-based polyether monomer, a water-based dispersant, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by the preparation of the water-based polyurethane A material, wherein the mass ratio of the components is as follows: 70:0.75:0.3:0.75:0.2:0.5:12.5:0.5:0, pouring the mixture into a stirring kettle, and stirring at the temperature of 25 ℃ at the speed of 2000r/min for 40min to obtain a waterborne polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, the polyphenyl polymethylene polyisocyanate, the deionized water and the cosolvent which are needed for preparing the waterborne polyurethane B material, wherein the mass ratio is as follows: 2:2:4:2, pouring the waterborne polyurethane A prepared in the step one into a stirring kettle, and immediately pouring diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and a cosolvent, wherein the overall weight ratio of the waterborne polyurethane A to the waterborne polyurethane B to the UV additive to the deionized water is 2:1:0.1:5, stirring at the temperature of 25 ℃ at the speed of 3500r/min for 2.0h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 40 ℃, preserving the heat for 6 hours, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
Example 3:
the method comprises the following steps:
quantificationally taking out a water-based polyether monomer, a water-based dispersing agent, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by preparing a water-based polyurethane A material, wherein the mass ratio of the components is as follows: 80:1:0.5:1:0.3:1:15:1:0, pouring the mixture into a stirring kettle, and stirring at the temperature of 25 ℃ at the speed of 3000r/min for 40min to obtain a waterborne polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, the polyphenyl polymethylene polyisocyanate, the deionized water and the cosolvent which are needed for preparing the waterborne polyurethane B material, wherein the mass ratio is as follows: 2:2:4:2, pouring the waterborne polyurethane A prepared in the step one into a stirring kettle, and immediately pouring diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and a cosolvent, wherein the overall weight ratio of the waterborne polyurethane A to the waterborne polyurethane B to the UV additive to the deionized water is 2:1:0.1:5, stirring at the temperature of 25 ℃ at the speed of 4000r/min for 2.0h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 40 ℃, preserving the heat for 6 hours, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
Example 4:
quantificationally taking out a water-based polyether monomer, a water-based dispersing agent, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by preparing a water-based polyurethane A material, wherein the mass ratio of the components is as follows: 60:0.5:0.2:0.5:0.1:0.2:10:0.1:0, pouring the mixture into a stirring kettle, and stirring at the temperature of 30 ℃ at the speed of 3000r/min for 60min to obtain a waterborne polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and cosolvent required by preparing the waterborne polyurethane B material, wherein the mass ratio is as follows: 1:3:4:2, pouring the waterborne polyurethane A prepared in the step one into a stirring kettle, and immediately pouring diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and a cosolvent, wherein the overall weight ratio of the waterborne polyurethane A to the waterborne polyurethane B to the UV additive to the deionized water is 6:1:0.3:5, stirring at the temperature of 30 ℃ at the speed of 3500r/min for 2.0h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 50 ℃, preserving the heat for 12 hours, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. A formula of a waterborne polyurethane high-performance UV-resistant finish paint is characterized in that: the formula of the waterborne polyurethane high-performance UV-resistant finish paint comprises the following raw materials: the water-based polyurethane comprises a water-based polyurethane material A, a water-based polyurethane material B, a UV additive and deionized water, wherein the water-based polyurethane material A comprises the following components in percentage by weight: 60-80% of water-based polyether monomer, 0.5-1% of water-based dispersant, 0.2-0.5% of water-based flatting agent, 0.5-1% of thickening agent, 0.1-0.3% of defoaming agent, 0.2-1% of film-forming assistant, 10-15% of filler, 0.1-1% of pH regulator and 0-10% of pigment, wherein the water-based polyurethane B material comprises the following components in percentage by weight: 20% of diphenylmethane diisocyanate, 20-60% of polyphenyl polymethylene polyisocyanate, 10-40% of deionized water and 10-20% of cosolvent, wherein the preparation process of the formula of the waterborne polyurethane high-performance anti-UV finish paint comprises the following steps:
the method comprises the following steps:
quantitatively taking out a water-based polyether monomer, a water-based dispersant, a water-based flatting agent, a thickening agent, a defoaming agent, a film-forming assistant, a filler, a pH regulator and a pigment which are required by the preparation of the water-based polyurethane A material, pouring the mixture into a stirring kettle, and stirring at the temperature of 25-30 ℃ at the speed of more than or equal to 2000r/min for 40-60min to obtain the water-based polyurethane A material;
step two:
quantifying and taking out the diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and cosolvent required by the preparation of the waterborne polyurethane B material, then pouring the waterborne polyurethane A material prepared in the step one into a stirring kettle, immediately pouring the diphenylmethane diisocyanate, polyphenyl polymethylene polyisocyanate, deionized water and cosolvent into the stirring kettle, and stirring at the temperature of 25-30 ℃ at the speed of 3500-4000r/min for 1.5-2.0h;
step three:
and after the stirring in the step two is finished, raising the temperature of the stirring kettle to 40-50 ℃, preserving the heat for 6-12h, and naturally cooling to room temperature after the heat preservation time is finished to obtain the waterborne polyurethane high-performance anti-UV finish paint.
2. The waterborne polyurethane high-performance UV-resistant finishing coat formula as claimed in claim 1, is characterized in that: the overall weight ratio of the aqueous polyurethane A material to the aqueous polyurethane B material to the UV additive to the deionized water is 2-6:1:0.1-0.3:5.
3. the waterborne polyurethane high-performance UV-resistant finishing coat formula as claimed in claim 1, is characterized in that: the waterborne polyurethane A is prepared from a waterborne dispersing agent which is polyethylene glycol type polyol, a waterborne flatting agent which is polyether modified siloxane, a thickening agent which is polyether polyurethane, a defoaming agent which is mineral oil containing hydrophobic silicon dioxide, a film-forming assistant which is ethylene glycol phenyl ether or 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, and fillers which are modified kaolin and nano-scaleAl 2 O 3 And SiO 2 One or more of the pH regulator and ammonia water.
4. The waterborne polyurethane high-performance UV-resistant finishing coat formula as claimed in claim 1, is characterized in that: the cosolvent is propylene glycol methyl ether acetate or ethyl acetate.
5. The waterborne polyurethane high-performance UV-resistant finish paint formula according to claim 1, is characterized in that: the UV additive is 2-hydroxy-4-n-octoxy benzophenone or 3, 5-di-tert-butyl-4-hydroxybenzoic acid n-hexadecyl ester.
CN202110628657.2A 2021-06-07 2021-06-07 Formula of waterborne polyurethane high-performance anti-UV finish paint Pending CN115505324A (en)

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CN202110628657.2A CN115505324A (en) 2021-06-07 2021-06-07 Formula of waterborne polyurethane high-performance anti-UV finish paint

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CN202110628657.2A CN115505324A (en) 2021-06-07 2021-06-07 Formula of waterborne polyurethane high-performance anti-UV finish paint

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060052176A (en) * 2004-10-12 2006-05-19 바이엘 머티리얼사이언스 아게 Aqueous foam coating with soft-feel effect
CN102443345A (en) * 2011-10-27 2012-05-09 北京东方雨虹防水技术股份有限公司 Aqueous polyurethane wall paint and preparation method thereof
CN104629607A (en) * 2015-02-05 2015-05-20 林伊铭 Environmental-friendly flame-retardant waterproof aqueous polyurethane coating and preparation method thereof
CN108624222A (en) * 2018-06-01 2018-10-09 合肥展游软件开发有限公司 A kind of wall covering with radiation protection corrosion resistance
CN112521848A (en) * 2020-12-29 2021-03-19 安徽酉阳防水科技有限公司 High-performance polyurethane water-based waterproof coating
CN112708340A (en) * 2020-12-29 2021-04-27 江苏雨中情防水材料有限责任公司 Anti-sagging single-component polyurethane waterproof coating capable of being sprayed and constructed

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060052176A (en) * 2004-10-12 2006-05-19 바이엘 머티리얼사이언스 아게 Aqueous foam coating with soft-feel effect
CN102443345A (en) * 2011-10-27 2012-05-09 北京东方雨虹防水技术股份有限公司 Aqueous polyurethane wall paint and preparation method thereof
CN104629607A (en) * 2015-02-05 2015-05-20 林伊铭 Environmental-friendly flame-retardant waterproof aqueous polyurethane coating and preparation method thereof
CN108624222A (en) * 2018-06-01 2018-10-09 合肥展游软件开发有限公司 A kind of wall covering with radiation protection corrosion resistance
CN112521848A (en) * 2020-12-29 2021-03-19 安徽酉阳防水科技有限公司 High-performance polyurethane water-based waterproof coating
CN112708340A (en) * 2020-12-29 2021-04-27 江苏雨中情防水材料有限责任公司 Anti-sagging single-component polyurethane waterproof coating capable of being sprayed and constructed

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* Cited by examiner, † Cited by third party
Title
吴蓁等, 同济大学出版社 *

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Application publication date: 20221223