CN115501813A - Device and method for preparing novel dosage form pesticide - Google Patents

Device and method for preparing novel dosage form pesticide Download PDF

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Publication number
CN115501813A
CN115501813A CN202211191843.5A CN202211191843A CN115501813A CN 115501813 A CN115501813 A CN 115501813A CN 202211191843 A CN202211191843 A CN 202211191843A CN 115501813 A CN115501813 A CN 115501813A
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China
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pesticide
defect
cavity
side wall
nozzle
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CN202211191843.5A
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CN115501813B (en
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张贵森
马涛
郭慧玲
王勇
聂苗苗
张宝俊
程永
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Shanxi Agricultural University
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Shanxi Agricultural University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a device and a method for preparing a novel pesticide formulation, and the device comprises a preparation module, a flow dividing module, a detection module and a signal connection module, wherein the preparation module comprises a drying cavity, a first nozzle, a second nozzle, a first storage tank and a second storage tank, a first mounting hole and a second mounting hole are symmetrically formed in two side walls of the drying cavity, the first nozzle is mounted on the first mounting hole, the second nozzle is mounted on the second mounting hole, the inlet end of the first nozzle is connected with one end of a first feeding pipe in a matching manner, the other end of the first feeding pipe is connected with the first storage tank in a matching manner, a first material pumping pump is arranged on the first feeding pipe, and the inlet end of the second nozzle is connected with one end of the second feeding pipe in a matching manner.

Description

Device and method for preparing novel pesticide
Technical Field
The invention relates to the technical field of pesticide preparation equipment, in particular to a device and a method for preparing a novel pesticide.
Background
Granular pesticide is a novel granular pesticide preparation, and is gradually applied to the field of agricultural control because of the advantages of good settleability, convenient application, labor and time saving, small drift, light environmental pollution, long residual life and the like in the application process. The production method of granular pesticide includes spray granulation, suspension granulation, extrusion granulation, high-strength mixing granulation, fluidized bed granulation, etc. Most of the existing spray granulation equipment pumps mother liquor (pesticide stock solution) to an atomizing nozzle in a drying cavity through a pressure pump, and heated air is introduced into the drying cavity at the same time, so that atomized mother liquor particles are continuously fluidized, dried and grown into required particle sizes and then discharged from a discharge port below the drying cavity to form granular pesticide. The spray granulation equipment has many defects, one is that the mother liquor can not carry a carrier in the preparation process, so that the strength of the finished granular pesticide is low, and pesticide particles collide with the inner wall of a drying cavity in the drying granulation process, so that the pesticide particles are damaged, and the quality of the finished pesticide particles is directly influenced; secondly, the spray granulation equipment does not have the functions of on-line monitoring and intelligent adjustment of processing parameters in the granulation process, so that a large quantity of unqualified products appear, and serious economic loss is caused.
Disclosure of Invention
The invention overcomes the defects of the prior art and provides a device and a method for preparing a novel dosage form pesticide.
In order to achieve the aim, the invention adopts the technical scheme that:
the invention discloses a device for preparing a novel pesticide, which comprises a preparation module, a shunting module, a detection module and a signal connection module, wherein the preparation module is used for preparing a pesticide;
the preparation module comprises a drying cavity, a first nozzle, a second nozzle, a first storage tank and a second storage tank, wherein a first mounting hole and a second mounting hole are symmetrically formed in two side walls of the drying cavity, the first nozzle is mounted on the first mounting hole, the second nozzle is mounted on the second mounting hole, the inlet end of the first nozzle is connected with one end of a first feeding pipe in a matched mode, the other end of the first feeding pipe is connected with the first storage tank in a matched mode, a first pumping pump is arranged on the first feeding pipe, the inlet end of the second nozzle is connected with one end of a second feeding pipe in a matched mode, the other end of the second feeding pipe is connected with the second storage tank in a matched mode, and a second pumping pump is arranged on the second feeding pipe; the first storage tank is used for storing a pesticide stock solution, and the second storage tank is used for storing a powdery carrier;
the top of the drying cavity is connected with a sealing cover in a matching manner, the bottom of the sealing cover is provided with a temperature sensor, and the temperature sensor is used for detecting temperature information in the drying cavity;
the flow dividing module comprises a flow dividing hopper, the top of the flow dividing hopper is connected with the bottom of the drying cavity in a matching manner, the bottom of the flow dividing hopper is connected with a flow dividing bin in a matching manner, a first driving motor is arranged on the flow dividing bin, the output end of the first driving motor is connected with a rotating shaft in a matching manner, a spiral blade is arranged on the rotating shaft, and a discharge hole is formed in the flow dividing bin;
the detection module comprises a conveyor belt, and the conveyor belt is connected with the discharge port.
Further, in a preferred embodiment of the present invention, the side wall of the drying chamber is a hollow structure, and includes a first outer side wall, a first inner side wall, and a first cavity, the first cavity is formed between the first outer side wall and the first inner side wall, and a plurality of retractable first adjusting rods are disposed between the first outer side wall and the first inner side wall, one end of each first adjusting rod is connected to the first outer side wall in a matching manner, the other end of each first adjusting rod is connected to the first inner side wall in a matching manner, the first outer side wall is made of a hard alloy material, and the first inner side wall is made of a soft leather material.
Further, in a preferred embodiment of the present invention, the first feeding pipe is connected with a regulating pipeline, a pipe wall of the regulating pipeline is a hollow structure, and includes a second outer sidewall, a second inner sidewall, and a second cavity, the second cavity is formed between the second outer sidewall and the second inner sidewall, a plurality of retractable second adjusting rods are disposed between the second outer sidewall and the second inner sidewall, one end of each second adjusting rod is connected to the second outer sidewall in a matching manner, the other end of each second adjusting rod is connected to the second inner sidewall in a matching manner, the second outer sidewall is made of a hard alloy material, and the second inner sidewall is made of a soft leather material.
Further, in a preferred embodiment of the present invention, an air supply pipe is disposed on the second outer sidewall, the air supply pipe penetrates through the second outer sidewall and extends into the second cavity, and a micro air pump is disposed on the air supply pipe.
Further, in a preferred embodiment of the present invention, the preparation module further includes a gas heater, an input end of the gas heater is connected to one end of a gas outlet pipe, the other end of the gas outlet pipe is connected to the first outer side wall and extends into the first cavity, an output end of the gas heater is connected to one end of a gas inlet pipe, the other end of the gas inlet pipe is connected to the first outer side wall and extends into the first cavity, and the gas outlet pipe and the gas inlet pipe are both provided with a suction pump.
Further, in a preferred embodiment of the present invention, a support frame is disposed on the conveyor belt, a second driving motor is disposed on the support frame, an output end of the second driving motor is connected to a threaded lead screw in a matching manner, a sliding block is connected to the threaded lead screw in a matching manner, a telescopic cylinder is fixedly mounted on the sliding block, and an output end of the telescopic cylinder is fixedly connected to the industrial camera.
Further, in a preferred embodiment of the present invention, the signal connection module can be in signal connection with the detection module and the control system of the preparation module, and the detection result generated by the detection module can be obtained through the signal connection module, and the detection result is fed back to the control system of the preparation module, so that the preparation module can adjust the processing parameters according to the detection result.
Further, in a preferred embodiment of the present invention, an air pressure sensor is disposed in the second cavity, the air pressure sensor is configured to detect an air pressure value inside the second cavity, and the air pressure sensor can feed back the detected air pressure value to a control system of the detection module, so that the detection module adjusts the expansion amount of the second adjustment rod according to the air pressure value inside the second cavity.
The invention also discloses a control method of the device for preparing the novel pesticide, which is applied to any one of the devices for preparing the novel pesticide, and comprises the following steps:
establishing a defect recognition model based on a neural network, and importing pre-trained defect image information into the defect recognition model for training to obtain a trained defect recognition model;
acquiring image information of the pesticide product to be detected on the conveyor belt through an industrial camera within a preset time;
importing the image information into the trained defect recognition model for recognition, recognizing whether a first preset defect and a second preset defect exist in the image information, and obtaining first preset defect data and second preset defect data; wherein the first preset defect is a bonding and hollow defect, and the second preset defect is a scorching and crushing defect;
calculating a first defect proportion value based on the first preset defect data, and calculating a second defect proportion value based on the second preset defect data;
judging whether the first defect proportion value and the second defect proportion value are larger than a preset threshold value or not;
and if so, adjusting the processing parameters of the preparation module based on the first defect proportion value and the second defect proportion value.
Further, in a preferred embodiment of the present invention, if the defect ratio is greater than the first defect ratio, the method for adjusting the processing parameters of the preparation module based on the first defect ratio and the second defect ratio specifically includes the following steps:
if the first defect proportion value is larger than a preset threshold value, acquiring first temperature information in the drying cavity through a temperature sensor, and judging whether the first temperature information is within a preset range value;
if the first temperature information is within the preset range value, the micro air pump is controlled to be started, external air is pumped into the second cavity through the micro air pump, the second adjusting rod is made to extend, the pressure of the pesticide stock solution in the first feeding pipe is increased, and the spraying speed of the pesticide stock solution in the first nozzle is increased;
if the first temperature information is not within the preset range value, increasing the heating power of the gas heater, and further increasing the drying temperature in the drying cavity;
if the second defect proportion value is larger than a preset threshold value, acquiring second temperature information in the drying cavity through a temperature sensor, and judging whether the second temperature information is within a preset range value;
if the second temperature information is within the preset range value, the micro air pump is controlled to be started, air in the second cavity is pumped out of the second cavity through the micro air pump, so that the second adjusting rod is shortened, the pressure of the pesticide stock solution in the first feeding pipe is reduced, and the spraying speed of the pesticide stock solution in the first nozzle is reduced;
and if the first temperature information is not within the preset range value, reducing the heating power of the gas heater, and further reducing the drying temperature in the drying cavity.
The invention solves the technical defects in the background technology, and has the following beneficial effects: granulation is carried out to the dry granulation's of STREAMING mode about adopting, and the high turbulence of striking face and very big alternate relative speed provide splendid transfer condition for pesticide stoste can fuse with the carrier fast, makes the pesticide granule that makes carry on the carrier, has improved its intensity and hardness, possesses higher anti crushing performance, does benefit to the transportation more and preserves. Because the material characteristic of first inside wall and the gaseous cushioning effect in the first cavity can play the buffering guard action to the pesticide granule for the pesticide granule is difficult consequently collided damaged, improvement pesticide granule off-the-shelf quality and yields that can to a great extent. Can discern the defect information of pesticide granule through detection module, and then generate corresponding testing result, then feed back corresponding testing result to the preparation module on through signal connection module for the processing parameter can be adjusted according to the testing result to the preparation module, has realized on-line monitoring and intelligent regulation's function, and then avoids appearing the condition of big batch defective products, is applicable to in the large-scale unmanned automated production workshop of supervising.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings of the embodiments can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic view of a first perspective structure of the present device;
FIG. 2 is a perspective view of the device from a second perspective;
FIG. 3 is a schematic view of the installation positions of the first nozzle and the second nozzle;
FIG. 4 is a schematic diagram of a cross-sectional structure of a drying chamber;
FIG. 5 is a schematic view of the installation position of the diversion hopper;
FIG. 6 is a schematic structural diagram of a shunting module;
FIG. 7 is a schematic view of the installation positions of the air outlet pipe and the air inlet pipe;
FIG. 8 is a schematic view of a vertical cross-section of a conditioning duct;
FIG. 9 is a schematic structural diagram of a detection module;
the reference numerals are explained below: 101. a drying chamber; 102. a first nozzle; 103. a second nozzle; 104. a first material storage tank; 105. a second material storage tank; 106. a first feeding pipe; 107. a first material pumping pump; 108. a second feed tube; 109. a second pump; 201. a first outer side wall; 202. a first inner side wall; 203. a first cavity; 204. a first adjusting lever; 205. a gas heater; 206. an air outlet pipe; 207. an air inlet pipe; 208. an air pump; 209. a sealing cover; 301. a flow distributing hopper; 302. a flow distribution bin; 303. a first drive motor; 304. a rotating shaft; 305. a helical blade; 306. a discharge port; 307. a conveyor belt; 308. a support frame; 309. a second drive motor; 401. a threaded lead screw; 402. a slider; 403. a telescopic cylinder; 404. an industrial camera; 405. regulating and controlling a pipeline; 406. a second exterior sidewall; 407. a second inner side wall; 408. a second cavity; 409. a second adjusting lever; 501. an air supply duct; 502. a miniature air pump.
Detailed Description
In order that the above objects, features and advantages of the present invention can be more clearly understood, the present invention will be further described in detail with reference to the accompanying drawings and the detailed description, wherein the drawings are simplified schematic drawings and only the basic structure of the present invention is illustrated schematically, so that only the structure related to the present invention is shown, and it is to be noted that the embodiments and features of the embodiments in the present application can be combined with each other without conflict.
In the description of the present application, it is to be understood that the terms "center," "longitudinal," "lateral," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like are used in the orientation or positional relationship indicated in the drawings for convenience in describing the present application and for simplicity in description, and are not intended to indicate or imply that the referenced devices or elements must have a particular orientation, be constructed in a particular orientation, and be operated in a particular manner, and are not to be considered limiting of the scope of the present application. Furthermore, the terms "first," "second," and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first," "second," etc. may explicitly or implicitly include one or more of that feature. In the description of the invention, the meaning of "a plurality" is two or more unless otherwise specified.
In the description of the present application, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present application can be understood by those of ordinary skill in the art through specific situations.
To facilitate an understanding of the invention, the invention will now be described more fully with reference to the accompanying drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
The invention discloses a device for preparing a novel pesticide, which comprises a preparation module, a shunting module, a detection module and a signal connection module, and is shown in figures 1 and 2.
As shown in fig. 3, the preparation module includes a drying chamber 101, a first nozzle 102, a second nozzle 103, a first storage tank 104, and a second storage tank 105, wherein two side walls of the drying chamber 101 are symmetrically provided with a first mounting hole and a second mounting hole, the first nozzle 102 is mounted on the first mounting hole, the second nozzle 103 is mounted on the second mounting hole, an inlet end of the first nozzle 102 is connected with one end of a first feeding pipe 106 in a matching manner, the other end of the first feeding pipe 106 is connected with the first storage tank 104 in a matching manner, a first pumping pump 107 is arranged on the first feeding pipe 106, an inlet end of the second nozzle 103 is connected with one end of a second feeding pipe 108 in a matching manner, the other end of the second feeding pipe 108 is connected with the second storage tank 105 in a matching manner, and a second pumping pump 109 is arranged on the second feeding pipe 108; the first storage tank 104 stores a stock solution of pesticide, and the second storage tank 105 stores a powdery carrier.
It should be noted that, the traditional spray granulator generally adopts up-down convection type drying granulation, and the process flow generally is that air is heated by a heater and then blown into the drying tower from the bottom end of the drying tower; the mother liquid (pesticide stock solution) is atomized into fog drops under the action of the atomizer, the fog drops enter the drying tower from the top end of the drying tower, and meet hot air blown into the drying tower in the drying tower to generate violent heat exchange, and the fog drops are dried into required granular powder after a very short time, are accumulated at the bottom of the tower and are discharged by a discharge valve. Although the drying rate is high, the finished product of the produced granules is prepared by directly passing through the drying mother liquor, the inside of the granules is not provided with a supporting carrier, the strength and the hardness are low, the crushing resistance is poor, the pulverization rate is high in the transportation process, the intangible loss is large, the transportation and the storage are not facilitated, and in the drying process inside the drying tower, the dried pesticide granules can be blown by hot air, so that the pesticide granules and the inside of the drying tower collide violently to cause the damage of the finished product of the pesticide granules, the quality of the finished product of the pesticide granules is directly influenced, and the yield of the finished product is low.
In the present invention, granulation is performed by convection drying granulation. Specifically, a stock solution of pesticide (mother liquor) is stored in a first storage tank 104, a powdery carrier is stored in a second storage tank 105, when pesticide particles need to be prepared, a first pumping pump 107 and a second pumping pump 109 are simultaneously started, the stock solution of pesticide stored in the first storage tank 104 is pumped out along a first feeding pipe 106 through the first pumping pump 107, and is conveyed to a first nozzle 102, and the stock solution of pesticide is accelerated, pressurized and atomized in the first nozzle 102 to form a high-speed fluid to be sprayed into a drying chamber 101; similarly, the carriers stored in the second storage tank 105 are pumped out along the second feeding pipe 108 by the second pumping pump 109 and are conveyed to the second nozzle 103, and the carriers form another high-speed fluid after accelerated pressurization in the second nozzle 103 and are simultaneously ejected into the drying chamber 101; at this time, the two high-speed fluids impact each other at the center of the drying cavity 101, and the two high-speed fluids perform amplitude-reducing oscillation movement back and forth, so as to form a highly turbulent impact surface, the impact surface is strongly mixed, and there is high-frequency pressure pulsation, and the axial velocity of the two high-speed fluids on the impact surface tends to zero and changes into radial flow, when the two high-speed fluids impact each other, the powdery carrier can penetrate into the pesticide raw liquid by inertia, and the relative velocity reaches a maximum value at the moment of starting penetration, ideally, the flow velocity can approach twice, so as to combine with the pesticide raw liquid to form mist drops, and when the mist drops carrying the carrier leave the impact surface, the mist drops are dried by the hot gas in the drying cavity 101 to form particles, and then fall onto the diversion bucket 301. Therefore, compared with the traditional up-down convection type drying granulation, the left-right convection type drying granulation is adopted for granulation, the high turbulence of the impact surface and the large phase-to-phase relative speed provide excellent transfer conditions, so that the pesticide stock solution and the carrier can be quickly fused, the prepared pesticide particles are carried with the carrier, the strength and the hardness of the carrier are improved, the crushing resistance is high, and the transportation and the storage are facilitated.
As shown in fig. 4, the side wall of the drying cavity 101 is a hollow structure, and includes a first outer side wall 201, a first inner side wall 202, and a first cavity 203, a first cavity 203 is formed between the first outer side wall 201 and the first inner side wall 202, and a plurality of telescopic first adjusting rods 204 are disposed between the first outer side wall 201 and the first inner side wall 202, one end of each first adjusting rod 204 is connected to the first outer side wall 201 in a matching manner, the other end of each first adjusting rod 204 is connected to the first inner side wall 202 in a matching manner, the first outer side wall 201 is made of a hard alloy material, and the first inner side wall 202 is made of a soft leather material.
As shown in fig. 2 and 7, the preparation module further includes a gas heater 205, an input end of the gas heater 205 is connected to one end of a gas outlet pipe 206, the other end of the gas outlet pipe 206 is connected to the first outer sidewall 201 and extends into the first cavity 203, an output end of the gas heater 205 is connected to one end of a gas inlet pipe 207, the other end of the gas inlet pipe 207 is connected to the first outer sidewall 201 and extends into the first cavity 203, and the gas outlet pipe 206 and the gas inlet pipe 207 are both provided with a suction pump 208.
It should be noted that the side wall of the drying cavity 101 is a hollow structure, and includes a first outer side wall 201, a first inner side wall 202, and a first cavity 203. On the one hand, in the process of drying and granulating, the air outlet pipe 206 and the air suction pump 208 on the air inlet pipe 207 are controlled to be started according to the preset operation power, after the air heater 205 heats the air, the hot air heated by the air heater 205 is conveyed into the first cavity 203 along the air inlet pipe 207 through the air suction pump 208 on the air inlet pipe 207, when the hot air enters into the first cavity 203, the hot air can enable the first inner side wall 202 to expand, and under the pushing of the first adjusting rod 204, the first cavity 203 between the first outer side wall 201 and the first inner side wall 202 forms a heat conduction space, the hot air inside the first cavity 203 can complete heat exchange with the air inside the drying cavity 101, so that the air inside the drying cavity 101 is heated into the hot air, the hot air with lower temperature inside the drying cavity 101 can be heated into the hot air, the hot air in the drying cavity 101 can dry the fog drops carrying carriers, the fog drops are dried to form pesticide particles, and when the hot air in the first cavity 203 completes heat exchange, the hot air can be pumped into the air outlet pipe 206, then the air can be heated into the fog drops carrying carriers, the pesticide particles, the finished product can be dried, the finished product drying and the finished product drying process can not be damaged by the hot air, and the hot air can be directly blown into the finished product drying tower, so that the finished product drying process can be improved. On the other hand, when hot gas enters into first cavity 203 inside, hot gas can make first inside wall 202 expand, and under the promotion of first regulation pole 204, still make first cavity 203 between first outside wall 201 and the first inside wall 202 form a buffer space, and because first inside wall 202 is soft cortex material, when the pesticide granule after the drying is in the in-process that drops and first inside wall 202 collision contact each other, because the material property characteristic of first inside wall 202 and the gaseous cushioning effect in first cavity 203, can play the buffering guard action to the pesticide granule, make the difficult consequently collision damage of pesticide granule, the off-the-shelf quality and the yields of improvement pesticide granule of ability to a great extent. In addition, in the in-service use process, the relative operating power of the air suction pump 208 on the air outlet pipe 206 and the air inlet pipe 207 can be adjusted, so that the first cavity 203 completes a plurality of contraction/expansion actions within a preset time, the material shaking motor is equivalent to the driving vibration, pesticide particles adhered to the inner wall of the drying cavity 101 are shaken down into the shunting bin 302, and the function of automatically cleaning the inner wall of the drying cavity 101 is realized.
The top cooperation of dry chamber 101 is connected with sealed lid 209, the bottom of sealed lid 209 is provided with temperature sensor, temperature sensor is used for detecting the inside temperature information of dry chamber 101.
It should be noted that the temperature information inside the drying chamber 101 can be obtained through the temperature sensor, and the number of the temperature sensors may be multiple, for example, four, and the temperature sensors are respectively arranged at the bottom of the sealing cover 209 in an array manner, so as to more accurately obtain the temperature information inside the drying chamber 101.
As shown in fig. 5 and 6, the flow dividing module includes a flow dividing hopper 301, the top of the flow dividing hopper 301 is connected to the bottom of the drying chamber 101 in a matching manner, the bottom of the flow dividing hopper 301 is connected to a flow dividing bin 302 in a matching manner, a first driving motor 303 is arranged on the flow dividing bin 302, an output end of the first driving motor 303 is connected to a rotating shaft 304 in a matching manner, a helical blade 305 is arranged on the rotating shaft 304, and a discharge hole 306 is arranged on the flow dividing bin 302.
The detection module comprises a conveyor belt 307, and the conveyor belt 307 is connected with the discharge hole 306.
It should be noted that, after the droplet is dry to form the pesticide granule, can drop to reposition of redundant personnel fill 301 in, then enter into reposition of redundant personnel storehouse 302 along reposition of redundant personnel fill 301 again, control first driving motor 303 at this moment and open, make first driving motor 303 drive rotation axis 304 rotatory, thereby it is rotatory to drive helical blade 305, under helical blade 305's drive, the pesticide granule can flow to discharge gate 306 one side along reposition of redundant personnel storehouse 302, then by discharge gate 306 flow to conveyer belt 307 on, so, can shunt the pesticide granule through reposition of redundant personnel module, make the comparatively scattered flow of pesticide granule to the conveyer belt 307 on, so that follow-up detection module shoots the detection to the pesticide granule finished product, improve the testing result reliability.
As shown in fig. 9, a support frame 308 is arranged on the conveyor belt 307, a second driving motor 309 is arranged on the support frame 308, an output end of the second driving motor 309 is connected with a threaded lead screw 401 in a matching manner, a sliding block 402 is connected on the threaded lead screw 401 in a matching manner, a telescopic cylinder 403 is fixedly mounted on the sliding block 402, and an output end of the telescopic cylinder 403 is fixedly connected with an industrial camera 404.
The signal connection module can be in signal connection with the detection module and the control system of the preparation module, the detection result generated by the detection module can be obtained through the signal connection module, and the detection result is fed back to the control system of the preparation module, so that the preparation module can adjust the processing parameters according to the detection result.
It should be noted that, after the finished pesticide particles are scattered and flow down onto the conveyor belt 307 from the discharge port 306, the conveyor belt 307 drives the finished pesticide particles to move to the position below the support frame 308, when the finished pesticide particles move to the position below the support frame 308, the image information of the finished pesticide particles is shot by the industrial camera 404, whether defects exist in the finished pesticide particles is identified according to the image information, and then the processing parameters of the preparation module are adjusted according to the corresponding defect proportion values, so that the function of intelligent adjustment is realized, and the defects in large batches are avoided. In addition, when the industrial camera 404 shoots the image information of the finished pesticide particles on the conveyor belt 307, the second driving motor 309 can be controlled to start, so that the second driving motor 309 drives the threaded screw 401 to rotate, the sliding block 402 can slide back and forth along the threaded screw 401, and the industrial camera 404 can move along the left and right directions of the conveyor belt 307; and start through control telescopic cylinder 403 to make telescopic cylinder 403 drive industrial camera 404 along the upper and lower direction removal of drive belt, so, just so, can make industrial camera 404 shoot the finished product image information of pesticide granule on conveyer belt 307 at different height position and different horizontal positions, in order to obtain the image information of different definition and different shooting scopes, can satisfy multiple detection conditions, application range is wider.
As shown in fig. 3 and 8, the first feeding pipe 106 is connected with a regulating pipe 405, a pipe wall of the regulating pipe 405 is of a hollow structure and includes a second outer side wall 406, a second inner side wall 407 and a second cavity 408, the second cavity 408 is formed between the second outer side wall 406 and the second inner side wall 407, a plurality of telescopic second adjusting rods 409 are disposed between the second outer side wall 406 and the second inner side wall 407, one end of each second adjusting rod 409 is connected with the second outer side wall 406 in a matching manner, the other end of each second adjusting rod 409 is connected with the second inner side wall 407 in a matching manner, the second outer side wall 406 is made of a hard alloy material, and the second inner side wall 407 is made of a soft leather material.
An air supply pipeline 501 is arranged on the second outer side wall 406, the air supply pipeline 501 penetrates through the second outer side wall 406 and extends into the second cavity 408, and a micro air pump 502 is arranged on the air supply pipeline 501.
It should be noted that the speed of the pesticide raw liquid sprayed out from the first nozzle 102 can be adjusted by adjusting the pipeline 405. Specifically, when the spraying speed of the pesticide raw liquid at the first nozzle 102 needs to be increased, a certain amount of external air is pumped into the second cavity 408 along the air feeding pipeline 501 through the micro air pump 502, after the certain amount of external air enters the second cavity 408, the second inner side wall 407 expands towards the side far away from the second outer side wall 406, and the second adjusting rod 409 extends to a certain length, so that the volume of a space formed between the second inner side wall 407 is reduced, at this time, when the pesticide raw liquid passes through the adjusting and controlling pipeline 405, the pesticide raw liquid is further compressed, the pressure of the pesticide raw liquid passing through the adjusting and controlling pipeline 405 is increased, and the spraying speed of the pesticide raw liquid at the first nozzle 102 is increased; on the contrary, when needs reduce the speed of pesticide stoste when first nozzle 102 blowout, take the external environment out through miniature air pump 502 to a certain amount of second cavity 408 inside air, take outside back out when a certain amount of second cavity 408 inside air, can make second inside wall 407 to be close to second outside wall 406 one side shrink, and make the second adjust pole 409 shorten to certain length, thereby increase the space volume that forms between the second inside wall 407, when the pesticide stoste was through regulation and control pipeline 405 this moment, the pesticide stoste just can further expand, and then reduce the pressure when the pesticide stoste passes through regulation and control pipeline 405, thereby reduce the speed of pesticide stoste when first nozzle 102 blowout. Therefore, the function of adjusting the spraying speed of the pesticide stock solution at the first nozzle 102 is realized through the adjusting and controlling pipeline 405, the structure is simple, the control is easy, the manufacturing cost is low, and the automatic spraying device is suitable for large-area automatic production workshops.
An air pressure sensor is arranged in the second cavity 408 and used for detecting the air pressure value inside the second cavity 408, and the air pressure sensor can feed the detected air pressure value back to a control system of the detection module, so that the detection module can adjust the expansion and contraction amount of the second adjusting rod 409 according to the air pressure value inside the second cavity 408.
It should be noted that, in the process of adjusting the speed of the pesticide stock solution sprayed out from the first nozzle 102 through the adjusting and controlling pipe 405, the gas pressure value inside the second cavity 408 is monitored in real time through the gas pressure sensor, and then the shrinkage or expansion of the second inner side wall 407 is converted according to the gas pressure value, so that the function of accurate adjustment and control is realized.
The invention also discloses a control method of the device for preparing the novel pesticide, which is applied to any one of the devices for preparing the novel pesticide and comprises the following steps:
establishing a defect recognition model based on a neural network, and importing pre-trained defect image information into the defect recognition model for training to obtain a trained defect recognition model;
acquiring image information of the pesticide product to be detected on the conveyor belt through an industrial camera within a preset time;
importing the image information into the trained defect recognition model for recognition, recognizing whether a first preset defect and a second preset defect exist in the image information, and obtaining first preset defect data and second preset defect data; wherein the first preset defect is a bonding and hollow defect, and the second preset defect is a scorching and crushing defect;
calculating a first defect proportion value based on the first preset defect data, and calculating a second defect proportion value based on the second preset defect data;
judging whether the first defect proportion value and the second defect proportion value are larger than a preset threshold value or not;
and if so, adjusting the processing parameters of the preparation module based on the first defect proportion value and the second defect proportion value.
It should be noted that the pre-trained defect image information includes image information of hollow, adhesive, charred, and broken defects. The first defect proportion value is the ratio of the total number of the bonded and hollow defective granular pesticides appearing in the image of the granular pesticide product shot by the industrial camera to the total number of all granular pesticides in the image during primary detection; the second defect proportion value is the ratio of the total number of burnt and broken defective granular pesticides appearing in the image of the granular pesticide product shot by the industrial camera to the total number of all granular pesticides in the image during one-time detection.
In the finished product of the obtained pesticide granules, defects such as adhesion, hollowness, scorching, and breakage may occur. In the process of forming the blank body, heat is transferred to the inside of the fog drop, and moisture diffuses from the surface of the internal phase of the fog drop and evaporates to the air, and in the process, if the moisture evaporation speed of the fog drop (namely the drying speed of the fog drop) is far less than the diffusion speed of water molecules from the external surface, the fog drop is easy to expand and deform, so that the particle pesticide has a defect of a hollow type, and the inside of the particle pesticide in the situation is not completely dried and falls onto the diversion bucket, and then the moisture in the particle pesticide expands towards the external surface of the particle pesticide, so that the external surface of the particle pesticide has higher humidity, and the particle pesticides are bonded with each other, so that the defect of a bonding type occurs, and the fundamental reason of the defects of hollowness and bonding is that the generated fog drops are too large or the drying temperature in the drying cavity is too low, so that the complete drying cannot be performed in time. On the contrary, if the evaporation rate of the water in the mist drops (i.e. the drying rate of the mist drops) is much higher than the diffusion rate of the water molecules from the outer surface, the water on the mist drops is evaporated rapidly, and before the granular pesticide falls out of the drying cavity, the water in the granular pesticide is evaporated excessively, so that the defects of the types of scorching and crushing are caused, and the root cause of the defects of the types of scorching and crushing is caused by that the water in the mist drops is evaporated too fast in the drying cavity because the generated mist drops are too small or the drying temperature in the drying cavity is too high.
Firstly, establishing a defect recognition model in advance through a neural network, and then importing pre-trained defect image information into the defect recognition model for training to obtain a trained defect recognition model; then shooting images of the pesticide product to be detected on one or more conveyor belts by an industrial camera within a preset time; the images are led into a trained defect recognition model for recognition, so that whether a first preset defect and a second preset defect exist in the shot images or not is recognized, the number of the corresponding defects is calculated, and then a first defect proportion value and a second defect proportion value are calculated; then judging whether the first defect proportion value and the second defect proportion value are larger than a preset threshold value or not; and if so, adjusting the processing parameters of the preparation module based on the first defect proportion value and the second defect proportion value.
Further, in a preferred embodiment of the present invention, if the defect ratio is greater than the first defect ratio, the method for adjusting the processing parameters of the preparation module based on the first defect ratio and the second defect ratio specifically includes the following steps:
if the first defect proportion value is larger than a preset threshold value, acquiring first temperature information in the drying cavity through a temperature sensor, and judging whether the first temperature information is within a preset range value;
if the first temperature information is within the preset range value, the micro air pump is controlled to be started, external air is pumped into the second cavity through the micro air pump, the second adjusting rod is made to extend, the pressure of the pesticide stock solution in the first feeding pipe is increased, and the spraying speed of the pesticide stock solution in the first nozzle is increased;
if the first temperature information is not within the preset range value, increasing the heating power of the gas heater, and further increasing the drying temperature in the drying cavity;
if the second defect proportion value is larger than a preset threshold value, acquiring second temperature information in the drying cavity through a temperature sensor, and judging whether the second temperature information is within a preset range value;
if the second temperature information is within the preset range value, the micro air pump is controlled to be started, air in the second cavity is pumped out of the second cavity through the micro air pump, so that the second adjusting rod is shortened, the pressure of the pesticide stock solution in the first feeding pipe is reduced, and the spraying speed of the pesticide stock solution in the first nozzle is reduced;
and if the first temperature information is not within the preset range value, reducing the heating power of the gas heater, and further reducing the drying temperature in the drying cavity.
In the right-left convection drying granulation method, the reason why the mist is too small is that the velocity of spraying the raw pesticide solution from the first nozzle is too high, so that the kinetic energy carried by the raw pesticide solution when the raw pesticide solution collides with the carrier on the collision surface is too high, so that the raw pesticide solution on the collision surface and the carrier keep high flow velocity after the collision direction is changed, and further the contact time of the raw pesticide solution and the carrier is short, and the generated mist is too small.
On the contrary, the reason that the fog drops are too big is that the kinetic energy carried by the pesticide stock solution when the impact surface impacts the carrier is too small due to the fact that the spraying speed of the pesticide stock solution at the first nozzle is too small, so that the pesticide stock solution on the impact surface and the carrier keep a low flow speed after the impact direction is changed, the contact time of the pesticide stock solution and the carrier is long, the generated fog drops are too big, and therefore when the fog drops are too big, the diameter of the fog drops can be reduced by improving the spraying speed of the pesticide stock solution at the first nozzle.
Therefore, in the invention, if the first defect proportion value is larger than the preset threshold value, the first temperature information in the drying cavity is obtained through the temperature sensor, and whether the first temperature information is within the preset range value is judged; if the second adjusting rod is located, the reason that the hollow is caused and the bonding defect is too much is not caused by too low drying temperature but caused by too large fog drops, the first detection result is generated at the moment, the first detection result is fed back to the control system of the preparation module through the signal connection module, the control system of the preparation module controls the micro air pump to be started at the moment, and the external air is pumped into the second cavity through the micro air pump, so that the second adjusting rod extends, the pressure of the pesticide stock solution in the first feeding pipe is increased, the spraying speed of the pesticide stock solution at the first nozzle is increased, the diameter of the fog drops is reduced, and the generation of the hollow and bonding defects is reduced. If not, the reason that the hollow and bonding defects are too much is caused by too low drying temperature, a second detection result is generated at the moment, the second detection result is fed back to the control system of the preparation module through the signal connection module, and the control system of the preparation module increases the heating power of the gas heater, so that the heat exchange capacity of hot gas in the first cavity is improved, the drying temperature in the drying cavity is further improved, and the generation of the hollow and bonding defects is further reduced.
And if the second defect proportion value is larger than a preset threshold value, acquiring second temperature information in the drying cavity through a temperature sensor, and judging whether the second temperature information is within a preset range value. If the second cavity adjusting rod is located, the third detection result is generated at the moment, the third detection result is fed back to the control system of the preparation module through the signal connection module, the control system of the preparation module controls the micro air pump to be started at the moment, air in the second cavity is pumped out of the second cavity through the micro air pump, the second adjusting rod is shortened, the pressure of the pesticide stock solution in the first feeding pipe is reduced, the spraying speed of the pesticide stock solution at the first nozzle is reduced, the diameter of the fog drops is increased, and the generation of scorching and breaking defects is reduced. If not, the reason that the burning and crushing defects are too much caused by too high drying temperature is shown, a fourth detection result is generated at the moment, the fourth detection result is fed back to the control system of the preparation module through the signal connection module, and the control system of the preparation module reduces the heating power of the gas heater, so that the heat exchange capacity of hot gas in the first cavity is reduced, the drying temperature in the drying cavity is reduced, and the burning and crushing defects are reduced.
In conclusion, the invention can identify the defect information of pesticide particles through the detection module to generate a corresponding detection result, and then feed the corresponding detection result back to the preparation module through the signal connection module, so that the preparation module can adjust the processing parameters according to the detection result, the functions of online monitoring and intelligent adjustment are realized, the condition of large-scale defective products is avoided, and the invention is suitable for large-scale unmanned automatic production workshops.
In addition, the control method of the device for preparing the novel dosage form pesticide further comprises the following steps:
acquiring the limit collision momentum values of various types of carriers through a big data network, and establishing a database based on the limit collision momentum values of the various types of carriers; wherein the limit collision momentum value is a critical value that the carrier is damaged due to collision;
acquiring carrier type information of a current preparation process, and importing the carrier type information of the current preparation process into the database to obtain a preset limit collision momentum value of the carrier of the current preparation process;
acquiring pressure values of a first nozzle and a second nozzle of the current preparation process, and calculating an actual collision momentum value when the pesticide stock solution collides with the carrier based on the pressure values of the first nozzle and the second nozzle;
judging whether the actual collision momentum value is larger than a preset limit collision momentum value or not;
if the pressure of the pesticide raw liquid in the first feeding pipe is higher than the pressure of the pesticide raw liquid in the first feeding pipe, the micro air pump pumps air in the second cavity out of the second cavity, so that the second adjusting rod is shortened, the pressure of the pesticide raw liquid in the first feeding pipe is reduced, and the spraying speed of the pesticide raw liquid in the first nozzle is reduced.
It should be noted that, because the structures of different types of carriers are not consistent, and the extreme collision momentum values are also different, first, the extreme collision momentum values of various types of carriers can be obtained through a big data network, and a database is established based on the extreme collision momentum values of the various types of carriers; then, when in actual production, firstly obtaining the carrier type information used in the current preparation process, and then importing the carrier type used in the current preparation process into a database so as to obtain a preset limit collision momentum value; then, working pressure information on the first nozzle and the second nozzle is obtained through a pressure sensor, and an actual collision momentum value when the pesticide stock solution collides with the carrier is calculated; if the actual collision momentum value is larger than the preset limit collision momentum value, the air in the second cavity is pumped out of the second cavity through the miniature air pump, so that the second adjusting rod is shortened, the pressure of the pesticide stock solution in the first feeding pipe is reduced, the spraying speed of the pesticide stock solution at the first nozzle is reduced, the actual collision momentum value when the pesticide stock solution collides with the carrier is reduced, and the phenomenon that the carrier is damaged by collision of the pesticide stock solution and the carrier is avoided.
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow. It should be noted that various changes and modifications can be made by those skilled in the art without departing from the spirit of the invention, and these changes and modifications are all within the scope of the invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (10)

1. The utility model provides a device for preparing new dosage form pesticide, includes preparation module, reposition of redundant personnel module, detection module and signal connection module, its characterized in that:
the preparation module comprises a drying cavity, a first nozzle, a second nozzle, a first storage tank and a second storage tank, wherein a first mounting hole and a second mounting hole are symmetrically formed in two side walls of the drying cavity, the first nozzle is mounted on the first mounting hole, the second nozzle is mounted on the second mounting hole, the inlet end of the first nozzle is connected with one end of a first feeding pipe in a matched mode, the other end of the first feeding pipe is connected with the first storage tank in a matched mode, a first material pumping pump is arranged on the first feeding pipe, the inlet end of the second nozzle is connected with one end of a second feeding pipe in a matched mode, the other end of the second feeding pipe is connected with the second storage tank in a matched mode, and a second material pumping pump is arranged on the second feeding pipe; the first storage tank is internally stored with a pesticide stock solution, and the second storage tank is internally stored with a powdery carrier;
the top of the drying cavity is connected with a sealing cover in a matching manner, the bottom of the sealing cover is provided with a temperature sensor, and the temperature sensor is used for detecting temperature information in the drying cavity;
the flow distribution module comprises a flow distribution hopper, the top of the flow distribution hopper is connected with the bottom of the drying cavity in a matching manner, the bottom of the flow distribution hopper is connected with a flow distribution bin in a matching manner, a first driving motor is arranged on the flow distribution bin, the output end of the first driving motor is connected with a rotating shaft in a matching manner, a spiral blade is arranged on the rotating shaft, and a discharge hole is formed in the flow distribution bin;
the detection module comprises a conveyor belt, and the conveyor belt is connected with the discharge port.
2. The apparatus for preparing a new dosage form of pesticide according to claim 1, characterized in that: the lateral wall of drying chamber is hollow structure, including first lateral wall, first inside wall, first cavity, form first cavity between first lateral wall and the first inside wall, just be provided with the first regulation pole of a plurality of scalabilities between first lateral wall and the first inside wall, the first one end of adjusting the pole with first lateral wall cooperation is connected, the other end of first regulation pole with first inside wall cooperation is connected, first lateral wall is made by carbide material, first inside wall is made for soft cortex material.
3. The apparatus for preparing a new dosage form of pesticide according to claim 1, characterized in that: the first feeding pipe is connected with a regulating pipeline, the pipe wall of the regulating pipeline is of a hollow structure and comprises a second outer side wall, a second inner side wall and a second cavity, the second cavity is formed between the second outer side wall and the second inner side wall, a plurality of telescopic second regulating rods are arranged between the second outer side wall and the second inner side wall, one ends of the second regulating rods are connected with the second outer side wall in a matched mode, the other ends of the second regulating rods are connected with the second inner side wall in a matched mode, the second outer side wall is made of hard alloy materials, and the second inner side wall is made of soft leather materials.
4. The apparatus for preparing a new dosage form of pesticide according to claim 3, characterized in that: an air supply pipeline is arranged on the second outer side wall, penetrates through the second outer side wall and extends into the second cavity, and a miniature air pump is arranged on the air supply pipeline.
5. The apparatus for preparing a pesticide in a new dosage form as claimed in claim 2, wherein: the preparation module further comprises a gas heater, the input end of the gas heater is connected with one end of the gas outlet pipe, the other end of the gas outlet pipe is connected with the first outer side wall and stretches into the first cavity, the output end of the gas heater is connected with one end of the gas inlet pipe, the other end of the gas inlet pipe is connected with the first outer side wall and stretches into the first cavity, and the gas outlet pipe and the gas inlet pipe are both provided with a gas suction pump.
6. The apparatus for preparing a pesticide in a new dosage form as claimed in claim 1, wherein: the camera comprises a conveying belt, and is characterized in that a supporting frame is arranged on the conveying belt, a second driving motor is arranged on the supporting frame, the output end of the second driving motor is connected with a threaded lead screw in a matched mode, a sliding block is connected on the threaded lead screw in a matched mode, a telescopic cylinder is fixedly mounted on the sliding block, and the output end of the telescopic cylinder is fixedly connected with an industrial camera.
7. The apparatus for preparing a pesticide in a new dosage form as set forth in claim 6, characterized in that: the signal connection module can be in signal connection with the detection module and the control system of the preparation module, the detection result generated by the detection module can be obtained through the signal connection module, and the detection result is fed back to the control system of the preparation module, so that the preparation module can adjust the processing parameters according to the detection result.
8. The apparatus for preparing a new dosage form of pesticide according to claim 3, characterized in that: the air pressure sensor is arranged in the second cavity and used for detecting the air pressure value in the second cavity, and the air pressure sensor can feed the detected air pressure value back to the control system of the detection module, so that the detection module can adjust the expansion and contraction amount of the second adjusting rod according to the air pressure value in the second cavity.
9. A control method of an apparatus for preparing a new formulation of pesticide, applied to the apparatus for preparing a new formulation of pesticide of any one of claims 1 to 8, comprising the steps of:
establishing a defect recognition model based on a neural network, and importing pre-trained defect image information into the defect recognition model for training to obtain a trained defect recognition model;
acquiring image information of the pesticide product to be detected on the conveyor belt through an industrial camera within a preset time;
importing the image information into the trained defect recognition model for recognition, recognizing whether a first preset defect and a second preset defect exist in the image information, and obtaining first preset defect data and second preset defect data; the first preset defect is a bonding and hollow defect, and the second preset defect is a scorching and crushing defect;
calculating a first defect proportion value based on the first preset defect data, and calculating a second defect proportion value based on the second preset defect data;
judging whether the first defect proportion value and the second defect proportion value are larger than a preset threshold value or not;
and if so, adjusting the processing parameters of the preparation module based on the first defect proportion value and the second defect proportion value.
10. The method for controlling the apparatus for preparing a pesticide in a new dosage form according to claim 9, wherein if the ratio is greater than the first defect ratio value, the method for controlling the apparatus for preparing a pesticide in a new dosage form adjusts the processing parameters of the preparation module based on the first defect ratio value and the second defect ratio value, and comprises the following steps:
if the first defect proportion value is larger than a preset threshold value, acquiring first temperature information in the drying cavity through a temperature sensor, and judging whether the first temperature information is within a preset range value;
if the first temperature information is within the preset range value, the micro air pump is controlled to be started, external air is pumped into the second cavity through the micro air pump, the second adjusting rod is made to extend, the pressure of the pesticide stock solution in the first feeding pipe is increased, and the spraying speed of the pesticide stock solution in the first nozzle is increased;
if the first temperature information is not within the preset range value, increasing the heating power of the gas heater, and further increasing the drying temperature in the drying cavity;
if the second defect proportion value is larger than a preset threshold value, acquiring second temperature information in the drying cavity through a temperature sensor, and judging whether the second temperature information is within a preset range value or not;
if the second temperature information is within the preset range value, the micro air pump is controlled to be started, air in the second cavity is pumped out of the second cavity through the micro air pump, so that the second adjusting rod is shortened, the pressure of the pesticide stock solution in the first feeding pipe is reduced, and the spraying speed of the pesticide stock solution in the first nozzle is further reduced;
if the first temperature information is not within the preset range value, the heating power of the gas heater is reduced, and then the drying temperature in the drying cavity is reduced.
CN202211191843.5A 2022-09-28 2022-09-28 Device and method for preparing novel pesticide Active CN115501813B (en)

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CA2096924A1 (en) * 1992-06-04 1993-12-05 Howard Littman Coating apparatus having opposed atomizing nozzles in a fluid bed column
CN104274320A (en) * 2013-07-11 2015-01-14 天士力制药集团股份有限公司 Dropping pill air cooling circulation device and dropping pill production line with air cooling circulation device
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