CN115446306A - Feeding and process preparation method of high-copper-content stainless steel powder metallurgy material - Google Patents

Feeding and process preparation method of high-copper-content stainless steel powder metallurgy material Download PDF

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Publication number
CN115446306A
CN115446306A CN202211209029.1A CN202211209029A CN115446306A CN 115446306 A CN115446306 A CN 115446306A CN 202211209029 A CN202211209029 A CN 202211209029A CN 115446306 A CN115446306 A CN 115446306A
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stainless steel
percent
steel powder
powder
main material
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王建国
乔永苹
陈健康
何春龙
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Dongguan Huanli Intelligent Technology Co ltd
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Dongguan Huanli Intelligent Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/103Metallic powder containing lubricating or binding agents; Metallic powder containing organic material containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content, which comprises the following preparation steps: mixing stainless steel powder and copper powder to obtain mixed powder; mixing polyformaldehyde, high-density polyethylene, ethylene-vinyl acetate copolymer, vinyl bis-stearamide, polypropylene wax micropowder and zinc stearate to prepare a high-molecular adhesive; carrying out zonal banburying on mixed powder formed by mixing stainless steel powder and copper powder as a main material and a high-molecular adhesive, and crushing and granulating the material after banburying processing is finished; putting the raw material particles into injection molding equipment, and molding by adopting an MIM injection mold in an injection molding manner; degreasing the injection molded product blank by an oxalic acid degreasing process; and sintering after degreasing is finished, and finally shaping the sintered product to obtain a finished product, thus finishing processing.

Description

Feeding and process preparation method of high-copper-content stainless steel powder metallurgy material
Technical Field
The invention belongs to the technical field of powder metallurgy materials, and relates to a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content.
Background
The invention is made on the basis of the conventional powder metallurgy feeding process technology, and because the copper content in the powder metallurgy material is generally less than or equal to 3 percent, the existing powder metallurgy stainless steel material has no sterilization and disinfection effects and can only achieve certain antirust effect. With the continuous development and application of stainless steel products in the fields of tableware, public health and furniture, the requirements of sterilization and disinfection on stainless steel products become the current mainstream requirements. Silver and copper, the two most popular inorganic antibacterial elements, have broad-spectrum antibacterial and antiviral abilities well known in the art, and have low toxicity to animal cells, and are common additives for preparing antibacterial materials. It was found that pure copper showed excellent antiviral efficiency against both SARS-CoV-2 and influenza A virus (H1N 1).
However, in the fields of tableware, public health and furniture, the stainless steel products are replaced by pure copper, so that the method has the disadvantages of high cost, low strength and poor corrosion resistance, and is impractical. Another method is to add copper to stainless steel in the form of plating or ion implantation to obtain the antibacterial effect. However, with this method, the deterioration of the surface coating significantly affects the antibacterial properties of the stainless steel, resulting in a limited service life. In order to solve the two limitations, copper powder and stainless steel powder are mixed according to a certain proportion, and a stainless steel test material with high copper content is prepared by using a powder metallurgy process. After continuous experiments, the culture solution containing various pathogens such as escherichia coli, H1N1 virus and the like is dripped on a test material, and the concentration of the residual virus is regularly observed. The experiment observation is carried out for 48 hours totally, and the result shows that the copper, the silver and the stainless steel are mixed according to different proportions, so that the copper-stainless steel mixed material with the mass fraction of 20 percent has ideal inactivation effect on various pathogens, and after the experiment is carried out for 6 hours, the virus is reduced to less than 0.01 percent, so that the inactivation on 99.99 percent of virus is realized.
Background art reference paper address: https:// pubmed.ncbi.nlm.nih.gov/34853550/.
In view of the above situation, the invention provides a stainless steel powder metallurgy material with high copper content and 20% of copper prepared by using a powder metallurgy technology and a preparation production process thereof. The antibacterial performance of the mixed material is effective for a long time, and even if the material is continuously damaged in the using process, the mixed material can also keep the killing effect on various pathogens for a long time, and the antirust capability of a salt spray test of more than 48H is realized. The existing powder metallurgy technology is used for mass production, the cost effect is very high, and the popularization and the use are convenient. The product can be used for disinfecting in the fields of tableware, public health, furniture and the like, and has more advantages and competitiveness.
Disclosure of Invention
In order to solve the technical problems, the invention adopts the following technical scheme:
a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content comprises the following preparation steps:
s1: mixing stainless steel powder and copper powder to obtain mixed powder;
s2: mixing polyformaldehyde, high-density polyethylene, ethylene-vinyl acetate copolymer, vinyl bis-stearamide, polypropylene wax micropowder and zinc stearate to prepare a high-molecular adhesive;
s3, carrying out partition banburying on mixed powder formed by mixing stainless steel powder and copper powder as a main material and a high-molecular adhesive, wherein the banburying time is 2H, and the partition temperatures are respectively as follows: the temperature of the first area is 160 +/-5 ℃, the temperature of the second area is 160 +/-5 ℃, the temperature of the third area is 160 +/-5 ℃, and the temperature of the fourth area is 200-210 ℃; crushing and granulating the materials after banburying processing;
s4: putting the raw material granules into injection molding equipment, and molding and processing in an injection molding mode by adopting an MIM injection mold;
s5: degreasing the injection molded product blank by an oxalic acid degreasing process;
s6: and finally, shaping the sintered pattern product to obtain a finished product, and finishing processing.
As a further scheme of the invention: stainless steel powders include, but are not limited to: one of SUS304, SUS316L, or SUS420 stainless steel powder.
As a further scheme of the invention: the mixing ratio of the stainless steel powder to the copper powder is as follows: 75-80% of stainless steel powder and 20-25% of copper powder.
As a further scheme of the invention: the mixing ratio of the main material of the mixed powder to the high-molecular adhesive is as follows: 91-96% of main material and 4-9% of high molecular adhesive.
As a further scheme of the invention: SUS304 stainless steel powder is adopted as the main material, and the mixing proportion is as follows: 80% SUS304 stainless steel powder and 20% copper powder;
and when SUS304 stainless steel powder is adopted as the main material, the mixing proportion of the polymer adhesive is as follows: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 95.758 percent of main material and 4.24 percent of high molecular adhesive.
As a further scheme of the invention: SUS316L stainless steel powder is adopted as the main material, and the mixing proportion is as follows: 80% of SUS316L stainless steel powder and 20% of copper powder;
and when SUS316L stainless steel powder is adopted as the main material, the mixing proportion of the high-molecular adhesive is as follows: 87.00 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.25 percent of vinyl bis stearamide, 1.50 percent of polypropylene wax micropowder and 0.50 percent of zinc stearate;
the mixing ratio of the main material to the high-molecular adhesive is as follows: 91.346% of main material and 8.65% of macromolecular adhesive.
As a further scheme of the invention: SUS420 stainless steel powder is adopted as the main material, and the mixing proportion is as follows: 80% of SUS420 stainless steel powder and 20% of copper powder;
and when SUS420 stainless steel powder is adopted as the main material, the mixing proportion of the high-molecular adhesive is as follows: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 92.563% of main material and 4.24% of high-molecular adhesive.
The invention has the beneficial effects that: the high-copper-content mixed stainless steel material prepared by the preparation process disclosed by the invention has long-term effective antibacterial performance, can keep killing effects on various pathogens for a long time even if the material is continuously damaged in the using process, and also realizes the antirust capacity of a salt spray test of more than 48H. The existing powder metallurgy technology is used for mass production, the cost effect is very high, and the popularization and the use are convenient. The product can be used for disinfection cost in the fields of tableware, public customs sanitation, furniture and the like, and has more advantages and competitiveness. The material and the process method can effectively improve the tableware environment and human environment.
Detailed Description
Technical solutions in the embodiments of the present application are clearly and completely described, and it should be understood that the described embodiments are only a part of the embodiments of the present application, and not all of the embodiments, and it should be understood that the present application is not limited to the example embodiments disclosed and described herein. All other embodiments obtained by a person of ordinary skill in the art based on the embodiments in the present application without making any creative effort belong to the protection scope of the present application.
In the embodiment of the invention, a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content comprises the following preparation steps:
s1: mixing stainless steel powder and copper powder to obtain mixed powder;
s2: mixing polyformaldehyde, high-density polyethylene, ethylene-vinyl acetate copolymer, vinyl bis-stearamide, polypropylene wax micropowder and zinc stearate to prepare a high-molecular adhesive;
s3, carrying out partition banburying on mixed powder formed by mixing stainless steel powder and copper powder as a main material and a high-molecular adhesive, wherein the banburying time is 2H, and the partition temperatures are respectively as follows: the temperature of the first area is 160 +/-5 ℃, the temperature of the second area is 160 +/-5 ℃, the temperature of the third area is 160 +/-5 ℃, and the temperature of the fourth area is 200-210 ℃; crushing and granulating the materials after banburying processing;
s4: putting the raw material granules into injection molding equipment, and molding and processing in an injection molding mode by adopting an MIM injection mold;
s5: degreasing the injection molded product blank by an oxalic acid degreasing process; the specific degreasing process parameters are as follows:
Figure BDA0003874448510000051
s6: putting the degreased product material into sintering equipment for sintering to form a pattern product corresponding to the pattern, wherein the specific sintering process parameters are as follows:
Figure BDA0003874448510000052
Figure BDA0003874448510000061
and finally, shaping the sintered product to obtain a finished product, and finishing the processing.
Further, the mixing ratio of the stainless steel powder and the copper powder is as follows: 75-80% of stainless steel powder and 20-25% of copper powder.
Further, the mixing ratio of the main material of the mixed powder and the high molecular adhesive is as follows: 91-96% of main material and 4-9% of high molecular adhesive.
The invention also provides three embodiment schemes, which specifically comprise the following steps:
the first embodiment is as follows:
in the embodiment, the stainless steel powder in the main material adopts stainless steel powder with the model of SUS304 as a mixed material of a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content; SUS304 stainless steel powder mixed with copper powder in a ratio of 80% to 20% copper powder;
in this embodiment, when SUS304 stainless steel powder is used as the main material, the polymer binder is mixed in the following ratio: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing ratio of the main material to the high-molecular adhesive is as follows: 95.758 percent of main material and 4.24 percent of high molecular adhesive;
the specific formula table is as follows:
Figure BDA0003874448510000071
Figure BDA0003874448510000081
the second embodiment: in the embodiment, the stainless steel powder in the main material adopts stainless steel powder with the model of SUS316L as a mixed material of the feeding and process preparation method of the stainless steel powder metallurgy material with high copper content; SUS316L stainless steel powder mixed with copper powder at a ratio of 80% to 20% copper powder;
in this embodiment, when SUS316L stainless steel powder is used as the main material, the mixing ratio of the polymer binder is: 87.00 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.25 percent of vinyl bis stearamide, 1.50 percent of polypropylene wax micropowder and 0.50 percent of zinc stearate;
the mixing ratio of the main material to the high-molecular adhesive is as follows: 91.346% of main material and 8.65% of macromolecular adhesive.
The specific formula table is as follows:
Figure BDA0003874448510000082
Figure BDA0003874448510000091
example two: in the embodiment, the stainless steel powder in the main material adopts stainless steel powder with the model of SUS420 as a mixed material of a feeding and process preparation method of a stainless steel powder metallurgy material with high copper content; SUS420 stainless steel powder with a mixing ratio of 80% to copper powder and 20% to copper powder;
in this embodiment, when SUS420 stainless steel powder is used as the main material, the polymer binder is mixed in the following ratio: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 92.563% of main material and 4.24% of high-molecular adhesive.
The specific formula table is as follows:
Figure BDA0003874448510000092
Figure BDA0003874448510000101
it is further noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element described by the phrase "comprising a. -" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present application. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the application. Thus, the present application is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (7)

1. A feeding and process preparation method of a stainless steel powder metallurgy material with high copper content is characterized by comprising the following preparation steps:
s1: mixing stainless steel powder and copper powder to obtain mixed powder;
s2: mixing polyformaldehyde, high-density polyethylene, ethylene-vinyl acetate copolymer, vinyl bis-stearamide, polypropylene wax micropowder and zinc stearate to prepare a high-molecular adhesive;
s3, carrying out partition banburying on mixed powder formed by mixing stainless steel powder and copper powder as a main material and a high-molecular adhesive, wherein the banburying time is 2H, and the partition temperatures are respectively as follows: the temperature of the first area is 160 +/-5 ℃, the temperature of the second area is 160 +/-5 ℃, the temperature of the third area is 160 +/-5 ℃, and the temperature of the fourth area is 200-210 ℃; crushing and granulating the materials after banburying processing;
s4: putting the raw material granules into injection molding equipment, and molding and processing in an injection molding mode by adopting an MIM injection mold;
s5: degreasing the injection molded product blank by an oxalic acid degreasing process;
s6: and finally, shaping the sintered pattern product to obtain a finished product, and finishing processing.
2. A method of feeding and preparing a high copper content stainless steel powder metallurgy material as claimed in claim 1 wherein, the stainless steel powder is selected from the group consisting of but not limited to: one of SUS304, SUS316L, or SUS420 stainless steel powder.
3. The feeding and process preparation method of the high copper content stainless steel powder metallurgy material according to claim 1, wherein the mixing ratio of the stainless steel powder and the copper powder is as follows: 75-80% of stainless steel powder and 20-25% of copper powder.
4. A feeding and process preparation method of a high copper content stainless steel powder metallurgy material according to claim 1, wherein the mixing ratio of the main material of the mixed powder and the high molecular binder is as follows: 91-96% of main material and 4-9% of high molecular adhesive.
5. A feeding and process preparation method of a stainless steel powder metallurgy material with high copper content according to claim 2, wherein SUS304 stainless steel powder is adopted as the main material, and the mixing ratio is as follows: 80% SUS304 stainless steel powder and 20% copper powder;
and when SUS304 stainless steel powder is adopted as the main material, the mixing proportion of the polymer adhesive is as follows: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis-stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 95.758 percent of main material and 4.24 percent of high molecular adhesive.
6. A feeding and process preparation method of stainless steel powder metallurgy material with high copper content as claimed in claim 2, wherein SUS316L stainless steel powder is adopted as main material, and the mixing ratio is: 80% of SUS316L stainless steel powder and 20% of copper powder;
and when SUS316L stainless steel powder is adopted as the main material, the mixing proportion of the high-molecular adhesive is as follows: 87.00 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.25 percent of vinyl bis-stearamide, 1.50 percent of polypropylene wax micro powder and 0.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 91.346% of main material and 8.65% of high molecular adhesive.
7. A feeding and process preparation method of a high copper content stainless steel powder metallurgy material according to claim 2, wherein SUS420 stainless steel powder is adopted as the main material, and the mixing ratio is: 80% SUS420 stainless steel powder and 20% copper powder;
and when SUS420 stainless steel powder is adopted as the main material, the mixing proportion of the high-molecular adhesive is as follows: 84.95 percent of polyformaldehyde, 8.00 percent of high-density polyethylene, 2.50 percent of ethylene-vinyl acetate copolymer, 2.50 percent of vinyl bis stearamide, 2.50 percent of polypropylene wax micropowder and 1.50 percent of zinc stearate;
the mixing proportion of the main material and the high-molecular adhesive is as follows: 92.563% of main material and 4.24% of high-molecular adhesive.
CN202211209029.1A 2022-09-30 2022-09-30 Feeding and process preparation method of high-copper-content stainless steel powder metallurgy material Pending CN115446306A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112453387A (en) * 2020-11-27 2021-03-09 深圳市日东科技发展有限公司 Powder metallurgy-based high-density stainless steel product formula and process thereof
US20210154924A1 (en) * 2018-08-27 2021-05-27 Hewlett-Packard Development Company, L.P. Binder agent
CN114000066A (en) * 2020-07-27 2022-02-01 香港大学 Antibacterial and antiviral copper-containing stainless steel and preparation and application thereof
CN114101657A (en) * 2021-11-12 2022-03-01 阳江市天骄家庭用品制造有限公司 Sterilized stainless steel feeding and cutting tool and preparation method thereof
CN114226716A (en) * 2021-12-24 2022-03-25 阳江市天骄家庭用品制造有限公司 Feed for preparing antibacterial stainless steel cutting tool, cutting tool and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210154924A1 (en) * 2018-08-27 2021-05-27 Hewlett-Packard Development Company, L.P. Binder agent
CN114000066A (en) * 2020-07-27 2022-02-01 香港大学 Antibacterial and antiviral copper-containing stainless steel and preparation and application thereof
CN112453387A (en) * 2020-11-27 2021-03-09 深圳市日东科技发展有限公司 Powder metallurgy-based high-density stainless steel product formula and process thereof
CN114101657A (en) * 2021-11-12 2022-03-01 阳江市天骄家庭用品制造有限公司 Sterilized stainless steel feeding and cutting tool and preparation method thereof
CN114226716A (en) * 2021-12-24 2022-03-25 阳江市天骄家庭用品制造有限公司 Feed for preparing antibacterial stainless steel cutting tool, cutting tool and preparation method thereof

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