CN115445533A - Dehydrogenation reactor of liquid organic hydrogen storage material - Google Patents
Dehydrogenation reactor of liquid organic hydrogen storage material Download PDFInfo
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- CN115445533A CN115445533A CN202211230753.2A CN202211230753A CN115445533A CN 115445533 A CN115445533 A CN 115445533A CN 202211230753 A CN202211230753 A CN 202211230753A CN 115445533 A CN115445533 A CN 115445533A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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Abstract
The invention relates to the technical field of hydrogen energy utilization, and discloses a dehydrogenation reactor of a liquid organic hydrogen storage material, which comprises: the preheating cavity and the catalytic dehydrogenation cavity are communicated with each other, and the preheating cavity is positioned on the upper side of the catalytic dehydrogenation cavity; the top of the preheating cavity is provided with a hydrogen outlet and a dehydrogenation liquid inlet, the catalytic dehydrogenation cavity is internally provided with a catalytic structure body, and the bottom of the catalytic dehydrogenation cavity is provided with a dehydrogenation liquid outlet. When the dehydrogenation reactor works, the liquid organic hydrogen storage material to be dehydrogenated enters the dehydrogenation reactor from the dehydrogenation liquid inlet, enters the catalytic dehydrogenation cavity for catalytic dehydrogenation after being preheated by the preheating cavity, a high-temperature hydrogen mixture generated by catalytic dehydrogenation is discharged from the hydrogen outlet after being condensed by the preheating cavity, and the liquid organic hydrogen storage material after catalytic dehydrogenation flows out from the dehydrogenation liquid outlet. In the invention, the preheating cavity is used for preheating the liquid organic hydrogen storage material entering the dehydrogenation reactor, and simultaneously condensing the volatile liquid organic hydrogen storage material and impurity gas with overhigh temperature, so that the purity of the obtained hydrogen is improved.
Description
Technical Field
The invention relates to the technical field of hydrogen energy utilization, in particular to a dehydrogenation reactor of a liquid organic hydrogen storage material.
Background
The hydrogen energy is used as an energy source with high energy density, cleanness, high efficiency and rich resources, can play an important role in solving the aspects of energy crisis, global warming and the like, and is considered as an ultimate energy carrier of human beings, so that the research and development of the hydrogen energy have great strategic significance.
The hydrogen energy development is restricted mainly by three aspects of hydrogen preparation, storage and transportation and utilization. At present, the storage and transportation modes of hydrogen mainly comprise four modes of high-pressure gaseous hydrogen storage, low-temperature liquid hydrogen storage, organic liquid storage and transportation and solid hydrogen storage. The liquid organic hydrogen storages (LOHC) uses unsaturated liquid organic matters such as alkene, alkyne and arene to fix hydrogen through hydrogenation reaction to form a liquid compound with hydrogen in molecules so as to realize the function of hydrogen storage. Compared with other hydrogen storage modes, the liquid organic hydrogen storage mode has the advantages of large volume hydrogen storage density, high liquid hydrogen storage purity, safe and efficient hydrogen storage process and huge development prospect.
The liquid organic hydrogen storage material is used for realizing hydrogen storage and transportation, and mainly involves two reactions of hydrogenation and dehydrogenation. At present, a dehydrogenation reactor for common liquid organic hydrogen storage materials is described in the chinese patent application with publication number CN 114682171A, and comprises: the reactor comprises a reactor body, wherein a gas outlet is formed in the upper end of the reactor body, a liquid phase outlet is formed in the lower end of the reactor body, a plurality of reaction tubes filled with a catalyst are arranged in the middle of the reactor body, a liquid adapter is connected to the lower ends of the reaction tubes, a heat exchange medium cavity is formed between the reaction tubes, two ends of the heat exchange medium cavity are sealed, a circulating tube extending along the axial direction of the reactor body is fixedly inserted into the heat exchange medium cavity, and two ends of the circulating tube are opened.
Although the prior art can realize high-efficiency dehydrogenation, the following problems still exist: 1) Because the dehydrogenation reactor does not have the preheating function, a plurality of reaction tubes filled with catalysts and a plurality of heat exchange medium cavities are needed, and a liquid adapter is used for liquid distribution, so that the volume of the whole reactor is large. 2) Because the temperature of dehydrogenation reaction is higher, generally about 200 ℃, therefore, impurities such as hydrogen storage liquid and the like are often mixed in the hydrogen generated in the dehydrogenation mode, and the existing dehydrogenation reactor does not have the hydrogen purification function, thereby influencing the subsequent utilization of the hydrogen.
Disclosure of Invention
In view of the existing problems, the present invention aims to provide a dehydrogenation reactor with small volume, higher dehydrogenation efficiency and higher purity of discharged hydrogen, and at least provides a useful choice or creation condition for solving one or more technical problems in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme.
A dehydrogenation reactor for a liquid organic hydrogen storage material comprising: the preheating cavity and the catalytic dehydrogenation cavity are communicated with each other, and the preheating cavity is positioned on the upper side of the catalytic dehydrogenation cavity; the top of the preheating cavity is provided with a hydrogen outlet and a dehydrogenation liquid inlet, the catalytic dehydrogenation cavity is internally provided with a catalytic structure body, and the bottom of the catalytic dehydrogenation cavity is provided with a dehydrogenation liquid outlet.
When the device works, the liquid organic hydrogen storage material to be dehydrogenated enters the dehydrogenation reactor from the dehydrogenation liquid inlet, enters the catalytic dehydrogenation cavity for catalytic dehydrogenation after being preheated by the preheating cavity, a high-temperature hydrogen mixture generated by catalytic dehydrogenation is discharged from the hydrogen outlet after being condensed by the preheating cavity, and the liquid organic hydrogen storage material after catalytic dehydrogenation flows out from the dehydrogenation liquid outlet.
More preferably, the preheating cavity and the catalytic dehydrogenation cavity are both cylindrical cavities, and the two cylindrical cavities are coaxially arranged; to facilitate rapid venting of hydrogen.
More preferably, the preheating chamber and the wall of the catalytic dehydrogenation chamber are separated by an insulating member.
More preferably, a microporous structure is provided in the preheating chamber, and the microporous structure is a column located on an axis of the preheating chamber.
More preferably, a first concave-convex flow channel is arranged on the wall of the preheating cavity, when the liquid organic hydrogen storage material to be dehydrogenated flows through the preheating cavity, a better preheating effect can be achieved under the action of the first concave-convex flow channel, and a generated hydrogen mixture can also achieve a better condensation impurity removal effect when flowing through the preheating cavity.
More preferably, the catalytic structure is a cylindrical body located on the axis of the catalytic dehydrogenation cavity, and a second concave-convex flow channel is arranged on the wall of the catalytic dehydrogenation cavity. The catalytic dehydrogenation effect can be improved by arranging the second concave-convex flow channel.
More preferably, the catalytic structure is comprised of a microporous conductor and a dehydrogenation catalyst deposited on the microporous conductor; when the device works, the micropore conductor is connected with an external power supply, and the dehydrogenation catalyst is heated after the micropore conductor is electrified, so that the temperature required by dehydrogenation reaction is reached.
More preferably, the wall of the catalytic dehydrogenation cavity is a heat insulating member, and a thermocouple is arranged on the wall of the catalytic dehydrogenation cavity and used for monitoring the catalytic reaction temperature in real time; when the device works, the temperature in the catalytic dehydrogenation cavity is monitored in real time and controlled in a closed-loop mode through the thermocouple, and the catalytic reaction temperature in the catalytic dehydrogenation cavity is controlled to be 180-200 ℃.
More preferably, a preheating device is connected to the preheating chamber, the preheating device includes a heat source, a coolant circulation pump, and a coolant circulation pipe, the heat source is used to provide heat required for preheating, the coolant circulation pipe is wound around the preheating section, and the heat source and the coolant circulation pump are disposed on the coolant circulation pipe.
More preferably, the temperature of the preheating chamber is controlled within the range of 65-75 ℃.
Compared with the prior art, the invention has the following beneficial effects.
1) By arranging the preheating cavity and the catalytic dehydrogenation cavity which are vertically arranged, when the device works, liquid organic hydrogen storage materials are injected from a dehydrogenation liquid inlet at the top of the preheating cavity, sequentially flow through the preheating cavity and the catalytic dehydrogenation cavity from top to bottom under the action of gravity, are preheated and dehydrogenated, and generated hydrogen is directly discharged from a hydrogen outlet at the top; the preheating cavity preheats the freshly injected liquid organic hydrogen storage material with lower temperature so as to improve the subsequent dehydrogenation efficiency, and simultaneously condenses the organic hydrogen storage material or impurities volatilized due to overhigh bottom temperature, thereby improving the purity of the finally obtained hydrogen.
2) The combined design of the microporous structure body, the first concave-convex flow channel and the like ensures that the effect of removing impurities in the hydrogen by preheating and condensation is better; the combined design of the catalytic structure body and the second concave-convex flow channel ensures that the liquid organic hydrogen storage material is more fully contacted with the catalyst, thereby improving the dehydrogenation reaction efficiency.
3) In the invention, based on the characteristics of the microporous conductor material and the thermal insulation property of the wall of the catalytic dehydrogenation cavity, the catalytic layer is directly heated by an external power supply, so that the energy consumption is saved.
Drawings
Fig. 1 is a schematic structural diagram of a dehydrogenation reactor of a liquid organic hydrogen storage material provided by the present invention.
FIG. 2 is a schematic sectional view of the reactor body.
FIG. 3 is a schematic diagram showing the results of the dehydrogenation reactor.
Reference numerals indicate the same.
1: preheating chamber, 2: catalytic dehydrogenation cavity, 3: insulating member, 4: liquid organic hydrogen storage material tank, 5: preheating device, 6: pipe, 7: and a circulating pump.
1-1: hydrogen outlet, 1-2: dehydrogenation liquid inlet, 1-3: microporous structure, 1-4: a first concave-convex flow passage.
2-1: catalytic structure, 2-2: dehydrogenation liquid outlet, 2-3: a second concave-convex flow channel, 2-4: and a thermocouple.
5-1: heat source, 5-2: cooling liquid circulating pump, 5-3: a coolant circulation line.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The following further describes embodiments of the present invention with reference to the accompanying drawings.
As shown in fig. 1 and fig. 2, a dehydrogenation reactor of a liquid organic hydrogen storage material comprises a reactor body, wherein the reactor body is composed of a preheating cavity 1 and a catalytic dehydrogenation cavity 2 which are communicated with each other, and the preheating cavity 1 is located on the upper side of the catalytic dehydrogenation cavity 2 and is connected with the catalytic dehydrogenation cavity 2 into a whole; the top of the preheating cavity 1 is provided with a hydrogen outlet 1-1 and a dehydrogenation liquid inlet 1-2, the catalytic dehydrogenation cavity 2 is internally provided with a catalytic structure body 2-1, and the bottom of the catalytic dehydrogenation cavity 2 is provided with a dehydrogenation liquid outlet 2-2.
When the device works, a liquid organic hydrogen storage material to be dehydrogenated enters a dehydrogenation reactor from the dehydrogenation liquid inlet 1-2, enters the catalytic dehydrogenation cavity 2 after being preheated by the preheating cavity 1 for catalytic dehydrogenation, a high-temperature hydrogen mixture generated by catalytic dehydrogenation is condensed by the preheating cavity 1 and then is discharged from the hydrogen outlet 1-1, and the liquid organic hydrogen storage material after catalytic dehydrogenation flows out from the dehydrogenation liquid outlet 2-2.
In this embodiment, the preheating chamber 1 and the catalytic dehydrogenation chamber 2 are both cylindrical chambers, and the two cylindrical chambers are coaxially arranged; to facilitate smooth flow of the liquid organic hydrogen storage material to be dehydrogenated and smooth discharge of hydrogen. Obviously, the shape and spatial layout of the preheating chamber 1 and the catalytic dehydrogenation chamber 2 can be appropriately changed by those skilled in the art according to different actual needs, and are not limited to the embodiment.
In this embodiment, it is preferable that a micro-porous structure 1-3 is provided in the preheating chamber 1, and the micro-porous structure 1-3 is a column located on the axis of the preheating chamber 1. The preheating effect of the liquid organic hydrogen storage material to be dehydrogenated and the condensation purification effect of the high-temperature hydrogen mixture can be further improved by arranging the microporous structural bodies 1-3. Further preferably, a first concave-convex flow channel 1-4 is further arranged on the wall of the preheating cavity 1, and the first concave-convex flow channel 1-4 is formed by a plurality of mutually parallel annular flow channels.
In this embodiment, the catalytic structure body 2-1 is a cylindrical body located on the axis of the catalytic dehydrogenation cavity 2, and a second concave-convex flow channel 2-3 is arranged on the cavity wall of the catalytic dehydrogenation cavity 2; the second concave-convex flow channel 2-3 is composed of a plurality of annular flow channels which are parallel to each other. Therefore, when the catalytic dehydrogenation is carried out, the liquid organic hydrogen storage material can be more fully contacted with the catalyst, and the dehydrogenation reaction efficiency is further improved.
In the present embodiment, it is preferable that the catalytic structure body 2-1 is composed of a microporous conductor and a dehydrogenation catalyst deposited on the microporous conductor; when the device works, the micropore conductor is connected with an external power supply, and the dehydrogenation catalyst is heated after the micropore conductor is electrified, so that the temperature required by dehydrogenation reaction is reached. In order to avoid electric leakage, the preheating cavity 2 and the cavity wall of the catalytic dehydrogenation cavity 2 are separated by an insulating part 3.
Further, the wall of the catalytic dehydrogenation cavity 2 is preferably a heat insulating member, and a thermocouple 2-4 is arranged on the wall of the catalytic dehydrogenation cavity 2 and used for monitoring the catalytic reaction temperature in real time, and during operation, the thermocouple 2-4 is used for monitoring the temperature in the catalytic dehydrogenation cavity 2 in real time and performing closed-loop control, so that the catalytic reaction temperature in the catalytic dehydrogenation cavity 2 is stabilized between 180 ℃ and 200 ℃. Further, it is preferable that the thermocouples 2 to 4 are plural and distributed on the upper, middle and lower sides of the wall of the catalytic dehydrogenation chamber 2, so as to better grasp the temperature distribution in the catalytic dehydrogenation chamber 2.
And as shown in fig. 3, the specific application schematic diagram of the dehydrogenation reactor is shown, and the dehydrogenation reactor comprises a liquid organic hydrogen storage material tank 4 and a preheating device 5 connected with the preheating cavity 1, wherein the liquid organic hydrogen storage material tank 2 is connected with the dehydrogenation reactor through a pipeline 6 to form a circulation loop, and a circulation pump 7 is arranged on the circulation loop, so that the liquid organic hydrogen storage material circulates between the liquid organic hydrogen storage material tank 2 and the dehydrogenation reactor.
The preheating device 5 comprises a heat source 5-1, a cooling liquid circulating pump 5-2 and a cooling liquid circulating pipeline 5-3, wherein the heat source 5-1 is used for providing heat required by preheating, the cooling liquid circulating pipeline 5-3 is coiled on the preheating cavity 1, and the heat source 5-1 and the cooling liquid circulating pump 5-2 are arranged on the cooling liquid circulating pipeline 5-3.
In this embodiment, the heat source 5-1 is preferably a heat dissipation system of the hydrogen end, so that the waste heat of the hydrogen end can be fully utilized. Taking a PEM fuel cell (proton exchange membrane fuel cell) heat dissipation system as an example, the temperature of the preheating cavity 1 can be maintained within the range of 65-75 ℃, the liquid organic hydrogen storage material with lower temperature which is freshly injected is preheated, and meanwhile, the organic hydrogen storage material or impurities volatilized due to overhigh bottom temperature are condensed, so that the purity of the obtained hydrogen is improved.
The liquid organic materials commonly used are unsaturated alkenes, alkynes or aromatics, etc. In this embodiment, unsaturated heterocyclic aromatic hydrocarbon is used as the liquid organic hydrogen storage material.
It should be further noted that in the description of the present invention, for the terms of orientation, there are terms such as "central", "lateral", "longitudinal", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", etc. indicating the orientation and positional relationship based on that shown in the drawings, which are used for convenience of description and simplification of the description, but do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and should not be construed as limiting the specific scope of protection of the present invention.
The terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features. Thus, a definition of "a first" or "a second" feature may explicitly or implicitly include one or more of the feature, and in the description of the invention, "at least" means one or more unless specifically defined otherwise.
In the present invention, unless otherwise explicitly defined or limited, the terms "assembled", "connected" and "connected" should be construed broadly and include, for example, fixed connections, detachable connections or integral connections; or may be a mechanical connection; the two elements can be directly connected or connected through an intermediate medium, and the two elements can be communicated with each other. The specific meanings of the above terms in the present invention can be understood by those of ordinary skill in the art according to specific situations.
In the present invention, unless otherwise specified and limited, "above" or "below" a first feature may include the first and second features being in direct contact, and may also include the first and second features not being in direct contact but being in contact with each other through another feature therebetween. Also, the first feature "above," "below," and "over" the second feature may include the first feature being directly above and obliquely above the second feature, or simply an elevation where the first feature is at a higher level than the second feature. The first feature being "above", "below" and "beneath" the second feature includes the first feature being directly below or obliquely below the second feature, or merely means that the first feature is at a lower level than the second feature.
It will be appreciated by those skilled in the art from the foregoing description of construction and principles that the invention is not limited to the specific embodiments described above, and that modifications and substitutions based on the teachings of the art may be made without departing from the scope of the invention as defined by the appended claims and their equivalents. The details not described in the detailed description are prior art or common general knowledge.
Claims (10)
1. A dehydrogenation reactor for a liquid organic hydrogen storage material, comprising: the preheating cavity and the catalytic dehydrogenation cavity are communicated with each other, and the preheating cavity is positioned on the upper side of the catalytic dehydrogenation cavity; the top of the preheating cavity is provided with a hydrogen outlet and a dehydrogenation liquid inlet, a catalytic structure body is arranged in the catalytic dehydrogenation cavity, and the bottom of the catalytic dehydrogenation cavity is provided with a dehydrogenation liquid outlet;
when the device works, the liquid organic hydrogen storage material to be dehydrogenated enters the dehydrogenation reactor from the dehydrogenation liquid inlet, enters the catalytic dehydrogenation cavity for catalytic dehydrogenation after being preheated by the preheating cavity, a high-temperature hydrogen mixture generated by catalytic dehydrogenation is discharged from the hydrogen outlet after being condensed by the preheating cavity, and the liquid organic hydrogen storage material after catalytic dehydrogenation flows out from the dehydrogenation liquid outlet.
2. The dehydrogenation reactor of claim 1, wherein the preheating chamber and the catalytic dehydrogenation chamber are both cylindrical chambers, and the two cylindrical chambers are coaxially disposed.
3. A dehydrogenation reactor for a liquid organic hydrogen storage material according to claim 1 or 2, characterized in that the preheating chamber and the wall of the catalytic dehydrogenation chamber are separated by an insulating member.
4. The dehydrogenation reactor of claim 2, wherein a microporous structure is disposed within the preheating chamber, the microporous structure being a column located on an axis of the preheating chamber.
5. The dehydrogenation reactor of claim 4, wherein a first concave-convex flow channel is disposed on a wall of the preheating chamber.
6. The dehydrogenation reactor of claim 2, wherein the catalytic structure is a cylindrical body located on the axis of the catalytic dehydrogenation cavity, and a second concave-convex flow channel is arranged on the wall of the catalytic dehydrogenation cavity.
7. The dehydrogenation reactor of a liquid organic hydrogen storage material of claim 1, wherein the catalytic structure is comprised of a microporous conductor and a dehydrogenation catalyst deposited on the microporous conductor; when the device works, the micropore conductor is connected with an external power supply, and the dehydrogenation catalyst is heated after the micropore conductor is electrified, so that the temperature required by dehydrogenation reaction is reached.
8. The dehydrogenation reactor of claim 7, wherein the wall of the catalytic dehydrogenation chamber is a thermal insulation member, and a thermocouple is disposed on the wall of the catalytic dehydrogenation chamber for monitoring the catalytic reaction temperature in real time; when the device works, the temperature in the catalytic dehydrogenation cavity is monitored in real time and controlled in a closed-loop mode through the thermocouple, and the catalytic reaction temperature in the catalytic dehydrogenation cavity is controlled to be 180-200 ℃.
9. The dehydrogenation reactor for liquid organic hydrogen storage material according to claim 1, wherein a preheating device is connected to the preheating chamber, the preheating device comprises a heat source, a coolant circulation pump and a coolant circulation pipeline, the heat source is used for providing heat required for preheating, the coolant circulation pipeline is wound on the preheating section, and the heat source and the coolant circulation pump are disposed on the coolant circulation pipeline.
10. A dehydrogenation reactor for a liquid organic hydrogen storage material according to claim 1, wherein the temperature of the preheating chamber is controlled within the range of 65-75 ℃.
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 100000 room 1041, 10th floor, Weiya building, No. 29 Suzhou street, Haidian District, Beijing Applicant after: Hanrui Hydrogen Technology Group Co.,Ltd. Address before: 100000 room 1041, 10th floor, Weiya building, No. 29 Suzhou street, Haidian District, Beijing Applicant before: Beijing Hanrui Hydrogen Energy Technology Co.,Ltd. |
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| CB02 | Change of applicant information |