CN115433624A - Dewatering antirust oil - Google Patents

Dewatering antirust oil Download PDF

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Publication number
CN115433624A
CN115433624A CN202211198862.0A CN202211198862A CN115433624A CN 115433624 A CN115433624 A CN 115433624A CN 202211198862 A CN202211198862 A CN 202211198862A CN 115433624 A CN115433624 A CN 115433624A
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China
Prior art keywords
parts
oil
alcohol
butyl
water
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Pending
Application number
CN202211198862.0A
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Chinese (zh)
Inventor
李晓栓
蒯文龙
王刚
郑威
朱珍珍
聂晓霖
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Nanjing Kerun Industrial Technology Co ltd
Nanjing Kerun New Material Technology Co ltd
Nanjing Kerun Industrial Media Co ltd
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Nanjing Kerun Industrial Technology Co ltd
Nanjing Kerun New Material Technology Co ltd
Nanjing Kerun Industrial Media Co ltd
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Priority to CN202211198862.0A priority Critical patent/CN115433624A/en
Publication of CN115433624A publication Critical patent/CN115433624A/en
Priority to PCT/CN2023/097739 priority patent/WO2024066435A1/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/56Boundary lubrication or thin film lubrication
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/48Slushing oils

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a dehydrated antirust oil which comprises the following components in parts by weight: 0.5-10 parts of butyl wax oxide, 0.5-10 parts of an auxiliary agent, 0-10 parts of oil-soluble sulfonate and 78-94 parts of base oil; wherein the auxiliary agent is at least one of alcohol ether solvent, alcohol or lactate. The dehydrating antirust oil disclosed by the invention uses the butyl wax oxide synergistic auxiliary as the dehydrating agent, can realize high-efficiency dehydration within a short time (10 s), has a dehydration rate of up to 100%, and can effectively delay the problem of rapid decrease of the dehydrating performance of the dehydrating agent caused by mixing of a large amount of water; the dewatering rust-preventive oil directly removes a large amount of water or aqueous solution attached to the metal surface, and can solve the problem that a large amount of water or aqueous solution is attached to the metal surface in the manufacturing process of metal products, so that the metal products can be directly soaked in the dewatering rust-preventive oil or other oil products without being dried.

Description

Dewatering antirust oil
Technical Field
The invention relates to a dehydrated antirust oil.
Background
In the process of producing a metal product, an aqueous medium such as an aqueous cutting fluid or a cleaning agent is used, and the medium forms a water film on the metal surface. The dehydrated antirust oil can quickly remove the water film on the metal surface, and simultaneously a layer of antirust oil film is deposited, thereby reducing the procedures of cleaning and drying the metal products.
At present, the dehydrating rust-preventive oil is widely applied to the manufacturing process of metal products, and the dehydrating agent in the dehydrating rust-preventive oil is an important factor influencing the dehydrating performance of the dehydrating rust-preventive oil. US2647839 in 1952 discloses the use of a 4 to 8 carbon aliphatic alcohol in combination with 0.1% to 3% water soluble surfactant as a dehydration composition for the removal of water from metal surfaces. Baker used 80% to 100% n-butanol as a dehydrating agent for dehydration in water intake equipment in 1961 (NRL REPORT 5606). 2016 to CN 105238520 discloses the addition of small amounts of ethers, alcohols or alcohol ethers to base oils to achieve a dewatering effect. In order to achieve the dehydration effect, ethers, alcohols or alcohol ethers and other substances used by the existing dehydrating agent have certain water solubility, but after a large amount of water enters the dehydrating antirust oil, the dehydrating agent is easily consumed or emulsified, thereby affecting the long-term use of the dehydrating antirust oil.
Disclosure of Invention
The purpose of the invention is as follows: the invention provides dewatering rust preventive oil which can dewater efficiently and delay the rapid reduction of dewatering performance of a dewatering agent caused by the mixing of a large amount of water.
The technical scheme is as follows: the dehydrated antirust oil comprises the following components in parts by weight: 0.5 to 10 portions of butyl wax oxide, 0.5 to 10 portions of auxiliary agent, 0 to 10 portions of oil-soluble sulfonate and 78 to 94 portions of base oil; wherein the auxiliary agent is at least one of alcohol ether solvent, alcohol or lactate.
Wherein the saponification value of the butyl wax oxide is more than or equal to 50mgKOH/g, and the dropping melting point is 30-60 ℃; the higher the saponification number, the more hydrophilic groups are contained, so that the water on the metal surface is easier to remove, and the lower the drop melting point, the better dissolution and dispersion in the system can be realized.
Wherein the alcohol ether solvent is ethylene glycol monobutyl ether, propylene glycol monobutyl ether, diethylene glycol monobutyl ether or dipropylene glycol monobutyl ether; the alcohol is a straight chain or isomeric alcohol with the carbon number between 4 and 13; the lactate is ethyl lactate or butyl lactate.
Wherein the oil-soluble sulfonate is barium dinonyl naphthalene sulfonate or/and calcium dinonyl naphthalene sulfonate; the barium nonyl naphthalene sulfonate is alkaline or neutral barium dinonyl naphthalene sulfonate; the calcium dinonylnaphthalenesulfonate is basic or neutral calcium dinonylnaphthalenesulfonate.
Wherein the base oil is solvent oil with the distillation range of 180-250 ℃. The lower the distillation range of the base oil, the lower the viscosity of the system, so that the dewatering effect of the system is better, and the dewatering effect is beneficial to the separation of water from the metal surface and the sedimentation of water in the system.
The preparation process of the dewatering antirust oil comprises the following steps: heating the butyl wax oxide into oily liquid, adding the base oil with the formula amount into a blending kettle, adding the auxiliary agent and the oil-soluble sulfonate with the formula amount, and stirring for 1 hour at 40-60 ℃.
Has the beneficial effects that: the dehydrating antirust oil disclosed by the invention uses the butyl wax oxide as a dehydrating agent in cooperation with the auxiliary agent, can realize high-efficiency dehydration within a short time (10 s), has a dehydration rate of up to 100%, and can effectively delay the problem of rapid decrease of the dehydration performance of the dehydrating agent caused by the mixing of a large amount of water; the dewatering rust-preventive oil directly removes a large amount of water or aqueous solution attached to the metal surface, and can solve the problem that a large amount of water or aqueous solution is attached to the metal surface in the manufacturing process of metal products, so that the metal products can be directly soaked in the dewatering rust-preventive oil or other oil products without being dried.
Detailed Description
Example 1
The invention relates to a dehydrated antirust oil which comprises the following components in parts by weight: 3 parts of butyl wax oxide, 1 part of ethylene glycol monobutyl ether, 2 parts of basic barium dinonylnaphthalenesulfonate and 94 parts of D60.
Example 2
The invention relates to a dehydrated antirust oil which comprises the following components in parts by weight: 10 parts of butyl wax oxide, 5 parts of ethylene glycol monobutyl ether, 5 parts of n-butanol, 2 parts of neutral barium dinonylnaphthalene sulfonate and 78 parts of D60.
Example 3
The invention relates to a dehydrated antirust oil which comprises the following components in parts by weight: 1 part of butyl wax oxide, 1 part of ethyl lactate, 1 part of n-hexanol and 97 parts of D60.
Example 4
The dehydrated antirust oil comprises the following components in parts by weight: 2 parts of butyl wax oxide, 2 parts of dipropylene glycol monobutyl ether, 1 part of butyl lactate, 2 parts of neutral calcium dinonylnaphthalenesulfonate and 93 parts of D60.
Comparative example 1
The dewatering anti-rust oil comprises the following components in parts by weight: 10 parts of butyl wax oxide, 2 parts of neutral barium dinonylnaphthalene sulfonate and 88 parts of D60.
Comparative example 2
The dewatering anti-rust oil comprises the following components in parts by weight: 5 parts of ethylene glycol monobutyl ether, 5 parts of n-butyl alcohol, 2 parts of neutral barium dinonylnaphthalene sulfonate and 88 parts of D60.
Comparative example 3
The dewatering antirust oil comprises the following components in parts by weight: 40 parts of ethylene glycol monobutyl ether, 40 parts of n-butanol, 2 parts of neutral barium dinonylnaphthalene sulfonate and 18 parts of D60.
And (3) cleaning the surfaces of the 7 standard metal test pieces by using an aqueous cleaning agent, and then washing the surfaces of the metal test pieces by using tap water so that a continuous water film can be formed on the surfaces of the metal test pieces. Seven metal test pieces were vertically put in a beaker filled with dehydrated rust-preventive oil according to examples 1 to 4 and comparative examples 1 to 3, respectively, and the metal test pieces were required to be completely immersed in the oil. The time for >95% water removal from the surface of the metal coupon and the final water residue on the surface of the metal coupon were recorded and are shown in Table 1.
TABLE 1
Figure BDA0003871665120000031
As can be seen from Table 1, the dehydrated rust preventive oil of example 2 can dehydrate water in an amount of 500 times the volume of the oil, the dehydration performance of comparative examples 1 to 2 is weak, and the dehydration performance of comparative example 3 can be significantly reduced by 5 times of water accumulation although the dehydration can be achieved by increasing the dosage of the auxiliary agent. The dehydration rust-preventive oil can be used for removing water or water-soluble substances on the surface of a metal product, has a good dehydration effect, can effectively delay the problem of dehydration performance reduction caused by mixing of a large amount of water, and can be used for dehydration procedures in the manufacturing process of steel pipes and automobile parts.

Claims (5)

1. The dewatering antirust oil is characterized by comprising the following components in parts by weight: 0.5-10 parts of butyl wax oxide, 0.5-10 parts of an auxiliary agent, 0-10 parts of oil-soluble sulfonate and 78-94 parts of base oil; wherein the auxiliary agent is at least one of alcohol ether solvent, alcohol or lactate.
2. The dehydrated rust preventive oil according to claim 1, characterized in that: the saponification value of the butyl wax oxide is more than or equal to 50mgKOH/g, and the drop melting point is 30-60 ℃.
3. The dehydrated rust preventive oil according to claim 1, characterized in that: the alcohol ether solvent is ethylene glycol monobutyl ether, propylene glycol monobutyl ether, diethylene glycol monobutyl ether or dipropylene glycol monobutyl ether; the alcohol is a straight chain or isomeric alcohol with the carbon number between 4 and 13; the lactate is ethyl lactate or butyl lactate.
4. The dehydrated rust preventive oil according to claim 1, characterized in that: the oil-soluble sulfonic acid is barium dinonylnaphthalenesulfonate or/and calcium dinonylnaphthalenesulfonate; the barium nonyl naphthalene sulfonate is alkaline or neutral barium dinonyl naphthalene sulfonate; the calcium dinonylnaphthalenesulfonate is alkaline or neutral calcium dinonylnaphthalenesulfonate.
5. The dehydrated rust preventive oil according to claim 1, characterized in that: the base oil is solvent oil with the distillation range of 180-250 ℃.
CN202211198862.0A 2022-09-29 2022-09-29 Dewatering antirust oil Pending CN115433624A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202211198862.0A CN115433624A (en) 2022-09-29 2022-09-29 Dewatering antirust oil
PCT/CN2023/097739 WO2024066435A1 (en) 2022-09-29 2023-06-01 Dewatering anti-rust oil

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024066435A1 (en) * 2022-09-29 2024-04-04 南京科润工业介质股份有限公司 Dewatering anti-rust oil

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110437917A (en) * 2019-08-23 2019-11-12 广州市联诺化工科技有限公司 A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4824934B2 (en) * 2005-02-14 2011-11-30 中部キレスト株式会社 Rust preventive additive, rust preventive oil composition, and rust preventive treatment method for metal material
JP5478032B2 (en) * 2008-05-27 2014-04-23 Jx日鉱日石エネルギー株式会社 Rust prevention oil composition
CN103484215A (en) * 2013-08-20 2014-01-01 安徽精一机械设备有限公司 Dehydrating rust-proof oil
CN115433624A (en) * 2022-09-29 2022-12-06 南京科润工业介质股份有限公司 Dewatering antirust oil

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110437917A (en) * 2019-08-23 2019-11-12 广州市联诺化工科技有限公司 A kind of iron-based powder metallurgy parts environment-friendly antirust oil and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024066435A1 (en) * 2022-09-29 2024-04-04 南京科润工业介质股份有限公司 Dewatering anti-rust oil

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Application publication date: 20221206