CN115418278A - Bio-based glass cleaning agent for automobiles and preparation method thereof - Google Patents
Bio-based glass cleaning agent for automobiles and preparation method thereof Download PDFInfo
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- CN115418278A CN115418278A CN202211152450.3A CN202211152450A CN115418278A CN 115418278 A CN115418278 A CN 115418278A CN 202211152450 A CN202211152450 A CN 202211152450A CN 115418278 A CN115418278 A CN 115418278A
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- 239000011521 glass Substances 0.000 title claims abstract description 59
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000004094 surface-active agent Substances 0.000 claims abstract description 37
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 34
- 229930182490 saponin Natural products 0.000 claims abstract description 34
- 150000007949 saponins Chemical class 0.000 claims abstract description 34
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 239000002738 chelating agent Substances 0.000 claims abstract description 20
- -1 alkyl glucoside Chemical class 0.000 claims abstract description 18
- 229930182470 glycoside Natural products 0.000 claims abstract description 14
- 239000003755 preservative agent Substances 0.000 claims abstract description 14
- 230000002335 preservative effect Effects 0.000 claims abstract description 14
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 13
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 13
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 13
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000002386 leaching Methods 0.000 claims abstract description 6
- 238000007873 sieving Methods 0.000 claims abstract description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 23
- 239000000284 extract Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 10
- 229920000805 Polyaspartic acid Polymers 0.000 claims description 9
- 108010064470 polyaspartate Proteins 0.000 claims description 9
- 241000205585 Aquilegia canadensis Species 0.000 claims description 8
- 229920001661 Chitosan Polymers 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 229920001529 polyepoxysuccinic acid Polymers 0.000 claims description 7
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000000419 plant extract Substances 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 238000009210 therapy by ultrasound Methods 0.000 claims description 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 4
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 4
- 241000218691 Cupressaceae Species 0.000 claims description 4
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 4
- 239000011425 bamboo Substances 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 241001122767 Theaceae Species 0.000 abstract description 14
- 239000000686 essence Substances 0.000 abstract description 10
- 238000005202 decontamination Methods 0.000 abstract description 7
- 230000003588 decontaminative effect Effects 0.000 abstract description 7
- 239000003093 cationic surfactant Substances 0.000 abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 abstract description 4
- 239000013543 active substance Substances 0.000 abstract description 2
- 239000012535 impurity Substances 0.000 abstract description 2
- 229930182478 glucoside Natural products 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 230000008014 freezing Effects 0.000 description 6
- 238000007710 freezing Methods 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- 229960001484 edetic acid Drugs 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 241001330002 Bambuseae Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000931143 Gleditsia sinensis Species 0.000 description 3
- 229920001800 Shellac Polymers 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 3
- 239000004208 shellac Substances 0.000 description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 3
- 229940113147 shellac Drugs 0.000 description 3
- 235000013874 shellac Nutrition 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 244000304337 Cuminum cyminum Species 0.000 description 1
- 235000007129 Cuminum cyminum Nutrition 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
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- Emergency Medicine (AREA)
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- Detergent Compositions (AREA)
Abstract
The invention relates to a bio-based glass cleaning agent for an automobile and a preparation method thereof, belonging to the technical field of cleaning agents, wherein the bio-based glass cleaning agent for the automobile comprises the following raw materials: the bio-based glass cleaner for the automobiles is prepared by stirring and mixing raw materials of bio-based surfactant, deionized water, isopropanol, propylene glycol, ethylene glycol monobutyl ether, chelating agent, carboxymethyl cellulose, preservative and essence, wherein the bio-based surfactant is prepared by crushing tea seeds and saponin, sieving, ultrasonically leaching, removing impurities, decoloring and mixing alkyl glucoside. According to the invention, the tea seeds, the saponin and the alkyl glycoside are compounded to prepare the bio-based surfactant, the saponin is a natural non-ionic surfactant, the alkyl glycoside belongs to the interaction of different surface active substances of a cationic surfactant, and the non-ionic surfactant and the cationic surfactant are compounded, so that the comprehensive decontamination capability of the bio-based glass cleaner for the automobile is improved.
Description
Technical Field
The invention belongs to the technical field of cleaning agents, and particularly relates to a bio-based glass cleaning agent for an automobile and a preparation method thereof.
Background
The automobile windshield is a very important component of an automobile, because the air pollution is increasingly serious, the automobile windshield is very easy to be dirty and can influence the sight of a driver, so the automobile windshield needs to be cleaned in time, the main components of a cleaning agent (commonly called as glass water) for cleaning the windshield are water, alcohol, glycol, a corrosion inhibitor and a surfactant, wherein the surfactant is mainly a petroleum-based surfactant such as sodium dodecyl sulfate and the like, meanwhile, the detergent is also added with sodium phosphate, EDTA (ethylene diamine tetraacetic acid), NTA (nitrilotriacetic acid) and other auxiliaries, the environmental protection requirement on the automobile cleaning agent is higher and higher along with the increase of the automobile reservation quantity in China, and chemical substances remained after the traditional automobile cleaning agent is used are often dispersed into soil and river channels through a city sewer system or directly or indirectly, so that the environment is continuously and deeply influenced at any moment. Therefore, the development of green and environment-friendly automobile glass cleaning agents is always a pursuit of cumin in the whole industry.
Disclosure of Invention
In order to solve the technical problems mentioned in the background art, the invention aims to provide a bio-based glass cleaner for automobiles and a preparation method thereof.
The purpose of the invention can be realized by the following technical scheme:
the bio-based glass cleaning agent for the automobile comprises the following raw materials in parts by weight: 5-8 parts of bio-based surfactant, 30-50 parts of deionized water, 40-50 parts of isopropanol, 8-10 parts of propylene glycol, 8-10 parts of ethylene glycol monobutyl ether, 5 parts of chelating agent, 0.1 part of carboxymethyl cellulose, 0.1 part of preservative and 0.1 part of essence.
The bio-based surfactant is prepared by the following steps:
a1, respectively cleaning and airing tea seeds and saponin, crushing and drying, crushing, sieving by a 100-mesh sieve, and mixing according to the proportion of 1:1, mixing the tea seed powder and the saponin powder to obtain a mixed material, adding 63% ethanol into the mixed material for leaching, carrying out ultrasonic treatment for 30min at the power of 400w, centrifuging to obtain a solution, and concentrating and drying the solution under reduced pressure to obtain crude bio-based powder;
a2, adding a 1% chitosan acetic acid solution into the crude bio-based powder, stirring for 10-15min at 40-45 ℃, standing for 8h, filtering, adding 5% hydrogen peroxide into the filtrate, and heating and refluxing for 1-2h at 80 ℃ to obtain a saponin extracting solution;
and A3, adding alkyl glycoside into the saponin extracting solution under stirring, heating to 35-45 ℃, and continuously stirring for 30-60min to obtain the bio-based surfactant.
In the preparation process, the saponin in the tea seeds and the saponin is firstly extracted by 63 percent ethanol, then the crude biological base powder is subjected to impurity removal and decoloration treatment by chitosan acetic acid solution to obtain saponin extract, and the saponin extract is compounded and mixed with alkyl glycoside, wherein the alkyl glycoside can be extracted from plants and belongs to natural extracts.
Further, the using amount ratio of the mixed material to the ethanol in the step A1 is 10g:100-200mL.
Further, the dosage ratio of the crude bio-based powder, the chitosan acetic acid solution and the hydrogen peroxide in the step A2 is 10g:20-30mL:50-100mL.
Further, the volume ratio of the saponin extract to the alkyl glycoside in the step A3 is 1:1.
further, the chelating agent is a polycarboxylate chelating agent, and the carboxylate chelating agent is one of polyaspartic acid and polyepoxysuccinic acid.
Further, the preservative is a plant extract, and the plant extract is one of a bamboo cypress extract, a honeysuckle extract and a honeysuckle extract.
Further, the bio-based glass cleaner for the automobile is prepared by the following steps:
adding isopropanol, propylene glycol and ethylene glycol monobutyl ether into deionized water under stirring, adding a chelating agent, a preservative and essence to obtain a builder, mixing and stirring the builder and a bio-based surfactant for 10-15min, finally adding carboxymethyl cellulose, and heating in a water bath at 55-60 ℃ for 2-3h to obtain the bio-based glass cleaner for the automobile.
In the step of preparing the bio-based glass cleaner for the automobile, firstly, isopropanol and propylene glycol are added, the freezing point of the isopropanol is-89 ℃, the freezing point of the propylene glycol is-59 ℃, and the isopropanol and the propylene glycol are selected as solvents, so that the use temperature range of the bio-based glass cleaner for the automobile is improved, wherein the content of the isopropanol is about 40-45%, and the content of the propylene glycol is about 8-10%, so that the bio-based glass cleaner for the automobile can be still normally used under the low-temperature condition of about-40 ℃;
generally speaking, the silt and dust on the automobile glass can be cleaned by water, so the main component of the automobile windshield cleaning agent is water, but some oil dirt, animal and plant colloid and the like are difficult to clean stains by water, therefore, the bio-based surfactant is added in the cleaning agent, the removal of the stains is realized by reducing the adhesive force of the stains on the glass, the bio-based surfactant is prepared by adopting a biological base material, and compared with the petroleum-based surfactant, the bio-based surfactant has the advantages of environmental protection and renewable raw materials.
The raw materials also comprise a chelating agent, carboxymethyl cellulose, a preservative and essence, wherein the chelating agent is selected from polyaspartic acid and polyepoxysuccinic acid, and the traditional chelating agents such as sodium tripolyphosphate, EDTA (ethylene diamine tetraacetic acid) and NTA (nitrilotriacetic acid), and the sodium tripolyphosphate can cause water eutrophication; EDTA and NTA have toxicity and carcinogenicity, compare with traditional chelant, choose polyaspartic acid and polyepoxysuccinic acid of green chelant, polyaspartic acid and polyepoxysuccinic acid have phosphorus-free, non-toxic, advantage suitable for biodegradation; adding small amount of carboxymethyl cellulose as thickener, and adopting green pollution-free plant extract or natural essential oil as antiseptic.
The invention has the beneficial effects that:
in the process of preparing the bio-based surfactant, firstly, ethanol is used as an extracting agent to extract saponin from tea seeds and Chinese honeylocust fruits, the tea seeds and the Chinese honeylocust fruits are all biological materials and are rich in saponin, the saponin is a natural non-ionic surfactant and has the performances of emulsification, sterilization, wetting and the like, the tea seeds and the Chinese honeylocust fruits are used for compounding the bio-based surfactant, different surface active substances interact, and compared with a single system, a complex mixed micelle is easier to form, so that the comprehensive decontamination capability of the bio-based glass cleaner for the automobile is improved; meanwhile, alkyl glycoside is added in the process of preparing the bio-based surfactant, the alkyl glycoside can be extracted from plants and belongs to natural extracts, the alkyl glycoside belongs to cationic surfactants, and the comprehensive decontamination capability of the bio-based glass cleaner for the automobile is further improved by compounding nonionic surfactants and cationic surfactants.
In the process of preparing the bio-based glass cleaner for the automobile, the isopropanol and the propylene glycol are added as solvents, so that the freezing point of the bio-based glass cleaner for the automobile is reduced, and the environmental applicability is improved; the bio-based surfactant is added, the surfactant can be used as a glass antifogging agent while being used for cleaning automobile glass, and after the surfactant is sprayed on the surface of the glass, a hydrophilic molecular layer is adsorbed on the surface of the glass to reduce the contact angle of water on the surface of the glass, and when the contact angle is small enough, the water can wet the surface of the glass and can not form water drops, so that the aim of preventing fog is fulfilled; the ethylene glycol butyl ether is added, and the wetting property of the alkyl alcohol ethoxy compound with the side chain is better than that of a straight-chain alkyl alcohol ethoxy compound, so that the wetting property of the bio-based surfactant is adjusted by adding the ethylene glycol butyl ether, and the decontamination effect of the bio-based glass cleaner for the automobile is improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Preparing a bio-based surfactant:
a1, respectively cleaning and airing tea seeds and saponin, crushing and drying, crushing, sieving by a 100-mesh sieve, mixing 500g of tea seed powder and 500g of saponin powder to obtain a mixed material, adding 10L of 63% ethanol into the mixed material for leaching, carrying out ultrasonic treatment for 30min at a power of 400w, centrifuging to obtain a solution, and concentrating and drying the solution under reduced pressure to obtain crude biological base powder;
a2, taking 10g of crude biological base powder, adding 20mL of 1% chitosan acetic acid solution, stirring for 10min at 40 ℃, standing for 8h, filtering, adding 50mL of 5% hydrogen peroxide into the filtrate, and heating and refluxing for 1h at 80 ℃ to obtain a saponin extracting solution;
and A3, taking 50mL of saponin extract, adding 50mL of alkyl glycoside into the extract under stirring, heating to 35 ℃, and continuously stirring for 30min to obtain the bio-based surfactant.
Example 2
Preparing a bio-based surfactant:
a1, respectively cleaning and airing tea seeds and saponin, crushing and drying, crushing, sieving by a 100-mesh sieve, mixing 500g of tea seed powder and 500g of saponin powder to obtain a mixed material, adding 14L of 63% ethanol into the mixed material for leaching, carrying out ultrasonic treatment for 30min at the power of 400w, centrifuging to obtain a solution, and carrying out reduced pressure concentration and drying on the solution to obtain crude bio-based powder;
a2, taking 10g of crude biological base powder, adding 23mL of 1% chitosan acetic acid solution, stirring for 10-15min at 48 ℃, standing for 8h, filtering, adding 80mL of 5% hydrogen peroxide into the filtrate, and heating and refluxing for 1h at 80 ℃ to obtain a saponin extracting solution;
and A3, taking 50mL of saponin extracting solution, adding 50mL of alkyl glycoside into the saponin extracting solution under stirring, heating to 38 ℃, and continuously stirring for 50min to obtain the bio-based surfactant.
Example 3
Preparing a bio-based surfactant:
a1, respectively cleaning and airing tea seeds and saponin, crushing and drying, crushing, sieving by a 100-mesh sieve, mixing 500g of tea seed powder and 500g of saponin powder to obtain a mixed material, adding 20L of 63% ethanol into the mixed material for leaching, carrying out ultrasonic treatment for 30min at a power of 400w, centrifuging to obtain a solution, and concentrating and drying the solution under reduced pressure to obtain crude biological base powder;
a2, taking 10g of crude biological base powder, adding 30mL of 1% chitosan acetic acid solution, stirring for 15min at 45 ℃, standing for 8h, filtering, adding 100mL of 5% hydrogen peroxide into the filtrate, and heating and refluxing for 2h at 80 ℃ to obtain a saponin extracting solution;
and A3, taking 50mL of saponin extracting solution, adding 50mL of alkyl glycoside into the saponin extracting solution under stirring, heating to 45 ℃, and continuously stirring for 60min to obtain the bio-based surfactant.
Example 4
Preparing a bio-based glass cleaner for automobiles:
the bio-based glass cleaning agent for the automobile comprises the following raw materials in parts by weight: 5 parts of bio-based surfactant prepared in example 1, 30 parts of deionized water, 40 parts of isopropanol, 8 parts of propylene glycol, 8 parts of butyl cellosolve, 5 parts of chelating agent, 0.1 part of carboxymethyl cellulose, 0.1 part of preservative and 0.1 part of essence;
the preparation process comprises the following steps:
adding isopropanol, propylene glycol and ethylene glycol monobutyl ether into deionized water under stirring, and then adding polyaspartic acid, bamboo cypress extract and essence, wherein the polyaspartic acid is a polycarboxylate chelating agent; the bamboo cypress extract is used as a preservative to obtain a builder, the builder and a bio-based surfactant are mixed and stirred for 10min, finally, carboxymethyl cellulose is added, and the mixture is heated in a water bath at 55 ℃ for 2h to obtain the bio-based glass cleaning agent for the automobile.
Through detection, the freezing point of the glass cleaning agent for the automobile is-39 ℃;
detergency: the automobile glass cleaning agent is tested according to the GB/T23436 standard, and the automobile glass cleaning agent has good decontamination effect on stains and shellac on automobile glass and has no residue after testing.
Example 5
Preparing a bio-based glass cleaner for automobiles:
the bio-based glass cleaning agent for the automobile comprises the following raw materials in parts by weight: 7 parts of bio-based surfactant prepared in example 2, 40 parts of deionized water, 46 parts of isopropanol, 9 parts of propylene glycol, 9 parts of ethylene glycol monobutyl ether, 5 parts of chelating agent, 0.1 part of carboxymethyl cellulose, 0.1 part of preservative and 0.1 part of essence;
the preparation process comprises the following steps:
adding isopropanol, propylene glycol and ethylene glycol butyl ether into deionized water under stirring, and adding polyepoxysuccinic acid, honeysuckle extract and essence, wherein the polyepoxysuccinic acid is a polycarboxylate type chelating agent; taking the honeysuckle extract as a preservative to obtain a builder, mixing and stirring the builder and a bio-based surfactant for 12min, finally adding carboxymethyl cellulose, and heating in a water bath at 58 ℃ for 3h to obtain the bio-based glass cleaner for the automobile.
The detection shows that the freezing point of the glass cleaner for the automobile is-40 ℃;
detergency ratio: the automotive glass cleaning agent is tested according to the GB/T23436 standard, and the automotive glass cleaning agent has a good decontamination effect on stains and shellac on automotive glass and has no residue after being tested.
Example 6
Preparing a bio-based glass cleaner for automobiles:
the bio-based glass cleaning agent for the automobile comprises the following raw materials in parts by weight: 8 parts of bio-based surfactant prepared in example 3, 50 parts of deionized water, 50 parts of isopropanol, 10 parts of propylene glycol, 10 parts of butyl cellosolve, 5 parts of chelating agent, 0.1 part of carboxymethyl cellulose, 0.1 part of preservative and 0.1 part of essence;
the preparation process comprises the following steps:
adding isopropanol, propylene glycol and ethylene glycol monobutyl ether into deionized water under stirring, and then adding polyaspartic acid, honeysuckle extract and essence, wherein the polyaspartic acid is a polycarboxylate chelating agent; the honeysuckle extract is used as a preservative to obtain a builder, the builder and a bio-based surfactant are mixed and stirred for 15min, finally, carboxymethyl cellulose is added, and the mixture is heated in a water bath at 60 ℃ for 3h to obtain the bio-based glass cleaner for the automobile.
The detection shows that the freezing point of the glass cleaner for the automobile is-40 ℃;
detergency: the automotive glass cleaning agent is tested according to the GB/T23436 standard, and the automotive glass cleaning agent has a good decontamination effect on stains and shellac on automotive glass and has no residue after being tested.
In the description of the specification, reference to the description of "one embodiment," "an example," "a specific example" or the like means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.
Claims (7)
1. The bio-based glass cleaning agent for the automobile is characterized by comprising the following raw materials in parts by weight: 5-8 parts of bio-based surfactant, 30-50 parts of deionized water, 40-50 parts of isopropanol, 8-10 parts of propylene glycol, 8-10 parts of ethylene glycol monobutyl ether, 5 parts of chelating agent, 0.1 part of carboxymethyl cellulose, 0.1 part of preservative and 0.1 part of essence;
the bio-based surfactant is prepared by the following steps:
a1, respectively cleaning and airing tea seeds and saponin, crushing and drying, crushing, sieving by a 100-mesh sieve, and mixing according to the weight ratio of 1:1, mixing the tea seed powder and the saponin powder to obtain a mixed material, adding 63% ethanol into the mixed material for leaching, carrying out ultrasonic treatment for 30min at the power of 400w, centrifuging to obtain a solution, and concentrating and drying the solution under reduced pressure to obtain crude bio-based powder;
a2, adding a 1% chitosan acetic acid solution into the crude biological base powder, stirring for 10-15min at 40-45 ℃, standing for 8h, filtering, adding 5% hydrogen peroxide into the filtrate, and heating and refluxing for 1-2h at 80 ℃ to obtain a saponin extracting solution;
and A3, adding alkyl glycoside into the saponin extracting solution under stirring, heating to 35-45 ℃, and continuously stirring for 30-60min to obtain the bio-based surfactant.
2. The bio-based glass cleaner for the automobile as claimed in claim 1, wherein the amount ratio of the mixed material to the ethanol in step A1 is 10g:100-200mL.
3. The bio-based glass cleaner for the automobile according to claim 1, wherein the amount ratio of the crude bio-based powder, the chitosan acetic acid solution and the hydrogen peroxide in the step A2 is 10g:20-30mL:50-100mL.
4. The bio-based glass cleaner for the automobile as claimed in claim 1, wherein the volume ratio of the saponin extract to the alkyl glycoside in step A3 is 1:1.
5. the bio-based glass cleaner for the automobile as claimed in claim 1, wherein the chelating agent is a polycarboxylate chelating agent, and the carboxylate chelating agent is one of polyaspartic acid and polyepoxysuccinic acid.
6. The bio-based glass cleaner for the automobile as claimed in claim 1, wherein the preservative is a plant extract, and the plant extract is one of a bamboo cypress extract, a honeysuckle extract and a honeysuckle extract.
7. The preparation method of the bio-based glass cleaner for the automobile according to claim 1, wherein the bio-based glass cleaner for the automobile is prepared by the following steps:
adding isopropanol, propylene glycol and ethylene glycol monobutyl ether into deionized water under stirring, then adding a chelating agent, a preservative and essence to obtain a builder, mixing and stirring the builder and a bio-based surfactant for 10-15min, finally adding carboxymethyl cellulose, and heating in a water bath at 55-60 ℃ for 2-3h to obtain the bio-based glass cleaner for the automobile.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015192603A1 (en) * | 2014-06-18 | 2015-12-23 | 中国科学院过程工程研究所 | Oil-in-water emulsion containing no surfactant and use thereof |
| CN109330933A (en) * | 2018-10-15 | 2019-02-15 | 安徽万春日化有限公司 | A method of the antibacterial component of toothpaste anti-inflammatory, antibacterial is prepared with medicinal material medicinal extract-micro-capsule |
| CN110819472A (en) * | 2019-10-21 | 2020-02-21 | 黑龙江大学 | Preparation method of anti-freezing and environment-friendly easily-degradable glass cleaning agent |
-
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- 2022-09-21 CN CN202211152450.3A patent/CN115418278A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015192603A1 (en) * | 2014-06-18 | 2015-12-23 | 中国科学院过程工程研究所 | Oil-in-water emulsion containing no surfactant and use thereof |
| CN109330933A (en) * | 2018-10-15 | 2019-02-15 | 安徽万春日化有限公司 | A method of the antibacterial component of toothpaste anti-inflammatory, antibacterial is prepared with medicinal material medicinal extract-micro-capsule |
| CN110819472A (en) * | 2019-10-21 | 2020-02-21 | 黑龙江大学 | Preparation method of anti-freezing and environment-friendly easily-degradable glass cleaning agent |
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Application publication date: 20221202 |