CN115418004A - Organic silicon waterproof emulsion and preparation method and application thereof - Google Patents
Organic silicon waterproof emulsion and preparation method and application thereof Download PDFInfo
- Publication number
- CN115418004A CN115418004A CN202211143039.XA CN202211143039A CN115418004A CN 115418004 A CN115418004 A CN 115418004A CN 202211143039 A CN202211143039 A CN 202211143039A CN 115418004 A CN115418004 A CN 115418004A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- waterproof
- silicone oil
- silicone
- portions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 88
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 19
- 239000010703 silicon Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000004945 emulsification Methods 0.000 title claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000011490 mineral wool Substances 0.000 claims abstract description 31
- 229920002545 silicone oil Polymers 0.000 claims abstract description 28
- 239000003921 oil Substances 0.000 claims abstract description 24
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 19
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 9
- 239000003899 bactericide agent Substances 0.000 claims abstract description 9
- 239000013530 defoamer Substances 0.000 claims abstract description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 6
- 230000003449 preventive effect Effects 0.000 claims abstract description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 17
- 239000002518 antifoaming agent Substances 0.000 claims description 14
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000005011 phenolic resin Substances 0.000 claims description 11
- 229920001568 phenolic resin Polymers 0.000 claims description 11
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 10
- 235000010199 sorbic acid Nutrition 0.000 claims description 10
- 229940075582 sorbic acid Drugs 0.000 claims description 10
- 239000004334 sorbic acid Substances 0.000 claims description 10
- 150000003863 ammonium salts Chemical group 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 8
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 6
- 235000010241 potassium sorbate Nutrition 0.000 claims description 6
- 239000004302 potassium sorbate Substances 0.000 claims description 6
- 229940069338 potassium sorbate Drugs 0.000 claims description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims description 3
- -1 alkyl dimethyl benzyl ammonium chloride Chemical compound 0.000 claims description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000011810 insulating material Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 4
- 229920000053 polysorbate 80 Polymers 0.000 description 4
- 238000004078 waterproofing Methods 0.000 description 4
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 229940083037 simethicone Drugs 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011489 building insulation material Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an organosilicon waterproof emulsion and a preparation method and application thereof, wherein the organosilicon waterproof emulsion comprises the following raw materials: 5 to 25 portions of silicone oil, 5 to 10 portions of dustproof oil, 2 to 10 portions of polyvinyl alcohol solution, 0.5 to 2.0 portions of emulsifier, 0.1 to 0.5 portion of bactericide, 0 to 0.5 portion of mildew preventive, 0.2 to 1.0 portion of defoamer and 51.0 to 87.2 portions of deionized water; wherein the silicone oil is one or a mixture of methyl silicone oil and hydroxyl silicone oil. The organic silicon waterproof emulsion disclosed by the invention is good in performance, low in cost, suitable for large-scale use, and durable in waterproof effect and excellent in waterproof performance when applied to rock wool heat-insulating boards.
Description
Technical Field
The invention belongs to the field of inorganic building insulation material waterproofing, relates to a waterproof emulsion, and particularly relates to an organic silicon waterproof emulsion and a preparation method and application thereof.
Background
Rock wool has the advantages of good heat preservation, low density, low heat conductivity coefficient, good sound absorption performance and the like, so the rock wool is widely applied to the field of building heat preservation materials, but rock wool materials are easy to absorb water and expand in the application process, so that the heat preservation layer is easy to lose effectiveness and fall off during the service period of a building, and the building safety is greatly damaged. In order to reduce the water absorption of rock wool products, several methods are generally used: for example, waterproof agent is added in the production process of rock wool; spraying a waterproof agent on the surface of the rock wool product; rock wool products and the like are impregnated with a waterproofing agent solution. The surface spraying and the dipping of rock wool products can not achieve a durable waterproof effect, and the addition of a waterproof agent in the production process of rock wool is the most common method at present.
Chinese patent application No. 201310017458.3 discloses an application of an organosilicon emulsion waterproof agent in an exterior wall rock wool heat-insulating material, and the organosilicon rock wool waterproof agent is prepared and mainly comprises methyl silicone oil, methyl alkoxy silicone oil, amino silicone oil and the like.
Disclosure of Invention
In order to solve the problems, the invention provides the organic silicon waterproof emulsion and the preparation method and application thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the organosilicon waterproof emulsion comprises the following raw materials in parts by weight: 5 to 25 portions of silicone oil, 5 to 10 portions of dust-proof oil, 2 to 10 portions of polyvinyl alcohol solution, 0.5 to 2.0 portions of emulsifier, 0.1 to 0.5 portion of bactericide, 0 to 0.5 portion of mildew preventive, 0.2 to 1.0 portion of defoamer and 51.0 to 87.2 portions of deionized water; wherein the silicone oil is one or a mixture of methyl silicone oil and hydroxyl silicone oil.
In a preferred embodiment of the present invention, the methyl silicone oil has a molecular weight of 500 to 3000 and the hydroxy silicone oil has a viscosity of 500 to 1500cst.
The dustproof oil is one or a mixture of SL-901, YS-600-1, YS-10, YS-010 and YS-05.
In a preferred embodiment of the present invention, the mass fraction of the polyvinyl alcohol solution is 10% to 30%.
As a preferred scheme of the invention, the emulsifier is at least one or a mixture of fatty alcohol-polyoxyethylene ether or Tween surfactant.
As a preferred scheme of the invention, the bactericide is a quaternary ammonium salt bactericide which comprises one or a combination of dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium chloride, DS-FC alkyl dimethyl benzyl ammonium chloride, polyazacyclo quaternary ammonium salt, polyquaternary ammonium salt or biquaternary ammonium salt.
As a preferable embodiment of the present invention, the mildewcide includes sorbic acid or potassium sorbate.
As a preferable aspect of the present invention, the defoaming agent includes a silicone defoaming agent.
The invention also provides a preparation method of the organic silicon waterproof emulsion, which comprises the following steps:
1) Pre-emulsification: adding an emulsifier and a polyvinyl alcohol solution into a reaction kettle, adding part of deionized water for the first time, stirring, adding silicone oil and dustproof oil in batches during stirring, adding the rest of deionized water, a bactericide and a mildew preventive for the second time, and continuously emulsifying to obtain a pre-emulsion;
2) Homogenizing and emulsifying: homogenizing and emulsifying the pre-emulsion obtained in the step 1), and adding a defoaming agent to obtain the organic silicon waterproof emulsion.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is better; centrifuging at the rotating speed of 3000r/min for 30min, and avoiding the layering phenomenon; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
As a preferred scheme of the invention, in the step 1), the adding amount of the first deionized water is 20-40% of the formula amount, the stirring speed is 1000-2000 r/min, and the stirring time is 1-2 h; in the step 2), homogenizing and emulsifying conditions are as follows: the pressure is 30-50 MPa, and the time for homogenizing and emulsifying is 5-15 min.
The invention finally provides the application of the organic silicon waterproof emulsion in the rock wool insulation board, wherein the organic silicon waterproof emulsion and phenolic resin are mixed and sprayed into rock wool fibers, and the mixture is processed and formed into the waterproof rock wool board.
Compared with the prior art, the invention has the following beneficial effects:
1) The invention uses the silicone oil with lower cost, reduces the cost and is suitable for large-scale use.
2) The invention takes water as solvent, is simple and convenient to use, and is green, safe and environment-friendly.
3) The organosilicon emulsion prepared by the invention has excellent thermal storage centrifugal performance and good stability.
4) The preparation method is simple and has mild conditions.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The raw materials used in the present invention are all commercially available.
Example 1
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials:
10kg of dimethyl silicone oil (molecular weight is 1200), 10kg of dustproof oil YS-600-1,4kg of polyvinyl alcohol solution (mass fraction is 15%), 1kg of Tween 60,0.2kg of dodecyl trimethyl ammonium chloride, 0.2kg of sorbic acid, 0.4kg of defoaming agent and 174.2kg of deionized water.
The preparation method of the (II) organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: adding 1kg of Tween 60 and 4kg of 15 mass percent polyvinyl alcohol solution in the proportion into a reaction kettle, adding 34.84kg of water, stirring at the rotating speed of 1500r/min for 1 hour, adding dimethyl silicone oil and dust-proof oil YS-600-1 for 3 times in the stirring process, adding the water of 139.36kg in the formula and 0.2kg of dodecyl trimethyl ammonium chloride and 0.2kg of sorbic acid in the formula after the oil is added, and continuing to emulsify for 1 hour.
2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 30MPa, homogenizing and emulsifying for 15min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the layering phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
Example 2
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials: 20.0kg of hydroxyl silicone oil (568 cst), 14.0kg of dustproof oil SL-901, 10.0kg of polyvinyl alcohol solution (20 percent by mass), 2.0kg of emulsifier 1310,0.4kg of dodecyl trimethyl ammonium chloride, 0.6kg of potassium sorbate, 0.6kg of defoamer and deionized water.
(II) the preparation method of the organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: 2kg of the emulsifier 1310 and 10kg of polyvinyl alcohol solution with the mass fraction of 20% in the proportion are added into a reaction kettle, 45.72kg of water is added, the mixture is stirred for 1.5h at the rotating speed of 2000r/min, the hydroxy silicone oil and the dust-proof oil SL-901 are added for 3 times in the stirring process, 6.67kg of the hydroxy silicone oil and 4.67kg of YS-600-1 are added each time, and the rest 106.68kg of water and 0.4kg of dodecyl trimethyl ammonium chloride and 0.6kg of potassium sorbate in the formula are added after the addition is finished, and the emulsification is continued for 1h.
2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 35MPa, homogenizing and emulsifying for 12min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the lamination phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
Example 3
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials:
30.0kg of hydroxyl silicone oil (1000 cst), 20.0kg of dustproof oil SL-901, 10.0kg of polyvinyl alcohol solution (the mass fraction is 15%), 2.0kg of emulsifier 1306,0.4kg of dodecyl trimethyl ammonium chloride, 0.6kg of potassium sorbate, 0.6kg of defoamer and 136.4kg of deionized water.
(II) the preparation method of the organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: adding 2kg of the emulsifier 1310 and 10kg of polyvinyl alcohol solution with the mass fraction of 15% in the proportion into a reaction kettle, adding 40.92kg of water, stirring at the rotating speed of 2000r/min for 2.0h, adding the hydroxy silicone oil and the dustproof oil SL-901 for 4 times in the stirring process, adding 10kg of the hydroxy silicone oil and 6.67kgYS-600-1 each time, adding the rest 95.48kg of water and 0.4kg of dodecyl trimethyl ammonium chloride and 0.6kg of potassium sorbate in the formula, and continuously emulsifying for 1h.
2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 40MPa, homogenizing and emulsifying for 10min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the layering phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
Example 4
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials:
30.0kg of simethicone (molecular weight 3000), 20.0kg of dustproof oil YS-10, 10.0kg of polyvinyl alcohol (25%), 2.0kg of span 80,0.4kg of biquaternary ammonium salt, 0.6kg of sorbic acid, 0.6kg of defoaming agent and 136.4kg of deionized water.
(II) the preparation method of the organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: adding 2kg of span 80 and 10kg of polyvinyl alcohol solution with the mass fraction of 25% in the proportion into a reaction kettle, adding 40.92kg of water, stirring at the rotating speed of 2000r/min for 2.0h, adding 10kg of hydroxy silicone oil and 6.67kg of dustproof oil YS-10 in 4 times in the stirring process, adding the rest 95.48kg of water and 0.4kg of biquaternary ammonium salt and 0.6kg of sorbic acid in the formula after adding, and continuing to emulsify for 1h.
(2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 35MPa, homogenizing and emulsifying for 15min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the layering phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
Example 5
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials:
30.0kg of simethicone (molecular weight 3000), 20.0kg of dustproof oil YS-010, 10.0kg of polyvinyl alcohol solution (mass fraction is 25%), 2.0kg of a mixture of span 60 and Tween 80 with the mass ratio of 1:3, 0.4kg of biquaternary ammonium salt, 0.6kg of sorbic acid, 0.6kg of defoaming agent and 136.4kg of deionized water.
(II) the preparation method of the organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: 2kg of the mixture of span 60 and Tween 80 with the mass ratio of 1:3 and 10kg of polyvinyl alcohol solution with the mass fraction of 25% are added into a reaction kettle, 40.92kg of water is added, the mixture is stirred for 2.0 hours at the rotating speed of 2000r/min, the hydroxy silicone oil and the dustproof oil YS-010 are added for 4 times in the stirring process, 10kg of the hydroxy silicone oil and 6.67kg of the dustproof oil YS-010 are added each time, and after the addition is finished, the rest 95.48kg of water, 0.4kg of biquaternary ammonium salt and 0.6kg of sorbic acid in the formula are added, and the emulsification is continued for 1 hour.
2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 35MPa, homogenizing and emulsifying for 15min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material. The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the layering phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs. Example 6
This example provides a silicone water-resistant emulsion.
The organosilicon waterproof emulsion is prepared from the following raw materials:
30.0kg of simethicone (molecular weight 4000), 20.0kg of dustproof oil YS-05, 10.0kg of polyvinyl alcohol solution (mass fraction is 25%), 2.0kg of a mixture of emulsifier 1310 and tween 80 in a mass ratio of 1:2, 0.4kg of polyazacyclic quaternary ammonium salt, 0.6kg of sorbic acid, 0.6kg of defoaming agent and 136.4kg of deionized water.
(II) the preparation method of the organosilicon waterproof emulsion comprises the following steps:
1) Pre-emulsification: 2kg of the mixture of 1310 and Tween 80 with the mass ratio of 1:2 and 10kg of polyvinyl alcohol solution with the mass fraction of 25% are added into a reaction kettle, 40.92kg of water is added, the mixture is stirred for 2.0h at the rotating speed of 2000r/min, the hydroxy silicone oil and the dust-proof oil YS-05 are added for 4 times in the stirring process, 10kg of the hydroxy silicone oil and 6.67kg of the dust-proof oil YS-05 are added each time, and after the addition is finished, the rest 95.48kg of water and 0.4kg of biquaternary ammonium salt and 0.6kg of sorbic acid in the formula are added for continuous emulsification for 1h.
2) Homogenizing and emulsifying: placing the pre-emulsion obtained in the step 1) into a high-pressure homogenizer with the pressure of 35MPa, homogenizing and emulsifying for 15min, and finally adding a defoaming agent to prepare the high-performance organic silicon waterproof emulsion for the low-cost exterior wall rock wool heat-insulating material.
The prepared organosilicon waterproof emulsion is white emulsion in appearance; the compatibility with phenolic resin is good, and the layering phenomenon does not occur after the centrifugal separation at the rotating speed of 3000r/min for 30 min; the emulsion is placed at 50 +/-2 ℃ for 7 days, and no layering phenomenon occurs.
Example 7
The embodiment provides an application performance test of a low-cost high-performance organosilicon waterproof emulsion in a rock wool insulation board
1) Compatibility with phenolic resin test: and uniformly mixing the rock wool waterproof agent and the phenolic resin according to the mass ratio of 1.
2) Centrifugal stability: 10mL of rock wool waterproofing agent is put into a centrifuge tube, and is centrifuged for 30min on a centrifuge at the rotating speed of 3000r/min, and then the rock wool waterproofing agent is taken out to observe whether the emulsion is layered with floating oil or not, and the phenomena of floating oil and layering are not generated in the experiment.
3) Thermal stability: 200g of the waterproof agent is put into a transparent plastic bottle, the plastic bottle is covered, the plastic bottle is placed in an oven at 50 +/-2 ℃ for 7 days, and then the plastic bottle is taken out to observe the emulsion, so that the layering phenomenon does not occur.
4) And (3) testing the waterproof performance of the organic silicon waterproof emulsion in the rock wool board: according to the national standard GB/T25975-2018, a customer is entrusted with a production line to produce the rock wool board added with the organic silicon waterproof emulsion.
For each example, 5 rock wool panels of 200mm x 200mm were cut and tested for water repellency and water absorption by volume and for long term water absorption (28 d), as shown in table 1.
TABLE 1 EXAMPLES 1 TO 6 physicochemical and water-repellent Effect test results of water-repellent agent
While the invention has been described with respect to a preferred embodiment, it will be understood by those skilled in the art that the foregoing and other changes, omissions and deviations in the form and detail thereof may be made without departing from the scope of this invention. Those skilled in the art can make various changes, modifications and equivalent arrangements, which are equivalent to the embodiments of the present invention, without departing from the spirit and scope of the present invention, and which may be made by utilizing the techniques disclosed above; meanwhile, any equivalent changes, modifications and evolutions of the above embodiments according to the essential technology of the present invention are still within the scope of the technical solution of the present invention.
Claims (10)
1. The organic silicon waterproof emulsion is characterized by comprising the following raw materials in parts by weight: 5 to 25 portions of silicone oil, 5 to 10 portions of dustproof oil, 2 to 10 portions of polyvinyl alcohol solution, 0.5 to 2.0 portions of emulsifier, 0.1 to 0.5 portion of bactericide, 0 to 0.5 portion of mildew preventive, 0.2 to 1.0 portion of defoamer and 51.0 to 87.2 portions of deionized water; wherein the silicone oil is one or a mixture of two of methyl silicone oil and hydroxyl silicone oil.
2. The waterproof silicone emulsion of claim 1, wherein the molecular weight of the methyl silicone oil is 500-3000, and the viscosity of the hydroxy silicone oil is 500-1500cst.
3. The waterproof silicone emulsion according to claim 1, wherein the mass fraction of the polyvinyl alcohol solution is 10% to 30%.
4. The waterproof silicone emulsion of claim 1, wherein the emulsifier is at least one or a mixture of fatty alcohol-polyoxyethylene ether or tween surfactant.
5. The organosilicon waterproof emulsion according to claim 1, wherein the bactericide is a quaternary ammonium salt bactericide comprising one or a combination of dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium chloride, DS-FC alkyl dimethyl benzyl ammonium chloride, polyazacyclic quaternary ammonium salt, polyquaternary ammonium salt or diquaternary ammonium salt.
6. The silicone water-resistant emulsion according to claim 1, wherein the mildewcide comprises sorbic acid or potassium sorbate.
7. The silicone water-resistant emulsion according to claim 1, wherein the defoamer comprises a silicone defoamer.
8. A process for the preparation of the silicone water-repellent emulsion according to any one of claims 1 to 7, comprising the steps of:
1) Pre-emulsification: adding an emulsifier and a polyvinyl alcohol solution into a reaction kettle, adding part of deionized water for the first time, stirring, adding silicone oil and dustproof oil in batches during stirring, adding the rest of deionized water, a bactericide and a mildew preventive for the second time, and continuously emulsifying to obtain a pre-emulsion;
2) Homogenizing and emulsifying: homogenizing and emulsifying the pre-emulsion obtained in the step 1), and adding a defoaming agent to obtain the organic silicon waterproof emulsion.
9. The preparation method of the organosilicon waterproof emulsion according to claim 8, characterized in that in step 1), the adding amount of the first deionized water is 20% -40% of the formula amount, the stirring speed is 1000-2000 r/min, and the stirring time is 1-2 h; in the step 2), homogenizing and emulsifying conditions are as follows: the pressure is 30-50 MPa, and the time for homogenizing and emulsifying is 5-15 min.
10. The application of the organosilicon waterproof emulsion as claimed in any one of claims 1 to 7, wherein the organosilicon waterproof emulsion is applied to rock wool insulation boards, and the organosilicon waterproof emulsion is mixed with phenolic resin, sprayed into rock wool fibers, and then processed into waterproof rock wool boards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211143039.XA CN115418004A (en) | 2022-09-20 | 2022-09-20 | Organic silicon waterproof emulsion and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211143039.XA CN115418004A (en) | 2022-09-20 | 2022-09-20 | Organic silicon waterproof emulsion and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115418004A true CN115418004A (en) | 2022-12-02 |
Family
ID=84203353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211143039.XA Pending CN115418004A (en) | 2022-09-20 | 2022-09-20 | Organic silicon waterproof emulsion and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115418004A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580356A (en) * | 2009-06-26 | 2009-11-18 | 郭元华 | Water-emulsion organic silicon waterproof agent |
| CN103043945A (en) * | 2013-01-17 | 2013-04-17 | 山东环绿康新材料科技有限公司 | Application of organic silicone emulsion waterproof agent in outer wall rock wool heat insulating material waterproof agent |
| CN103911104A (en) * | 2014-01-06 | 2014-07-09 | 河北金源建材科技有限公司 | Lignin rock wool phenolic resin binder and its preparation method and use method |
| CN103922638A (en) * | 2014-03-24 | 2014-07-16 | 成都理工大学 | Preparation method of mortar concrete waterproof agent |
| KR20170002769A (en) * | 2015-06-29 | 2017-01-09 | 주식회사 케이씨씨 | Waterproof agent for a gypsum board and a method for preparing waterproofing gypsum board using the same |
| WO2017131400A1 (en) * | 2016-01-28 | 2017-08-03 | 주식회사 인실리코 | Water-repellent agent of silicone-based emulsion and fabric water-repellent processing method using same |
| CN108729235A (en) * | 2018-07-05 | 2018-11-02 | 南雄鼎成新材料科技有限公司 | A kind of preparation method and application of single-component low temperature solidification superhydrophobic fabric waterproofing agent |
| KR20190126575A (en) * | 2018-05-02 | 2019-11-12 | 주식회사 인실리코 | Silicone-based water repellent for thermal insulator and thermal insulator using the same |
| CN112062498A (en) * | 2020-09-11 | 2020-12-11 | 杭州埃比森新材料有限公司 | Self-emulsifying type organic silicon powder water repellent and preparation method thereof |
-
2022
- 2022-09-20 CN CN202211143039.XA patent/CN115418004A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580356A (en) * | 2009-06-26 | 2009-11-18 | 郭元华 | Water-emulsion organic silicon waterproof agent |
| CN103043945A (en) * | 2013-01-17 | 2013-04-17 | 山东环绿康新材料科技有限公司 | Application of organic silicone emulsion waterproof agent in outer wall rock wool heat insulating material waterproof agent |
| CN103911104A (en) * | 2014-01-06 | 2014-07-09 | 河北金源建材科技有限公司 | Lignin rock wool phenolic resin binder and its preparation method and use method |
| CN103922638A (en) * | 2014-03-24 | 2014-07-16 | 成都理工大学 | Preparation method of mortar concrete waterproof agent |
| KR20170002769A (en) * | 2015-06-29 | 2017-01-09 | 주식회사 케이씨씨 | Waterproof agent for a gypsum board and a method for preparing waterproofing gypsum board using the same |
| WO2017131400A1 (en) * | 2016-01-28 | 2017-08-03 | 주식회사 인실리코 | Water-repellent agent of silicone-based emulsion and fabric water-repellent processing method using same |
| KR20190126575A (en) * | 2018-05-02 | 2019-11-12 | 주식회사 인실리코 | Silicone-based water repellent for thermal insulator and thermal insulator using the same |
| CN108729235A (en) * | 2018-07-05 | 2018-11-02 | 南雄鼎成新材料科技有限公司 | A kind of preparation method and application of single-component low temperature solidification superhydrophobic fabric waterproofing agent |
| CN112062498A (en) * | 2020-09-11 | 2020-12-11 | 杭州埃比森新材料有限公司 | Self-emulsifying type organic silicon powder water repellent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113045915A (en) | Fireproof aerogel heat-preservation and heat-insulation middle coating and preparation method thereof | |
| CN105293992B (en) | A kind of timber high-effective penetrating type waterproofing agent of organosilicon and preparation method thereof | |
| CN106147471A (en) | A kind of preparation method of the thermal insulation coatings with water proof anti-soil performance | |
| CN113248981A (en) | Graphene modified water-based elastic coating and preparation method thereof | |
| CN115418004A (en) | Organic silicon waterproof emulsion and preparation method and application thereof | |
| CN103642467B (en) | low-fluorescence anti-blocking lubricant for drilling fluid and preparation method thereof | |
| CN108948932B (en) | Heat-preservation and heat-insulation coating and preparation method thereof | |
| CN105060737B (en) | Hydrophober, its preparation method and its application | |
| CN111732445A (en) | Preparation method of durable composite waterproof material for concrete | |
| CN112521855A (en) | Preparation method of high-weather-resistance heat-insulation composite coating | |
| CN113999583A (en) | Ultrathin flame-retardant water-based paint for manufacturing tank and preparation method thereof | |
| CN108084860B (en) | Environment-friendly heat-insulating coating and preparation method thereof | |
| CN107556050A (en) | A kind of low volatilization environment-friendly type silane Impregnation and preparation method thereof | |
| CN112778813A (en) | Environment-friendly high-temperature-resistant waterproof epoxy coating and preparation process thereof | |
| CN112266198A (en) | Elastic heat-insulating slurry and preparation method thereof | |
| CN110028902B (en) | Paraffin emulsion waterproof agent and preparation method thereof | |
| CN106590118A (en) | Heat insulation and heat preservation coating for building external wall and preparation method thereof | |
| CN111517736A (en) | Light non-combustible sound insulation board and preparation method thereof | |
| CN117801527A (en) | Organosilicon waterproof emulsion for heat insulating material, and preparation method and application thereof | |
| CN115193104A (en) | Special defoaming agent for coal chemical industry desulfurization system and preparation method thereof | |
| CN113637112A (en) | Acrylic emulsion for kraft paper, preparation method and application thereof | |
| CN107722681A (en) | A kind of aqueous insulation insulating moulding coating and preparation method thereof | |
| CN104327616B (en) | Glass-wool inorganic heat-insulating coating | |
| CN111117691A (en) | Mineral oil defoaming auxiliary agent for water-based paint and preparation method thereof | |
| CN112646401A (en) | Inorganic heat-insulating heat-preserving paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20221202 |